CN109679538A - A kind of low VOC mixed type glue spraying and preparation method thereof - Google Patents
A kind of low VOC mixed type glue spraying and preparation method thereof Download PDFInfo
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- CN109679538A CN109679538A CN201811649982.1A CN201811649982A CN109679538A CN 109679538 A CN109679538 A CN 109679538A CN 201811649982 A CN201811649982 A CN 201811649982A CN 109679538 A CN109679538 A CN 109679538A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
- C09J133/02—Homopolymers or copolymers of acids; Metal or ammonium salts thereof
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/08—Macromolecular additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Adhesives Or Adhesive Processes (AREA)
Abstract
The invention discloses a kind of low VOC mixed type glue sprayings, including following parts by weight of component: solid content is 25-35 parts of water-soluble spraying glue lotion of 30-35%；20-30 parts of resin；Sorbester p18 or 3-10 parts of sorbester p17；Fire-retardant organic solvent is added to 100 parts by weight.The present invention relates to glue spraying field, the glue spraying organic solvent content is low, conventional lance spraying, performance can be used similar with oiliness glue spraying.Meanwhile the present invention also provides the preparation methods of the glue spraying.
Description
Technical field
The present invention relates to glue spraying fields, and in particular to a kind of low VOC mixed type glue spraying and preparation method thereof.
Background technique
Glue spraying is divided into oiliness glue spraying and water-soluble spraying glue, and the two respectively has its advantage and defect, and the spraying of oiliness glue spraying is easy, just viscous
Performance is good, but VOC emission amount is big, and the water-soluble spraying glue feature of environmental protection is good, but sprays inconvenience, needs spray gun special.
The earlier application ZL201710363362.0 of the applicant discloses a kind of ageing-resistant antiscirrhous bi-component waterborne
Glue spraying, including component A and B component, in which: component A includes following parts by weight of component: 39-41 parts of watersoluble neoprene latex rubber, propylene
30-40 parts of yogurt liquid, 7-9 parts of aqueous terpenes tackifying resin, 2-10 parts of neopelex；B component is by following parts by weight
Group is grouped as: 5-10 parts of rosin resin, 1-5 parts of isocyanates, 1-3 parts of fumed silica, 30-40 parts of deionized water.
CN201610375153.3 discloses a kind of multipurpose glue spraying, including following parts by weight of component: SBR rubber, carbonic acid
Dimethyl ester, disproportionated rosin, ethyl acetate, tackifying resin, polyvinyl alcohol, the metering system that number-average molecular weight is 16000-20000
Sour hydroxyl ethyl ester, butane；
The two respectively has its advantage, and this programme mainly solves the problems, such as to be: proposing that one kind is mixed with resin and water-base resin
Glue spraying, be desirable to reduce VOC content, while can be can be operated with conventional lance.
Summary of the invention
The object of the present invention is to provide a kind of low VOC mixed type glue spraying and preparation method thereof, the glue spraying organic solvent contents
It is low, can using conventional lance spraying, performance it is similar with oiliness glue spraying.
Concrete scheme of the invention is as follows: a kind of low VOC mixed type glue spraying, including following parts by weight of component:
Solid content is 25-35 parts of water-soluble spraying glue lotion of 30-35%；
20-30 parts of resin；
Sorbester p18 or 3-10 parts of sorbester p17；
Fire-retardant organic solvent is added to 100 parts by weight.
In above-mentioned low VOC mixed type glue spraying, the resin is SBS1401, SBS1301, terpene resin, hydrogenates stone
One of oleoresin, newtrex, disproportionated rosin are a variety of.
In above-mentioned low VOC mixed type glue spraying, the water-soluble spraying glue lotion includes watersoluble neoprene latex rubber, acrylic acid
Lotion, aqueous terpenes tackifying resin and suitable emulsifier.
In above-mentioned low VOC mixed type glue spraying, the water-soluble spraying glue lotion includes 39-41 parts by weight watersoluble neoprene rubber
The dodecyl of latex, 30-40 parts by weight of acrylic acid lotion, the aqueous terpenes tackifying resin of 7-9 parts by weight and 2-10 parts by weight
Benzene sulfonic acid sodium salt.
In above-mentioned low VOC mixed type glue spraying, the fire-retardant organic solvent is methylene chloride or tetrachloromethane.
Meanwhile the invention also discloses a kind of preparation methods of low VOC mixed type glue spraying as described above, including walk as follows
It is rapid:
Step 1: sorbester p18 or the dissolution of sorbester p17 and resin are distributed in fire-retardant organic solvent；
Step 2: water-soluble spraying glue lotion being added slowly in step 1 in the case of stirring, stirring forms stable
Lotion.
The present invention has the following advantages and effects with respect to the prior art:
It is compounded using resin and water-based emulsion, reduces consumption of organic solvent, while making using fire-retardant organic solvent
For solvent phase, preferable fire retardation can be played, performance is similar to the performance of oiliness glue spraying.
In order to improve the stability of this system, using the emulsifier of Water-In-Oil as primary emulsion, use is oil-in-water
Emulsifier as water-soluble spraying glue lotion as coemulsifier, by this compounding, improve in system water-soluble spraying glue lotion and
Stability under resin Coexistence Situation.
Specific embodiment
Below with reference to embodiment, the invention will be further described, but does not constitute any limitation of the invention, any
In the modification for the limited times that scope of the invention as claimed is made, still in scope of the presently claimed invention.
Embodiment 1
A kind of low VOC mixed type glue spraying, including following parts by weight of component:
Solid content is 30 parts of water-soluble spraying glue lotion of 30-35%；
20 parts of resin；
5 parts of sorbester p18；
Methylene chloride is added to 100 parts.
Wherein, resin SBS1401, terpene resin, newtrex, hydrogenated petroleum resin, weight ratio are as follows: 1:1:2:1.
Component A of the water-soluble spraying glue lotion with the embodiment 1 of ZL201710363362.0.
The preparation method comprises the following steps:
Step 1: sorbester p18 and resin dissolution are distributed in fire-retardant organic solvent；
Step 2: water-soluble spraying glue lotion being added slowly in step 1 in the case of stirring, stirring forms stable
Lotion.
Embodiment 2
A kind of low VOC mixed type glue spraying, including following parts by weight of component:
Solid content is 35 parts of water-soluble spraying glue lotion of 30-35%；
25 parts of resin；
8 parts of sorbester p17；
Methylene chloride is added to 100 parts.
Wherein, resin SBS1401, terpene resin, newtrex, hydrogenated petroleum resin, weight ratio are as follows: 2:1:2:1.
Component A of the water-soluble spraying glue lotion with the embodiment 2 of ZL201710363362.0.
The preparation method comprises the following steps:
Step 1: sorbester p17 and resin dissolution are distributed in fire-retardant organic solvent；
Step 2: water-soluble spraying glue lotion being added slowly in step 1 in the case of stirring, stirring forms stable
Lotion.
Embodiment 3
A kind of low VOC mixed type glue spraying, including following parts by weight of component:
Solid content is 30 parts of water-soluble spraying glue lotion of 30-35%；
28 parts of resin；
7 parts of sorbester p17；
Methylene chloride is added to 100 parts.
Wherein, resin SBS1301, terpene resin, newtrex, disproportionated rosin resin, weight ratio are as follows: 1:1:1:2.
Component A of the water-soluble spraying glue lotion with the embodiment 2 of ZL201710363362.0.
The preparation method comprises the following steps:
Step 1: sorbester p17 and resin dissolution are distributed in fire-retardant organic solvent；
Step 2: water-soluble spraying glue lotion being added slowly in step 1 in the case of stirring, stirring forms stable
Lotion.
Embodiment 4
A kind of low VOC mixed type glue spraying, including following parts by weight of component:
Solid content is 35 parts of water-soluble spraying glue lotion of 30-35%；
20 parts of resin；
3 parts of sorbester p18；
Methylene chloride is added to 100 parts.
Wherein, resin SBS1301, terpene resin, newtrex, disproportionated rosin resin, weight ratio are as follows: 1:1:2:1.
Component A of the water-soluble spraying glue lotion with the embodiment 3 of ZL201710363362.0.
The preparation method comprises the following steps:
Step 1: sorbester p18 and resin dissolution are distributed in fire-retardant organic solvent；
Step 2: water-soluble spraying glue lotion being added slowly in step 1 in the case of stirring, stirring forms stable
Lotion.
Embodiment 5
A kind of low VOC mixed type glue spraying, including following parts by weight of component:
Solid content is 28 parts of water-soluble spraying glue lotion of 30-35%；
29 parts of resin；
6 parts of sorbester p18；
Methylene chloride is added to 100 parts.
Wherein, resin SBS1301, terpene resin, newtrex, disproportionated rosin resin, weight ratio are as follows: 1:1:1:1.
Component A of the water-soluble spraying glue lotion with the embodiment 4 of ZL201710363362.0.
The preparation method comprises the following steps:
Step 1: sorbester p18 and resin dissolution are distributed in fire-retardant organic solvent；
Step 2: water-soluble spraying glue lotion being added slowly in step 1 in the case of stirring, stirring forms stable
Lotion.
Performance test
1. peel strength test: aluminium alloy (LY12-CZ) test piece is just glued, having a size of width x thickness × length=(25 ± 0.5)
Mm × (2 ± 0.3) mm × (200 ± 1) mm, canvas test piece, canvas meets the regulation of GB/T2909, having a size of width × length
=(25 ± 0.5) mm × (230 ± 1) mm.It is used respectively on the bonding plane of aluminium alloy test piece and the processed 200mm of canvas test piece
Spray gun sprays glue uniformly, glue quantity 3g ± 0.5g, and 5min is hung after spraying uniformly, and alignment bonding location is bonded.
In bonding site pressure 0.4MPa pressure, time 5min.After release, test specimen is hung into 30min naturally, then aluminium alloy test piece is pressed from both sides
Tightly on fixed collet, the long end of canvas test piece not being glued is bent 180 °, is clamped on lower collet.Testing machine is started,
Collet is set to remove test specimen with (100 ± 5) mm/min speed, being effectively peeled off length should be in 125mm or more.It is asked automatically by testing machine
Obtain just viscous peel strength σ (KN/m).
2. dry heat resistance is tested: referring to GB T27561-2011 Styrene-Butadiene-Styrene Block Copolymer (SBS) glue
Stick, 5.7.2 save the dry heat resistance test of glue spraying.
3.T peel strength: referring to GB T27561-2011 Styrene-Butadiene-Styrene Block Copolymer (SBS) gluing
Agent, the T peeling strength test of Section of 5.6 glue spraying.
4. peel strength test: aluminium alloy (LY12-CZ) test piece is glued eventually, having a size of width x thickness × length=(25 ± 0.5)
Mm × (2 ± 0.3) mm × (200 ± 1) mm, canvas test piece, canvas meets the regulation of GB/T2909, having a size of width × length
=(25 ± 0.5) mm × (230 ± 1) mm.It is used respectively on the bonding plane of aluminium alloy test piece and the processed 200mm of canvas test piece
Spray gun sprays glue uniformly, glue quantity 3g ± 0.5g, and 5min is hung after spraying uniformly, and alignment bonding location is bonded.
In bonding site pressure 0.4MPa pressure, time 5min.After release, test specimen is hung into 48h naturally, then aluminium alloy test piece is clamped
On fixed collet, the long end of canvas test piece not being glued is bent 180 °, is clamped on lower collet.Testing machine is started, is made
Collet removes test specimen with (100 ± 5) mm/min speed, and being effectively peeled off length should be in 125mm or more.It is acquired automatically by testing machine
Viscous peel strength σ (KN/m) eventually.
Table 1: the first viscous peel strength test result of embodiment 1-5
By above-mentioned test it can be found that being compounded using resin and water-soluble spraying glue lotion complete in actual application
Be entirely it is feasible, although this programme does not completely remove organic solvent, from the point of view of actual application angle, effectively
The dosage of organic solvent is reduced, and its performance is fully able to reach the performance requirement of oiliness glue spraying, with quick-drying, resistance to
The big advantage of heat, peel strength.
Meanwhile the glue spraying of this programme is not necessarily to spray gun special, can be operated using conventional spray guns.
The above embodiment is a preferred embodiment of the present invention, but embodiments of the present invention are not by above-described embodiment
Limitation, other any changes, modifications, substitutions, combinations, simplifications made without departing from the spirit and principles of the present invention,
It should be equivalent substitute mode, be included within the scope of the present invention.
Claims (6)
1. a kind of low VOC mixed type glue spraying, which is characterized in that including following parts by weight of component:
Solid content is 25-35 parts of water-soluble spraying glue lotion of 30-35%；
20-30 parts of resin；
Sorbester p18 or 3-10 parts of sorbester p17；
Fire-retardant organic solvent is added to 100 parts by weight.
2. low VOC mixed type glue spraying according to claim 1, which is characterized in that the resin be SBS1401,
One of SBS1301, terpene resin, hydrogenated petroleum resin, newtrex, disproportionated rosin are a variety of.
3. low VOC mixed type glue spraying according to claim 1, which is characterized in that the water-soluble spraying glue lotion includes water
Property neoprene cream, acrylic emulsion, aqueous terpenes tackifying resin and suitable emulsifier.
4. low VOC mixed type glue spraying according to claim 3, which is characterized in that the water-soluble spraying glue lotion includes 39-
41 parts by weight watersoluble neoprene latex rubbers, 30-40 parts by weight of acrylic acid lotion, the aqueous terpenes tackifying resin of 7-9 parts by weight and 2-
The neopelex of 10 parts by weight.
5. low VOC mixed type glue spraying according to claim 1, which is characterized in that the fire-retardant organic solvent is dichloro
Methane.
6. a kind of preparation method of the low VOC mixed type glue spraying as described in claim 1-5 is any, which is characterized in that including such as
Lower step:
Step 1: sorbester p18 or the dissolution of sorbester p17 and resin are distributed in fire-retardant organic solvent；
Step 2: water-soluble spraying glue lotion being added slowly in step 1 in the case of stirring, stirring forms stable lotion.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811649982.1A CN109679538B (en) | 2018-12-31 | 2018-12-31 | Low-VOC (volatile organic compound) mixed spray adhesive and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811649982.1A CN109679538B (en) | 2018-12-31 | 2018-12-31 | Low-VOC (volatile organic compound) mixed spray adhesive and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN109679538A true CN109679538A (en) | 2019-04-26 |
| CN109679538B CN109679538B (en) | 2022-03-08 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201811649982.1A Active CN109679538B (en) | 2018-12-31 | 2018-12-31 | Low-VOC (volatile organic compound) mixed spray adhesive and preparation method thereof |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112724929A (en) * | 2021-01-13 | 2021-04-30 | 深圳市顾康力化工有限公司 | Water-in-oil type emulsion adhesive and preparation method thereof |
| CN112759984A (en) * | 2021-01-19 | 2021-05-07 | 广东美涂士建材股份有限公司 | Water-in-oil neoprene spray adhesive and preparation method thereof |
| CN116694264A (en) * | 2023-06-15 | 2023-09-05 | 刘丽 | Acrylic resin spray adhesive |
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|---|---|---|---|---|
| JPH05320600A (en) * | 1992-05-21 | 1993-12-03 | Aica Kogyo Co Ltd | Aqueous adhesive for spray-coating |
| CN101058704A (en) * | 2007-05-29 | 2007-10-24 | 林润强 | Multifunctional aqueous adhesive and preparation method thereof |
| CN102295912A (en) * | 2010-06-25 | 2011-12-28 | 东莞市大洋化工有限公司 | Multifunctional spray glue formula and process |
| CN104946166A (en) * | 2015-06-27 | 2015-09-30 | 广东远东高分子科技有限公司 | Water-based spray gel and preparation method thereof |
-
2018
- 2018-12-31 CN CN201811649982.1A patent/CN109679538B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH05320600A (en) * | 1992-05-21 | 1993-12-03 | Aica Kogyo Co Ltd | Aqueous adhesive for spray-coating |
| CN101058704A (en) * | 2007-05-29 | 2007-10-24 | 林润强 | Multifunctional aqueous adhesive and preparation method thereof |
| CN102295912A (en) * | 2010-06-25 | 2011-12-28 | 东莞市大洋化工有限公司 | Multifunctional spray glue formula and process |
| CN104946166A (en) * | 2015-06-27 | 2015-09-30 | 广东远东高分子科技有限公司 | Water-based spray gel and preparation method thereof |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112724929A (en) * | 2021-01-13 | 2021-04-30 | 深圳市顾康力化工有限公司 | Water-in-oil type emulsion adhesive and preparation method thereof |
| CN112759984A (en) * | 2021-01-19 | 2021-05-07 | 广东美涂士建材股份有限公司 | Water-in-oil neoprene spray adhesive and preparation method thereof |
| CN116694264A (en) * | 2023-06-15 | 2023-09-05 | 刘丽 | Acrylic resin spray adhesive |
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| CN109679538B (en) | 2022-03-08 |
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Denomination of invention: A Low VOC Mixed Spray Adhesive and Its Preparation Method Effective date of registration: 20230328 Granted publication date: 20220308 Pledgee: Qingyuan Branch of Postal Savings Bank of China Co.,Ltd. Pledgor: GUANGDONG TAIQIANG TECHNOLOGY INDUSTRY CO.,LTD. Registration number: Y2023980036556 |
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