CN1097018A - Emulsion resin adhesive for gluing plastic and paper - Google Patents
Emulsion resin adhesive for gluing plastic and paper Download PDFInfo
- Publication number
- CN1097018A CN1097018A CN 93107535 CN93107535A CN1097018A CN 1097018 A CN1097018 A CN 1097018A CN 93107535 CN93107535 CN 93107535 CN 93107535 A CN93107535 A CN 93107535A CN 1097018 A CN1097018 A CN 1097018A
- Authority
- CN
- China
- Prior art keywords
- glue
- paper
- resin
- vinylformic acid
- emulsion
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Adhesives Or Adhesive Processes (AREA)
Abstract
Emulsion resin adhesive for gluing plastic and paper, it relates to tackiness agent, relates in particular to compound thermosetting adhesive.This tackiness agent is mixed by vinylformic acid or vinylformic acid vinegar milk liquid, vinyl-formal resin glue, toluene resin glue, severe property polystyrene glue, FS-5 glue.It is specially adapted to the ply adhesion of matrix materials such as polypropylene woven cloth-plastic film, paper-plastic film, and it both had been applicable to that non-polar material was bonding, was applicable to that also polar material is bonding; Compound tense adopts hot blast to give the heat applying positioning process of colding pressing, and is convenient to suitability for industrialized production.It is bonding firmly, heatproof, moisture-proof, ageing resistance are good, and purposes is very extensive, and price is low.
Description
The present invention relates to tackiness agent, relate in particular to the composite type heat cure adhesive.
As everyone knows, along with the development of industrial or agricultural and commodity economy, the novel porous materials of purposes building, decoration, packing etc. is constantly asked the city.As the tackiness agent of one of composite material base, different with needs because of the physical and chemical performance of matrix material, the category of tackiness agent and specification are extremely various, as: polyvinyl alcohol, polyvinyl acetal, its ester of Vinyl Acetate Copolymer, polyacrylic acid and vinegar, urethane etc.The various matrix materials of making thus, because of its have respectively high-strength, corrosion resistant, anti-aging, outward appearance is beautiful, sound insulation, heat insulation or have certain special performances concurrently, and be widely used in each field such as machinery, chemical industry, building, commodity packaging, bringing into play huge social benefit and economic benefit.
But, in this process, people are many unavoidably to be concentrated on energy high-grade or expensive matrix material and corresponding tackiness agent, and the compound package material of the not high commodity of appearance requirement and low lattice cheap and the development and the exploitation of the tackiness agent that performance requriements is higher have been ignored, so chemical fertilizer, grain, cement, salt, alkali, ore in sand form are led particulate materials, still use paper bag, gunnysack or polypropylene woven bag, plastic bag packaging.Because there is intensity difference respectively in this packing bag or wet strength is poor, the shortcoming of water resistance difference,, cause huge financial loss so the normal accidents such as packing bag cracking, rainwater infiltration that take place cause material leakage or circuitous aqueous metamorphism.
The present invention's purpose is: a kind of tackiness agent that is used to make paper one plastic composite materials is provided, makes matrix material have advantages such as intensity height, good waterproof performance, thereby reduce or stop to be wrapped the material leakage or the accident that becomes damp and rotten.
The present invention realizes above-mentioned purpose like this:
Along with the development of chemical industry, paper bag, cloth bag or polypropylene woven bag that much more more and more the heavy packages bag of China adopts plastic lining to put.When dress food, the lining plastics adopt avirulent polyethylene.In view of polyethylene or polypropylene all are non-polar material " difficult sticking material ", and common paper and Bu Ze are polar material, so this tackiness agent must be the non-polar material tackiness agent.For when making matrix material, not damaging plastics, paper, cloth or woven bag, this tackiness agent must be the thermotolerance hot melt adhesive, can with lower molecular weight low density olefines: miscible preferably, bonding as polyethylene, polypropylene.Owing to be subjected to the packing material price lower, the packing bag price can not be high, so this tackiness agent is essential cheap.
Based on above-mentioned requirements, I obtain the paper compound resin emulsion viscose binder of best results at last through a large amount of technological tests of filling a prescription and screening and making cloth/film and cloth/film/paper composites.This tackiness agent is by vinylformic acid or acrylic ester emulsion, and vinyl-formal resin glue, toluene resin glue, severe property polystyrene glue, FS-5 glue are formed.
Its prescription is as follows:
Vinylformic acid or acrylate latex 22-27%
Vinyl-formal resin glue 6-10%
Toluene resin glue 22-27%
Severe property polystyrene glue 22-37%
FS-5 glue 16-21%
Its optimum formula is
Vinylformic acid or acrylate latex 24-25%
Vinyl-formal resin glue 8-8.5%
Toluene resin glue 24-25%
Severe property polystyrene glue 24-25%
FS-5 glue 18-19%.
With vinylformic acid or acrylic ester emulsion and vinyl-formal resin mixing, it is standby to make mixture (I) by above-mentioned prescription; Toluene resin glue is mixed with severe property polystyrene glue, make mixture (II); With behind (I) and (II) thorough mixing, add FS-5 glue and mix, emulsion resin adhesive for gluing plastic and paper.
Embodiment and effect:
Example 1: the tackiness agent of making by above-mentioned prescription and technology, when being used in the matrix material manufacturing of kraft paper one plastic film, polypropylene woven cloth-plastic film, polypropylene woven cloth-plastic film-kraft paper respectively, adopt hot blast to give the heat applying localization method technology of colding pressing, be convenient to streamline operration.Through evidence, ply adhesion is firm, moisture-proof, heat-resisting, and ageing resistance is good; From performance, easy to process and price is investigated, and all is better than (all not succeeding) commercial binder once on probation.
Example 2: after above-mentioned enforcement success, try out in polyethylene, polystyrene, polyester, nylon, the poly-third ethene packing film, paraffin paper, wood-based plate edge sealing, Mierocrystalline cellulose and porous material bondingly again respectively, all obtain good result.
Claims (2)
1, a kind of compound resin emulsion adhesive by various kinds of resin emulsion (glue) preparation, it is characterized in that: this emulsion resin adhesive for gluing plastic and paper is mixed by vinylformic acid or acrylic ester emulsion, vinyl-formal resin glue, toluene resin glue, severe property polystyrene glue and FS-5 glue, and its prescription is:
Vinylformic acid or vinylformic acid vinegar milk liquid 22-27%
Polyvinylformal Resin adhesive 6-10%
Toluene resin glue 22-27%
Severe property polystyrene glue 22-27%
FS-5 glue 16-21%.
2, emulsion resin adhesive for gluing plastic and paper according to claim 1 is characterized in that: the optimum formula of this tackiness agent is:
Vinylformic acid or acrylic ester emulsion 24-25%
Vinyl-formal resin glue 8-8.5%
Toluene resin glue 24-25%
Severe property polystyrene glue 24-25%
FS-5 glue 18-19%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 93107535 CN1097018A (en) | 1993-06-30 | 1993-06-30 | Emulsion resin adhesive for gluing plastic and paper |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 93107535 CN1097018A (en) | 1993-06-30 | 1993-06-30 | Emulsion resin adhesive for gluing plastic and paper |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1097018A true CN1097018A (en) | 1995-01-04 |
Family
ID=4986750
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 93107535 Pending CN1097018A (en) | 1993-06-30 | 1993-06-30 | Emulsion resin adhesive for gluing plastic and paper |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1097018A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110312773A (en) * | 2017-02-20 | 2019-10-08 | 3M创新有限公司 | From wet adhesive composition |
-
1993
- 1993-06-30 CN CN 93107535 patent/CN1097018A/en active Pending
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110312773A (en) * | 2017-02-20 | 2019-10-08 | 3M创新有限公司 | From wet adhesive composition |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US6582830B2 (en) | Adhesive tape and products made therefrom | |
| EP1976953B1 (en) | Hot melt adhesive composition | |
| Ülker | Wood adhesives and bonding theory | |
| CN105733494B (en) | A kind of hot melt adhesive and preparation method thereof | |
| CA2376503A1 (en) | Water-based pressure sensitive adhesives having enhanced characteristics | |
| WO1996011301A1 (en) | Resin-coated overlays for solid substrates | |
| CN110435273A (en) | One kind overlaying waterproof roll and preparation method thereof | |
| US3558418A (en) | Blocking-resistant plasticizer articles,compositions and processes | |
| CN1097018A (en) | Emulsion resin adhesive for gluing plastic and paper | |
| CN101045357A (en) | Coating technology for enhancing secondary base material composite fastness in extrusion composite | |
| CN1119979A (en) | Water-resistant plywood and its production method | |
| CN2196086Y (en) | Composite paper for cement pack bag | |
| CN203614994U (en) | Decorative insulation plate and refrigeration equipment applying same | |
| CN2635356Y (en) | Paper plastic composite structure | |
| CN105368331A (en) | Multifunctional bamboo wood processing adhesive and manufacturing method thereof | |
| CN109736523A (en) | A kind of dalle of Dampproof | |
| CN208615432U (en) | PET opal special type sequin sheet material | |
| CN215708569U (en) | Packaging film with strong weather resistance | |
| CN2124132U (en) | Composite plastic board | |
| CN202319180U (en) | Biaxially oriented polypropylene (BOPP) paper imitating film | |
| JPH03193440A (en) | Reflective sheet | |
| CN1163409A (en) | Material and technology for producing reflective film | |
| CN1074466A (en) | Quick-drying silver powder lacquer and method for making | |
| CN201981148U (en) | Safe pre-coating film used for light ceramic plate | |
| CN109135164B (en) | Low-energy-consumption direct-throwing granular colored asphalt and preparation method and use method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C01 | Deemed withdrawal of patent application (patent law 1993) | ||
| WD01 | Invention patent application deemed withdrawn after publication |