CN109705703A - A kind of environment-friendlyweather-proof weather-proof type big-pattern Cu-Zn alloy powder - Google Patents

A kind of environment-friendlyweather-proof weather-proof type big-pattern Cu-Zn alloy powder Download PDF

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Publication number
CN109705703A
CN109705703A CN201811485591.0A CN201811485591A CN109705703A CN 109705703 A CN109705703 A CN 109705703A CN 201811485591 A CN201811485591 A CN 201811485591A CN 109705703 A CN109705703 A CN 109705703A
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China
Prior art keywords
powder
polyester
pigment
antioxidant
wax
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CN201811485591.0A
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Chinese (zh)
Inventor
金跃善
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Zhejiang Shuang Jin Powder Coating Co Ltd
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Zhejiang Shuang Jin Powder Coating Co Ltd
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Priority to CN201811485591.0A priority Critical patent/CN109705703A/en
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Abstract

The invention discloses a kind of environment-friendlyweather-proof weather-proof type big-pattern Cu-Zn alloy powders, are made of two kinds of bottom powder, metal powder and special efficacy texture agent;Described two bottom powder are divided into the bottom A powder and the bottom B powder;The weight of above-mentioned each material are as follows: the bottom A powder 50%, the bottom B powder 50%, metal powder 0.5-3% and special efficacy texture agent 0.1-0.5%;Such environment-friendlyweather-proof weather-proof type big-pattern Cu-Zn alloy powder has the advantages that environmental protection and excellent weather resistance and hard.

Description

A kind of environment-friendlyweather-proof weather-proof type big-pattern Cu-Zn alloy powder
Technical field
The present invention relates to a kind of environment-friendlyweather-proof weather-proof type big-pattern Cu-Zn alloy powders.
Background technique
Various security doors or other types of Men Douhui can be decorated on doorframe and door-plate with pattern on the market.But It is the problems such as coating used much has no idea to keep color and antioxygenic property etc. for a long time.And existing many party Plane materiel material all can generation environment pollution.
Summary of the invention
The technical problem to be solved in the present invention is to provide a kind of environmental protection and the environment-friendlyweather-proof weather-proof type big-pattern copper gold of excellent weather resistance and hard Powder.
To solve the above problems, the present invention adopts the following technical scheme:
A kind of environment-friendlyweather-proof weather-proof type big-pattern Cu-Zn alloy powder is made of two kinds of bottom powder, metal powder and special efficacy texture agent;It is described two Bottom powder is divided into the bottom A powder and the bottom B powder;The weight of above-mentioned each material are as follows: the bottom A powder 50%, the bottom B powder 50%, metal powder 0.5-3% and special efficacy texture agent 0.1-0.5%;
The bottom A powder includes A polyester, TGIC, CAB, wax powder, UV resistant agent, antioxidant, bloom barium, pigment;It is described The weight of each material of the bottom A powder is A polyester 65-70%, TGIC4.5-6%, CAB0.03-0.1%, wax powder 0.2- 0.6%, UV resistant agent 0.3%, antioxidant 0.6%, bloom barium 20-30%, pigment 1-2%;
The bottom B powder includes B polyester, Primid, CAB, wax powder, UV resistant agent, antioxidant, bloom barium, pigment;Institute The weight for stating each material of the bottom B powder is B polyester 65-70%, Primid3.5-5%, CAB0.03-0.1%, wax powder 0.2- 0.6%, UV resistant agent 0.3%, antioxidant 0.6%, bloom barium 20-30%, pigment 1-2%.
Further, described two bottom powder are divided into the bottom A powder and the bottom B powder;The weight of above-mentioned each material are as follows: The bottom A powder 50%, the bottom B powder 50%, metal powder 0.5% and special efficacy texture agent 0.1%;
The bottom A powder includes A polyester, TGIC, CAB, wax powder, UV resistant agent, antioxidant, bloom barium, pigment;It is described The weight of each material of the bottom A powder is A polyester 65%, TGIC4.5%, CAB0.03%, wax powder 0.2%, UV resistant agent 0.3%, antioxidant 0.6%, bloom barium 20%, pigment 1%;
The bottom B powder includes B polyester, Primid, CAB, wax powder, UV resistant agent, antioxidant, bloom barium, pigment;Institute The weight for stating each material of the bottom B powder is B polyester 65-70%, Primid3.5%, CAB0.03%, wax powder 0.2%, anti-purple Outside line agent 0.3%, antioxidant 0.6%, bloom barium 20%, pigment 1%.
Further, it is made of two kinds of bottom powder, metal powder and special efficacy texture agent;Described two bottom powder are divided into the bottom A powder and B Bottom powder;The weight of above-mentioned each material are as follows: the bottom A powder 50%, the bottom B powder 50%, metal powder 1.7% and special efficacy texture agent 0.3%;
The bottom A powder includes A polyester, TGIC, CAB, wax powder, UV resistant agent, antioxidant, bloom barium, pigment;It is described The weight of each material of the bottom A powder is A polyester 67%, TGIC5%, CAB0.07%, wax powder 0.5%, UV resistant agent 0.3%, antioxidant 0.6%, bloom barium 40%, pigment 1.5%;
The bottom B powder includes B polyester, Primid, CAB, wax powder, UV resistant agent, antioxidant, bloom barium, pigment;Institute The weight for stating each material of the bottom B powder is B polyester 67%, Primid4.2%, CAB0.07%, wax powder 0.4%, uvioresistant Agent 0.3%, antioxidant 0.6%, bloom barium 40%, pigment 1.5%.
Further, it is made of two kinds of bottom powder, metal powder and special efficacy texture agent;Described two bottom powder are divided into the bottom A powder and B Bottom powder;The weight of above-mentioned each material are as follows: the bottom A powder 50%, the bottom B powder 50%, metal powder 3% and special efficacy texture agent 0.5%;
The bottom A powder includes A polyester, TGIC, CAB, wax powder, UV resistant agent, antioxidant, bloom barium, pigment;It is described The weight of each material of the bottom A powder is A polyester 70%, TGIC6%, CAB0.1%, wax powder 0.6%, UV resistant agent 0.3%, antioxidant 0.6%, bloom barium 30%, pigment 2%;
The bottom B powder includes B polyester, Primid, CAB, wax powder, UV resistant agent, antioxidant, bloom barium, pigment;Institute The weight for stating each material of the bottom B powder is B polyester 70%, Primid5%, CAB0.1%, wax powder 0.6%, UV resistant agent 0.3%, antioxidant 0.6%, bloom barium 30%, pigment 2%.
Further, bisphenol-A is not contained in A, B polyester.
Another technical problem to be solved by the present invention is that providing a kind of environmentally friendly and excellent weather resistance and hard environment-friendlyweather-proof weather-proof type big-pattern The preparation method of Cu-Zn alloy powder.
To solve the above problems, the present invention adopts the following technical scheme: the following steps are included:
The preparation method is divided into following steps, successively are as follows: ingredient, mixing squeeze out melting, tabletting, broken slice, mill Powder, sieving, semi-finished product, rear mixed, finished product are packaged.
Further, temperature needs when being squeezed out in the extrusion melting process using extruder, and squeezing out machine operation Reach 90 DEG C or more, 120 DEG C or less.
Further, it needs to carry out cooling technique in the tableting processes, and water temperature is at 10-13 DEG C.
Further, powder is dispelled using air-cooler in the milling process, and the cold wind temperature of air-cooler It is 3-6 DEG C.
The beneficial effect of environment-friendlyweather-proof weather-proof type big-pattern Cu-Zn alloy powder of the present invention is:
TGIC and Primid is respectively adopted in the bottom A powder and the bottom B powder to mix with A, B polyester, the mixing of TGIC and A polyester mentions Rise and ensure the weatherability of product;The mixing of Primid and B polyester makes product reach resistance in the case where pollution-free environmental protection The stable performances such as time property.
Specific embodiment
Embodiment one:
A kind of environment-friendlyweather-proof weather-proof type big-pattern Cu-Zn alloy powder is made of two kinds of bottom powder, metal powder and special efficacy texture agent;It is described two Bottom powder is divided into the bottom A powder and the bottom B powder;The weight of above-mentioned each material are as follows: the bottom A powder 50%, the bottom B powder 50%, metal powder 0.5-3% and special efficacy texture agent 0.1-0.5%;
The bottom A powder includes A polyester, TGIC, CAB, wax powder, UV resistant agent, antioxidant, bloom barium, pigment;It is described The weight of each material of the bottom A powder is A polyester 65-70%, TGIC4.5-6%, CAB0.03-0.1%, wax powder 0.2- 0.6%, UV resistant agent 0.3%, antioxidant 0.6%, bloom barium 20-30%, pigment 1-2%;
The bottom B powder includes B polyester, Primid, CAB, wax powder, UV resistant agent, antioxidant, bloom barium, pigment;Institute The weight for stating each material of the bottom B powder is B polyester 65-70%, Primid3.5-5%, CAB0.03-0.1%, wax powder 0.2- 0.6%, UV resistant agent 0.3%, antioxidant 0.6%, bloom barium 20-30%, pigment 1-2%.
Embodiment two:
A kind of environment-friendlyweather-proof weather-proof type big-pattern Cu-Zn alloy powder is made of two kinds of bottom powder, metal powder and special efficacy texture agent;It is described two Bottom powder is divided into the bottom A powder and the bottom B powder;The weight of above-mentioned each material are as follows: the bottom A powder 50%, the bottom B powder 50%, metal powder 0.5% and special efficacy texture agent 0.1%;
The bottom A powder includes A polyester, TGIC, CAB, wax powder, UV resistant agent, antioxidant, bloom barium, pigment;It is described The weight of each material of the bottom A powder is A polyester 65%, TGIC4.5%, CAB0.03%, wax powder 0.2%, UV resistant agent 0.3%, antioxidant 0.6%, bloom barium 20%, pigment 1%;
The bottom B powder includes B polyester, Primid, CAB, wax powder, UV resistant agent, antioxidant, bloom barium, pigment;Institute The weight for stating each material of the bottom B powder is B polyester 65-70%, Primid3.5%, CAB0.03%, wax powder 0.2%, anti-purple Outside line agent 0.3%, antioxidant 0.6%, bloom barium 20%, pigment 1%.
Embodiment three:
A kind of environment-friendlyweather-proof weather-proof type big-pattern Cu-Zn alloy powder is made of two kinds of bottom powder, metal powder and special efficacy texture agent;It is described two Bottom powder is divided into the bottom A powder and the bottom B powder;The weight of above-mentioned each material are as follows: the bottom A powder 50%, the bottom B powder 50%, metal powder 1.7% and special efficacy texture agent 0.3%;
The bottom A powder includes A polyester, TGIC, CAB, wax powder, UV resistant agent, antioxidant, bloom barium, pigment;It is described The weight of each material of the bottom A powder is A polyester 67%, TGIC5%, CAB0.07%, wax powder 0.5%, UV resistant agent 0.3%, antioxidant 0.6%, bloom barium 40%, pigment 1.5%;
The bottom B powder includes B polyester, Primid, CAB, wax powder, UV resistant agent, antioxidant, bloom barium, pigment;Institute The weight for stating each material of the bottom B powder is B polyester 67%, Primid4.2%, CAB0.07%, wax powder 0.4%, uvioresistant Agent 0.3%, antioxidant 0.6%, bloom barium 40%, pigment 1.5%.
Example IV:
A kind of environment-friendlyweather-proof weather-proof type big-pattern Cu-Zn alloy powder is made of two kinds of bottom powder, metal powder and special efficacy texture agent;It is described two Bottom powder is divided into the bottom A powder and the bottom B powder;The weight of above-mentioned each material are as follows: the bottom A powder 50%, the bottom B powder 50%, metal powder 3% and special efficacy texture agent 0.5%;
The bottom A powder includes A polyester, TGIC, CAB, wax powder, UV resistant agent, antioxidant, bloom barium, pigment;It is described The weight of each material of the bottom A powder is A polyester 70%, TGIC6%, CAB0.1%, wax powder 0.6%, UV resistant agent 0.3%, antioxidant 0.6%, bloom barium 30%, pigment 2%;
The bottom B powder includes B polyester, Primid, CAB, wax powder, UV resistant agent, antioxidant, bloom barium, pigment;Institute The weight for stating each material of the bottom B powder is B polyester 70%, Primid5%, CAB0.1%, wax powder 0.6%, UV resistant agent 0.3%, antioxidant 0.6%, bloom barium 30%, pigment 2%.
Bisphenol-A is not contained in A, B polyester.
A kind of preparation method of environment-friendlyweather-proof weather-proof type big-pattern Cu-Zn alloy powder:
The preparation method is divided into following steps, successively are as follows: ingredient, mixing squeeze out melting, tabletting, broken slice, mill Powder, sieving, semi-finished product, rear mixed, finished product are packaged.
When being squeezed out in the extrusion melting process using extruder, and squeezing out machine operation temperature need to reach 90 DEG C with On, 120 DEG C or less.
Need to carry out cooling technique in the tableting processes, and water temperature is at 10-13 DEG C.
Powder is dispelled using air-cooler in the milling process, and the cold wind temperature of air-cooler is 3-6 DEG C.
The beneficial effect of environment-friendlyweather-proof weather-proof type big-pattern Cu-Zn alloy powder of the present invention is:
TGIC and Primid is respectively adopted in the bottom A powder and the bottom B powder to mix with A, B polyester, the mixing of TGIC and A polyester mentions Rise and ensure the weatherability of product;The mixing of Primid and B polyester makes product reach resistance in the case where pollution-free environmental protection The stable performances such as time property.
The above description is merely a specific embodiment, but scope of protection of the present invention is not limited thereto, any The change or replacement expected without creative work, should be covered by the protection scope of the present invention.Therefore, of the invention Protection scope should be determined by the scope of protection defined in the claims.

Claims (9)

1. a kind of environment-friendlyweather-proof weather-proof type big-pattern Cu-Zn alloy powder, it is characterised in that: by two kinds of bottom powder, metal powder and special efficacy texture agent group At;Described two bottom powder are divided into the bottom A powder and the bottom B powder;The weight of above-mentioned each material are as follows: the bottom A powder 50%, the bottom B powder 50%, metal powder 0.5-3% and special efficacy texture agent 0.1-0.5%;
The bottom A powder includes A polyester, TGIC, CAB, wax powder, UV resistant agent, antioxidant, bloom barium, pigment;The bottom A The weight of each material of powder is A polyester 65-70%, TGIC4.5-6%, CAB0.03-0.1%, wax powder 0.2-0.6%, resists Ultraviolet light agent 0.3%, antioxidant 0.6%, bloom barium 20-30%, pigment 1-2%;
The bottom B powder includes B polyester, Primid, CAB, wax powder, UV resistant agent, antioxidant, bloom barium, pigment;The B The weight of each material of bottom powder is B polyester 65-70%, Primid3.5-5%, CAB0.03-0.1%, wax powder 0.2- 0.6%, UV resistant agent 0.3%, antioxidant 0.6%, bloom barium 20-30%, pigment 1-2%.
2. environment-friendlyweather-proof weather-proof type big-pattern Cu-Zn alloy powder according to claim 1, it is characterised in that: described two bottom powder are divided into A Bottom powder and the bottom B powder;The weight of above-mentioned each material are as follows: the bottom A powder 50%, the bottom B powder 50%, metal powder 0.5% and spy Imitate texture agent 0.1%;
The bottom A powder includes A polyester, TGIC, CAB, wax powder, UV resistant agent, antioxidant, bloom barium, pigment;The bottom A The weight of each material of powder is A polyester 65%, TGIC4.5%, CAB0.03%, wax powder 0.2%, UV resistant agent 0.3%, antioxidant 0.6%, bloom barium 20%, pigment 1%;
The bottom B powder includes B polyester, Primid, CAB, wax powder, UV resistant agent, antioxidant, bloom barium, pigment;The B The weight of each material of bottom powder is B polyester 65-70%, Primid3.5%, CAB0.03%, wax powder 0.2%, uvioresistant Agent 0.3%, antioxidant 0.6%, bloom barium 20%, pigment 1%.
3. environment-friendlyweather-proof weather-proof type big-pattern Cu-Zn alloy powder according to claim 1, it is characterised in that: by two kinds of bottom powder, metal powders And special efficacy texture agent composition;Described two bottom powder are divided into the bottom A powder and the bottom B powder;The weight of above-mentioned each material are as follows: A Bottom powder 50%, the bottom B powder 50%, metal powder 1.7% and special efficacy texture agent 0.3%;
The bottom A powder includes A polyester, TGIC, CAB, wax powder, UV resistant agent, antioxidant, bloom barium, pigment;The bottom A The weight of each material of powder be A polyester 67%, TGIC5%, CAB0.07%, wax powder 0.5%, UV resistant agent 0.3%, Antioxidant 0.6%, bloom barium 40%, pigment 1.5%;
The bottom B powder includes B polyester, Primid, CAB, wax powder, UV resistant agent, antioxidant, bloom barium, pigment;The B The weight of each material of bottom powder is B polyester 67%, Primid4.2%, CAB0.07%, wax powder 0.4%, UV resistant agent 0.3%, antioxidant 0.6%, bloom barium 40%, pigment 1.5%.
4. environment-friendlyweather-proof weather-proof type big-pattern Cu-Zn alloy powder according to claim 1, it is characterised in that: by two kinds of bottom powder, metal powders And special efficacy texture agent composition;Described two bottom powder are divided into the bottom A powder and the bottom B powder;The weight of above-mentioned each material are as follows: A Bottom powder 50%, the bottom B powder 50%, metal powder 3% and special efficacy texture agent 0.5%;
The bottom A powder includes A polyester, TGIC, CAB, wax powder, UV resistant agent, antioxidant, bloom barium, pigment;The bottom A The weight of each material of powder is A polyester 70%, TGIC6%, CAB0.1%, wax powder 0.6%, UV resistant agent 0.3%, resists Oxidant 0.6%, bloom barium 30%, pigment 2%;
The bottom B powder includes B polyester, Primid, CAB, wax powder, UV resistant agent, antioxidant, bloom barium, pigment;The B The weight of each material of bottom powder is B polyester 70%, Primid5%, CAB0.1%, wax powder 0.6%, UV resistant agent 0.3%, antioxidant 0.6%, bloom barium 30%, pigment 2%.
5. environment-friendlyweather-proof weather-proof type big-pattern Cu-Zn alloy powder according to claim 1, it is characterised in that: be free of in A, B polyester There is bisphenol-A.
6. a kind of preparation method of environment-friendlyweather-proof weather-proof type big-pattern Cu-Zn alloy powder as described in claim 1, which is characterized in that including with Lower step:
The preparation method is divided into following steps, successively are as follows: ingredient, mixing squeeze out melting, tabletting, broken slice, milling, mistake Sieve, semi-finished product, rear mixed, finished product are packaged.
7. environment-friendlyweather-proof weather-proof type big-pattern Cu-Zn alloy powder according to claim 6, it is characterised in that: in the extrusion melting process Temperature needs to reach 90 DEG C or more, 120 DEG C or less when being squeezed out using extruder, and squeezing out machine operation.
8. environment-friendlyweather-proof weather-proof type big-pattern Cu-Zn alloy powder according to claim 6, it is characterised in that: needed in the tableting processes Cooling technique is carried out, and water temperature is at 10-13 DEG C.
9. environment-friendlyweather-proof weather-proof type big-pattern Cu-Zn alloy powder according to claim 6, it is characterised in that: used in the milling process Air-cooler dispels powder, and the cold wind temperature of air-cooler is 3-6 DEG C.
CN201811485591.0A 2018-12-06 2018-12-06 A kind of environment-friendlyweather-proof weather-proof type big-pattern Cu-Zn alloy powder Pending CN109705703A (en)

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Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1308658A (en) * 1998-07-03 2001-08-15 国际涂料有限公司 Powder coating compositions
CN102666754A (en) * 2010-09-13 2012-09-12 阿克苏诺贝尔粉末涂料(宁波)有限公司 Durable powder coating composition

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1308658A (en) * 1998-07-03 2001-08-15 国际涂料有限公司 Powder coating compositions
CN102666754A (en) * 2010-09-13 2012-09-12 阿克苏诺贝尔粉末涂料(宁波)有限公司 Durable powder coating composition

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