CN109593470A - Natural real stone paint coating and preparation method thereof - Google Patents
Natural real stone paint coating and preparation method thereof Download PDFInfo
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- CN109593470A CN109593470A CN201811476517.2A CN201811476517A CN109593470A CN 109593470 A CN109593470 A CN 109593470A CN 201811476517 A CN201811476517 A CN 201811476517A CN 109593470 A CN109593470 A CN 109593470A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D201/00—Coating compositions based on unspecified macromolecular compounds
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1687—Use of special additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
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Abstract
The invention discloses a kind of natural real stone paint coating, it is related to paint field, its key points of the technical solution are that according to the mass fraction, including following component, 0~600 part of 1820.2~1921.2 parts of lacquer paint lotion 838A-2,411.2~452.2 parts of 15wt% aqueous solution of zinc stearate, 2wt% powder water MZ413.2~450.2 part, 402.2~461.2 parts of water, 264.2~311.4 parts of 2wt% hydroxyethyl cellulose, 12~87.2 parts of alcohol ester, 26.3~29.9 parts of ethylene glycol, 6.0~8.4 parts of preservative, 10486.2~11390.6 parts of quartz sand and other auxiliary agents.Through the above technical solutions, being effectively guaranteed the characteristic of coating antipollution and freedom from cracking, and the relatively simple suitable scale of preparation method of the application coating produces.
Description
Technical field
The present invention relates to paint field, in particular to a kind of natural real stone paint coating and preparation method thereof.
Background technique
Lithotome is commonly used, but lithotome is by natural crystal in building at present to achieve the effect that natural stone material
Limitation, color and figure line are inhomogenous after decoration, can not also renovate, tool exploitation processing difficulties, expensive；Bulk density
Greatly, wall is loaded greatly, is unsuitable for the decoration of light-weight building, in addition, difficulty of construction is big, especially corner part needs special add
Work is handled, and the gap between stone material will add close joint glue, and whole waxing is carried out after construction.
The spraying effect of lacquer is solemnly elegant, can sufficiently show the abundant texture of lithotome, while having extremely strong
Adhesive force, high rigidity, rich texture, cost economic, good weatherability also have fire prevention, acid and alkali-resistance, anti-pollution, nontoxic, nothing
Taste shows the features such as beautiful texture of the will never fade holding wall of color for a long time using natural rubble.The application of lacquer is very
Extensively, its decorative effect is comparable to stone material, and is more suitable for moulding various designs than stone material, can be used as exterior wall and embossment, beam
The abnormal shape wall decoration such as column, suitable for doing exterior wall mural painting, it can also be used to which interior decoration has granite, marble, the color as numb stone
Damp effect, in particular for can get the effect mixed the spurious with the genuine on the decoration such as indoor cylinder, FRP Columns.
However, traditional lacquer be coated on body surface after, surface vulnerable to pollution and cracking, thus up for
It improves.
Summary of the invention
The object of the present invention is to provide a kind of natural real stone paint coating, have the property of antipollution and freedom from cracking well
Can, it is suitble to different finishings to be used, while preparation method is relatively simple, suitable scale is produced.
Above-mentioned technical purpose of the invention has the technical scheme that
A kind of natural real stone paint coating, which is characterized in that according to the mass fraction, including following component, lacquer paint lotion 838A-
2 1820.2~1921.2 parts, 411.2~452.2 parts of 15wt% aqueous solution of zinc stearate, 2wt% powder water MZ413.2~450.2
Part, 402.2~461.2 parts of water, 264.2~311.4 parts of 2wt% hydroxyethyl cellulose, 12~87.2 parts of alcohol ester, second two
26.3~29.9 parts of alcohol, 6.0~8.4 parts of preservative, 10486.2~11390.6 parts of quartz sand, 0~600 part of other auxiliary agents.
It can will be applied after paint solidification by using above-mentioned technical proposal due to the addition of hydroxyethyl cellulose
Multiple points connect in expecting, to also just have effectively achieved the entirety of coating, and then also just reduce coating and are cracked
Probability.Secondly as the addition of zinc stearate, can make coating after solidification, surface has good glossiness, thus
Also the probability that spot is attached to coating surface is just reduced, and then realizes the resistant to pollution characteristic of coating.
Preferably, the 2wt% hydroxyethyl cellulose according to the mass fraction, including following component, hydroxyethyl cellulose 40
Part, 1 part of defoaming agent NXZ, 1 part of preservative FE-15,0.5 part of multifunctional assistant AMP-95 and 1957.5 parts of water.
Preferably, the 2wt% powder water MZ according to the mass fraction, including following component: 40 parts of captax Z, defoaming agent
1 part of NXZ, 1 part of preservative FE-15,0.5 part of multifunctional assistant AMP-95,1957.5 parts of water.
By using above-mentioned technical proposal, fluid is first made in the auxiliary agents such as hydroxyethyl cellulose and promotor, is then added to
In coating, be conducive to improve the mobility in mixed process such as hydroxyethyl cellulose and promotor in this way, thus also just effectively
Ground enhances hydroxyethyl cellulose and promotor dispersion effect.
Preferably, other described auxiliary agents be iodized salt, conch meal, antioxidant and diatomite, wherein iodized salt, conch meal,
The mass ratio of antioxidant and diatomite is 1: 1.2: 2.8: 45.
Preferably, the iodized salt is middle one kind of lithium iodide or cuprous iodide.
By using above-mentioned technical proposal, the people after selecting lithium iodide and cuprous iodide to can be improved paint solidification stablizes
Property.Simultaneously as lithium iodide is compared to other iodized salts, not only due to the physical property of itself and improve the thermostabilization of coating
Performance.Meanwhile the lithium ion in lithium iodide can also there are mating reactions between the carbonyl in coating, produce similar network
Structure, hinder the movement of coating strand and corresponding free radical, thus make polymer molecular chain when being thermally decomposed than complete
Complete free strand need to overcome bigger energy barrier, thus, effectively widen the application field of the application emulsion paint.
Preferably, the conch meal is through the mixed enzyme solution processing containing alkali protease, papain and trypsase
Grinding shells after be made.
It can accelerate coating because the main component of conch meal is calcium carbonate by using above-mentioned technical proposal and apply
Solidification rate during work.Meanwhile after three kinds of enzymatic treatments, the chitin in shell can be released effectively.
And chitin inherently has stronger antibiotic and sterilizing performance, so that it is enterprising in building wall to advantageously reduce fungal microbe
Row growth, and the metope of building is damaged, and then also just play certain antiseptic property.In addition, chitin also has
Stronger year viscosity, the adhesion firmness that can be further ensured that between each component, to improve the adhesive ability of coating.
Preferably, the antioxidant is the mixture of antioxidant 1076, antioxidant 1010 and irgasfos 168, and antioxidant
1076, the mass ratio of antioxidant 1010 and irgasfos 168 is 1: 3: 1.
By using above-mentioned technical proposal, above-mentioned antioxidant can effectively improve the antioxidant of coating, be conducive in this way
Extend the service life of coating.Also, the composite antioxidant being made into antioxidant 1076, antioxidant 1010 and irgasfos 168
With preferably antioxygenic property.
Preferably, the preservative is the mixture of preservative FE-15 and potassium sorbate, and preservative FE-15 and sorb
The mass ratio of sour potassium is 1: 1.
By using above-mentioned technical proposal, since potassium sorbate easily decomposes in air, and compound antioxidant energy
It is enough to play a protective role to the potassium sorbate on coating surface layer, and then also just extend the anti-corrosion time of potassium sorbate.Also, sorb
The antiseptic property of sour potassium in acid condition can be promoted effectively, and ethylene glycol in air relative to potassium sorbate more
It is oxidized easily, so that the ethylene glycol on surface layer is oxidized easily generation carboxyl after construction, is provided for the anti-corrosion of potassium sorbate
Certain acidic environment.
A kind of preparation method of natural real stone paint coating, includes the following steps:
Step 1: the preparation of 2wt% hydroxyethyl cellulose: by 40 parts of hydroxyethyl celluloses, 1 part of defoaming agent NXZ, 1 portion of preservative
FE-15,0.5 part of multifunctional assistant AMP-95 and 1957.5 parts of water are added in mixer and are stirred, until being sufficiently mixed；
Step 2: the preparation of 2wt% powder water MZ: by 40 parts of captax Z, 1 part of defoaming agent NXZ, 1 part of preservative FE-15,0.5
Part multifunctional assistant AMP-95 and 1957.5 parts of water are added in mixer and are stirred, until being sufficiently mixed；
Step 3: 402.2~461.2 parts of water of measurement and 26.3~29.9 parts of ethylene glycol are thoroughly mixed, double solvents is obtained；
Step 4: by 264.2~311.4 parts made from 1820.2~1921.2 parts of lacquer paint lotion 838A-2, step 1
413.2~450.2 parts of 2wt% powder water MZ and 411.2~452.2 parts of 15wt% made from 2wt% hydroxyethyl cellulose, step 2
Aqueous solution of zinc stearate is added in the double solvents of step 3, continues to be stirred, and obtains just mixture；
Step 5: by 81.1~87.2 parts of alcohol esters, 12,6.0~8.4 portions of preservatives, 10486.2~11390.6 parts of quartz sands and
0~600 part of other auxiliary agent is added in the first mixed object of step 4, and further progress is stirred, filtered later to obtain into
Product natural real stone paint coating.
Preferably, in step 5 in filtered filtrate the granularity of solid particle less than 10 μm.
By using above-mentioned technical proposal, the fine and smooth sense of natural real stone paint coating is advantageously ensured that in this way, to facilitate
The planarization of emulsion paint after application.
In conclusion the invention has the following advantages:
1, under the collective effect of hydroxyethyl cellulose and zinc stearate, so that globality is more preferable after hardening for coating, surface is more
To be smooth, to also just improve coating freedom from cracking and resistant to pollution performance；
2, the addition of iodized salt effectively improves the thermal stability of coating, consequently facilitating carried out in hot environment using；
3, conch meal can be improved the solidification effect and anti-microbial property of coating, occur breeding very to also just reduce coating surface
The probability of bacterium, and then decrease destruction of the fungi to dope layer.
Detailed description of the invention
Fig. 1 is the preparation method flow chart of natural real stone paint coating.
Specific embodiment
Below in conjunction with attached drawing 1, invention is further described in detail.
Embodiment one,
A kind of preparation method of natural real stone paint coating, includes the following steps:
Step 1: the preparation of 2wt% hydroxyethyl cellulose: by 40Kg hydroxyethyl cellulose, 1Kg defoaming agent NXZ, 1Kg preservative
FE-15,0.5Kg multifunctional assistant AMP-95 and 1957.5Kg water are added in mixer, are stirred with 100rpm revolving speed
30min, until being sufficiently mixed；
Step 2: the preparation of 2wt% powder water MZ: by 40Kg captax Z, 1Kg defoaming agent NXZ, 1Kg preservative FE-15,
0.5Kg multifunctional assistant AMP-95 and 1957.5Kg water is added in mixer, is stirred 30min with 100rpm revolving speed, directly
To being sufficiently mixed；
Step 3: measurement 402.2Kg water and 26.3Kg ethylene glycol are abundant, are mixed, obtained with 300rpm revolving speed stirring 10min
Double solvents；
Step 4: by 264.2Kg2wt% hydroxyethyl cellulose made from 1820.2Kg lacquer paint lotion 838A-2, step 1,
413.2Kg2wt% powder water MZ and 411.2Kg15wt% aqueous solution of zinc stearate made from step 2 is added to the compound of step 3
In solvent, continues former speed and be stirred 1h mixing, while being warming up to 50 DEG C, obtain just mixture；
Step 5: 81.1Kg alcohol ester 12,6.0Kg preservative and 10486.2Kg quartz sand to be added to the first mixed object of step 4
In, 2h mixing is further stirred with 500rpm revolving speed, while temperature rises to 80 DEG C, and it is natural that finished product is obtained by filtration while hot later
Lacquer coating.Wherein, in filtered filtrate the granularity of solid particle less than 10 μm.
Herein, lacquer paint lotion 838A-2 can be bought from Bao Lijia Group Co., Ltd, and preservative FE-15 can be from Shanghai
Mai Ken Biotechnology Co., Ltd buys.
Embodiment two,
A kind of preparation method of natural real stone paint coating, the difference with embodiment one be only that,
Step 3: measurement 461.2Kg water and 29.9Kg ethylene glycol are abundant, are mixed, obtained with 300rpm revolving speed stirring 10min
Double solvents；
Step 4: by 311.4Kg2wt% hydroxyethyl cellulose made from 1921.2Kg lacquer paint lotion 838A-2, step 1,
450.2Kg2wt% powder water MZ and 452.2Kg15wt% aqueous solution of zinc stearate made from step 2 is added to the compound of step 3
In solvent, continues former speed and be stirred 1h mixing, while being warming up to 50 DEG C, obtain just mixture；
Step 5: 87.2Kg alcohol ester 12,8.4Kg preservative, 11390.6Kg quartz sand and 600Kg other auxiliary agents are added to
In the first mixed object of step 4,2h mixing is further stirred with 500rpm revolving speed, while temperature rises to 80 DEG C, later mistake while hot
Filter obtains finished product natural real stone paint coating.Wherein, in filtered filtrate the granularity of solid particle less than 10 μm.
Herein, other auxiliary agents are iodized salt, conch meal, antioxidant and diatomite, wherein iodized salt, conch meal, antioxidant
Mass ratio with diatomite is 1: 1.2: 2.8: 45.And iodized salt is mainly cuprous iodide.
And conch meal the preparation method comprises the following steps: first prepare the sodium sulfite buffer solution that 50ml pH is 8.0, it is logical with 1ml Qula
As surfactant, and use the alkali protease that mass ratio is 1: 1: 1, the group synthase 5g of papain and trypsase
It is catalyzed；By sodium sulfite buffer solution, Qula is logical and group synthase three is mixed to get enzyme solution；Shell is soaked in enzyme solution,
Controlling constant temperature shaker temperature is 50 DEG C, is hydrolyzed 2 hours under conditions of revolving speed 300r/min；Later, by grinding shells at average grain
The conch meal that degree is 10 μm.Wherein, the preparation of sodium sulfite buffer solution is the prior art, and be not the application core in
Hold, because without being developed in details herein.
In addition, antioxidant herein is antioxidant 1076, the mixture of antioxidant 1010 and irgasfos 168, and antioxidant
1076, the mass ratio of antioxidant 1010 and irgasfos 168 is 1: 3: 1.And preservative is the mixed of preservative FE-15 and potassium sorbate
Object is closed, and the mass ratio of preservative FE-15 and potassium sorbate is 1: 1.
Embodiment three,
A kind of preparation method of natural real stone paint coating, the difference with embodiment one be only that,
Step 3: measurement 431.7Kg water and 28.1Kg ethylene glycol are abundant, are mixed, obtained with 300rpm revolving speed stirring 10min
Double solvents；
Step 4: by 287.8Kg2wt% hydroxyethyl cellulose made from 1870.7Kg lacquer paint lotion 838A-2, step 1,
431.7Kg2wt% powder water MZ and 431.7Kg15wt% aqueous solution of zinc stearate made from step 2 is added to the compound of step 3
In solvent, continues former speed and be stirred 1h mixing, while being warming up to 50 DEG C, obtain just mixture；
Step 5: 84.15Kg alcohol ester 12,7.2Kg preservative, 10938.4Kg quartz sand and 300Kg other auxiliary agents are added to
In the first mixed object of step 4,2h mixing is further stirred with 500rpm revolving speed, while temperature rises to 80 DEG C, later mistake while hot
Filter obtains finished product natural real stone paint coating.Wherein, in filtered filtrate the granularity of solid particle less than 10 μm.
Herein, other auxiliary agents are iodized salt, conch meal, antioxidant and diatomite, wherein iodized salt, conch meal, antioxidant
Mass ratio with diatomite is 1: 1.2: 2.8: 45.And iodized salt is mainly lithium iodide.
And conch meal the preparation method comprises the following steps: first prepare the sodium sulfite buffer solution that 50ml pH is 8.0, it is logical with 1ml Qula
As surfactant, and use the alkali protease that mass ratio is 1: 1: 1, the group synthase 5g of papain and trypsase
It is catalyzed；By sodium sulfite buffer solution, Qula is logical and group synthase three is mixed to get enzyme solution；Shell is soaked in enzyme solution,
Controlling constant temperature shaker temperature is 50 DEG C, is hydrolyzed 2 hours under conditions of revolving speed 300r/min；Later, by grinding shells at average grain
The conch meal that degree is 10 μm.Wherein, the preparation of sodium sulfite buffer solution is the prior art, and be not the application core in
Hold, because without being developed in details herein.
In addition, antioxidant herein is antioxidant 1076, the mixture of antioxidant 1010 and irgasfos 168, and antioxidant
1076, the mass ratio of antioxidant 1010 and irgasfos 168 is 1: 3: 1.And preservative is the mixed of preservative FE-15 and potassium sorbate
Object is closed, and the mass ratio of preservative FE-15 and potassium sorbate is 1: 1.
Example IV,
A kind of preparation method of natural real stone paint coating, the difference with embodiment one be only that,
Step 3: measurement 402.2Kg water and 29.9Kg ethylene glycol are abundant, are mixed, obtained with 300rpm revolving speed stirring 10min
Double solvents；
Step 4: by 311.4Kg2wt% hydroxyethyl cellulose made from 1870.7Kg lacquer paint lotion 838A-2, step 1,
431.7Kg2wt% powder water MZ and 411.2Kg15wt% aqueous solution of zinc stearate made from step 2 is added to the compound of step 3
In solvent, continues former speed and be stirred 1h mixing, while being warming up to 50 DEG C, obtain just mixture；
Step 5: 84.15Kg alcohol ester 12,6.0Kg preservative, 10938.4Kg quartz sand and 600Kg other auxiliary agents are added to
In the first mixed object of step 4,2h mixing is further stirred with 500rpm revolving speed, while temperature rises to 80 DEG C, later mistake while hot
Filter obtains finished product natural real stone paint coating.Wherein, in filtered filtrate the granularity of solid particle less than 10 μm.
Herein, other auxiliary agents are iodized salt, conch meal, antioxidant and diatomite, wherein iodized salt, conch meal, antioxidant
Mass ratio with diatomite is 1: 1.2: 2.8: 45.And iodized salt is mainly lithium iodide.
And conch meal the preparation method comprises the following steps: first prepare the sodium sulfite buffer solution that 50ml pH is 8.0, it is logical with 1m1 Qula
As surfactant, and use the alkali protease that mass ratio is 1: 1: 1, the group synthase 5g of papain and trypsase
It is catalyzed；By sodium sulfite buffer solution, Qula is logical and group synthase three is mixed to get enzyme solution；Shell is soaked in enzyme solution,
Controlling constant temperature shaker temperature is 50 DEG C, is hydrolyzed 2 hours under conditions of revolving speed 300r/min；Later, by grinding shells at average grain
The conch meal that degree is 10 μm.Wherein, the preparation of sodium sulfite buffer solution is the prior art, and be not the application core in
Hold, because without being developed in details herein.
In addition, antioxidant herein is antioxidant 1076, the mixture of antioxidant 1010 and irgasfos 168, and antioxidant
1076, the mass ratio of antioxidant 1010 and irgasfos 168 is 1: 3: 1.And preservative is the mixed of preservative FE-15 and potassium sorbate
Object is closed, and the mass ratio of preservative FE-15 and potassium sorbate is 1: 1.
Embodiment five,
A kind of preparation method of natural real stone paint coating, the difference with embodiment one be only that,
Step 3: measurement 461.2Kg water and 29.9Kg ethylene glycol are abundant, are mixed, obtained with 300rpm revolving speed stirring 10min
Double solvents；
Step 4: by 311.4Kg2wt% hydroxyethyl cellulose made from 1820.2Kg lacquer paint lotion 838A-2, step 1,
413.2Kg2wt% powder water MZ and 431.7Kg15wt% aqueous solution of zinc stearate made from step 2 is added to the compound of step 3
In solvent, continues former speed and be stirred 1h mixing, while being warming up to 50 DEG C, obtain just mixture；
Step 5: 87.2Kg alcohol ester 12,8.4Kg preservative, 10486.2Kg quartz sand and 300Kg other auxiliary agents are added to
In the first mixed object of step 4,2h mixing is further stirred with 500rpm revolving speed, while temperature rises to 80 DEG C, later mistake while hot
Filter obtains finished product natural real stone paint coating.Wherein, in filtered filtrate the granularity of solid particle less than 10 μm.
Herein, other auxiliary agents are iodized salt, conch meal, antioxidant and diatomite, wherein iodized salt, conch meal, antioxidant
Mass ratio with diatomite is 1: 1.2: 2.8: 45.And iodized salt is mainly cuprous iodide.
And conch meal the preparation method comprises the following steps: first prepare the sodium sulfite buffer solution that 50ml pH is 8.0, it is logical with 1ml Qula
As surfactant, and use the alkali protease that mass ratio is 1: 1: 1, the group synthase 5g of papain and trypsase
It is catalyzed；By sodium sulfite buffer solution, Qula is logical and group synthase three is mixed to get enzyme solution；Shell is soaked in enzyme solution,
Controlling constant temperature shaker temperature is 50 DEG C, is hydrolyzed 2 hours under conditions of revolving speed 300r/min；Later, by grinding shells at average grain
The conch meal that degree is 10 μm.Wherein, the preparation of sodium sulfite buffer solution is the prior art, and be not the application core in
Hold, because without being developed in details herein.
In addition, antioxidant herein is antioxidant 1076, the mixture of antioxidant 1010 and irgasfos 168, and antioxidant
1076, the mass ratio of antioxidant 1010 and irgasfos 168 is 1: 3: 1.And preservative is the mixed of preservative FE-15 and potassium sorbate
Object is closed, and the mass ratio of preservative FE-15 and potassium sorbate is 1: 1.
Meanwhile comparative example one has also been devised to comparative example five, every object according to the preparation method of embodiment three in the application
The content of material is as shown in Table 1:
Table one
Above-described embodiment one to embodiment five and comparative example one to comparative example five are detected as follows, the result of detection such as table
Two and table three shown in, the method for detection is as follows:
(1) adhesive force is tested: standard GB/T9286-1998；
(2) heat stability testing: will be placed in 120 DEG C of water vapors with a thickness of the coating film-making of 2mm, and observation is crushed
The required time；
(3) solidification timeliness test: standard GB/T1728-79 (89)；
(4) ageing-resistant test: standard GB/T 1865-1997, ageing time 10h；
(5) cell culture fluid: being directly added dropwise the coating surface of 10cm*10cm after hardening by antibacterial test, and by the coating
It is placed in room temperature 3 days, observes the quantity of bacterium colony；
(6) VOCs content measuring: the 3rd day after finishing, testing the VOCs content in room using VOCs detector,
US-EPA(1996)≤0.2mg/m3；
(7) antipollution is tested: machine oil and mud are poured into respectively on the metope of coated coating, see whether that spot is attached
?；
(8) freedom from cracking test: by coating be coated on a sheet glass on, paint thickness 1mm, and be put into 120 DEG C of baking oven into
Whether row baking 10 hours, observation coating are cracked.
Table two
Table three
It can be clearly seen from upper table two and table three, the coating of the application not only has good antipollution and freedom from cracking
Performance.Meanwhile the comparative example one in embodiment three and table three is compared and analyzed to comparative example five it can be concluded that, conch meal
Addition effectively improves the certain adhesive force of coating and antibiotic property, and the antioxidant effect of compound antioxidant is more anti-than single
The antioxidant effect of oxygen agent is more effective.Furthermore the content of the application coating VOCs is lower, and meets the standard in the U.S., thus right
The influence of human health is relatively low, is suitble to multi-field use.
This specific embodiment is only explanation of the invention, is not limitation of the present invention, those skilled in the art
Member can according to need the modification that not creative contribution is made to the present embodiment after reading this specification, but as long as at this
All by the protection of Patent Law in the scope of the claims of invention.
Claims (10)
1. a kind of natural real stone paint coating, which is characterized in that according to the mass fraction, including following component,
2. a kind of natural real stone paint coating according to claim 1, which is characterized in that the 2wt% hydroxyethyl cellulose
According to the mass fraction, including following component,
3. a kind of natural real stone paint coating according to claim 1, it is characterised in that: the 2wt% powder water MZ presses quality
Number meter, including following component:
4. a kind of natural real stone paint coating according to claim 1, it is characterised in that: other described auxiliary agents be iodized salt,
Conch meal, antioxidant and diatomite, wherein the mass ratio of iodized salt, conch meal, antioxidant and diatomite is 1: 1.2: 2.8: 45.
5. a kind of natural real stone coating according to claim 1, it is characterised in that: the iodized salt is lithium iodide or iodate
Cuprous middle one kind.
6. a kind of natural real stone paint coating according to claim 1, it is characterised in that: the conch meal is passed through containing alkaline egg
It is made after the grinding shells of the mixed enzyme solution processing of white enzyme, papain and trypsase.
7. a kind of natural real stone paint coating according to claim 1, it is characterised in that: the antioxidant is antioxidant
1076, the mixture of antioxidant 1010 and irgasfos 168, and the mass ratio of antioxidant 1076, antioxidant 1010 and irgasfos 168
It is 1: 3: 1.
8. a kind of natural real stone paint coating according to claim 1, it is characterised in that: the preservative is preservative FE-
15 and potassium sorbate mixture, and the mass ratio of preservative FE-15 and potassium sorbate be 1: 1.
9. a kind of preparation method of natural real stone paint coating as described in any one of claim 1 to 8 claim, including
Following steps:
Step 1: the preparation of 2wt% hydroxyethyl cellulose: by 40 parts of hydroxyethyl celluloses, 1 part of defoaming agent NXZ, 1 portion of preservative
FE-15,0.5 part of multifunctional assistant AMP-95 and 1957.5 parts of water are added in mixer and are stirred, until being sufficiently mixed；
Step 2: the preparation of 2wt% powder water MZ: by 40 parts of captax Z, 1 part of defoaming agent NXZ, 1 part of preservative FE-15,0.5 part
Multifunctional assistant AMP-95 and 1957.5 parts of water are added in mixer and are stirred, until being sufficiently mixed；
Step 3: 402.2~461.2 parts of water of measurement and 26.3~29.9 parts of ethylene glycol are thoroughly mixed, double solvents is obtained；
Step 4: by 264.2~311.4 parts made from 1820.2~1921.2 parts of lacquer paint lotion 838A-2, step 1
413.2~450.2 parts of 2wt% powder water MZ and 411.2~452.2 parts of 15wt% made from 2wt% hydroxyethyl cellulose, step 2
Aqueous solution of zinc stearate is added in the double solvents of step 3, continues to be stirred, and obtains just mixture；
Step 5: by 81.1~87.2 parts of alcohol esters, 12,6.0~8.4 portions of preservatives, 10486.2~11390.6 parts of quartz sands and
0~600 part of other auxiliary agent is added in the first mixed object of step 4, and further progress is stirred, filtered later to obtain into
Product natural real stone paint coating.
10. a kind of preparation method of natural real stone paint coating according to claim 9, it is characterised in that: mistake in step 5
The granularity of solid particle is less than 10 μm in filtrate after filter.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110964386A (en) * | 2019-12-10 | 2020-04-07 | 上海保立佳新材料有限公司 | Exterior wall coating with high stain resistance and preparation method thereof |
| CN111533492A (en) * | 2020-04-29 | 2020-08-14 | 广东法兰迪涂料有限公司 | Real stone paint and preparation method thereof |
| CN114806296A (en) * | 2022-03-31 | 2022-07-29 | 苏州皇冠涂料科技发展有限公司 | Natural stone paint and preparation method thereof |
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| CN102533038A (en) * | 2011-12-19 | 2012-07-04 | 河南省德嘉丽科技开发有限公司 | Natural stone paint |
| CN108440778A (en) * | 2018-03-26 | 2018-08-24 | 余远见 | One kind being used for photovoltaic module isolating bar and its production method |
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Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102533038A (en) * | 2011-12-19 | 2012-07-04 | 河南省德嘉丽科技开发有限公司 | Natural stone paint |
| CN108440778A (en) * | 2018-03-26 | 2018-08-24 | 余远见 | One kind being used for photovoltaic module isolating bar and its production method |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110964386A (en) * | 2019-12-10 | 2020-04-07 | 上海保立佳新材料有限公司 | Exterior wall coating with high stain resistance and preparation method thereof |
| CN111533492A (en) * | 2020-04-29 | 2020-08-14 | 广东法兰迪涂料有限公司 | Real stone paint and preparation method thereof |
| CN114806296A (en) * | 2022-03-31 | 2022-07-29 | 苏州皇冠涂料科技发展有限公司 | Natural stone paint and preparation method thereof |
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Application publication date: 20190409 |