CN109651983A - A kind of textile fabric modified back water-coating fire retardant glue and preparation method thereof - Google Patents
A kind of textile fabric modified back water-coating fire retardant glue and preparation method thereof Download PDFInfo
- Publication number
- CN109651983A CN109651983A CN201811638298.3A CN201811638298A CN109651983A CN 109651983 A CN109651983 A CN 109651983A CN 201811638298 A CN201811638298 A CN 201811638298A CN 109651983 A CN109651983 A CN 109651983A
- Authority
- CN
- China
- Prior art keywords
- parts
- agitator tank
- persistently
- deionized water
- mixing speed
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
- C09J133/04—Homopolymers or copolymers of esters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2227—Oxides; Hydroxides of metals of aluminium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The invention discloses a kind of textile fabric modified back water-coating fire retardant glues and preparation method thereof, are made of following weight item: A group ingredient, 5 parts ~ 7 parts of aluminium hydroxide, 3 parts ~ 5 parts of calcium carbonate, 3 parts ~ 5 parts of antimony oxide, 30 parts ~ 40 parts of deionized water；B group ingredient, 30 parts ~ 35 parts of aqueous acrylic emulsion, 15 parts ~ 20 parts of decabromodiphenylethane, 4 parts ~ 7 parts of cosolvent, 10 parts ~ 20 parts of deionized water.And prefabricated mixed liquor A and prefabricated mixed liquid B is respectively prepared in A group ingredient and B group ingredient, it is then mixed and white paste finished product is made.The present invention passes through optimization design, lower with cost of material, is easy buying and obtains, in addition the feature good to the anti-flammability coating adherence of textile fabric surface formation, the tough shape of bullet is good and film sense is comfortable has good flame retardant property；Relatively simple, lower production costs are processed in the preparation of product, without using expensive equipment.
Description
Technical field
The present invention relates to combustion-supporting glue technical field, more particularly, to a kind of modified back water-coating fire retardant glue of textile fabric and
Preparation method.
Background technique
China is the big country of textile production and outlet, and china textile industry itself passes through the development of many years, competitive advantage
It is fairly obvious, have most complete industrial chain in the world, highest process mating is horizontal, copes with to the industry cluster of numerous prosperities
The capacity of self-regulation of the market risk constantly enhances, and keeps steady developing steps to provide solid guarantee to industry.From state
Border environment sees, still there be larger expand space and opportunity in international market.Limit with 2007 end of the year Central Europe textiles expire, 2008
Bottom China-America Textile quota is limited end, and China Textile quota-free era is coming, account for about global piece market 60% with
Upper share area all-round opening, it will bring huge opportunity to China Textile trade.And coming years world economy will be located
In first transition, the growth of international trade will be promoted, this will increase to China Textile Clothing Export brings the advantageous world
Market ensures.
In textile field, the industries such as especially various tents, curtain, sofa cloth, seat cloth, carpet, tablecloth are used or family
It is a kind of fire-retardant mode of both economical material benefit using the fire-retardant mode that flame-retardant coatings glue carries out back painting in terms of with textile, it
Processing technology is simple, and convenient for operation, low production cost is easy to industrialize.
Existing bromine antimony type fire retardant glue is most mature, cost performance highest, most widely used product.However most bromine antimony
Type fire retardant glue is using decabromodiphenyl oxide, but on 2 10th, 2017, European Union official's bulletin issued committee's regulation (EU)
2017/227, REACH regulation attachment XVII formally increases the restrictive clause to decabromodiphenyl oxide (decaBDE) newly.March 2 in 2019
After day, the mass percentage of decabromodiphenyl oxide (decaBDE) is equal to or more than 0.1% in substance, mixture and article, then
It must not produce or launch.As widely used flame-retardant additive, the promulgation of decabromodiphenyl oxide (decaBDE) limitation requirement
And implement will affect the defeated Europe trade of textile and plastic product, adhesive, sealant, coating and ink product also will receive wave
And.
For this purpose, industrial circle releases rapidly decabromodiphenylethane, however the type fire retardant glue is hanging down to frivolous and heavily fabric
Effective in straight combustion testing but very big on zephyr feel color and style influence, there are film sense deficiency, firmness are poor
And the problem of playing slag.
Summary of the invention
In view of the above-mentioned problems, the present invention is intended to provide a kind of textile fabric modified back water-coating fire retardant glue and its preparation side
Method has the characteristics that fabric coating adhesiveness is good, the tough shape of bullet is good and film sense is comfortable.
Technical problem solved by the invention can be realized using following technical scheme:
A kind of modified back water-coating fire retardant glue of textile fabric, is made of: A group ingredient, aluminium hydroxide 5 parts ~ 7 following weight item
Part, 3 parts ~ 5 parts of calcium carbonate, 3 parts ~ 5 parts of antimony oxide, 30 parts ~ 40 parts of deionized water；B group ingredient, aqueous acrylic emulsion 30
Part ~ 35 parts, 15 parts ~ 20 parts of decabromodiphenylethane, 4 parts ~ 7 parts of cosolvent, 10 parts ~ 20 parts of deionized water.
A kind of modified back water-coating fire retardant glue of textile fabric, is made of: A group ingredient, aluminium hydroxide 5 following weight item
Part, 3 parts of calcium carbonate, 3 parts of antimony oxide, 30 parts of deionized water；B group ingredient, 30 parts of aqueous acrylic emulsion, decabrominated dipheny second
16 parts of alkane, 4 parts of cosolvent, 10 parts of deionized water.
A kind of modified back water-coating fire retardant glue of textile fabric, is made of: A group ingredient, aluminium hydroxide 6 following weight item
Part, 4 parts of calcium carbonate, 3 parts of antimony oxide, 35 parts of deionized water；B group ingredient, 32 parts of aqueous acrylic emulsion, decabrominated dipheny second
18 parts of alkane, 5 parts of cosolvent, 15 parts of deionized water.
A kind of modified back water-coating fire retardant glue of textile fabric, is made of: A group ingredient, aluminium hydroxide 7 following weight item
Part, 5 parts of calcium carbonate, 4 parts of antimony oxide, 40 parts of deionized water；B group ingredient, 35 parts of aqueous acrylic emulsion, decabrominated dipheny second
20 parts of alkane, 7 parts of cosolvent, 20 parts of deionized water.
A kind of modified back water-coating fire retardant glue of textile fabric, the cosolvent is dipropylene glycol methyl ether and dipropylene glycol
Mixed liquor, wherein the ratio of dipropylene glycol methyl ether and dipropylene glycol is between 0.25 ~ 0.4.
The ratio of a kind of modified back water-coating fire retardant glue of textile fabric, dipropylene glycol methyl ether and dipropylene glycol is 3:10.
A method of the modified back water-coating fire retardant glue of textile fabric is prepared, is included the following steps:
S1, according to above-mentioned weight proportion, the aluminium hydroxide of deionized water, calcium carbonate and 1/2 proportion, heating are added in agitator tank
It to 35 DEG C ~ 40 DEG C, while persistently being stirred in agitator tank, mixing speed is 300r/min ~ 350r/min, continues mixing time
15min~20min；Then again by antimony oxide and residue 1/2 proportion aluminium hydroxide be added agitator tank in, be warming up to 45 DEG C ~
50 DEG C, while persistently being stirred in agitator tank, mixing speed is 420r/min ~ 450r/min, lasting mixing time 30min ~
45min, heat preservation stand 10min ~ 15min, obtain prefabricated mixed liquor A；
S2, according to above-mentioned weight proportion, deionized water, aqueous acrylic emulsion, decabromodiphenylethane are added in agitator tank, adds
Heat persistently stirs in agitator tank to 30 DEG C ~ 35 DEG C, and mixing speed is 300r/min ~ 350r/min, continues mixing time
10min~25min；Then cosolvent is added in agitator tank again, is warming up to 35 DEG C ~ 40 DEG C, while persistently stirring in agitator tank,
Mixing speed is 450r/min ~ 500r/min, continues mixing time 25min ~ 35min, and heat preservation stands 10min ~ 15min, filtering
After obtain prefabricated mixed liquid B；
S3, prefabricated mixed liquor A will be obtained in step S1 be poured into the prefabricated mixed liquid B obtained in step S2, be heated to 40 DEG C ~
50 DEG C, while persistently being stirred in agitator tank, mixing speed is 500r/min ~ 600r/min, lasting mixing time 20min ~
30min naturally cools to room temperature, obtains white paste finished product.
A method of the modified back water-coating fire retardant glue of textile fabric is prepared, is included the following steps:
S1, according to above-mentioned weight proportion, the aluminium hydroxide of deionized water, calcium carbonate and 1/2 proportion, heating are added in agitator tank
It to 35 DEG C, while persistently being stirred in agitator tank, mixing speed 350r/min, continues mixing time 18min；Then again by three oxygen
The aluminium hydroxide for changing 1/2 proportion of two antimony and residue is added in agitator tank, is warming up to 48 DEG C, while persistently stirring in agitator tank, stirs
Mixing speed is 420r/min, continues mixing time 35min, and heat preservation stands 10min, obtains prefabricated mixed liquor A；
S2, according to above-mentioned weight proportion, deionized water, aqueous acrylic emulsion, decabromodiphenylethane are added in agitator tank, adds
Heat persistently stirs in agitator tank to 32 DEG C, mixing speed 320r/min, continues mixing time 15min；Then it will help again
Solvent is added in agitator tank, is warming up to 40 DEG C, while persistently stirring in agitator tank, mixing speed 480r/min, lasting to stir
Time 30min, heat preservation stand 10min, prefabricated mixed liquid B are obtained after filtering；
S3, prefabricated mixed liquor A will be obtained in step S1 be poured into the prefabricated mixed liquid B obtained in step S2, be heated to 45 DEG C,
It is persistently stirred in agitator tank simultaneously, mixing speed 550r/min continues mixing time 25min, naturally cools to room temperature, obtains
White paste finished product.
A method of the modified back water-coating fire retardant glue of textile fabric is prepared, is included the following steps:
S1, according to above-mentioned weight proportion, the aluminium hydroxide of deionized water, calcium carbonate and 1/2 proportion, heating are added in agitator tank
It to 36 DEG C, while persistently being stirred in agitator tank, mixing speed 360r/min, continues mixing time 18min；Then again by three oxygen
The aluminium hydroxide for changing 1/2 proportion of two antimony and residue is added in agitator tank, is warming up to 48 DEG C, while persistently stirring in agitator tank, stirs
Mixing speed is 430r/min, continues mixing time 35min, and heat preservation stands 12min, obtains prefabricated mixed liquor A；
S2, according to above-mentioned weight proportion, deionized water, aqueous acrylic emulsion, decabromodiphenylethane are added in agitator tank, adds
Heat persistently stirs in agitator tank to 32 DEG C, mixing speed 330r/min, continues mixing time 18min；Then it will help again
Solvent is added in agitator tank, is warming up to 40 DEG C, while persistently stirring in agitator tank, mixing speed 480r/min, lasting to stir
Time 30min, heat preservation stand 12min, prefabricated mixed liquid B are obtained after filtering；
S3, prefabricated mixed liquor A will be obtained in step S1 be poured into the prefabricated mixed liquid B obtained in step S2, be heated to 45 DEG C,
It is persistently stirred in agitator tank simultaneously, mixing speed 550r/min continues mixing time 25min, naturally cools to room temperature, obtains
White paste finished product.
A method of the modified back water-coating fire retardant glue of textile fabric is prepared, is included the following steps:
S1, according to above-mentioned weight proportion, the aluminium hydroxide of deionized water, calcium carbonate and 1/2 proportion, heating are added in agitator tank
It to 38 DEG C, while persistently being stirred in agitator tank, mixing speed 350r/min, continues mixing time 20min；Then again by three oxygen
The aluminium hydroxide for changing 1/2 proportion of two antimony and residue is added in agitator tank, is warming up to 50 DEG C, while persistently stirring in agitator tank, stirs
Mixing speed is 450r/min, continues mixing time 40min, and heat preservation stands 15min, obtains prefabricated mixed liquor A；
S2, according to above-mentioned weight proportion, deionized water, aqueous acrylic emulsion, decabromodiphenylethane are added in agitator tank, adds
Heat persistently stirs in agitator tank to 32 DEG C, mixing speed 330r/min, continues mixing time 20min；Then it will help again
Solvent is added in agitator tank, is warming up to 40 DEG C, while persistently stirring in agitator tank, mixing speed 480r/min, lasting to stir
Time 30min, heat preservation stand 15min, prefabricated mixed liquid B are obtained after filtering；
S3, prefabricated mixed liquor A will be obtained in step S1 be poured into the prefabricated mixed liquid B obtained in step S2, be heated to 45 DEG C,
It is persistently stirred in agitator tank simultaneously, mixing speed 550r/min continues mixing time 25min, naturally cools to room temperature, obtains
White paste finished product.
The present invention has cost of material lower by optimization design, is easy buying and obtains, is formed to textile fabric surface
Anti-flammability coating adherence is good, plays the feature that tough shape is good and film sense is comfortable, in addition has good flame retardant property；The preparation of product
Relatively simple, lower production costs are processed, without using expensive equipment.
The features of the present invention sees this case or less preferably detailed description of embodiment and is well understood.
Specific embodiment
In order to be easy to understand the technical means, the creative features, the aims and the efficiencies achieved by the present invention, tie below
Specific embodiment is closed, the present invention is further explained.
Embodiment 1
A kind of modified back water-coating fire retardant glue of textile fabric, is made of: A group ingredient, aluminium hydroxide 5 parts ~ 7 following weight item
Part, 3 parts ~ 5 parts of calcium carbonate, 3 parts ~ 5 parts of antimony oxide, 30 parts ~ 40 parts of deionized water；B group ingredient, aqueous acrylic emulsion 30
Part ~ 35 parts, 15 parts ~ 20 parts of decabromodiphenylethane, 4 parts ~ 7 parts of cosolvent, 10 parts ~ 20 parts of deionized water.
Wherein, cosolvent is the mixed liquor of dipropylene glycol methyl ether and dipropylene glycol, wherein dipropylene glycol methyl ether and dipropyl two
The ratio of alcohol is between 0.25 ~ 0.4, and the ratio of preferred dipropylene glycol methyl ether and dipropylene glycol is 3:10.
The present embodiment additionally provides a kind of method for preparing the modified back water-coating fire retardant glue of textile fabric, including walks as follows
It is rapid:
S1, according to above-mentioned weight proportion, the aluminium hydroxide of deionized water, calcium carbonate and 1/2 proportion, heating are added in agitator tank
It to 35 DEG C ~ 40 DEG C, while persistently being stirred in agitator tank, mixing speed is 300r/min ~ 350r/min, continues mixing time
15min~20min；Then again by antimony oxide and residue 1/2 proportion aluminium hydroxide be added agitator tank in, be warming up to 45 DEG C ~
50 DEG C, while persistently being stirred in agitator tank, mixing speed is 420r/min ~ 450r/min, lasting mixing time 30min ~
45min, heat preservation stand 10min ~ 15min, obtain prefabricated mixed liquor A；
S2, according to above-mentioned weight proportion, deionized water, aqueous acrylic emulsion, decabromodiphenylethane are added in agitator tank, adds
Heat persistently stirs in agitator tank to 30 DEG C ~ 35 DEG C, and mixing speed is 300r/min ~ 350r/min, continues mixing time
10min~25min；Then cosolvent is added in agitator tank again, is warming up to 35 DEG C ~ 40 DEG C, while persistently stirring in agitator tank,
Mixing speed is 450r/min ~ 500r/min, continues mixing time 25min ~ 35min, and heat preservation stands 10min ~ 15min, filtering
After obtain prefabricated mixed liquid B；
S3, prefabricated mixed liquor A will be obtained in step S1 be poured into the prefabricated mixed liquid B obtained in step S2, be heated to 40 DEG C ~
50 DEG C, while persistently being stirred in agitator tank, mixing speed is 500r/min ~ 600r/min, lasting mixing time 20min ~
30min naturally cools to room temperature, obtains white paste finished product.
Embodiment 2
A kind of modified back water-coating fire retardant glue of textile fabric, is made of following weight item: A group ingredient, 5 parts of aluminium hydroxide,
3 parts of calcium carbonate, 3 parts of antimony oxide, 30 parts of deionized water；B group ingredient, 30 parts of aqueous acrylic emulsion, decabromodiphenylethane
16 parts, 4 parts of cosolvent, 10 parts of deionized water.
Wherein, cosolvent is the mixed liquor of dipropylene glycol methyl ether and dipropylene glycol, wherein dipropylene glycol methyl ether and dipropyl two
The ratio of alcohol is 3:10.
The present embodiment additionally provides a kind of method for preparing the modified back water-coating fire retardant glue of textile fabric, including walks as follows
It is rapid:
S1, according to above-mentioned weight proportion, the aluminium hydroxide of deionized water, calcium carbonate and 1/2 proportion, heating are added in agitator tank
It to 35 DEG C, while persistently being stirred in agitator tank, mixing speed 350r/min, continues mixing time 18min；Then again by three oxygen
The aluminium hydroxide for changing 1/2 proportion of two antimony and residue is added in agitator tank, is warming up to 48 DEG C, while persistently stirring in agitator tank, stirs
Mixing speed is 420r/min, continues mixing time 35min, and heat preservation stands 10min, obtains prefabricated mixed liquor A；
S2, according to above-mentioned weight proportion, deionized water, aqueous acrylic emulsion, decabromodiphenylethane are added in agitator tank, adds
Heat persistently stirs in agitator tank to 32 DEG C, mixing speed 320r/min, continues mixing time 15min；Then it will help again
Solvent is added in agitator tank, is warming up to 40 DEG C, while persistently stirring in agitator tank, mixing speed 480r/min, lasting to stir
Time 30min, heat preservation stand 10min, prefabricated mixed liquid B are obtained after filtering；
S3, prefabricated mixed liquor A will be obtained in step S1 be poured into the prefabricated mixed liquid B obtained in step S2, be heated to 45 DEG C,
It is persistently stirred in agitator tank simultaneously, mixing speed 550r/min continues mixing time 25min, naturally cools to room temperature, obtains
White paste finished product.
Embodiment 3
A kind of modified back water-coating fire retardant glue of textile fabric, is made of following weight item: A group ingredient, 6 parts of aluminium hydroxide,
4 parts of calcium carbonate, 3 parts of antimony oxide, 35 parts of deionized water；B group ingredient, 32 parts of aqueous acrylic emulsion, decabromodiphenylethane
18 parts, 5 parts of cosolvent, 15 parts of deionized water.
Wherein, cosolvent is the mixed liquor of dipropylene glycol methyl ether and dipropylene glycol, wherein dipropylene glycol methyl ether and dipropyl two
The ratio of alcohol is 3:10.
S1, according to above-mentioned weight proportion, the aluminium hydroxide of deionized water, calcium carbonate and 1/2 proportion is added in agitator tank,
36 DEG C are heated to, while persistently being stirred in agitator tank, mixing speed 360r/min continues mixing time 18min；Then again will
The aluminium hydroxide of 1/2 proportion of antimony oxide and residue is added in agitator tank, is warming up to 48 DEG C, while persistently stirring in agitator tank
It mixes, mixing speed 430r/min, continues mixing time 35min, heat preservation stands 12min, obtains prefabricated mixed liquor A；
S2, according to above-mentioned weight proportion, deionized water, aqueous acrylic emulsion, decabromodiphenylethane are added in agitator tank, adds
Heat persistently stirs in agitator tank to 32 DEG C, mixing speed 330r/min, continues mixing time 18min；Then it will help again
Solvent is added in agitator tank, is warming up to 40 DEG C, while persistently stirring in agitator tank, mixing speed 480r/min, lasting to stir
Time 30min, heat preservation stand 12min, prefabricated mixed liquid B are obtained after filtering；
S3, prefabricated mixed liquor A will be obtained in step S1 be poured into the prefabricated mixed liquid B obtained in step S2, be heated to 45 DEG C,
It is persistently stirred in agitator tank simultaneously, mixing speed 550r/min continues mixing time 25min, naturally cools to room temperature, obtains
White paste finished product.
Embodiment 4
A kind of modified back water-coating fire retardant glue of textile fabric, is made of following weight item: A group ingredient, 7 parts of aluminium hydroxide,
5 parts of calcium carbonate, 4 parts of antimony oxide, 40 parts of deionized water；B group ingredient, 35 parts of aqueous acrylic emulsion, decabromodiphenylethane
20 parts, 7 parts of cosolvent, 20 parts of deionized water.
Wherein, cosolvent is the mixed liquor of dipropylene glycol methyl ether and dipropylene glycol, wherein dipropylene glycol methyl ether and dipropyl two
The ratio of alcohol is 3:10.
S1, according to above-mentioned weight proportion, the aluminium hydroxide of deionized water, calcium carbonate and 1/2 proportion is added in agitator tank,
38 DEG C are heated to, while persistently being stirred in agitator tank, mixing speed 350r/min continues mixing time 20min；Then again will
The aluminium hydroxide of 1/2 proportion of antimony oxide and residue is added in agitator tank, is warming up to 50 DEG C, while persistently stirring in agitator tank
It mixes, mixing speed 450r/min, continues mixing time 40min, heat preservation stands 15min, and filtering obtains prefabricated mixed liquor A；
S2, according to above-mentioned weight proportion, deionized water, aqueous acrylic emulsion, decabromodiphenylethane are added in agitator tank, adds
Heat persistently stirs in agitator tank to 32 DEG C, mixing speed 330r/min, continues mixing time 20min；Then it will help again
Solvent is added in agitator tank, is warming up to 40 DEG C, while persistently stirring in agitator tank, mixing speed 480r/min, lasting to stir
Time 30min, heat preservation stand 15min, prefabricated mixed liquid B are obtained after filtering；
S3, prefabricated mixed liquor A will be obtained in step S1 be poured into the prefabricated mixed liquid B obtained in step S2, be heated to 45 DEG C,
It is persistently stirred in agitator tank simultaneously, mixing speed 550r/min continues mixing time 25min, naturally cools to room temperature, obtains
White paste finished product.
In conjunction with the various embodiments described above, the present invention optimizes process recipe, selects antimony oxide combination decabromodiphenylethane, tool
There is good effect, can make coating adhesive that there is soft service performance, while in order to obtain effect of preferably dissolving each other
Fruit avoids occurring slag particle in colloid, it is preferred to use the cosolvent that dipropylene glycol methyl ether and dipropylene glycol are mixed, to improve
The miscible effect of decabromodiphenylethane；Then optimization manufacturing process is mixed again using double groups of prefabricated mixed configurations,
Convenient for improving processing efficiency, while each group early period being made to all have good compatibility, improve product quality, guarantees product most
White paste product can be obtained eventually, avoid the occurrence of the insoluble matters such as agglomeration, the crust block of suspended particulate shape.
The modification back water-coating fire retardant glue of prepared acquisition in any one above-mentioned embodiment is suitable for synthetic fibers and mixes
The protective coating of textile surfaces.This product meets " the textile combustion performance vertical direction GB/T 5455-2014 damage length
Spend the measurement glowed with after flame time ", " GB/T 15357-2014 surfactant and detergent rotary viscosity design determining liquid
The viscosity and flowing property of product ", " HJ2537-2014 environmental labelling product technical requirements water paint " relevant criterion, simultaneously
Standard execution is pressed in coherent detection.
The physicochemical property of the said goods is detailed in following table:
| Project | Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 |
| Appearance | White paste | White paste | White paste | White paste |
| PH value (1% aqueous solution) | 6~8 | 7 | 7 | 6.5 |
| Non-volatile content % | 50±1 | 50 | 50 | 50 |
| Viscosity (room temperature) mPa.s | 10000~30000 | 20000~25000 | 20000~25000 | 20000~25000 |
| After flame time | ≤2.0S | ≤2.0S | ≤2.0S | ≤2.0S |
| The density flaming droplet time | 0S | 0S | 0S | 0S |
| Char length | ≤180mm | ≤180mm | ≤180mm | ≤180mm |
The detection method of each detection project among the above specifically:
Appearance detection is using the range estimation progress under natural light.
PH value detection is surveyed using precision test paper, precision test paper range ability 5.5 ~ 10；1g sample is weighed in beaker, essence
0.01g is really arrived, adds distilled water to 100g, stirs evenly, then dipped on a little solution to precision test paper with glass bar, with standard
Colour atla compares, and reads the pH value of sample.
Non-volatile content measures the sample quality of nonvolatile component and original sample matter under the conditions of certain time and temperature
The ratio of amount, is indicated with quality percentage, and nonvolatile component includes solid and liquid；Weighing bottle first dries 1.5h in an oven,
Removal is placed in cooling in drier, weighs 1g sample and pours into dried weighing bottle, is accurate to 0.0002g, and gently shake
Weighing bottle is shaken, so that sample is uniformly distributed in weighing bottle bottom, bottle cap will be weighed and slightly opened, as in baking oven, open drum
Weighing bottle bottle cap sealing is put into drier and is cooled to room temperature by wind baking 3h, is weighed, is passed through X=100%*(m2-m1)/m,
Middle X is non-volatile content %, and m1 is weighing bottle quality g, and m2 is the quality of weighing bottle and sample after drying process, and m1 is to claim
Measuring bottle and sample original quality, taking the arithmetic mean number of secondary parallel determination is measurement result, the difference of secondary parallel determinations
It is effective no more than 0.3%.
Viscosimetric analysis is according to " GB/T 15357-2014 surfactant and detergent rotary viscosity design determining liquid product
Viscosity and flowing property " standard regulation.
Flame retardant property, including after flame time, density flaming droplet time and char length, according to " GB/T 5455-2014 is spun
The measurement that fabric combustibility vertical direction char length glows with after flame time ".
In addition limits of harmful substances measures, according to " HJ2537-2014 environmental labelling product technical requirements water paint " phase
Standard regulation in pass executes.
The above is only better embodiment of the invention, not makes any form of restriction to invention, it is all according to
According to technical principle any simple modification, equivalent variations or modification made to the above embodiment of the invention, the present invention is still fallen within
In the range of technical solution.
Claims (10)
1. a kind of modified back water-coating fire retardant glue of textile fabric, which is characterized in that be made of following weight item: A group ingredient,
5 parts ~ 7 parts of aluminium hydroxide, 3 parts ~ 5 parts of calcium carbonate, 3 parts ~ 5 parts of antimony oxide, 30 parts ~ 40 parts of deionized water；B group ingredient, water
Property 30 parts ~ 35 parts of acrylic emulsion, 15 parts ~ 20 parts of decabromodiphenylethane, 4 parts ~ 7 parts of cosolvent, 10 parts ~ 20 parts of deionized water.
2. a kind of modified back water-coating fire retardant glue of textile fabric according to claim 1, which is characterized in that by weighing as follows
It measures into and is grouped as: A group ingredient, 5 parts of aluminium hydroxide, 3 parts of calcium carbonate, 3 parts of antimony oxide, 30 parts of deionized water；B group ingredient,
30 parts of aqueous acrylic emulsion, 16 parts of decabromodiphenylethane, 4 parts of cosolvent, 10 parts of deionized water.
3. a kind of modified back water-coating fire retardant glue of textile fabric according to claim 1, which is characterized in that by weighing as follows
It measures into and is grouped as: A group ingredient, 6 parts of aluminium hydroxide, 4 parts of calcium carbonate, 3 parts of antimony oxide, 35 parts of deionized water；B group ingredient,
32 parts of aqueous acrylic emulsion, 18 parts of decabromodiphenylethane, 5 parts of cosolvent, 15 parts of deionized water.
4. a kind of modified back water-coating fire retardant glue of textile fabric according to claim 1, which is characterized in that by weighing as follows
It measures into and is grouped as: A group ingredient, 7 parts of aluminium hydroxide, 5 parts of calcium carbonate, 4 parts of antimony oxide, 40 parts of deionized water；B group ingredient,
35 parts of aqueous acrylic emulsion, 20 parts of decabromodiphenylethane, 7 parts of cosolvent, 20 parts of deionized water.
5. a kind of textile fabric as claimed in any of claims 1 to 4 modified back water-coating fire retardant glue, feature
Be: the cosolvent is the mixed liquor of dipropylene glycol methyl ether and dipropylene glycol, wherein dipropylene glycol methyl ether and dipropylene glycol
Ratio is between 0.25 ~ 0.4.
6. a kind of modified back water-coating fire retardant glue of textile fabric according to claim 5, it is characterised in that: dipropylene glycol
The ratio of methyl ether and dipropylene glycol is 3:10.
7. a kind of method for preparing the modified back water-coating fire retardant glue of textile fabric, which comprises the steps of:
S1, according to above-mentioned weight proportion, the aluminium hydroxide of deionized water, calcium carbonate and 1/2 proportion, heating are added in agitator tank
It to 35 DEG C ~ 40 DEG C, while persistently being stirred in agitator tank, mixing speed is 300r/min ~ 350r/min, continues mixing time
15min~20min；Then again by antimony oxide and residue 1/2 proportion aluminium hydroxide be added agitator tank in, be warming up to 45 DEG C ~
50 DEG C, while persistently being stirred in agitator tank, mixing speed is 420r/min ~ 450r/min, lasting mixing time 30min ~
45min, heat preservation stand 10min ~ 15min, obtain prefabricated mixed liquor A；
S2, according to above-mentioned weight proportion, deionized water, aqueous acrylic emulsion, decabromodiphenylethane are added in agitator tank, adds
Heat persistently stirs in agitator tank to 30 DEG C ~ 35 DEG C, and mixing speed is 300r/min ~ 350r/min, continues mixing time
10min~25min；Then cosolvent is added in agitator tank again, is warming up to 35 DEG C ~ 40 DEG C, while persistently stirring in agitator tank,
Mixing speed is 450r/min ~ 500r/min, continues mixing time 25min ~ 35min, and heat preservation stands 10min ~ 15min, filtering
After obtain prefabricated mixed liquid B；
S3, prefabricated mixed liquor A will be obtained in step S1 be poured into the prefabricated mixed liquid B obtained in step S2, be heated to 40 DEG C ~
50 DEG C, while persistently being stirred in agitator tank, mixing speed is 500r/min ~ 600r/min, lasting mixing time 20min ~
30min naturally cools to room temperature, obtains white paste finished product.
8. a kind of method for preparing the modified back water-coating fire retardant glue of textile fabric according to claim 7, feature exist
In including the following steps:
S1, according to above-mentioned weight proportion, the aluminium hydroxide of deionized water, calcium carbonate and 1/2 proportion, heating are added in agitator tank
It to 35 DEG C, while persistently being stirred in agitator tank, mixing speed 350r/min, continues mixing time 16min；Then again by three oxygen
The aluminium hydroxide for changing 1/2 proportion of two antimony and residue is added in agitator tank, is warming up to 48 DEG C, while persistently stirring in agitator tank, stirs
Mixing speed is 420r/min, continues mixing time 35min, and heat preservation stands 10min, obtains prefabricated mixed liquor A；
S2, according to above-mentioned weight proportion, deionized water, aqueous acrylic emulsion, decabromodiphenylethane are added in agitator tank, adds
Heat persistently stirs in agitator tank to 32 DEG C, mixing speed 320r/min, continues mixing time 15min；Then it will help again
Solvent is added in agitator tank, is warming up to 40 DEG C, while persistently stirring in agitator tank, mixing speed 480r/min, lasting to stir
Time 30min, heat preservation stand 10min, prefabricated mixed liquid B are obtained after filtering；
S3, prefabricated mixed liquor A will be obtained in step S1 be poured into the prefabricated mixed liquid B obtained in step S2, be heated to 45 DEG C,
It is persistently stirred in agitator tank simultaneously, mixing speed 550r/min continues mixing time 25min, naturally cools to room temperature, obtains
White paste finished product.
9. a kind of method for preparing the modified back water-coating fire retardant glue of textile fabric according to claim 7, feature exist
In including the following steps:
S1, according to above-mentioned weight proportion, the aluminium hydroxide of deionized water, calcium carbonate and 1/2 proportion, heating are added in agitator tank
It to 36 DEG C, while persistently being stirred in agitator tank, mixing speed 360r/min, continues mixing time 18min；Then again by three oxygen
The aluminium hydroxide for changing 1/2 proportion of two antimony and residue is added in agitator tank, is warming up to 48 DEG C, while persistently stirring in agitator tank, stirs
Mixing speed is 430r/min, continues mixing time 35min, and heat preservation stands 12min, obtains prefabricated mixed liquor A；
S2, according to above-mentioned weight proportion, deionized water, aqueous acrylic emulsion, decabromodiphenylethane are added in agitator tank, adds
Heat persistently stirs in agitator tank to 32 DEG C, mixing speed 330r/min, continues mixing time 18min；Then it will help again
Solvent is added in agitator tank, is warming up to 40 DEG C, while persistently stirring in agitator tank, mixing speed 480r/min, lasting to stir
Time 30min, heat preservation stand 12min, prefabricated mixed liquid B are obtained after filtering；
S3, prefabricated mixed liquor A will be obtained in step S1 be poured into the prefabricated mixed liquid B obtained in step S2, be heated to 45 DEG C,
It is persistently stirred in agitator tank simultaneously, mixing speed 550r/min continues mixing time 25min, naturally cools to room temperature, obtains
White paste finished product.
10. a kind of method for preparing the modified back water-coating fire retardant glue of textile fabric according to claim 7, feature exist
In including the following steps:
S1, according to above-mentioned weight proportion, the aluminium hydroxide of deionized water, calcium carbonate and 1/2 proportion, heating are added in agitator tank
It to 38 DEG C, while persistently being stirred in agitator tank, mixing speed 350r/min, continues mixing time 20min；Then again by three oxygen
The aluminium hydroxide for changing 1/2 proportion of two antimony and residue is added in agitator tank, is warming up to 50 DEG C, while persistently stirring in agitator tank, stirs
Mixing speed is 450r/min, continues mixing time 40min, and heat preservation stands 15min, obtains prefabricated mixed liquor A；
S2, according to above-mentioned weight proportion, deionized water, aqueous acrylic emulsion, decabromodiphenylethane are added in agitator tank, adds
Heat persistently stirs in agitator tank to 32 DEG C, mixing speed 330r/min, continues mixing time 20min；Then it will help again
Solvent is added in agitator tank, is warming up to 40 DEG C, while persistently stirring in agitator tank, mixing speed 480r/min, lasting to stir
Time 30min, heat preservation stand 15min, prefabricated mixed liquid B are obtained after filtering；
S3, prefabricated mixed liquor A will be obtained in step S1 be poured into the prefabricated mixed liquid B obtained in step S2, be heated to 45 DEG C,
It is persistently stirred in agitator tank simultaneously, mixing speed 550r/min continues mixing time 25min, naturally cools to room temperature, obtains
White paste finished product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811638298.3A CN109651983A (en) | 2018-12-29 | 2018-12-29 | A kind of textile fabric modified back water-coating fire retardant glue and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811638298.3A CN109651983A (en) | 2018-12-29 | 2018-12-29 | A kind of textile fabric modified back water-coating fire retardant glue and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN109651983A true CN109651983A (en) | 2019-04-19 |
Family
ID=66118507
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201811638298.3A Pending CN109651983A (en) | 2018-12-29 | 2018-12-29 | A kind of textile fabric modified back water-coating fire retardant glue and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN109651983A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111893779A (en) * | 2020-07-23 | 2020-11-06 | 杭州众逸布业有限公司 | Three-proofing sofa fabric and preparation method thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101654604A (en) * | 2008-08-20 | 2010-02-24 | Lg化学株式会社 | Composition of acrylic pressure-sensitive adhesive and surface finishing material comprising the same |
| CN105462469A (en) * | 2015-11-27 | 2016-04-06 | 自贡市华尔美科技有限公司 | House inner wall decorative coating |
| CN106366723A (en) * | 2016-10-18 | 2017-02-01 | 嘉兴市新加新化工有限公司 | Burnthrough-resistant water-based fire retardant glue for spinning |
| CN106833196A (en) * | 2017-01-24 | 2017-06-13 | 安徽华晟涂料有限公司 | A kind of extinguishing waterborn coating |
| CN107556840A (en) * | 2017-09-05 | 2018-01-09 | 绍兴思安阻燃科技有限公司 | A kind of chemical fibre sofa fabric flame retardant |
-
2018
- 2018-12-29 CN CN201811638298.3A patent/CN109651983A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101654604A (en) * | 2008-08-20 | 2010-02-24 | Lg化学株式会社 | Composition of acrylic pressure-sensitive adhesive and surface finishing material comprising the same |
| CN105462469A (en) * | 2015-11-27 | 2016-04-06 | 自贡市华尔美科技有限公司 | House inner wall decorative coating |
| CN106366723A (en) * | 2016-10-18 | 2017-02-01 | 嘉兴市新加新化工有限公司 | Burnthrough-resistant water-based fire retardant glue for spinning |
| CN106833196A (en) * | 2017-01-24 | 2017-06-13 | 安徽华晟涂料有限公司 | A kind of extinguishing waterborn coating |
| CN107556840A (en) * | 2017-09-05 | 2018-01-09 | 绍兴思安阻燃科技有限公司 | A kind of chemical fibre sofa fabric flame retardant |
Non-Patent Citations (2)
| Title |
|---|
| 刘东发 等: "环保阻燃聚丙烯的研究", 《塑料工业》 * |
| 马元好 等: "高光泽阻燃增强PET-PBT合金材料的研究与开发", 《现代工业经济和信息化》 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111893779A (en) * | 2020-07-23 | 2020-11-06 | 杭州众逸布业有限公司 | Three-proofing sofa fabric and preparation method thereof |
| CN111893779B (en) * | 2020-07-23 | 2022-09-06 | 杭州众逸布业有限公司 | Three-proofing sofa fabric and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104109444B (en) | Biomass interior wall coating and preparation method thereof | |
| CN107243968B (en) | A kind of colouring method of wicker wicker plaiting article | |
| CN109234043A (en) | A kind of laundry lasting pearl and preparation method thereof | |
| CN109651983A (en) | A kind of textile fabric modified back water-coating fire retardant glue and preparation method thereof | |
| CN101942771B (en) | Cotton-polyester fabric burn-out printing gum and preparation method thereof | |
| CN103725071A (en) | Method for self-making finger painting pigment from food materials | |
| CN107044058A (en) | Resist agent and preparation method, batik and batik method | |
| CN105625051A (en) | Environment-friendly and safe printing paste and printing color paste as well as application of printing paste and printing color paste | |
| CN103409994A (en) | Dry method polyacrylonitrile fiber oil and manufacture method thereof | |
| CN103790043B (en) | A kind of environmental protection high temperature levelling agent and preparation method thereof | |
| CN103937291B (en) | A kind of stamp Disperse black azo dye mixture and preparation method thereof | |
| CN109023998B (en) | Safe and environment-friendly printing paste and preparation method thereof | |
| CN107254785A (en) | A kind of application of high temperature direct-injection dispersible ink | |
| CN104530755A (en) | Composite active black dye | |
| CN102828422B (en) | Preparation method of environment-friendly high temperature leveling agent | |
| CN111712547B (en) | Basic dye composition, dyeing method using same, and dyed product | |
| CN106120396A (en) | A kind of environment-friendly type migration inhibitor and preparation method thereof | |
| CN108583141B (en) | A kind of production method of propylene casting picture | |
| CN110004509A (en) | A kind of colorful flame-retardant fiber and preparation method thereof | |
| CN102787487B (en) | Application of nano transparent thermal insulation coating on textile fabrics | |
| CN109183457A (en) | A kind of extruding accelerant and preparation method thereof | |
| CN105671995B (en) | A kind of environmental protection dyeing antishifting agent and preparation method thereof | |
| CN104179042A (en) | Dye fixing agent and preparation method of dye fixing agent | |
| CN107254784A (en) | A kind of high temperature direct-injection dispersible ink and preparation method thereof | |
| CN106758417A (en) | The preparation method and obtained color fixing agent of a kind of pad dyeing high temperature resistant acidic color fixing agent |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20190419 |
|
| RJ01 | Rejection of invention patent application after publication |