CN109649031A - A kind of laminated multi-layer formula is without chromatography side transfer film - Google Patents

A kind of laminated multi-layer formula is without chromatography side transfer film Download PDF

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Publication number
CN109649031A
CN109649031A CN201811376101.3A CN201811376101A CN109649031A CN 109649031 A CN109649031 A CN 109649031A CN 201811376101 A CN201811376101 A CN 201811376101A CN 109649031 A CN109649031 A CN 109649031A
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China
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layer
hole
ink layer
ink
parts
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Granted
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CN201811376101.3A
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Chinese (zh)
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CN109649031B (en
Inventor
陈志润
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Jiangsu Xuetai Printing Co Ltd
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Jiangsu Xuetai Printing Co Ltd
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41MPRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00Duplicating or marking methods; Sheet materials for use therein
    • B41M5/025Duplicating or marking methods; Sheet materials for use therein by transferring ink from the master sheet
    • B41M5/035Duplicating or marking methods; Sheet materials for use therein by transferring ink from the master sheet by sublimation or volatilisation of pre-printed design, e.g. sublistatic
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41MPRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00Duplicating or marking methods; Sheet materials for use therein
    • B41M5/025Duplicating or marking methods; Sheet materials for use therein by transferring ink from the master sheet
    • B41M5/035Duplicating or marking methods; Sheet materials for use therein by transferring ink from the master sheet by sublimation or volatilisation of pre-printed design, e.g. sublistatic
    • B41M5/0353Duplicating or marking methods; Sheet materials for use therein by transferring ink from the master sheet by sublimation or volatilisation of pre-printed design, e.g. sublistatic using heat shrinkable film material; Thermotransfer combined with the shaping of the workpiece; Recto-verso printing; Image correction
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41MPRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00Duplicating or marking methods; Sheet materials for use therein
    • B41M5/025Duplicating or marking methods; Sheet materials for use therein by transferring ink from the master sheet
    • B41M5/035Duplicating or marking methods; Sheet materials for use therein by transferring ink from the master sheet by sublimation or volatilisation of pre-printed design, e.g. sublistatic
    • B41M5/0356Duplicating or marking methods; Sheet materials for use therein by transferring ink from the master sheet by sublimation or volatilisation of pre-printed design, e.g. sublistatic characterised by the inks used for printing the pattern on the temporary support or additives therefor, e.g. dyes, transferable compounds, binders or transfer promoting additives
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41MPRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00Duplicating or marking methods; Sheet materials for use therein
    • B41M5/025Duplicating or marking methods; Sheet materials for use therein by transferring ink from the master sheet
    • B41M5/035Duplicating or marking methods; Sheet materials for use therein by transferring ink from the master sheet by sublimation or volatilisation of pre-printed design, e.g. sublistatic
    • B41M5/0358Duplicating or marking methods; Sheet materials for use therein by transferring ink from the master sheet by sublimation or volatilisation of pre-printed design, e.g. sublistatic characterised by the mechanisms or artifacts to obtain the transfer, e.g. the heating means, the pressure means or the transport means
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41MPRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M2205/00Printing methods or features related to printing methods; Location or type of the layers
    • B41M2205/36Backcoats; Back layers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41MPRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M2205/00Printing methods or features related to printing methods; Location or type of the layers
    • B41M2205/38Intermediate layers; Layers between substrate and imaging layer
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41MPRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M2205/00Printing methods or features related to printing methods; Location or type of the layers
    • B41M2205/40Cover layers; Layers separated from substrate by imaging layer; Protective layers; Layers applied before imaging
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41MPRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M2205/00Printing methods or features related to printing methods; Location or type of the layers
    • B41M2205/42Multiple imaging layers

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  • Laminated Bodies (AREA)

Abstract

A kind of laminated multi-layer formula is without chromatography side transfer film; belong to cultural product printing technical field of new material preparation; including base film layer, release layer, protective layer, the first ink layer, the second ink layer, third ink layer and the adhesive layer from top to bottom successively stacked; the first base film layer is equipped between first ink layer and the second ink layer; the second base film layer is equipped between second ink layer and third ink layer; the thickness of second ink layer is greater than the thickness of the first ink layer, and the thickness of the third ink layer is greater than the sum of the first ink layer and the second ink film thickness.The present invention passes through multiple thermal transfer, the pattern being arranged on different ink layers can be finally synthesizing to a secondary pattern and be printed on product surface to be printed, and figure is equipped with concaveconvex structure, improve the aesthetic measure and quality of printed matter, it is able to carry out the design of diversified complex pattern, the concave convex texture structure of formation, after carrying out thermal transfer, it is imitated with more vision, enriches the design space sense of transfer film.

Description

A kind of laminated multi-layer formula is without chromatography side transfer film
Technical field
The invention belongs to cultural products to print technical field of new material preparation, and in particular, to a kind of laminated multi-layer formula without Chromatography side transfer film.
Background technique
Hot-pressing transfer printing film refers to the picture and text with solid, can be together with protective layer under heating power and/or pressure effect It is separated from carrier film, securely then has the print film of specific function in surface of the stock.Traditional conventional plastic cement hot-pressing transfer printing film It is by carrier film, the release layer that carrier film can be made to be detached from, decorative layer and the following layer composition for playing cementation, decorative layer is generally wrapped Include protective layer, the picture and text layer to shield to picture and text surface.Protective layer is usually to be made of polyurethane or acrylic resin Layer of transparent smooth resin layer after transfer, makes printing object possess a smooth, bright surface.
But at present transfer film be generally directly print good pattern or by icking tool depict corresponding pattern into Row forms the printed patterns of plane on product after printing, for currently requiring that higher and higher pattern print request, how The printing effect for enough showing concaveconvex structure improves the quality of thermal transfer, is that there are no solve the problems, such as in currently available technology.
Summary of the invention
Goal of the invention: the object of the present invention is to provide a kind of laminated multi-layer formulas without chromatography side transfer film, solves current heat The technical issues of transfer film prints product surface single effect, can only carry out planographic effect.
Technical solution: the present invention provides a kind of laminated multi-layer formulas without chromatography side transfer film, including base film layer, release layer, Protective layer, the first ink layer, the second ink layer, third ink layer and adhesive layer, the base film layer, release layer, protective layer, first Ink layer, the second ink layer, third ink layer and adhesive layer are successively stacked according to sequence from top to bottom, on first ink layer Equipped with first through hole and the second through-hole, second ink layer is equipped with third through-hole and the first graph area, first figure Area is correspondingly arranged up and down with first through hole, and the first graph area is identical as first through hole shape, the third through-hole and second Through-hole face setting up and down, and third through-hole is identical as the shape of the second through-hole, and the third ink layer is equipped with the second figure Shape area, the second graph area and third through-hole and the second through-hole are correspondingly arranged up and down, and second graph area, third through-hole and The shape of second through-hole is identical, and first ink layer, the second ink layer and third ink layer are all made of UV photo-curing material, institute It states and is equipped with the first base film layer between the first ink layer and the second ink layer, first base film layer is equipped with and first through hole and the The corresponding fourth hole of two through-holes and fifth hole are equipped with the second base film layer between second ink layer and third ink layer, Second base film layer is equipped with the 6th through-hole corresponding with third through-hole, and the thickness of second ink layer is greater than the first ink The thickness of the thickness of layer, the third ink layer is greater than the sum of the first ink layer and the second ink film thickness.
Further, above-mentioned laminated multi-layer formula includes: without chromatography side transfer film, the UV photo-curing material
30-50 parts of epoxy acrylate
40-60 parts of acrylate
1-5 parts of photoinitiator
0.1-0.2 parts of levelling agent
0.1-0.3 parts of defoaming agent
0.1-0.2 parts of stabilizer
0.1-0.4 parts of dispersing agent.
The present invention provides a kind of manufacture craft of the laminated multi-layer formula without chromatography side transfer film, includes the following steps:
1) base film layer unreels: base film layer passes through among printing cylinder and plate cylinder, adjusts setting printing paper and drying Temperature;
2) coating of release layer: importing hopper for release coating, using silk version printing, with the auxiliary rotation of reticulate pattern intaglio plate in hopper, So that ink cell is stained with coating, while hanging by coating extra outside anilox roll ink cell with scraper, presses auxiliary pressure that will apply by rubber Material is transferred on substrate film, so that solvent is volatilized by drying tunnel;
3) coating of protective layer: heat-curable component and curing agent being mixed and stirred evenly, using the painting of release layer in step 2 Mode for cloth is coated;
4) coating of third ink layer: the base film layer picture and text with release layer and protective layer are stenciled using intaglio process and are located at second On graph area, except other regions in second graph area are transparent region;
5) coating of the second ink layer: third through-hole and the 6th through-hole are blocked, in the picture and text with the second base film layer using recessed Version printing print is located on the first graph area, other regions on the second ink layer except the first graph area are transparent region;
6) coating of the first ink layer: first through hole, the second through-hole, fourth hole and fifth hole are blocked, and will have first The picture and text of base film layer are stenciled to set and are printed on the first ink layer using intaglio process, make solvent volatilization, drying by drying tunnel.
The present invention provides a kind of manufacture craft of the laminated multi-layer formula without chromatography side transfer film, further includes following steps:
7) third through-hole, the 6th through-hole, first through hole, the second through-hole, fourth hole and fifth hole is fully open, by base Film, release layer, protective layer, the first ink layer, the second ink layer, third ink layer and adhesive layer are folded according to sequence from top to bottom It puts, and places the first base film layer between the first ink layer and the second ink layer, put between the second ink layer and third ink layer Set the second base film layer;
8) winder is dried by adhesive even spread and printing film in the coating process for using intaglio printing.
The present invention provides a kind of manufacture craft of the laminated multi-layer formula without chromatography side transfer film, further includes following steps:
Above-mentioned steps 7) in, the second graph area on third ink layer is arranged with face above and below third through-hole and the 6th through-hole.
The present invention provides a kind of manufacture craft of the laminated multi-layer formula without chromatography side transfer film, further includes following steps:
Above-mentioned steps 7) in, by the second graph area on third ink layer, third through-hole, the 6th through-hole, the second through-hole and the 5th Through-hole face setting up and down, by the second ink layer the first graph area, face is arranged above and below first through hole and fourth hole.
Further, above-mentioned laminated multi-layer formula is without chromatography side transfer film, and the weight of the levelling agent raw material is such as Under:
50 parts of organic silicon modified by polyether
5 parts of nanosized SiO_2-Ag antibacterial agent
0.9 part of nano-titanium oxide
1.2 parts of nano silicon oxide
30 parts of N,N-Dimethylformamide
0.13 part of suspending agent.
Further, above-mentioned laminated multi-layer formula is without chromatography side transfer film, and the weight of the defoaming agent raw material is such as Under:
25 parts of dimethicone,
3.5 parts of potassium iodide
6 parts of polyethers
4 parts of paraffin
7 parts of emulsifier
4 parts of ethylene glycol
1 part of stearic acid
8 parts of tributyl phosphate.
Further, above-mentioned laminated multi-layer formula is without chromatography side transfer film, and the weight of the stabilizer raw material is such as Under:
1- ethanamidine base -20 parts of second river -1.1- di 2 ethylhexyl phosphonic acid
3 parts of Sodium Polyacrylate
2 parts of ethylene glycol.
Above-mentioned technical proposal can be seen that the invention has the following beneficial effects: laminated multi-layer formulas of the present invention without chromatography The pattern being arranged on different ink layers can be finally synthesizing a secondary pattern and be printed on by side transfer film by multiple thermal transfer Product surface to be printed, and figure is equipped with concaveconvex structure, improves the aesthetic measure and quality of printed matter, is able to carry out multiplicity Change the design of complex pattern, the concave convex texture structure of formation imitates with more vision after carrying out thermal transfer, enriches and turn Feel the design space of die.
Detailed description of the invention
Fig. 1 is structural schematic diagram of the laminated multi-layer formula without chromatography side transfer film of the present invention;
Fig. 2 is the structural schematic diagram of the first ink layer of the present invention;
Fig. 3 is the structural schematic diagram of the second ink layer of the present invention;
Fig. 4 is the structural schematic diagram of third ink layer of the present invention;
Fig. 5 is the structural schematic diagram of the first base film layer of the present invention;
Fig. 6 is the structural schematic diagram of the second base film layer of the present invention.
In figure: base film layer 1, release layer 2, protective layer 3, the first ink layer 4, first through hole 41, second the 42, second oil of through-hole Layer of ink 5, third through-hole 51, the first graph area 52, third ink layer 6, second graph area 61, adhesive layer 7, the first base film layer 8, Four through-holes 81, fifth hole 82, the second base film layer 9, the 6th through-hole 91.
Specific embodiment
The embodiment of the present invention is described below in detail, examples of the embodiments are shown in the accompanying drawings, wherein from beginning to end Same or similar label indicates same or similar element or element with the same or similar functions.Below with reference to attached The embodiment of figure description is exemplary, it is intended to is used to explain the present invention, and is not considered as limiting the invention.
In the description of the present invention, it is to be understood that, term " center ", " longitudinal direction ", " transverse direction ", " length ", " width ", " thickness ", "upper", "lower", "front", "rear", "left", "right", "vertical", "horizontal", "top", "bottom" "inner", " clockwise ", " inverse The orientation or positional relationship of the instructions such as hour hands " is to be based on the orientation or positional relationship shown in the drawings, and is merely for convenience of description originally Invention and simplified description, rather than the device or element of indication or suggestion meaning must have a particular orientation, with specific side Position construction and operation, therefore be not considered as limiting the invention.
In addition, term " first ", " second " are used for descriptive purposes only and cannot be understood as indicating or suggesting relative importance Or implicitly indicate the quantity of indicated technical characteristic.Define " first " as a result, the feature of " second " can be expressed or Implicitly include one or more of the features.In the description of the present invention, unless otherwise indicated, the meaning of " plurality " is two It is a or more than two, unless otherwise restricted clearly.
In the present invention unless specifically defined or limited otherwise, term " installation ", " connected ", " connection ", " fixation " etc. Term shall be understood in a broad sense, for example, it may be being fixedly connected, may be a detachable connection, or be integrally connected;It can be machine Tool connection, is also possible to be electrically connected;It can be directly connected, two members can also be can be indirectly connected through an intermediary Connection inside part.For the ordinary skill in the art, above-mentioned term can be understood in this hair as the case may be Concrete meaning in bright.
In the present invention unless specifically defined or limited otherwise, fisrt feature second feature "upper" or "lower" It may include that the first and second features directly contact, also may include that the first and second features are not direct contacts but pass through it Between other characterisation contact.Moreover, fisrt feature includes the first spy above the second feature " above ", " above " and " above " Sign is right above second feature and oblique upper, or is merely representative of first feature horizontal height higher than second feature.Fisrt feature exists Second feature " under ", " lower section " and " following " include that fisrt feature is directly below and diagonally below the second feature, or is merely representative of First feature horizontal height is less than second feature.
Embodiment
Laminated multi-layer formula as shown in Figure 1 is without chromatography side transfer film, including base film layer 1, release layer 2, protective layer 3, first Ink layer 4, the second ink layer 5, third ink layer 6 and adhesive layer 7, the base film layer 1, release layer 2, protective layer 3, the first ink The 4, second ink layer 5 of layer, third ink layer 6 and adhesive layer 7 are successively stacked according to sequence from top to bottom, first ink layer 4 It is equipped with first through hole 41 and the second through-hole 42, second ink layer 5 is equipped with third through-hole 51 and the first graph area 52, institute It states the first graph area 52 to be correspondingly arranged with about 41 first through hole, and the first graph area 52 is identical as 41 shape of first through hole, The third through-hole 51 and about 42 face of the second through-hole are arranged, and third through-hole 51 is identical as the shape of the second through-hole 42, The third ink layer 6 is equipped with second graph area 61, the second graph area 61 on third through-hole 51 and the second through-hole 42 Under be correspondingly arranged, and second graph area 61, third through-hole 51 are identical with the shape of the second through-hole 42, first ink layer 4, Second ink layer 5 and third ink layer 6 are all made of UV photo-curing material, set between first ink layer 4 and the second ink layer 5 Have the first base film layer 8, first base film layer 8 be equipped with fourth hole 81 corresponding with first through hole 41 and the second through-hole 42 and Fifth hole 82 is equipped with the second base film layer 9, on second base film layer 9 between second ink layer 5 and third ink layer 6 Equipped with the 6th through-hole 91 corresponding with third through-hole 51, the thickness of second ink layer 5 is greater than the thickness of the first ink layer 4, The thickness of the third ink layer 6 is greater than the sum of 5 thickness of the first ink layer 4 and the second ink layer.
The UV photo-curing material used in the application includes:
30-50 parts of epoxy acrylate
40-60 parts of acrylate
1-5 parts of photoinitiator
0.1-0.2 parts of levelling agent
0.1-0.3 parts of defoaming agent
0.1-0.2 parts of stabilizer
0.1-0.4 parts of dispersing agent.
On the basis of above-mentioned transfer film, a kind of manufacture craft of the laminated multi-layer formula without chromatography side transfer film of the present invention, Include the following steps:
1) base film layer 1 unreels: base film layer 1 passes through among printing cylinder and plate cylinder, adjusts setting printing paper and baking Dry temperature;
2) coating of release layer 2: importing hopper for release coating, using silk version printing, with the auxiliary rotation of reticulate pattern intaglio plate in hopper, So that ink cell is stained with coating, while hanging by coating extra outside anilox roll ink cell with scraper, presses auxiliary pressure that will apply by rubber Material is transferred on substrate film, so that solvent is volatilized by drying tunnel;
3) coating of protective layer 3: heat-curable component and curing agent being mixed and stirred evenly, using release layer 2 in step 2 Coating method is coated;
4) coating of third ink layer 6: 1 picture and text of base film layer with release layer 2 and protective layer 3 are stenciled using intaglio process and are located at In second graph area 61, except other regions in second graph area 61 are transparent region;
5) coating of the second ink layer 5: third through-hole 51 and the 6th through-hole 91 are blocked, in the picture and text for having the second base film layer 9 It is stenciled and is located on the first graph area 52 using intaglio process, other regions on the second ink layer 5 except the first graph area 52 are transparent Region;
6) coating of the first ink layer 4: first through hole 41, the second through-hole 42, fourth hole 81 and fifth hole 82 are blocked, Picture and text with the first base film layer 8 are stenciled to set using intaglio process and are printed on the first ink layer 4, wave solvent by drying tunnel Hair, drying.
Further include following steps in specific above-mentioned steps:
7) third through-hole 51, the 6th through-hole 91, first through hole 41, the second through-hole 42, fourth hole 81 and fifth hole 82 is complete Portion opens, by base film layer 1, release layer 2, protective layer 3, the first ink layer 4, the second ink layer 5, third ink layer 6 and adhesive layer 7 According to from top to bottom sequentially stacking, and the first base film layer 8, the second ink are placed between the first ink layer 4 and the second ink layer 5 The second base film layer 9 is placed between layer 5 and third ink layer 6;
8) winder is dried by adhesive even spread and printing film in the coating process for using intaglio printing.
Above-mentioned steps 7) in, it will be in the second graph area 61 and third through-hole 51 and the 6th through-hole 91 on third ink layer 6 Lower face setting.
Above-mentioned steps 7) in, by the second graph area 61 on third ink layer 6, third through-hole 51, the 6th through-hole 91, second Through-hole 42 and fifth hole 82 face setting up and down, by the first graph area 52 on the second ink layer 5, first through hole 41 and the The setting of four through-holes, about 81 face.
When above-mentioned transfer film carries out thermal transfer, the first ink layer 4, the second ink layer 5, third ink layer 6 individually into Row printing, there are two the first pattern layers of through-hole by the first ink layer 4 and the first base film layer 8 formation band by head, then by second Ink layer 5 and the second base film layer 9 are located in the first pattern layer, carry out thermal transfer, the first graph area 52 is printed onto the first pattern On layer, since the thickness of two ink layers 5 is greater than the thickness of the first ink layer 4, so the first graph area 52 can protrude the first ink Third ink layer 6, is finally located on molding second layer pattern by layer 4, carries out thermal transfer, the printing of second graph area 61 to the In one pattern layer, because therefore the thickness of three ink layers 6 is greater than the sum of 5 thickness of the first ink layer 4 and the second ink layer, finally Form the unity structure that concave-convex surface rises and falls.
In order to improve the performance of UV photo-curing material, special configuration, the parts by weight of levelling agent raw material are carried out to partial supplementary material It matches as follows:
50 parts of organic silicon modified by polyether
5 parts of nanosized SiO_2-Ag antibacterial agent
0.9 part of nano-titanium oxide
1.2 parts of nano silicon oxide
30 parts of N,N-Dimethylformamide
0.13 part of suspending agent.
The weight of the defoaming agent raw material is as follows:
25 parts of dimethicone,
3.5 parts of potassium iodide
6 parts of polyethers
4 parts of paraffin
7 parts of emulsifier
4 parts of ethylene glycol
1 part of stearic acid
8 parts of tributyl phosphate.
The weight of the stabilizer raw material is as follows:
1- ethanamidine base -20 parts of second river -1.1- di 2 ethylhexyl phosphonic acid
3 parts of Sodium Polyacrylate
2 parts of ethylene glycol.
The above is only a preferred embodiment of the present invention, it is noted that those skilled in the art are come It says, without departing from the principle of the present invention, several improvement can also be made, these improvement also should be regarded as protection of the invention Range.

Claims (9)

1. a kind of laminated multi-layer formula is without chromatography side transfer film, it is characterised in that: including base film layer (1), release layer (2), protective layer (3), the first ink layer (4), the second ink layer (5), third ink layer (6) and adhesive layer (7), the base film layer (1), release layer (2), protective layer (3), the first ink layer (4), the second ink layer (5), third ink layer (6) and adhesive layer (7) according to by up to Lower sequence successively stacks, and first ink layer (4) is equipped with first through hole (41) and the second through-hole (42), second ink Layer (5) is equipped with third through-hole (51) and the first graph area (52), and first graph area (52) and first through hole (41) are up and down It is correspondingly arranged, and the first graph area (52) are identical as first through hole (41) shape, the third through-hole (51) and the second through-hole (42) face is arranged up and down, and third through-hole (51) is identical as the shape of the second through-hole (42), on the third ink layer (6) Equipped with second graph area (61), the second graph area (61) and third through-hole (51) and the second through-hole (42) is corresponding up and down sets It sets, and second graph area (61), third through-hole (51) are identical with the shape of the second through-hole (42), first ink layer (4), Second ink layer (5) and third ink layer (6) are all made of UV photo-curing material, first ink layer (4) and the second ink layer (5) the first base film layer (8) are equipped between, first base film layer (8) is equipped with and first through hole (41) and the second through-hole (42) Corresponding fourth hole (81) and fifth hole (82) are equipped with second between second ink layer (5) and third ink layer (6) Base film layer (9), second base film layer (9) are equipped with the 6th through-hole (91) corresponding with third through-hole (51), second oil The thickness of layer of ink (5) is greater than the thickness of the first ink layer (4), and the thickness of the third ink layer (6) is greater than the first ink layer (4) The sum of with the second ink layer (5) thickness.
2. laminated multi-layer formula according to claim 1 is without chromatography side transfer film, it is characterised in that: the UV photo-curing material Include:
30-50 parts of epoxy acrylate
40-60 parts of acrylate
1-5 parts of photoinitiator
0.1-0.2 parts of levelling agent
0.1-0.3 parts of defoaming agent
0.1-0.2 parts of stabilizer
0.1-0.4 parts of dispersing agent.
3. manufacture craft of the laminated multi-layer formula without chromatography side transfer film according to claim 2, it is characterised in that: including such as Lower step:
1) base film layer (1) unreels: base film layer (1) passes through among printing cylinder and plate cylinder, adjusts setting printing paper And drying temperature;
2) coating of release layer (2): release coating is imported into hopper, using silk version printing, with the auxiliary rotation of reticulate pattern intaglio plate and hopper It is interior, so that ink cell is stained with coating, while hanging by coating extra outside anilox roll ink cell with scraper, presses auxiliary pressure will by rubber Coating is transferred on substrate film, so that solvent is volatilized by drying tunnel;
3) coating of protective layer (3): heat-curable component and curing agent are mixed and stirred evenly, using release layer in step 2 (2) coating method is coated;
4) base film layer (1) picture and text with release layer (2) and protective layer (3) coating of third ink layer (6): are used into intaglio process It stencils and is located on second graph area (61), except other regions of second graph area (61) are transparent region;
5) coating of the second ink layer (5): third through-hole (51) and the 6th through-hole (91) are blocked, and are having the second base film layer (9) picture and text are stenciled using intaglio process and are located on the first graph area (52), except the first graph area (52) on the second ink layer (5) Other regions are transparent region;
6) coating of the first ink layer (4): by first through hole (41), the second through-hole (42), fourth hole (81) and fifth hole (82) it blocks, the picture and text with the first base film layer (8) is stenciled to set and be printed on the first ink layer (4) using intaglio process, are passed through Drying tunnel makes solvent volatilization, drying.
4. manufacture craft of the laminated multi-layer formula without chromatography side transfer film according to claim 3, it is characterised in that: further include Following steps:
7) by third through-hole (51), the 6th through-hole (91), first through hole (41), the second through-hole (42), fourth hole (81) and Five through-holes (82) are fully open, by base film layer (1), release layer (2), protective layer (3), the first ink layer (4), the second ink layer (5), third ink layer (6) and adhesive layer (7) are according to from top to bottom sequentially stacking, and the first ink layer (4) and the second ink It is placed the first base film layer (8) between layer (5), the second base film layer (9) is placed between the second ink layer (5) and third ink layer (6);
8) winder is dried by adhesive even spread and printing film in the coating process for using intaglio printing.
5. manufacture craft of the laminated multi-layer formula without chromatography side transfer film according to claim 4, it is characterised in that: further include Following steps:
Above-mentioned steps 7) in, by third ink layer (6) second graph area (61) and third through-hole (51) and the 6th through-hole (91) face is arranged up and down.
6. the manufacture craft that laminated multi-layer formula according to claim 5 is transferred without chromatography side, it is characterised in that: further include as Lower step:
Above-mentioned steps 7) in, by third ink layer (6) second graph area (61), third through-hole (51), the 6th through-hole (91), The face setting up and down of second through-hole (42) and fifth hole (82), by the second ink layer (5) the first graph area (52), the Face is arranged up and down for one through-hole (41) and fourth hole (81).
7. laminated multi-layer formula according to claim 2 is without chromatography side transfer film, it is characterised in that: the levelling agent raw material Weight is as follows:
50 parts of organic silicon modified by polyether
5 parts of nanosized SiO_2-Ag antibacterial agent
0.9 part of nano-titanium oxide
1.2 parts of nano silicon oxide
30 parts of N,N-Dimethylformamide
0.13 part of suspending agent.
8. laminated multi-layer formula according to claim 7 is without chromatography side transfer film, it is characterised in that: the defoaming agent raw material Weight is as follows:
25 parts of dimethicone,
3.5 parts of potassium iodide
6 parts of polyethers
4 parts of paraffin
7 parts of emulsifier
4 parts of ethylene glycol
1 part of stearic acid
8 parts of tributyl phosphate.
9. laminated multi-layer formula according to claim 8 is without chromatography side transfer film, it is characterised in that: the stabilizer raw material Weight is as follows:
1- ethanamidine base -20 parts of second river -1.1- di 2 ethylhexyl phosphonic acid
3 parts of Sodium Polyacrylate
2 parts of ethylene glycol.
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