CN109585579A - Solar battery and its manufacturing method and solar cell module - Google Patents

Solar battery and its manufacturing method and solar cell module Download PDF

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Publication number
CN109585579A
CN109585579A CN201711159534.9A CN201711159534A CN109585579A CN 109585579 A CN109585579 A CN 109585579A CN 201711159534 A CN201711159534 A CN 201711159534A CN 109585579 A CN109585579 A CN 109585579A
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China
Prior art keywords
solar battery
electrode
finger
finger electrode
strip structure
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CN201711159534.9A
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Chinese (zh)
Inventor
张评款
李济群
魏志铭
王亮棠
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Motech Industries Inc
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Motech Industries Inc
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/02Details
    • H01L31/0224Electrodes
    • H01L31/022408Electrodes for devices characterised by at least one potential jump barrier or surface barrier
    • H01L31/022425Electrodes for devices characterised by at least one potential jump barrier or surface barrier for solar cells
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/02Details
    • H01L31/0236Special surface textures
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/04Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices
    • H01L31/042PV modules or arrays of single PV cells
    • H01L31/048Encapsulation of modules
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/04Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices
    • H01L31/042PV modules or arrays of single PV cells
    • H01L31/05Electrical interconnection means between PV cells inside the PV module, e.g. series connection of PV cells
    • H01L31/0504Electrical interconnection means between PV cells inside the PV module, e.g. series connection of PV cells specially adapted for series or parallel connection of solar cells in a module
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/18Processes or apparatus specially adapted for the manufacture or treatment of these devices or of parts thereof
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E10/00Energy generation through renewable energy sources
    • Y02E10/50Photovoltaic [PV] energy
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50Manufacturing or production processes characterised by the final manufactured product

Abstract

A kind of solar battery and its manufacturing method and solar cell module.This solar battery includes substrate, emitter layer, passivation layer, at least a bus electrode, multiple finger electrodes and rear electrode.Emitter layer is located at the front of substrate.Passivation layer is configured on emitter layer.Bus electrode is configured at the front of substrate.Finger electrode is configured at the positive place of substrate and connect respectively with bus electrode, wherein each finger electrode includes that coarse top surface and two inclined sides connect with coarse top surface respectively, coarse top surface includes several strip structures, strip structure is configured along the width direction interval of the finger electrode at place, and each strip structure extends along the length direction of the finger electrode at place.Rear electrode is configured at the back side of substrate.The light of directive finger electrode can be effectively totally reflected in solar battery by strip structure, therefore can promote the absorptivity of solar battery, and then can increase the wattage output of solar cell module.

Description

Solar battery and its manufacturing method and solar cell module
Technical field
The invention relates to a kind of photoelectric conversion devices, and in particular to a kind of solar battery and its manufacturer Method and solar cell module.
Background technique
In order to promote the price advantage of solar cell module product, the product demand for meeting client and cooperation government's political affairs Plan, solar cell module manufacturer are there's no one who doesn't or isn't dedicated to developing high performance solar batteries module product.High efficiency p-type solar energy at present Battery module innately has cell package to lose (cell to module loss) higher disadvantage at module, leads to p-type solar energy The actual generation power of battery module is far below the initial designs of battery.Therefore, increase the wattage output of solar cell module And it reduces cell package and has become the important topic for developing high performance solar batteries module at module loss.
Efficiency in addition to improving solar battery, and using the upper plate of high-penetration rate, lower plate and encapsulating material outside, at present It proposes to make micro-structure on conductive welding and form light and capture conductive welding (light capturing ribbon, LCR) Technology and conductive welding attach light-redirecting film (light redirecting film, LRF) technology.Both Micro-structure or the micro-structure that is attached to conductive welding on of the light capturing technology using conductive welding itself, by directive conduction welding Light source is effectively totally reflected on solar battery, promotes the absorptivity of solar battery whereby, and then promote solar battery The wattage output of module.
However, the material cost of both conductive weldings is high, and cooperate the use of both conductive weldings that need to newly buy more string Welding machine, leads to that the production cost increases.In addition, light captures the electroplating surface silver of conductive welding, therefore need first in solar battery The conducting resinl of low temperature is coated on bus electrode, light captures conductive welding and could connect with bus electrode, so also results in processing procedure The increase of cost.In addition, light-redirecting film is attached at the stress increase that will lead to entire conductive welding structure on conductive welding, After thermal cycle (thermal cycle), solar cell module is easy to produce the problems such as finger electrode (finger) breaks.
Summary of the invention
Therefore, a purpose of the invention is exactly to provide a kind of solar battery and its manufacturing method and solar battery Module, wherein the finger electrode of solar battery includes coarse top surface, and coarse top surface includes several strip structures.Finger electrode Strip structure the light of directive finger electrode can be effectively totally reflected in solar battery, therefore solar battery can taken into account In the case where the reliability and reduction processing procedure cost of module, the absorptivity of solar battery is effectively promoted, and then can increase too The wattage output of positive energy battery module.
Above-mentioned purpose according to the present invention proposes a kind of solar battery.This solar battery include substrate, emitter layer, Passivation layer, at least a bus electrode, multiple finger electrodes and rear electrode.Substrate has front and the back side.Emitter layer is located at At front.Passivation layer is configured on emitter layer.Bus electrode is configured at the front of substrate.Finger electrode is being configured at substrate just It is connect at face and respectively with bus electrode, wherein each finger electrode includes coarse top surface and two inclined sides, this two inclined side Face connects with coarse top surface respectively, coarse top surface include several strip structures, strip structure along the finger electrode at place width The configuration of direction interval is spent, each strip structure extends along the length direction of the finger electrode at place.Rear electrode is configured at base At the back side of plate.
An embodiment according to the present invention, above-mentioned each strip structure are extended in parallel along the length direction of finger electrode Or it approaches and extends in parallel.
An embodiment according to the present invention, above-mentioned each strip structure extend to one of finger electrode far from bus electrode At end.
An embodiment according to the present invention, above-mentioned strip structure include multiple first strip structures and multiple second strips Structure, these first strip structures and the second strip structure are configured with the length direction interval for approaching parallel finger electrodes.
An embodiment according to the present invention, the bottom surface of above-mentioned each finger electrode and coarse top surface and two inclined sides Between general trapezoidal shape.
An embodiment according to the present invention, end of the above-mentioned finger electrode far from bus electrode are connected by a connection electrode It connects, multiple elongate configurations outstanding is configured in connection electrode, these elongate configuration intervals configure and along the length of connection electrode Direction extends.
An embodiment according to the present invention, above-mentioned each strip structure include at least one side, and this at least one side Tilt angle be about 20.9 degree to about 30 degree.
An embodiment according to the present invention, above-mentioned each strip structure include an at least arcuate flanks.
Above-mentioned purpose according to the present invention separately proposes a kind of solar cell module.This solar cell module includes upper Plate, lower plate, above-mentioned solar battery, the first encapsulated layer and the second encapsulated layer.Solar battery be set to upper plate and lower plate it Between.First encapsulated layer is set between upper plate and solar battery, to combine upper plate and solar battery.Second encapsulated layer is set to down Between plate and solar battery, to combine lower plate and solar battery.
Above-mentioned purpose according to the present invention more proposes a kind of manufacturing method of solar battery.In this method, base is provided Plate, wherein substrate has front and the back side.Emitter layer is formed at front.Passivation layer is formed on emitter layer.Form at least one Bus electrode is at the front of substrate.Formed multiple finger electrodes in substrate positive place and respectively with it is aforementioned at least one confluence electricity Pole connection, wherein each finger electrode include coarse top surface and two inclined sides, this two inclined side respectively with coarse top surface Connecting, this coarse top surface includes multiple strip structures, and strip structure is configured along the width direction interval of the finger electrode at place, Each strip structure extends along the length direction of the finger electrode at place.Rear electrode is formed at the back side of substrate.
An embodiment according to the present invention, forming above-mentioned finger electrode includes to form multiple finger electrode material layers in base At the front of plate and the top surface of each finger electrode material layer is roughened.
An embodiment according to the present invention forms after above-mentioned finger electrode is also contained in roughening treatment, refers to these Shape electrode material layer carries out drying and processing.
An embodiment according to the present invention forms above-mentioned finger electrode and is also contained in form finger electrode material layer in base The positive place of plate and between being roughened, carries out drying and processing to finger electrode material layer.
An embodiment according to the present invention, above-mentioned each strip structure are extended in parallel along the length direction of finger electrode Or it approaches and extends in parallel.
An embodiment according to the present invention, above-mentioned each strip structure extend to one of finger electrode far from bus electrode At end.
An embodiment according to the present invention, above-mentioned strip structure include multiple first strip structures and multiple second strips Structure, these first strip structures and the second strip structure are configured with the length direction interval for approaching parallel finger electrodes.
An embodiment according to the present invention, the bottom surface of above-mentioned each finger electrode and coarse top surface and two inclined sides Between general trapezoidal shape.
An embodiment according to the present invention, end of the above-mentioned finger electrode far from bus electrode are connected by a connection electrode It connects, multiple elongate configurations outstanding is configured in this connection electrode, these elongate configuration intervals configure and along the length of connection electrode Direction is spent to extend.
An embodiment according to the present invention, above-mentioned each strip structure include at least one side, and this at least one side Tilt angle be 20.9 degree to 30 degree.
An embodiment according to the present invention, above-mentioned each strip structure include an at least arcuate flanks.
Detailed description of the invention
For above and other purpose, feature, advantage and embodiment of the invention can be clearer and more comprehensible, appended attached drawing is said It is bright as follows:
Fig. 1 is the diagrammatic cross-section for being painted a kind of solar cell module according to one embodiment of the present invention;
Fig. 2 is the upper schematic diagram for being painted a kind of solar battery according to one embodiment of the present invention;
Fig. 3 is the enlarged local section schematic diagram for being painted the AA hatching cutting solar battery obtained along Fig. 2;
Fig. 4 is the amagnified partial perspective schematic diagram for being painted a kind of solar battery according to one embodiment of the present invention;
Fig. 5 is the enlarged local section signal being painted according to a kind of solar cell module of one embodiment of the present invention Figure;
Fig. 6 is the amagnified partial perspective schematic diagram for being painted a kind of solar battery according to one embodiment of the present invention;
Fig. 7 is the amagnified partial perspective signal being painted according to a kind of solar battery of another embodiment of the present invention Figure;And
Fig. 8 is the manufacturing flow chart for being painted a kind of solar battery according to one embodiment of the present invention.
Specific embodiment
Fig. 1 is please referred to, is to be painted to show according to a kind of section of solar cell module of one embodiment of the present invention It is intended to.In some embodiments, solar cell module 100 mainly may include solar battery 110, upper plate 120, lower plate 130, First encapsulated layer 140 and the second encapsulated layer 150.As shown in Figure 1, in solar cell module 100, solar battery 110 It is arranged between upper plate 120 and lower plate 130.First encapsulated layer 140 is set between upper plate 120 and solar battery 110, to combine Upper plate 120 and solar battery 110.Second encapsulated layer 150 is then set between lower plate 130 and solar battery 110, under combination Plate 130 and solar battery 110.For example, pass through the program of high-temperature laminating, the first encapsulated layer 140 and the second encapsulated layer 150 Solar battery 110 can be combined with upper plate 120 and lower plate 130 respectively when molten state.
When solar cell module 100 is that single side enters light type and is that front enters light, upper plate 120 is transparent panel, such as glass Glass plate.At this point, the first encapsulated layer 140 is also transparent configuration, lower plate 130 and the second encapsulated layer 150 can be transparent configuration or non- Bright structure.And when solar cell module 100 is that single side enters light type and is that the back side enters light, lower plate 130 is transparent back panel, such as Glass plate.At this point, the second encapsulated layer 150 is also transparent configuration, upper plate 120 and the first encapsulated layer 140 can be transparent configuration or non- Transparent configuration.Solar cell module 100 be it is two-sided enter light type when, upper plate 120 and lower plate 130 are transparent panel, such as glass Glass plate.At this point, the first encapsulated layer 140 and the second encapsulated layer 150 are transparent configuration.First encapsulated layer 140 and the second encapsulated layer EVA material can be used in 150 implementations.
Referring to figure 2. to Fig. 4, wherein Fig. 2 is a kind of solar battery mould being painted according to one embodiment of the present invention The top view of block, Fig. 3 are the enlarged fragmentary cross sections for being painted the AA hatching cutting solar battery obtained along Fig. 2, Fig. 4 is the amagnified partial perspective schematic diagram for being painted the solar battery of Fig. 2.In some embodiments, solar battery 110 is main Include substrate 112, emitter layer 113, passivation layer 115, at least a bus electrode 114, several finger electrodes 116 and back side electricity Pole 117.The material of substrate 112 may be, for example, the semiconductor materials such as silicon.Substrate 112 includes positive 112a and the back side relative to each other 112b.Substrate 112 can be the first conductive type or the second conductive type substrate, and wherein the first conductive type may be, for example, p-type, and second leads Electric type can be N-shaped.
As shown in figure 3, emitter layer 113 is located at the positive 112a of substrate 112.Emitter layer 113 can comprehensively be set to base Position in plate 112 and close to front 112a.Emitter layer 113 can be the doped layer in substrate 112, and conductivity type is different from base Plate 112.For example, when the electrical property of substrate 112 is N-type, emitter layer 113 can be p-type doped layer, such as boron (B), aluminium (Al), gallium (Ga), indium (In) or thallium (Tl) doped layer.Passivation layer 115 can be covered on the positive 112a of substrate 112 and contact and penetrate Pole layer 113, to be passivated positive 112a.In some instances, the material of passivation layer 115 can be silica, silicon nitride or aluminium oxide, And first passivation layer 115 can be single layer structure or multilayer stacking structure.
In the embodiment shown in Figure 2, solar battery 110 includes that three bus electrodes 114 pass through passivation layer 115 and arrange It arranges and configures at the positive 112a of substrate 112.Finger electrode 116 again pass through passivation layer 115 and configure substrate 112 just At the 112a of face, wherein these finger electrodes 116 are connect with these three bus electrodes 114 respectively.These finger electrodes 116 respectively from The extension of these three bus electrodes 114 is dispersed at the positive 112a of substrate 112, and electric current is transferred to bus electrode 114.One It is a little it is two-sided enter light type solar battery example in, the back side 112b of substrate 112 is also equipped with extremely such as the configuration of positive 112a A few bus electrode and several finger electrodes.
As shown in figure 3, each finger electrode 116 includes coarse top surface 116t and two inclined side 116s, the two inclinations Side 116s connects with coarse top surface 116t respectively.In some instances, the bottom surface 116b of each finger electrode 116 and coarse top General trapezoidal shape between face 116t and two inclined side 116s.Coarse top surface 116t includes several strip structures 118.In Fig. 3 Shown in embodiment, coarse top surface 116t includes two strip structures 118, and this two strip structures 118 are along finger-like electricity The width direction 116w of pole 116 is close to configuration.In other examples, strip structure 118 can be spaced configuration to each other and between having Away from non-close setting.In some illustrative examples, each strip structure 118 includes at least one side 118s, and side 118s Tilt angle theta is about 20.9 degree to about 30 degree.The side 118s of strip structure 118 can be plane, convex globoidal or cancave cambered surface.
Referring to figure 4., these strip structures 118 extend along the length direction 116L of the finger electrode 116 at place.One In a little illustrative examples, strip structure 118 is extended in parallel or is approached along the length direction 116L of finger electrode 116 and extends in parallel. In other examples, the extending direction of strip structure 118 does not have the length direction 116L of parallel finger electrodes 116.Some In specific examples, the extending direction of the strip structure 118 of part and the length direction 116L of finger electrode 116 are parallel, another portion The extending direction of the strip structure 118 divided does not have the length direction 116L of parallel finger electrodes 116.As shown in figure 4, each strip Structure 118 extend to finger electrode 116 far from one end 116e of bus electrode 114 at.Rear electrode 117 is then configured in substrate At 112 back side 112b.
It referring to figure 5., is to be painted to put according to a kind of part of solar cell module of one embodiment of the present invention Heavy gauge schematic diagram.In some embodiments, upper plate 120 is glass plate, and the refractive index of the first encapsulated layer 140 is substantially identical in upper The refractive index of plate 120.At this point, the cirtical angle of total reflection degree between the upper surface and air of upper plate 120 is about 41.8 degree, finger electrode The tilt angle theta of the side 118s of strip structure 118 on 116 need to be greater than about 20.9 degree.Whereby, towards the item of finger electrode 116 After the incident light 160 of shape structure 118 is reflected by strip structure 118, the light 160 of the upper surface of directive upper plate 120 can be totally reflected It returns in substrate 112, therefore the absorptivity of solar battery 110 can be promoted, and then the output of 100 solar cell modules can be increased Wattage.Since strip structure 118 is arranged on finger electrode 116, it can save and conductive welding is captured using light and is attached There is light to relocate the increased cost of conductive welding institute of film, and the disconnection problem caused by avoiding because of thermal stress.
It please refers to referring concurrently to Fig. 2 and Fig. 6, wherein Fig. 6 is a kind of sun being painted according to one embodiment of the present invention The amagnified partial perspective schematic diagram of energy battery.It end of the finger electrode 116 far from bus electrode 114 can be by a connection electrode 111 Connection.In some instances, as shown in fig. 6, may be configured with several elongate configuration 111a outstanding in connection electrode 111.These Elongate configuration 111a can be close to configuration, or can be spaced configuration to each other and have spacing.Elongate configuration 111a can be along connection electricity The length direction 111L of pole 111 extends.
Fig. 7 is please referred to, is the partial enlargement for being painted a kind of solar battery according to another embodiment of the present invention Stereoscopic schematic diagram.In this embodiment, the coarse top surface 116t of each finger electrode 116a also includes several strip structures, In several first strip structure 118a and several Article 2 shape structure 118b are included at least in these strip structures.These first Shape structure 118a and the second strip structure 118b is with the interval length direction 116L parallel or nearly parallel to finger electrode 116a Configuration.
Please with reference to Fig. 8 and Fig. 2 to Fig. 4, wherein Fig. 8 is the one kind being painted according to one embodiment of the present invention The manufacturing flow chart of solar battery.In some embodiments, when manufacturing solar battery 110, step 200 can be first carried out, with Substrate 112 is provided.Step 210 is carried out again, in a manner of being for example doped processing procedure to the positive 112a of substrate 112, and just Emitter layer 113 is formed on the 112a of face.This emitter layer 113 extends on entire front 112a, and in practice, emitter layer 113 is set In the position in substrate 112 and close to front 112a.Next, step 220 can be carried out, it is blunt to be formed using such as deposition technique Change layer 115 and be covered on the positive 112a of substrate 112 and contact emitter layer 113, so as to being passivated front 112a.
Then, an at least bus electrode 114 is formed with multiple finger electrodes 116 on the positive 112a of substrate 112.One In a little illustrative examples, when forming bus electrode 114 and finger electrode 116, step 230 can be first carried out, to utilize such as wire mark side Formula forms an at least bus electrode material layer and multiple finger electrode material layers on the positive 112a of substrate 112.Bus electrode The material of material layer and finger electrode material layer can be metal paste.Then, step 240 is carried out, to each finger electrode material The top surface of layer is roughened.This roughening treatment is carried out using such as coining mode.To finger electrode material layer It, can be before coining first to finger electrode material if the slurry for constituting finger electrode material layer is too soft when top surface is roughened The bed of material carries out drying and processing, with finger electrode material layer of being slightly formed, then imprints finger electrode material layer.If constituting finger electrode The slurry of material layer is more sticky, then can carry out drying and processing to finger electrode material layer again after coining.For example, it dries The process temperatures of processing may be, for example, about 200 DEG C.
Then, step 250 can be carried out, to be sintered processing procedure to bus electrode material layer and finger electrode material layer, and Bus electrode 114 is respectively formed to pass through passivation layer 115 with finger electrode 116 and contact with emitter layer 113.Finger electrode 116 divides It does not connect with bus electrode 114, and is dispersed at the positive 112a of substrate 112 from the extension of bus electrode 114 respectively, and can will be electric It spreads and is handed to bus electrode 114.The roughened processing in the top surface of finger electrode material layer is simultaneously formed by finger-like electricity after sintering Pole 116 includes the coarse top surface 116t and two inclined side 116s to connect respectively with coarse top surface 116t.Coarse top surface 116t Include one or more strip structures 118.In the example of multiple strip structures 118, these strip structures 118 can be along finger-like electricity The width direction 116w of pole 116 is disposed proximate to, or is had spacing to each other rather than be disposed proximate to.For example, each strip Structure 118 includes at least one side 118s, and the tilt angle theta of side 118s can be about 20.9 degree to about 30 degree.Strip structure 118 side 118s can be plane, convex globoidal or cancave cambered surface.
The extending direction of strip structure 118 can be parallel or nearly parallel with the length direction 116L of finger electrode 116;Or Can not parallel finger electrode 116 length direction 116L;Or there are the extending direction parallel finger electrodes of the strip structure of part 116 length direction 116L, the extending direction of the strip structure of part do not have the length direction 116L of parallel finger electrodes 116.
In some embodiments, it can be processed by precision machinery, microscopic carvings are carved, are carried out in the way of laser carved or micro Process The roughening treatment of finger electrode 116.When being roughened, in bus electrode material layer and it can be referred to using these modes After shape electrode material layer completes sintering process, then sintered finger electrode material layer is roughened.In some examples In son, bus electrode material layer and finger electrode material layer are formed using plating mode.Then, it recycles and for example imprints mode Finger electrode material layer is roughened.
Then, step 260 is carried out, to form rear electrode 117 in substrate 112 using such as deposition or mode of printing At the 112b of the back side, and it is substantially completed the production of solar battery 110.
By above-mentioned embodiment it is found that an advantage of the invention is exactly the finger-like electricity because of solar battery of the invention Pole includes coarse top surface, and coarse top surface includes several strip structures.The strip structure of finger electrode can be by directive finger electrode Light be effectively totally reflected in solar battery, therefore in the reliability for taking into account solar cell module and processing procedure cost can be reduced In the case where, the absorptivity of solar battery is effectively promoted, and then the wattage output of solar cell module can be increased.
Although the present invention has been disclosed by way of example above, it is not intended to limit the present invention., any in this technical field Middle tool usually intellectual, without departing from the spirit and scope of the present invention, when can be used for a variety of modifications and variations, therefore this hair Bright protection scope is subject to the view scope of which is defined in the appended claims.

Claims (20)

1. a kind of solar battery, which is characterized in that the solar battery includes:
One substrate has a front and a back side;
One emitter layer is located at the front;
One passivation layer is configured on the emitter layer;
An at least bus electrode is configured at the front of the substrate;
Multiple finger electrodes, are configured at the front of the substrate and at least a bus electrode is connect with this respectively, wherein each The finger electrode includes a coarse top surface and two inclined sides, which connects with the coarse top surface respectively, should Coarse top surface include multiple strip structures, the multiple strip structure along the finger electrode at place a width direction interval Configuration, each strip structure extend along a length direction of the finger electrode at place;And
One rear electrode is configured at the back side of the substrate.
2. solar battery according to claim 1, which is characterized in that each strip structure is along the finger electrode The length direction extend in parallel or close to extending in parallel.
3. solar battery according to claim 2, which is characterized in that each strip structure extends to finger-like electricity Extremely at one end far from the bus electrode.
4. solar battery according to claim 2, which is characterized in that the multiple strip structure includes multiple first Shape structure and multiple second strip structures, the multiple first strip structure are parallel to approach with the multiple second strip structure The length direction interval of the finger electrode configures.
5. solar battery according to claim 1, which is characterized in that the bottom surface of each finger electrode is coarse with this General trapezoidal shape between top surface and two inclined side.
6. solar battery according to claim 1, which is characterized in that the multiple finger electrode is far from the bus electrode End connected by a connection electrode, in the connection electrode be configured with multiple elongate configurations outstanding, the multiple elongate configuration Interval configures and extends along a length direction of the connection electrode.
7. solar battery according to claim 1, which is characterized in that each strip structure includes at least side Face, and a tilt angle of at least one side is 20.9 degree to 30 degree.
8. solar battery according to claim 1, which is characterized in that each strip structure includes an at least arc Side.
9. a kind of solar cell module, which is characterized in that the solar cell module includes:
One upper plate;
One lower plate;
Just like the solar battery of any one of claim 1~8, it is set between the upper plate and the lower plate;
One first encapsulated layer is set between the upper plate and the solar battery, to combine the upper plate and the solar battery;And
One second encapsulated layer is set between the lower plate and the solar battery, to combine the lower plate and the solar battery.
10. a kind of manufacturing method of solar battery, which is characterized in that the manufacturing method of the solar battery includes:
A substrate is provided, wherein the substrate has a front and a back side;
An emitter layer is formed at the front;
A passivation layer is formed on the emitter layer;
An at least bus electrode is formed at the front of the substrate;
Forming multiple finger electrodes, at least a bus electrode is connect at the front of the substrate and respectively with this, wherein each institute Stating finger electrode includes a coarse top surface and two inclined sides, which connects with the coarse top surface respectively, this is thick Rough top surface includes multiple strip structures, and the multiple strip structure is matched along a width direction interval of the finger electrode at place It sets, each strip structure extends along a length direction of the finger electrode at place;And
A rear electrode is formed at the back side of the substrate.
11. the manufacturing method of solar battery according to claim 10, which is characterized in that form the multiple finger-like electricity Pole includes:
Multiple finger electrode material layers are formed at the front of the substrate;And
One roughening treatment is carried out to a top surface of each finger electrode material layer.
12. the manufacturing method of solar battery according to claim 11, which is characterized in that form the multiple finger-like electricity After pole is also contained in the roughening treatment, a drying and processing is carried out to the multiple finger electrode material layer.
13. the manufacturing method of solar battery according to claim 11, which is characterized in that form the multiple finger-like electricity Pole is also contained in form the multiple finger electrode material layer at the front of the substrate and carry out between the roughening treatment, One drying and processing is carried out to the multiple finger electrode material layer.
14. the manufacturing method of solar battery according to claim 10, which is characterized in that each strip structure edge The length direction of the finger electrode extend in parallel or close to extending in parallel.
15. the manufacturing method of solar battery according to claim 14, which is characterized in that each strip structure prolongs Reach the finger electrode far from one end of the bus electrode at.
16. the manufacturing method of solar battery according to claim 14, which is characterized in that the multiple strip structure packet Containing multiple first strip structures and multiple second strip structures, the multiple first strip structure and the multiple second strip knot Structure is configured with the length direction interval for approaching the parallel finger electrode.
17. the manufacturing method of solar battery according to claim 10, which is characterized in that each finger electrode General trapezoidal shape between bottom surface and the coarse top surface and two inclined side.
18. the manufacturing method of solar battery according to claim 10, which is characterized in that the multiple finger electrode is remote End from the bus electrode is connected by a connection electrode, and multiple elongate configurations outstanding are configured in the connection electrode, described Multiple elongate configuration intervals configure and extend along a length direction of the connection electrode.
19. the manufacturing method of solar battery according to claim 10, which is characterized in that each strip structure packet Containing at least one side, and a tilt angle of at least one side is 20.9 degree to 30 degree.
20. the manufacturing method of solar battery according to claim 10, which is characterized in that each strip structure packet Containing an at least arcuate flanks.
CN201711159534.9A 2017-09-28 2017-11-20 Solar battery and its manufacturing method and solar cell module Withdrawn CN109585579A (en)

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