Dedicated Water soluble fertilizer of a kind of apple with flower thinning effect and preparation method thereof
One, technical field
The present invention relates to a kind of water-soluble fertilizer, in particular to the system of a kind of apple Water-soluble fertilizer special with flower thinning effect
Standby and application method is made of two kinds of Water soluble fertilizer of apple special solid type flower thinning Water soluble fertilizer and apple dedicated liquid type flower thinning, is belonged to
In technical field of fertilizer production.
Two, background technique
In time, appropriate that high quality fruit ratio can be improved to fruit tree progress flower and fruit thinning and keep healthy and strong tree vigo(u)r.Scale
Change the inexorable trend that plantation has become modern agricultural development, however traditional artificial flower and fruit thinning method is difficult in time in fruit tree life
Flower and fruit thinning is completed in long best period.Therefore, safety, quick flower and fruit thinning become saving of work and time, save the cost must
One of right means, chemical flower and fruit thinning is developed rapidly with the advantages that its saving of work and time, save the cost.
The presently disclosed patent about apple tree chemistry Flower thinning agent is more: application No. is 201610505094.7 patents
A kind of flower and fruit thinning method of apple tree is disclosed, i.e. preparation flower and fruit thinning agent carries out apple tree to spray fruit thinning, then uses
Human assistance shedding and artificial mend are dredged, and carry out fortification using fertilizer to tree body after fruit thinning.Application No. is
201410146950.5 disclose a kind of mixed aqueous solution prepared by formic acid calcium (5~10g/L) and sevin (0.5~1g/L)
The apple tree Flower thinning agent of composition after spraying flower thinning medicament, is manually vibrated apple tree and is mended using fruit thinning scissors and dredged.Application number
201410697462.3 a kind of apple tree flower thinning fruit conditioner being prepared from the following components of disclosure of the invention: 82% naphthalene
4-10 parts of acetic acid powder, 50% 1-2 parts of wettable carbaryl, 20% 200-300 parts of sulphur water, 300-400 parts of formaldehyde, ammonium hydroxide 10-
50 parts, 5-10 parts of peregal.
Although these patents can carry out flower and fruit thinning for apple tree, the main component of these Flower thinning agents is west
Denapon.And scientific investigations showed that, the effect is unsatisfactory for flower and fruit thinning of the sevin to Fuji apple, and sevin is a kind of desinsection
Agent can injure foraging insects, and these Flower thinning agents cannot adjust blooming for apple tree by controlling the nutrition of tree body
Situation.General Flower thinning agent, which is also easy to produce, to be removed deficiency or removes phenomena such as excessive, so that this technology be made to have in practical applications
Certain limitation.Chemical flower thinning must with apply fertilizers scientifically, integrated pest prevention and control etc. combines, can just make yield, fruit product
Matter and economic benefit reach best.Therefore, the application, which is intended to prepare, a kind of not only with flower thinning but also can be supplied to apple tree nutrition
Water-soluble fertilizer special.
Three, summary of the invention
For overcome the deficiencies in the prior art, the present invention provide a kind of dedicated Water soluble fertilizer of the apple with flower thinning effect and its
Preparation method, this flower thinning Water soluble fertilizer are by apple special solid type flower thinning Water soluble fertilizer and apple dedicated liquid type flower thinning Water soluble fertilizer two
The fertilizer of kind form is formed, and while carrying out chemical flower and fruit thinning to apple tree, be can also be provided and is grown to the apple tree florescence
Required various nutrients.Can solve apple flower and fruit thinning work under the conditions of water-fertilizer integral take a lot of work, be time-consuming, safety it is low
Problem.
To achieve the above object, technical scheme is as follows:
A kind of dedicated Water soluble fertilizer of apple with flower thinning effect be by apple special solid type flower thinning Water soluble fertilizer and
Apple dedicated liquid type flower thinning Water soluble fertilizer composition.
Apple special solid type flower thinning Water soluble fertilizer is made of following component and content:
Macronutrient (N+P2O5+K2O) total content is 35%~60%, in which: N 5%-11%, P2O520%-
37%, K2O 5%-15%;
Moderate-element Mg content is 0.1%~1.0%;
Microelement (B+Zn+Mo) total content is 0.21%~5.0%, in which: B0.1%~3.0%, Zn 0.1%~
2.0%, Mo 0.01%~0.05%;
Rare earth element 0.01%~0.1%;
Plant growth regulator combines 0.01-0.8%;
Water-soluble anticaking agent 0~10.0%.
The macronutrient refers to nitrogen, phosphorus, potassium, and content is respectively with N, P2O5、K2O meter, is selected from urea, sulfuric acid
Ammonium, sodium tripolyphosphate, ammonium dihydrogen phosphate, potassium dihydrogen phosphate, urea phosphate, potassium nitrate, two or more in potassium sulfate:
The moderate-element refers to magnesium, and content is in terms of Mg, selected from one of magnesium sulfate, magnesium nitrate, chelated magnesium or one kind
More than.
The microelement refers to boron, zinc and molybdenum, respectively in terms of B, Zn and Mo, is respectively selected from borax, boric acid, four water, eight boron
Acid disodium, zinc sulfate, chelated zinc, zinc nitrate, the three kinds or more in ammonium molybdate, sodium molybdate.
The rare earth element is by lanthanum (La), cerium (Ce), praseodymium (Pr), neodymium (Nd) two or more rare earth element group
At selected from soluble nitric acid rare earth.
The plant modifying agent combination are as follows: brassin lactones and Thidiazuron are in 1: (1~4) ratio combination.
The apple special solid type flower thinning Water soluble fertilizer preparation method is: special according to a kind of apple with flower thinning effect
With the ingredient and content of solid type Water soluble fertilizer, the material quantity being added required for calculating, the raw material after quantitatively weighing drying will be big
Graininess crushes, is sieved, and investment powder fertilizer production equipment, which is sufficiently mixed, to stir evenly, and subpackage is finished product.
Apple dedicated liquid type flower thinning Water soluble fertilizer is made of following component and content:
5~9 parts of humic acid substance
2.5~4 parts of nitric acid
5~8 parts of urea
10~16.5 parts of ammonium dihydrogen phosphate
4.5~7 parts of urea phosphate
3.5~6 parts of potassium hydroxide
2~3 parts of calcium of chelating
1~2 part of organic matter
1.5~2 parts of boron fertilizer
1.6~2.6 parts of chelated zinc
0.01~0.2 part of ammonium molybdate
0.01~0.06 part of nitric acid rare earth
Regulator combines 0.1~0.26 part
40~80 parts of water
The humic acid substance refers to one or both of mineral humic acid potassium, mineral sodium humate.
The nitric acid refers to the nitric acid of 40%~60% active constituent content.
The boron fertilizer refers to one of boric acid, borax, four water eight borate two sodium salt, liquid boron fertilizer or a variety of.
The chelated zinc refers to the chelates such as the EDTA of Zn-ef ficiency, citric acid.
Regulator combination refers to Nafusaku and 'Inshuzhi ' in 1: the combination of (1~3) ratio.
The chelating calcium refers to the chelates such as the EDTA of calcium, citric acid.
The organic matter refer to acetic acid, citric acid, citric acid derivant, soluble starch, glucose, in amino acid
It is one or more.
Apple dedicated liquid type flower thinning Water soluble fertilizer preparation method is:
Step 1: a certain amount of water is added in a kettle, stirring is opened, is slowly added to potassium hydroxide, stirring 5-10 divides
Clock is completely dissolved potassium hydroxide, and humic acid substance is added later, and stirring dissolves it sufficiently in 10-20 minutes.
Step 2: nitric acid is uniformly slowly added, neutralize it sufficiently with alkaline matter.
It is stirred respectively 20-30 minutes step 3: being down to 50 DEG C to temperature hereinafter, sequentially adding ammonium dihydrogen phosphate, urea phosphate
Dissolution.
Step 4: sequentially adding boron fertilizer, chelated zinc chelates calcium, and organic matter stirs 45~60 minutes respectively, makes it sufficiently
Dissolution.
Step 5: ammonium molybdate is added, stir 60~90 minutes, dissolves it all.
Step 6: urea is added, stir 10~20 minutes, dissolves it all.
Step 7: combining nitric acid rare earth and regulator, after first being dissolved with 2 parts of water respectively, sequentially add to the 6th step institute
It in the mixing liquid obtained, stirs 90-120 minutes, until being completely dissolved to get the apple moderate to dark brown, pH value 6-8, viscosity
Fruit dedicated liquid type flower and fruit thinning agent.Mixing time in preparation process can be adjusted according to the actual situation.
A kind of optimal use method of the dedicated Water soluble fertilizer of apple with flower thinning effect of the invention is as follows:
1, after full-bloom stage, i.e. the center 80-95% is used resulting apple dedicated liquid type flower thinning Water soluble fertilizer after the flowers are in blossom
A small amount of water dissolution, then plus clear water be made into 300-500 times of concentration, sprayed after then sufficiently shaking up once.
2, after apple dedicated liquid type flower thinning Water soluble fertilizer sprays 7-10 days, according to weather condition, by apple special solid type
Flower thinning Water soluble fertilizer is primary according to spraying after 1: 1000-1200 times of dilution, dredges and supplement fruits nutrition to mend.
The dedicated Water soluble fertilizer application notice of apple with flower thinning effect:
Because apple tree is not of uniform size, the age of tree, result situation are variant, and different cultivars uses concentration slightly difference, fall naturally
The big kind spraying concentration of fruit amount wants low, and the kind spraying concentration of difficult shedding wants high.Same piece of land has multiple apple varieties, and one
Secondary to prepare, concentration sprays same breed, has sprayed a kind and has sprayed another kind again.
It is ready-to-use, it should not put long, spray front and back utensil must be cleaned with clear water, sprayed other fertilizer medicaments, need to be separated by 7
More than it.
Compared with prior art, excellent results of the invention are as follows:
1, can Quan Rong, be instantly dissolved in water after be administered by water-fertilizer integral equipment.
2, this product is safer to natural enemy and people and animals.
3, effective flower thinning, safety do not hurt tree.While flower thinning, nutriment when fruit tree blooms can be supplemented.
4, the costs waste such as artificial is reduced, work efficiency is 5-8 times of traditional artificial flower and fruit thinning.
5, using this Flower thinning agent, the applicable time is long, range is wide, and climate condition influences smaller, promotes next year at flower, can show
Writing reduces biennial bearing, improves apple quality and yield.
Four, specific implementation method
The technical solution in the present invention is clearly and completely described below, it is clear that described embodiment is only
Several embodiments in the present invention, instead of all the embodiments.Based on the embodiments of the present invention, ordinary skill people
Member's every other embodiment obtained without creative efforts, shall fall within the protection scope of the present invention.
Example one:
1. the preparation of the dedicated Water soluble fertilizer of apple with flower thinning effect
(1) solid type has the preparation of the dedicated water-soluble fertilizer product of apple of flower thinning effect
After weighing drying, crushing, sieving 90 parts of urea (N, 46%), 100 parts of ammonium sulfate (N, 20%), potassium nitrate (N,
12%;K2O, 46%) 110 parts, ammonium dihydrogen phosphate (N, 11.5%;P2O5, 61%) and 294 parts, potassium dihydrogen phosphate (P2O5, 52%;
K2O, 34%) 234 parts, potassium sulfate (K2O, 52%) 36 parts, 34 parts of magnesium sulfate (Mg, 16%), 60 parts of boric acid (B, 17%), molybdic acid
1 part of ammonium (Mo, 54%), 35 parts of EDTA zinc (Zn, 14.5%), 1.4 parts of brassin lactones (effective component 99%) and benzthiazuron (have
Imitate ingredient 99%) 3.6 parts, 1 part of nitric acid rare earth (effective component 99%).
By above-mentioned raw materials under the small weather conditions of normal temperature and pressure, humidity, investment powder fertilizer production equipment is sufficiently mixed
It stirs evenly, subpackage is the water-soluble fertilizer product of apple special solid type with flower thinning effect.
This example solid type produced has the character of the dedicated water-soluble fertilizer product of apple of flower thinning effect as follows:
Macronutrient (N+P2O5+K2O) total content is 62.5%, in which: N 11%, P2O537%, K2O
14.5%;Moderate-element Mg content is 0.5%;Microelement (B+Zn+Mo) total content is 1.55%, in which: B 1%, Zn
0.5%, Mo 0.05%;Rare earth element 0.1%;Brassin lactones 0.14% and benzthiazuron 0.36%.
(2) liquid-type has the preparation of the dedicated water-soluble fertilizer product of apple of flower thinning effect
The water of 600kg is added in a kettle, opens stirring, is slowly added to 55kg potassium hydroxide, stirs 10 minutes, makes hydrogen
Potassium oxide is completely dissolved, and humic acid substance 60kg is added later, and stirring dissolves it sufficiently in 20 minutes.Mixing slowly process
In, 40% concentration nitric acid 30kg is uniformly slowly added, neutralizes it sufficiently with alkali.50 DEG C are down to hereinafter, successively adding to temperature
Enter ammonium dihydrogen phosphate 125kg, urea phosphate 70kg to stir 30 minutes;Boric acid 15kg is added, stirs 60 minutes, dissolves it sufficiently;
EDTA chelated zinc 20kg is added, stirs 45 minutes, dissolves it sufficiently;EDTA is added and chelates calcium 25kg, stirs 60 minutes, makes it
Sufficiently dissolution;Citric acid 15kg is added, stirs 50 minutes, dissolves it sufficiently;Ammonium molybdate 1kg is added, stirs 80 minutes, makes it
All dissolutions;Urea 60kg is added, stirs 20 minutes, dissolves it all.0.5kg nitric acid rare earth 20kg water is dissolved, it will
After 1kg methyl α-naphthyl acetate and 1kg 'Inshuzhi ' use 10kg water to dissolve respectively, before being added sequentially in the resulting mixing liquid of step, stirring
120 minutes, until being completely dissolved to get the apple dedicated liquid type flower and fruit thinning agent dark brown, viscosity is moderate is arrived.
This example liquid-type produced has the nutrient character of the dedicated water-soluble fertilizer product of apple of flower thinning effect as follows:
The pH value of liquid fertilizer is 7.55, partial neutral.Contain mineral sources humic acid 36g/L, N 50g/L, P2O5105g/L,
K2O 44g/L, Ca 2.23g/L, B 2.52g/L, Zn 2.8g/L, Mo 0.53g/L, organic matter 43g/L, methyl α-naphthyl acetate 1g/L, Yin
Ripe ester 1g/L.
2. application effect
2017, after red fuji apple full-bloom stage, i.e. the center 80-95% was after the flowers are in blossom, by the resulting liquid of embodiment one
Figure Flower thinning agent is dissolved with a small amount of water, then plus clear water, be made into the solution of 300 times of concentration, sprayed after sufficiently shaking up primary.Liquid-type
After Flower thinning agent sprays 9 days, after fine at 4 points in afternoon, after solid type Flower thinning agent is diluted according to rich water than 1: 1000 times
It sprays once, dredges and supplement fruits nutrition to mend.
As it can be seen from table 1 using the present invention is produced there is flower thinning to make on Shaanxi Province's Luochuan County red fuji apple
The dedicated Water soluble fertilizer of apple, flower thinning effect is strong compared with sevin, and fruit shape index, stain index and finish index compare sevin
Processing is high, applies the Water soluble fertilizer of flower thinning effect of the invention compared with sevin processing, single fruit weight can be made to improve 27.4%, yield mentions
It is 278kg/ mus high.As it can be seen that the dedicated Water soluble fertilizer of apple with flower thinning effect of the invention, is dredged carrying out chemical flower thinning to apple tree
While fruit, it can also be provided to various nutrients needed for the growth of apple tree florescence, solve apple under the conditions of water-fertilizer integral
Fruit flower and fruit thinning work take a lot of work, be time-consuming, the problem that safety is low, reduce the cost of peasant.Improve fruit shape index, coloring refers to
The quality factors such as number, also significantly improve apple single fruit weight and per mu yield, improve the income of peasant.
Table 1 has using effect of the dedicated Water soluble fertilizer of apple of flower thinning effect on the red fuji apple of Luochuan
Example two:
1. the preparation of the dedicated Water soluble fertilizer of apple with flower thinning effect
(1) solid type has the preparation of the dedicated water-soluble fertilizer product of apple of flower thinning effect
After weighing drying, sieving 190 parts of ammonium sulfate (N, 20%), potassium nitrate (N, 12%;K2O, 46%) 50 parts, phosphoric acid
Urea (N, 11%;P2O5, 44%) and 113 parts, potassium sulfate (K2O, 52%) 200 parts, sodium tripolyphosphate (P2O5, 57%) and 300 parts, sulfuric acid
60 parts of magnesium (Mg, 17%), 20 parts of boric acid (B, 17%), 1 part of ammonium molybdate (Mo, 54%), 10 parts of monohydrate zinc sulphate (Zn, 35%),
2 parts of brassin lactones (effective component 99%), 3.5 parts of benzthiazuron (effective component 99%), nitric acid rare earth (effective component 99%)
0.5 part, 50 parts of water-soluble anticaking agent.
By above-mentioned raw materials under the small weather conditions of normal temperature and pressure, humidity, investment powder fertilizer production equipment is sufficiently mixed
It stirs evenly, subpackage is the water-soluble fertilizer product of apple special solid type with flower thinning effect.
This example solid type produced has the character of the dedicated water-soluble fertilizer product of apple of flower thinning effect as follows:
Macronutrient (N+P2O5+K2O) total content is 40.3%, in which: N 6.3%, P2O521.6%, K2O
12.4%;Moderate-element Mg content is 1.0%;Microelement (B+Zn+Mo) total content is 1.55%, in which: B 0.33%, Zn
0.34%, Mo 0.05%;Rare earth element 0.05%;Brassin lactones 0.2%, benzthiazuron (effective component 99%) 0.35%.
(2) liquid-type has the preparation of the dedicated water-soluble fertilizer product of apple of flower thinning effect
The water of 700kg is added in a kettle, opens stirring, is slowly added to 52kg potassium hydroxide, stirs 10 minutes, makes hydrogen
Potassium oxide is completely dissolved, and humic acid substance 52kg is added later, and stirring dissolves it sufficiently in 20 minutes.Mixing slowly process
In, 40% concentration nitric acid 32kg is uniformly slowly added, neutralizes it sufficiently with alkali.50 DEG C are down to hereinafter, successively adding to temperature
Enter ammonium dihydrogen phosphate 105kg, urea phosphate 66kg to stir 30 minutes;Boric acid 16kg is added, stirs 60 minutes, dissolves it sufficiently;
EDTA chelated zinc 22kg is added, stirs 45 minutes, dissolves it sufficiently;EDTA is added and chelates calcium 30kg, stirs 60 minutes, makes it
Sufficiently dissolution: being added citric acid 11kg, stirs 50 minutes, dissolves it sufficiently;Ammonium molybdate 1.5kg is added, stirs 80 minutes, makes
It is all dissolved;Urea 50kg is added, stirs 20 minutes, dissolves it all.0.1kg nitric acid rare earth 20kg water is dissolved,
After using 10kg water to dissolve respectively 0.3kg methyl α-naphthyl acetate and 1kg 'Inshuzhi ', before being added sequentially in the resulting mixing liquid of step,
Stirring 120 minutes, until being completely dissolved to get the apple dedicated liquid type flower and fruit thinning agent dark brown, viscosity is moderate is arrived.
This example liquid-type produced has the nutrient character of the dedicated water-soluble fertilizer product of apple of flower thinning effect as follows:
The pH value of liquid fertilizer is 7.82, contains mineral sources humic acid 31g/L, N 45g/L, P2O591g/L, K2O 41g/
L, Ca 2.67g/L, B 2.69g/L, Zn 3.16g/L, Mo 0.8g/L, organic matter 37g/L, methyl α-naphthyl acetate 0.3g/L, 'Inshuzhi '
1g/L。
2. application effect
2017, after Cold region apple apple full-bloom stage, i.e. the center 80-95% was resulting by embodiment one after the flowers are in blossom
Liquid-type Flower thinning agent is made into the solution of 500 times of concentration, sprays after sufficiently shaking up primary.After liquid-type Flower thinning agent sprays 10 days,
It is before fine 10 AM, solid type Flower thinning agent is primary according to spraying after than 1: 1200 times dilution of rich water, dredged with to mend and
Supplement fruits nutrition.
From table 2 it can be seen that using the present invention is produced there is flower thinning to make on the Cold region apple apple of Shaanxi Province Tongchuan
The dedicated Water soluble fertilizer of apple, flower thinning effect, fruit shape index, stain index and finish index are higher than sevin processing, apply
The Water soluble fertilizer acted on flower thinning of the invention can make single fruit weight improve 22.3%, output increased 690kg/ compared with sevin processing
Mu.As it can be seen that the dedicated Water soluble fertilizer of apple with flower thinning effect of the invention, is carrying out the same of chemical flower and fruit thinning to apple tree
When, it can also be provided to various nutrients needed for the growth of apple tree florescence, apple flower thinning under the conditions of water-fertilizer integral can be solved
Fruit thinning work take a lot of work, be time-consuming, the problem that safety is low, reduce the cost of peasant.Improve the product such as fruit shape index, stain index
Prime factor also significantly improves apple single fruit weight and per mu yield, improves the income of peasant.
Table 2 has using effect of the dedicated Water soluble fertilizer of apple of flower thinning effect on the Cold region apple apple of Baoji