CN109627859A - A kind of green environment protection water wood oil - Google Patents
A kind of green environment protection water wood oil Download PDFInfo
- Publication number
- CN109627859A CN109627859A CN201811538793.7A CN201811538793A CN109627859A CN 109627859 A CN109627859 A CN 109627859A CN 201811538793 A CN201811538793 A CN 201811538793A CN 109627859 A CN109627859 A CN 109627859A
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- Prior art keywords
- agent
- wood oil
- aqueous
- environment protection
- green environment
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D125/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Coating compositions based on derivatives of such polymers
- C09D125/02—Homopolymers or copolymers of hydrocarbons
- C09D125/04—Homopolymers or copolymers of styrene
- C09D125/08—Copolymers of styrene
- C09D125/14—Copolymers of styrene with unsaturated esters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2207/00—Properties characterising the ingredient of the composition
- C08L2207/06—Properties of polyethylene
- C08L2207/062—HDPE
Abstract
A kind of green environment protection water wood oil, is film forming matter by waterborne styrene-acrylic emulsion and aqueous acrylic emulsion blending, and cooperation coalescing agent, pH value adjustment agent, defoaming agent, wetting agent, levelling agent, dispersing agent, waterproofing agent, thickener and aqueous wax liquor are prepared.Each component is by weight: waterborne styrene-acrylic emulsion 55~63%, aqueous acrylic emulsion 10~15%, coalescing agent 1.5~7%, pH value adjustment agent 0.1~0.5%, defoaming agent 0.1~0.4%, wetting agent 0.1~0.3%, levelling agent 0.05~0.3%, dispersing agent 0.2~0.5%, waterproofing agent 0.1~0.25%, thickener 0.5~1.8%, the sliding wax emulsion 0.5~2.5% of height, aqueous delustring wax liquor 1.5~5.5, deionized water 11.75~20.9%.Aqueous wood oil ordor removing prepared by the present invention, low VOC, green and healthy environmental protection non-stimulated to human body；Good penetrability has splendid adhesive force to most of timber, applied widely；The protective capability that hardness of paint film is high, surface property is good, water resistance is good, splendid；Feel is splendid, improves the added value of wooden articles.
Description
Technical field
The present invention relates to a kind of green environment protection water wood oils, belong to environmentally friendly class Waterborne wood oil tech field.
Background technique
Wood oil is originated from the tung oil tree forest fruit oil in China, the most universal with the aleurites fordii and the aleurite montana that originate in China.Tung oil tree
The oil that seed is squeezed out is tung oil；For the oil that wood oil tree seed is squeezed out wood oil, quality is slightly inferior.Wood oil is crude vegetal, belongs to stemness
Oil.
Notification number CN102604518 discloses a kind of Environment-friendlynatural natural wood oil, and the wood oil is by IPDI modified soyabean oil urushiol acid
Resin, anti skinning agent, high efficiency composition drier, composite environmental-friendly solvent are prepared, and belong to solvent borne oiliness wood oil.Solvent borne wood oil
A large amount of volatile organic compounds VOC can be generated when production, polluted the environment.
Water-borne acrylic coatings are a kind of Environmentally friendly coatings, without triphen, heavy metal, formaldehyde, poly- without alkyl phenol
Ethylene oxide ether and other poisonous and harmful substances, non-stimulated to human body, such coating has shallow color, guarantor's color, guarantor light, weather-proof, corrosion resistant
The advantages that erosion and anti-pollution, high comprehensive performance is widely used.From 2009, Chinese woodwork coating yield leapt to the whole world the
One, but wherein most of is solvent based coating, brings a large amount of VOC, for this purpose, water-borne wood coating become it is concerned by people heavy
One of point, water soluble acrylic acid woodwork coating, low VOC, good decorative property, comprehensive performance is good, and applicability is good, is that woodwork coating increases
One of most fast kind.
Woodwork is using, in storing process, is highly prone to the infringement of water, occur moisture infiltration drying process cause it is wooden
Product deformation, the wet environment mouldy raw bacterium situations such as, the service life of woodwork will can be greatly reduced in this.Woodwork is closed
The coating of reason not only can provide protection for woodwork, can also improve it apparently, promote its value.
Summary of the invention
The object of the present invention is to which in order to solve the environmental issue of woodwork coating, the present invention discloses a kind of environmental type
Aqueous wood oil.
The technical solution that the present invention realizes is as follows: a kind of green environment protection water wood oil, and the wood oil is by aqueous phenylpropyl alcohol cream
Liquid and aqueous acrylic emulsion blending are film forming matter, cooperate coalescing agent, pH value adjustment agent, defoaming agent, wetting agent, levelling
Agent, dispersing agent, waterproofing agent, thickener and aqueous wax liquor are prepared.
Each component is by weight: waterborne styrene-acrylic emulsion 55~63%, aqueous acrylic emulsion 10~15%, coalescing agent
1.5~7%, pH value adjustment agent 0.1~0.5%, defoaming agent 0.1~0.4%, wetting agent 0.1~0.3%, levelling agent 0.05~
0.3%, dispersing agent 0.2~0.5%, waterproofing agent 0.1~0.25%, thickener 0.5~1.8%, high cunning wax emulsion 0.5~
2.5%, aqueous delustring wax liquor 1.5~5.5, deionized water 11.75~20.9%.
The coalescing agent is propylene glycol monomethyl ether, dipropylene glycol methyl ether, propylene glycol phenylate, propandiol butyl ether, dipropylene glycol
Two or more in butyl ether, Texanol (ester alcohol 12).
The pH value adjustment agent is N, one or both of N dimethyl ethanol amine, AMP-95.
The defoaming agent is organosilicon aqueous defoamer, and ingredient is the mixing of polysiloxanes and hydrophobic solid polyethylene glycol
Object.
The wetting agent is organic silicon surfactant, and ingredient is polyether siloxane copolymer.
The levelling agent is the surface modifier of organic silicon, and ingredient is polyether-modified dimethyl silicone polymer solution, polyethers
The one or two of silicone copolymers.
The dispersing agent is the high molecular weight block copolymer class wetting dispersing agent with pigment affinity groups.
The waterproofing agent is waterproofing agent of organosilicon.
The thickener is polyurethane associative thickener.
The invention has the advantages that aqueous wood oil ordor removing prepared by the present invention, low VOC, non-stimulated to human body, green is strong
Kang Huanbao；Good penetrability has splendid adhesive force to most of timber, applied widely；Hardness of paint film height, surface property
Protective capability good, water resistance is good, splendid；Feel is splendid, improves the added value of wooden articles.
The waterborne styrene-acrylic emulsion that the present invention uses is quick-dry type styrene-acrylic emulsion, water-tolerant, vitrifying with higher turn
Temperature；Using aqueous alkali-soluble acrylic emulsions, glass transition temperature is lower, and flexibility is good, water-tolerant, to substrate
Permeability, adhesive force it is splendid；Two kinds of resin collocation film qualities are more preferable, excellent performance.
The present invention uses high density polyethylene waxes, anti-scratch significant, the high greasy feel of lubricating oil, and scrub performance is anti-to after-tack
With hydrophobic lotus-leaf significant effect；Using aqueous delustring wax liquor, easily disperse, transparency is high, and delustring is strong, and feel is smooth without emulsification
Agent helps defoaming；Two kinds of wax liquor compounding effects are more preferable.
Present invention employs advanced defoaming agent, levelling agent, wetting agent, dispersing agent, waterproofing agent, thickening agent aids, meet
The production of current wood oil and construction requirement.
The composite membrane-forming auxiliary agent toxicity that the present invention uses is low, smell is small, non-toxic, degradable, absolutely without benzene and VOC content
It is low, meet the requirement of environmentally protective health.
Specific embodiment
Embodiment 1:
A kind of the present embodiment green environment protection water wood oil, painting technique is made by, formula specifically at
Point and by mass ratio as follows:
Aqueous quick-drying styrene acrylic lotion 55%, aqueous alkali-soluble acrylic emulsions 15%, the first coalescing agent 5%, the
Two coalescing agents 2%, pH value adjustment agent 0.2%, defoaming agent 0.4%, wetting agent 0.3%, levelling agent 0.1%, dispersing agent
0.3%, waterproofing agent 0.2%, thickener 1.6%, the sliding wax emulsion 2% of height, aqueous delustring wax liquor 5%, deionized water 12.9%.
In the present embodiment, coalescing agent includes that two kinds: first coalescing agents are dipropylene glycol methyl ether, and the second coalescing agent is
Dipropylene.
PH value adjustment agent is multifunctional assistant AMP-95, and main component is 2-amino-2-methyl-1-propanol.
Defoaming agent is organosilicon aqueous defoamer, and main component is the mixing of polysiloxanes and hydrophobic solid polyethylene glycol
Object.
Wetting agent is organic silicon surfactant, and main component is polyether siloxane copolymer.
Levelling agent is the one or two of polyether-modified dimethyl silicone polymer solution, polyether siloxane copolymer.
Dispersing agent is the high molecular weight block copolymer class solution with pigment affinity groups.
Waterproofing agent is organosilicon cross-linking agent.
Thickener is polyurethane associative thickener.
Aqueous wax liquor in the present embodiment is high density polyethylene waxes, is used cooperatively for two kinds of polyethylene wax products, a kind of
For aqueous high sliding transparent wax emulsion, another kind is aqueous wax liquor.
Embodiment 2:
A kind of the present embodiment green environment protection water wood oil, painting technique is made by, formula specifically at
Point and by mass ratio as follows:
Aqueous quick-drying styrene acrylic lotion 55%, aqueous alkali-soluble acrylic emulsions 15%, the first coalescing agent 3%, the
Two coalescing agents 1.5%, pH value adjustment agent 0.2%, defoaming agent 0.4%, wetting agent 0.2%, levelling agent 0.5%, dispersing agent
0.1%, waterproofing agent 0.2%, thickener 1.8%, the sliding wax emulsion 1% of height, aqueous delustring wax liquor 2%, deionized water 19.1%.
There are two types of coalescing agents in the present embodiment: the first coalescing agent is dipropylene glycol methyl ether, and the second coalescing agent is
Dipropylene.
PH value adjustment agent is multifunctional assistant AMP-95, and main component is 2-amino-2-methyl-1-propanol.
Defoaming agent is organosilicon aqueous defoamer, and main component is the mixing of polysiloxanes and hydrophobic solid polyethylene glycol
Object.
Wetting agent is organic silicon surfactant, and main component is polyether siloxane copolymer.
Levelling agent is the one or two of polyether-modified dimethyl silicone polymer solution, polyether siloxane copolymer.
Dispersing agent is the high molecular weight block copolymer class solution with pigment affinity groups.
Waterproofing agent is organosilicon cross-linking agent.
Thickener is polyurethane associative thickener.
Aqueous wax liquor in the present embodiment is high density polyethylene waxes, is used cooperatively for two kinds of polyethylene wax products, a kind of
For aqueous high sliding transparent wax emulsion, another kind is aqueous wax liquor.
Embodiment 3:
A kind of the present embodiment green environment protection water wood oil, painting technique is made by, formula specifically at
Point and by mass ratio as follows:
Aqueous quick-drying styrene acrylic lotion 63%, aqueous alkali-soluble acrylic emulsions 10%, third coalescing agent 5%, the
Four coalescing agents 2%, pH value adjustment agent 0.15%, defoaming agent 0.3%, wetting agent 0.3%, levelling agent 0.1%, dispersing agent
0.3%, waterproofing agent 0.2%, thickener 1.8%, the sliding wax emulsion 2% of height, aqueous delustring wax liquor 5%, deionized water 9.85%.
There are two types of coalescing agents in the present embodiment: third coalescing agent is propylene glycol monomethyl ether, and the 4th coalescing agent is third
Glycol phenylate.
PH value adjustment agent is multifunctional assistant AMP-95, and main component is 2-amino-2-methyl-1-propanol.
Defoaming agent is organosilicon aqueous defoamer, and main component is the mixing of polysiloxanes and hydrophobic solid polyethylene glycol
Object.
Wetting agent is organic silicon surfactant, and main component is polyether siloxane copolymer.
Levelling agent is the one or two of polyether-modified dimethyl silicone polymer solution, polyether siloxane copolymer.
Dispersing agent is the high molecular weight block copolymer class solution with pigment affinity groups.
Waterproofing agent is organosilicon cross-linking agent.
Thickener is polyurethane associative thickener.
Aqueous wax liquor in the present embodiment is high density polyethylene waxes, is used cooperatively for two kinds of polyethylene wax products, a kind of
For aqueous high sliding transparent wax emulsion, another kind is aqueous wax liquor.
Embodiment 4:
A kind of the present embodiment green environment protection water wood oil, painting technique is made by, formula specifically at
Point and by mass ratio as follows:
Aqueous quick-drying styrene acrylic lotion 55%, aqueous alkali-soluble acrylic emulsions 15%, the 5th coalescing agent 5%, the
Six coalescing agents 2%, pH value adjustment agent 0.2%, defoaming agent 0.3%, wetting agent 0.3%, levelling agent 0.3%, dispersing agent
0.3%, waterproofing agent 0.2%, thickener 0.6%, the sliding wax emulsion 2% of height, aqueous delustring wax liquor 5%, deionized water 13.8%.
There are two types of coalescing agents in the present embodiment: the 5th coalescing agent is dipropylene glycol methyl ether, and the 6th coalescing agent is
Texanol (ester alcohol 12).
PH value adjustment agent is N, N dimethyl ethanol amine.
Defoaming agent is organosilicon aqueous defoamer, and main component is the mixing of polysiloxanes and hydrophobic solid polyethylene glycol
Object.
Wetting agent is organic silicon surfactant, and main component is polyether siloxane copolymer.
Levelling agent is the one or two of polyether-modified dimethyl silicone polymer solution, polyether siloxane copolymer.
Dispersing agent is the high molecular weight block copolymer class solution with pigment affinity groups.
Waterproofing agent is organosilicon cross-linking agent.
Thickener is polyurethane associative thickener.
Originally the aqueous wax liquor implemented in example is high density polyethylene waxes, is used cooperatively for two kinds of polyethylene wax products, one
Kind is aqueous high sliding transparent wax emulsion, and another kind is aqueous wax liquor.
Embodiment 5:
A kind of the present embodiment green environment protection water wood oil, painting technique is made by, formula specifically at
Point and by mass ratio as follows:
Aqueous quick-drying styrene acrylic lotion 59%, aqueous alkali-soluble acrylic emulsions 12%, the 5th coalescing agent 2%, the
Six coalescing agents 1%, pH value adjustment agent 0.17%, defoaming agent 0.3%, wetting agent 0.2%, levelling agent 0.2%, dispersing agent
0.2%, waterproofing agent 0.2%, thickener 1.9%, the sliding wax emulsion 2% of height, aqueous delustring wax liquor 3%, deionized water 17.83%.
There are two types of coalescing agents in the present embodiment: the 5th coalescing agent is dipropylene glycol methyl ether, and the 6th coalescing agent is
Texanol (ester alcohol 12).
PH value adjustment agent is multifunctional assistant AMP-95, and main component is 2-amino-2-methyl-1-propanol.
Defoaming agent is organosilicon aqueous defoamer, and main component is the mixing of polysiloxanes and hydrophobic solid polyethylene glycol
Object.
Wetting agent is organic silicon surfactant, and main component is polyether siloxane copolymer.
Levelling agent is the one or two of polyether-modified dimethyl silicone polymer solution, polyether siloxane copolymer.
Dispersing agent is the high molecular weight block copolymer class solution with pigment affinity groups.
Waterproofing agent is organosilicon cross-linking agent.
Thickener is polyurethane associative thickener.
Aqueous wax liquor in the present embodiment is high density polyethylene waxes, is used cooperatively for two kinds of polyethylene wax products, a kind of
For aqueous high sliding transparent wax emulsion, another kind is aqueous wax liquor.
The green environment protection water wood oil performance indexes and environmental protection index are as follows:
1 quick-drying styrene-acrylic emulsion performance indicator of table
| Solid content | 40% |
| PH value | 8.0-8.5 |
| Viscosity (mpa.s/25 DEG C) | 100 |
| MFFT minimum film formation temperature (DEG C) | 44 |
| Characteristic | Without alkyl phenol polyoxyethylene ether |
2 aqueous alkali-soluble acrylic emulsions performance indicator of table
| Solid content | 45% |
| PH value | 5.3 |
| Viscosity (mpa.s/25 DEG C) | 25 |
| MFFT minimum film formation temperature (DEG C) | 10 |
| Characteristic | Without alkyl phenol polyoxyethylene ether |
3 green environment protection water wood oil performance of table and limit of harmful substance index
Although the above embodiment is a preferred embodiment of the present invention, embodiments of the present invention are not by above-mentioned implementation
The constraint of example, any change made without departing from the spirit and principles of the present invention of others, substitution, combine, are simple at modification
Change, should be equivalent substitute mode, be included within the scope of the present invention.
Claims (9)
1. a kind of green environment protection water wood oil, which is characterized in that the wood oil is by waterborne styrene-acrylic emulsion and aqueous acrylamide yogurt
Liquid blending be film forming matter, cooperation coalescing agent, pH value adjustment agent, defoaming agent, wetting agent, levelling agent, dispersing agent, waterproofing agent,
Thickener and aqueous wax liquor are prepared；
Each component is by weight: waterborne styrene-acrylic emulsion 55~63%, aqueous acrylic emulsion 10~15%, and coalescing agent 1.5~
7%, pH value adjustment agent 0.1~0.5%, defoaming agent 0.1~0.4%, wetting agent 0.1~0.3%, levelling agent 0.05~0.3%, dispersion
Agent 0.2~0.5%, waterproofing agent 0.1~0.25%, thickener 0.5~1.8%, the sliding wax emulsion 0.5~2.5% of height, aqueous delustring wax liquor
1.5~5.5, deionized water 11.75~20.9%.
2. a kind of green environment protection water wood oil according to claim 1, which is characterized in that the coalescing agent is propylene glycol
Methyl ether, dipropylene glycol methyl ether, propylene glycol phenylate, propandiol butyl ether, dipropylene, two or more in ester alcohol 12.
3. a kind of green environment protection water wood oil according to claim 1, which is characterized in that the pH value adjustment agent is N, N
One or both of dimethylethanolamine, AMP-95.
4. a kind of green environment protection water wood oil according to claim 1, which is characterized in that the defoaming agent is organosilicon water
Property defoaming agent, ingredient is the mixture of polysiloxanes and hydrophobic solid polyethylene glycol.
5. a kind of green environment protection water wood oil according to claim 1, which is characterized in that the wetting agent is organosilicon table
Face activating agent, ingredient are polyether siloxane copolymers.
6. a kind of green environment protection water wood oil according to claim 1, which is characterized in that the levelling agent is organic silicon
Surface modifier, ingredient is the one or two of polyether-modified dimethyl silicone polymer solution, polyether siloxane copolymer.
7. a kind of green environment protection water wood oil according to claim 1, which is characterized in that the dispersing agent is with pigment
The high molecular weight block copolymer class wetting dispersing agent of affinity groups.
8. a kind of green environment protection water wood oil according to claim 1, which is characterized in that the waterproofing agent is organosilicon
Waterproofing agent.
9. a kind of green environment protection water wood oil according to claim 1, which is characterized in that the thickener is polyurethane
Association thickener.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811538793.7A CN109627859A (en) | 2018-12-17 | 2018-12-17 | A kind of green environment protection water wood oil |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811538793.7A CN109627859A (en) | 2018-12-17 | 2018-12-17 | A kind of green environment protection water wood oil |
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| Publication Number | Publication Date |
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| CN109627859A true CN109627859A (en) | 2019-04-16 |
Family
ID=66074363
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| CN201811538793.7A Pending CN109627859A (en) | 2018-12-17 | 2018-12-17 | A kind of green environment protection water wood oil |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111154362A (en) * | 2020-01-16 | 2020-05-15 | 上海立邦长润发涂料有限公司 | Water-based single-component tannin-resistant seal primer and preparation method thereof |
| WO2021051340A1 (en) * | 2019-09-19 | 2021-03-25 | 河北比尔尼克新材料科技股份有限公司 | Water-based paint for cast iron substrate, preparation method therefor, and application thereof |
| CN112662238A (en) * | 2020-12-03 | 2021-04-16 | 嘉宝莉化工集团股份有限公司 | Water-based woodware roller coating base paint and preparation method and application thereof |
| CN114574051A (en) * | 2021-12-31 | 2022-06-03 | 浙江鸿星文具有限公司 | Environment-friendly varnish suitable for automatic pencil coloring machine and preparation method thereof |
| CN115960501A (en) * | 2022-11-03 | 2023-04-14 | 上海君子兰新材料股份有限公司 | Water-based door and window varnish and preparation method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20020173576A1 (en) * | 2001-02-21 | 2002-11-21 | Gwin Steven R. | Coating composition |
| CN103756471A (en) * | 2013-12-18 | 2014-04-30 | 广州市诚美涂饰工程有限公司 | Water-based semi-gloss varnish |
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2018
- 2018-12-17 CN CN201811538793.7A patent/CN109627859A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20020173576A1 (en) * | 2001-02-21 | 2002-11-21 | Gwin Steven R. | Coating composition |
| CN103756471A (en) * | 2013-12-18 | 2014-04-30 | 广州市诚美涂饰工程有限公司 | Water-based semi-gloss varnish |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2021051340A1 (en) * | 2019-09-19 | 2021-03-25 | 河北比尔尼克新材料科技股份有限公司 | Water-based paint for cast iron substrate, preparation method therefor, and application thereof |
| CN111154362A (en) * | 2020-01-16 | 2020-05-15 | 上海立邦长润发涂料有限公司 | Water-based single-component tannin-resistant seal primer and preparation method thereof |
| CN112662238A (en) * | 2020-12-03 | 2021-04-16 | 嘉宝莉化工集团股份有限公司 | Water-based woodware roller coating base paint and preparation method and application thereof |
| CN114574051A (en) * | 2021-12-31 | 2022-06-03 | 浙江鸿星文具有限公司 | Environment-friendly varnish suitable for automatic pencil coloring machine and preparation method thereof |
| CN115960501A (en) * | 2022-11-03 | 2023-04-14 | 上海君子兰新材料股份有限公司 | Water-based door and window varnish and preparation method thereof |
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