CN109694782A - A kind of ceramics cleaning agent and preparation method thereof - Google Patents
A kind of ceramics cleaning agent and preparation method thereof Download PDFInfo
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- CN109694782A CN109694782A CN201711002544.1A CN201711002544A CN109694782A CN 109694782 A CN109694782 A CN 109694782A CN 201711002544 A CN201711002544 A CN 201711002544A CN 109694782 A CN109694782 A CN 109694782A
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/044—Hydroxides or bases
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2068—Ethers
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/33—Amino carboxylic acids
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/36—Organic compounds containing phosphorus
- C11D3/361—Phosphonates, phosphinates or phosphonites
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
- C11D1/146—Sulfuric acid esters
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
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Abstract
The present invention provides a kind of ceramic cleaning agent, including 3-10 parts of inorganic base, 3-14 parts of intercalating agent, 5-18 parts of solubilizer, 3.5-17 parts of surfactant and balance deionized water.Using ceramic cleaning agent of the invention, effect is: (1) formula is simplified, and raw material is easy to get, moderate cost;(2) each raw material is using reasonable proportion, have the characteristics that alkalinity is weak, wettability is strong, do not corrode ceramic base material and has unique penetration, ceria, silica, aluminum oxide granules of accessories residual used in rough polishing process, essence throwing process can be efficiently removed, product qualification rate is up to 96%.The present invention also provides a kind of preparation method of ceramic cleaning agent, preparation process is simplified, is convenient for industrialized production.
Description
Technical field
The present invention relates to cleaning technique fields, and in particular to a kind of ceramics cleaning agent and preparation method thereof.
Background technique
In recent years, the spectrum technology of 3Ghz or more will be used as 5G is communicated, because zirconia ceramics cell phone rear cover has
No signal screen disadvantage, hardness are high, perception is strong and the features such as close to metal material excellent heat radiation, when becoming cellphone enterprise and marching 5G
The important selection in generation.
Zirconia ceramics is cell phone rear cover inorganic non-metallic material and high score after a kind of collection metal material, nonmetallic materials
The Common advantages of sub- material, the zirconia ceramics of emergence is then to have conduction under insulator, high temperature under super-strength resistant to high temperatures, room temperature
The excellent performances such as Optimality, multi-functional are leading in the new material world, (outstanding to high-grade wrist-watch industry and touch screen manufacturing enterprise
It is touch-screen mobile phone manufacturing enterprise) unlimited development space is brought, touch screen back shroud processing enterprise is also with rapid hair
Exhibition is grown.
The processing technologys such as the application of zirconia ceramics be unable to do without rough polishing, essence is thrown, usually there are titanium dioxides on its surface after processing
The liquid grain such as cerium, silica, aluminum oxide, if cleaning is bad, will lead to product, there are surfaces to be easily corroded, it is heterochromatic to generate
Etc. bad.
Existing cleaning agent is many kinds of, is suitable for glass mostly, and the cleaning agent type for being directed to ceramics is also various, such as
Under:
Application No. is 201510842551.7 patent applications to disclose a kind of ceramic membrane cleaning agent comprising following quality
Part raw material: 50-60 parts of glycolic, 1-6 parts of sodium tetraborate, 5-10 parts of neopelex, 10-20 parts of sodium citrate,
1-10 parts and methylcellulose 1-4 parts of potassium silicate.Above-mentioned ceramic membrane cleaning agent is used to clean Chinese medicine of the micro-filtration based on botanical medicine
The ceramic membrane of liquid preparation has effects that clean and sterilize double-deck.
Application No. is 201510381577.6 patent applications to disclose a kind of ceramic cleaning agent, the ceramics cleaning agent packet
Include the raw material of following parts by weight: 8-12 parts of acrylic acid, 6-10 parts of alkyl phosphate, 6-10 parts of sodium alklyarylsulfonate, cocounut oil rouge
1-5 parts of fat acid diglycollic amide, 4-8 parts of trihydroxyethyl methyl quaternary amine Methylsulfate, 4-8 parts of lauryl sodium sulfate, sesame
2-6 parts oily, 1-5 parts of tea oil and 80-120 parts of deionized water.This ceramic cleaning agent can thoroughly remove rapidly all kinds of ceramic tile surfaces,
Tough stains in gap.
Application No. is 201310036507.8 patent applications to disclose a kind of Alkaline cleaner for ceramic hand mold, required raw material
And weight proportion is as follows: potassium hydroxide or sodium hydroxide 0.5-30%;Hydroxyl organic carboxyl acid salt ion chelating agent 0.1-20%;
Corrosion inhibiter 0.1-10%;Sodium hypochlorite stabilizer 0.1-10%;Water surplus.This cleaning agent is for removing remaining fat on fingerprint
Sour attachment and yellow strain object etc..
In addition to this, there are also other ceramic cleaning agents, purpose is all to remove the pollutant etc. for being attached to ceramic surface, really
Protect the cleaning of ceramic product.Existing ceramics cleaning agent cannot be used for the ceramic thick, essence of removal and throw the polishing of process zirconia ceramics
The particles such as rear surface ceria, silica, aluminum oxide or liquid grain.
Therefore, remaining particle or liquid grain and the high cleaning agent of removal rate during a kind of suitable removal Ceramic manufacturing are researched and developed
It is of great significance.
Summary of the invention
It is simplified it is an object of that present invention to provide a kind of formula and can efficiently remove ceramic thick, essence and thrown process zirconia ceramics and throw
The ceramic cleaning agent of the particles such as light rear surface ceria, silica, aluminum oxide or liquid grain, specific technical solution is such as
Under:
A kind of ceramics cleaning agent, includes following raw material based on parts by weight: 3-10 parts of inorganic base, increases 3-14 parts of intercalating agent
5-18 parts of solvent, 3.5-17 parts of surfactant and 60-82 parts of deionized water.
Preferred in above technical scheme, the surfactant is by 0.5-1 parts of anionic surfactant and nonionic
3-16 parts of surfactant compositions.
It is preferred in above technical scheme, the intercalating agent be tetrasodium ethylenediamine tetraacetate, disodium ethylene diamine tetraacetate with
And at least one of 1-hydroxy ethylidene-1,1-diphosphonic acid;
The solubilizer is diethylene glycol monobutyl ether, diethylene glycol dimethyl ether, ethylene glycol ethyl ether, ethylene glycol monomethyl ether and ethyl alcohol
At least one of;
The nonionic surfactant is octyl phenol polyoxyethylene ether, nonylphenol polyoxyethylene ether, isomerous tridecanol are poly-
At least one of ethylene oxide ether and octenyl succinic acid anhydride.
Preferred in above technical scheme, the anionic surfactant is lauryl sodium sulfate, isooctanol polyoxy
At least one of ethylene ether phosphate and neopelex;
The inorganic base is potassium hydroxide;
The intercalating agent is by 3-8 parts of 1-hydroxy ethylidene-1,1-diphosphonic acids, 1-3 parts of tetrasodium ethylenediamine tetraacetates and 0.5-2.5 parts of second two
Amine tetraacethyl disodium mixes;
The solubilizer is by 3-6 parts of diethylene glycol monobutyl ethers, 1-3 parts of diethylene glycol dimethyl ethers, 1-3 parts of ethylene glycol ethyl ethers, 1-3
Part ethylene glycol monomethyl ether and 1-3 parts of ethyl alcohol mix;
The nonionic surfactant is by 1-3 parts of octyl phenol polyoxyethylene ether, 2-5 parts of nonylphenol polyoxyethylene ether, 1-4
Part isomerous tridecanol polyoxyethylene ether and 0.2-1.1 parts of octenyl succinic acid anhydrides mix.
Using ceramic cleaning agent of the invention, have the following characteristics that
Formula is simplified, and raw material is easy to get, moderate cost.
The present invention uses the combination of inorganic base, intercalating agent, solubilizer, surfactant and deionized water, inorganic base
Using so that entire ceramics cleaning agent is in alkalescent;Intercalating agent can neutralize free alkali in ionized water, reduce corrosion substrate, subtract
Less because of surface color difference caused by corroding, and chelating agent combines stirring, can make particle fast-falling;Solubilizer and surface-active
The combination of agent, it is ensured that ceramic cleaning agent has high penetration, so that particle can thoroughly be detached from substrate surface;Inorganic base,
Chelating agent, solubilizer and surfactant etc. are applied in combination, and act synergistically each other, greatly improve ceria, dioxy
The removal rate of the granules of accessories such as SiClx, aluminum oxide;Each raw material uses reasonable proportion, has alkaline weak, wettability by force, no
Corrode ceramic base material and have the characteristics that unique penetration, can efficiently remove rough polishing process, essence is thrown two used in process
Cerium oxide, silica, aluminum oxide granules of accessories residual, product qualification rate are up to 96%.
Of the invention also discloses a kind of preparation method of ceramic cleaning agent, specifically: by inorganic base, intercalating agent, solubilising
Agent, anionic surfactant, nonionic surfactant and deionized water are uniformly mixed to get ceramic cleaning agent;Mixing
Mixing speed in the process is 10-60 revs/min.Preparation method process flow is simplified, and production cost is low, is convenient for extensive metaplasia
It produces.
The invention also discloses another preparation methods of ceramic cleaning agent, specifically: the following steps are included:
Step 1: will be added in reactor by the weighed deionized water of part;Deionization will be added by the weighed inorganic base of part
The first mixed liquor is stirred to get in water;It will be added in the first mixed liquor and be stirred by the weighed chelating agent of part again, and obtain second
Mixed liquor;
It is stirred evenly step 2: will be added in the second mixed solution by the weighed solubilizer of part, obtains third mixed liquor;
Step 3: by being added by the weighed anionic surfactant of part etc. in the third mixed liquor of weight after mixing evenly
It is added in the third mixed liquor of surplus and is stirred, obtain the 4th mixed liquor;
It stirs evenly, obtains ceramic clear step 4: will be added in the 4th mixed liquor by the weighed nonionic surfactant of part
Lotion;
Raw material includes 3-10 parts of inorganic base, 3-11 parts of intercalating agent, 5-18 parts of solubilizer, anionic surfactant 0.5-1
Part, 3.0-16 parts of nonionic surfactant and 60-82 parts of deionized water.
Preferred in above technical scheme, the anionic surfactant is lauryl sodium sulfate, isooctanol polyoxy
At least one of ethylene ether phosphate and neopelex;
The inorganic base is potassium hydroxide;
The intercalating agent is by 3-8 parts of 1-hydroxy ethylidene-1,1-diphosphonic acids, 1-3 parts of tetrasodium ethylenediamine tetraacetates and 0.5-2.5 parts of second two
Amine tetraacethyl disodium mixes;
The solubilizer is by 3-6 parts of diethylene glycol monobutyl ethers, 1-3 parts of diethylene glycol dimethyl ethers, 1-3 parts of ethylene glycol ethyl ethers, 1-3
Part ethylene glycol monomethyl ether and 1-3 parts of ethyl alcohol mix;
The nonionic surfactant is by 1-3 parts of octyl phenol polyoxyethylene ether, 2-5 parts of nonylphenol polyoxyethylene ether, 1-4
Part isomerous tridecanol polyoxyethylene ether and 0.2-1.1 parts of octenyl succinic acid anhydrides mix.
Preferred in above technical scheme, the reactor is the reaction kettle with blender and cooling recirculation system;
The cooling recirculation system of reaction kettle is opened when inorganic base is added in deionized water, the revolving speed of blender is 10-15
Rev/min;The temperature of the first mixed liquor is 30 DEG C -40 DEG C when chelating agent is added, and the revolving speed of blender is 10-15 revs/min;
The temperature that the second mixed solution is added in solubilizer is 30 DEG C -40 DEG C, and the mixing speed of blender is 30-35 revs/min
Clock;
Anionic surfactant and etc. weight third mixed liquor mixing when be stirred;With the third mixed liquor of surplus
The mixing speed of blender is 25-32 revs/min when being mixed;
The temperature of the 4th mixed liquor is 35 DEG C -45 DEG C when nonionic surfactant is added, and the mixing speed of blender is
28-32 revs/min.
Using the preparation method of ceramic cleaning agent of the invention, inorganic base, chelating agent, solubilizer, anion surface active
Agent and nonionic surfactant sequentially add, it is ensured that the efficiency of each component play best (details are: can quickly neutralize ceramics
Free alkali in cleaning agent process for preparation, free alkali can reduce in the process of cleaning to substrate corrode it is heterochromatic, and using control
The revolving speed of blender obtains the interworking chelating power of component, and temperature and agitator speed control make solubilizer obtain better system increasing
Molten effect can obtain the ceramic cleaning agent finished product of golden transparent moment) so that last ceramic cleaning agent obtained has alkalinity
Weak, wettability is strong, does not corrode ceramic base material and has the characteristics that unique penetration, except making in rough polishing process, essence throwing process
Ceria, silica, aluminum oxide oxygen granules of accessories residual, cleaning effect is good, can thoroughly remove mobile phone rapidly
Stubbornness on rear cover ceramic surface is dirty, and cleaning product can test qualification rate 96% or more, conducive to pushing away extensively by five wave lamp inspections
Wide application;Preparation process is simple, is easily achieved, high production efficiency, the long service life of cleaning solution.
Other than objects, features and advantages described above, there are also other objects, features and advantages by the present invention.
Below with reference to specific embodiment, the present invention is described in further detail.
Specific embodiment
Technical solution of the present invention is described in detail below in conjunction with specific embodiment, but the present invention can be according to right
It is required that the multitude of different ways for limiting and covering is implemented.
Embodiment 1:
A kind of ceramics cleaning agent, is specially adapted to the cleaning of zirconia ceramics, raw material includes as follows based on parts by weight
Ingredient: 10 parts of inorganic base, 10 parts of intercalating agent, 10 parts of solubilizer, 1 part of anionic surfactant, nonionic surfactant 7
Part;62 parts of deionized water.
The inorganic base is that potassium hydroxide purity is greater than 85%, and the potassium hydroxide of electrolysis takes off after being dissolved in water than sodium hydroxide difficulty
Water dissolves in ethyl alcohol, is slightly soluble in ether.
The intercalating agent be 1-hydroxy ethylidene-1,1-diphosphonic acid, a kind of white crystalline, important intercalating agent that is nontoxic, being easy to become solution in water,
Stable structure.
The solubilizer is diethylene glycol monobutyl ether, and smell is small, water-soluble and alcohol.
The anionic surfactant is lauryl sodium sulfate, a kind of white needles, nontoxic anionic surface work
Property agent, biological solution degree > 90% has decontamination, emulsification and an excellent foaming power, when spicule operation it is not volatile to human body without
Injury.
The nonionic surfactant is mixed by 4 parts of octyl phenol polyoxyethylene ether and 3 parts of octenyl succinic acid anhydrides.
A kind of preparation method of above-mentioned ceramic cleaning agent comprising following steps:
The first step weighs deionized water by weight, is added in reaction kettle;Inorganic base weighed by weight is slowly poured into again
In reaction kettle, be uniformly mixing to obtain the first mixed liquor (mixing speed be 10 revs/min), when being stirred due to being added after inorganic base from
Sub- coolant-temperature gage can increase, while need to open the cooling recirculation system of reaction kettle;When the first mixeding liquid temperature is down to 35 DEG C, stop
Reaction kettle stirring, intercalating agent weighed by weight is slowly added into the first mixed liquor, is added rear turn on agitator and is carried out at a slow speed
Stirring (agitator speed is 12 revs/min), (stirs evenly up to the second mixed liquor) after being completely dissolved intercalating agent in carrying out
Speed stirring (revolving speed of blender is 30 revs/min);
Second step, when the temperature of the second mixed liquor in reaction kettle is down to 35 DEG C, will solubilizer weighed by weight slowly
It pours into the second mixed liquor and is stirred, the mixing speed of blender is 30 revs/min;
Third step weighs anionic surfactant by weight, and equivalent is taken from reaction kettle with small white glue bucket second mixes
It closes and is stirred by hand in liquid addition anionic surfactant, after anionic surfactant dissolves in the second mixed liquor again slowly
It pours into the second mixed liquor of surplus in reaction kettle and starts quick stirring and dissolving, preferably the revolving speed of blender is 30 revs/min, is stirred
It mixes uniformly up to third mixed liquor;
4th step, when third mixeding liquid temperature is down to 40 DEG C in reaction kettle, weighed non-ionic surface by weight is living
Property agent slowly pour into the third mixed liquor in reaction kettle, the revolving speed of the preferred blender of middling speed is 30 revs/min, is stirred and dissolved into
Ceramic cleaning agent is made after transparent clear liquid.
The specific method that the present embodiment carries out zirconia ceramics cleaning is carried out clearly using automatic nine groove ultrasonics cleaning machine
It washes, can refer to the prior art.
The formula of ceramics cleaning agent provided by the invention is reasonable, Cleaning principle are as follows: ceria, silica, three oxygen
Change two aluminum oxides small difficulty of partial size in the cleaning of zirconia ceramics product to wash, and the 1-hydroxy ethylidene-1,1-diphosphonic acid in intercalating agent can
Free alkali in ionized water is neutralized, reduction corrosion substrate is heterochromatic, under huge legendary turtle and agent effect, increases machine by means of increasing ultrasonic wave galvanic electricity
The effect of tool power makes particle quickly shake to loosen and fall;Reaching unique penetration more using the effect of alcohol ether interworking can increase sharply
Scavenging period and temperature make particle be detached from substrate surface, to reach cleaning purpose.
Compared with prior art, the invention has the following advantages:
1, the present embodiment ceramics cleaning agent formula is reasonable, and alkalinity is weak, wettability is strong, does not corrode ceramic base material.Unique infiltration
Saturating power can more remove rapidly rough polishing process, essence throws ceria, silica, aluminum oxide oxygen auxiliary material used in process
Grain residual, cleaning effect is good, and the stubbornness that can be thoroughly removed rapidly on cell phone rear cover ceramic surface is dirty, and cleaning product can pass through five
Wave lamp inspection tests qualification rate 96% or more, is conducive to wide popularization and application.
2, preparation process is simple, is easily achieved, high production efficiency, and the long service life of cleaning solution is (for conventional ceramic cleaning
One times of agent service life, about 48 hours).
Above-described embodiment is only the preferable embodiment of the present invention, and the present invention cannot enumerate out whole embodiment party
Formula, all technical solutions using one of above-described embodiment, or the equivalent variations done according to above-described embodiment are protected in the present invention
It protects in range.
Embodiment 2:
The present embodiment difference from Example 1 is only that: when the preparation method of ceramic cleaning agent: by inorganic base, chelating
Agent, solubilizer, anionic surfactant, nonionic surfactant and deionized water are uniformly mixed to get ceramics cleaning
Agent.Mixing speed is 30 revs/min.
Zirconia ceramics is carried out clearly according to identical method in embodiment 1 using ceramic cleaning agent obtained by the present embodiment
It washes, effect is:
Qualification rate is 96% or more.
The service life of cleaning solution is one times, about 48 hours of conventional ceramic cleaning agent service life.
Embodiment 3-5:
Embodiment 3-5 difference from Example 1 is table 1:
The component proportion of the ceramic cleaning agent of 1 embodiment 1-5 of table
Table 2 implements the component proportion Commissioning Contrast effect of the ceramic cleaning agent of 1-5:
As shown in Table 2: the technical solution of Application Example 3-5, it is relatively good to the cleaning effect of ceramics.
The foregoing is only a preferred embodiment of the present invention, is not intended to restrict the invention, for the skill of this field
For art personnel, the invention may be variously modified and varied.All within the spirits and principles of the present invention, made any to repair
Change, equivalent replacement, improvement etc., should all be included in the protection scope of the present invention.
Claims (9)
1. a kind of ceramics cleaning agent, which is characterized in that based on parts by weight include following raw material: 3-10 parts of inorganic base, intercalating agent
3-14 parts, 5-18 parts of solubilizer, 3.5-17 parts of surfactant and 60-82 parts of deionized water.
2. ceramics cleaning agent according to claim 1, which is characterized in that the surfactant is by anion surface active
0.5-1 parts and nonionic surfactant 3-16 parts compositions of agent.
3. it is according to claim 2 ceramics cleaning agent, which is characterized in that the intercalating agent be tetrasodium ethylenediamine tetraacetate,
At least one of disodium ethylene diamine tetraacetate and 1-hydroxy ethylidene-1,1-diphosphonic acid;
The solubilizer is in diethylene glycol monobutyl ether, diethylene glycol dimethyl ether, ethylene glycol ethyl ether, ethylene glycol monomethyl ether and ethyl alcohol
It is at least one;
The nonionic surfactant is octyl phenol polyoxyethylene ether, nonylphenol polyoxyethylene ether, isomerous tridecanol polyoxy second
At least one of alkene ether and octenyl succinic acid anhydride.
4. ceramics cleaning agent according to claim 3, which is characterized in that the anionic surfactant is dodecyl
At least one of sodium sulphate, Phosphate of Polyoxyethylene Isooctyl Ether and neopelex;
The inorganic base is potassium hydroxide;
The intercalating agent is by 3-8 parts of 1-hydroxy ethylidene-1,1-diphosphonic acids, 1-3 parts of tetrasodium ethylenediamine tetraacetates and 0.5-2.5 parts of ethylenediamine tetraacetics
Acetic acid disodium mixes;
The solubilizer is by 3-6 parts of diethylene glycol monobutyl ethers, 1-3 parts of diethylene glycol dimethyl ethers, 1-3 parts of ethylene glycol ethyl ethers, 1-3 parts of second
Glycol methyl ether and 1-3 parts of ethyl alcohol mix;
The nonionic surfactant by 1-3 parts of octyl phenol polyoxyethylene ether, 2-5 parts of nonylphenol polyoxyethylene ether, 1-4 parts it is different
Structure tridecanol polyoxyethylene ether and 0.2-1.1 parts of octenyl succinic acid anhydrides mix.
5. a kind of preparation method of ceramics cleaning agent, which is characterized in that inorganic base, intercalating agent, solubilizer, anionic surface is living
Property agent, nonionic surfactant and deionized water be uniformly mixed to get ceramic cleaning agent;
Raw material includes 3-10 parts of inorganic base, 3-11 parts of intercalating agent, 5-18 parts of solubilizer, 0.5-1 parts of anionic surfactant, non-
3.0-16 parts of ionic surface active agent and 60-82 parts of deionized water.
6. the preparation method of ceramics cleaning agent according to claim 5, which is characterized in that the anionic surfactant
For at least one of lauryl sodium sulfate, Phosphate of Polyoxyethylene Isooctyl Ether and neopelex;
The inorganic base is potassium hydroxide;
The intercalating agent is by 3-8 parts of 1-hydroxy ethylidene-1,1-diphosphonic acids, 1-3 parts of tetrasodium ethylenediamine tetraacetates and 0.5-2.5 parts of ethylenediamine tetraacetics
Acetic acid disodium mixes;
The solubilizer is by 3-6 parts of diethylene glycol monobutyl ethers, 1-3 parts of diethylene glycol dimethyl ethers, 1-3 parts of ethylene glycol ethyl ethers, 1-3 parts of second
Glycol methyl ether and 1-3 parts of ethyl alcohol mix;
The nonionic surfactant by 1-3 parts of octyl phenol polyoxyethylene ether, 2-5 parts of nonylphenol polyoxyethylene ether, 1-4 parts it is different
Structure tridecanol polyoxyethylene ether and 0.2-1.1 parts of octenyl succinic acid anhydrides mix;
Mixing speed in mixed process is 10-60 revs/min.
7. a kind of preparation method of ceramics cleaning agent, which comprises the following steps:
Step 1: will be added in reactor by the weighed deionized water of part;It will be added in deionized water by the weighed inorganic base of part
Stir to get the first mixed liquor;It will be added in the first mixed liquor and be stirred by the weighed chelating agent of part again, and obtain the second mixing
Liquid;
It is stirred evenly step 2: will be added in the second mixed solution by the weighed solubilizer of part, obtains third mixed liquor;
Step 3: being stirring evenly and then adding into being added by the weighed anionic surfactant of part etc. in the third mixed liquor of weight
It is stirred in the third mixed liquor of surplus, obtains the 4th mixed liquor;
It is cleaned step 4: will be added in the 4th mixed liquor to stir evenly by the weighed nonionic surfactant of part to get ceramics
Agent;
Raw material includes 3-10 parts of inorganic base, 3-11 parts of intercalating agent, 5-18 parts of solubilizer, 0.5-1 parts of anionic surfactant, non-
3.0-16 parts of ionic surface active agent and 60-82 parts of deionized water.
8. the preparation method of ceramics cleaning agent according to claim 7, which is characterized in that the anionic surfactant
For at least one of lauryl sodium sulfate, Phosphate of Polyoxyethylene Isooctyl Ether and neopelex;
The inorganic base is potassium hydroxide;
The intercalating agent is by 3-8 parts of 1-hydroxy ethylidene-1,1-diphosphonic acids, 1-3 parts of tetrasodium ethylenediamine tetraacetates and 0.5-2.5 parts of ethylenediamine tetraacetics
Acetic acid disodium mixes;
The solubilizer is by 3-6 parts of diethylene glycol monobutyl ethers, 1-3 parts of diethylene glycol dimethyl ethers, 1-3 parts of ethylene glycol ethyl ethers, 1-3 parts of second
Glycol methyl ether and 1-3 parts of ethyl alcohol mix;
The nonionic surfactant by 1-3 parts of octyl phenol polyoxyethylene ether, 2-5 parts of nonylphenol polyoxyethylene ether, 1-4 parts it is different
Structure tridecanol polyoxyethylene ether and 0.2-1.1 parts of octenyl succinic acid anhydrides mix.
9. the preparation method of ceramics cleaning agent according to claim 7, which is characterized in that the reactor is with stirring
The reaction kettle of device and cooling recirculation system;
The cooling recirculation system of reaction kettle is opened when inorganic base is added in deionized water, the revolving speed of blender is 10-15 revs/min
Clock;The temperature of the first mixed liquor is 30 DEG C -40 DEG C when chelating agent is added, and the revolving speed of blender is 10-15 revs/min;
The temperature that the second mixed solution is added in solubilizer is 30 DEG C -40 DEG C, and the mixing speed of blender is 30-35 revs/min;
Anionic surfactant and etc. weight third mixed liquor mixing when be stirred;It is carried out with the third mixed liquor of surplus
The mixing speed of blender is 25-32 revs/min when mixing;
The temperature of the 4th mixed liquor is 35 DEG C -45 DEG C when nonionic surfactant is added, and the mixing speed of blender is 28-32
Rev/min.
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CN110791390A (en) * | 2019-11-15 | 2020-02-14 | 南京魄力倍清洁科技有限公司 | Composite alkaline cleaning agent |
CN111575123A (en) * | 2019-07-31 | 2020-08-25 | 河北金力新能源科技股份有限公司 | Special cleaning agent for ceramic anilox roller and preparation method and application thereof |
CN112961738A (en) * | 2021-02-05 | 2021-06-15 | 上海佐航新材料科技有限公司 | Novel alkaline hard floor cleaning agent and preparation method thereof |
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