CN109681175B - Method for draining liquid and producing gas by using solid foam drainage agent with pH value response - Google Patents
Method for draining liquid and producing gas by using solid foam drainage agent with pH value response Download PDFInfo
- Publication number
- CN109681175B CN109681175B CN201710969729.3A CN201710969729A CN109681175B CN 109681175 B CN109681175 B CN 109681175B CN 201710969729 A CN201710969729 A CN 201710969729A CN 109681175 B CN109681175 B CN 109681175B
- Authority
- CN
- China
- Prior art keywords
- gas
- foam drainage
- drainage agent
- foam
- agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000013051 drainage agent Substances 0.000 title claims abstract description 57
- 239000007788 liquid Substances 0.000 title claims abstract description 37
- 239000008259 solid foam Substances 0.000 title claims abstract description 35
- 238000000034 method Methods 0.000 title claims abstract description 34
- 230000004044 response Effects 0.000 title abstract description 8
- 239000006260 foam Substances 0.000 claims abstract description 84
- 229920000768 polyamine Polymers 0.000 claims abstract description 57
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 37
- 239000000243 solution Substances 0.000 claims abstract description 33
- 150000001875 compounds Chemical class 0.000 claims abstract description 26
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 25
- 235000019198 oils Nutrition 0.000 claims abstract description 19
- 238000004519 manufacturing process Methods 0.000 claims abstract description 18
- 239000007787 solid Substances 0.000 claims abstract description 17
- 238000002156 mixing Methods 0.000 claims abstract description 15
- 239000000945 filler Substances 0.000 claims abstract description 13
- 239000000853 adhesive Substances 0.000 claims abstract description 10
- 230000001070 adhesive effect Effects 0.000 claims abstract description 10
- 239000012530 fluid Substances 0.000 claims abstract description 6
- 239000011259 mixed solution Substances 0.000 claims abstract description 4
- 230000009467 reduction Effects 0.000 claims abstract description 4
- 235000019476 oil-water mixture Nutrition 0.000 claims abstract description 3
- 239000007789 gas Substances 0.000 claims description 64
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 40
- 229920000570 polyether Polymers 0.000 claims description 40
- 238000006243 chemical reaction Methods 0.000 claims description 29
- -1 hydrocarbyl carboxylates Chemical class 0.000 claims description 26
- 235000002639 sodium chloride Nutrition 0.000 claims description 20
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims description 18
- 239000003921 oil Substances 0.000 claims description 18
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 claims description 18
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 16
- 239000002253 acid Substances 0.000 claims description 15
- 238000003756 stirring Methods 0.000 claims description 14
- 229910052783 alkali metal Inorganic materials 0.000 claims description 13
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 12
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 12
- 150000003839 salts Chemical class 0.000 claims description 11
- 125000001183 hydrocarbyl group Chemical group 0.000 claims description 10
- 239000003054 catalyst Substances 0.000 claims description 9
- 229910000027 potassium carbonate Inorganic materials 0.000 claims description 9
- 238000002360 preparation method Methods 0.000 claims description 9
- RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 claims description 8
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 8
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 8
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 8
- 239000004202 carbamide Substances 0.000 claims description 8
- IJGRMHOSHXDMSA-UHFFFAOYSA-N nitrogen Substances N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 8
- 239000002904 solvent Substances 0.000 claims description 8
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 claims description 7
- 239000002202 Polyethylene glycol Substances 0.000 claims description 7
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims description 7
- OHJMTUPIZMNBFR-UHFFFAOYSA-N biuret Chemical compound NC(=O)NC(N)=O OHJMTUPIZMNBFR-UHFFFAOYSA-N 0.000 claims description 7
- 229920001223 polyethylene glycol Polymers 0.000 claims description 7
- 238000001704 evaporation Methods 0.000 claims description 6
- 229920002401 polyacrylamide Polymers 0.000 claims description 6
- HELHAJAZNSDZJO-OLXYHTOASA-L sodium L-tartrate Chemical compound [Na+].[Na+].[O-]C(=O)[C@H](O)[C@@H](O)C([O-])=O HELHAJAZNSDZJO-OLXYHTOASA-L 0.000 claims description 6
- 239000001433 sodium tartrate Substances 0.000 claims description 6
- 229960002167 sodium tartrate Drugs 0.000 claims description 6
- 235000011004 sodium tartrates Nutrition 0.000 claims description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 5
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims description 5
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 claims description 5
- 229920002472 Starch Polymers 0.000 claims description 5
- 239000013067 intermediate product Substances 0.000 claims description 5
- 239000003350 kerosene Substances 0.000 claims description 5
- 239000012280 lithium aluminium hydride Substances 0.000 claims description 5
- 229910052757 nitrogen Inorganic materials 0.000 claims description 5
- 238000003825 pressing Methods 0.000 claims description 5
- 238000006722 reduction reaction Methods 0.000 claims description 5
- HPALAKNZSZLMCH-UHFFFAOYSA-M sodium;chloride;hydrate Chemical compound O.[Na+].[Cl-] HPALAKNZSZLMCH-UHFFFAOYSA-M 0.000 claims description 5
- 239000008107 starch Substances 0.000 claims description 5
- 235000019698 starch Nutrition 0.000 claims description 5
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 claims description 4
- 229910019142 PO4 Inorganic materials 0.000 claims description 4
- VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 claims description 4
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 claims description 4
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 claims description 4
- 150000008044 alkali metal hydroxides Chemical class 0.000 claims description 4
- 150000001340 alkali metals Chemical class 0.000 claims description 4
- 239000000010 aprotic solvent Substances 0.000 claims description 4
- 239000002585 base Substances 0.000 claims description 4
- 230000015572 biosynthetic process Effects 0.000 claims description 4
- 229910021538 borax Inorganic materials 0.000 claims description 4
- 239000012267 brine Substances 0.000 claims description 4
- LNTHITQWFMADLM-UHFFFAOYSA-N gallic acid Chemical compound OC(=O)C1=CC(O)=C(O)C(O)=C1 LNTHITQWFMADLM-UHFFFAOYSA-N 0.000 claims description 4
- 229910052751 metal Inorganic materials 0.000 claims description 4
- 239000002184 metal Substances 0.000 claims description 4
- 239000003345 natural gas Substances 0.000 claims description 4
- 235000021317 phosphate Nutrition 0.000 claims description 4
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 claims description 4
- 239000001632 sodium acetate Substances 0.000 claims description 4
- 229910000029 sodium carbonate Inorganic materials 0.000 claims description 4
- 239000011780 sodium chloride Substances 0.000 claims description 4
- 235000010339 sodium tetraborate Nutrition 0.000 claims description 4
- 125000000547 substituted alkyl group Chemical group 0.000 claims description 4
- 239000011975 tartaric acid Substances 0.000 claims description 4
- 235000002906 tartaric acid Nutrition 0.000 claims description 4
- BSVBQGMMJUBVOD-UHFFFAOYSA-N trisodium borate Chemical compound [Na+].[Na+].[Na+].[O-]B([O-])[O-] BSVBQGMMJUBVOD-UHFFFAOYSA-N 0.000 claims description 4
- 229920001353 Dextrin Polymers 0.000 claims description 3
- 239000004375 Dextrin Substances 0.000 claims description 3
- 229910010082 LiAlH Inorganic materials 0.000 claims description 3
- 239000003513 alkali Substances 0.000 claims description 3
- 239000011230 binding agent Substances 0.000 claims description 3
- 239000001913 cellulose Substances 0.000 claims description 3
- 229920002678 cellulose Polymers 0.000 claims description 3
- 239000000460 chlorine Substances 0.000 claims description 3
- 229910052801 chlorine Inorganic materials 0.000 claims description 3
- FOCAUTSVDIKZOP-UHFFFAOYSA-N chloroacetic acid Chemical compound OC(=O)CCl FOCAUTSVDIKZOP-UHFFFAOYSA-N 0.000 claims description 3
- 235000015165 citric acid Nutrition 0.000 claims description 3
- 235000019425 dextrin Nutrition 0.000 claims description 3
- GOMCKELMLXHYHH-UHFFFAOYSA-L dipotassium;phthalate Chemical compound [K+].[K+].[O-]C(=O)C1=CC=CC=C1C([O-])=O GOMCKELMLXHYHH-UHFFFAOYSA-L 0.000 claims description 3
- 239000012634 fragment Substances 0.000 claims description 3
- 238000011084 recovery Methods 0.000 claims description 3
- 235000017281 sodium acetate Nutrition 0.000 claims description 3
- 235000017550 sodium carbonate Nutrition 0.000 claims description 3
- FSSPGSAQUIYDCN-UHFFFAOYSA-N 1,3-Propane sultone Chemical compound O=S1(=O)CCCO1 FSSPGSAQUIYDCN-UHFFFAOYSA-N 0.000 claims description 2
- FXKMTSIKHBYZSZ-UHFFFAOYSA-N 2-chloroethanesulfonic acid Chemical compound OS(=O)(=O)CCCl FXKMTSIKHBYZSZ-UHFFFAOYSA-N 0.000 claims description 2
- DDLBHIIDBLGOTE-UHFFFAOYSA-N 3-chloro-2-hydroxypropane-1-sulfonic acid Chemical compound ClCC(O)CS(O)(=O)=O DDLBHIIDBLGOTE-UHFFFAOYSA-N 0.000 claims description 2
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical group [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 claims description 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 claims description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical compound OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 claims description 2
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 claims description 2
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical group [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 claims description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims description 2
- BDAGIHXWWSANSR-UHFFFAOYSA-M Formate Chemical compound [O-]C=O BDAGIHXWWSANSR-UHFFFAOYSA-M 0.000 claims description 2
- 229910010084 LiAlH4 Inorganic materials 0.000 claims description 2
- 229910006146 SO3M1 Inorganic materials 0.000 claims description 2
- UIIMBOGNXHQVGW-DEQYMQKBSA-M Sodium bicarbonate-14C Chemical compound [Na+].O[14C]([O-])=O UIIMBOGNXHQVGW-DEQYMQKBSA-M 0.000 claims description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 2
- 229910000288 alkali metal carbonate Inorganic materials 0.000 claims description 2
- 150000008041 alkali metal carbonates Chemical class 0.000 claims description 2
- 150000008051 alkyl sulfates Chemical class 0.000 claims description 2
- 229940045714 alkyl sulfonate alkylating agent Drugs 0.000 claims description 2
- 238000007112 amidation reaction Methods 0.000 claims description 2
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Chemical group BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 claims description 2
- 229910052794 bromium Inorganic materials 0.000 claims description 2
- 230000021523 carboxylation Effects 0.000 claims description 2
- 238000006473 carboxylation reaction Methods 0.000 claims description 2
- 125000001309 chloro group Chemical group Cl* 0.000 claims description 2
- 229940106681 chloroacetic acid Drugs 0.000 claims description 2
- 239000010779 crude oil Substances 0.000 claims description 2
- 239000003822 epoxy resin Substances 0.000 claims description 2
- 230000032050 esterification Effects 0.000 claims description 2
- 238000005886 esterification reaction Methods 0.000 claims description 2
- 125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 claims description 2
- WBJINCZRORDGAQ-UHFFFAOYSA-N ethyl formate Chemical compound CCOC=O WBJINCZRORDGAQ-UHFFFAOYSA-N 0.000 claims description 2
- 125000000816 ethylene group Chemical group [H]C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 2
- 229940074391 gallic acid Drugs 0.000 claims description 2
- 235000004515 gallic acid Nutrition 0.000 claims description 2
- 239000011630 iodine Chemical group 0.000 claims description 2
- 229910052740 iodine Chemical group 0.000 claims description 2
- 229910001507 metal halide Inorganic materials 0.000 claims description 2
- 150000005309 metal halides Chemical class 0.000 claims description 2
- 229910052987 metal hydride Inorganic materials 0.000 claims description 2
- 150000004681 metal hydrides Chemical class 0.000 claims description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 2
- 239000010452 phosphate Substances 0.000 claims description 2
- 229920000647 polyepoxide Polymers 0.000 claims description 2
- 125000002572 propoxy group Chemical group [*]OC([H])([H])C(C([H])([H])[H])([H])[H] 0.000 claims description 2
- 239000012279 sodium borohydride Substances 0.000 claims description 2
- 229910000033 sodium borohydride Inorganic materials 0.000 claims description 2
- 239000001509 sodium citrate Substances 0.000 claims description 2
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 claims description 2
- 235000011083 sodium citrates Nutrition 0.000 claims description 2
- 125000001424 substituent group Chemical group 0.000 claims description 2
- 238000006277 sulfonation reaction Methods 0.000 claims description 2
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 claims description 2
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen(.) Chemical compound [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 claims 2
- 239000003570 air Substances 0.000 claims 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 claims 1
- 238000000748 compression moulding Methods 0.000 claims 1
- 229910021645 metal ion Inorganic materials 0.000 claims 1
- 238000007599 discharging Methods 0.000 abstract description 10
- 230000002378 acidificating effect Effects 0.000 abstract description 7
- 238000009825 accumulation Methods 0.000 abstract description 2
- 238000011049 filling Methods 0.000 abstract description 2
- 239000008258 liquid foam Substances 0.000 abstract description 2
- 239000007921 spray Substances 0.000 abstract description 2
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 15
- 238000005187 foaming Methods 0.000 description 13
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 12
- 230000000052 comparative effect Effects 0.000 description 11
- 238000010992 reflux Methods 0.000 description 11
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 9
- 230000032683 aging Effects 0.000 description 9
- 239000011734 sodium Substances 0.000 description 9
- 239000000203 mixture Substances 0.000 description 7
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 7
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 6
- 239000007864 aqueous solution Substances 0.000 description 6
- SCVFZCLFOSHCOH-UHFFFAOYSA-M potassium acetate Substances [K+].CC([O-])=O SCVFZCLFOSHCOH-UHFFFAOYSA-M 0.000 description 6
- ZSZFXZHKVNYPLL-UHFFFAOYSA-M sodium;1-hydroxypropane-1-sulfonate Chemical compound [Na+].CCC(O)S([O-])(=O)=O ZSZFXZHKVNYPLL-UHFFFAOYSA-M 0.000 description 6
- 229910002092 carbon dioxide Inorganic materials 0.000 description 5
- 229940125904 compound 1 Drugs 0.000 description 5
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 4
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 4
- UBMXFGVZFUYLSN-UHFFFAOYSA-N azanium;propane-1-sulfonate Chemical compound [NH4+].CCCS([O-])(=O)=O UBMXFGVZFUYLSN-UHFFFAOYSA-N 0.000 description 4
- 238000004821 distillation Methods 0.000 description 4
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 4
- 239000005457 ice water Substances 0.000 description 4
- 238000010907 mechanical stirring Methods 0.000 description 4
- 230000007935 neutral effect Effects 0.000 description 4
- 229910052938 sodium sulfate Inorganic materials 0.000 description 4
- 235000011152 sodium sulphate Nutrition 0.000 description 4
- 230000000087 stabilizing effect Effects 0.000 description 4
- 239000004094 surface-active agent Substances 0.000 description 4
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 3
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 description 3
- 150000001412 amines Chemical class 0.000 description 3
- 150000007942 carboxylates Chemical class 0.000 description 3
- 229940125782 compound 2 Drugs 0.000 description 3
- 229940126214 compound 3 Drugs 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 238000005259 measurement Methods 0.000 description 3
- 238000005201 scrubbing Methods 0.000 description 3
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 3
- ALSTYHKOOCGGFT-KTKRTIGZSA-N (9Z)-octadecen-1-ol Chemical compound CCCCCCCC\C=C/CCCCCCCCO ALSTYHKOOCGGFT-KTKRTIGZSA-N 0.000 description 2
- FYGHSUNMUKGBRK-UHFFFAOYSA-N 1,2,3-trimethylbenzene Chemical compound CC1=CC=CC(C)=C1C FYGHSUNMUKGBRK-UHFFFAOYSA-N 0.000 description 2
- KVNYFPKFSJIPBJ-UHFFFAOYSA-N 1,2-diethylbenzene Chemical compound CCC1=CC=CC=C1CC KVNYFPKFSJIPBJ-UHFFFAOYSA-N 0.000 description 2
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- YNQLUTRBYVCPMQ-UHFFFAOYSA-N Ethylbenzene Chemical compound CCC1=CC=CC=C1 YNQLUTRBYVCPMQ-UHFFFAOYSA-N 0.000 description 2
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 2
- VFTKIWJJPDJBKD-UHFFFAOYSA-N OCCC[Na] Chemical compound OCCC[Na] VFTKIWJJPDJBKD-UHFFFAOYSA-N 0.000 description 2
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 2
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 2
- WQDUMFSSJAZKTM-UHFFFAOYSA-N Sodium methoxide Chemical compound [Na+].[O-]C WQDUMFSSJAZKTM-UHFFFAOYSA-N 0.000 description 2
- 125000003368 amide group Chemical group 0.000 description 2
- 239000012298 atmosphere Substances 0.000 description 2
- 125000002511 behenyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 230000033558 biomineral tissue development Effects 0.000 description 2
- BGTOWKSIORTVQH-UHFFFAOYSA-N cyclopentanone Chemical compound O=C1CCCC1 BGTOWKSIORTVQH-UHFFFAOYSA-N 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 230000018109 developmental process Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- XIRNKXNNONJFQO-UHFFFAOYSA-N ethyl hexadecanoate Chemical compound CCCCCCCCCCCCCCCC(=O)OCC XIRNKXNNONJFQO-UHFFFAOYSA-N 0.000 description 2
- NBVXSUQYWXRMNV-UHFFFAOYSA-N fluoromethane Chemical compound FC NBVXSUQYWXRMNV-UHFFFAOYSA-N 0.000 description 2
- 239000004088 foaming agent Substances 0.000 description 2
- 230000002209 hydrophobic effect Effects 0.000 description 2
- QSQLTHHMFHEFIY-UHFFFAOYSA-N methyl behenate Chemical compound CCCCCCCCCCCCCCCCCCCCCC(=O)OC QSQLTHHMFHEFIY-UHFFFAOYSA-N 0.000 description 2
- 239000012452 mother liquor Substances 0.000 description 2
- 229940055577 oleyl alcohol Drugs 0.000 description 2
- XMLQWXUVTXCDDL-UHFFFAOYSA-N oleyl alcohol Natural products CCCCCCC=CCCCCCCCCCCO XMLQWXUVTXCDDL-UHFFFAOYSA-N 0.000 description 2
- 125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 229920000056 polyoxyethylene ether Polymers 0.000 description 2
- 229940051841 polyoxyethylene ether Drugs 0.000 description 2
- 239000001508 potassium citrate Substances 0.000 description 2
- 229960002635 potassium citrate Drugs 0.000 description 2
- QEEAPRPFLLJWCF-UHFFFAOYSA-K potassium citrate (anhydrous) Chemical compound [K+].[K+].[K+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O QEEAPRPFLLJWCF-UHFFFAOYSA-K 0.000 description 2
- 235000011082 potassium citrates Nutrition 0.000 description 2
- KQFAFFYKLIBKDE-UHFFFAOYSA-M sodium;ethanesulfonate Chemical compound [Na+].CCS([O-])(=O)=O KQFAFFYKLIBKDE-UHFFFAOYSA-M 0.000 description 2
- 239000008247 solid mixture Substances 0.000 description 2
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- RPNUMPOLZDHAAY-UHFFFAOYSA-N Diethylenetriamine Chemical compound NCCNCCN RPNUMPOLZDHAAY-UHFFFAOYSA-N 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- OVXRPXGVKBHGQO-UHFFFAOYSA-N abietic acid methyl ester Natural products C1CC(C(C)C)=CC2=CCC3C(C(=O)OC)(C)CCCC3(C)C21 OVXRPXGVKBHGQO-UHFFFAOYSA-N 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 235000011114 ammonium hydroxide Nutrition 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 229940077388 benzenesulfonate Drugs 0.000 description 1
- SRSXLGNVWSONIS-UHFFFAOYSA-M benzenesulfonate Chemical compound [O-]S(=O)(=O)C1=CC=CC=C1 SRSXLGNVWSONIS-UHFFFAOYSA-M 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 238000009903 catalytic hydrogenation reaction Methods 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 239000012295 chemical reaction liquid Substances 0.000 description 1
- MRUAUOIMASANKQ-UHFFFAOYSA-N cocamidopropyl betaine Chemical compound CCCCCCCCCCCC(=O)NCCC[N+](C)(C)CC([O-])=O MRUAUOIMASANKQ-UHFFFAOYSA-N 0.000 description 1
- 229940073507 cocamidopropyl betaine Drugs 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- 238000006073 displacement reaction Methods 0.000 description 1
- QYDYPVFESGNLHU-UHFFFAOYSA-N elaidic acid methyl ester Natural products CCCCCCCCC=CCCCCCCCC(=O)OC QYDYPVFESGNLHU-UHFFFAOYSA-N 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 229940067592 ethyl palmitate Drugs 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 125000005842 heteroatom Chemical group 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- 150000003951 lactams Chemical class 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 150000002736 metal compounds Chemical class 0.000 description 1
- OVXRPXGVKBHGQO-UYWIDEMCSA-N methyl (1r,4ar,4br,10ar)-1,4a-dimethyl-7-propan-2-yl-2,3,4,4b,5,6,10,10a-octahydrophenanthrene-1-carboxylate Chemical compound C1CC(C(C)C)=CC2=CC[C@H]3[C@@](C(=O)OC)(C)CCC[C@]3(C)[C@H]21 OVXRPXGVKBHGQO-UYWIDEMCSA-N 0.000 description 1
- QYDYPVFESGNLHU-KHPPLWFESA-N methyl oleate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OC QYDYPVFESGNLHU-KHPPLWFESA-N 0.000 description 1
- 229940073769 methyl oleate Drugs 0.000 description 1
- LSHROXHEILXKHM-UHFFFAOYSA-N n'-[2-[2-[2-(2-aminoethylamino)ethylamino]ethylamino]ethyl]ethane-1,2-diamine Chemical compound NCCNCCNCCNCCNCCN LSHROXHEILXKHM-UHFFFAOYSA-N 0.000 description 1
- 125000001624 naphthyl group Chemical group 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 238000005457 optimization Methods 0.000 description 1
- XNLICIUVMPYHGG-UHFFFAOYSA-N pentan-2-one Chemical compound CCCC(C)=O XNLICIUVMPYHGG-UHFFFAOYSA-N 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 229960003975 potassium Drugs 0.000 description 1
- 239000001103 potassium chloride Substances 0.000 description 1
- 235000011164 potassium chloride Nutrition 0.000 description 1
- LVTJOONKWUXEFR-FZRMHRINSA-N protoneodioscin Natural products O(C[C@@H](CC[C@]1(O)[C@H](C)[C@@H]2[C@]3(C)[C@H]([C@H]4[C@@H]([C@]5(C)C(=CC4)C[C@@H](O[C@@H]4[C@H](O[C@H]6[C@@H](O)[C@@H](O)[C@@H](O)[C@H](C)O6)[C@@H](O)[C@H](O[C@H]6[C@@H](O)[C@@H](O)[C@@H](O)[C@H](C)O6)[C@H](CO)O4)CC5)CC3)C[C@@H]2O1)C)[C@H]1[C@H](O)[C@H](O)[C@H](O)[C@@H](CO)O1 LVTJOONKWUXEFR-FZRMHRINSA-N 0.000 description 1
- 238000005086 pumping Methods 0.000 description 1
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 1
- 235000017557 sodium bicarbonate Nutrition 0.000 description 1
- BVIXLMYIFZGRBH-UHFFFAOYSA-M sodium;2-chloroethanesulfonate Chemical compound [Na+].[O-]S(=O)(=O)CCCl BVIXLMYIFZGRBH-UHFFFAOYSA-M 0.000 description 1
- TZLNJNUWVOGZJU-UHFFFAOYSA-M sodium;3-chloro-2-hydroxypropane-1-sulfonate Chemical compound [Na+].ClCC(O)CS([O-])(=O)=O TZLNJNUWVOGZJU-UHFFFAOYSA-M 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 238000004659 sterilization and disinfection Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000008399 tap water Substances 0.000 description 1
- 235000020679 tap water Nutrition 0.000 description 1
- 239000012085 test solution Substances 0.000 description 1
- 238000005979 thermal decomposition reaction Methods 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
Images
Classifications
-
- E—FIXED CONSTRUCTIONS
- E21—EARTH OR ROCK DRILLING; MINING
- E21B—EARTH OR ROCK DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
- E21B43/00—Methods or apparatus for obtaining oil, gas, water, soluble or meltable materials or a slurry of minerals from wells
- E21B43/16—Enhanced recovery methods for obtaining hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
- C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
- C08G65/2618—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds the other compounds containing nitrogen
- C08G65/2621—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds the other compounds containing nitrogen containing amine groups
- C08G65/2624—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds the other compounds containing nitrogen containing amine groups containing aliphatic amine groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
- C08G65/32—Polymers modified by chemical after-treatment
- C08G65/329—Polymers modified by chemical after-treatment with organic compounds
- C08G65/337—Polymers modified by chemical after-treatment with organic compounds containing other elements
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K8/00—Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
- C09K8/58—Compositions for enhanced recovery methods for obtaining hydrocarbons, i.e. for improving the mobility of the oil, e.g. displacing fluids
- C09K8/584—Compositions for enhanced recovery methods for obtaining hydrocarbons, i.e. for improving the mobility of the oil, e.g. displacing fluids characterised by the use of specific surfactants
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K8/00—Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
- C09K8/58—Compositions for enhanced recovery methods for obtaining hydrocarbons, i.e. for improving the mobility of the oil, e.g. displacing fluids
- C09K8/594—Compositions used in combination with injected gas, e.g. CO2 orcarbonated gas
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2650/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G2650/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule characterized by the type of post-polymerisation functionalisation
- C08G2650/04—End-capping
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Medicinal Chemistry (AREA)
- Geology (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Mining & Mineral Resources (AREA)
- Polymers & Plastics (AREA)
- Fluid Mechanics (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Environmental & Geological Engineering (AREA)
- Physics & Mathematics (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
The invention relates to a method for draining liquid and producing gas by using a solid foam water draining agent with pH value response, which mainly solves the problem that the existing foam water draining agent contains H2S、CO2The high-temperature and high-salt resistance performance in an acidic environment is poor, and the problems of production reduction and even spray stopping of a high-temperature and high-salt ultra-deep gas well caused by liquid accumulation and difficulty in filling of a liquid foam discharging agent cannot be solved. The invention adopts a liquid drainage gas production method, which comprises the following steps: (1) mixing the solid foam drainage agent with water to obtain a foam drainage agent solution; (2) fully contacting a foam drainage agent solution or a mixed solution of the foam drainage agent solution and oil with gas to form a foam fluid, and displacing water or an oil-water mixture in the foam drainage agent solution; the solid foam drainage agent includes: 1 part of a long-chain polyamine compound; 0.05-1000 parts of solid filler; the technical scheme of 0-0.5 part of the adhesive well solves the problem and can be used for drainage and gas production of acidic high-temperature high-salinity ultra-deep gas wells.
Description
Technical Field
The invention relates to a method for draining liquid and producing gas by adopting a solid foam water draining agent, in particular to a method for draining liquid and producing gas by adopting a solid foam water draining agent with pH value response.
Background
With the enhancement of the exploitation strength of the gas field, the water output of the gas field becomes a key problem restricting the normal production of the gas well. Foam drainage gas production is a drainage gas production technology which is rapidly developed at home and abroad in recent years, and has the advantages of simple equipment, convenience in construction, low cost, wide applicable well depth range, no influence on normal production of gas wells and the like. Foam drainage is to inject foam drainage agent into a well through an oil pipe or an oil casing ring, and foam with certain stability is generated under the stirring of airflow. The liquid phase slipped and deposited in the pipe is changed into foam, the relative density of fluid at the lower part in the pipe is changed, and the continuously produced gas phase displacement foam flows out of the shaft, so that the accumulated liquid in the shaft is discharged, and the purposes of water drainage and gas production are achieved.
The development of foam drainage agent since the sixties of the last century is carried out abroad, and surfactants such as sulfonate, benzene sulfonate, alkylphenol polyoxyethylene and the like are mostly selected. At present, a multi-component compound system is mostly adopted in the foam drainage agent for drainage and gas production, and in order to enhance the stability of single foam, auxiliaries such as alkali, alcohol, polymer, alkanolamide and the like are usually added into a formula to form reinforced foam. US7122509 reports a high temperature foam drainage agent formulation, which adopts a research idea of neutralization of anionic surfactant and amine to improve the temperature resistance of the system, and the drainage effect and use concentration are not referred to in the patent. US20120279715 reports a foam fluid for increasing oil yield by recovering gas in a gas well, which is an amido group-containing quaternary ammonium salt surfactant having both foam drainage and sterilization functions, a hydrophobic chain is a hydrophobic segment in substituted naphthalene ring, benzene ring or natural oil ester, and has strong chlorine resistance and condensate oil resistance, and also has good corrosion inhibition performance, the foam agent with an active matter concentration of 400ppm has a foam drainage rate of 86.8% in tap water and a foam drainage rate of 79.1% in simulated brine with a mineralization degree of 130000mg/L, however, because an amide group sensitive to high temperature is contained in a molecular structure, the foam fluid has poor adaptability to gas wells with a temperature of more than 100 ℃. China is a technology for researching foam drainage and gas production processes from the last 80 years, and a patent CN102212348A discloses a salt-resistant and methanol-resistant foam drainage agent, which comprises the following components in percentage by weight: 20-40% of cocamidopropyl betaine, 45-65% of amine oxide, 5-20% of alpha-olefin sulfonate, 5-15% of triethanolamine, 0.2-2% of fluorocarbon surfactant and 0-5% of methanol, wherein the mineralization resistance can reach 18 ten thousand, and the amount of the foaming agent is 5000ppm, but the agent contains the fluorocarbon surfactant, so that not only the cost is greatly improved, but also the environmental impact is large.
The results show that the poor high temperature resistance is a main factor for restricting the development of the foam drainage technology of the high-temperature ultra-deep gas well.
Disclosure of Invention
The invention aims to solve the technical problems that the existing foam drainage agent has poor high-temperature resistance in an acid environment, cannot solve the problems of yield reduction and even spray stopping caused by liquid accumulation of a high-temperature ultra-deep gas well and difficulty in filling a liquid foam drainage agent, provides a method for draining liquid and collecting gas by adopting a solid foam drainage agent, particularly a method for draining liquid and collecting gas by adopting a solid foam drainage agent with pH value response, is applied to a high-temperature deep well, has very excellent temperature resistance under an acid condition, and has strong liquid carrying, foaming and foam stabilizing properties.
In order to solve the technical problems, the technical scheme adopted by the invention is as follows: a method for draining liquid and producing gas by adopting a solid foam drainage agent comprises the following steps:
(1) mixing the solid foam drainage agent with water to obtain a foam drainage agent solution;
(2) fully contacting a foam drainage agent solution or a mixed solution of the foam drainage agent solution and oil with gas to form a foam fluid, and displacing water or an oil-water mixture in the foam drainage agent solution;
the solid foam drainage agent comprises the following components in parts by weight:
1)1 part of a long-chain polyamine compound;
2) 0.05-1000 parts of solid filler;
3) 0-0.5 parts of adhesive;
wherein the long-chain polyamine compound has a general molecular formula shown in formula (1):
in the formula (1), R1Is selected from C4～C32One of hydrocarbyl or substituted hydrocarbyl, R2、R3、R4Independently selected from H, C1～C5Hydrocarbyl or substituted hydrocarbyl carboxylates, C1～C5Alkyl or substituted alkyl sulfonates, C1～C5Hydrocarbyl or substituted hydrocarbyl phosphates or C1～C5At least one of alkyl sulfate or substituted alkyl sulfate, which is not H at the same time; m is-N (A) CH2CH2-the number of fragments, m ═ 1 to 10; a is a substituent represented by the formula (2); s1, s2 and s3 are the addition number of propoxy groups PO, s1 is 0-30, s2 is 0-30, and s3 is 0-30; r1, r2 and r3 are addition numbers of ethoxy groups EO, r1 is 0-30, r2 is 0-30, r3 is 0-30, and s1+ s2+ m × s3 and r1+ r2+ m × r3 are not zero at the same time;
the gas is at least one of air, nitrogen, methane or natural gas, and may or may not contain H2S or CO2An acid gas; the oil is at least one of kerosene, crude oil or condensate oil.
In the above technical scheme, R1Preferably C8～C24Hydrocarbyl or substituted hydrocarbyl.
In the above technical scheme, R2、R3、R4Preferably H, CH2COOM、(CH2)3SO3M or CH2(CHOH)CH2SO3One of M is not H at the same time.
In the above-mentioned embodiments, M is preferably hydrogen, an alkali metal or a compound represented by the formula NR5(R6(R7)(R8) One of the groups shown.
In the above technical scheme, R5、R6、R7、R8Preferably H, (CH)2)aOH or (CH)2)bCH3One kind of (1).
In the above technical means, a is preferably 2 to 4, and b is preferably 0 to 5.
In the above-mentioned technical means, m is preferably 1 to 5.
In the above technical solution, s1+ s2+ mxs 3 is preferably 0 to 5, and r1+ r2+ mxr 3 is preferably 0 to 10, and is not zero at the same time; more preferably, s1+ s2+ m × s3 is 1 to 5, and r1+ r2+ m × r3 is 1 to 10.
In the above technical solution, the solid filler is preferably at least one of carbonate, bicarbonate, sulfate, phosphate, borate, metal halide, formate, acetate, tartaric acid and salts, citric acid and salts, phthalic acid and salts, gallic acid and salts, urea, biuret, and the like; more preferably at least one of sodium carbonate, sodium bicarbonate, sodium borate, sodium chloride, sodium acetate, tartaric acid, sodium tartrate, citric acid, sodium citrate, potassium phthalate, urea and biuret.
In the above technical solution, the binder is preferably at least one of dextrin, epoxy resin, polyacrylamide, starch, cellulose, polyethylene glycol, and the like; further preferably at least one of polyacrylamide, starch and polyethylene glycol.
In the technical scheme, the mass ratio of the long-chain polyamine compound, the solid filler and the adhesive in the solid foam drainage agent is 1: (0.1-200): (0.01-0.1).
In the above technical solution, the gas is preferably at least one of nitrogen, methane or natural gas.
In the above technical scheme, H in the gas2S and CO2The content of (b) is preferably 15 to 35%.
In the above technical solution, the oil is preferably at least one of kerosene and condensate.
The key active ingredient of the solid foam-remover composition of the present invention is (1), and the long-chain polyamine compound, the solid filler and the binder may be mixed in a desired ratio, and preferably obtained by the following technical scheme for solving the second technical problem.
In the above technical scheme, the preparation method of the solid foam drainage agent with pH value response comprises the following steps:
(1) preparation of long-chain polyamine compounds
a. Amidation reaction:
r is to be0COOR' and H (NHCH)2CH2)mNH2The catalysts are mixed according to the molar ratio of 1 (1-2) to 0-0.5,reacting for 3-15 hours at the reaction temperature of 50-200 ℃ under stirring, and evaporating alcohol or water generated in the reaction under the normal pressure or reduced pressure condition to obtain an amide compound R0CO(NHCH2CH2)mNH2(ii) a Wherein R is0Is selected from C3～C31One of hydrocarbyl or substituted hydrocarbyl, R' is selected from H and C1～C8C is 1-10, and the catalyst is at least one selected from alkali metal hydroxide, alkali metal alkoxide and alkali metal carbonate;
b. reduction reaction:
R0CO(NHCH2CH2)mNH2reducing the lactam by adopting a catalytic hydrogenation method, and carrying out heterogeneous catalytic reaction at high temperature and high pressure to generate corresponding amine; or the following steps are adopted: the R synthesized in the step a0CO(NHCH2CH2)mNH2With metal hydrides H-Y+Reduction in an aprotic solvent to give R0CH2(NHCH2CH2)mNH2(ii) a Wherein, Y+Is a metal compound, a metal alkyl compound, a metal amino compound;
c. and (3) polyether esterification:
in the presence of a basic catalyst, the R synthesized in the step b0CH2(NHCH2CH2)mNH2Sequentially reacting with required amount of propylene oxide and ethylene oxide to obtain long-chain polyamine polyether intermediate product R0CH2{N[(CHCH3CH2O)s3(CH2CH2O)r3H][CH2CH2]}mN[(CHCH3CH2O)s1(CH2CH2O)r1H][CHCH3CH2O)s2(CH2CH2O)r2)H]；
d. Carboxylation or sulfonation reaction:
c, mixing the long-chain polyamine polyether intermediate product obtained in the step c with an ionizing agent and a base in a molar ratio of 1: (1-5): (1-10) in a solvent at a reaction temperature of 50-120 deg.CReacting at the temperature of 3-20 hours to generate a long-chain polyamine compound shown as a structural formula (1); the ionizing agent is selected from XR9Y1Or X R'9Y′1At least one of; the base is selected from alkali metal hydroxide or alkali metal alkoxide; y is1And Y'1Is SO3M1Or COON1，M1And N1Is an alkali metal, and X is chlorine, bromine or iodine;
(2) and (2) uniformly mixing the long-chain polyamine compound synthesized in the step (1), the solid filler and the adhesive according to the required mass parts, and then pressing and forming to prepare the solid foam drainage agent.
In the above technical solution, the solid foam drainage agent may be in the shape of a rod or a ball.
In the above technical scheme, R in the step a1COOR’、H(NHCH2CH2)mNH2The molar ratio of the catalyst is preferably 1 (1-1.3) to 0-0.1.
In the above technical scheme, the catalyst in step a is preferably at least one of sodium hydroxide, potassium hydroxide, sodium carbonate and potassium carbonate.
In the above technical scheme, step b is H-Y+Preferably LiAlH4、LiAlH(OEt)3Or NaBH4One kind of (1).
In the above technical solution, the aprotic solvent in step b is preferably at least one of diethyl ether, tetrahydrofuran, and dioxane.
In the above technical scheme, the long-chain polyamine polyether intermediate in step d: ionizing agent: the molar ratio of the alkali is preferably 1: (1-2): (1-4).
In the above technical scheme, the solvent in the step d is preferably selected from C3～C8Ketone and C6～C9For example, at least one of the group consisting of acetone, butanone, pentanone, benzene, toluene or xylene, trimethylbenzene, ethylbenzene and diethylbenzene.
In the above technical solution, the XR9Y1Examples of (1) are but not limited toBut are not limited to alkali metal salts of chloroacetic acid, bromoacetic acid, 3-chloro-2-hydroxypropanesulfonic acid, and 2-chloroethanesulfonic acid.
The pH value response solid foam drainage agent has good compatibility, and can also contain other treating agents commonly used in the field.
In the technical scheme, the drainage gas recovery method is suitable for stratum optimization of high-temperature acid gas-containing gas reservoir, the stratum temperature is 150-200 ℃, the total salinity of stratum brine is 5000-200000 mg/L, and H2S and CO2The content of (A) is 0-35%.
The long-chain polyamine compound containing stable chemical bonds can avoid hydrolysis under acidic high-temperature and high-salt conditions, maintain the stability of a molecular structure and maintain the foam drainage capability of the foam drainage agent to the maximum extent.
The thermal decomposition temperature of the polyamine polyether carboxylate or the polyamine polyether sulfonate prepared by the invention is 200 ℃ or above, and the polyamine polyether carboxylate or the polyamine polyether sulfonate is not hydrolyzed or is hydrolyzed in a trace amount in an acidic aqueous solution, so that the polyamine polyether carboxylate or the polyamine polyether sulfonate has good temperature resistance; secondly, the nonionic fragment and the multi-hydrophilic group in the molecule increase the salt resistance on one hand, and increase the amount of bound water and bound water carried by the foaming agent on the other hand, so that the liquid carrying amount of the foam is increased, and the liquid separation is slowed down; the molecules contain heteroatoms responding to pH, so that the method can be applied to the drainage and gas production process of acidic high-temperature high-salt ultra-deep wells at the temperature of 150-200 ℃.
The key effective component (1) of the foam scrubbing agent, the solid filler and the adhesive have good compatibility, and the formed solid composition does not influence the foam scrubbing performance of the solid composition.
The content or concentration of the foam scrubbing agent in the invention refers to the content or concentration of the molecular general formula (1) in the technical scheme.
The method for liquid drainage and gas production can also comprise methods such as gas lift, mechanical pumping and the like commonly used in the field.
The invention adopts the measurement of foaming, foam stabilizing and liquid carrying performances of the foam drainage agent to evaluate the foam drainage performance, and evaluates the high temperature resistance of the foam drainage agent by comparing the foaming, foam stabilizing and liquid carrying performances before and after high-temperature aging, wherein the specific evaluation method comprises the following steps:
(1) foam row performance
The initial foaming height of the foam drainage agent and the foaming height after a certain period of time were measured by a Roche foam tester (ROSS-Miles method) to evaluate the foaming ability and foam stabilizing ability. Continuously introducing gas with a certain flow rate into the foam water discharging agent solution or the mixed solution of the foam water discharging agent solution and the oil to form foam, measuring the amount of liquid (water, oil and water) carried out by the foam after a certain time, calculating the liquid carrying rate, and evaluating the liquid carrying capacity of the foam water discharging agent solution.
(2) High temperature resistance
And (3) after the foam drainage agent solution is aged at high temperature by adopting a pressure-resistant and acid-resistant aging device, measuring the foam drainage performance and the high-temperature resistance again.
The liquid drainage gas recovery method can be used for, but is not limited to, the formation temperature of 150-200 ℃, the total salinity of formation brine of 5000-200000 mg/L and H2S and CO2The content of the acid gas is 15-35%. According to the mass percentage, the solid foam drainage agent with the pH value response and the dosage of 0.02-0.15 wt% is used in 0-200,000 mg/L salinity saline, the foaming height reaches 171mm before and after high-temperature aging, the liquid carrying rate reaches 93.3%, and the solid foam drainage agent has excellent temperature resistance, salt resistance, foaming and liquid carrying performances in an acid environment, and achieves better technical effects.
Drawings
FIG. 1 is a schematic view showing a flow of measuring the amount of liquid carried by a foam drainage agent. Wherein, 1 is a constant temperature water bath, 2 is a measuring cup, 3 is circulating water, 4 is a foam collector, 5 is a foaming pipe, 6 is a test solution, 7 is a rotameter, and 8 is a gas cylinder.
The invention is further illustrated by the following examples.
Detailed Description
In order to better understand the present invention, the following examples are further provided to illustrate the present invention, but the present invention is not limited to the following examples.
[ example 1 ]
(1) Preparation of foam discharging agent FS01
a. 127.6 g (0.55 mol) of pentaethylenehexamine and 1.4 g (0.025 mol) of potassium hydroxide solid are added into a reaction bottle provided with a mechanical stirring device, a thermometer, a dropping funnel and an atmospheric distillation device, 148 g (0.5 mol) of methyl oleate is slowly dropped into the reaction bottle under stirring, the reaction is carried out for 6 hours at the reaction temperature of 120-160 ℃, and methanol generated by the reaction is collected at the same time, so that the required amide compound C can be obtained17H33CO(NHCH2CH2)5NH2The yield thereof was found to be 93.8%.
b. Removing water from a three-neck flask device provided with a reflux condenser tube, a dropping funnel and a thermometer, adding 11.4 g (0.3 mol) of lithium aluminum hydride and 90 ml of dry dioxane, stirring, dispersing and mixing, and dropping 49.6 g (0.1 mol) of C at-10-5 DEG C17H33CO(NHCH2CH2)5NH2The 40 wt% dioxane solution is added dropwise and slowly heated to about 35 ℃ for reaction for 3 hours. Carefully pouring the reaction solution into ice water, and carrying out post-treatment to obtain a long-chain polyamine compound C17H33CH2(NHCH2CH2)5NH2The yield thereof was found to be 89.0%.
c. A pressure reactor equipped with a stirring device was charged with 192.8 g (0.4 mol) of C17H33CH2(NHCH2CH2)5NH24.0 g of potassium hydroxide, 469.8 g (8.1 mol) of propylene oxide and 52.8 g (1.2 mol) of ethylene oxide react sequentially at 140-160 ℃ to obtain the long-chain polyamine polyether compound1(R1＝C18H35，m＝5，s1+s2+ms3＝20，r1+r2+mr3＝3，R2＝R3＝R4H), yield 96.2%.
d. Long-chain polyamine polyether compounds1(R1＝C18H35，m＝5，s1+s2+m*s3＝20，r1+r2+m*r3＝3，R2＝R3＝R4H)177.4 g (0.1 mol) were mixed with 8.0 g (0.2 mol) of sodium hydroxide, 29.5 g (0.15 mol) of sodium 3-chloro-2-hydroxypropanesulfonate and 300 ml of toluene/benzene (v/v ═ 1) in a four-neck flask equipped with a mechanical stirrer, a thermometer and a reflux condenser, and heated to 90 ℃ for 7 hours.Evaporating the solvent to obtain the long-chain polyamine polyether compound1(R1＝C18H35Sodium hydroxypropanesulfonate (R1 + R2+5R3 ═ 3), m ═ 5, s1+ s2+5s3 ═ 20, and R1+ R2+5R3 ═ 32、R3、R4One of them is CH2CH(OH)CH2SO3Na, remainder H).
e. Long-chain polyamine polyether compound1(R1＝C18H35Sodium hydroxypropanesulfonate (R1 + R2+5R3 ═ 3), m ═ 5, s1+ s2+5s3 ═ 20, and R1+ R2+5R3 ═ 32、R3、R4One of them is CH2CH(OH)CH2SO3Na and the balance of H), 120 g of potassium citrate, 100 g of urea and 30 g of biuret are uniformly mixed, 30 g of 1 percent polyacrylamide aqueous solution is added, and the mixture is pressed into a rod shape to prepare the foam drainage rod FS 01.
(2) FS01 was dissolved in deionized water, 100,000mg/L, 200,000mg/L NaCl water, respectively, to make 0.3 wt% foam-drain mother liquor. The mother liquor was diluted to a predetermined concentration and introduced into a Roche foam meter, and the initial height of foaming and the height of foaming after 5 minutes of the foam discharging agent FS01 were measured by the ROSS-Miles method, and the results are shown in Table 1.
4000mL/min of nitrogen was continuously introduced into the aqueous solution of foam discharging agent FS01, the amount of water carried out by the foam in 15 minutes was measured, and the liquid carrying rate was calculated and the results are shown in Table 1. The liquid carrying amount measuring apparatus used is shown in FIG. 1. The experiment is carried out by adopting a pressure-resistant and acid-resistant aging device, the performances such as initial foaming height, foaming height after 5 minutes, liquid carrying rate after 15 minutes and the like are measured again after aging for 24 hours at 180 ℃, and the results are shown in table 1.
[ example 2 ]
The same as [ example 1 ] except that when the FS01 performance was measured, pH was adjusted to 7 and 4 with hydrochloric acid to simulate neutral and acid gas environments, and the results are shown in table 2.
[ example 3 ]
The same as [ example 1 ] except that a long-chain polyamine polyether compound is used1(R1＝C18H35Sodium hydroxypropanesulfonate (R1 + R2+5R3 ═ 3), m ═ 5, s1+ s2+5s3 ═ 20, and R1+ R2+5R3 ═ 32、R3、R4One of them is CH2CH(OH)CH2SO3Na and the balance H)120 g, sodium sulfate 100 g, potassium carbonate 100 g and urea 70 g are mixed uniformly, 10% polyethylene glycol 60 g is added, the mixture is mixed and pressed into a rod shape, and a foam drainage rod FS02 is prepared, and the result is shown in Table 3.
[ example 4 ]
(1) Preparation of foam discharging agent FS 03:
a. adding 67.0 g (0.65 mol) of diethylenetriamine and 6.9 g (0.05 mol) of potassium carbonate solid into a reaction bottle provided with a mechanical stirring device, a thermometer, a dropping funnel and a normal pressure distillation device, slowly dropping 142.0 g (0.5 mol) of ethyl palmitate while stirring, reacting for 4 hours at the reaction temperature of 120-160 ℃, and collecting ethanol generated by the reaction to obtain the required amide compound C15H31CO(NHCH2CH2)2NH2The yield thereof was found to be 94.5%.
b. After removing water from a three-necked flask equipped with a reflux condenser, a dropping funnel and a thermometer, LiAlH (OEt) was added351 g (0.3 mol) and 120 ml of anhydrous ether are stirred and mixed, and 34.1 g (0.1 mol) of C is dripped into the mixture at the temperature of minus 5 to 5 DEG C15H31CO(NHCH2CH2)2NH2Adding 50 wt% anhydrous ether solution, slowly heating to about 30 deg.C, and reacting for 5 hr. Carefully pouring the reaction solution into ice water, and carrying out post-treatment to obtain a long-chain polyamine compound C15H31CH2(NHCH2CH2)2NH2The yield thereof was found to be 83.4%.
c. A pressure reactor equipped with a stirring device was charged with 130.8 g (0.4 mol) of C15H31CH2(NHCH2CH2)2NH25.2 g of potassium carbonate, 70.8 g (1.22 mol) of propylene oxide and 35.2 g (0.8 mol) of ethylene oxide are sequentially reacted at 140-160 ℃ to obtain the long-chain polyamine polyether compound2(R1＝C16H33，m＝2，s1+s2+2s3＝3，r1+r2+2r3＝2，R2＝R3＝R4H), yield 97.6%.
d. Polyether of long-chain polyamineCompound (I)2(R1＝C16H33，m＝2，s1+s2+ms3＝3，r1+r2+mr3＝2，R2＝R3＝R4H)58.9 g (0.1 mol) were mixed with 5.7 g (0.11 mol) of sodium methoxide, 13.4 g (0.11 mol of 1, 3-propanesultone and 100 ml of cyclopentanone in a four-neck flask equipped with a mechanical stirrer, a thermometer and a reflux condenser, and after the addition, the temperature was raised to reflux for 5 hours. Evaporating to remove solvent, adding ammonia water to obtain long-chain polyamine polyether compound2(R1＝C16H33Ammonium propanesulfonate (R1 + R2+2R3 ═ 2, s1+ s2+2s3 ═ 3, R1+ R2+2R3 ═ 2)2、R3、R4One of them is CH2CH2CH2SO3NH4And the balance is H).
e. Long-chain polyamine polyether compound2(R1＝C16H33Ammonium propanesulfonate (R1 + R2+2R3 ═ 2, s1+ s2+2s3 ═ 3, R1+ R2+2R3 ═ 2)2、R3、R4One of them is CH2CH2CH2SO3NH4And the balance of H)120 g, sodium tartrate 100 g, sodium chloride 70 g and urea 30 g, and adding 10% cellulose aqueous solution 30 g, mixing and pressing into a rod shape to obtain the foam drainage rod FS 03.
(2) The same as [ example 1 ] except that the aging was carried out at 150 ℃ for 72 hours, the results are shown in Table 4.
[ example 5 ]
The same as [ example 4 ] except that in the measurement of FS03 performance, pH was adjusted to 7 and 4 with hydrochloric acid to simulate neutral and acidic gas environments, and aged at 150 ℃ for 72 hours, the results are shown in table 5.
[ example 6 ]
The same as [ example 4 ], except that a long-chain polyamine polyether compound is used2(R1＝C16H33Ammonium propanesulfonate (R1 + R2+2R3 ═ 2, s1+ s2+2s3 ═ 3, R1+ R2+2R3 ═ 2)2、R3、R4One of them is CH2CH2CH2SO3NH4The balance of H)120 g, sodium tartrate 100 g, sodium bicarbonate 70 g and sodium borate 30 g are mixed evenlyAfter homogenizing, 30 g of a 5% starch aqueous solution was added and mixed, and the mixture was pressed into a stick to obtain a foam drainage stick FS04, and the results are shown in Table 6.
[ example 7 ]
(1) Preparation of foam discharging agent FS 05:
a. adding 36.0 g (0.6 mol) of ethylenediamine and 13.8 g (0.1 mol) of potassium carbonate solid into a reaction bottle provided with a mechanical stirring device, a thermometer, a dropping funnel and a normal pressure distillation device, slowly dropping 177.0 g (0.5 mol) of methyl behenate under stirring, reacting for 3 hours at the reaction temperature of 120-160 ℃, and collecting methanol generated by the reaction to obtain the required amide compound C21H43CONHCH2CH2NH2The yield thereof was found to be 91.6%.
b. Removing water from a three-neck flask device provided with a reflux condenser tube, a dropping funnel and a thermometer, adding 15.2 g (0.4 mol) of lithium aluminum hydride and 100 ml of dry dioxane, stirring, dispersing and mixing, and dropping 38.2 g (0.1 mol) of C at-10-5 DEG C21H43CONHCH2CH2NH2The 40 wt% dioxane solution is added dropwise and slowly heated to about 35 ℃ for reaction for 3 hours. Carefully pouring the reaction solution into ice water, and carrying out post-treatment to obtain a long-chain polyamine compound C21H43CH2NHCH2CH2NH2The yield thereof was found to be 87.9%.
c. A pressure reactor equipped with a stirring device was charged with 147.2 g (0.4 mol) of C21H43CH2NHCH2CH2NH25.2 g of potassium carbonate and 280.7 g (4.84 mol) of propylene oxide react at 140-160 ℃ to obtain a long-chain polyamine polyether compound3(R1＝C22H45，m＝1，s1+s2+s3＝12，r1+r2+r3＝0，R2＝R3＝R4H), yield 98.1%.
d. Long-chain polyamine polyether compounds3(R1＝C22H45，m＝1，s1+s2+s3＝12，r1+r2+r3＝0，R2＝R3＝R4H)106.4 g (0.1 mol) with 16.8 g (0.3 mol) of potassium hydroxide and 15.9 g (0.12 mol) of chloroacetic acidPotassium and 400 ml of acetone are mixed in a reaction kettle provided with a mechanical stirrer, a thermometer and a reflux condenser tube, and heated to reflux reaction for 10 hours. Evaporating the solvent to obtain the long-chain polyamine polyether compound3(R1＝C22H45Sodium acetate (R) of 1, s1+ s2+ s 3-12, R1+ R2+ R3-02、R3、R4One of them is CH2COOK and the rest is H).
e. Long-chain polyamine polyether compound3(R1＝C22H45Potassium acetate (R) of m 1, s1+ s2+ s 3-12, R1+ R2+ R3-02、R3、R4One of them is CH2COOK and the balance H), 120 g of sodium sulfate, 150 g of sodium tartrate, 100 g of sodium tartrate and 20 g of potassium chloride, adding 60 g of 10% polyethylene glycol, mixing, pressing into a rod shape, and preparing the foam drainage rod FS 05.
(2) The same as [ example 1 ] except that the aging was carried out at 200 ℃ for 24 hours, the results are shown in Table 7.
[ example 8 ]
The same as [ example 7 ] except that in the measurement of FS05 performance, pH was adjusted to 7 and 4 with hydrochloric acid to simulate neutral and acidic gas environments, and aging was performed at 200 ℃ for 24 hours, and the results are shown in table 8.
[ example 9 ]
The same as [ example 7 ], except that a long-chain polyamine polyether compound is used3(R1＝C22H45Potassium acetate (R) of m 1, s1+ s2+ s 3-12, R1+ R2+ R3-02、R3、R4One of them is CH2COOK and the balance of H), 120 g of sodium sulfate, 100 g of sodium sulfate, 50 g of potassium carbonate, 30 g of sodium borate and 30 g of biuret, adding 30 g of 5% dextrin water solution, mixing, pressing into a rod shape, and obtaining the foam drainage rod FS06, wherein the results are shown in Table 9.
[ example 10 ]
(1) Preparation of foam discharging agent FS 07:
a. a reaction flask equipped with mechanical stirring, thermometer, dropping funnel and atmospheric distillation was charged with 36.0 g (0.6 mole) of ethylenediamine and 13.8 g (0.1 mole) of potassium carbonate-solidThen, 158.3 g (0.5 mol) of methyl abietate (formula 3) was slowly dropped while stirring, reacted at a reaction temperature of 120 to 160 ℃ for 8 hours, and methanol produced by the reaction was collected to obtain the desired amide compound C19H29CONHCH2CH2NH2The yield thereof was found to be 85.6%.
b. Removing water from a three-neck flask device provided with a reflux condenser tube, a dropping funnel and a thermometer, adding 13.3 g (0.35 mol) of lithium aluminum hydride and 100 ml of dry dioxane, stirring, dispersing and mixing, and dropping 34.4 g (0.1 mol) of C at-10-5 DEG C19H29CONHCH2CH2NH2The 40 wt% dioxane solution is added dropwise and slowly heated to about 35 ℃ for reaction for 5 hours. Carefully pouring the reaction liquid into ice water, and carrying out post-treatment to obtain a rosin polyamine compound C19H29CH2NHCH2CH2NH2The yield thereof was found to be 73.2%.
c. To a pressure reactor equipped with a stirring device was added 132.0 g (0.4 mol) of C19H29CH2NHCH2CH2NH25.0 g of potassium hydroxide and 160.2 g (3.64 mol) of ethylene oxide react at 140-160 ℃ to obtain the rosin polyamine polyether compound4(R1＝C20H31，m＝1，s1+s2+s3＝0，r1+r2+r3＝9，R2＝R3＝R4H), yield 91.4%.
d. Rosin polyamine polyether compounds4(R1＝C20H31，m＝1，s1+s2+s3＝0，r1+r2+r3＝9，R2＝R3＝R4H)72.6 g (0.1 mol) were mixed with 8.0 g (0.2 mol) of sodium hydroxide, 33.3 g (0.2 mol) of sodium 2-chloroethanesulfonate and 100 ml of toluene in a reaction vessel equipped with a mechanical stirrer, a thermometer and a reflux condenser and heated to reflux for 6 hours. Evaporating the solvent to obtain the long-chain polyamine polyether compound4(R1＝C20H31Sodium ethanesulfonate (R) of m 1, s1+ s2+ s 30, R1+ R2+ R3 92、R3、R4One of them is CH2CH2SO3Na, remainder H).
e. Long-chain polyamine polyether compound4(R1＝C20H31M is 1, s1+ s2+ s3 is 0, r1+ r2+ r3 is 9), potassium phthalate 50 g and biuret 100 g are mixed with 5% polyethylene glycol solution 30 g and then pressed into a rod shape, thus obtaining the foam drainage rod FS 07.
(2) The results are shown in Table 10, as in example 1.
[ example 11 ]
The same as [ example 10 ] except that when the FS07 performance was measured, the pH was adjusted to 2 with hydrochloric acid to simulate a high acid-containing gas atmosphere, and the results are shown in table 11.
[ example 12 ]
The same as [ example 10 ] except that a long-chain polyamine polyether compound is used4(R1＝C20H31M 1, s1+ s2+ s3 is 0, r1+ r2+ r3 is 9), 120 g of sodium ethanesulfonate, 100 g of potassium citrate, 50 g of urea, 30 g of potassium carbonate and 60 g of sodium acetate are uniformly mixed, 30 g of a 1% polyacrylamide aqueous solution is added, the mixture is mixed and then pressed into a stick shape, and a foam drainage stick FS08 is prepared, and the results are shown in Table 12.
[ example 13 ]
The same as [ example 1 ] except that kerosene was added in a given amount by mass, and the results before aging were shown in Table 13.
[ example 14 ]
The same as in example 2, except that hydrogen sulfide and carbon dioxide acid gas were introduced into the gas when the amount of liquid carried was measured, the results are shown in Table 14.
[ COMPARATIVE EXAMPLE 1 ]
The same as [ example 1 ], except that C is used17H33CO(NHCH2CH2)5NH2Substituted long-chain polyamine polyether compounds1(R1＝C18H35，m＝5，s1+s2+5s3＝20，r1+r2+5R3 ═ 3) sodium hydroxypropanesulfonate (R)2、R3、R4One of them is CH2CH(OH)CH2SO3Na, balance H) produced foam drainage stick FS09 with simulated water of 100,000mg/LNaCl, the results of which are shown in Table 15.
[ COMPARATIVE EXAMPLE 2 ]
The same as in comparative example 1, except that when the FS09 performance was measured, pH was adjusted to 7 and 4 with hydrochloric acid to simulate neutral and acid gas environments, and the results are shown in table 16.
[ COMPARATIVE EXAMPLE 3 ]
The same as [ example 4 ], except that C is used15H31CO(NHCH2CH2)2NH2Substituted long-chain polyamine polyether compounds2(R1＝C16H33Ammonium propanesulfonate (R1 + R2+2R3 ═ 2, s1+ s2+2s3 ═ 3, R1+ R2+2R3 ═ 2)2、R3、R4One of them is CH2CH2CH2SO3NH4And the remainder H) produced foam drainage stick FS10 with simulated water of 100,000mg/LNaCl, the results of which are shown in Table 15.
[ COMPARATIVE EXAMPLE 4 ]
The same as [ example 7 ], except that C is used21H43CONHCH2CH2NH2Substituted long-chain polyamine polyether compounds3(R1＝C22H45Potassium acetate (R) of m 1, s1+ s2+ s 3-12, R1+ R2+ R3-02、R3、R4One of them is CH2COOK, remainder H) produced foam drainage sticks FS11 with simulated water of 100,000mg/LNaCl, the results are shown in Table 15.
[ COMPARATIVE EXAMPLE 5 ]
The same as [ example 10 ], except that C is used19H29CONHCH2CH2NH2Substituted long-chain polyamine polyether compounds4(R1＝C20H31M 1, s1+ s2+ s 3-0, r1+ r2+ r 3-9) was used to make foam drainage bars FS12 with simulated water of 100,000mg/LNaCl, the results are shown in table 15.
[ COMPARATIVE EXAMPLE 6 ]
The same as in comparative example 5, except that the FS12 performance was measured, the pH was adjusted to 2 with hydrochloric acid to simulate a high acid gas containing atmosphere, and the results are shown in Table 16.
[ COMPARATIVE EXAMPLE 7 ]
The same as comparative example 1 except that oleyl alcohol polyoxyethylene ether hydroxypropyl sodium sulfonate C was used18H35O(C2H4O)3CH2CH(OH)CH2SO3Na (F09) substituted long-chain polyamine polyether compound1(R1＝C18H35Sodium hydroxypropanesulfonate (R1 + R2+5R3 ═ 3), m ═ 5, s1+ s2+5s3 ═ 20, and R1+ R2+5R3 ═ 32、R3、R4One of them is CH2CH(OH)CH2SO3Na, balance H) produced foam drainage stick FS13 with simulated water of 100,000mg/LNaCl, the results of which are shown in Table 15.
The same as comparative example 2 except that oleyl alcohol polyoxyethylene ether hydroxypropyl sodium sulfonate C was used18H35O(C2H4O)3CH2CH(OH)CH2SO3Na (F09) substituted long-chain polyamine polyether compound1(R1＝C18H35Sodium hydroxypropanesulfonate (R1 + R2+5R3 ═ 3), m ═ 5, s1+ s2+5s3 ═ 20, and R1+ R2+5R3 ═ 32、R3、R4One of them is CH2CH(OH)CH2SO3Na, balance H) produced foam drainage stick FS13 with simulated water of 100,000mg/LNaCl, the results of which are shown in Table 16.
TABLE 1
TABLE 2
TABLE 3
TABLE 4
TABLE 5
TABLE 6
TABLE 7
TABLE 8
TABLE 9
Watch 10
TABLE 11
TABLE 12
Watch 13
TABLE 14
Watch 15
TABLE 16
Claims (16)
1. A method for draining liquid and producing gas by adopting a solid foam drainage agent comprises the following steps:
(1) mixing the solid foam drainage agent with water to obtain a foam drainage agent solution;
(2) fully contacting a foam drainage agent solution or a mixed solution of the foam drainage agent solution and oil with gas to form a foam fluid, and displacing water or an oil-water mixture in the foam drainage agent solution;
the solid foam drainage agent comprises the following components in parts by weight:
1)1 part of a long-chain polyamine compound;
2) 0.05-1000 parts of solid filler;
3) 0-0.5 parts of adhesive;
wherein the long-chain polyamine compound has a general molecular formula shown in formula (1):
in the formula (1), R1Is selected from C4～C32One of hydrocarbyl or substituted hydrocarbyl, R2、R3、R4Independently selected from H, C1～C5Hydrocarbyl or substituted hydrocarbyl carboxylates, C1～C5Alkyl or substituted alkyl sulfonates, C1～C5Hydrocarbyl or substituted hydrocarbyl phosphates or C1～C5One of alkyl sulfate or substituted alkyl sulfate, which is not H at the same time; m is-N (A) CH2CH2-the number of fragments, m ═ 1 to 10; a is a substituent represented by the formula (2); s1, s2 and s3 are the addition number of propoxy groups PO, s1 is 0-30, s2 is 0-30, and s3 is 0-30; r1, r2 and r3 are addition numbers of ethoxy groups EO, r1 is 0-30, r2 is 0-30, r3 is 0-30, and s1+ s2+ m × s3 and r1+ r2+ m × r3 are not zero at the same time;
the gas is at least one of air, nitrogen or natural gas; the oil is crude oil;
the preparation method of the solid foam drainage agent comprises the steps of uniformly mixing 1 part of long-chain polyamine compound, 0.05-1000 parts of solid filler and 0-0.5 part of adhesive, and then performing compression molding to obtain the solid foam drainage agent.
2. The method of liquid drainage gas production using solid foam drainage agent according to claim 1, wherein the gas is methane.
3. The method of claim 1, wherein the gas comprises H, and wherein the gas comprises H2S and/or CO2An acid gas.
4. The method of gas recovery from drainage using a solid foam drainage agent as claimed in claim 1 wherein the oil is a condensate.
5. The method of liquid drainage gas production using solid foam drainage agent according to claim 1, wherein the oil is kerosene.
6. The method of claim 1, wherein R is selected from the group consisting of1Is C8～C24Hydrocarbyl or substituted hydrocarbyl; r2、R3、R4Independently selected from H, CH2COOM、(CH2)3SO3M or CH2(CHOH)CH2SO3One of M is not H at the same time; m is 1-5; s1+ s2+ mxs 3 is 0-5, r1+ r2+ mxr 3 is 0-10, and is not zero at the same time; wherein M is an alkali metal or is represented by the formula NR5(R6(R7)(R8) R) one of the groups shown5、R6、R7、R8Independently selected from H, (CH)2)aOH or (CH)2)bCH3Wherein a is any integer of 2-4, and b is any integer of 0-5.
7. The method of claim 1, wherein the solid filler is at least one of carbonate, bicarbonate, sulfate, phosphate, borate, metal halide, formate, acetate, tartaric acid and salts, citric acid and salts, phthalic acid and salts, gallic acid and salts, urea, biuret; the adhesive is at least one of dextrin, epoxy resin, polyacrylamide, starch, cellulose and polyethylene glycol.
8. The method of claim 7, wherein the solid filler is at least one of sodium carbonate, sodium bicarbonate, sodium borate, sodium chloride, sodium acetate, tartaric acid, sodium tartrate, citric acid, sodium citrate, potassium phthalate, urea, biuret; the adhesive is at least one of polyacrylamide, starch and polyethylene glycol.
9. The method for drainage and gas production by using a solid foam drainage agent according to claim 1, wherein the mass ratio of the long-chain polyamine compound, the solid filler and the binder is 1: (0.1-200): (0.01-0.1).
10. The method for draining liquid and producing gas by using the solid foam drainage agent according to any one of claims 1 to 9, characterized in that the preparation method of the solid foam drainage agent comprises the following steps:
(1) preparation of long-chain polyamine compounds
a. Amidation reaction:
r is to be0COOR' and H (NHCH)2CH2)mNH2Mixing the catalysts according to the molar ratio of 1 (1-2) to 0-0.5, reacting for 3-15 hours at the reaction temperature of 50-200 ℃ under stirring, and evaporating alcohol or water generated in the reaction under normal pressure or reduced pressure to obtain the amide compound R0CO(NHCH2CH2)mNH2(ii) a Wherein R is0Is selected from C3～C31One of hydrocarbyl or substituted hydrocarbyl, R' is selected from H and C1～C8M is 1-10, and the catalyst is at least one selected from alkali metal hydroxide, alkali metal alkoxide and alkali metal carbonate;
b. reduction reaction:
the R synthesized in the step a0CO(NHCH2CH2)mNH2With metal hydrides H-Y+Reduction in an aprotic solvent to give R0CH2(NHCH2CH2)mNH2(ii) a Wherein, Y+Is metal ion, metal alkyl ion, metal amino ion;
c. and (3) polyether esterification:
in the presence of a basic catalystb synthetic R0CH2(NHCH2CH2)mNH2Sequentially reacting with required amount of propylene oxide and ethylene oxide to obtain long-chain polyamine polyether intermediate product R0CH2{N[(CHCH3CH2O)s3(CH2CH2O)r3H][CH2CH2]}mN[(CHCH3CH2O)s1(CH2CH2O)r1H][CHCH3CH2O)s2(CH2CH2O)r2)H]；
d. Carboxylation or sulfonation reaction:
c, mixing the long-chain polyamine polyether intermediate product obtained in the step c with an ionizing agent and a base in a molar ratio of 1: (1-5): (1-10) reacting in a solvent at the reaction temperature of 50-120 ℃ for 3-20 hours to generate a long-chain polyamine compound shown in the structural formula (1); the ionizing agent is selected from XR9Y1(ii) a The base is selected from alkali metal hydroxide or alkali metal alkoxide; y is1Is SO3M1Or COON1，M1And N1Is an alkali metal, and X is chlorine, bromine or iodine; wherein, XR9Y1Is at least one of alkali metal salt of chloroacetic acid, alkali metal salt of bromoacetic acid, alkali metal salt of 3-chloro-2-hydroxypropanesulfonic acid, alkali metal salt of 2-chloroethanesulfonic acid and 1, 3-propanesultone;
(2) and (2) uniformly mixing the long-chain polyamine compound synthesized in the step (1), the solid filler and the adhesive according to the required mass parts, and then pressing and forming to prepare the solid foam drainage agent.
11. The method of claim 10, wherein R is the amount of water in step a0COOR’、H(NHCH2CH2)mNH2The molar ratio of the catalyst is (1-1.3) to (0-0.1), and the catalyst is at least one of sodium hydroxide, potassium hydroxide, sodium carbonate and potassium carbonate.
12. The method of claim 10The method for draining liquid and producing gas by adopting the solid foam drainage agent is characterized in that the step b is H-Y+Is LiAlH4、LiAlH(OEt)3Or NaBH4The aprotic solvent is at least one of diethyl ether, tetrahydrofuran and dioxane; the long-chain polyamine polyether intermediate product in the step d: ionizing agent: the molar ratio of the alkali is 1 to (1-2) to (1-4), and the solvent is selected from C3～C8Ketone and C6～C9At least one aromatic hydrocarbon of (1).
13. The method of claim 3, wherein the gas is nitrogen or natural gas, H2S and CO2The content of (A) is 15-35%; the oil is condensate oil.
14. The method of liquid drainage gas production using solid foam drainage agent of claim 13 wherein the gas is methane.
15. The method of liquid drainage gas production using solid foam drainage agent of claim 13 wherein the oil is kerosene.
16. The method for liquid drainage gas production by using the solid foam drainage agent according to any one of claims 1 to 9 and 11 to 15, wherein the method is applied under the conditions of high-temperature acid gas-containing gas reservoir, formation temperature of 150 to 200 ℃, total salinity of formation brine of 5000 to 200000mg/L, and H2S and CO2The content of (A) is 0-35%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710969729.3A CN109681175B (en) | 2017-10-18 | 2017-10-18 | Method for draining liquid and producing gas by using solid foam drainage agent with pH value response |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710969729.3A CN109681175B (en) | 2017-10-18 | 2017-10-18 | Method for draining liquid and producing gas by using solid foam drainage agent with pH value response |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN109681175A CN109681175A (en) | 2019-04-26 |
| CN109681175B true CN109681175B (en) | 2021-08-03 |
Family
ID=66182771
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710969729.3A Active CN109681175B (en) | 2017-10-18 | 2017-10-18 | Method for draining liquid and producing gas by using solid foam drainage agent with pH value response |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN109681175B (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113881418B (en) * | 2020-07-02 | 2023-10-31 | 中国石油化工股份有限公司 | Alkylaniline polyether benzene sulfonate oil displacement surfactant and preparation method and application thereof |
| CN117625165B (en) * | 2023-11-14 | 2024-06-18 | 长江大学 | High-temperature-resistant high-salt-resistant nano foam discharging agent and preparation method and application thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101580705A (en) * | 2009-06-12 | 2009-11-18 | 中国石油大学(华东) | Foaming agent with low gas liquid ratio foam for common heavy oil reservoir and injection method thereof |
| CN102373053A (en) * | 2010-08-23 | 2012-03-14 | 中国石油化工股份有限公司 | Foaming agent composition and purpose thereof |
| CN105114046A (en) * | 2015-08-05 | 2015-12-02 | 中国石油化工股份有限公司 | Energy increase type foam drainage gas recovery process |
| CN105754571A (en) * | 2016-03-29 | 2016-07-13 | 江南大学 | Dimeric surfactant containing foam oil-displacing agent and preparation method thereof |
| CN106590583A (en) * | 2015-10-20 | 2017-04-26 | 中国石油化工股份有限公司 | Hypersalinity-resistant foam discharging agent composition for drainage gas production as well as preparation method and application thereof |
-
2017
- 2017-10-18 CN CN201710969729.3A patent/CN109681175B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101580705A (en) * | 2009-06-12 | 2009-11-18 | 中国石油大学(华东) | Foaming agent with low gas liquid ratio foam for common heavy oil reservoir and injection method thereof |
| CN102373053A (en) * | 2010-08-23 | 2012-03-14 | 中国石油化工股份有限公司 | Foaming agent composition and purpose thereof |
| CN105114046A (en) * | 2015-08-05 | 2015-12-02 | 中国石油化工股份有限公司 | Energy increase type foam drainage gas recovery process |
| CN106590583A (en) * | 2015-10-20 | 2017-04-26 | 中国石油化工股份有限公司 | Hypersalinity-resistant foam discharging agent composition for drainage gas production as well as preparation method and application thereof |
| CN105754571A (en) * | 2016-03-29 | 2016-07-13 | 江南大学 | Dimeric surfactant containing foam oil-displacing agent and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN109681175A (en) | 2019-04-26 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN107573917B (en) | Solid foam drainage agent composition and preparation method and application thereof | |
| CN109681175B (en) | Method for draining liquid and producing gas by using solid foam drainage agent with pH value response | |
| CN107043463B (en) | Humic acid condensation polymer and preparation method thereof | |
| CN109679607B (en) | Method for water drainage and gas production by adopting high-temperature-resistant high-salt foam drainage agent | |
| CN109679631B (en) | Foam drainage agent composition for ultra-deep gas well, preparation method and application | |
| CN109679637B (en) | Method for draining water and producing gas by adopting solid foam water draining agent composition for ultra-deep gas well | |
| CN109401743B (en) | Foam scrubbing agent composition for salt-resistant acid-resistant water drainage and gas production and preparation method and application thereof | |
| CN109679615B (en) | Method for draining water and producing gas by adopting foam water draining agent composition for ultra-deep gas well | |
| CN109679608B (en) | High-temperature-resistant acid-resistant foam drainage agent, preparation method and application | |
| CN109679617B (en) | Solid foam drainage agent composition suitable for ultra-deep gas well, preparation method and application | |
| CN109679609B (en) | Foam drainage agent composition suitable for ultra-deep gas well, preparation method and application | |
| CN109681174B (en) | Method for water drainage and gas production by adopting high-temperature-resistant high-salt solid foam drainage agent | |
| CN109679610B (en) | Solid foam drainage agent with pH value response, preparation method and application | |
| CN107674665B (en) | Foam drainage agent composition for ultra-deep gas well and preparation method and application thereof | |
| CN109679618B (en) | High-temperature-resistant high-salt foam drainage agent, and preparation method and application thereof | |
| CN109681169B (en) | Method for draining water and producing gas by adopting foam water draining agent composition in ultra-deep gas well | |
| CN109681170B (en) | Method for discharging liquid and gas production by adopting pH value response foam drainage agent | |
| CN109679614B (en) | Method for water drainage and gas recovery by adopting high-temperature-resistant acid-resistant solid foam drainage agent | |
| CN109679616B (en) | Foam drainage agent with pH value response, preparation method and application | |
| CN109681166B (en) | Method for water drainage and gas recovery by adopting high-temperature-resistant acid-resistant foam drainage agent | |
| CN109679636B (en) | Method for discharging liquid and gas production by adopting oil-resistant solid foam discharging agent composition | |
| CN109681171B (en) | Method for discharging liquid and producing gas by adopting solid foam water discharging agent composition | |
| CN109679621B (en) | High-temperature-resistant high-salt solid foam drainage agent, and preparation method and application thereof | |
| CN109679612B (en) | Solid oil-resistant foam drainage agent composition, preparation method and application thereof | |
| CN109679630B (en) | High-temperature-resistant acid-resistant solid foam drainage agent, and preparation method and application thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |