CN109722885A - A kind of preparation method of type of heat heat accumulation thermal comfortable textile product - Google Patents

A kind of preparation method of type of heat heat accumulation thermal comfortable textile product Download PDF

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Publication number
CN109722885A
CN109722885A CN201811596222.9A CN201811596222A CN109722885A CN 109722885 A CN109722885 A CN 109722885A CN 201811596222 A CN201811596222 A CN 201811596222A CN 109722885 A CN109722885 A CN 109722885A
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China
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heat
textile product
type
preparation
moisture absorption
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CN201811596222.9A
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Chinese (zh)
Inventor
魏取福
张倩
李大伟
韩梦臣
刘畅
王卓
王小虎
李其安
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Jiangnan University
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Jiangnan University
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Abstract

The invention discloses a kind of preparation methods of type of heat heat accumulation thermal comfortable textile product comprising, it prepares coating solution: phase-change microcapsule, the mixing of crosslinking agent ultrasound is configured to coating solution;Electrostatic spraying: by the coating solution electrostatic spraying in moisture absorption heating fabric;Drying solidification: drying, flint dry solidification obtain type of heat heat accumulation thermal comfortable textile product of the present invention.Temperature adjustment accumulation of heat principle of the invention is essentially different with traditional heat insulating material, it preferably solves the problems, such as that clothing is lightening to adjust with temperature, the time of moisture absorption heating is extended, and moisture absorption heating performance obtains larger raising, and ambient humidity is higher, moisture absorption heating performance is better, wetness guiding perspiration discharging and surface smoothness energy are improved, under the premise of heat generating and retention, increases moisture absorption sweat discharging functions, and the comfort level and pleasant softness on surface are enhanced, so that clothing comfort is guaranteed.

Description

A kind of preparation method of type of heat heat accumulation thermal comfortable textile product
Technical field
The invention belongs to the preparation technical fields of textile, and in particular to a kind of type of heat heat accumulation thermal comfortable textile The preparation method of product.
Background technique
Warming is the important indicator of water clothes comfort, and the warming mode of clothes is generally divided into two classes: positive type Warming and passive type is warming.Positive type is warming to refer to that, by introducing extraneous heating element, the autonomous heat that generates reaches warming Purpose.Warming passive type is then to control the content of still air layer by the thickness of increase and decrease clothes itself, prevent the heat of human body It scatters and disappears outward, it is warming to achieve the purpose that.With the fast development and continuous improvement of people's living standards of science and technology, passively The warming traditional heat insulating material of formula has been unable to satisfy requirement of the modern people to clothes, and people are to fabric and clothes utility function It is required that tending to diversification, therefore actively the exploitation of heat production formula heat insulating material is of great significance.
Due to moisture absorption heating principle exploitation thermal fiber material can only active heat production, cannot cope with and not need amount of heat Situation.For the problems of moisture absorption heating principle and phase-change accumulation energy principle, how to prepare one kind and both adapted to colder ring Border, but the intelligent fiber for adapting to human body fever perspiration situation is that have technical problem to be solved.
Summary of the invention
The purpose of this section is to summarize some aspects of the embodiment of the present invention and briefly introduce some preferable implementations Example.It may do a little simplified or be omitted to avoid our department is made in this section and the description of the application and the title of the invention Point, the purpose of abstract of description and denomination of invention it is fuzzy, and this simplification or omit and cannot be used for limiting the scope of the invention.
In view of above-mentioned technological deficiency, the present invention is proposed.
Therefore, as one aspect of the present invention, the present invention overcomes the deficiencies in the prior art, provides a kind of new The preparation method of type fever heat accumulation thermal comfortable textile product.
In order to solve the above technical problems, the present invention provides the following technical scheme that a kind of type of heat heat accumulation thermal is comfortable The preparation method of property textile comprising,
It prepares coating solution: phase-change microcapsule, the mixing of crosslinking agent ultrasound is configured to coating solution;
Electrostatic spraying: by the coating solution electrostatic spraying in moisture absorption heating fabric;
Drying solidification: drying, flint dry solidification obtain type of heat heat accumulation thermal comfortable textile product of the present invention.
A kind of preferred embodiment of preparation method as type of heat heat accumulation thermal comfortable textile product of the present invention: The phase-change microcapsule, preparation method include,
The TDI of the compound paraffin of 2g and 1g is dissolved in 20mL cyclohexane solvent, until completely molten in 70 DEG C of waters bath with thermostatic control Uniformly mixed oil-based system is made in solution, stirring;
It weighs 0.15gOP-10 to be added in the beaker equipped with 10mL distilled water, uniformly mixed aqueous phase system is made in stirring;
The oil-based system is poured into the aqueous phase system beaker, 10min is stirred on mulser, W/O lotion is made;
The EDA aqueous solution of 1g is slowly poured into above-mentioned W/O lotion, it is 9 that sodium hydroxide, which is added, and adjusts PH, 60~ It is stirred to react 2h in 80 DEG C of waters bath with thermostatic control, water washing is distilled, filtered, it is dry, obtain the phase-change microcapsule.
A kind of preferred embodiment of preparation method as type of heat heat accumulation thermal comfortable textile product of the present invention: It is that 4:6 is mixed at 90 DEG C and compounded that the compound paraffin, which is solid paraffin, with liquid according to mass ratio.
A kind of preferred embodiment of preparation method as type of heat heat accumulation thermal comfortable textile product of the present invention: The mass ratio of the phase-change microcapsule and the crosslinking agent is 2:1, and in the coating solution, the quality of the phase-change microcapsule is accounted for Than being 30%, the quality accounting of the crosslinking agent is 15%.
A kind of preferred embodiment of preparation method as type of heat heat accumulation thermal comfortable textile product of the present invention: The crosslinking agent is AF3200.
A kind of preferred embodiment of preparation method as type of heat heat accumulation thermal comfortable textile product of the present invention: The electrostatic spraying, velocity pressure 0.45MPa, electrostatic potential 70KV, pressure 0.45MPa, syringe needle is to receiving tinfoil Distance is 250mm.
A kind of preferred embodiment of preparation method as type of heat heat accumulation thermal comfortable textile product of the present invention: The moisture absorption heating fabric is modified acrylic fibers fabric.
A kind of preferred embodiment of preparation method as type of heat heat accumulation thermal comfortable textile product of the present invention: The flint dry solidification, temperature are 140 DEG C.
A kind of preferred embodiment of preparation method as type of heat heat accumulation thermal comfortable textile product of the present invention: It further include before electrostatic spraying, the moisture absorption heating fabric being put into baking oven and is dried.
A kind of preferred embodiment of preparation method as type of heat heat accumulation thermal comfortable textile product of the present invention: The electrostatic spraying, including by the coating solution electrostatic spraying in the single or double of moisture absorption heating fabric
Beneficial effects of the present invention: temperature adjustment accumulation of heat principle of the invention is essentially different with traditional heat insulating material, compared with It solves the problems, such as that clothing is lightening well to adjust with temperature, the fabric arranged through the present invention, the time of moisture absorption heating obtains Extend, moisture absorption heating performance obtains larger raising, and ambient humidity is higher, and moisture absorption heating performance is better.Present invention improves lead Wet perspire increases moisture absorption sweat discharging functions under the premise of heat generating and retention with surface smoothness energy, and enhances relaxing for surface Appropriateness and pleasant softness make clothing comfort be guaranteed.It, can be under conditions of equally warming function using the present invention Thinner clothing is produced, so that raw material are conserved.Therefore the present invention is more economical, more has practicability, actually makes It is stronger with expection;This fibrous material of the present invention, can be further processed into fabric, can be widely used for knitted underwear, gym suit, wind Clothing, jacket, insulated cold wear, overcoat, cold-proof footwear, bedding etc..The present invention can be made into pattern beauty, light and warm comfortable clothes, be used for All kinds of textiles are made, and then realize that the intelligent of people's dress ornament adjusts temperature, keeps it more frivolous, wears more comfortable;This Two kinds of involved structures of invention, three kinds of weather microenvironments can satisfy the warming requirement under different condition, more adapt to work as Biggish circumstances is differed with outdoor temperature for the interior that people often faces.
Detailed description of the invention
In order to illustrate the technical solution of the embodiments of the present invention more clearly, required use in being described below to embodiment Attached drawing be briefly described, it should be apparent that, drawings in the following description are only some embodiments of the invention, for this For the those of ordinary skill of field, without any creative labor, it can also be obtained according to these attached drawings other Attached drawing.Wherein:
Fig. 1 is tri- kinds of structural schematic diagrams of A, B, C of type of heat heat accumulation thermal comfortable textile product of the invention.
Specific embodiment
In order to make the foregoing objectives, features and advantages of the present invention clearer and more comprehensible, right combined with specific embodiments below A specific embodiment of the invention is described in detail.
In the following description, numerous specific details are set forth in order to facilitate a full understanding of the present invention, but the present invention can be with Implemented using other than the one described here other way, those skilled in the art can be without prejudice to intension of the present invention In the case of do similar popularization, therefore the present invention is not limited by the specific embodiments disclosed below.
Secondly, " one embodiment " or " embodiment " referred to herein, which refers to, may be included at least one realization side of the invention A particular feature, structure, or characteristic in formula." in one embodiment " that different places occur in the present specification not refers both to The same embodiment, nor the individual or selective embodiment mutually exclusive with other embodiments.
Embodiment 1:
It takes the moisture absorption heating fabric of 35cmX35cm to be put into baking oven to drying, takes phase-change microcapsule 30g, crosslinking agent AF3200 Incorporated in water for 15g and 100g solution be made and stirs evenly it by ultrasonic wave coating is made, using electrostatic painting process to Moisture absorption heating fabric front or back or obverse and reverse spraying stirring gained coating after drying, obtain required textile, most The textile is placed baking oven afterwards extremely to dry, then is solidified with 140 celsius temperature dryings, type of heat accumulation of heat of the present invention is obtained and protects Warm comfortable textile product.
Electrostatic painting process design parameter are as follows:
Velocity pressure: 0.45MPa, electrostatic potential: 70KV, pressure: 0.45MPa, syringe needle is to receiving tinfoil distance: 250mm.
Electrostatic coating method of the present invention is coated compared to other spraying methods, such as directly, significantly extends moisture absorption heating Fabric generated heat to the time used of maximum value, reached the heat production coefficient and lasting heat release warming effect for improving moisture absorption heating fabric. The study found that by phase-change microcapsule electrostatic spraying on moisture absorption heating fabric, so that phase-change microcapsule and moisture absorption heating fabric produce Synergistic effect has been given birth to, the heat production coefficient and lasting heat release warming effect of fabric are collectively promoted.Electrostatic painting process is sent out for extending The hot time is particularly significant, and after changing electrostatic painting process parameter of the present invention, velocity pressure is such as changed to 0.8MPa, electrostatic electricity Pressure: 90KV, pressure: 0.7MPa, for syringe needle to tinfoil is received after being 350mm, fever time shortens 20%.
It has been investigated that the selection of crosslinking agent of the present invention and proportion directly affect the time of moisture absorption heating, crosslinking agent is preferred For AF3200, crosslinking agent AF3200 is replaced with into other substances, after NJ101, fever time shortens 15%.
The preferred modified acrylic fibers fabric of moisture absorption heating fabric (Japan provided by Wei Feng Textile Co., Ltd., Shenzhen of the present invention Spin Acrylic Fiber fabric).
In the present invention, the coating of phase-change microcapsule pulvis single side forms the external world-moisture absorption heating fabric-phase-change material (i.e. phase Become microcapsule powder)-human body or the external world-phase-change material-moisture absorption heating fabric-two kinds of human body structure (structure A, B in Fig. 1); Or
Phase-change microcapsule pulvis dual coating forms the external world-phase-change material-moisture absorption heating fabric-phase-change material-people The structure (structure C in Fig. 1) of body.
Fig. 1 is tri- kinds of structural schematic diagrams of A, B, C of type of heat heat accumulation thermal comfortable textile product of the invention.Through surveying Examination, structure A textile rise to 40 DEG C by 15 DEG C and need 40min, drop to 15 DEG C from 40 DEG C and need 27min or so;Structure B is by 15 DEG C It rises to 40 DEG C and needs 30min or so, drop to 15 DEG C from 40 DEG C and need 23min or so;Structure C rises to 40 DEG C of needs by 15 DEG C 50min drops to 15 DEG C from 40 DEG C and needs 30min or so.Common Hygroscopic material rises to 40 DEG C by 15 DEG C and needs 5min, drops from 40 DEG C 7min is needed to 15 DEG C.Meanwhile the present invention using Electrostatic Spray Technology preparation product and common starching, pad, be sprayed, applying Treated that product is compared for equal method for sorting, substantially prolongs soaking time, soaking time improves 30% or more.
The characteristics of the characteristics of present invention combination hygroscopic heating fibers " active " generate heat and phase-change energy-storage fibre " passive " fever, It develops one kind and had not only adapted to colder environment, but also adapt to the intelligent fiber of human body fever perspiration situation.It plays phase-changing and temperature-regulating and inhales Wet exothermic synergistic effect, moisture absorption heating fabric can be absorbed by the heat issued after moisture absorption by phase-change microcapsule, to prolong The fever of moisture absorption heating fabric has been grown to the time used of maximum value, is reached the heat production coefficient for improving moisture absorption heating fabric and is persistently put Hot warming effect, but the maximum calorific value of moisture absorption heating fabric can be also reduced simultaneously, the microcapsules of surface coating also can slightly press down The hygroscopicity of moisture absorption heating fabric processed.The fabric that scheme obtains through the invention has the function of the heat accumulation thermal that generates heat, and utilizes solid-liquid The conversion of state can initiatively, intelligently control the temperature of surrounding, form " micro climate " environment, sufficiently sent out using phase-changing and temperature-regulating material The effect of moisture absorption heating fabric is waved, to realize that using energy source maximizes, and solves that winter clothes is excessively too fat to move but warming effect Still unsatisfactory problem meets modern people to comfortable features of clothing, functionality.
Embodiment 2:
In embodiment 1, phase-change microcapsule is that the core material as made from in-situ polymerization interfacial polymerization is octadecane, and shell material is Synthesize the phase-change microcapsule of polyureas.Required substance: TDI (2,4-diisocyanate of toluene), OP-10 (octyl phenol polyoxyethanyl Ether), EDA (ethylenediamine), hexamethylene, atoleine, solid paraffin.Preparation method: by the compound paraffin of 2g, (solid paraffin 5g, is pressed The atoleine for weighing different quality according to different quality proportion mixes at 90 DEG C, melts, stirs evenly, compound paraffin is made) It is dissolved in 20mL cyclohexane solvent with 1g TDI, until being completely dissolved in 70 DEG C of waters bath with thermostatic control, stirs, be made and be uniformly mixed Oil-based system;It weighs 0.15g OP10 to be added in the beaker equipped with 10mL distilled water, uniformly mixed water phase body is made in stirring System;Above-mentioned oil is mutually poured into water phase beaker, 10min is stirred with certain mixing speed on mulser, W/O cream is made Liquid;1gEDA aqueous solution (molar ratio 1:1) is slowly poured into above-mentioned W/O lotion, it is 9 that sodium hydroxide, which is added, and adjusts PH, It is stirred to react 2h in 60~80 DEG C of waters bath with thermostatic control, water washing is distilled, filtered, it is dry, paraffin/PU phase-change microcapsule is obtained, is wrapped Include the pulvis of phase-change microcapsule, phase transformation lotion and the solid-liquid mixed dispersion of other forms phase-change material etc..Pass through experiment It was found that the coating effect of phase transformation lotion is good not as good as pulvis effect, still preferred phase transformation capsule powder.
To sum up, temperature adjustment accumulation of heat principle of the invention is essentially different with traditional heat insulating material, preferably solves clothing The problem of object is lightening and temperature is adjusted, the fabric arranged through the present invention, the time of moisture absorption heating is extended, moisture absorption heating Performance obtains larger raising, and ambient humidity is higher, and moisture absorption heating performance is better.
Present invention improves wetness guiding perspiration dischargings and surface smoothness energy, under the premise of heat generating and retention, increase moisture absorbing and sweat releasing Function, and the comfort level and pleasant softness on surface are enhanced, so that clothing comfort is guaranteed.
Using the present invention, thinner clothing can be produced under conditions of equally warming function, so that raw material obtain To save.Therefore the present invention is more economical, more has practicability, and actual use expection is stronger;
Fibrous material of the present invention can be further processed into fabric, realize that the intelligent of people's dress ornament adjusts temperature, make it more Add light and comfortable.
It is involved in the present invention to two kinds of structures, three kinds of weather microenvironments can satisfy the warming requirement under different condition, It more adapts to the interior that contemporary people often faces and differs biggish circumstances with outdoor temperature.
It should be noted that the above examples are only used to illustrate the technical scheme of the present invention and are not limiting, although referring to preferable Embodiment describes the invention in detail, those skilled in the art should understand that, it can be to technology of the invention Scheme is modified or replaced equivalently, and without departing from the spirit and scope of the technical solution of the present invention, should all be covered in this hair In bright scope of the claims.

Claims (10)

1. a kind of preparation method of type of heat heat accumulation thermal comfortable textile product, it is characterised in that: including,
It prepares coating solution: phase-change microcapsule, the mixing of crosslinking agent ultrasound is configured to coating solution;
Electrostatic spraying: by the coating solution electrostatic spraying in moisture absorption heating fabric;
Drying solidification: drying, flint dry solidification obtain type of heat heat accumulation thermal comfortable textile product of the present invention.
2. the preparation method of type of heat heat accumulation thermal comfortable textile product as described in claim 1, it is characterised in that: described Phase-change microcapsule, preparation method include,
The TDI of the compound paraffin of 2g and 1g is dissolved in 20mL cyclohexane solvent, until being completely dissolved in 70 DEG C of waters bath with thermostatic control, is stirred It mixes, uniformly mixed oil-based system is made;
It weighs 0.15gOP-10 to be added in the beaker equipped with 10mL distilled water, uniformly mixed aqueous phase system is made in stirring;
The oil-based system is poured into the aqueous phase system beaker, 10min is stirred on mulser, W/O lotion is made;
The EDA aqueous solution of 1g is slowly poured into above-mentioned W/O lotion, it is 9 that sodium hydroxide, which is added, and adjusts PH, at 60~80 DEG C It is stirred to react 2h in water bath with thermostatic control, is distilled water washing, filtered, it is dry, obtain the phase-change microcapsule.
3. the preparation method of type of heat heat accumulation thermal comfortable textile product as claimed in claim 2, it is characterised in that: described It is that 4:6 is mixed at 90 DEG C and compounded that compound paraffin, which is solid paraffin, with liquid according to mass ratio.
4. the preparation method of the type of heat heat accumulation thermal comfortable textile product as described in claims 1 to 3 is any, feature exist In the mass ratio of: the phase-change microcapsule and the crosslinking agent be 2:1, in the coating solution, the matter of the phase-change microcapsule Measuring accounting is 30%, and the quality accounting of the crosslinking agent is 15%.
5. the preparation method of type of heat heat accumulation thermal comfortable textile product as claimed in claim 4, it is characterised in that: described Crosslinking agent is AF3200.
6. the preparation method of the type of heat heat accumulation thermal comfortable textile product as described in any in claims 1 to 3,5, special Sign is: the electrostatic spraying, velocity pressure 0.45MPa, electrostatic potential 70KV, pressure 0.45MPa, and syringe needle is to connecing It is 250mm by tinfoil distance.
7. the preparation method of the type of heat heat accumulation thermal comfortable textile product as described in any in claims 1 to 3,5, special Sign is: the moisture absorption heating fabric is modified acrylic fibers fabric.
8. the preparation method of the type of heat heat accumulation thermal comfortable textile product as described in any in claims 1 to 3,5, special Sign is: the flint dry solidification, temperature are 140 DEG C.
9. the preparation method of the type of heat heat accumulation thermal comfortable textile product as described in any in claims 1 to 3,5, special Sign is: further including before electrostatic spraying, the moisture absorption heating fabric being put into baking oven and is dried.
10. such as the preparation method of the type of heat heat accumulation thermal comfortable textile product as described in any in claims 1 to 3,5, It is characterized by: the electrostatic spraying, including by the coating solution electrostatic spraying in the single or double of moisture absorption heating fabric.
CN201811596222.9A 2018-12-26 2018-12-26 A kind of preparation method of type of heat heat accumulation thermal comfortable textile product Pending CN109722885A (en)

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CN111411533A (en) * 2020-04-17 2020-07-14 成都新柯力化工科技有限公司 Method for preparing graphene heating non-woven fabric through roll-to-roll printing
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CN111411533A (en) * 2020-04-17 2020-07-14 成都新柯力化工科技有限公司 Method for preparing graphene heating non-woven fabric through roll-to-roll printing
CN114197220A (en) * 2021-11-12 2022-03-18 福建江夏学院 Cloth structure with heat insulation layer and preparation method thereof
CN114197220B (en) * 2021-11-12 2023-12-08 徐州市海格德生物科技有限公司 Cloth structure with heat preservation layer and preparation method thereof

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