CN109679155A - A kind of veneer list pin vehicle track pin bush(ing) rubber - Google Patents
A kind of veneer list pin vehicle track pin bush(ing) rubber Download PDFInfo
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- CN109679155A CN109679155A CN201811503825.XA CN201811503825A CN109679155A CN 109679155 A CN109679155 A CN 109679155A CN 201811503825 A CN201811503825 A CN 201811503825A CN 109679155 A CN109679155 A CN 109679155A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L7/00—Compositions of natural rubber
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2296—Oxides; Hydroxides of metals of zinc
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Abstract
The invention discloses a kind of veneer list pin vehicle track pin bush(ing) rubber, its constituent and mass fraction are respectively as follows: 100 parts of natural rubber, 30~50 parts of carbon black, 4~10 parts of carbon fiber, 2~5 parts of anti-aging agent, 3~6 parts of activating agent, 1~3 part of softening agent, 3~8 parts of reinforcing agent, 1~4 part of vulcanizing agent, 1~4 part of promotor.The present invention can be improved Double Pressures-torsional shear loss of the twisting resistance and rubber bushing of conventional bushings rubber receiving, realizes the optimization of crawler belt entirety driving functions, extends the mileage service life of crawler belt.
Description
Technical field
The invention belongs to armored vehicle technical field of composite materials, are related to a kind of veneer list pin vehicle track pin bush(ing) rubber
Glue specifically prepares functional track pin bushing rubber, has the characteristics that anti-extrusion bumper and absorbing shock and high voltage, torsion.
Background technique
Tank track is the important component of tank power behavioral system, and effect is the driving wheel by means of engaging
Driving moment or braking moment are transmitted, tractive force is generated by the interaction with ground or brake force realizes tank movement, and
It ensures tank smooth-ride, passes through various complex road surfaces and various barriers.Creeper tread and track pin are by high-strength wear-resistant alloy
Steel is made, to slow down tractive force of track in tank driving process to the great force of plate body and track pin, in metallic pin and plate
It is pressed into rubber bushing between body pin ear, so that the performance and used life of crawler belt all greatly improves.The U.S. is first with addition
The mode of rubber block improves the country of tank track, and the U.S. has used rubber-metal hinge after World War II, and structure has single pin and double
Point of pin.For example, double-pin track pin is round steel rod, there is the structure affixed with end connected device at both ends.Gum cover and sulphur are bonded on pin
Change, be then pressed among plate body earhole, the pin of adjacent track plate is affixed integral with end connected device.Gum cover outer diameter is greater than pin earhole
Diameter prevents the relative motion of gum cover and earhole contact surface by interference, realizes that pin and the opposite of earhole turn by gum cover torsional deflection
It is dynamic.
It is relatively early on the vehicles such as U.S. M48 series tank, M113 panzer, 2 tank of German leopard, Russia's T72 tank to use
Rubber bushed track plate, rubber bushing technology are more mature.In order to reduce the compressed axial deflection of rubber bushing, generally
Longer whole section gum cover is replaced using shorter more piece gum cover.For example, there is 14 short glue on U.S. M48 tank crawler plates track pin
It covers, has 16 short gum covers on German 2 tank track pin of leopard.
As tank develops to heavy duty, high speed direction, shearing that the rubber bushing of crawler belt is born, tension and compression, twisting action are more
Reinforce it is strong, because bushing earlier period damage caused by the crawler belt mileage travelled service life and target gap it is larger.Bushing early fatigue damage
Bad factor is complicated, and the extreme operating condition for bearing to reverse or tension and compression alternate stress is big is principal element, and crawler belt working environment is severe (high
Temperature, high humidity, intensive ultraviolet, more dirt etc.) and the design for rubber formulation failure process for also accelerating bushing such as unreasonable.Therefore,
Track pin rubber bushing material performance is improved, mechanical strength, elasticity, anti-aging, fatigue performance are improved, reduces hysteresis loss
While, the improvement in track bushings functional structure is necessary.
Whole tank metal track is connected by track pin, bushing by metal track plate body block-by-block, undertakes tank traveling
In the process land and driving function, in order to slow down in tank cross-country run crawler belt shock and vibration stress fatigue to track plate
With the damage of track pin metallic matrix, bushing is provided between the track pin and creeper tread of connecting band track, by metallic sheath and
The rubber layer of outer rim cladding is composed.During high speed driving, track bushings bear the huge traction of vehicle driving to tank
Radial compression that power is formed, shearing, impact vibration effect, also subject to the combined stress of axial torsional shear, while also by
High speed cross-country run road surface silt acts on the erosive wear in crawler belt plate hole.Practical application and documents and materials show that crawler belt serves as a contrast
Set is easy to appear following two problem in practical applications and causes to destroy and fail: 1. bearing the huge tractive force of vehicle driving
The extrusion damage of bushing rubber layer caused by radial compression, the impact vibration power of formation act on；2. caterpillar drive to driving wheel and
The tearing that bushing rubber layer caused by axial torsion, shear fatigue combined stress occurs for inducer position bushing and track pin is broken
It is bad.
Summary of the invention
(1) goal of the invention
The object of the present invention is to provide a kind of veneer list pin vehicle track pin bush(ing) rubber, are used for original natural gum
Crawler belt rubber bushing is improved to the yielding rubber bushing with high-modulus, resistance to torsional fatigue, by the anti-extrusion damping of track bushings
It is improved with high resistance to torsion function, realizes the optimization of crawler belt entirety driving functions, it is short to solve whole crawler belt service life in the prior art
Technology slot, on the whole improve tank track service life and maneuverability.
(2) technical solution
In order to solve the above technical problem, the present invention provides a kind of veneer list pin vehicle track pin bush(ing) rubber,
Constituent and mass fraction are respectively as follows: 100 parts of natural rubber, and 30~50 parts of carbon black, 4~10 parts of carbon fiber, anti-aging agent 2~5
Part, 3~6 parts of activating agent, 1~3 part of softening agent, 3~8 parts of reinforcing agent, 1~4 part of vulcanizing agent, 1~4 part of promotor.
The anti-aging agent is that graphene oxide is grafted antioxidant MB, by the hydroxyl and γ-chloropropyl of surface of graphene oxide
Triethoxysilane carries out the grafting of graphene oxide made from graft reaction and obtains with 2-mercaptobenzimidazole generation graft reaction.
The activating agent uses zinc oxide.The softening agent uses stearic acid.The reinforcing agent uses the poly- isoamyl two of liquid
Alkene.The vulcanizing agent uses Sulfur.The promotor uses accelerant CZ.The carbon black uses carbon black N330.
Preferably, the bushing rubber constituent and mass fraction are respectively as follows: 100 parts of natural rubber, and 5 parts of zinc oxide,
1 part of stearic acid, carbon black N330 has 50 parts, and 6 parts of carbon fiber, 6 parts of liquid polyisoprene, graphene oxide is grafted antioxidant MB 5
Part, 3 parts of Sulfur, 1 part of accelerant CZ.
Preferably, the bushing rubber constituent and mass fraction are respectively as follows: 100 parts of natural rubber, and 3 parts of zinc oxide,
2 parts of stearic acid, carbon black N330 has 40 parts, and 10 parts of carbon fiber, 3 parts of liquid polyisoprene, graphene oxide is grafted antioxidant MB 2
Part, 1 part of Sulfur, 3 parts of accelerant CZ.
(3) beneficial effect
Veneer list pin vehicle track pin bush(ing) rubber provided by above-mentioned technical proposal will for making crawler belt pin bush(ing)
It is applied in the armored vehicle of veneer single-pin track, has the function of anti-extrusion damping and resistance to torsion, bears caterpillar drive process
Middle tractive force is delivered in extruding force and twisting resistance on track pin, has the characteristics that anti-extrusion bumper and absorbing shock, can reduce tank
Damage of the vibration stress fatigue to crawler belt in driving process；Bushing has the characteristics that high voltage, anti-torsion simultaneously, bears crawler belt fortune
Twisting resistance when relative torsion occurs for two pieces of creeper treads when moving driving wheel, inducer position is improved and is passed with resistance to twisting action
Double Pressures-torsional shear loss of the twisting resistance and rubber bushing of bushing rubber receiving of uniting, realizes crawler belt and integrally travels function
The optimization of energy, extends the mileage service life of crawler belt, and the crawler belt of tank behavioral system is enabled to better adapt to harsh complicated row
Sail operating condition.
Specific embodiment
To keep the purpose of the present invention, content and advantage clearer, below with reference to embodiment, to specific reality of the invention
The mode of applying is described in further detail.
Veneer list pin vehicle track pin bush(ing) rubber of the present invention is when making veneer list pin vehicle track pin bush(ing), by Gao Mo
Amount rubber layer and bushing parent metal take whole sulfuration process, and high-modulus rubber layer uses the rubber material with high-modulus performance
Material.
Specifically, the ingredient of veneer list pin vehicle track pin bush(ing) rubber and mass fraction are respectively as follows: natural rubber 100
Part, 30~50 parts of carbon black, 4~10 parts of carbon fiber, 2~5 parts of anti-aging agent, 3~6 parts of activating agent, 1~3 part of softening agent, reinforcing agent 3
~8 parts, 1~4 part of vulcanizing agent, 1~4 part of promotor.
Wherein, anti-aging agent is that graphene oxide is grafted antioxidant MB, by the hydroxyl and γ-chloropropyl of surface of graphene oxide
Triethoxysilane carries out the grafting of graphene oxide made from graft reaction and obtains with 2-mercaptobenzimidazole generation graft reaction.
Activating agent uses zinc oxide, and softening agent uses stearic acid, and reinforcing agent uses liquid polyisoprene, and vulcanizing agent uses
Sulfur, promotor use accelerant CZ, and carbon black uses carbon black N330.
The ingredient and quality of two specific veneer list pin vehicle track pin bush(ing) rubber are provided below by Tables 1 and 2
Number example.
Table 1
Table 2
| Composition | Number |
| Natural rubber | 100 |
| Zinc oxide | 3 |
| Stearic acid | 2 |
| Carbon black N330 | 40 |
| Carbon fiber | 10 |
| Liquid polyisoprene | 3 |
| Graphene oxide is grafted antioxidant MB | 2 |
| Sulfur | 1 |
| Accelerant CZ | 3 |
It is detected by being formed by rubber performance to above-mentioned Tables 1 and 2, testing result such as the following table 3.
Table 3
Above-mentioned veneer list pin vehicle track pin bush(ing) rubber, main body constituent material natural rubber have low lag heat, power
Learn the feature that intensity is high, resistance against compression (especially high-intensitive to squeeze) is good, composition material carbon black N330 have the characteristics that it is HR highly reinforcing,
And the high-termal conductivity using carbon fiber, it can effectively reduce the compression fatigue heat of vulcanized rubber.Using liquid polyisoprene
(molecular weight is about 30000) is used as softening agent, can improve dispersion of the fillers such as carbon black in rubber, shortens mixing time, adjusts
The modulus and hardness of vulcanized rubber are saved, while can be to avoid small molecule softening agent (such as machine oil, naphthenic oil) in Heat Ageing
In volatilization, prevent the modulus of vulcanized rubber and hardness when fatigue aging from increasing considerably.By preparing graphene oxide grafting
2-mercaptobenzimidazole (Graphene-g-MB), can obtain it is a kind of acted on efficient reinforcement and anti-aging it is multi-functional
Anti-aging agent has long-acting anti-aging characteristic, effectively prevents small molecule anti-aging agent in Heat Ageing from rubber matrix
It moves out, the heat aging performance of rubber is caused to be decreased obviously.The track pin bushing rubber that the present invention designs has high-modulus, small deformation
Feature, effectively absorb the destruction of tank track vibration in the process of moving, slow down impact stress to the damage of crawler belt and track pin
It is bad.
In the formula of the high-modulus rubber layer of bushing, in reinforced filling and with suitable carbon fiber, sulphur can be significantly improved
The heating conduction for changing glue, reduces the dynamic fatigue heat of vulcanizate.In addition, being grafted antioxidant MB, a side using graphene oxide
Efficient reinforcement is carried out in face of natural rubber, is on the other hand also improved with long-acting anti-aging effect (inhibiting moving out for anti-aging agent)
The mechanical property and ageing-resistant performance of rubber inhibits deformation of the rubber under high-load condition, tank is effectively prevent to travel
Tractive force, which is formed by, in the process squeezes destruction to rubber bushing body, and rubber is made to have preferable wear-resisting, tear-proof and anti-cut
Cut performance.
The present invention further refers to a kind of preparation method of veneer list pin vehicle track pin rubber bushing, including following step
It is rapid:
S1: it is grafted first with the hydroxyl and γ-chloropropyl triethoxysilane (CTS) of surface of graphene oxide, instead
Graphene oxide grafting CTS should be made；Then reaction product is further connect with anti-aging agent 2-mercaptobenzimidazole (MB)
Branch reaction obtains graphene oxide grafting antioxidant MB；
S2: natural rubber is plasticated 1-3min in mixer, and being then added includes activating agent, softening agent, anti-aging agent, benefit
Compounding agent and carbon fiber including strong agent are kneaded 3-5min on mixer, add carbon black filler and are kneaded 9-11min；Then exist
Promotor is added on open mill and Sulfur is kneaded 4-6min, obtains the rubber compound for high-modulus yielding rubber ring, test is kneaded
The sulfurizing time T1 of glue is used for being kneaded vulcanization when gum forming prepares different product；
Wherein, the mass fraction of above-mentioned each ingredient is respectively as follows: 100 parts of natural rubber, and 30~50 parts of carbon black, carbon fiber 4~
10 parts, 2~5 parts of anti-aging agent, 3~6 parts of activating agent, 1~3 part of softening agent, 3~8 parts of reinforcing agent, 1~4 part of Sulfur, promotor 1~
4 parts.
Activating agent uses zinc oxide, and softening agent uses stearic acid, and reinforcing agent uses liquid polyisoprene, and vulcanizing agent uses
Sulfur, promotor use accelerant CZ, and carbon black uses carbon black N330.
S3: the rubber compound progress for being used for track pin rubber bushing yielding rubber ring in right amount is preforming, it has been placed in metal liner
In the sulfurizing mould of set, prevulcanisation time T1-1-3min, then vulcanize 100-130min and track pin rubber bushing is prepared.
Below for preparation method, a specific example is provided.
Embodiment 1:
(1) high-modulus rubber bushing preparation process
5g graphene oxide and 15g γ-chloropropyl triethoxysilane (CTS) are first dispersed in the anhydrous second of 400ml together
In alcohol, 50 DEG C of stirrings for 24 hours, react and graphene oxide grafting CTS are made.Then 0.5g sodium hydroxide (NaOH) is added and 2g is anti-old
Agent 2-mercaptobenzimidazole (MB), nitrogen protection are stirred to react for 24 hours, reaction product are filtered, and are respectively washed with ethyl alcohol and deionized water
It washs 3 times, it is dry, obtain graphene oxide grafting antioxidant MB.
Natural rubber and various compounding agents needed for weighing high-modulus formula 1, plasticate 2 for natural rubber raw rubber in mixer
Minute, zinc oxide, stearic acid, graphene oxide grafting antioxidant MB, liquid polyisoprene and carbon fiber are sequentially added, is kneaded
4 minutes, it is eventually adding carbon black, is kneaded 10 minutes, dumping.After sizing material is cooling, continue to be kneaded with open mill, accelerant CZ is added
And Sulfur, it is kneaded 5 minutes, obtains the rubber compound for being used to prepare high modulus layer carcass rubber, test the sulfurizing time of rubber compound
T1 is used for being kneaded vulcanization when gum forming prepares different product.
Wherein, this process of dumping is used to prepare semi-finished product, in actual needs glue, further vulcanizes.
The rubber compound progress for being used for high-modulus yielding rubber ring in right amount is preforming, it is placed in the sulfurizing mould of metal lining
In, prevulcanisation time T1-2min, then vulcanize 120min and high-modulus yielding rubber ring is prepared.
A small amount of processability index test sample is taken from the rubber compound of above-mentioned formula, other glue stuff compoundings use aforementioned sulphur
Chemical industry skill integrally vulcanizes, and the bushing with the anti-extrusion function of vibration damping is made, is then tested for the property.
(2) performance test
A. compression heating test
On compression heat generation testing machine, compression heat generation performance test is carried out to vulcanization sample referring to GB/T1687-1993 standard.
Prestressing force is set as 2.00 ± 0.06MPa, 30 ± 0.3Hz of compression frequency, constant temperature room temperature is 55 ± 1 DEG C, and preheating time is
30min, sample stroke are selected as 5.71 ± 0.03mm, testing time 25min, the measurable examination of infrared temperature probe on testing machine
The temperature change of sample during the test.
B. durability test is tested
The method referring to as defined in 4.7.3.1 in GJB2628-96 standard carries out the durability test of crawler belt pin bush(ing), test bar
Torsion angle as defined in d is set as ± 13 ° in part, and the test period 200,000 times, acceptable criterion is content specified in standard.
(3) performance test
A. conventional mechanical property is tested
The test sample and test specimen test result prepared in above embodiments meets scheduled technical indicator, and (specific list is mended
It fills)；There are two types of the bushings of different function after carrying out engine bench test for the tool of preparation, does not occur rubber layer and self-lubricating layer surface
Cracking, explosion and delamination, are examined by engine bench test.
As can be seen from the above technical solutions, the outer ring material of bushing of the present invention is high-modulus rubber layer, bears caterpillar drive
Tractive force is delivered in extruding-twisting resistance on track pin in the process, has the characteristics that anti-extrusion bumper and absorbing shock, can reduce tank
Damage of the vibration stress fatigue to crawler belt in driving process；It bears tractive force in crawler belt action and is delivered in squeezing on track pin
The opposite of pin and earhole when relative torsion occurs for two pieces of creeper treads when pressure and caterpillar drive are to driving wheel, inducer position
The twisting resistance of rotation slows down Double Pressures-torsion loss of rubber bushing, realizes the optimization of crawler belt entirety driving functions, prolong
The mileage service life of long crawler belt enables the crawler belt of tank behavioral system to better adapt to harsh complicated driving cycle.It is novel
The production of veneer list pin tank track pin bush(ing), high-modulus rubber layer bushing take the technique integrally vulcanized, guarantee that rubber layer is equal
Even, interface is bonded, is firmly bonded, and is bonded and integrated formed in mould technique in metal lining outer rim heat cure, guarantees uniform, boundary
Face paste is closed, is firmly bonded.Veneer list pin tank track pin bush(ing) prepared by the present invention has the higher mileage travelled service life and resists
The effective protection to crawler belt and track pin is realized in extruding-torque failure ability, is solved current tank veneer list latch structure and is carried out
It is smooth to improving with the earlier period damage problem in high-speed overload driving process in track pin metal to rubber bushing torsion-extrusion process
The military maneuverability of gram equal Armored tracklayers is of great significance.
The above is only a preferred embodiment of the present invention, it is noted that for the ordinary skill people of the art
For member, without departing from the technical principles of the invention, several improvement and deformations can also be made, these improvement and deformations
Also it should be regarded as protection scope of the present invention.
Claims (10)
1. a kind of veneer list pin vehicle track pin bush(ing) rubber, which is characterized in that constituent and mass fraction are respectively as follows: naturally
100 parts of rubber, 30~50 parts of carbon black, 4~10 parts of carbon fiber, 2~5 parts of anti-aging agent, 3~6 parts of activating agent, 1~3 part of softening agent,
3~8 parts of reinforcing agent, 1~4 part of vulcanizing agent, 1~4 part of promotor.
2. veneer list pin vehicle track pin bush(ing) rubber as described in claim 1, which is characterized in that the anti-aging agent is oxidation
Graphene is grafted antioxidant MB, carries out graft reaction by hydroxyl and γ-chloropropyl triethoxysilane of surface of graphene oxide
Graphene oxide grafting obtained occurs graft reaction with 2-mercaptobenzimidazole and obtains.
3. veneer list pin vehicle track pin bush(ing) rubber as claimed in claim 2, which is characterized in that the activating agent uses oxygen
Change zinc.
4. veneer list pin vehicle track pin bush(ing) rubber as claimed in claim 3, which is characterized in that the softening agent is using hard
Resin acid.
5. veneer list pin vehicle track pin bush(ing) rubber as claimed in claim 4, which is characterized in that the reinforcing agent uses liquid
Body polyisoprene.
6. veneer list pin vehicle track pin bush(ing) rubber as claimed in claim 5, which is characterized in that the vulcanizing agent uses sulphur
It is yellow.
7. veneer list pin vehicle track pin bush(ing) rubber as claimed in claim 6, which is characterized in that the promotor is using rush
Into agent CZ.
8. veneer list pin vehicle track pin bush(ing) rubber as claimed in claim 7, which is characterized in that the carbon black uses carbon black
N330。
9. veneer list pin vehicle track pin bush(ing) rubber as claimed in claim 8, which is characterized in that the bushing rubber composition
Ingredient and mass fraction are respectively as follows: 100 parts of natural rubber, and 5 parts of zinc oxide, 1 part of stearic acid, carbon black N330 has 50 parts, carbon fiber 6
Part, 6 parts of liquid polyisoprene, graphene oxide is grafted 5 parts of antioxidant MB, 3 parts of Sulfur, 1 part of accelerant CZ.
10. veneer list pin vehicle track pin bush(ing) rubber as claimed in claim 8, which is characterized in that the bushing rubber group
It is respectively as follows: 100 parts of natural rubber at ingredient and mass fraction, 3 parts of zinc oxide, 2 parts of stearic acid, carbon black N330 there are 40 parts, carbon fiber
10 parts of dimension, 3 parts of liquid polyisoprene, graphene oxide is grafted 2 parts of antioxidant MB, 1 part of Sulfur, 3 parts of accelerant CZ.
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| CN113308029A (en) * | 2020-12-08 | 2021-08-27 | 湖北鲁鸣精密科技有限公司 | High-tensile-strength natural odor-resistant rubber and preparation method thereof |
| CN115093622A (en) * | 2022-08-19 | 2022-09-23 | 保定三源橡胶有限公司 | Anti-aging anti-ultraviolet rubber material and preparation method thereof |
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| CN110117390B (en) * | 2019-05-23 | 2021-08-10 | 河北科技大学 | Graphene oxide modified anti-aging agent, thermal-oxidative-aging-resistant rubber containing graphene oxide modified anti-aging agent and preparation method of thermal-oxidative-aging-resistant rubber |
| CN111484654A (en) * | 2020-05-11 | 2020-08-04 | 徐工集团工程机械有限公司 | Heat conduction rubber material and rubber track |
| CN113308029A (en) * | 2020-12-08 | 2021-08-27 | 湖北鲁鸣精密科技有限公司 | High-tensile-strength natural odor-resistant rubber and preparation method thereof |
| CN115093622A (en) * | 2022-08-19 | 2022-09-23 | 保定三源橡胶有限公司 | Anti-aging anti-ultraviolet rubber material and preparation method thereof |
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Application publication date: 20190426 |
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