CN109609207A - A kind of clean fuel and preparation method thereof for reducing exhaust emissions - Google Patents

A kind of clean fuel and preparation method thereof for reducing exhaust emissions Download PDF

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Publication number
CN109609207A
CN109609207A CN201811559026.4A CN201811559026A CN109609207A CN 109609207 A CN109609207 A CN 109609207A CN 201811559026 A CN201811559026 A CN 201811559026A CN 109609207 A CN109609207 A CN 109609207A
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Prior art keywords
fuel
parts
exhaust emissions
reducing
clean
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Application number
CN201811559026.4A
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Chinese (zh)
Inventor
李兴周
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Fujian Xiaoxi New Energy Technology Co ltd
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Yan Meifen
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Priority to CN201811559026.4A priority Critical patent/CN109609207A/en
Publication of CN109609207A publication Critical patent/CN109609207A/en
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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/02Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/143Organic compounds mixtures of organic macromolecular compounds with organic non-macromolecular compounds
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/22Organic compounds containing nitrogen
    • C10L1/234Macromolecular compounds
    • C10L1/236Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds derivatives thereof
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/22Organic compounds containing nitrogen
    • C10L1/234Macromolecular compounds
    • C10L1/238Macromolecular compounds obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/30Organic compounds compounds not mentioned before (complexes)
    • C10L1/301Organic compounds compounds not mentioned before (complexes) derived from metals

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  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Solid Fuels And Fuel-Associated Substances (AREA)
  • Liquid Carbonaceous Fuels (AREA)

Abstract

The invention discloses a kind of clean fuels and preparation method thereof for reducing exhaust emissions, it is preferable that the fuel includes according to parts by weight: 40 parts of methanol, 45 parts of light dydrocarbon lighter hydrocarbons, 7 parts of ethyl acetate, 4 parts of dehydrated alcohol, 4 parts of petroleum ether.It also include fuel oil additive and ferrocene, mass content total 1.3 ‰ in the fuel.The present invention also provides the preparation methods of the fuel, include: step 1 weighs each raw material in proportion;Step 2 takes methanol to be put into blender, and ethyl acetate is added, stands after stirring;Step 3 adds light dydrocarbon lighter hydrocarbons into the mixture of step 2, stands after stirring;Step 4 sequentially adds petroleum ether, dehydrated alcohol, fuel oil additive and ferrocene into the mixture of step 3, stands after stirring.Provided by the present invention for reducing the clean fuel and preparation method thereof of exhaust emissions, carbon distribution can be cleared up, reduce exhaust emissions, have the advantages that the effect of low-carbon environment-friendly, energy-saving and emission-reduction and a variety of.

Description

A kind of clean fuel and preparation method thereof for reducing exhaust emissions
Technical field
The present invention relates to a kind of automobile clean fuel and preparation method thereof, and in particular, to one kind is for reducing tail gas row Clean fuel put and preparation method thereof.
Background technique
Vehicle fuel mainly include motor petrol, derv fuel, vehicle alternative fuel (such as methanol, ethyl alcohol, emulsion fuel, Natural gas, oil gas, hydrogen) etc..The service performance of vehicle fuel has a direct impact the dynamic property of automobile, emission performance.It is automobile-used The consumption costs of fuel accounts for about 1/3 of motor transport cost or so, directly affects the economy that automobile uses.
Vehicle can generate exhaust gas, i.e. vehicle exhaust when in use, wherein containing hundreds of different compound, dirt therein Dye object has solid aerosol, carbon monoxide, carbon dioxide, hydrocarbon, oxynitrides, lead and oxygen sulfur compound etc.. Tail gas can also exert far reaching influence to the environment of human lives while being directly detrimental to health.Titanium dioxide in tail gas Sulphur has strong impulse smell, and the generation of " acid rain " is easy to cause when reaching a certain concentration, causes soil and water source to be acidified, shadow Ring the growth of crops and forest.Due to the serious dispersibility of automobilism and mobility, brought centainly to purification treatment technology Limitation, it is therefore desirable to Devoting Major Efforts To Developing internal purification technology, such as: improve combustion rate, the anti-pollution processing equipment of installation of fuel oil With take exploitation new engine etc., changing propellant composition is wherein one of very effective means.
Summary of the invention
The object of the present invention is to provide a kind of automobile clean fuel and preparation method thereof, for motor vehicle exhaust emission to greatly certainly The problem of right pollution is on the rise, the fuel of preparation have effects that low-carbon environment-friendly, energy-saving and emission-reduction, being capable of replacing gasoline Product.
In order to achieve the above object, the present invention provides a kind of for reducing the clean fuel of exhaust emissions, wherein described Fuel include according to parts by weight: 38~42 parts of methanol, 44~46 parts of light dydrocarbon lighter hydrocarbons, 6~8 parts of ethyl acetate, dehydrated alcohol 3 ~5 parts, 3~5 parts of petroleum ether.
The above-mentioned clean fuel for being used to reduce exhaust emissions, wherein the fuel includes according to parts by weight: methanol 40 parts, 45 parts of light dydrocarbon lighter hydrocarbons, 7 parts of ethyl acetate, 4 parts of dehydrated alcohol, 4 parts of petroleum ether.
It is above-mentioned for reducing the clean fuel of exhaust emissions, wherein in the fuel also comprising fuel oil additive and Ferrocene.
The above-mentioned clean fuel for being used to reduce exhaust emissions, wherein fuel oil additive and two cyclopentadienyls in the fuel The mass content of iron total 1.3 ‰.
The above-mentioned clean fuel for being used to reduce exhaust emissions, wherein the fuel oil additive and ferrocene is with any Ratio mixing.
The above-mentioned clean fuel for being used to reduce exhaust emissions, wherein the fuel oil additive includes that clean type adds Agent, maintaining additive or power hoist type additive.
The above-mentioned clean fuel for being used to reduce exhaust emissions, wherein the fuel oil additive includes polyisobutylene amine (fuel oil is precious) or polyetheramine (direct-injection is precious).
The present invention also provides the preparation methods of the above-mentioned clean fuel for reducing exhaust emissions, wherein described Method includes: step 1 weighs each raw material in proportion;Step 2 takes methanol to be put into blender, and ethyl acetate is added, quiet after stirring It sets;Step 3 adds light dydrocarbon lighter hydrocarbons into the mixture of step 2, stands after stirring;Step 4, into the mixture of step 3 according to Secondary addition petroleum ether, dehydrated alcohol, fuel oil additive and ferrocene, stand after stirring.
The preparation method of the above-mentioned clean fuel for reducing exhaust emissions, wherein in the step 2 and step 3 Mixing time be 10 minutes, then again respectively stand 5 minutes.
It is above-mentioned for reducing the preparation method of the clean fuel of exhaust emissions, wherein when stirring in the step 4 Between be 20 minutes, then stand 10 minutes again.
Clean fuel and preparation method thereof provided by the present invention for reducing exhaust emissions has the advantage that
The fuel can add completely or part addition is as the fuel of gasoline car, can be mixed with arbitrary proportion and gasoline It uses.If power is more powerful with 20% gasoline and the product mix using gasoline combustion can be made more abundant.
The fuel has cleaning carbon distribution, reduces exhaust emissions, reduces engine noise, extends the function such as engine life in application Effect.
9000 kcal/kg of the fuel value > of the fuel, for density between 0.70~0.74, main ingredient has methanol, second Alcohol, bio-alcohol and part petrochemicals, bio-alcohol, which is added, can reduce corrosivity, swellability, the anti-knock properties of fuel.Wherein Methanol, ethyl alcohol increase the content of oxygen element and protium in product, generate water after burning.To reach low-carbon environment-friendly, save The effect of energy emission reduction.
The raw material for producing the fuel are easy to purchase, and manufacture craft is simple, at low cost, can be with scale volume production, can also be with Individual workship's production.
Specific embodiment
A specific embodiment of the invention is further described below.
Provided by the present invention for the clean fuel of reduction exhaust emissions, include according to parts by weight: 38~42 parts of methanol, 44~46 parts of light dydrocarbon lighter hydrocarbons, 6~8 parts of ethyl acetate, 3~5 parts of dehydrated alcohol, 3~5 parts of petroleum ether.
Hydrocarbon is a series of substances that two kinds of carbon, hydrogen elements mix in different proportions, wherein lighter type is called The hydrocarbon of lighter hydrocarbons, C5~C16 in lighter hydrocarbons is liquid at normal temperatures and pressures, referred to as liquid light hydrocarbon, and usually former oil and gas is opened Adopt and petroleum deep-processing process in byproduct, most light part is C5, C6 in liquid light hydrocarbon, and C5 is light dydrocarbon, includes isoamyl Diene, cyclopentadiene, pentadiene, iso-amylene, 1- amylene, 2- butine, 3-methyl-1-butene, pentamethylene, cyclopentene, isoamyl Alkane, pentane etc..
Preferably, which includes according to parts by weight: 40 parts of methanol, 45 parts of light dydrocarbon lighter hydrocarbons, 7 parts of ethyl acetate, anhydrous 4 parts of ethyl alcohol, 4 parts of petroleum ether.
It also include fuel oil additive and ferrocene in the fuel.
Preferably, the mass content of the fuel oil additive in fuel and ferrocene total 1.3 ‰, wherein fuel oil additive and Ferrocene is mixed with arbitrary proportion.
The fuel oil additive includes clean type additive, maintaining additive or power hoist type additive.
Clean type additive adds dosage larger, and concentration in the oil is high, and at high cost, cleaning action is strong, quick, effect Good product, which only needs one bottle, to thoroughly remove the carbon distribution of (atomizer, combustion chamber etc.) in fuel system, only stage is needed to make With.Maintaining additive adds dosage small, the gasoline cleaning agent that is otherwise known as " GB19592-2004 ", and the fuel oil sold in gas station is precious It is exactly such product, concentration in the oil is low, and at low cost, usual price need to be used continuously for a long time within 30 yuan.It can be compared with The deposit for inhibiting automobile engine fuel oil gas handling system to generate well.Its cleaning effect is significant and cleaning effect is weak, is applicable in more In most multiple spot EFI (manifold injection) vehicle of market maintenance.Octane number adjustment can be understood as power hoist type, this Product contains the metallic compound of MMT (manganese), can effectively make up because the decaying of ethanol petrol bring power, calorific value deficiency etc. are asked Topic.
Preferably, which includes polyisobutylene amine (fuel oil is precious) or polyetheramine (direct-injection is precious).
Include third generation detergent additive (being commonly called as fuel oil treasured) in fuel oil additive: being applied to the 1990-2010 age, for Mainstream car design be multiple spot EFI (manifold injection) engine, the main atomizer for being to solve air intake duct position, intake valve product Carbon needs to continue addition, be easy to cause combustion chamber deposit, and chemical component is that PIBA (polyisobutylene amine) is in the majority.Forth generation is clear Net additive (being commonly called as direct-injection treasured): 2010 so far, and mainstream car design is in-cylinder direct fuel-injection engine, and the cleaning additive that should be used is special Door solves the problems, such as the carbon distribution of atomizer in high-temperature region, combustion chamber and piston, and chemical component is PEA (polyetheramine).
The present invention also provides the preparation methods of the clean fuel for being used to reduce exhaust emissions, include:
Step 1 weighs each raw material in proportion;Step 2 takes methanol to be put into blender, and ethyl acetate is added, quiet after stirring It sets;Step 3 adds light dydrocarbon lighter hydrocarbons into the mixture of step 2, stands after stirring;Step 4, into the mixture of step 3 according to Secondary addition petroleum ether, dehydrated alcohol, fuel oil additive and ferrocene, stand after stirring.
Mixing time in step 2 and step 3 is 10 minutes, then stands 5 minutes respectively again.
Mixing time in step 4 is 20 minutes, then stands 10 minutes again.
The clean fuel and preparation method thereof provided by the present invention for reducing exhaust emissions is done below with reference to embodiment It is further described.
Examples 1 to 3
It is a kind of for reducing the clean fuel of exhaust emissions, ingredient is as shown in table 1 below.
1 ingredient composition table of table.
Ingredient Embodiment 1 Embodiment 2 Embodiment 3
Methanol 40 parts 38 parts 42 parts
Light dydrocarbon lighter hydrocarbons 45 parts 44 parts 46 parts
Ethyl acetate 7 parts 6 parts 8 parts
Dehydrated alcohol 4 parts 3 parts 5 parts
Petroleum ether 4 parts 3 parts 5 parts
Fuel oil additive and ferrocene 1.3‰ 1.3‰ 1.3‰
Various embodiments of the present invention additionally provide the preparation method of the clean fuel for being used to reduce exhaust emissions, include:
Step 1 weighs each raw material in proportion.
Step 2 takes methanol to be put into blender, and ethyl acetate is added, stands after stirring.
Preferably, mixing time is 10 minutes, then stands 5 minutes again.
Step 3 adds light dydrocarbon lighter hydrocarbons into the mixture of step 2, stands after stirring.
Preferably, mixing time is 10 minutes, then stands 5 minutes again.
Step 4 sequentially adds petroleum ether, dehydrated alcohol, fuel oil additive and ferrocene into the mixture of step 3, stirs It is stood after mixing.
Preferably, mixing time is 20 minutes, then stands 10 minutes again.
Fuel prepared by Example 1 carries out quality testing, and the results are shown in Table 2.
2. fuel inspection result of table.
Provided by the present invention for reducing the clean fuel and preparation method thereof of exhaust emissions, carbon distribution can be cleaned, reduced Exhaust emissions, reduction engine noise, extension engine life in application etc., have the advantages that a variety of.It can directly use, it can also be with Petrochemical industry gasoline is referred and synthesized mixed or is used alone in routine with arbitrary proportion.Preferably, two kinds can be divided into, one is absolutely add The product added, another kind can be added 70%.If using the fuel by current 7 yuan or more every liter of oil price as saving 30% or more oily money.
It is discussed in detail although the contents of the present invention have passed through above preferred embodiment, but it should be appreciated that above-mentioned Description is not considered as limitation of the present invention.After those skilled in the art have read above content, for of the invention A variety of modifications and substitutions all will be apparent.Therefore, protection scope of the present invention should be limited to the appended claims.

Claims (10)

1. a kind of for reducing the clean fuel of exhaust emissions, which is characterized in that the fuel includes according to parts by weight: first 38~42 parts of alcohol, 44~46 parts of light dydrocarbon lighter hydrocarbons, 6~8 parts of ethyl acetate, 3~5 parts of dehydrated alcohol, 3~5 parts of petroleum ether.
2. as described in claim 1 for reducing the clean fuel of exhaust emissions, which is characterized in that the fuel is by weight Number meter includes: 40 parts of methanol, 45 parts of light dydrocarbon lighter hydrocarbons, 7 parts of ethyl acetate, 4 parts of dehydrated alcohol, 4 parts of petroleum ether.
3. as claimed in claim 2 for reducing the clean fuel of exhaust emissions, which is characterized in that also wrapped in the fuel Containing fuel oil additive and ferrocene.
4. as claimed in claim 3 for reducing the clean fuel of exhaust emissions, which is characterized in that the combustion in the fuel The mass content of oil additive and ferrocene total 1.3 ‰.
5. as claimed in claim 4 for reducing the clean fuel of exhaust emissions, which is characterized in that the fuel oil additive It is mixed with ferrocene with arbitrary proportion.
6. as claimed in claim 5 for reducing the clean fuel of exhaust emissions, which is characterized in that the fuel oil additive Include clean type additive, maintaining additive or power hoist type additive.
7. as claimed in claim 6 for reducing the clean fuel of exhaust emissions, which is characterized in that the fuel oil additive Include polyisobutylene amine or polyetheramine.
8. a kind of preparation method of the clean fuel for reducing exhaust emissions as described in any one of claim 1~7, It is characterized in that, the method includes:
Step 1 weighs each raw material in proportion;
Step 2 takes methanol to be put into blender, and ethyl acetate is added, stands after stirring;
Step 3 adds light dydrocarbon lighter hydrocarbons into the mixture of step 2, stands after stirring;
Step 4 sequentially adds petroleum ether, dehydrated alcohol, fuel oil additive and ferrocene into the mixture of step 3, after stirring It stands.
9. as claimed in claim 8 for reducing the preparation method of the clean fuel of exhaust emissions, which is characterized in that described Mixing time in step 2 and step 3 is 10 minutes, then stands 5 minutes respectively again.
10. as claimed in claim 8 for reducing the preparation method of the clean fuel of exhaust emissions, which is characterized in that described Step 4 in mixing time be 20 minutes, then stand 10 minutes again.
CN201811559026.4A 2018-12-19 2018-12-19 A kind of clean fuel and preparation method thereof for reducing exhaust emissions Withdrawn CN109609207A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110331011A (en) * 2019-05-09 2019-10-15 杨龙 It is a kind of for removing the fuel assistants of automobile carbon deposition
CN110819396A (en) * 2019-11-22 2020-02-21 湖南红宝科技开发有限公司 Composite additive, ethanol gasoline and preparation method thereof
CN113881467A (en) * 2021-11-13 2022-01-04 程天 Clean hydrogen-rich fuel for vehicle

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104711044A (en) * 2015-02-28 2015-06-17 刘燕 Alcohol-based fuel and preparation method thereof
CN105567344A (en) * 2015-12-29 2016-05-11 丁正本 High portion methanol gasoline capable of being used in low temperature environment
CN105567345A (en) * 2015-12-29 2016-05-11 丁正本 Methanol gasoline with high portion
CN106350125A (en) * 2016-09-30 2017-01-25 广西东奇能源技术有限公司 Alcohol-based fuel with high calorific value

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104711044A (en) * 2015-02-28 2015-06-17 刘燕 Alcohol-based fuel and preparation method thereof
CN105567344A (en) * 2015-12-29 2016-05-11 丁正本 High portion methanol gasoline capable of being used in low temperature environment
CN105567345A (en) * 2015-12-29 2016-05-11 丁正本 Methanol gasoline with high portion
CN106350125A (en) * 2016-09-30 2017-01-25 广西东奇能源技术有限公司 Alcohol-based fuel with high calorific value

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110331011A (en) * 2019-05-09 2019-10-15 杨龙 It is a kind of for removing the fuel assistants of automobile carbon deposition
CN110819396A (en) * 2019-11-22 2020-02-21 湖南红宝科技开发有限公司 Composite additive, ethanol gasoline and preparation method thereof
CN113881467A (en) * 2021-11-13 2022-01-04 程天 Clean hydrogen-rich fuel for vehicle

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