CN109621553A - A kind of preparation method of porous spherical environmental protection filtrate - Google Patents
A kind of preparation method of porous spherical environmental protection filtrate Download PDFInfo
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- CN109621553A CN109621553A CN201910040953.3A CN201910040953A CN109621553A CN 109621553 A CN109621553 A CN 109621553A CN 201910040953 A CN201910040953 A CN 201910040953A CN 109621553 A CN109621553 A CN 109621553A
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D39/00—Filtering material for liquid or gaseous fluids
- B01D39/14—Other self-supporting filtering material ; Other filtering material
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/001—Processes for the treatment of water whereby the filtration technique is of importance
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2239/00—Aspects relating to filtering material for liquid or gaseous fluids
- B01D2239/10—Filtering material manufacturing
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2239/00—Aspects relating to filtering material for liquid or gaseous fluids
- B01D2239/12—Special parameters characterising the filtering material
- B01D2239/1241—Particle diameter
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/10—Inorganic compounds
- C02F2101/16—Nitrogen compounds, e.g. ammonia
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Hydrology & Water Resources (AREA)
- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Organic Chemistry (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Soil Conditioners And Soil-Stabilizing Materials (AREA)
Abstract
The present invention provides a kind of preparation methods of porous spherical environmental protection filtrate, and steps are as follows: clay, polycrystalline mullite fibre, cow dung charcoal, silicon powder and baryta fledspar powder being mixed, fineness < 0.1mm is ground to；Add water polo to be milled to partial size≤5 μm, dries to obtain mixed powder；Zasiokaurin is mixed with dehydrated alcohol, and is washed under magnetic agitation effect, in triplicate；Filtration drying is soaked in 5% hydrochloric acid solution, is washed with deionized water to neutrality, is put into drying box and dries；It is equably laid in low-temperature plasma processing unit and handles to obtain modified corn pollen；Mixed powder, zasiokaurin, guar gum and deionized water are mixed；It is dry after filtering；It is put into silicon carbon rod electric furnace and is burnt into；It is cooled to room temperature, coupling agent KH550 and deionized water stirring is added；Filtering drying to obtain the final product.Porous spherical environmental protection filtrate is for COD, BOD and NH prepared by this law4- N has extraordinary filter effect.
Description
Technical field
The present invention relates to a kind of preparation methods of porous spherical environmental protection filtrate.
Background technique
With the fast development of modern industry, the surge of population, energy problem is increasingly severe, meanwhile, environmental pollution
Problem is also being further exacerbated by, and water resources crisis also has become a worldwide problem urgently to be resolved.With industrial or agricultural and
The rapid development in city, the discharge of a large amount of pollutants, natural water decline by serious pollution, the utilization rate of water resource,
The problem of even more exacerbating China's shortage of water resources.Pollution entering the water includes industrial pollution source, agricultural pollution source and domestic pollution source
Three parts, and according to polluter difference, water pollution is broadly divided into chemical contamination, physical pollution and biologic contamination again
Three categories.In recent years, the discharge amount of China's industrial wastewater and municipal wastewater is about 57,200,000,000 tons, and water pollution is processed into order to urgently
Problem to be solved.Filtrate as processing waste water a kind of mode, at present mainly using glass reinforced plastic filtrate, plastic honeycomb filtrate,
Stereo corrugated filtrate, soft fiber filtrate, irregular particulate filter etc..Glass reinforced plastic filtrate and plastic honeycomb filter material surface are smooth,
Biomembrane poor adhesive force, it is easy to aging, and tend to generate different degrees of blocking in practical applications.Water in soft filtrate
Stream mode is undesirable, is easily bonded together by biomembrane, generates balling phenomenon, greatly reduces its surface area, and then in balling
Inside generates anaerobic effect, influences treatment effect.Irregular particulate filter resistance to water-flow is big, easily causes to block.China in recent years
Also carried out and handled sewage using ceramic grain filter, but, but its resistance to water-flow is big, is easy blocking, therefore, researchs and develops novel filter
Material is that new road is opened up in sewage treatment.
Summary of the invention
Technical problems to be solved: a kind of preparation method of porous spherical environmental protection filtrate, gained porous spherical environmental protection are provided
Filtrate is for COD, BOD and NH4- N has extraordinary filter effect.
Technical solution: a kind of preparation method of porous spherical environmental protection filtrate, ingredient is by weight, comprising the following steps:
(1) by 5-10 parts of clays, 2-5 parts of polycrystalline mullite fibres, 2-5 parts of cow dung charcoals, 3-7 parts of silicon powders and 3-6 parts of barium
Feldspar powder mixing, is ground to fineness < 0.1mm；
(2) plus water polo is milled to partial size≤5 μm, dries to obtain mixed powder；
(3) 5-10 parts of zasiokaurins and dehydrated alcohol are sufficiently mixed in the ratio that mass volume ratio is 1g:10-14mL, and
Magnetic agitation effect is lower to wash 10h, in triplicate；
(4) filtration drying is soaked in 3-4h in 5% hydrochloric acid solution, is washed with deionized water to neutrality, is put into drying box,
It is dried at 80-85 DEG C；
(5) it is equably laid on the ground electrode in low-temperature plasma processing unit, in supply frequency 8-10kHz, operating voltage
6-9min is handled under the conditions of 20kV, discharge power 70-80W obtains modified corn pollen；
(6) mixed powder, zasiokaurin, 5-10 parts of guar gums and 50-80 parts of deionized waters are mixed, in revolving speed 500-600rpm
Lower stirring 1-2h；
(7) dry after filtering；
(8) it is put into silicon carbon rod electric furnace and is burnt into, the first stage: being warming up to 90-100 DEG C, keeps the temperature 60min；Second stage: it rises
Temperature keeps the temperature 30min to 500-600 DEG C；Phase III: being warming up to 1100-1150 DEG C, keeps the temperature 30-40min；
(9) it is cooled to room temperature, coupling agent KH550 and deionized water is added, stir 20-30min；
(10) it filters, is put into porous spherical environmental protection filtrate obtained by drying in baking oven.
Further, the cow dung charcoal the preparation method comprises the following steps:
Step 1: take cow dung, picks and carry out after the sundries such as stone air-dried, be crushed to partial size less than 20 mesh；
6h is carbonized step 2: being put into Muffle furnace, is taken out after being cooled to room temperature, 60 meshes are crossed；
Step 3: being washed with deionized water after filtering with salt acid elution 5 times of 1mol/L to neutrality；
Step 4: porous spherical environmental protection filtrate obtained by drying.
Further, the partial size of the porous spherical environmental protection filtrate is 150-200 μm.
Further, in the step (5) supply frequency be 7kHz, discharge power 75W.
Further, the first stage in the step (8): being warming up to 95 DEG C, keeps the temperature 60min；Second stage: being warming up to 550 DEG C,
Keep the temperature 30min；Phase III: being warming up to 1130 DEG C, keeps the temperature 35min.
The utility model has the advantages that
1. joined cow dung charcoal, novel structure is introduced, increases surface area.
2. introducing completely new biological structure, while spherical surface area is big using zasiokaurin as biological template, filter effect is good.
3. generating intensive and uniform aperture after the processing of low-temperature plasma processing unit, filter effect is more preferable.
4. through porous spherical environmental protection filtrate prepared by the present invention for COD, BOD and NH4- N has extraordinary filter effect,
After filtering, COD, BOD and NH4The amount of-N is all down to 25.9mg/L, 18.7mg/L and 1.07mg/L.
Specific embodiment
Embodiment 1
A kind of preparation method of porous spherical environmental protection filtrate, ingredient is by weight, comprising the following steps:
(1) 5 parts of clays, 2 parts of polycrystalline mullite fibres, 2 parts of cow dung charcoals, 3 parts of silicon powders and 3 parts of baryta fledspar powder are mixed,
It is ground to fineness < 0.1mm；
(2) plus water polo is milled to partial size≤5 μm, dries to obtain mixed powder；
(3) 5 parts of zasiokaurins and dehydrated alcohol are sufficiently mixed in the ratio that mass volume ratio is 1g:10mL, and are stirred in magnetic force
The effect of mixing is lower to wash 10h, in triplicate；
(4) filtration drying is soaked in 3h in 5% hydrochloric acid solution, is washed with deionized water to neutrality, is put into drying box, 80
It is dried at DEG C；
(5) it is equably laid on the ground electrode in low-temperature plasma processing unit, in supply frequency 8kHz, operating voltage
6min is handled under the conditions of 20kV, discharge power 70W obtains modified corn pollen；
(6) mixed powder, zasiokaurin, 5 parts of guar gums and 50 parts of deionized waters are mixed, stirs 1h at revolving speed 500rpm；
(7) dry after filtering；
(8) it is put into silicon carbon rod electric furnace and is burnt into, the first stage: being warming up to 90 DEG C, keeps the temperature 60min；Second stage: it is warming up to
500 DEG C, keep the temperature 30min；Phase III: being warming up to 1100 DEG C, keeps the temperature 30min；
(9) it is cooled to room temperature, coupling agent KH550 and deionized water is added, stir 20min；
(10) it filters, is put into porous spherical environmental protection filtrate obtained by drying in baking oven.
Embodiment 2
A kind of preparation method of porous spherical environmental protection filtrate, ingredient is by weight, comprising the following steps:
(1) 6 parts of clays, 3 parts of polycrystalline mullite fibres, 3 parts of cow dung charcoals, 4 parts of silicon powders and 4 parts of baryta fledspar powder are mixed,
It is ground to fineness < 0.1mm；
(2) plus water polo is milled to partial size≤5 μm, dries to obtain mixed powder；
(3) 7 parts of zasiokaurins and dehydrated alcohol are sufficiently mixed in the ratio that mass volume ratio is 1g:11mL, and are stirred in magnetic force
The effect of mixing is lower to wash 10h, in triplicate；
(4) filtration drying is soaked in 3.5h in 5% hydrochloric acid solution, is washed with deionized water to neutrality, is put into drying box,
It is dried at 80 DEG C；
(5) it is equably laid on the ground electrode in low-temperature plasma processing unit, in supply frequency 9kHz, operating voltage
7min is handled under the conditions of 20kV, discharge power 75W obtains modified corn pollen；
(6) mixed powder, zasiokaurin, 7 parts of guar gums and 60 parts of deionized waters are mixed, is stirred at revolving speed 550rpm
1.5h；
(7) dry after filtering；
(8) it is put into silicon carbon rod electric furnace and is burnt into, the first stage: being warming up to 95 DEG C, keeps the temperature 60min；Second stage: it is warming up to
550 DEG C, keep the temperature 30min；Phase III: being warming up to 1130 DEG C, keeps the temperature 35min；
(9) it is cooled to room temperature, coupling agent KH550 and deionized water is added, stir 25min；
(10) it filters, is put into porous spherical environmental protection filtrate obtained by drying in baking oven.
Embodiment 3
A kind of preparation method of porous spherical environmental protection filtrate, ingredient is by weight, comprising the following steps:
(1) 8 parts of clays, 4 parts of polycrystalline mullite fibres, 3.5 parts of cow dung charcoals, 5 parts of silicon powders and 5 parts of baryta fledspar powder are mixed
It closes, is ground to fineness < 0.1mm；
(2) plus water polo is milled to partial size≤5 μm, dries to obtain mixed powder；
(3) 8 parts of zasiokaurins and dehydrated alcohol are sufficiently mixed in the ratio that mass volume ratio is 1g:12mL, and are stirred in magnetic force
The effect of mixing is lower to wash 10h, in triplicate；
(4) filtration drying is soaked in 3.5h in 5% hydrochloric acid solution, is washed with deionized water to neutrality, is put into drying box,
It is dried at 80 DEG C；
(5) it is equably laid on the ground electrode in low-temperature plasma processing unit, in supply frequency 9kHz, operating voltage
8min is handled under the conditions of 20kV, discharge power 75W obtains modified corn pollen；
(6) mixed powder, zasiokaurin, 8 parts of guar gums and 65 parts of deionized waters are mixed, is stirred at revolving speed 550rpm
1.5h；
(7) dry after filtering；
(8) it is put into silicon carbon rod electric furnace and is burnt into, the first stage: being warming up to 95 DEG C, keeps the temperature 60min；Second stage: it is warming up to
550 DEG C, keep the temperature 30min；Phase III: being warming up to 1130 DEG C, keeps the temperature 35min；
(9) it is cooled to room temperature, coupling agent KH550 and deionized water is added, stir 25min；
(10) it filters, is put into porous spherical environmental protection filtrate obtained by drying in baking oven.
Embodiment 4
A kind of preparation method of porous spherical environmental protection filtrate, ingredient is by weight, comprising the following steps:
(1) 9 parts of clays, 4 parts of polycrystalline mullite fibres, 4 parts of cow dung charcoals, 6 parts of silicon powders and 5 parts of baryta fledspar powder are mixed,
It is ground to fineness < 0.1mm；
(2) plus water polo is milled to partial size≤5 μm, dries to obtain mixed powder；
(3) 9 parts of zasiokaurins and dehydrated alcohol are sufficiently mixed in the ratio that mass volume ratio is 1g:13mL, and are stirred in magnetic force
The effect of mixing is lower to wash 10h, in triplicate；
(4) filtration drying is soaked in 3.5h in 5% hydrochloric acid solution, is washed with deionized water to neutrality, is put into drying box,
It is dried at 85 DEG C；
(5) it is equably laid on the ground electrode in low-temperature plasma processing unit, in supply frequency 9kHz, operating voltage
8min is handled under the conditions of 20kV, discharge power 75W obtains modified corn pollen；
(6) mixed powder, zasiokaurin, 9 parts of guar gums and 70 parts of deionized waters are mixed, is stirred at revolving speed 550rpm
1.5h；
(7) dry after filtering；
(8) it is put into silicon carbon rod electric furnace and is burnt into, the first stage: being warming up to 95 DEG C, keeps the temperature 60min；Second stage: it is warming up to
550 DEG C, keep the temperature 30min；Phase III: being warming up to 1130 DEG C, keeps the temperature 35min；
(9) it is cooled to room temperature, coupling agent KH550 and deionized water is added, stir 25min；
(10) it filters, is put into porous spherical environmental protection filtrate obtained by drying in baking oven.
Embodiment 5
A kind of preparation method of porous spherical environmental protection filtrate, ingredient is by weight, comprising the following steps:
(1) 10 parts of clays, 5 parts of polycrystalline mullite fibres, 5 parts of cow dung charcoals, 7 parts of silicon powders and 6 parts of baryta fledspar powder are mixed,
It is ground to fineness < 0.1mm；
(2) plus water polo is milled to partial size≤5 μm, dries to obtain mixed powder；
(3) 10 parts of zasiokaurins and dehydrated alcohol are sufficiently mixed in the ratio that mass volume ratio is 1g:14mL, and are stirred in magnetic force
The effect of mixing is lower to wash 10h, in triplicate；
(4) filtration drying is soaked in 4h in 5% hydrochloric acid solution, is washed with deionized water to neutrality, is put into drying box, 85
It is dried at DEG C；
(5) it is equably laid on the ground electrode in low-temperature plasma processing unit, in supply frequency 10kHz, operating voltage
9min is handled under the conditions of 20kV, discharge power 80W obtains modified corn pollen；
(6) mixed powder, zasiokaurin, 10 parts of guar gums and 80 parts of deionized waters are mixed, stirs 2h at revolving speed 600rpm；
(7) dry after filtering；
(8) it is put into silicon carbon rod electric furnace and is burnt into, the first stage: being warming up to 100 DEG C, keeps the temperature 60min；Second stage: heating
To 600 DEG C, 30min is kept the temperature；Phase III: being warming up to 1150 DEG C, keeps the temperature 40min；
(9) it is cooled to room temperature, coupling agent KH550 and deionized water is added, stir 30min；
(10) it filters, is put into porous spherical environmental protection filtrate obtained by drying in baking oven.
Filtrate prepared by the present invention is carried out to the filtering of sewage, the COD of sewage is 484mg/L, BOD 373mg/L, NH4- N is
36.3mg/L。
The performance indicator of the sewage after porous spherical environmental protection media filtration of table 1
| Name of product | COD(mg/L) | BOD(mg/L) | NH4-N(mg/L) |
| Embodiment 1 | 26.3 | 19.2 | 1.12 |
| Embodiment 2 | 26.1 | 18.9 | 1.09 |
| Embodiment 3 | 25.9 | 18.7 | 1.07 |
| Embodiment 4 | 26.1 | 18.8 | 1.09 |
| Embodiment 5 | 26.2 | 19.0 | 1.11 |
Note: filtrate usage amount is 3g/L
Through porous spherical environmental protection filtrate prepared by the present invention for COD, BOD and NH4- N has extraordinary filter effect, warp
After filtering, COD, BOD and NH4The amount of-N is all down to 25.9mg/L, 18.7mg/L and 1.07mg/L.
Claims (5)
1. a kind of preparation method of porous spherical environmental protection filtrate, it is characterised in that: ingredient is by weight, comprising the following steps:
(1) by clay, polycrystalline mullite fibre, cow dung charcoal, silicon powder and baryta fledspar powder mix, be ground to fineness <
0.1mm；
(2) plus water polo is milled to partial size≤5 μm, dries to obtain mixed powder；
(3) zasiokaurin and dehydrated alcohol are sufficiently mixed in the ratio that mass volume ratio is 1g:10-14mL, and are stirred in magnetic force
The effect of mixing is lower to wash 10h, in triplicate；
(4) filtration drying is soaked in 3-4h in 5% hydrochloric acid solution, is washed with deionized water to neutrality, is put into drying box,
It is dried at 80-85 DEG C；
(5) it is equably laid on the ground electrode in low-temperature plasma processing unit, in supply frequency 8-10kHz, operating voltage
6-9min is handled under the conditions of 20kV, discharge power 70-80W obtains modified corn pollen；
(6) mixed powder, zasiokaurin, guar gum and deionized water are mixed, stirs 1-2h at revolving speed 500-600rpm；
(7) dry after filtering；
(8) it is put into silicon carbon rod electric furnace and is burnt into, the first stage: being warming up to 90-100 DEG C, keeps the temperature 60min；Second stage: it rises
Temperature keeps the temperature 30min to 500-600 DEG C；Phase III: being warming up to 1100-1150 DEG C, keeps the temperature 30-40min；
(9) it is cooled to room temperature, coupling agent KH550 and deionized water is added, stir 20-30min；
(10) it filters, is put into porous spherical environmental protection filtrate obtained by drying in baking oven.
2. a kind of preparation method of porous spherical environmental protection filtrate according to claim 1, it is characterised in that: the cow dung is raw
Object charcoal the preparation method comprises the following steps:
Step 1: take cow dung, picks and carry out after the sundries such as stone air-dried, be crushed to partial size less than 20 mesh；
6h is carbonized step 2: being put into Muffle furnace, is taken out after being cooled to room temperature, 60 meshes are crossed；
Step 3: being washed with deionized water after filtering with salt acid elution 5 times of 1mol/L to neutrality；
Step 4: porous spherical environmental protection filtrate obtained by drying.
3. a kind of preparation method of porous spherical environmental protection filtrate according to claim 1, it is characterised in that: the porous ball
The partial size of shape environmental protection filtrate is 150-200 μm.
4. a kind of preparation method of porous spherical environmental protection filtrate according to claim 1, it is characterised in that: the step
(5) in supply frequency be 7kHz, discharge power 75W.
5. a kind of preparation method of porous spherical environmental protection filtrate according to claim 1, it is characterised in that: the step
(8) first stage in: being warming up to 95 DEG C, keeps the temperature 60min；Second stage: being warming up to 550 DEG C, keeps the temperature 30min；Phase III: it rises
Temperature keeps the temperature 35min to 1130 DEG C.
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| CN201910040953.3A CN109621553A (en) | 2019-01-16 | 2019-01-16 | A kind of preparation method of porous spherical environmental protection filtrate |
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| CN201910040953.3A CN109621553A (en) | 2019-01-16 | 2019-01-16 | A kind of preparation method of porous spherical environmental protection filtrate |
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105921110A (en) * | 2016-06-02 | 2016-09-07 | 环境保护部华南环境科学研究所 | Preparation method and application of cow dung biological carbon |
| CN107999041A (en) * | 2017-12-25 | 2018-05-08 | 佛山市中环环境检测中心 | A kind of preparation method of Wastewater processing absorbent |
| WO2018124752A1 (en) * | 2016-12-28 | 2018-07-05 | 엘지전자 주식회사 | Water treatment apparatus filter and water treatment apparatus including same |
| CN109046254A (en) * | 2018-08-17 | 2018-12-21 | 中国科学院合肥物质科学研究院 | A kind of low-temperature plasma modified charcoal adsorbent material and the preparation method and application thereof |
-
2019
- 2019-01-16 CN CN201910040953.3A patent/CN109621553A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105921110A (en) * | 2016-06-02 | 2016-09-07 | 环境保护部华南环境科学研究所 | Preparation method and application of cow dung biological carbon |
| WO2018124752A1 (en) * | 2016-12-28 | 2018-07-05 | 엘지전자 주식회사 | Water treatment apparatus filter and water treatment apparatus including same |
| CN107999041A (en) * | 2017-12-25 | 2018-05-08 | 佛山市中环环境检测中心 | A kind of preparation method of Wastewater processing absorbent |
| CN109046254A (en) * | 2018-08-17 | 2018-12-21 | 中国科学院合肥物质科学研究院 | A kind of low-temperature plasma modified charcoal adsorbent material and the preparation method and application thereof |
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