CN109720071A - A kind of cloth seam construction and the preparation method and application thereof - Google Patents
A kind of cloth seam construction and the preparation method and application thereof Download PDFInfo
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- CN109720071A CN109720071A CN201711023231.4A CN201711023231A CN109720071A CN 109720071 A CN109720071 A CN 109720071A CN 201711023231 A CN201711023231 A CN 201711023231A CN 109720071 A CN109720071 A CN 109720071A
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Landscapes
- Laminated Bodies (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
The invention discloses a kind of cloth seam constructions and the preparation method and application thereof.The cloth seam construction includes at least two cloth products layers, the cloth products layer includes thermoplastic resin fibre's product layer, or, the cloth products layer includes thermoplastic resin fibre's product layer and the liquid barrier material layer for being set to thermoplastic resin fibre's product layer surface, the seam crossing of two cloth products layers is provided with Resin adhesive layer at least in, it is sealingly engaged two cloth products layers, the Resin adhesive layer is formed by curing by the response type adhesive that can be set to the cloth products layer surface and/or inside.Cloth seam construction of the invention and corresponding clothing such as medical operating clothes, medical protection clothes etc. have the function of high stable liquid barrier property and anti-virus, while having performances, the application prospects such as durable and high-tenacity extensive.
Description
Technical field
The present invention relates to a kind of cloth seam construction product, more particularly to it is a kind of based on textile, non-woven fabrics and its spread out
Raw joint product medical operating clothes, industrial protection clothes etc. seam converted products.
Background technique
Textile, non-woven fabrics and a variety of composite materials derived from it have been widely used in various clothing finished products at present, such as
Ordinary clothing, medical operating clothing, medical protection clothes, industrial protection clothes etc..In ready-made clothes machining process, cloth, which needs, to be connect
Seam.Such as coat-sleeve, shoulder, neckline.Common joint technique has sewing, ultrasonic compressing, thermal-adhering etc..
In application aspects such as medical operating clothes, barrier gown, medical protection clothes, industrial protection clothes, it is necessary to have very high resistances
It every property, prevents in its application environment, such as hospital operating room, epidemic-stricken area, chemical plant, disaster field application places, hazardous substance
Such as body fluid, blood, bacterial virus, soda acid liquid, toxic organic compound pass through clothes and damage human body.
To meet the above demand, have above in the designing and manufacturing of the clothes of physical protection function, on the one hand, logical
It crosses and uses the Strand Feeding Techniques such as feltwork weaving and non-woven fabrics and the progress of cloth and film compound, there are clothing materials and hinder
Every property.On the other hand, it at the positions such as the seam of cloth, connector, such as coat-sleeve seam, shoulder seam, cuff, needs by effective
Method guarantees the sealing of seam crossing, so that finished garment be made to have fine protective performance.Meanwhile medical operating clothes are needed by ring
Oxidative ethane or steam sterilizing processing, seam crossing need to keep after these sterilising conditions stable sealing effect.
However, sewing, ultrasonic compressing and thermal-adhering these traditional seaming methods have respective defect.Use linear slit
The method threaded is actually and not formed strict seam.Gap and needle-penetration line between cloth is practical to the destruction of cloth
On make seam crossing that can not form strict barriering effect to the various liquid that endanger.Typical such as industrial protection takes, and passes through sewer
After skill carries out coat-sleeve seam, generally require seam crossing again adhesive tape to reach sealing effect.Ultrasound involves heat sealing technology
Principle is to make two panels cloth be softened or melted to form one in seam crossing local heating cloth by ultrasound or hot pressing item, it
Cooling forms seam construction product after restoring solid state afterwards.By taking polypropylene non-woven fabric as an example, temperature reaches 130 degrees Celsius or more
When, polypropylene starts to soften and gradually melt, thus the fusible melt for forming one of two panels cloth seam crossing.
Ultrasonic wave and hot pressing both methods theoretically can form continuous closely sealed seam in seam crossing, to be formed
Good barriering effect achievees the purpose that protection endangers liquid.However, both methods is in large-scale production to process conditions
Setting and stability in terms of have very big challenge.
Ultrasonic method has higher requirements to pressure, ultrasonic roller surface cleannes etc..Such as in continuous production, melting
Cloth has a few fibres and is bonded in roller surface, with bond amount increase and roller surface uneven distribution, meeting
The product seam of subsequent production is set physical defect occur.
The method of hot pressing, three-layer structure material is such as previously mentioned in United States Patent (USP) US7390376, and (non-woven fabrics/barrier is thin
Film/non-woven fabrics) seam, method is that it is molten to be heated to internal layer nonwoven layer to the seam crossing of two panels material laminate using fire-bar
Or more, but in barrier film fusing point hereinafter, melting internal layer non-woven fabrics, so that the internal layer non-woven fabrics of two sheet materials melts patch
It is combined the seam for being formed with barrier property.The method is the currently the only widely commercialized medical anti-virus operation dress (U.S.
4 rank of AAMI) product coat-sleeve seam method.However, the method has considerable challenge.First, it needs from outer in principle
Layer nonwoven heating makes heat pass through outer layer non-woven fabrics, middle layer barrier film, finally again by internal layer non-woven fabrics by heat transfer
Material molten.To which the temperature of outer layer non-woven fabrics is much higher than its melting temperature, outer layer non-woven fabrics is set to be also at molten condition, to it
Physical property has larger impact.Second, the stability of hot press and its accessory in large-scale production.Hot press configuration needs
Two hot pressing items above and below about one meter long have very high-precision and are substantially parallel, to keep in hot pressing to cloth
Complete consistent pressure.And size, the stability of shape are kept in the circulation that long-time hot pressing, heating cool down.In temperature control
System aspect, needs to keep the temperature uniformity of whole hot pressing item and the accuracy of set temperature.Simultaneously as need heat from
Outer layer is conducted to internal layer, and internal layer is made to reach the temperature of melting, and influence, quality fluctuation of material of external condition etc. will affect work
The stabilization of skill window.Third, in large-scale production, if more than a small amount of melting macromolecule sticks on fire-bar and can significantly destroy
Needs various accurate equipment and process conditions.These problems make hot pressing method equally in commercialization seam barrier property side
There is very big challenge in face.
On the other hand, the melt processing to high molecular material is belonged to thermal-adhering scheme due to ultrasound, and operated
All in air, there is oxidative phenomena inevitably to destroy the initial performance of high molecular material, while melting cools down again
Processing, melt crystallinity of the high molecular material of seam region etc. and also have change compared with cloth.So that is shown is
Cloth is compared by the seam strength that this two methods is processed to be decreased significantly.Such as initial cloth is poly- the third of 50 grams/m
Alkene spins molten (SMS) nonwoven cloth material, and initial strength is 50N/5cm (cloth tearing), after heat sealing, strongly drops significantly to
10-15N/5cm, and tearing occurs in primarily in the edge of seam and cloth.The decline of seam crossing strength causes in use process
In, since the movements such as toggle cause coat-sleeve seam crossing to will appear phenomenon of cracking, thus make the disabler of operation dress and protective garment,
Infection, pollution etc. is brought to cause the injury to human body.
Seamed product based on adhesive technology is also described in United States Patent (USP) US 4,114,200.The invention uses heat
Melten gel cooperates sewing technology to reach sealing effect and need joint strength.But it does not embody effectively to nuisance wherein
The barrier action of matter.Meanwhile there is balance various aspects of performance requirement in common hot melt adhesive, water-base cement etc., include ensuring that uniform sizing,
Ensure effective infiltration of the glue to adhesive surface cloth, it is ensured that form fine and close barrier, final joint strength and subsequent processing are as sterilized
The problem of condition stability inferior.Such as rubber-based hot melt glue in order to be maintained under the conditions of steam sterilizing and can soften, flowing leads to seam
Form defect.
In the Chinese patent of Publication No. CN1774332A, thermoplastic seam seal tape, the i.e. hot melt of tape backing are used
Adhesive phase cooperates the fluffy textile fabric of bi-component to help to achieve the effect that seam crossing waterproof.Its bi-component used first
Fabric needs a kind of component to keep stablizing under at least 140 degrees Celsius, is selected as 6,6 material of nylon.Medical treatment and industrial protection clothes
Used polypropylene spun-bonded melt-blown nonwoven cloth material has had begun softening under 140 degrees Celsius.Secondly, being added by hot pressing
Work melts thermoplastic seam seal tape and infiltrates through fluffy textile material, so that the closely sealed processing method of seam crossing is formed, with
Above-mentioned listed directly hot pressing mode has similar technique stability challenges.Such as temperature of deviation setting in large-scale production, pressure,
Then thermoplastic seam seal tape can not be melted by ideal design and be penetrated into the woven face bed of material, so that sealing layer is possible to lack
It falls into.The melting temperature of third, the thermoplastic sealing tape used can be lower than 120 degrees Celsius, use steam sterilizing in medical industry
Under the conditions of, softening will cause the defect of seam crossing, to lose protective performance.
Summary of the invention
It is existing to overcome the main purpose of the present invention is to provide a kind of cloth seam construction and the preparation method and application thereof
The deficiency of technology.
For realization aforementioned invention purpose, the technical solution adopted by the present invention includes:
The embodiment of the invention provides a kind of cloth seam constructions comprising at least two cloth products layers, the cloth
Product layer includes thermoplastic resin fibre's product layer, alternatively, the cloth products layer include thermoplastic resin fibre's product layer with
And it is set to the liquid barrier material layer of thermoplastic resin fibre's product layer surface;Also, two clothes at least in
The seam crossing of product layer is provided with Resin adhesive layer, is sealingly engaged two cloth products layers, the resin gluing
Oxidant layer is formed by curing by the response type adhesive that can be set to the cloth products layer surface and/or inside.
The embodiment of the invention also provides a kind of preparation methods of cloth seam construction comprising:
At least two cloth products layers are provided, the cloth products layer includes thermoplastic resin fibre's product layer, alternatively, institute
Cloth products layer is stated to include thermoplastic resin fibre's product layer and be set to thermoplastic resin fibre's product layer surface
Liquid barrier material layer;
Response type adhesive is applied between at least two cloth products layers using gluing process, passes through pressure later
Conjunction, glue penetration and reaction solidification, the response type adhesive can be set to thermoplastic resin fibre's product layer surface, and/or,
The response type adhesive is also at least uniformly binded in liquid barrier after infiltrating through thermoplastic resin fibre's product layer
In material layer, so that the seam crossing of two layers of cloth products layer is formed fine and close flawless Resin adhesive layer, make described two
A cloth products layer is sealingly engaged, and cloth seam construction is made.
The embodiment of the invention also provides the cloth seam constructions prepared by preceding method.
The embodiment of the invention also provides cloth seam constructions above-mentioned in preparing the purposes in garment elements.
Preferably, the garment elements include coat-sleeve or shoulder or collar.
The embodiment of the invention also provides cloth seam constructions above-mentioned in preparing clothing, shield, bedding or medical
Purposes in packaging.
Preferably, the clothing includes medical operating clothes, medical protection clothes, isolation clothes, industrial protection clothes or lab-gown, institute
It states shield or bedding includes that medical operating paving is single.
The prior art is compared, the invention has the advantages that
1) cloth products layer includes thermoplastic resin fibre's product layer in cloth seam construction provided by the invention, such as pure spinning
It knits, nonwoven cloth material etc., barrier property to 3 rank of U.S. AAMI, durable and high-tenacity with stable seam etc. is excellent
Performance;
2) cloth products layer includes thermoplastic resin fibre's product layer and sets in cloth seam construction provided by the invention
The liquid barrier material layer being placed between thermoplastic resin fibre's product layer, from the liquid barrier material of one side to another side
The flawless resin layer of one is formed between liquid barrier material prevents liquid so that seam crossing be made to have high stable liquid barrier property
Body seeped, and had the function of anti-virus, while having the excellent properties such as durable and high-tenacity, was suitble to multiple material and processing ring
Border, the stabilization of retention property in long lasting for production, can be widely applied to medical operating clothes, medical protection clothes, isolation clothes,
Industrial protection clothes or medical operating spread single etc. preparation, are mainly used in the infiltration such as anti-virus, blood, chemical substance, application
Meet 4 rank of U.S. AAMI in product medically;
3) preparation method of cloth seam construction provided by the invention passes through the spot gluing equipment accurately controlled, and applying performance is equal
One stable adhesive applies steady pressure by the pressure roller of rotation, thus ensure that it is accurate along seam crossing, uniform with it is stable
Adhesive resin and to the infiltration of weaving/nonwoven cloth material;
4) preparation method of cloth seam construction provided by the invention passes through rear curing reaction, the intensity of adhesive resin
It is obviously improved, shear strength maximum is up to 6Mpa, much larger than the numerical value of common hot melt adhesive about 0.1-0.3 megapascal, to connect
Theoretical strength at seam, which is much larger than, uses common hot melt adhesive.
5) preparation method of cloth seam construction provided by the invention passes through rear curing reaction, the heatproof of adhesive resin
Property be obviously improved, softening point be higher than 160 degrees Celsius, so as to effectively pass through steam sterilizing condition.
Detailed description of the invention
It, below will be to required in embodiment or description of the prior art in order to illustrate more clearly of technical solution of the present invention
The attached drawing used is simply introduced, it should be apparent that, drawings discussed below is as just some implementations invented herein
Example, for those of ordinary skill in the art, without creative efforts, can also obtain according to these attached drawings
Obtain other accompanying drawings.
Fig. 1 is the structural schematic diagram for the cloth seam construction that an exemplary embodiments of the invention provide.
Fig. 2 is the structural schematic diagram for the cloth seam construction that another exemplary embodiments of the present invention provide.
Description of symbols: 1- spins molten non-woven fabrics, 2- Resin adhesive layer, 3- thermoplastic resin membrane.
Specific embodiment
As previously mentioned, inventor is studied for a long period of time and largely practiced in view of the defect of the prior art, it is able to propose this
The technical solution of invention, be mainly to provide it is a kind of by reactive resin gluing technology realize based on textile material, nonwoven
Cloth material and derivatives composite material with high-barrier, prevent liquid from seeping, the seamed product with anti-virus function.Such as
Under the technical solution, its implementation process and principle etc. will be further explained.
As the one aspect of technical solution of the present invention, involved in be a kind of cloth seam construction comprising at least
Two cloth products layers, the cloth products layer includes thermoplastic resin fibre's product layer, alternatively, the cloth products layer includes
Thermoplastic resin fibre's product layer and the liquid barrier material layer for being set to thermoplastic resin fibre's product layer surface;And
And the seam crossing of two cloth products layers is provided with Resin adhesive layer at least in, makes two cloth products layers
It is sealingly engaged, the Resin adhesive layer is by that can be set to the cloth products layer surface and/or internal response type gluing
Agent is formed by curing.
Preferably, at least two cloth products layers are folded from same fabric construction, such as seal-coat
Sleeve structure.
Preferably, the thermoplastic resin is at least infiltrated through to form the response type adhesive of the Resin adhesive layer
Rouge fibre layer.
Wherein, the material of cloth products layer include but is not limited to thermoplastic resin fibre's product (including weaving and/or nonwoven
Cloth products), thermoplastic resin fibre's product and thermoplastic resin membrane's bilayer and/or multilayer materials.
Among an embodiment, the cloth products layer includes at least double-layer structure, and wherein at least one layer is with liquid
The material of body barrier action, such as thermoplastic resin membrane, and at least one layer of is thermoplastic resin fibre's product layer, thermoplastic resin
Rouge fibre is defined as textile fabric and/or non-woven fabrics, and (non-spun-bonded non-woven fabrics contain spun-bonded non-woven fabrics, spin molten non-woven fabrics knot
The material of structure);The above two panels has the cloth of fluid barrier in the Resin adhesive layer for needing seam crossing to apply, and forms cloth
Material/resin/cloth three-decker.By pressing, glue penetration and reaction solidify the seam crossing for making two panels cloth, from the liquid of one side
Body barrier material is to the flawless resin layer of one is formed between another side liquid barrier material, so that seam crossing be made to hinder with liquid
Every effect.
Among an embodiment, the material of thermoplastic resin fibre's product layer includes textile fabric, non-woven fabrics etc.,
But not limited to this.
Wherein, the material the grammes per square metre scope of thermoplastic resin fibre's product layer is 1~250g/m2, preferably 5~
150g/m2, structure includes but is not limited to spun-bonded non-woven fabrics, spunbond melt spraying non-woven fabrics, spunlace non-woven cloth, hot-wind nonwoven cloth, needle thorn
Any one in non-woven fabrics etc. or two or more combinations.
Wherein, the material of the thermoplastic fibre product layer include polyolefin spunbonded non-woven fabrics, polyolefin spin molten non-woven fabrics,
Spunbond polyester non-woven fabrics, polyester fiber spunlace non-woven cloth, polyesters polyolefins fiber hot-wind nonwoven cloth, polyester wet nonwoven fabrics and
Any one in the above high molecular material mixing or copolymerization non-woven fabrics etc. or two or more combinations, but not limited to this.Wherein,
The polyolefin spunbonded non-woven fabrics includes polypropylene spun-bonded non-woven fabrics, polyethylene spun-bonded non-woven fabrics etc., and the polyolefin spins molten nothing
Woven fabric includes that polypropylene spun melts non-woven fabrics, polyethylene spins molten non-woven fabrics etc., but not limited to this.
Preferably, the thermoplastic resin is being infiltrated through to form the response type adhesive of the Resin adhesive layer
After fibre layer, also at least uniformly bind on liquid barrier material layer.
Preferably, the seam crossing of two cloth products layers at least in, the liquid barrier material in a cloth products layer
The bed of material engages to form the flawless liquid barrier of one with the liquid barrier material layer in another cloth products layer.
Preferably, the liquid barrier material layer includes but is not limited to this thermoplastic resin membrane, any to have liquid resistance
Every the material of function.
Preferably, the seam crossing of two cloth products layers at least in, two cloth products layers and resin glue
Adhensive layer forms integral structure.
Among an embodiment, Resin adhesive used in the present invention is response type adhesive, including rubber-type is anti-
Answer type adhesive, acrylic system response type adhesive, vinylacetate system response type adhesive, epoxy systems response type glue
The response type adhesive of the mixture manufacturing of glutinous agent, polyurethane system response type adhesive and the above system, preferably polyurethane
System adhesive, including polyethers, polyester and its derivative and its mixture, more preferably based on polyether polyester system
Base polyurethane prepolymer for use as carry out cured adhesive system by reacting with water.
Specifically, the response type adhesive includes polyolefin, natural rubber, synthetic rubber, polybutene, poly- butylbenzene two
It is any one in alkene, polyisoprene, polyacrylate, epoxy resin, polyethers, polyester, polyurethane and organic silicon adhesive etc.
Kind or two or more combinations, but not limited to this.
Further, the response type adhesive have reaction active groups, the reaction active groups include methoxyl group,
Any one in epoxy group, acetoxy group, hydroxyl and isocyanate group etc. or two or more combinations, but not limited to this.It is described
Resin reaction active group can carry out following chemically react: epoxy group heats ring-opening polymerisation, epoxy-amino group ring-opening polymerisation, vinegar
Acidic group reacted with hydroxyl condensation, isocyanate group with water self condense, isocyanate group and hydroxyl or acetoxy group reactive polymeric etc..
Further, the response type adhesive include: matter average molecular weight be 1000~50000 multi-hydroxy polyether 5~
80wt%, 5~80wt% of polyol polyester that matter average molecular weight is 1000~50000, there are more than two isocyanate groups
1~10wt% of 10~30wt% of compound and filler and catalyst.
Preferably, the compound with molecule with more than two isocyanate groups includes diisocyanate chemical combination
Object;Especially preferred, the diisocyanate cpd includes but is not limited to MDI (methyl diphenylene diisocyanate), TDI
Any one or two or more combination in (toluene di-isocyanate(TDI)), HDI (hexamethylene diisocyanate) form more
Aggressiveness.
Among an embodiment, with fluid barrier material include thermoplastic resin membrane material be selected from
Following a kind of thermoplastic and its derivative and mixture: polyene hydrocarbons and their derivates, polyvinyl acetate and its derivative
Object and mixture, polyvinyl chloride and its derivative and mixture, polyvinyl acetate alcohol and its derivative and mixture gather to benzene two
Formic acid glycol ester and its derivative and mixture and polybutylene terephthalate (PBT) and its derivative and mixture.
Among an embodiment, the material with fluid barrier includes that the material of thermoplastic resin membrane is polyethers
Ester and its derivative and mixture, polyether ester amides and its derivative and mixture, polyurethane and its derivative and mixture,
Any mixture of TPO and its derivative and mixture and TPV and its derivative and mixture etc. and above-mentioned material.
Among an embodiment, the material with fluid barrier include thermoplastic resin membrane material be with
Penetrability polyether ester and its derivative and mixture, polyether ester amides and its derivative and mixture, polyurethane and its derivative
It is any with mixture, TPO and its derivative and mixture and TPV and its derivative and mixture etc. and above-mentioned material
Mixture.
Among an embodiment, the material with fluid barrier includes microporous thermoplastic resin film, material
For thermoplastic and its derivative and mixture selected from following one kind: polyene hydrocarbons and their derivates, polyvinyl chloride and its spreading out
Biology and mixture, polyester and its derivative and mixture, polyurethane and its derivative and mixture, polyethers and its derivative and
Mixture, polycarbonate and its derivative and mixture.
Wherein, the grammes per square metre of the thermoplastic resin membrane is 1~250g/m2。
Among an embodiment, the cloth products layer includes that thermoplastic resin fibre's product layer and thermoplastic resin are thin
Film two-layer composite, total grammes per square metre are 10~500g/m2。
Among an embodiment, the cloth products layer includes that thermoplastic resin fibre's product layer and thermoplastic resin are thin
Film three-layer composite structure, total grammes per square metre are 10~750g/m2。
Wherein, the Resin adhesive layer is uniformly distributed between two thermoplastic resin membranes.Resin adhesive
Layer forms strong bond after hardening, with liquid barrier material layer surface, to make the liquid barrier material of two panels joint filler
Layer, thermoplastic fibre product layer and Resin adhesive form the material structure of an entirety, and overall structure can prevent seam crossing
Liquid penetrate and virus penetrates.
As the other side of technical solution of the present invention, involved in be a kind of cloth seam construction preparation side
Method, the main production including adhesive, packaging, the construction method of adhesive, applying method, curing method.
Among an embodiment, the preparation method includes:
At least two cloth products layers are provided, the cloth products layer includes thermoplastic resin fibre's product layer, alternatively, institute
Cloth products layer is stated to include thermoplastic resin fibre's product layer and be set to thermoplastic resin fibre's product layer surface
Liquid barrier material layer;
Response type adhesive is applied between at least two cloth products layers using gluing process, passes through pressure later
Conjunction, glue penetration and reaction solidification, the response type adhesive can be set to thermoplastic resin fibre's product layer surface, and/or,
The response type adhesive is also at least uniformly binded in liquid barrier after infiltrating through thermoplastic resin fibre's product layer
In material layer, so that the seam crossing of two layers of cloth products layer is formed fine and close flawless Resin adhesive layer, make described two
A cloth products layer is sealingly engaged, and cloth seam construction is made.
Preferably, at least two cloth products layers are folded from same fabric construction, such as seal-coat
Sleeve structure.
Further, the seam crossing of two cloth products layers at least in, the liquid barrier in a cloth products layer
Material layer engages to form the flawless liquid barrier of one with the liquid barrier material layer in another cloth products layer.
Preferably, the liquid barrier material layer includes but is not limited to this thermoplastic resin membrane, any to have liquid resistance
Every the material of function.
Wherein, the resin reaction active group of the Resin adhesive carries out under certain environmental conditions after Construction Joint
To solidify, the environment includes normal temperature cure, is heating and curing, humidity cure for reaction.
Among an embodiment, the application temperature of the response type adhesive is fine not higher than the thermoplastic resin of adhesive surface
The fusing point of the material of fiber products layer.
Specifically, the application temperature of the response type adhesive be 20~180 DEG C, preferably 80~150 DEG C, more preferably
100~130 DEG C.
Wherein, described to be formed effectively to the infiltration of non-woven fabrics fiber structure to form fine and close flawless adhesive layer
The working viscosity of response type adhesive is 500~50000cps, preferably 1000~20000cps at a temperature of application.
Further, the applied amount of the response type adhesive is that 0.1~5g/m is glued along seam strip, preferably 0.1
~1g/m, more preferably 0.15~0.5g/m.
Further, the open hour of the response type adhesive are 5~600s.
Among an embodiment, the preparation method includes: that the Resin adhesive layer of seam crossing is equal using spot gluing equipment
Even sizing.It specifically includes: using spot gluing equipment, by making the response type adhesive at a temperature of specific application in softening shape
State, and perhaps air pressure is quantitative by sebific duct mouth or metering pumping method by applying mechanical pressure to the response type adhesive
Uniformly sizing.
More specifically, the ingredient of adhesive include: matter average molecular weight be 1000~50000 multi-hydroxy polyether 5~
80wt%, 5~80wt% of polyol polyester that matter average molecular weight is 1000~50000, there are more than two isocyanate groups
Compound, such as diisocyanate cpd, as MDI (methyl diphenylene diisocyanate), TDI (toluene di-isocyanate(TDI)),
1~10wt% of HDI (hexamethylene diisocyanate) and its 10~30wt% of polymer and filler and catalyst etc..
Adhesive is encapsulated into after the production is completed in storage sebific duct.Generally aluminum pipe or PA tube, gum outlet preceding,
Sealing piston is rear.
Further, adhesive aluminum pipe is placed in heating muff, air pressure or machinery of the rear portion by solenoid valve control
Pressure applies the pressure needed to sebific duct piston.Sebific duct front end gum outlet and dispensing needle head combine closely and (can pass through screw thread).Out
Jiao Kou reaches the glue amount of needs by the syringe needle of different-diameter.Gluing scheme also can be the needle for passing through metering pump and cooperating different-diameter
Head control rubber quality.
Among an embodiment, in the gluing process, phase between the spot gluing equipment and the cloth products layer
To movement.
Specifically, can have following two mode to the gluing process of cloth.One fixes for cloth, and Glue dripping head is needed along cloth
Position for dispensing glue is wanted to automatically move.Another kind is fixed for Glue dripping head, and cloth is fixed on a moving belt.Seam crossing is needed to apply along cloth
With the adhesive of specific quantity.The present invention passes through the spot gluing equipment accurately controlled, the adhesive of applying performance stable homogeneous, by turning
Dynamic pressure roller applies steady pressure, to ensure that accurate along seam crossing, uniform and stable adhesive resin and to spinning
Knit/the infiltration of nonwoven cloth material.
Among an embodiment, Resin adhesive layer construction method can also have for the thickness for being first coated with needs other
In the transfer substrate of release ability, such as release paper coated with silicon, apply silicon release film, paraffin paper, fluorine carbon release film, transfer to later to
Seam areas between few two layers of cloth products layer.
After the completion of sizing, second cloth can be needed bonding plane fit in the first face and form double-layer structure, can also incited somebody to action
First face folds fitting and forms closing sleeve structure.
The present invention is obviously improved by rear curing reaction, the intensity of adhesive resin.Its shear strength maximum is up to 6,000,000
Pa (6Mpa), much larger than the numerical value of common hot melt adhesive about 0.1-0.3 megapascal.It is used to which the theoretical strength of seam crossing is much larger than
Common hot melt adhesive.The present invention is obviously improved by rear curing reaction, the temperature tolerance of adhesive resin, and softening point is higher than 160 and takes the photograph
Family name's degree, so as to effectively pass through steam sterilizing condition.
Further, Resin adhesive layer penetrates binding face thermoplastic fibre product layer after sizing, and uniformly bonding exists
Liquid barrier material layer surface, Resin adhesive layer form strong bond after hardening, with liquid barrier material layer surface, thus
Make the liquid barrier material layer of two panels joint filler, thermoplastic fibre product layer and Resin adhesive form the material of an entirety
Structure, the overall structure can prevent that the liquid of seam crossing penetrates and virus penetrates.
In conclusion including: by above-mentioned the obtained seamed product of preparation method
A) cloth products layer, including one or more layers composite construction.Structure includes thermoplastic resin fibre's product layer, is had
The material of fluid barrier, such as thermoplastic resin membrane, and the multi-layer compound structure of the above material.Thermoplastic resin fibre
Product is defined as textile fabric and/or non-woven fabrics, and (non-spun-bonded non-woven fabrics contain spun-bonded non-woven fabrics, spin the material of molten nonwoven fabric construct
Material);
B) with the above structure two panels cloth need seam crossing apply Resin adhesive layer, formed cloth/resin/
The three-decker of cloth;
C) by pressing, resin glue infiltrates through the rear solidification of thermoplastic resin fibre's product layer and resin glue, makes seam crossing
Material (Resin adhesive layer can penetrate into binding face thermoplastic fibre product layer after sizing, and after hardening, with two
The thermoplastic resin fibre of binding face) composite material of an entirety is formed, to make seam crossing that there is fluid barrier.
Wherein, preparation method of the present invention is raw materials used such as response type adhesive, thermoplastic resin fibre's product layer, thermoplasticity
The material of resin film is as mentioned before.
Among an embodiment, the material of thermoplastic resin fibre's product layer includes textile fabric, non-woven fabrics etc.,
But not limited to this.
Wherein, the material the grammes per square metre scope of thermoplastic resin fibre's product layer is 1~250g/m2, especially preferably 5~
150g/m2, structure includes but is not limited to spun-bonded non-woven fabrics, spunbond melt spraying non-woven fabrics, spunlace non-woven cloth, hot-wind nonwoven cloth, needle thorn
Any one in non-woven fabrics etc. or two or more combinations.
Wherein, the material of the thermoplastic fibre product layer include polyolefin spunbonded non-woven fabrics, polyolefin spin molten non-woven fabrics,
Spunbond polyester non-woven fabrics, polyester fiber spunlace non-woven cloth, polyesters polyolefins fiber hot-wind nonwoven cloth, polyester wet nonwoven fabrics and
Any one in the above high molecular material mixing or copolymerization non-woven fabrics etc. or two or more combinations, but not limited to this.Wherein,
The polyolefin spunbonded non-woven fabrics includes polypropylene spun-bonded non-woven fabrics, polyethylene spun-bonded non-woven fabrics etc., and the polyolefin spins molten nothing
Woven fabric includes that polypropylene spun melts non-woven fabrics, polyethylene spins molten non-woven fabrics etc., but not limited to this.
Among an embodiment, with fluid barrier material include thermoplastic resin membrane material be selected from
Following a kind of thermoplastic and its derivative and mixture: polyene hydrocarbons and their derivates, polyvinyl acetate and its derivative
Object and mixture, polyvinyl chloride and its derivative and mixture, polyvinyl acetate alcohol and its derivative and mixture gather to benzene two
Formic acid glycol ester and its derivative and mixture and polybutylene terephthalate (PBT) and its derivative and mixture.
Among an embodiment, the material with fluid barrier includes that the material of thermoplastic resin membrane is polyethers
Ester and its derivative and mixture, polyether ester amides and its derivative and mixture, polyurethane and its derivative and mixture,
Any mixture of TPO and its derivative and mixture and TPV and its derivative and mixture etc. and above-mentioned material.
Among an embodiment, the material with fluid barrier include thermoplastic resin membrane material be with
Penetrability polyether ester and its derivative and mixture, polyether ester amides and its derivative and mixture, polyurethane and its derivative
It is any with mixture, TPO and its derivative and mixture and TPV and its derivative and mixture etc. and above-mentioned material
Mixture.
Among an embodiment, the material with fluid barrier includes microporous thermoplastic resin film, material
For thermoplastic and its derivative and mixture selected from following one kind: polyene hydrocarbons and their derivates, polyvinyl chloride and its spreading out
Biology and mixture, polyester and its derivative and mixture, polyurethane and its derivative and mixture, polyethers and its derivative and
Mixture, polycarbonate and its derivative and mixture.
Wherein, the grammes per square metre of the thermoplastic resin membrane is 1~250g/m2。
Among an embodiment, Resin adhesive used in the present invention is response type adhesive, including rubber-type is anti-
Answer type adhesive, acrylic system response type adhesive, vinylacetate system response type adhesive, epoxy systems response type glue
The response type adhesive of the mixture manufacturing of glutinous agent, polyurethane system response type adhesive and the above system, preferably polyurethane
System adhesive, including polyethers, polyester and its derivative and its mixture, more preferably based on polyether polyester system
Base polyurethane prepolymer for use as carry out cured adhesive system by reacting with water.
Specifically, the response type adhesive includes polyolefin, natural rubber, synthetic rubber, polybutene, poly- butylbenzene two
Alkene, polyisoprene, polyacrylate, epoxy resin, polyethers, polyester, polyurethane and organosiloxane with methoxyl group etc.
In any one or two or more combinations, but not limited to this.
Further, the response type adhesive have reaction active groups, the reaction active groups include methoxyl group,
Any one in epoxy group, acetoxy group, hydroxyl and isocyanate group etc. or two or more combinations, but not limited to this.It is described
Resin reaction active group can carry out following chemically react: epoxy group heats ring-opening polymerisation, epoxy-amino group ring-opening polymerisation, vinegar
Acidic group reacted with hydroxyl condensation, isocyanate group with water self condense, isocyanate group and hydroxyl or acetoxy group reactive polymeric etc..
The other side of the embodiment of the present invention additionally provides the cloth seam construction prepared by preceding method.
The other side of the embodiment of the present invention additionally provides cloth seam construction above-mentioned in preparing in garment elements
Purposes.
Preferably, the garment elements include coat-sleeve or shoulder or collar.
The other side of the embodiment of the present invention additionally provides cloth seam construction above-mentioned in preparing clothing, shield, bed
Purposes in Bed linens or medical package.
Preferably, the clothing includes medical operating clothes, medical protection clothes, isolation clothes, industrial protection clothes or lab-gown, institute
It states shield or bedding includes that medical operating paving is single.
Wherein, the said goods meet 1,2,3,4 rank of U.S. AAMI.
By above-mentioned technical proposal, cloth products layer includes thermoplastic resin fibre's system in cloth seam construction of the invention
Product layer, such as pure weaving, nonwoven cloth material, the excellent properties such as durable and high-tenacity with stable seam;Cloth of the invention
Cloth products layer includes thermoplastic resin fibre's product layer and is set to thermoplastic resin fibre's system in material seam construction
Liquid barrier material layer between product layer, from the liquid barrier material of one side to the integrated nothing of formation another side liquid barrier material
The resin layer of defect prevents liquid from seeping, has the function of anti-virus so that seam crossing be made to have high stable liquid barrier property,
There are the excellent properties such as durable and high-tenacity simultaneously, be suitble to multiple material and processing environment, protected in long lasting for production
Hold the stabilization of performance.
Following will be combined with the drawings in the embodiments of the present invention, and technical solution in the embodiment of the present invention carries out detailed retouch
It states, it is clear that described embodiments are only a part of the embodiments of the present invention, instead of all the embodiments.Based on the present invention
In embodiment, those of ordinary skill in the art's every other implementation obtained without making creative work
Example, shall fall within the protection scope of the present invention.
Referring to Fig. 1, being that (non-woven fabrics is to non-woven fabrics for a kind of structural schematic diagram of cloth seam construction provided in this embodiment
Fitting) comprising the molten non-woven fabrics 1 of two layers of spinning, and it is set to the Resin adhesive layer 2 spun between molten non-woven fabrics 1.
Referring to Fig. 2, for structural schematic diagram (the penetrability film nonwoven of another cloth seam construction provided in this embodiment
Cloth three-decker cloth pasting) comprising the cloth products layer with fluid barrier, and it is set to two layers of cloth
Resin adhesive layer 2 between product layer.The cloth products layer includes that two layers of spinning melts non-woven fabrics 1 and be set to the molten nonwoven of spinning
Thermoplastic resin membrane 3 between cloth 1.
It can be seen that the Resin adhesive layer 2 from Fig. 1 and Fig. 2 and penetrate into binding face and spin and melt non-woven fabrics 1, and
Even bonding forms the composite material of an entirety with the molten non-woven fabrics 1 of spinning of two binding faces on 3 surface of thermoplastic resin membrane,
To make seam crossing that there is fluid barrier.
Below by way of several embodiments technical solution that present invention be described in more detail.However, selected embodiment is only
For illustrating the present invention, and do not limit the scope of the invention.
Embodiment 1
(SMS) non-woven fabrics two panels is melted using 44 grams of polypropylene spuns to be bonded.Use hundred vast Weicon new material Co., Ltd of Suzhou
1027 polyurethane prepolymer resin adhesives, are glued at 130 DEG C, and glue amount is 0.4 grams m, carry out cloth cover after sizing after 10 seconds
Fitting is placed 24 hours.Strength is tested using puller system.The average tensile strength of original cloth is 45N/5cm, and seam crossing is
35N/5cm.Comparison carries out heat sealing with money material, and average tensile strength is only 15N/5cm at sealing.
After accelerated ageing (simulation natural aging in 1 year), original cloth average tensile strength drops to 40N/5cm,
Seam crossing average tensile strength drops to 29N/5cm, and heat sealing sample average tensile strength drops to 12N/5cm.
Embodiment 2
Keep remaining condition constant, by embodiment 1 condition change are as follows: be glued at 150 DEG C, glue amount be 0.1 gram/
Rice carries out cloth cover fitting after sizing 10 seconds, places 12 hours.Strength is tested using puller system, seam crossing average tensile strength is
32N/5cm。
Embodiment 3
Keep remaining condition constant, by embodiment 1 condition change are as follows: be glued at 100 DEG C, glue amount be 0.6 gram/
Rice carries out cloth cover fitting after sizing 20 seconds, places 24 hours.Strength is tested using puller system, the average tensile of original cloth is strong
Power is 45N/5cm, and seam crossing average tensile strength is 36N/5cm.
Embodiment 4
Use 68 grams of polypropylene spun-bonded non-woven fabrics/polyether ester moisture permeable membrane/polypropylene spun-bonded non-woven fabrics 3-layer composite material
(Ahlstrom company BVB material) two panels bonding.Use hundred vast Weicon new material Co., Ltd of Suzhou, 1057 adhesive polyurethane
Prepolymer resin adhesive is glued at 120 DEG C, and glue amount is 0.4 grams m, and it is small to place 24 for progress cloth cover fitting in 5 seconds after sizing
When, do following test:
1. seam strength.Original cloth average tensile strength 55N/5cm, seam crossing average tensile strength is 45N/5cm.It is right
Commercially produced product heat sealing seam average tensile strength according to same cloth is 35N/5cm.
2. blood penetration tests (ASTM F1670), no blood is penetrated.
3. viral inter-hole testing (ASTM F1671), virus-free to penetrate.
Embodiment 5
Use 68 grams of polypropylene spun-bonded non-woven fabrics/polyether ester moisture permeable membrane/polypropylene spun-bonded non-woven fabrics 3-layer composite material
(Ahlstrom company BVB material), with hundred vast Weicon new material Co., Ltd of Suzhou, 1057 adhesive (300 grams of aluminum pipes are packed),
It is glued at 120 DEG C, glue amount is 0.4 grams m, and progress cloth cover fitting in 15 seconds after sizing is placed 24 hours.Do following test:
1. blood penetration tests (ASTM F1670), no blood is penetrated.
Embodiment 6
Use 44 grams of polypropylene spun-bonded non-woven fabrics materials.Use hundred vast Weicon new material Co., Ltd of Suzhou, 1077 adhesive
(300 grams of aluminum pipe packagings), applies the adhesive tape that glue amount is 0.4 grams m, 5 points after sizing at 160 DEG C on release paper coated with silicon volume
Glue surface is bonded a face cloth seam crossing and tears release paper off again by the second face cloth pasting after slightly applying pressure, puts by clock
It sets 24 hours.Do following test:
1. the average tensile strength of original cloth is 45N/5cm, and seam crossing average tensile is strong using puller system test strength
Power is 35N/5cm.
Embodiment 7
Use 68 grams of polypropylene spun-bonded non-woven fabrics/polyether ester moisture permeable membrane/polypropylene spun-bonded non-woven fabrics 3-layer composite material
(Ahlstrom company BVB material) two panels bonding.Use hundred vast Weicon new material Co., Ltd of Suzhou, 2080 adhesive asphalt mixtures modified by epoxy resin
Rouge adhesive is glued at 40 DEG C, and glue amount is 2 grams ms, carries out cloth cover fitting after sizing after 600 seconds, it is Celsius to be placed in 80 later
Degree is solidified for environment 30 minutes, later room temperature 24 hours, does following test:
1. seam strength.Original cloth average tensile strength 55N/5cm, seam crossing average tensile strength is 48N/5cm.It is right
Commercially produced product heat sealing seam average tensile strength according to same cloth is 35N/5cm.
2. blood penetration tests (ASTM F1670), no blood is penetrated.
Embodiment 8
It is bonded using 15 grams of spunbond polyester non-woven fabrics two panels.Use hundred vast Weicon new material Co., Ltd of Suzhou, 2010 epoxy
Resin adhesive is glued at 20 DEG C, and glue amount is 0.4 grams m, is carried out cloth cover fitting after sizing after 100 seconds, is placed in later
100 degrees Celsius are solidified for environment 20 minutes, use puller system test strength within room temperature 24 hours later.The average drawing of original cloth
Stretching strength is 45N/5cm, and seam crossing average tensile strength is 40N/5cm.
Embodiment 9
It is bonded using 68 grams of polypropylene spun-bonded non-woven fabrics/polyolefin/polypropylene spun-bonded non-woven fabrics 3-layer composite material two panels.
It using 3145 organic silicon adhesive of Dow Corning Corporation, is glued at 20 DEG C, glue amount is 1 grams m, carries out cloth after sizing after 100 seconds
Face paste is closed, and is placed room temperature 24 hours later, is done following test:
1. blood penetration tests (ASTM F1670), no blood is penetrated.
Embodiment 10
(SMS) non-woven fabrics two panels is melted using 44 grams of polypropylene spuns to be bonded.Changed using Shanghai Condar Wanda's WD1001 acrylic acid
Property AB glue, mix glue and being glued at 23 DEG C, glue amount is 0.3 grams m, carries out cloth cover fitting after sizing after 10 seconds, later holding chamber
Use puller system test strength within temperature 12 hours.The average tensile strength of original cloth is 45N/5cm, seam crossing average tensile strength
For 32N/5cm.
Embodiment 11
It is bonded using 36 grams of polyester fiber wet nonwoven fabrics two panels.Use hundred vast Weicon new material Co., Ltd 1077 of Suzhou
Adhesive is glued at 120 DEG C, and glue amount is 5 grams ms, carries out cloth cover fitting after sizing after 60 seconds, is placed room temperature 24 hours later
Strength is tested using puller system.The average tensile strength of original cloth is 40N/5cm, and seam crossing average tensile strength is 35N/
5cm。
Embodiment 12
Operation dress fabric two panels is knitted using medical cotton to be bonded.Use hundred vast Weicon new material Co., Ltd of Suzhou, 1077 gluing
Agent is glued at 120 DEG C, and glue amount is 1 grams m, carries out cloth cover fitting after sizing after 60 seconds.Seam crossing forms close bonding.
Seam is kept completely without breakoff phenomenon under the pulling force of 50N/5cm.
Embodiment 13
It is bonded using 15 grams of spunbond polyester non-woven fabrics two panels.Use hundred vast Weicon new material Co., Ltd of Suzhou, 1027 gluing
Agent is glued at 180 DEG C, and glue amount is 0.1 grams m, carries out cloth cover fitting after sizing after 40 seconds, and place room temperature 24 hours makes later
Strength is tested with puller system.The average tensile strength of original cloth is 45N/5cm, and seam crossing average tensile strength is 30N/5cm.
In conclusion cloth seam construction of the invention and corresponding clothing are such as by above-mentioned technical proposal of the invention
Medical operating clothes, medical protection clothes etc. have the function of high stable liquid barrier property and anti-virus, while having durable and high-strength
The performances such as power, application prospect are extensive.
In addition, inventor also refers to the mode of embodiment 1~13, with the other raw materials and item listed in this specification
Part etc. is tested, and has equally been made and has the function of high stable liquid barrier property and anti-virus, at the same have it is durable and
The cloth seam construction of the performances such as high-tenacity.
It should be appreciated that the technical concepts and features of above-described embodiment only to illustrate the invention, its object is to allow be familiar with this
The personage of item technology cans understand the content of the present invention and implement it accordingly, and it is not intended to limit the scope of the present invention.It is all
Equivalent change or modification made by Spirit Essence according to the present invention, should be covered by the protection scope of the present invention.
Claims (10)
1. a kind of cloth seam construction, it is characterised in that including at least two cloth products layers, the cloth products layer includes heat
Plastic resin fibre layer, alternatively, the cloth products layer includes thermoplastic resin fibre's product layer and is set to described
The liquid barrier material layer of thermoplastic resin fibre's product layer surface;Also, the seam of two cloth products layers at least in
Place is provided with Resin adhesive layer, is sealingly engaged two cloth products layers, the Resin adhesive layer is by that can set
The response type adhesive for being placed in the cloth products layer surface and/or inside is formed by curing.
2. cloth seam construction according to claim 1, it is characterised in that: at least two cloth products layers from
Same fabric construction is through folding.
3. cloth seam construction according to claim 1, it is characterised in that: to form the anti-of the Resin adhesive layer
The type adhesive of answering at least infiltrates through thermoplastic resin fibre's product layer;Preferably, thermoplastic resin fibre's product
The material of layer includes textile fabric and/or non-woven fabrics;Preferably, the grammes per square metre of thermoplastic resin fibre's product layer be 1~
250g/m2, especially preferably 5~150g/m2;
Preferably, the material of thermoplastic resin fibre's product layer include spun-bonded non-woven fabrics, spunbond melt spraying non-woven fabrics, spun lacing without
Woven fabric, hot-wind nonwoven cloth, any one or two or more combinations in needle punched non-woven fabrics;
Preferably, the material of thermoplastic resin fibre's product layer includes polyolefin spunbonded non-woven fabrics, the molten nonwoven of polyolefin spinning
Cloth, spunbond polyester non-woven fabrics, polyester fiber spunlace non-woven cloth, polyesters polyolefins fiber hot-wind nonwoven cloth, polyester wet nonwoven fabrics
In any one or two or more combinations;Especially preferred, the polyolefin spunbonded non-woven fabrics includes polypropylene spun-bonded nothing
Woven fabric and/or polyethylene spun-bonded non-woven fabrics, it includes that polypropylene spun melts non-woven fabrics and/or polyethylene that the polyolefin, which spins molten non-woven fabrics,
Spin molten non-woven fabrics.
4. cloth seam construction according to claim 1 or 3, it is characterised in that: to form the Resin adhesive layer
Response type adhesive after infiltrating through thermoplastic resin fibre's product layer, also at least uniformly bonding in liquid barrier material
On the bed of material;Preferably, the seam crossing of two cloth products layers at least in, the liquid barrier material in a cloth products layer
Layer engages to form the flawless liquid barrier of one with the liquid barrier material layer in another cloth products layer;Preferably,
The liquid barrier material layer includes thermoplastic resin membrane;
Preferably, the seam crossing of two cloth products layers at least in, two cloth products layers and Resin adhesive
Layer forms integral structure.
5. cloth seam construction according to claim 1, it is characterised in that: the response type adhesive has reactivity
Group;
Preferably, the response type adhesive includes rubber-type response type adhesive, acrylic system response type adhesive, acetic acid
It is any one in vinyl acetate system response type adhesive, epoxy systems response type adhesive and polyurethane system response type adhesive
Kind or two or more combinations;Preferably, the polyurethane system response type adhesive includes polyethers, polyether derivative, polyester
With any one or the two or more combinations in polyester derivatives;
Preferably, the response type adhesive includes polyolefin, natural rubber, synthetic rubber, polybutene, poly- butylbenzene diene, gathers
Any one in isoprene, polyacrylate, epoxy resin, polyethers, polyester, polyurethane and organic silicon adhesive or two kinds
Above combination;
Preferably, the response type adhesive be base polyurethane prepolymer for use as based on polyether polyester system by reacted with water into
The cured adhesive system of row;
Preferably, the response type adhesive include: matter average molecular weight be 1000~50000 5~80wt% of multi-hydroxy polyether,
Polyol polyester 5~80wt% of the matter average molecular weight for 1000~50000, the compound with more than two isocyanate groups
10~30wt% and filler and 1~10wt% of catalyst;Preferably, the change with more than two isocyanate groups
Closing object includes diisocyanate cpd;Especially preferred, the diisocyanate cpd includes appointing in MDI, TDI, HDI
The polymer that a combination of one or more of anticipating is formed.
6. cloth seam construction according to claim 4, it is characterised in that: the material of the thermoplastic resin membrane includes
The derivative of thermoplastic and/or thermoplastic;Preferably, the thermoplastic include polyolefin, polyester, polyethers,
Polyvinyl acetate, polyethylene terephthalate, polybutylene terephthalate (PBT), polyether ester, gathers polyvinyl acetate alcohol
Any one in polyetheresteramide, polyurethane, TPO, TPV, polycarbonate and polyvinyl chloride or two or more combinations;It is preferred that
, the grammes per square metre of the thermoplastic resin membrane is 1~250g/m2;
Preferably, the cloth products layer includes thermoplastic resin fibre's product layer and thermoplastic resin membrane's two-layer compound knot
Structure, total grammes per square metre are 10~500g/m2;
Preferably, the cloth products layer includes thermoplastic resin fibre's product layer and three layers of composite junction of thermoplastic resin membrane
Structure, total grammes per square metre are 10~750g/m2。
7. a kind of preparation method of cloth seam construction, characterized by comprising:
At least two cloth products layers are provided, the cloth products layer includes thermoplastic resin fibre's product layer, alternatively, the cloth
Material products layer includes thermoplastic resin fibre's product layer and the liquid for being set to thermoplastic resin fibre's product layer surface
Spacer material layer;
Response type adhesive is applied between at least two cloth products layers using gluing process, later by pressing,
Glue penetration and reaction solidification, the response type adhesive can be set to thermoplastic resin fibre's product layer surface, and/or, institute
Response type adhesive is stated after infiltrating through thermoplastic resin fibre's product layer, is also at least uniformly binded in liquid barrier material
On the bed of material, so that the seam crossing of two layers of cloth products layer is formed fine and close flawless Resin adhesive layer, make described two
Cloth products layer is sealingly engaged, and cloth seam construction is made.
8. preparation method according to claim 7, it is characterised in that: at least two cloth products layers are from same
Fabric construction is through folding;
Preferably, the seam crossing of two cloth products layers at least in, the liquid barrier material layer in a cloth products layer
It engages to form the flawless liquid barrier of one with the liquid barrier material layer in another cloth products layer;Preferably, institute
Stating liquid barrier material layer includes thermoplastic resin membrane;
Preferably, reaction solidification includes normal temperature cure, is heating and curing or humidity cure;
Preferably, the application temperature of the response type adhesive is molten not higher than the material of thermoplastic resin fibre's product layer
Point;Especially preferred, the application temperature of the response type adhesive is 20~180 DEG C, preferably 80~150 DEG C, more preferably
100~130 DEG C;Especially preferred, viscosity of response type adhesive at a temperature of application is 500~50000cps, more excellent
It is selected as 1000~20000cps;
Preferably, the applied amount of the response type adhesive is to be glued 0.1~5g/m, preferably 0.1~1g/m along seam strip,
More preferably 0.15~0.5g/m;Preferably, the open hour of the response type adhesive are 5~600s;
Preferably, the preparation method includes: using spot gluing equipment, by making the response type adhesive in specific application temperature
It is in soft state down, and perhaps air pressure or metering pumping method are fixed by applying mechanical pressure to the response type adhesive
Amount uniformly sizing;It is especially preferred, in the gluing process, opposite fortune between the spot gluing equipment and the cloth products layer
It is dynamic;
Preferably, the preparation method includes: and is first applied to the response type adhesive with release ability to set thickness
Transfer substrate on, transfer to the seam areas between at least two layers cloth products layer later;It is especially preferred, it is described
Transfer substrate includes any one or two or more groups in release paper coated with silicon, painting silicon release film, paraffin paper and fluorine carbon release film
It closes;
Preferably, the response type adhesive has reaction active groups, and the reaction active groups include methoxyl group, epoxy
Any one in base, acetoxy group, hydroxyl and isocyanate group or two or more combinations;
Preferably, the response type adhesive includes rubber-type response type adhesive, acrylic system response type adhesive, acetic acid
It is any one in vinyl acetate system response type adhesive, epoxy systems response type adhesive and polyurethane system response type adhesive
Kind or two or more combinations;Preferably, the polyurethane system response type adhesive includes polyethers, polyether derivative, polyester
With any one or the two or more combinations in polyester derivatives;
Preferably, the response type adhesive includes polyolefin, natural rubber, synthetic rubber, polybutene, poly- butylbenzene diene, gathers
Any one in isoprene, polyacrylate, epoxy resin, polyethers, polyester, polyurethane and organic silicon adhesive or two kinds
Above combination;
Preferably, the response type adhesive be base polyurethane prepolymer for use as based on polyether polyester system by reacted with water into
The cured adhesive system of row;
Preferably, the response type adhesive include: matter average molecular weight be 1000~50000 5~80wt% of multi-hydroxy polyether,
Polyol polyester 5~80wt% of the matter average molecular weight for 1000~50000, the compound with more than two isocyanate groups
10~30wt% and filler and 1~10wt% of catalyst;Preferably, the change with more than two isocyanate groups
Closing object includes diisocyanate cpd;Especially preferred, the diisocyanate cpd includes appointing in MDI, TDI, HDI
The polymer that a combination of one or more of anticipating is formed;
Preferably, the material of thermoplastic resin fibre's product layer includes textile fabric and/or non-woven fabrics;Preferably, described
The grammes per square metre of thermoplastic resin fibre's product layer is 1~250g/m2, especially preferably 5~150g/m2;
Preferably, the material of thermoplastic resin fibre's product layer include spun-bonded non-woven fabrics, spunbond melt spraying non-woven fabrics, spun lacing without
Woven fabric, hot-wind nonwoven cloth, any one or two or more combinations in needle punched non-woven fabrics;
Preferably, the material of thermoplastic resin fibre's product layer includes polyolefin spunbonded non-woven fabrics, the molten nonwoven of polyolefin spinning
Cloth, spunbond polyester non-woven fabrics, polyester fiber spunlace non-woven cloth, polyesters polyolefins fiber hot-wind nonwoven cloth, polyester wet nonwoven fabrics
In any one or two or more combinations;Especially preferred, the polyolefin spunbonded non-woven fabrics includes polypropylene spun-bonded nothing
Woven fabric and/or polyethylene spun-bonded non-woven fabrics, it includes that polypropylene spun melts non-woven fabrics and/or polyethylene that the polyolefin, which spins molten non-woven fabrics,
Spin molten non-woven fabrics;
Preferably, the material of the thermoplastic resin membrane includes the derivative of thermoplastic and/or thermoplastic;Especially
Preferably, the thermoplastic includes polyolefin, polyester, polyethers, polyvinyl acetate, polyvinyl acetate alcohol, gathers to benzene two
Formic acid glycol ester, polybutylene terephthalate (PBT), polyether ester, polyether ester amides, polyurethane, TPO, TPV, polycarbonate and
Any one in polyvinyl chloride or two or more combinations.
9. the cloth seam construction prepared by any one of claim 7-8 the method.
10. cloth seam construction described in any one of claim 1-6,9 is in preparing the purposes in garment elements;Preferably,
The garment elements include coat-sleeve or shoulder or collar;And/or cloth seam knot described in any one of claim 1-9,9
Structure is in preparing the purposes in clothing, shield, bedding or medical package;Preferably, the clothing includes medical operating clothes, doctor
Protective garment, isolation clothes, industrial protection clothes or lab-gown are treated, the shield or bedding include that medical operating paving is single.
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CN201711023231.4A CN109720071A (en) | 2017-10-27 | 2017-10-27 | A kind of cloth seam construction and the preparation method and application thereof |
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN111500210A (en) * | 2020-05-20 | 2020-08-07 | 深圳市美信电子有限公司 | Adhesive tape, preparation method and application thereof and medical protective clothing |
CN111642828A (en) * | 2020-07-09 | 2020-09-11 | 江西服装学院 | Seamless garment and manufacturing method thereof |
CN111732900A (en) * | 2020-07-06 | 2020-10-02 | 江西服装学院 | Adhesive glue and manufacturing method of seamless clothes |
CN113733684A (en) * | 2021-09-16 | 2021-12-03 | 圣华盾防护科技股份有限公司 | Chemical protective clothing fabric and protective clothing |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5569507A (en) * | 1995-02-28 | 1996-10-29 | W. L. Gore & Associates, Inc. | Protective covers with virus impenetrable seams |
US20010001300A1 (en) * | 1996-08-30 | 2001-05-17 | Springs Industries, Inc. | Textile products constructed using curable adhesive threadless sewing and processes for producing same |
CN207466058U (en) * | 2017-10-27 | 2018-06-08 | 苏州百瀚卫康新材料有限公司 | A kind of cloth seam construction |
-
2017
- 2017-10-27 CN CN201711023231.4A patent/CN109720071A/en active Pending
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5569507A (en) * | 1995-02-28 | 1996-10-29 | W. L. Gore & Associates, Inc. | Protective covers with virus impenetrable seams |
US20010001300A1 (en) * | 1996-08-30 | 2001-05-17 | Springs Industries, Inc. | Textile products constructed using curable adhesive threadless sewing and processes for producing same |
CN207466058U (en) * | 2017-10-27 | 2018-06-08 | 苏州百瀚卫康新材料有限公司 | A kind of cloth seam construction |
Non-Patent Citations (1)
Title |
---|
高亦文: "户外服饰设计与产品开发", vol. 1, 31 March 2015, 上海:东华大学出版社, pages: 39 - 40 * |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN111500210A (en) * | 2020-05-20 | 2020-08-07 | 深圳市美信电子有限公司 | Adhesive tape, preparation method and application thereof and medical protective clothing |
CN111500210B (en) * | 2020-05-20 | 2023-06-27 | 美信新材料股份有限公司 | Adhesive tape, preparation method and application thereof and medical protective clothing |
CN111732900A (en) * | 2020-07-06 | 2020-10-02 | 江西服装学院 | Adhesive glue and manufacturing method of seamless clothes |
CN111642828A (en) * | 2020-07-09 | 2020-09-11 | 江西服装学院 | Seamless garment and manufacturing method thereof |
CN113733684A (en) * | 2021-09-16 | 2021-12-03 | 圣华盾防护科技股份有限公司 | Chemical protective clothing fabric and protective clothing |
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