CN109667153A - 一种织物用阻燃涂料及应用该阻燃涂料的阻燃布料 - Google Patents
一种织物用阻燃涂料及应用该阻燃涂料的阻燃布料 Download PDFInfo
- Publication number
- CN109667153A CN109667153A CN201811369041.2A CN201811369041A CN109667153A CN 109667153 A CN109667153 A CN 109667153A CN 201811369041 A CN201811369041 A CN 201811369041A CN 109667153 A CN109667153 A CN 109667153A
- Authority
- CN
- China
- Prior art keywords
- parts
- flaming dope
- cloth
- fabric
- flame retardant
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000004744 fabric Substances 0.000 title claims abstract description 108
- 239000003063 flame retardant Substances 0.000 title claims abstract description 50
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 title claims abstract description 36
- 229920002050 silicone resin Polymers 0.000 claims abstract description 28
- -1 Methyl Hydrogen Chemical compound 0.000 claims abstract description 24
- 229910000000 metal hydroxide Inorganic materials 0.000 claims abstract description 17
- 150000004692 metal hydroxides Chemical class 0.000 claims abstract description 17
- 229920001223 polyethylene glycol Polymers 0.000 claims abstract description 17
- 239000002202 Polyethylene glycol Substances 0.000 claims abstract description 16
- YGCOKJWKWLYHTG-UHFFFAOYSA-N [[4,6-bis[bis(hydroxymethyl)amino]-1,3,5-triazin-2-yl]-(hydroxymethyl)amino]methanol Chemical compound OCN(CO)C1=NC(N(CO)CO)=NC(N(CO)CO)=N1 YGCOKJWKWLYHTG-UHFFFAOYSA-N 0.000 claims abstract description 16
- 229940051841 polyoxyethylene ether Drugs 0.000 claims abstract description 16
- 229920000056 polyoxyethylene ether Polymers 0.000 claims abstract description 16
- 239000000835 fiber Substances 0.000 claims abstract description 15
- 239000001257 hydrogen Substances 0.000 claims abstract description 15
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 15
- 229920000742 Cotton Polymers 0.000 claims abstract description 14
- 150000002191 fatty alcohols Chemical class 0.000 claims abstract description 14
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 claims abstract description 12
- 229920001296 polysiloxane Polymers 0.000 claims abstract description 12
- 229920005573 silicon-containing polymer Polymers 0.000 claims abstract description 12
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims abstract description 11
- 239000012530 fluid Substances 0.000 claims abstract description 11
- 229910052710 silicon Inorganic materials 0.000 claims abstract description 11
- 239000010703 silicon Substances 0.000 claims abstract description 11
- 239000002994 raw material Substances 0.000 claims abstract description 10
- 239000004952 Polyamide Substances 0.000 claims abstract description 9
- 229920002647 polyamide Polymers 0.000 claims abstract description 9
- 239000000203 mixture Substances 0.000 claims abstract description 8
- 229920004933 Terylene® Polymers 0.000 claims abstract description 3
- 239000005020 polyethylene terephthalate Substances 0.000 claims abstract description 3
- 239000011248 coating agent Substances 0.000 claims description 13
- 238000000576 coating method Methods 0.000 claims description 13
- 238000001035 drying Methods 0.000 claims description 11
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims description 10
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 claims description 8
- 239000000347 magnesium hydroxide Substances 0.000 claims description 8
- 229910001862 magnesium hydroxide Inorganic materials 0.000 claims description 8
- 238000010792 warming Methods 0.000 claims description 5
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 claims description 4
- 229910021502 aluminium hydroxide Inorganic materials 0.000 claims description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 2
- 239000004593 Epoxy Substances 0.000 claims 1
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 claims 1
- 229910021505 gold(III) hydroxide Inorganic materials 0.000 claims 1
- WDZVNNYQBQRJRX-UHFFFAOYSA-K gold(iii) hydroxide Chemical compound O[Au](O)O WDZVNNYQBQRJRX-UHFFFAOYSA-K 0.000 claims 1
- 150000002576 ketones Chemical class 0.000 claims 1
- 229920005989 resin Polymers 0.000 claims 1
- 239000011347 resin Substances 0.000 claims 1
- 239000000463 material Substances 0.000 abstract description 21
- 239000004753 textile Substances 0.000 abstract description 7
- 238000012545 processing Methods 0.000 abstract description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 14
- 239000001301 oxygen Substances 0.000 description 14
- 229910052760 oxygen Inorganic materials 0.000 description 14
- 230000000052 comparative effect Effects 0.000 description 13
- 239000003795 chemical substances by application Substances 0.000 description 8
- 230000000694 effects Effects 0.000 description 8
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 7
- 241000219146 Gossypium Species 0.000 description 7
- 238000000034 method Methods 0.000 description 7
- 238000012986 modification Methods 0.000 description 6
- 230000004048 modification Effects 0.000 description 6
- 239000010410 layer Substances 0.000 description 5
- 239000000314 lubricant Substances 0.000 description 5
- 239000000243 solution Substances 0.000 description 5
- 239000004902 Softening Agent Substances 0.000 description 4
- MCWXGJITAZMZEV-UHFFFAOYSA-N dimethoate Chemical compound CNC(=O)CSP(=S)(OC)OC MCWXGJITAZMZEV-UHFFFAOYSA-N 0.000 description 4
- 229920002545 silicone oil Polymers 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- 239000007789 gas Substances 0.000 description 3
- 150000002431 hydrogen Chemical class 0.000 description 3
- 230000035699 permeability Effects 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 240000000047 Gossypium barbadense Species 0.000 description 2
- 235000009429 Gossypium barbadense Nutrition 0.000 description 2
- 230000006750 UV protection Effects 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 229920006231 aramid fiber Polymers 0.000 description 2
- 239000012752 auxiliary agent Substances 0.000 description 2
- 230000000740 bleeding effect Effects 0.000 description 2
- 150000001768 cations Chemical class 0.000 description 2
- 238000002485 combustion reaction Methods 0.000 description 2
- 239000003995 emulsifying agent Substances 0.000 description 2
- 238000004079 fireproofing Methods 0.000 description 2
- 239000003230 hygroscopic agent Substances 0.000 description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
- 238000010422 painting Methods 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 238000011056 performance test Methods 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 230000004224 protection Effects 0.000 description 2
- 239000002689 soil Substances 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 230000009967 tasteless effect Effects 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 238000009941 weaving Methods 0.000 description 2
- FHVDTGUDJYJELY-UHFFFAOYSA-N 6-{[2-carboxy-4,5-dihydroxy-6-(phosphanyloxy)oxan-3-yl]oxy}-4,5-dihydroxy-3-phosphanyloxane-2-carboxylic acid Chemical compound O1C(C(O)=O)C(P)C(O)C(O)C1OC1C(C(O)=O)OC(OP)C(O)C1O FHVDTGUDJYJELY-UHFFFAOYSA-N 0.000 description 1
- 241001474374 Blennius Species 0.000 description 1
- XZMCDFZZKTWFGF-UHFFFAOYSA-N Cyanamide Chemical compound NC#N XZMCDFZZKTWFGF-UHFFFAOYSA-N 0.000 description 1
- 206010021143 Hypoxia Diseases 0.000 description 1
- 229920000877 Melamine resin Polymers 0.000 description 1
- AFCARXCZXQIEQB-UHFFFAOYSA-N N-[3-oxo-3-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)propyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(CCNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 AFCARXCZXQIEQB-UHFFFAOYSA-N 0.000 description 1
- 229910007161 Si(CH3)3 Inorganic materials 0.000 description 1
- OLBVUFHMDRJKTK-UHFFFAOYSA-N [N].[O] Chemical compound [N].[O] OLBVUFHMDRJKTK-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 230000003213 activating effect Effects 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 229940072056 alginate Drugs 0.000 description 1
- 229920000615 alginic acid Polymers 0.000 description 1
- 235000010443 alginic acid Nutrition 0.000 description 1
- OJMOMXZKOWKUTA-UHFFFAOYSA-N aluminum;borate Chemical compound [Al+3].[O-]B([O-])[O-] OJMOMXZKOWKUTA-UHFFFAOYSA-N 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 1
- 239000004327 boric acid Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000013065 commercial product Substances 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- 229940008099 dimethicone Drugs 0.000 description 1
- 239000004205 dimethyl polysiloxane Substances 0.000 description 1
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 239000004519 grease Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
- 208000018875 hypoxemia Diseases 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 230000001535 kindling effect Effects 0.000 description 1
- 239000004816 latex Substances 0.000 description 1
- 229920000126 latex Polymers 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- OKKJLVBELUTLKV-UHFFFAOYSA-N methanol Natural products OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 238000011017 operating method Methods 0.000 description 1
- 125000006353 oxyethylene group Chemical group 0.000 description 1
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 235000019353 potassium silicate Nutrition 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 230000000979 retarding effect Effects 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-N sulfuric acid Substances OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 1
- 239000002344 surface layer Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 238000005829 trimerization reaction Methods 0.000 description 1
- BIKXLKXABVUSMH-UHFFFAOYSA-N trizinc;diborate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]B([O-])[O-].[O-]B([O-])[O-] BIKXLKXABVUSMH-UHFFFAOYSA-N 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/643—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/44—Oxides or hydroxides of elements of Groups 2 or 12 of the Periodic Table; Zincates; Cadmates
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/45—Oxides or hydroxides of elements of Groups 3 or 13 of the Periodic Table; Aluminates
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/35—Heterocyclic compounds
- D06M13/355—Heterocyclic compounds having six-membered heterocyclic rings
- D06M13/358—Triazines
- D06M13/364—Cyanuric acid; Isocyanuric acid; Derivatives thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/368—Hydroxyalkylamines; Derivatives thereof, e.g. Kritchevsky bases
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/53—Polyethers
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M2101/34—Polyamides
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/30—Flame or heat resistance, fire retardancy properties
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
本发明涉及纺织材料的技术领域，具体涉及一种织物用阻燃涂料，包括如下重量份数的原料：硅酮树脂30‑60份、金属氢氧化物5‑10份、六羟甲基三聚氰胺5‑15份、聚乙二醇10‑20份和脂肪醇聚氧乙烯醚1‑5份，所述硅酮树脂由聚二甲基硅氧烷与甲基含氢硅油按照硅质量含量比为3:1‑8:1的配比聚合而成；从而使本发明的阻燃涂料适合贴身衣物或日常所穿棉质或较柔软衣物布料的处理，应用范围和适用性更强；还涉及一种应用该阻燃涂料的阻燃布料，所述布料选自棉、涤纶、锦纶或涤棉混纺；使布料在使用该阻燃涂料后，保持原有舒适度和柔软度的基础上，提高了布料的阻燃性能。
Description
技术领域
本发明涉及纺织材料的技术领域，具体涉及一种织物用阻燃涂料及应用该阻燃涂料的阻燃布料。
背景技术
纤维织物经纺织而成，由于其成分组成的缘故，大多都易燃，即使碰到些许的火星，也容易着火，或者部分烧坏，轻则表面受损，重则烧出孔洞等，这严重影响了其使用效果，如果抗阻燃性不好，织物的使用会受到很大的局限性。
为了提高织物或布料的阻燃性能，现有技术中出现了很多防火阻燃布料以及防火服。在专利CN105220314B中，公开了一种耐320～340℃的耐火布及其制备方法，属于纺织材料与防火技术领域。经纱组成为：(按质量百分比)聚磷酰胺纤维30～70％，芳纶纤维30～70％，纬纱组成为：长绒棉1～30％，聚磷酰胺纤维29～70％，海藻纤维29～70％；该申请中用聚磷酰胺纤维和芳纶纤维混纺成经纱纱线；用长绒棉、聚磷酰胺纤维和海藻纤维混纺成纬纱纱线；将经纱与纬纱结合，采用交错织法，织成具有一定密度的耐火布；其采用结构强度较大的纤维交错相织得到的布料硬度较大，柔软性能欠佳，不适于制作贴身衣物或日常所穿棉质或较柔软的衣物。
在专利CN105734958A中，公开了一种防火布料的制造方法，包括以下步骤：（1）取硼酸、硼酸锌和硼酸铝溶解于水中配制溶液，将编织好的布料放在配置好的溶液中，浸泡15小时以上，每隔5个小时，翻动，用刷子在布料表面来回刷动布料；（2）将所得的布料在温度大于40℃的环境中晾干；（3）将步骤（2）所得的布料，在密闭的环境中，浸泡在纯丙烯酸乳液中，浸泡12个小时，并取出，在温度不大于25℃的环境中，用风速不大于5.5m/s的风，将其吹干；（4）将步骤（1）所得的面料浸没到水玻璃溶液中，浸泡1.5个小时，取出后，平整地铺开，三层叠合，用挤压辊挤压定型，并在微风中，直到面料干燥。此方法通过对布料进行三次浸泡处理来提高其防火性能，对织物自身原有的性能如强度、色牢度等影响较大，控制不当可能会使织物手感发硬，从而会影响到布料的质感和质量。
发明内容
针对现有技术存在的不足，本发明的第一个目的在于提供一种适合贴身衣物或日常所穿棉质或较柔软衣物布料的织物用阻燃涂料。
本发明的第一个目的通过以下技术方案来实现：
一种织物用阻燃涂料，包括如下重量份数的原料：硅酮树脂30-60份、金属氢氧化物5-10份、六羟甲基三聚氰胺5-15份、聚乙二醇10-20份和脂肪醇聚氧乙烯醚1-5份，所述硅酮树脂由聚二甲基硅氧烷与甲基含氢硅油按照硅质量含量比为3:1-8:1的配比聚合而成。
通过采用上述技术方案，聚二甲基硅氧烷也称为二甲基硅油，无色或浅黄色液体，无味，透明度高，具有耐热性、耐寒性、黏度随温度变化小、防水性、表面张力小等优点。二甲基硅油无毒无味，具有生理惰性及良好的化学稳定性，其电绝缘性、耐候性、疏水性好，并具有很高的抗剪切能力，可在-50℃～200℃下长期使用。甲基含氢硅油俗称含氢硅油，其分子式为:(CH3)3SiO[(CH3)(H)SiO]nSi(CH3)3，将甲基含氢硅油与线形的聚二甲基硅氧烷聚合得到网状的硅酮树脂，既能保持织物原来的透气性和柔软性，又能提高织物的撕裂强度、磨擦强度和防污性，且具有较为优良的防紫外功能。六羟甲基三聚氰胺，在不带酸性的水溶液中可保持数天稳定，它可与阳离子及非离子型的柔软剂和渗透剂共用。金属氢氧化物起到主要阻燃的作用，但是需要配合本发明中的六羟甲基三聚氰胺才可以充分发挥其在阻燃涂料中的阻燃作用，然后将网状的硅酮树脂与金属氢氧化物聚合改性，辅助以乳化匀染剂脂肪醇聚氧乙烯醚，抗静电润滑剂聚乙二醇，相互之间协同作用，形成具有较好阻燃效果并且适用于柔软或绵软布料的阻燃涂料，从而可以应用于贴身衣物或日常所穿棉质或较柔软衣物布料的阻燃处理中。
作为优选，包括如下重量份数的原料：硅酮树脂40-50份、金属氢氧化物6-8份、六羟甲基三聚氰胺8-12份、聚乙二醇12-16份和脂肪醇聚氧乙烯醚2-4份，所述硅酮树脂由聚二甲基硅氧烷与甲基含氢硅油按照硅质量含量比为5:1-7:1的配比聚合而成。
作为优选，所述脂肪醇聚氧乙烯醚中环氧乙烷的加成数为11-16。
通过采用上述技术方案，脂肪醇聚氧乙烯醚，RO（CH2CH2O）nH，R一般为饱和的或不饱和的C12~18的烃基，是直链烃基，也可以是带支链的烃基；n是环氧乙烷的加成数，也就是表面活性剂分子中氧乙烯基的数目。n越大，分子亲水基上的氧越多，与水就能形成更多的氢键，水溶性就越好。n=1~5时，产物能溶于油而不溶于水，常做为制备硫酸酯类阴离子表面活性剂的原料。n=6~8时，能溶于水，常用作纺织品的洗涤剂和油脂乳化剂。n=10~20时，常用作乳化剂和匀染剂。经过大量实验证明，本发明中在n=11~16时配合其他原料，处理后的布料色泽最佳。
作为优选，所述聚乙二醇的平均分子量为4000-6000。
通过采用上述技术方案，聚乙二醇，简称PEG，PEG-4000、6000在纺织工业中用作抗静电剂、润滑剂等，应用于本发明的阻燃涂料中，起到一定的润湿性能，使硅酮树脂与金属氢氧化物之间更容易相互渗透改性，提高阻燃涂料的整体阻燃透气透湿的性能。
作为优选，所述金属氢氧化物为氢氧化镁或氢氧化铝。
作为优选，所述金属氢氧化物的平均粒径为1-10μm。
通过采用上述技术方案，保证阻燃物质发挥作用的同时，降低阻燃物质颗粒，降低对布料柔软性能的影响，从而避免因使用该阻燃涂料而导致衣物的硬度增加，舒适度下降的问题出现。
作为优选，还包括三乙醇胺5-15份。
通过采用上述技术方案，三乙醇胺，用于纺织工业中是良好的溶剂，吸湿剂，是织物柔软剂的原料。添加适量的三乙醇胺可以进一步的改善被处理布料的柔软性，从而提高舒适度。
本发明的第二个目的是提供一种应用上述织物用阻燃涂料加工得到的阻燃布料，使布料在使用该阻燃涂料后，保持原有舒适度和柔软度的基础上，提高布料的阻燃性能。
本发明的第二个目的通过以下技术方案来实现：
一种织物用阻燃涂料加工得到的阻燃布料，所述布料选自棉、涤纶、锦纶或涤棉混纺。
作为优选，其通过如下步骤处理得到：
（1）将待处理布料的双面均涂布绝缘层，烘干得到布料初胚；
（2）将上述布料初胚的双面均涂布所述阻燃涂料，涂布厚度为1-2mm，烘干后即得阻燃布料。
作为优选，所述步骤（1）中，于80-95℃下烘干20-40min；所述步骤（2）中，先于100℃下烘干1-3min，再升温至180-195℃下烘干3-5min。
通过采用上述技术方案，将绵软布料的表层涂布绝缘层后，涂布本发明的阻燃涂料，烘干即可。并且控制烘干的温度和时间，尤其是涂布阻燃涂料后的烘干时间较短，烘干温度相对较高，使阻燃涂料被“闪烘”并牢固的涂布在布料上，不会对布料自身的硬度等性能产生不利的影响，保证布料的绵软舒适度。
综上所述，本发明具有如下有益效果：
（1）将硅酮树脂与阻燃材料复配得到阻燃涂料，兼具硅酮树脂的透气透湿性和阻燃材料的阻燃性能，并且辅助其他助剂，使本发明的阻燃涂料适用于绵软布料，从而适合日常衣物布料的加工处理，扩大了应用范围；
（2）将本发明的阻燃涂料直接按照涂布的方式对待处理布料进行加工处理，得到具有阻燃性能的阻燃布料，极限氧指数最高达到39.9%，在保证布料自身柔软度等性能不被影响的同时，提高了布料的阻燃性能。
具体实施方式
本发明中所用各助剂及原料均为市售产品。本发明中的阻燃涂料可以用于棉、涤纶、锦纶或涤棉混纺的布料阻燃加工处理中，具体加工方法相同，下面以锦纶布料为例进行说明。
实施例1
将硅酮树脂60g、平均粒径为5μm的氢氧化镁10g、六羟甲基三聚氰胺10g、平均分子量为4000的聚乙二醇10g和环氧乙烷的加成数为11的脂肪醇聚氧乙烯醚5g充分搅拌混合，得到实施例1的阻燃涂料。其中，硅酮树脂由聚二甲基硅氧烷与甲基含氢硅油按照硅质量含量比为3:1的配比聚合而成，聚合方法与操作步骤为硅酮树脂聚合的常规技术手段，在此不再赘述。
实施例2
实施例2与实施例1的区别在于：实施例2中的阻燃涂料为硅酮树脂50g、平均粒径为10μm的氢氧化铝8g、六羟甲基三聚氰胺12g、平均分子量为4000的聚乙二醇16g和环氧乙烷的加成数为16的脂肪醇聚氧乙烯醚4g充分搅拌混合而得。其中，硅酮树脂由聚二甲基硅氧烷与甲基含氢硅油按照硅质量含量比为7:1的配比聚合而成。
实施例3
实施例3与实施例1的区别在于：实施例3中的阻燃涂料为硅酮树脂40g、平均粒径为1μm的氢氧化镁6g、六羟甲基三聚氰胺8g、平均分子量为4000的聚乙二醇12g和环氧乙烷的加成数为14的脂肪醇聚氧乙烯醚2g充分搅拌混合而得。其中，硅酮树脂由聚二甲基硅氧烷与甲基含氢硅油按照硅质量含量比为5:1的配比聚合而成。
实施例4
实施例4与实施例1的区别在于：实施例4中的阻燃涂料为硅酮树脂30g、平均粒径为5μm的氢氧化镁5g、六羟甲基三聚氰胺5g、平均分子量为4000的聚乙二醇20g和环氧乙烷的加成数为13的脂肪醇聚氧乙烯醚1g充分搅拌混合而得。其中，硅酮树脂由聚二甲基硅氧烷与甲基含氢硅油按照硅质量含量比为8:1的配比聚合而成。
实施例5
实施例5与实施例1的区别在于：实施例5中的阻燃涂料为硅酮树脂45g、平均粒径为5μm的氢氧化镁8g、六羟甲基三聚氰胺15g、平均分子量为4000的聚乙二醇15g和环氧乙烷的加成数为14的脂肪醇聚氧乙烯醚3g充分搅拌混合而得。其中，硅酮树脂由聚二甲基硅氧烷与甲基含氢硅油按照硅质量含量比为6:1的配比聚合而成。
实施例6
实施例6与实施例5的区别在于：实施例6中的阻燃涂料中还加入了5g的三乙醇胺。
实施例7
实施例7与实施例5的区别在于：实施例7中的阻燃涂料中还加入了10g的三乙醇胺。
实施例8
实施例8与实施例5的区别在于：实施例8中的阻燃涂料中还加入了15g的三乙醇胺。
本发明制备的阻燃涂料的应用例
应用例1
将长宽均为5m的锦纶布料的双面涂布绝缘层，于80℃下烘干40min，然后再双面涂布实施例7的阻燃涂料，涂布厚度为1-2mm，涂布均匀后，先于100℃下烘干3min，再升温至180℃下烘干5min，得应用例1的阻燃布料。
应用例2
应用例2与应用例1的区别在于：应用例2中将长宽均为5m的锦纶布料的双面涂布绝缘层，于90℃下烘干20min，然后再双面涂布实施例7的阻燃涂料，涂布厚度为1-2mm，涂布均匀后，先于100℃下烘干1min，再升温至195℃下烘干3min，得应用例2的阻燃布料。
应用例3
应用例3与应用例1的区别在于：应用例3中将长宽均为5m的锦纶布料的双面涂布绝缘层，于95℃下烘干30min，然后再双面涂布实施例7的阻燃涂料，涂布厚度为1-2mm，涂布均匀后，先于100℃下烘干2min，再升温至190℃下烘干2min，得应用例3的阻燃布料。
应用例4-10
应用例4-10为用应用例2的方法依次将实施例1-6及实施例8的阻燃涂料涂布在锦纶布料上得到的应用例4-10的阻燃布料。
对比例1
对比例1与应用例2的区别在于：阻燃布料中未添加六羟甲基三聚氰胺。
对比例2
对比例2与应用例2的区别在于：阻燃涂料涂布均匀后，于100℃下烘干5min，得对比例2的阻燃布料。
对比例3
对比例3与应用例2的区别在于：阻燃涂料中无氢氧化镁，其余与应用例2相同。
空白组
空白组与应用例2的区别在于：布料双面未涂布任何阻燃涂料，其余与应用例2相同。
性能测试
按照GB/T 5454-1997的方法对应用例1-10和对比例1-2的阻燃布料进行阻燃性能测试；观察各个布料的色泽情况以及水洗50次后的色泽变化；并检测手感程度，测试结果见表1所示。其中，极限氧指数是指聚合物在氧和氮混合气体中当刚能支撑其燃烧时氧的体积分数浓度。是表征材料燃烧行为的指数。通常认为极限氧指数为22时，该物质可以在空气中燃烧。极限氧指数是指在规定的条件下，材料在氧氮混合气流中进行有焰燃烧所需的最低氧浓度。以氧所占的体积百分数的数值来表示。氧指数高表示材料不易燃烧，氧指数低表示材料容易燃烧，一般认为氧指数<22%属于易燃材料，氧指数在22%-27%之间属可燃材料，氧指数>27%属难燃材料。
表1 各阻燃布料的性能测试结果
由表1的结果可知，经过本发明的阻燃涂料处理后的布料，其均具有优良的阻燃性能，使其由易燃材料转变为了难燃材料，且极限氧指数最高达到39.9%，使绵软布料的阻燃性能得到了很大的改善。由空白组与应用例1-3以及应用例9和10的结果对比可知，本发明的阻燃涂料中添加有三乙醇胺后，对布料的手感得到了进一步的改善，使布料更加顺滑，细腻。
由对比例1的检测结果可知，本发明中六羟甲基三聚氰胺对阻燃涂料的阻燃性能有较大的影响，若无六羟甲基三聚氰胺则布料的阻燃性能大大降低，且由难燃变为可燃。并且结合对比例3可知，金属氢氧化物起到主要阻燃的作用，若无金属氢氧化物即本发明实施例中的氢氧化镁和氢氧化铝的存在，则所得的布料的阻燃性能大大降低，由难燃变为易燃。由对比例1结合对比例3证明，本发明中的金属氢氧化物需要配合本发明中的六羟甲基三聚氰胺才可以充分发挥其在阻燃涂料中的阻燃作用，然后将网状的硅酮树脂与金属氢氧化物聚合改性，辅助以乳化匀染剂脂肪醇聚氧乙烯醚，抗静电润滑剂聚乙二醇，相互之间协同作用，形成具有较好阻燃效果并且适用于柔软或绵软布料的阻燃涂料，从而可以应用于贴身衣物或日常所穿棉质或较柔软衣物布料的阻燃处理中。
本发明中，将甲基含氢硅油与线形的聚二甲基硅氧烷聚合得到网状的硅酮树脂，既能保持织物原来的透气性和柔软性，又能提高织物的撕裂强度、磨擦强度和防污性，且具有较为优良的防紫外功能。六羟甲基三聚氰胺，在不带酸性的水溶液中可保持数天稳定，它可与阳离子及非离子型的柔软剂和渗透剂共用。金属氢氧化物起到主要阻燃的作用，但是需要配合本发明中的六羟甲基三聚氰胺才可以充分发挥其在阻燃涂料中的阻燃作用，然后将网状的硅酮树脂与金属氢氧化物聚合改性，辅助以乳化匀染剂脂肪醇聚氧乙烯醚，抗静电润滑剂聚乙二醇，相互之间协同作用，形成具有较好阻燃效果并且适用于柔软或绵软布料的阻燃涂料，从而可以应用于贴身衣物或日常所穿棉质或较柔软衣物布料的阻燃处理中。此外，PEG-4000、6000在纺织工业中用作抗静电剂、润滑剂等，应用于本发明的阻燃涂料中，起到一定的润湿性能，使硅酮树脂与金属氢氧化物之间更容易相互渗透改性，提高阻燃涂料的整体阻燃透气透湿的性能。三乙醇胺，用于纺织工业中是良好的溶剂，吸湿剂，是织物柔软剂的原料。本发明中添加适量的三乙醇胺，可以进一步的改善被处理布料的柔软性，从而提高舒适度。
本具体实施例仅仅是对本发明的解释，其并不是对本发明的限制，本领域技术人员在阅读完本说明书后可以根据需要对本实施例做出没有创造性贡献的修改，但只要在本发明的权利要求范围内都受到专利法的保护。
Claims (10)
1.一种织物用阻燃涂料，其特征在于，包括如下重量份数的原料：硅酮树脂30-60份、金属氢氧化物5-10份、六羟甲基三聚氰胺5-15份、聚乙二醇10-20份和脂肪醇聚氧乙烯醚1-5份，所述硅酮树脂由聚二甲基硅氧烷与甲基含氢硅油按照硅质量含量比为3:1-8:1的配比聚合而成。
2.根据权利要求1所述的织物用阻燃涂料，其特征在于，包括如下重量份数的原料：硅酮树脂40-50份、金属氢氧化物6-8份、六羟甲基三聚氰胺8-12份、聚乙二醇12-16份和脂肪醇聚氧乙烯醚2-4份，所述硅酮树脂由聚二甲基硅氧烷与甲基含氢硅油按照硅质量含量比为5:1-7:1的配比聚合而成。
3.根据权利要求1所述的织物用阻燃涂料，其特征在于：所述脂肪醇聚氧乙烯醚中环氧乙烷的加成数为11-16。
4.根据权利要求1所述的织物用阻燃涂料，其特征在于：所述聚乙二醇的平均分子量为4000-6000。
5.根据权利要求1所述的织物用阻燃涂料，其特征在于：所述金属氢氧化物为氢氧化镁或氢氧化铝。
6.根据权利要求1所述的织物用阻燃涂料，其特征在于：所述金属氢氧化物的平均粒径为1-10μm。
7.根据权利要求1所述的织物用阻燃涂料，其特征在于：还包括三乙醇胺5-15份。
8.一种用权利要求1-7任一项所述的织物用阻燃涂料加工得到的阻燃布料，其特征在于：所述布料选自棉、涤纶、锦纶或涤棉混纺。
9.根据权利要求8所述的阻燃布料，其特征在于，其通过如下步骤处理得到：
（1）将待处理布料的双面均涂布绝缘层，烘干得到布料初胚；
（2）将上述布料初胚的双面均涂布所述阻燃涂料，涂布厚度为1-2mm，烘干后即得阻燃布料。
10.根据权利要求9所述的阻燃布料，其特征在于：所述步骤（1）中，于80-95℃下烘干20-40min；所述步骤（2）中，先于100℃下烘干1-3min，再升温至180-195℃下烘干3-5min。
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811369041.2A CN109667153A (zh) | 2018-11-16 | 2018-11-16 | 一种织物用阻燃涂料及应用该阻燃涂料的阻燃布料 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811369041.2A CN109667153A (zh) | 2018-11-16 | 2018-11-16 | 一种织物用阻燃涂料及应用该阻燃涂料的阻燃布料 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN109667153A true CN109667153A (zh) | 2019-04-23 |
Family
ID=66142741
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201811369041.2A Pending CN109667153A (zh) | 2018-11-16 | 2018-11-16 | 一种织物用阻燃涂料及应用该阻燃涂料的阻燃布料 |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN109667153A (zh) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113308878A (zh) * | 2021-06-24 | 2021-08-27 | 天津市花儿正红仿真花卉有限公司 | 一种经防火处理的布艺阻燃花的制备方法 |
| CN118124219A (zh) * | 2024-05-08 | 2024-06-04 | 晋江市金灿纺织有限公司 | 一种抗拉伸防断裂织带 |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20090258182A1 (en) * | 2005-07-08 | 2009-10-15 | Daikyo Chemical Co., Ltd., | Artificial sueded leather being excellent in flame retardance and method of producing the same |
| CN103225215A (zh) * | 2013-04-28 | 2013-07-31 | 百利合化工（中山）有限公司 | 一种环保阻燃型纺织印花涂料及其制备方法 |
| CN103321052A (zh) * | 2012-03-23 | 2013-09-25 | 东丽纤维研究所（中国）有限公司 | 安全气囊用涂层织物及其生产方法 |
| CN103835131A (zh) * | 2012-11-24 | 2014-06-04 | 无锡市银泰纺织品有限公司 | 一种阻燃纺织品的生产工艺 |
-
2018
- 2018-11-16 CN CN201811369041.2A patent/CN109667153A/zh active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20090258182A1 (en) * | 2005-07-08 | 2009-10-15 | Daikyo Chemical Co., Ltd., | Artificial sueded leather being excellent in flame retardance and method of producing the same |
| CN103321052A (zh) * | 2012-03-23 | 2013-09-25 | 东丽纤维研究所（中国）有限公司 | 安全气囊用涂层织物及其生产方法 |
| CN103835131A (zh) * | 2012-11-24 | 2014-06-04 | 无锡市银泰纺织品有限公司 | 一种阻燃纺织品的生产工艺 |
| CN103225215A (zh) * | 2013-04-28 | 2013-07-31 | 百利合化工（中山）有限公司 | 一种环保阻燃型纺织印花涂料及其制备方法 |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113308878A (zh) * | 2021-06-24 | 2021-08-27 | 天津市花儿正红仿真花卉有限公司 | 一种经防火处理的布艺阻燃花的制备方法 |
| CN118124219A (zh) * | 2024-05-08 | 2024-06-04 | 晋江市金灿纺织有限公司 | 一种抗拉伸防断裂织带 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| DE60026043T2 (de) | Copolymere und diese enthaltende öl- und wasserabweisende zusammensetzungen | |
| JP5596081B2 (ja) | 伸縮性コーティング布帛及びその製造方法 | |
| WO1993015254A1 (en) | Treatment agent for fiber product, method of treating fiber product, and fiber product treated thereby | |
| CN109667153A (zh) | 一种织物用阻燃涂料及应用该阻燃涂料的阻燃布料 | |
| US4576840A (en) | Pile fabric having shrunken pile and non-shrinkable pile | |
| US5602225A (en) | Process for imparting oil- and water-repellency to textile fibres, skin, leather and the like | |
| US6511929B1 (en) | Method of improving washfastness of metallized fabric | |
| US3323944A (en) | Process and composition for improving the mechanical properties of flameproofed cellulosic textile materials | |
| Chowdhury et al. | Comparative enactment of fluorocarbon-free and fluorocarbon-based water repellent finishes on cotton single jersey fabrics | |
| JP2008202187A (ja) | 繊維構造物 | |
| CN113502588A (zh) | 一种阻燃复合服装面料及其生产方法 | |
| JP2016113725A (ja) | 難燃性布帛 | |
| US3318659A (en) | Process of treating cellulose textiles with polyvinyl chloride polymers, a polysiloxane and zirconium acetate and optionally with flame resistant and rot resistant agents | |
| JP4391379B2 (ja) | 撥水性高強度合成繊維構造物および撥水加工方法 | |
| Tai et al. | The Effect of Tetrakis (hydrogymethyl) phosphonium Chloride (THPC) on Selected Properties of Fibers | |
| US3932124A (en) | Process for setting textiles | |
| WO2020136148A1 (en) | Process for producing textile articles and textile articles obtained therefrom | |
| JPS6246672B2 (zh) | ||
| CN108893892B (zh) | 一种刺绣布料及其制作方法 | |
| CN108085830A (zh) | 一种高强阻燃防静电面料 | |
| JPS6032752B2 (ja) | アクリロニトリル系合成繊維の処理方法 | |
| Borah et al. | Novel functional finishing of eri silk for fire retardant | |
| CN105350326A (zh) | 一种阻燃针刺棉的制备方法 | |
| KR930000365B1 (ko) | 초발수성 직물의 제조방법 | |
| JP2014145134A (ja) | ビニロン混紡糸布帛及びその製造方法 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20190423 |
|
| RJ01 | Rejection of invention patent application after publication |