CN109652979A - A kind of preparation method of antiultraviolet bath curtain fabric - Google Patents

A kind of preparation method of antiultraviolet bath curtain fabric Download PDF

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Publication number
CN109652979A
CN109652979A CN201811476456.XA CN201811476456A CN109652979A CN 109652979 A CN109652979 A CN 109652979A CN 201811476456 A CN201811476456 A CN 201811476456A CN 109652979 A CN109652979 A CN 109652979A
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Prior art keywords
chinese small
small iris
antiultraviolet
fiber
curtain fabric
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CN201811476456.XA
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Chinese (zh)
Inventor
吴菊
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Huzhou Pin Chuan Brooder Co Ltd
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Huzhou Pin Chuan Brooder Co Ltd
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Priority to CN201811476456.XA priority Critical patent/CN109652979A/en
Publication of CN109652979A publication Critical patent/CN109652979A/en
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    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/77Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof
    • D06M11/79Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof with silicon dioxide, silicic acids or their salts
    • DTEXTILES; PAPER
    • D02YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02GCRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
    • D02G3/00Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
    • D02G3/02Yarns or threads characterised by the material or by the materials from which they are made
    • D02G3/04Blended or other yarns or threads containing components made from different materials
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/244Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
    • D06M13/282Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing phosphorus
    • D06M13/288Phosphonic or phosphonous acids or derivatives thereof
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M16/00Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/34General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using natural dyestuffs
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P3/00Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
    • D06P3/58Material containing hydroxyl groups
    • D06P3/60Natural or regenerated cellulose
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/02Natural fibres, other than mineral fibres
    • D06M2101/04Vegetal fibres
    • D06M2101/06Vegetal fibres cellulosic
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/25Resistance to light or sun, i.e. protection of the textile itself as well as UV shielding materials or treatment compositions therefor; Anti-yellowing treatments
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2101/00Inorganic fibres
    • D10B2101/02Inorganic fibres based on oxides or oxide ceramics, e.g. silicates
    • D10B2101/08Ceramic
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2201/00Cellulose-based fibres, e.g. vegetable fibres
    • D10B2201/01Natural vegetable fibres

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Biochemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Microbiology (AREA)
  • Mechanical Engineering (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)
  • Coloring (AREA)
  • Woven Fabrics (AREA)

Abstract

The present invention provides a kind of preparation method of antiultraviolet bath curtain fabric, the fabric is formed by sun-proof ceramic fibre, modified Chinese small iris fiber blend, and fabric has good antibacterial, anti-xanthochromia performance, and ultraviolet protection grade reaches UPF50+;Chinese small iris fiber is in a tubular form, and there is cavity, tert-butylphosphonic acid diphenyl is dissolved in the mixed solution of ethyl acetate and distilled water, after carrying out ultrasonication, tert-butylphosphonic acid diphenyl can penetrate into the inside of Chinese small iris fiber, to effectivelying prevent Chinese small iris fiber to be oxidized, Chinese small iris fiber is effectively prevented the phenomenon that humidity is big, often xanthochromia under the mal-conditions such as quick-fried Sai.

Description

A kind of preparation method of antiultraviolet bath curtain fabric
Technical field
The present invention relates to functional form garment material fields, more particularly to a kind of preparation side of antiultraviolet bath curtain fabric Method.
Background technique
Chinese small iris nickname Ma Lian, kalimeris, flagger, non-irrigated Pu, horse fragrant-flowered garlic etc. are that Iridaceae Jris perennial herb perennial root is planted Object is the mutation of white flower Chinese small iris, perennial thicket draft.
Root, stem and leaf is sturdy, the dense prosperity of fibrous root, and length is distributed up to 1 meter or more in umbrella.Phyllopodium is raw, the wide line shape, height It can reach 1250px, 0.4~25px of width, celadon, the high about 250px of scape, 2~4 flowers, flower is light blue, blue or blue Purple has darker striped on perianth;The long ellipticity cylindricality of capsule, there is 6 apparent ribs, and there is short beak on top;Long by 4~ 150px, seed are irregular polyhedron, sepia, slightly gloss, seed September part maturation.The month at florescence 5-6, the fruiting period 6-9 month. It is born in wasteland, roadside, patana, it is especially more to be grown on the salinization of soil grassland that overgrazes.
Chinese small iris has important medicinal, feeding and industrial value.Chinese small iris utilization periods are long, and grass yield is high, and nutritional ingredient is rich Richness is fond of for all kinds of livestocks especially sheep.Flower, seed, the root of Chinese small iris can people's medicines.Flower dries that take can diuresis defaecation;Kind Son and root can have the effect of bringing down a fever, detoxify, expelling parasite except damp and hot, hemostasis, removing toxic substances seed.As fibre plant, Taro Aso can replace Paper, rope are produced, leaf is the raw material of basketry product, and root can make brush.It is really " Chinese small iris whole body is precious ".
Currently, being not much both at home and abroad to the research of the textile performance of Chinese small iris fiber, it is substantially at laboratory stage, Shaanxi work The Luo Dong of industry Vocationl Technical College has studied setting for terylene and Chinese small iris fibre prickling geotextile fabric according to the characteristic of Chinese small iris fiber Meter and application, the pad which is mainly used for the dam facing slope protection bed course of dykes and dams upstream, gutter bed course, the dykes and dams in downstream fill The filtering layer of the reinforcing of layer, soft foundation.
In order to improve the utility value of Chinese small iris fiber, depth excavates Chinese small iris fiber and is made into the various characteristics after fabric, and having must It further the textile performance to Chinese small iris fiber and method to study.
Summary of the invention
In view of this, the object of the present invention is to provide a kind of antiultraviolet bath curtain fabrics and preparation method thereof.
A kind of preparation method of antiultraviolet bath curtain fabric carries out as steps described below:
A, by the sword-like iris leaf of harvest with pH value be 7.5-8.0 buck boiling 15-20min after, rubbing beats and removes pectin And lignin, obtain Chinese small iris fiber;
B, after mixing ethyl acetate and distilled water in proportion, surfactant is added, is heated to 40 DEG C, 300-500rpm 30-40min is stirred, after completely dissolution to surfactant, tert-butylphosphonic acid diphenyl and expanded vermiculite powder is added, with high speed Dispersion machine persistently emulsifies 10-15min under conditions of 8000-10000rpm, forms uniform emulsion liquid;
C, Chinese small iris fiber and natural plants coloring agent are put into emulsion liquid, under the ultrasonic frequency of 10-20kHz, Handle 8-15min;
D, after Chinese small iris fiber being taken out, dry 8-10h at a temperature of 30-40 DEG C;
E, Chinese small iris fiber will be added with crude oil, and stand 10-12h, pre-processed;
F, sun-proof ceramic fibre is dyed;
G, Chinese small iris fiber and sun-proof ceramic fibre are sufficiently mixed, the uniform carded sliver is made;
H, mixed fiber is obtained into antiultraviolet bath curtain fabric by drafting, rove, spun yarn, woven fabric.
In the antiultraviolet bath curtain fabric, the weight percent of sun-proof ceramic fibre is 25-40%, Chinese small iris fiber Weight percent is 60-75%.
The structural formula of the tert-butylphosphonic acid diphenyl are as follows:
From open source literature, someone isolates flavone compound, xanthones compound and steroid from sword-like iris leaf Alcohol compound, these have disclosed makes sword-like iris leaf have certain anti-microbial property with not yet disclosed ingredient, if can spin Guarantee that these compound structures will not be destroyed during knitting, can make it is blended after fiber there is certain anti-microbial property.
In the present invention, pH value when handling sword-like iris leaf is alkalescence, while not to the treatment temperature of Chinese small iris fiber Higher than 40 DEG C, frequency when along with ultrasonication is lower, dyes in early period to fiber, is made after fabric and no longer carries out High-temperature dyeing, arrangement, these be destroyed the structure of the antibiotic effective ingredients such as the ketone in Chinese small iris fiber will not.
Preferably, in the step B, the surfactant is neopelex.
Preferably, in the step B, the weight percent of each raw material is respectively as follows:
Ethyl acetate 25-35%
20-50 μm of 1-3% of expanded vermiculite powder
Surfactant 4-8%
Tert-butylphosphonic acid diphenyl 6-10%
Distilled water surplus.
For fabric and raw-vermiculite piece after high-temperature roasting, volume energy expands rapidly several times to tens times, the vermiculite after volume expansion It just is expanded vermiculite, is layer structure, interlayer contains the crystallization water, and bulk density is in 50-200kg/m3, thermal conductivity is small, is good Heat-barrier material.The second best in quality expanded vermiculite, maximum operation (service) temperature is up to 1100 DEG C.It, can be with after being modified to Chinese small iris fiber Among Chinese small iris fiberoptic fiber, and part is emerging in fiber surface, is remarkably improved anti-ultraviolet property.
Preferably, in the step C natural plants coloring agent additive amount be Chinese small iris fibre weight 5-12%.
Chinese small iris fiber in a tubular form, and has cavity, and tert-butylphosphonic acid diphenyl is dissolved in ethyl acetate and distilled water In mixed solution, after carrying out ultrasonication, tert-butylphosphonic acid diphenyl can penetrate into the inside of Chinese small iris fiber, to have Effect prevents Chinese small iris fiber to be oxidized, and effectively prevents Chinese small iris fiber humidity is big, often xanthochromia shows under the mal-conditions such as quick-fried Sai As.
The preparation method of a kind of antiultraviolet bath curtain fabric provided by the present invention, by sun-proof ceramic fibre and modified Chinese small iris fiber carries out blended, whole preparation process environmental protection;Fabric has good antibacterial, anti-xanthochromia performance, ultraviolet protection etc. Grade reaches UPF50+.
Specific embodiment
Embodiment 1
A kind of preparation method of antiultraviolet bath curtain fabric carries out as steps described below:
A, by the sword-like iris leaf of harvest with pH value be 7.5-8.0 buck boiling 18min after, rubbing beats and removes pectin and wood Quality obtains Chinese small iris fiber;
B, after mixing ethyl acetate and distilled water in proportion, surfactant is added, is heated to 40 DEG C, 350rpm stirring 35min after completely dissolution to surfactant is added tert-butylphosphonic acid diphenyl and expanded vermiculite powder, uses high speed disperser 12min is persistently emulsified under conditions of 8500rpm, forms uniform emulsion liquid;
C, Chinese small iris fiber and natural plants coloring agent are put into emulsion liquid, under the ultrasonic frequency of 15kHz, processing 10min;
D, after Chinese small iris fiber being taken out, dry 9h at a temperature of 35 DEG C;
E, Chinese small iris fiber will be added with crude oil, and stand 11h, pre-processed;
F, sun-proof ceramic fibre is dyed;
G, Chinese small iris fiber and sun-proof ceramic fibre are sufficiently mixed, the uniform carded sliver is made;
H, mixed fiber is obtained into antiultraviolet bath curtain fabric by drafting, rove, spun yarn, woven fabric.
In the antiultraviolet bath curtain fabric, the weight percent of sun-proof ceramic fibre is 35%, the weight of Chinese small iris fiber Measuring percentage is 65%.
In the step B, the surfactant is neopelex.
In the step B, the weight percent of each raw material is respectively as follows:
Ethyl acetate 28%
20-50 μm 2.5% of expanded vermiculite powder
Surfactant 7%
Tert-butylphosphonic acid diphenyl 8%
Distilled water surplus.
The additive amount of natural plants coloring agent is the 7% of Chinese small iris fibre weight in the step C.
Embodiment 2
A kind of preparation method of antiultraviolet bath curtain fabric carries out as steps described below:
A, by the sword-like iris leaf of harvest with pH value be 7.5-8.0 buck boiling 20min after, rubbing beats and removes pectin and wood Quality obtains Chinese small iris fiber;
B, after mixing ethyl acetate and distilled water in proportion, surfactant is added, is heated to 40 DEG C, 500rpm stirring 30min after completely dissolution to surfactant is added tert-butylphosphonic acid diphenyl and expanded vermiculite powder, uses high speed disperser 10min is persistently emulsified under conditions of 10000rpm, forms uniform emulsion liquid;
C, Chinese small iris fiber and natural plants coloring agent are put into emulsion liquid, under the ultrasonic frequency of 10kHz, processing 15min;
D, after Chinese small iris fiber being taken out, dry 8h at a temperature of 38 DEG C;
E, Chinese small iris fiber will be added with crude oil, and stand 12h, pre-processed;
F, sun-proof ceramic fibre is dyed;
G, Chinese small iris fiber and sun-proof ceramic fibre are sufficiently mixed, the uniform carded sliver is made;
H, mixed fiber is obtained into antiultraviolet bath curtain fabric by drafting, rove, spun yarn, woven fabric.
In the antiultraviolet bath curtain fabric, the weight percent of sun-proof ceramic fibre is 25%, the weight of Chinese small iris fiber Measuring percentage is 75%.
In the step B, the surfactant is neopelex.
In the step B, the weight percent of each raw material is respectively as follows:
Ethyl acetate 25%
20-50 μm 3% of expanded vermiculite powder
Surfactant 4%
Tert-butylphosphonic acid diphenyl 10%
Distilled water surplus.
The additive amount of natural plants coloring agent is the 5% of Chinese small iris fibre weight in the step C.
Embodiment 3
A kind of preparation method of antiultraviolet bath curtain fabric carries out as steps described below:
A, by the sword-like iris leaf of harvest with pH value be 7.5-8.0 buck boiling 15min after, rubbing beats and removes pectin and wood Quality obtains Chinese small iris fiber;
B, after mixing ethyl acetate and distilled water in proportion, surfactant is added, is heated to 40 DEG C, 300rpm stirring 40min after completely dissolution to surfactant is added tert-butylphosphonic acid diphenyl and expanded vermiculite powder, uses high speed disperser 15min is persistently emulsified under conditions of 8000rpm, forms uniform emulsion liquid;
C, Chinese small iris fiber and natural plants coloring agent are put into emulsion liquid, under the ultrasonic frequency of 20kHz, processing 8min;
D, after Chinese small iris fiber being taken out, dry 8h at a temperature of 38 DEG C;
E, Chinese small iris fiber will be added with crude oil, and stand 12h, pre-processed;
F, sun-proof ceramic fibre is dyed;
G, Chinese small iris fiber and sun-proof ceramic fibre are sufficiently mixed, the uniform carded sliver is made;
H, mixed fiber is obtained into antiultraviolet bath curtain fabric by drafting, rove, spun yarn, woven fabric.
In the antiultraviolet bath curtain fabric, the weight percent of sun-proof ceramic fibre is 40%, the weight of Chinese small iris fiber Measuring percentage is 60%.
In the step B, the surfactant is neopelex.
In the step B, the weight percent of each raw material is respectively as follows:
Ethyl acetate 35%
20-50 μm 1% of expanded vermiculite powder
Surfactant 8%
Tert-butylphosphonic acid diphenyl 6%
Distilled water surplus.
The additive amount of natural plants coloring agent is the 12% of Chinese small iris fibre weight in the step C.
Comparative example 1
By the tert-butylphosphonic acid diphenyl removal in embodiment 1, remaining proportion and preparation method are constant.
The bath curtain fabric sample for detecting 1-3 of the embodiment of the present invention and comparative example 1 uses 3 years when factory and in Kunming Areas Whiteness afterwards, obtained testing result are shown in Table 1.Detecting instrument: U.S. Datacolor-2000 whiteness instrument (d/0, xenon lamp).
Table 1: the whiteness testing result (using R457 whiteness formulas) of bath curtain fabric sample;
Embodiment 1 Embodiment 2 Embodiment 3 Comparative example 1
Factory whiteness 92.8 91.7 92.4 92.5
Whiteness after 3 years 90.7 90.1 90.3 52.1
By the above test result it is recognised that the whiteness of the present invention treated bath curtain fabric sample can be kept for a long time, Color inhibition effect is good.
The foregoing is only a preferred embodiment of the present invention, but scope of protection of the present invention is not limited thereto, Anyone skilled in the art in the technical scope disclosed by the present invention, according to the technique and scheme of the present invention and its Inventive concept is subject to equivalent substitution or change, should be covered by the protection scope of the present invention.

Claims (4)

1. a kind of preparation method of antiultraviolet bath curtain fabric, which is characterized in that carry out as steps described below:
A, by the sword-like iris leaf of harvest with pH value be 7.5-8.0 buck boiling 15-20min after, rubbing beats and removes pectin and wood Quality obtains Chinese small iris fiber;
B, after mixing ethyl acetate and distilled water in proportion, surfactant is added, is heated to 40 DEG C, 300-500rpm stirring 30-40min after completely dissolution to surfactant is added tert-butylphosphonic acid diphenyl and expanded vermiculite powder, uses high speed dispersion Machine persistently emulsifies 10-15min under conditions of 8000-10000rpm, forms uniform emulsion liquid;
C, Chinese small iris fiber and natural plants coloring agent are put into emulsion liquid, under the ultrasonic frequency of 10-20kHz, processing 8-15min;
D, after Chinese small iris fiber being taken out, dry 8-10h at a temperature of 30-40 DEG C;
E, Chinese small iris fiber will be added with crude oil, and stand 10-12h, pre-processed;
F, sun-proof ceramic fibre is dyed;
G, Chinese small iris fiber and sun-proof ceramic fibre are sufficiently mixed, the uniform carded sliver is made;
H, mixed fiber is obtained into antiultraviolet bath curtain fabric by drafting, rove, spun yarn, woven fabric;
In the antiultraviolet bath curtain fabric, the weight percent of sun-proof ceramic fibre is 25-40%, the weight of Chinese small iris fiber Percentage is 60-75%.
2. the preparation method of antiultraviolet bath curtain fabric as described in claim 1, which is characterized in that in the step B, institute The surfactant stated is neopelex.
3. the preparation method of antiultraviolet bath curtain fabric as described in claim 1, which is characterized in that in the step B, The weight percent of each raw material is respectively as follows:
Ethyl acetate 25-35%
20-50 μm of 1-3% of expanded vermiculite powder
Surfactant 4-8%
Tert-butylphosphonic acid diphenyl 6-10%
Distilled water surplus.
4. the preparation method of antiultraviolet bath curtain fabric as described in claim 1, which is characterized in that day in the step C The additive amount of right vegetable dyeing agent is the 5-12% of Chinese small iris fibre weight.
CN201811476456.XA 2018-11-28 2018-11-28 A kind of preparation method of antiultraviolet bath curtain fabric Withdrawn CN109652979A (en)

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Application Number Priority Date Filing Date Title
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Publication Number Publication Date
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Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105755643A (en) * 2016-04-06 2016-07-13 德清县新鑫达丝绸炼染有限公司 Outdoor work garment fabric and preparation method thereof
CN105862226A (en) * 2016-05-16 2016-08-17 长兴华海纺织有限公司 Preparation method of anti-microbial wear-proof protective clothing fabric
CN105862204A (en) * 2016-05-16 2016-08-17 长兴如龙纺织有限公司 Preparation method of protective clothing blended fabric
CN105970409A (en) * 2016-05-16 2016-09-28 长兴华海纺织有限公司 Preparation method of antibacterial and flame-retardant curtain fabric
CN205682506U (en) * 2016-06-14 2016-11-16 晋江知保企业管理咨询有限公司 A kind of sun-proof clothing
CN206651412U (en) * 2017-03-16 2017-11-21 际华三五四三针织服饰有限公司 Sunproof clothes
CN108085491A (en) * 2016-11-22 2018-05-29 厦门稀土材料研究所 A kind of method that neutrality phosphine extractant is used for extract and separate thorium

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105755643A (en) * 2016-04-06 2016-07-13 德清县新鑫达丝绸炼染有限公司 Outdoor work garment fabric and preparation method thereof
CN105862226A (en) * 2016-05-16 2016-08-17 长兴华海纺织有限公司 Preparation method of anti-microbial wear-proof protective clothing fabric
CN105862204A (en) * 2016-05-16 2016-08-17 长兴如龙纺织有限公司 Preparation method of protective clothing blended fabric
CN105970409A (en) * 2016-05-16 2016-09-28 长兴华海纺织有限公司 Preparation method of antibacterial and flame-retardant curtain fabric
CN205682506U (en) * 2016-06-14 2016-11-16 晋江知保企业管理咨询有限公司 A kind of sun-proof clothing
CN108085491A (en) * 2016-11-22 2018-05-29 厦门稀土材料研究所 A kind of method that neutrality phosphine extractant is used for extract and separate thorium
CN206651412U (en) * 2017-03-16 2017-11-21 际华三五四三针织服饰有限公司 Sunproof clothes

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