CN109619673A - Cigarette spansule and preparation method thereof and cigarette filter - Google Patents

Cigarette spansule and preparation method thereof and cigarette filter Download PDF

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Publication number
CN109619673A
CN109619673A CN201910127753.1A CN201910127753A CN109619673A CN 109619673 A CN109619673 A CN 109619673A CN 201910127753 A CN201910127753 A CN 201910127753A CN 109619673 A CN109619673 A CN 109619673A
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China
Prior art keywords
cigarette
capsule
spansule
ball
preparation
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Granted
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CN201910127753.1A
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Chinese (zh)
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CN109619673B (en
Inventor
黎洪利
朱立军
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Chongqing China Tobacco Industry Co Ltd
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Chongqing China Tobacco Industry Co Ltd
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    • AHUMAN NECESSITIES
    • A24TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24DCIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
    • A24D3/00Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
    • A24D3/06Use of materials for tobacco smoke filters
    • A24D3/061Use of materials for tobacco smoke filters containing additives entrapped within capsules, sponge-like material or the like, for further release upon smoking
    • AHUMAN NECESSITIES
    • A24TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24DCIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
    • A24D3/00Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
    • A24D3/04Tobacco smoke filters characterised by their shape or structure

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Cigarettes, Filters, And Manufacturing Of Filters (AREA)

Abstract

The present invention relates to technical field of cigarettes, more particularly to cigarette spansule and preparation method thereof and cigarette filter, the cyst wall that cigarette spansule of the invention includes capsule-core and is wrapped in outside capsule-core, the capsule-core is the support frame by plasticity, and absorption or the object being filled in the support frame are constituted, the cyst wall is made of thermo-sensitive material, and support frame has netted or porous structure;Also disclose the preparation method of cigarette spansule, using one of active carbon, sepiolite, montmorillonite, medical stone, silica gel, macroreticular resin or more than one mixture, preparation forms porous ball, after porous ball absorption or filling object, the micropore of closed circular bead surface forms capsule.The present invention solves after existing cigarette is racked with capsule the problems such as causing filter tip to collapse, content abrupt release amount is excessive, and rate of release is uncontrollable.

Description

Cigarette spansule and preparation method thereof and cigarette filter
Technical field
The present invention relates to technical field of cigarettes more particularly to cigarette spansule and preparation method thereof and cigarette filters.
Background technique
With the development of world economy society, deep variation is occurring for cigarette market.It on the one hand is that consumer taste needs It asks and becomes more diversified, product needs more tastes just to meet different consumer demands;It on the other hand is in production Technological means have biggish development, but the means of flavoring are limited always, simultaneously because the volatilization of most of flavors and fragrances Property make it be difficult to retain for a long time, the dissolubility in different solvents also limit its it is further use, and with tar reduction Harm reduction deepens continuously, and cigarettes reduce coke damage inevitably makes part fragrance component and perfume quantity loss in cigarette, causes Phenomena such as original suction comfort decline of cigarette, suction taste distortion, dry sensation rises, is obvious.Domestic and international each cigarette manufacturer opens Issue numerous flavoring technologies, such as tobacco perfuming, cigarette paper flavoring, packaging material flavoring, filter tip flavoring, filter tip flavoring mode by In can avoid cigarette storage and the loss thermal decomposition of fragrance during burning and sucking, reduce pipe tobacco etc. to the obstruction of fragrance, increase fragrance Utilization efficiency and have unique advantage.
Filter tip flavoring mode can be divided into solvent method, adsorbent method, fragrant collimation method, capsule method etc. again.Capsule method is to utilize height Spices are implanted into filter tip in capsule, then by capsule by molecular material, it is advantageous that effectively avoiding outside environmental elements Interference prevents flavor degradation rotten.Existing cigarette is had the following problems with capsule: smoker is to increase flue gas fragrance to need glue Capsule racks, and racks rear content and flows out rapidly, so that the position for being placed with capsule collapses, especially contains the filter tip of more capsules, It is the most prominent to collapse effect, collapses and will lead to filter tip sectional area reduction at capsule, content abrupt release amount is excessive, rate of release Uncontrollable, especially liposoluble substance enters oral cavity with flue gas after capsule is broken, and smoker can significantly feel greasy Sense, influences cigarette taste quality.
Summary of the invention
In view of this, being solved existing the object of the present invention is to provide cigarette spansule and preparation method thereof and cigarette filter Filter tip is caused to collapse after having cigarette to be racked with capsule, the problems such as content moment amount of releasing is excessive, and rate of release is uncontrollable.
The present invention solves above-mentioned technical problem by following technological means:
Cigarette spansule, including capsule-core and the cyst wall being wrapped in outside capsule-core, the capsule-core is the support frame by plasticity, And absorption or the object being filled in the support frame are constituted, the cyst wall is made of thermo-sensitive material.
The support frame of plasticity has certain non-deformability, is able to maintain certain shape.The support frame of plasticity Setting can be pinched brokenly to avoid existing cigarette with capsule after the problem of causing filter tip to collapse;And cyst wall is made of thermo-sensitive material, is taken out Melt thermo-sensitive material to discharge the substance in content using temperature when suction, does not need to rack capsule, further avoid The problem of filter tip collapses.
Further, the support frame has netted or porous structure.
Further, the support frame is the porous sphere made of strong absorption property material, the strong absorption property material Material is one of active carbon, sepiolite, montmorillonite, medical stone, silica gel, macroreticular resin or more than one mixing material.
Netted or porous structure support frame has biggish surface area, and object can be adsorbed in hole wall material, Can be in hole, the thermo-sensitive material on surface melts when suction, and the flavouring essence for tobacco on support frame then slowly releases, and avoids Existing cigarette racks the phenomenon that moment taste is overweight, and subsequent fragrance gradually weakens with capsule, to keep every mouth suction fragrance basic Unanimously, hence it is evident that the mouthfeel quality for improving every mouthful of cigarette, to further increase cigarette quality.
Further, the thermo-sensitive material is wax material.
Further, the object be one of essence spice for cigarette, harm reduction functional material, humectant or more than one Mixing, the harm reduction functional material are one of amino acid, amino acid derivativges, polyaminoacid or more than one combination Object, the humectant are one of water, propylene glycol, glycerol, xylitol, sorbierite or more than one composition.
Closed material using the wax material that can melt at a certain temperature as ball surface micropore, when suction with Cigarette be ignited, the raising of filter tip temperature can melt ball surface micropore, to discharge tobacco aromaticss, do not have to squeeze.It is preferred that The wax that can melt at 40~50 DEG C.
The invention also discloses a kind of preparation method of cigarette spansule, it is described the preparation method is as follows:
Using one of active carbon, sepiolite, montmorillonite, medical stone, silica gel, macroreticular resin or more than one mixing Object, preparation form porous ball;
Porous ball is set to contain object by adsorbed target object or the method for filling object;
The micropore of closed circular bead surface forms capsule.
Further, the method for the filling object, which is selected from, impregnates absorption method, and the immersion absorption method is by porous ball It is added in the solution containing object, first stirs 10~20min, then be standing and soaking 1~2h.
Further, the method for the adsorbed target object is that porous ball is placed in the gas of the object containing volatility, is inhaled Attached 0.1~for 24 hours.
Further, the enclosure method of the ball surface micropore is as follows:
Ball is immersed in wax liquor, is pulled out, cooling and solidifying closed circular bead surface micropore forms cyst wall;
Or uniformly spray wax liquor on ball or uniformly smear wax liquor, cooling and solidifying closed circular bead surface micropore forms capsule Wall.
Further, the ball makes built-in target prior to temperature -15~-5 DEG C precooling before carrying out surface micropore closing Object is at solid-state.
The invention also discloses a kind of cigarette filter, above-mentioned spansule is placed in the cigarette filter.
When suction is using the filter tip, the temperature of cigarette burning melts the wax material on ball surface, slowly releases branch The essence spice for cigarette of filling is adsorbed in support bone frame, increases fragrance, improves cigarette taste quality.
Cigarette of the invention uses thermo-sensitive material confining surface micropore with spansule, can be at a certain temperature without squeezing Flavors and fragrances inside slow release avoids extruding capsule that filter tip is caused to collapse, and maintains the integrality of filter tip, and strong using having Netted or porous structure support frame is made in the material of absorption property, is adsorbed using netted or porous structure or filling essence is fragrant Material, humectant etc., flavouring essence for tobacco when suction on support frame slowly release, avoid existing cigarette with capsule and rack moment The phenomenon that taste is overweight, and subsequent fragrance gradually weakens, to keep every mouth suction fragrance almost the same, hence it is evident that improve every mouthful of cigarette Mouthfeel quality, to further increase cigarette quality.
Specific embodiment
Below with reference to specific embodiment, the present invention is described in detail:
Cigarette spansule of the invention, including capsule-core and the cyst wall being wrapped in outside capsule-core, capsule-core is the support by plasticity Skeleton, and absorption or the object being filled in support frame are constituted.Plastic support skeleton does not have elastic characteristic, has one Fixed non-deformability is able to maintain certain shape, and support frame is the porous sphere made of strong absorption property material, by force Absorption property material is one of active carbon, sepiolite, montmorillonite, medical stone, silica gel, macroreticular resin or more than one is mixed Condensation material.Ball adsorbs filling object by support frame and is made.Object be essence spice for cigarette, harm reduction functional material, One of humectant or more than one mixing, flavors and fragrances therein are menthol, benzyl carbinol, linalool oxide, anise The alcohols such as alcohol, the carboxylic acids such as citric acid, benzoic acid, methylvaleric acid, myristic acid, lactic acid, hydroxyacetic acid, phenylacetaldehyde, vanillic aldehyde, The aldoketones such as solanone, three ketenes of sentence beans, the phenols such as eugenol, maltol, the lactones such as dihydroactinidiolide, 2,3- dimethyl The heterocyclics such as pyrazine, 2- acetylpyridine, tobacco extract, ginseng extract, dried orange peel extracts, cocoa bean extract, fruit Extract etc. extracts the composition of species or mentioned component;Harm reduction functional material is amino acid, amino acid derivativges, poly- amino One of acid or more than one composition;Humectant is one of water, propylene glycol, glycerol, xylitol, sorbierite or one Kind or more composition.Cyst wall is made of thermo-sensitive material, the preferred wax material of thermo-sensitive material, more preferably can be at 40~50 DEG C The wax of lower thawing.
Embodiment one
The cigarette spansule of the present embodiment the preparation method is as follows:
Using conventional method that absorbent charcoal material is processed into diameter is the porous ball of 2.5mm or so as support frame, Porous ball is immersed in the compound target liquid of water, sorbierite, menthol and tobacco extract, first stirs 10min, then stand 1.5h is impregnated, the effective component in porous ball absorption filling target liquid obtains ball, then by ball in temperature -15~-5 DEG C temperature under the conditions of precooling make built-in object at solid-state, then ball is immersed in wax liquor rapidly, is pulled out rapidly, it is cold But the micropore for solidifying closed circular bead surface, obtains cigarette spansule.
Capsule manufactured in the present embodiment is added in cigarette filter by common process, cigarette is made.Aspirate the cigarette When, the wax material of capsule surface is gradually melted, and mint flavored, and mint flavored lasting stability is released, until cigarette It has been sucked and has still kept concentration consistent, and flue gas irritation is substantially reduced, cigarette perfume is strong.
Embodiment two
The cigarette spansule of the present embodiment the preparation method is as follows:
Using conventional method that absorbent charcoal material is processed into diameter is the porous ball of 3.0mm or so as support frame, Porous ball is immersed in the compound target liquid of water, Fructus Fici extract and tobacco extract, first stirs 15min, then stand 2.0h is impregnated, the effective component in porous ball absorption filling target liquid obtains ball, then by ball in temperature -15~-5 DEG C temperature under the conditions of precooling make built-in object into solid-state, wax liquor, cooling and solidifying closing are then uniformly sprayed on ball The micropore on ball surface obtains cigarette spansule.
Capsule manufactured in the present embodiment is added in cigarette filter by common process, cigarette is made.Aspirate the cigarette When, the wax material of capsule surface is gradually melted, and releases capsule fragrance, can cover cigarette foreign gas, and keep flue gas soft, Fragrance is fine and smooth.
Embodiment three
The cigarette spansule of the present embodiment the preparation method is as follows:
The porous ball for using conventional method that absorbent charcoal material is processed into diameter as 2.6mm or so, porous ball is soaked Enter in the compound target liquid of dried orange peel extracts, glycerol and tobacco extract, first stirs 20min, then be standing and soaking 1.0h, it is porous Effective component in ball absorption filling target liquid, obtains ball, then by ball under the conditions of the temperature of temperature -15~-5 DEG C Precooling makes built-in object at solid-state, and wax liquor is then uniformly smeared on ball, cools and solidifies the micropore of closed circular bead surface, Obtain cigarette spansule.
Capsule manufactured in the present embodiment is added in cigarette filter by common process, cigarette is made.Aspirate the cigarette When, the wax material of capsule surface is gradually melted, and releases capsule fragrance, and medicine perfume (or spice) and cigarette perfume harmony are preferable, is improved With modification cigarette odor-absorbing, plentiful flue gas, mitigation irritation.
Example IV
The cigarette spansule of the present embodiment the preparation method is as follows:
The porous ball for using conventional method that absorbent charcoal material is processed into diameter as 2.8mm or so, porous ball is soaked Enter in the compound target liquid of water, aromatic acid berry extract, propylene glycol and tobacco extract, first stirs 16min, then be standing and soaking 1.3h, porous ball absorption fill the effective component in target liquid, ball are obtained, then by ball in temperature -15~-5 DEG C Precooling makes built-in object at solid-state under the conditions of temperature, and ball is immersed in wax liquor rapidly, is pulled out rapidly, cooling and solidifying closing The micropore on ball surface obtains cigarette spansule.
Capsule manufactured in the present embodiment is added in cigarette filter by common process, cigarette is made.Aspirate the cigarette When, the wax material of capsule surface is gradually melted, and releases capsule fragrance, can be removed the miscellaneous gas of cigarette, be improved and repair Fragrance is adornd, the soft exquisiteness of flue gas is made.
Embodiment five
The cigarette spansule of the present embodiment the preparation method is as follows:
The macroreticular resin ball that diameter is 3.0mm or so is placed in lavender, stands 0.1-24h, this implementation in rose Example standing adsorption for 24 hours, allows ball sufficiently to adsorb volatile fragrant components, is then immersed in ball in wax liquor rapidly, fishes out rapidly Out, the micropore for cooling and solidifying closed circular bead surface, obtains cigarette spansule.
Capsule manufactured in the present embodiment is added in cigarette filter by common process, cigarette is made.Aspirate the cigarette When, the wax material of capsule surface is gradually melted, and releases fragrance matter, and it can assign cigarette a kind of special natural flavor, And the flavor lasting stability, the roughness of flue gas can be reduced, is improved and is inhaled taste, mitigate irritation, remove removal of impurities gas, cigarette product are improved Matter.
Embodiment six
The cigarette spansule of the present embodiment the preparation method is as follows:
By mass ratio be 1:1:1 sepiolite, montmorillonite, medical stone mixture be prepared into the circle that diameter is 3.0mm or so Pearl is placed in lavender, stands 1h in Chloranthus spicatus Mak, allows ball sufficiently to adsorb volatile fragrant components, then uniformly smears on ball Wax liquor, the micropore of cooling and solidifying film forming closed circular bead surface, obtains cigarette spansule.
Capsule manufactured in the present embodiment is added in cigarette filter by common process, cigarette is made.Aspirate the cigarette When, the wax material of capsule surface is gradually melted, and releases fragrance matter, and it can assign cigarette a kind of special natural flavor, And the flavor lasting stability, irritation can be mitigated, make the plentiful exquisiteness of flue gas, improve cigarette quality.
The above examples are only used to illustrate the technical scheme of the present invention and are not limiting, although referring to preferred embodiment to this hair It is bright to be described in detail, those skilled in the art should understand that, it can modify to technical solution of the present invention Or equivalent replacement should all cover without departing from the objective and range of technical solution of the present invention in claim of the invention In range.Technology not described in detail in the present invention, shape, construction portion are well-known technique.

Claims (11)

1. cigarette spansule, including capsule-core and the cyst wall being wrapped in outside capsule-core, which is characterized in that the capsule-core is by plasticity Support frame, and absorption or the object being filled in the support frame are constituted, and the cyst wall is made of thermo-sensitive material.
2. cigarette spansule according to claim 1, which is characterized in that the support frame has netted or porous knot Structure.
3. cigarette spansule according to claim 2, which is characterized in that the support frame is by strong absorption property material Porous sphere made of expecting, the strong absorption property material is active carbon, sepiolite, montmorillonite, medical stone, silica gel, macropore tree One of rouge or more than one mixing material.
4. cigarette spansule according to claim 3, which is characterized in that the thermo-sensitive material is wax material.
5. cigarette spansule according to claim 1 to 4, which is characterized in that the object is flavouring essence for tobacco perfume One of material, harm reduction functional material, humectant or more than one mixing, the harm reduction functional material are amino acid, amino acid One of derivative, polyaminoacid or more than one composition, the humectant be water, propylene glycol, glycerol, xylitol, One of sorbierite or more than one composition.
6. the preparation method of cigarette spansule, which is characterized in that it is described the preparation method is as follows:
Using one of active carbon, sepiolite, montmorillonite, medical stone, silica gel, macroreticular resin or more than one mixture, Preparation forms porous ball;
Porous ball is set to contain object by adsorbed target object or the method for filling object;
The micropore of closed circular bead surface forms capsule.
7. the preparation method of cigarette spansule according to claim 6, which is characterized in that the side of the filling object Method, which is selected from, impregnates absorption method, and the immersion absorption method is that porous ball is added in the solution containing object, and first stirring 10~ 20min, then it is standing and soaking 1~2h.
8. the preparation method of cigarette spansule according to claim 6, which is characterized in that the side of the adsorbed target object Method is that porous ball is placed in the gas of the object containing volatility, absorption 0.1~for 24 hours.
9. the preparation method of cigarette spansule according to claim 6, which is characterized in that the ball surface micropore Enclosure method is as follows:
Ball is immersed in wax liquor, is pulled out, cooling and solidifying closed circular bead surface micropore forms cyst wall;
Or uniformly spray wax liquor on ball or uniformly smear wax liquor, cooling and solidifying closed circular bead surface micropore forms cyst wall.
10. the preparation method of cigarette spansule according to claim 9, which is characterized in that the ball is carrying out table Before the closing of face micropore, make built-in object at solid-state prior to temperature -15~-5 DEG C precooling.
11. cigarette filter, which is characterized in that place the sustained release glue any just like claim 1-4 in the cigarette filter Capsule.
CN201910127753.1A 2019-02-18 2019-02-18 Sustained-release capsule for cigarette, preparation method thereof and cigarette filter Active CN109619673B (en)

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Cited By (4)

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CN109875114A (en) * 2019-04-17 2019-06-14 云南中烟工业有限责任公司 A kind of cigarette functional microsphere and the preparation method and application thereof with nucleocapsid interlayer structure
CN111789286A (en) * 2020-06-05 2020-10-20 山东将军烟草新材料科技有限公司 Porous frame solid bead and preparation method and application thereof
WO2020258386A1 (en) * 2019-06-27 2020-12-30 广东中烟工业有限责任公司 Slow-release flavorant and application thereof in chinese-flavor tobacco product
CN112674384A (en) * 2019-10-17 2021-04-20 宁波合康生物医药科技有限公司 Additive for reducing harmful substances in smoke and preparation method and application thereof

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Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109875114A (en) * 2019-04-17 2019-06-14 云南中烟工业有限责任公司 A kind of cigarette functional microsphere and the preparation method and application thereof with nucleocapsid interlayer structure
CN109875114B (en) * 2019-04-17 2021-09-14 云南中烟工业有限责任公司 Functional microsphere with core-shell sandwich structure for cigarettes and preparation method and application thereof
WO2020258386A1 (en) * 2019-06-27 2020-12-30 广东中烟工业有限责任公司 Slow-release flavorant and application thereof in chinese-flavor tobacco product
KR20210018948A (en) * 2019-06-27 2021-02-18 차이나 토바코 광동 인더스트리얼 컴퍼니 리미티드 Delayed Release Flavoring and Its Application in Chinese Flavored Tobacco Products
KR102583379B1 (en) 2019-06-27 2023-09-26 차이나 토바코 광동 인더스트리얼 컴퍼니 리미티드 Delayed release flavoring and its application in Chinese flavored tobacco products
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CN112674384A (en) * 2019-10-17 2021-04-20 宁波合康生物医药科技有限公司 Additive for reducing harmful substances in smoke and preparation method and application thereof
CN111789286A (en) * 2020-06-05 2020-10-20 山东将军烟草新材料科技有限公司 Porous frame solid bead and preparation method and application thereof

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