CN109581572A - A kind of quantum dot polaroid - Google Patents

A kind of quantum dot polaroid Download PDF

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Publication number
CN109581572A
CN109581572A CN201811544611.7A CN201811544611A CN109581572A CN 109581572 A CN109581572 A CN 109581572A CN 201811544611 A CN201811544611 A CN 201811544611A CN 109581572 A CN109581572 A CN 109581572A
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CN
China
Prior art keywords
quantum dot
layer
polaroid
quantum
variety
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201811544611.7A
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Chinese (zh)
Inventor
周淼
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
TCL China Star Optoelectronics Technology Co Ltd
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Shenzhen China Star Optoelectronics Technology Co Ltd
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Publication date
Application filed by Shenzhen China Star Optoelectronics Technology Co Ltd filed Critical Shenzhen China Star Optoelectronics Technology Co Ltd
Priority to CN201811544611.7A priority Critical patent/CN109581572A/en
Priority to PCT/CN2019/081171 priority patent/WO2020124865A1/en
Publication of CN109581572A publication Critical patent/CN109581572A/en
Pending legal-status Critical Current

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Classifications

    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B5/00Optical elements other than lenses
    • G02B5/30Polarising elements
    • G02B5/3025Polarisers, i.e. arrangements capable of producing a definite output polarisation state from an unpolarised input state
    • G02B5/3033Polarisers, i.e. arrangements capable of producing a definite output polarisation state from an unpolarised input state in the form of a thin sheet or foil, e.g. Polaroid
    • G02B5/3041Polarisers, i.e. arrangements capable of producing a definite output polarisation state from an unpolarised input state in the form of a thin sheet or foil, e.g. Polaroid comprising multiple thin layers, e.g. multilayer stacks
    • G02B5/305Polarisers, i.e. arrangements capable of producing a definite output polarisation state from an unpolarised input state in the form of a thin sheet or foil, e.g. Polaroid comprising multiple thin layers, e.g. multilayer stacks including organic materials, e.g. polymeric layers
    • GPHYSICS
    • G02OPTICS
    • G02FOPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/13Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on liquid crystals, e.g. single liquid crystal display cells
    • G02F1/133Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
    • G02F1/1333Constructional arrangements; Manufacturing methods
    • G02F1/1335Structural association of cells with optical devices, e.g. polarisers or reflectors
    • G02F1/133528Polarisers

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  • Physics & Mathematics (AREA)
  • Nonlinear Science (AREA)
  • General Physics & Mathematics (AREA)
  • Optics & Photonics (AREA)
  • Mathematical Physics (AREA)
  • Chemical & Material Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Polarising Elements (AREA)
  • Liquid Crystal (AREA)

Abstract

A kind of quantum dot polaroid, including quantum dot layer and the polarizing layer being set on the quantum dot layer;Wherein, low-index layer is additionally provided between the quantum dot layer and the polarizing layer, the low-index layer includes glass substrate and the low refractive index material layer for being coated on the glass baseplate surface.The utility model has the advantages that quantum dot polaroid provided by the invention, low-index layer is set between quantum dot layer and polarizing layer, the translucidus of quantum dot polaroid is improved, the colour gamut of liquid crystal display is further improved, further improves the display effect of liquid crystal display.

Description

A kind of quantum dot polaroid
Technical field
The present invention relates to field of display technology more particularly to a kind of quantum dot polaroids.
Background technique
At present since high color purity, spectrum possessed by quanta point material (Quantum Dot, QD) itself are continuously adjustable etc. Excellent properties become 21 century the most outstanding luminescent material, can increase substantially existing LCD's in display colour gamut Color representation, therefore its display application is widely studied in recent years.Existing QD-OC (quantum dot liquid crystal display panel) has view Angle is very big, the higher advantage of colour gamut.However, quantum dot layer direct combination will cause liquid crystal display panel on polaroid surface The phenomenon that light efficiency is lower.Therefore, it is necessary to introduce low fold structure between quantum dot layer and polarizing layer to improve LCD display The whole light efficiency of plate.
In conclusion existing quantum dot polaroid will cause liquid crystal by quantum dot layer direct combination on polaroid surface The phenomenon that light efficiency of display panel is lower further affects the display effect of liquid crystal display panel.
Summary of the invention
The present invention provides a kind of quantum dot polaroid, is able to ascend the translucidus of quantum dot polaroid, existing to solve Quantum dot polaroid, by quantum dot layer direct combination on polaroid surface, will cause that the light efficiency of liquid crystal display panel is lower shows As the technical issues of further affecting liquid crystal display panel display effect.
To solve the above problems, technical solution provided by the invention is as follows:
The present invention provides a kind of quantum dot polaroid, including quantum dot layer and the polarisation being set on the quantum dot layer Layer;Wherein, low-index layer is additionally provided between the quantum dot layer and the polarizing layer, the low-index layer includes glass Glass substrate and the low refractive index material layer for being coated on the glass baseplate surface.
According to one preferred embodiment of the present invention, the low refractive index material layer is hot setting resin.
According to one preferred embodiment of the present invention, the quantum dot polaroid further includes inorganic encapsulated layer, the inorganic encapsulated Layer is deposited on the outside of the quantum dot layer.
According to one preferred embodiment of the present invention, the inside edge and institute that the inorganic encapsulated layer is contacted with the quantum dot layer The distance range at the length and width edge of glass substrate is stated between 0~60 micron.
According to one preferred embodiment of the present invention, the material of the inorganic encapsulated layer is silica.
According to one preferred embodiment of the present invention, the material of the polarizing layer is polyvinyl alcohol.
According to one preferred embodiment of the present invention, the material of the quantum dot layer includes polymer substrate and is scattered in polymer Quantum dot in matrix.
According to one preferred embodiment of the present invention, the polymer substrate is resin transparent material, the resin transparent material Including one of acrylic resin, epoxy resin, cyclic olefin polymer, organosilan resinoid and cellulose ester or more Kind.
According to one preferred embodiment of the present invention, the quantum dot include luminous nucleon be wrapped in it is inorganic outside the luminous nucleon Shell is protected, the red light material of the luminous nucleon includes CdSe, Cd2One of SeTe and InAs or a variety of;The luminous nucleon Green light material include ZnCdSe2, InP and Cd2One of SSe or a variety of;The inorganic protection shell include CdS, ZnSe, ZnCdS2, one of ZnS and ZnO or a variety of.
According to one preferred embodiment of the present invention, the quantum dot layer includes high stability composite quantum dot layer structure, described High stability composite quantum dot layer structure is mounted with hydrogel, MOFs or CdSe-SiO2;The quantum dot layer further includes having The II-VI of fluorescence polarization propertyA、III-VAQuantum dot nano stick, quantum dot nuclear shell structure nano rod, double transmittings, three transmitting quantum Point material and perovskite quanta point material.
The invention has the benefit that quantum dot polaroid provided by the invention, sets between quantum dot layer and polarizing layer Index layer is set low, the translucidus of quantum dot polaroid is improved, further improves the colour gamut of liquid crystal display, further Improve the display effect of liquid crystal display.
Detailed description of the invention
It, below will be to embodiment or the prior art in order to illustrate more clearly of embodiment or technical solution in the prior art Attached drawing needed in description is briefly described, it should be apparent that, the accompanying drawings in the following description is only some of invention Embodiment for those of ordinary skill in the art without creative efforts, can also be attached according to these Figure obtains other attached drawings.
Fig. 1 is quantum dot polaroid structure schematic diagram of the present invention.
Fig. 2 is another structural schematic diagram of quantum dot polaroid of the present invention.
Specific embodiment
The explanation of following embodiment is referred to the additional illustration, the particular implementation that can be used to implement to illustrate the present invention Example.The direction term that the present invention is previously mentioned, such as [on], [under], [preceding], [rear], [left side], [right side], [interior], [outer], [side] Deng being only the direction with reference to annexed drawings.Therefore, the direction term used be to illustrate and understand the present invention, rather than to The limitation present invention.The similar unit of structure is with being given the same reference numerals in the figure.
The present invention is directed to existing quantum dot polaroid, due to that on polaroid surface, can make quantum dot layer direct combination The phenomenon that being lower at the light efficiency of liquid crystal display panel, the technical issues of further affecting liquid crystal display panel display effect, this Embodiment is able to solve the defect.
As shown in Figure 1, being quantum dot polaroid structure schematic diagram of the present invention.Wherein, it is inclined to provide a kind of quantum dot by the present invention Mating plate, including quantum dot layer 10 and the polarizing layer 30 being set on the quantum dot layer 10;Wherein, in the quantum dot layer 10 Low-index layer 20 is additionally provided between the polarizing layer 30, the low-index layer 20 includes being coated on 21 table of glass substrate The low refractive index material layer 22 in face.
Specifically, the material of the polarizing layer 30 includes polyvinyl alcohol (Polyvinyl Alcohol, PVA).
Specifically, the material of the quantum dot layer 10 includes polymer substrate and the quantum that is scattered in polymer substrate Point.Wherein, the polymer substrate acts not only as the carrier of quantum dot, and protection can be packaged to quantum dot, Promote the service life of quantum dot.
Specifically, the polymer substrate be resin transparent material, the resin transparent material include acrylic resin, One of epoxy resin, cyclic olefin polymer, organosilan resinoid and cellulose ester are a variety of.Preferably, the polymerization Object matrix includes one of cyclic olefin polymer and organosilan resinoid or a variety of.Due to cyclic olefin polymer and organosilicon Alkanes resin has excellent barrier water oxygen characteristic, therefore is applied to preferably seal quantum dot in quantum dot layer 10 Dress protection.
Specifically, the quantum dot is oil-soluble quantum dot, the quantum dot includes red light quantum point and green light quantum point.
Specifically, the quantum dot includes luminous nucleon and the inorganic protection shell that is wrapped in outside the luminous nucleon, the hair The red light material of light core includes CdSe, Cd2One of SeTe and InAs or a variety of;The green light material of the luminous nucleon includes ZnCdSe2, InP and Cd2One of SSe or a variety of;The inorganic protection shell includes CdS, ZnSe, ZnCdS2, ZnS and ZnO One of or it is a variety of.
Specifically, the quantum dot layer 10 includes high stability composite quantum dot layer structure, the high stability compound quantity Son point layer structure is mounted with hydrogel, MOFs or CdSe-SiO2;The quantum dot layer 10 further includes with fluorescence polarization property II-VIA、III-VAQuantum dot nano stick, quantum dot nuclear shell structure nano rod, double transmittings, three emissive quantum dots materials and calcium Titanium ore quanta point material.
Specifically, the low refractive index material layer 22 is hot setting resin.
Specifically, quantum dot polaroid of the present invention the production method is as follows:
Firstly, providing a ultra thin glass substrates 21,21 high temperature resistant of glass substrate;It prepared by hot setting resin low Refractive index material 22 is coated on the surface of the glass substrate 21, forms low-index layer 20;Then by the low-refraction Material layer 22 is bonded with the lower surface of a polarizing layer 30, and the lower surface of the low-index layer 20 and a quantum dot layer 10 are pasted It closes, forms quantum dot polaroid of the present invention.
Specifically, the production method of the quantum dot layer 10 are as follows: in the lower surface of the glass substrate 21, coating is comprising poly- The mixture of polymer matrix, quantum dot and dispersion solvent removes the dispersion solvent in mixture and keeps the polymer substrate solid Quantum dot layer 10 is made after change.
Specifically, the dispersion solvent is nonpolar solvent.Preferably, the dispersion solvent include pentane, n-hexane, One or more of normal heptane, pentamethylene, hexamethylene, methylene chloride, chloroform, toluene and petroleum ether.It is furthermore preferred that institute Stating dispersion solvent includes one or more of n-hexane, hexamethylene and toluene.
Specifically, keeping the cured method heat cure of the polymer substrate, photocuring or melting hot extrusion cooling solid Change.
As shown in Fig. 2, being another structural schematic diagram of quantum dot polaroid of the present invention.Wherein, the present invention provides a kind of quantum Polaroid is selected, including quantum dot layer 10 and the polarizing layer 30 being set on the quantum dot layer 10;Wherein, in the quantum dot Low-index layer 20 is additionally provided between layer 10 and the polarizing layer 30, the low-index layer 20 includes being coated on glass substrate The low refractive index material layer 22 on 21 surfaces.
Specifically, the quantum dot polaroid further includes inorganic encapsulated layer 40, the inorganic encapsulated layer 40 is deposited on described 10 outside of quantum dot layer;The length of inside edge and liquid crystal display panel that the inorganic encapsulated layer 40 is contacted with the quantum dot layer The distance range of broad edge is between 0~60 micron;The material of the inorganic encapsulated layer 40 is silica.
Specifically, the material of the polarizing layer 30 includes polyvinyl alcohol (Polyvinyl Alcohol, PVA).
Specifically, the material of the quantum dot layer 10 includes polymer substrate and the quantum that is scattered in polymer substrate Point.Wherein, the polymer substrate acts not only as the carrier of quantum dot, and protection can be packaged to quantum dot, Promote the service life of quantum dot.
Specifically, the polymer substrate be resin transparent material, the resin transparent material include acrylic resin, One of epoxy resin, cyclic olefin polymer, organosilan resinoid and cellulose ester are a variety of.Preferably, the polymerization Object matrix includes one of cyclic olefin polymer and organosilan resinoid or a variety of.Due to cyclic olefin polymer and organosilicon Alkanes resin has excellent barrier water oxygen characteristic, therefore is applied to preferably seal quantum dot in quantum dot layer 10 Dress protection.
Specifically, the quantum dot is oil-soluble quantum dot, the quantum dot includes red light quantum point and green light quantum point.
Specifically, the quantum dot includes luminous nucleon and the inorganic protection shell that is wrapped in outside the luminous nucleon, the hair The red light material of light core includes CdSe, Cd2One of SeTe and InAs or a variety of;The green light material of the luminous nucleon includes ZnCdSe2, InP and Cd2One of SSe or a variety of;The inorganic protection shell includes CdS, ZnSe, ZnCdS2, ZnS and ZnO One of or it is a variety of.
Specifically, the quantum dot layer 10 includes high stability composite quantum dot layer structure, the high stability compound quantity Son point layer structure is mounted with hydrogel, MOFs or CdSe-SiO2;The quantum dot layer 10 further includes with fluorescence polarization property II-VIA、III-VAQuantum dot nano stick, quantum dot nuclear shell structure nano rod, double transmittings, three emissive quantum dots materials and calcium Titanium ore quanta point material.
Specifically, the low refractive index material layer 22 is hot setting resin.
Specifically, quantum dot polaroid of the present invention the production method is as follows:
Firstly, providing a ultra thin glass substrates 21,21 high temperature resistant of glass substrate;It prepared by hot setting resin low Refractive index material 22 is coated on the surface of the glass substrate 21, forms low-index layer 20;Then by the low-refraction Material layer 22 is bonded with the lower surface of a polarizing layer 30;It is coated with quantum dot layer 10 in the lower surface of the glass substrate 21, it is described The distance range at the length and width edge of quantum dot layer 10 and the glass substrate 21 is between 0~60 micron;Later, in the quantum Periphery one layer of inorganic encapsulated layer 40 of deposition of point layer 10, the material of the inorganic encapsulated layer 40 is silica;Ultimately form this Invention quantum dot polaroid.
Specifically, the production method of the quantum dot layer 10 are as follows: in the lower surface of the glass substrate 21, coating is comprising poly- The mixture of polymer matrix, quantum dot and dispersion solvent removes the dispersion solvent in mixture and keeps the polymer substrate solid Quantum dot layer 10 is made after change.The dispersion solvent is nonpolar solvent.Preferably, the dispersion solvent includes pentane, just One or more of hexane, normal heptane, pentamethylene, hexamethylene, methylene chloride, chloroform, toluene and petroleum ether.More preferably , the dispersion solvent includes one or more of n-hexane, hexamethylene and toluene.Keep the polymer substrate cured Method is heat cure, photocuring or melting hot extrusion cooling and solidifying.
Red illuminating material and green luminescent material is arranged in quantum dot polaroid of the invention in the quantum dot layer 10, Red illuminating material when so that quantum dot polaroid of the invention and Blue backlight being used cooperatively, in the quantum dot polaroid Feux rouges and green light are issued under the excitation of Blue backlight with green luminescent material, the feux rouges and green light and unabsorbed blue are carried on the back The white light that high color purity is formed after light mixing projects.
Since quantum dot itself has light transfer capability, in the case where being excited by blue light, electron transition occurs, then The compound of electron hole is completed in the form of fluorescent radiation;As typical zero dimensional nanometer materials, quantum dot is equal in all directions With the size within the scope of quantum confinement, therefore direction selection is not present in its fluorescent radiation, can be with 360 ° of indifferences after being stimulated Other eradiation fluorescence, so as to each visual angle brightness of active balance liquid crystal display.
The invention has the benefit that quantum dot polaroid provided by the invention, sets between quantum dot layer and polarizing layer Index layer is set low, the translucidus of quantum dot polaroid is improved, further improves the colour gamut of liquid crystal display, further Improve the display effect of liquid crystal display.
In conclusion although the present invention has been disclosed above in the preferred embodiment, but above preferred embodiment is not to limit The system present invention, those skilled in the art can make various changes and profit without departing from the spirit and scope of the present invention Decorations, therefore protection scope of the present invention subjects to the scope of the claims.

Claims (10)

1. a kind of quantum dot polaroid, which is characterized in that including quantum dot layer and the polarisation being set on the quantum dot layer Layer;Wherein, low-index layer is additionally provided between the quantum dot layer and the polarizing layer, the low-index layer includes glass Glass substrate and the low refractive index material layer for being coated on the glass baseplate surface.
2. quantum dot polaroid according to claim 1, which is characterized in that the low refractive index material layer is hot setting Resin.
3. quantum dot polaroid according to claim 1, which is characterized in that the quantum dot polaroid further includes inorganic envelope Layer is filled, the inorganic encapsulated layer is deposited on the outside of the quantum dot layer.
4. quantum dot polaroid according to claim 3, which is characterized in that the inorganic encapsulated layer and the quantum dot layer The distance range at the inside edge of contact and the length and width edge of the glass substrate is between 0~60 micron.
5. quantum dot polaroid according to claim 3, which is characterized in that the material of the inorganic encapsulated layer is titanium dioxide Silicon.
6. quantum dot polaroid according to claim 1, which is characterized in that the material of the polarizing layer is polyvinyl alcohol.
7. quantum dot polaroid as described in claim 1, which is characterized in that the material of the quantum dot layer includes polymer matrix Matter and the quantum dot being scattered in polymer substrate.
8. quantum dot polaroid as claimed in claim 7, which is characterized in that the polymer substrate is resin transparent material, The resin transparent material includes acrylic resin, epoxy resin, cyclic olefin polymer, organosilan resinoid and fiber One of ester is a variety of.
9. quantum dot polaroid as claimed in claim 7, which is characterized in that the quantum dot includes luminous nucleon and is wrapped in institute The inorganic protection shell outside luminous nucleon is stated, the red light material of the luminous nucleon includes CdSe, Cd2One of SeTe and InAs or It is a variety of;The green light material of the luminous nucleon includes ZnCdSe2, InP and Cd2One of SSe or a variety of;The inorganic protective shell Layer includes CdS, ZnSe, ZnCdS2, one of ZnS and ZnO or a variety of.
10. quantum dot polaroid as claimed in claim 7, which is characterized in that the quantum dot layer includes that high stability is compound Quantum dot layer structure, the high stability composite quantum dot layer structure are mounted with hydrogel, MOFs or CdSe-SiO2;It is described Quantum dot layer further includes the II-VI with fluorescence polarization propertyA、III-VAQuantum dot nano stick, quantum dot nuclear shell structure nano Stick, double transmittings, three emissive quantum dots materials and perovskite quanta point material.
CN201811544611.7A 2018-12-17 2018-12-17 A kind of quantum dot polaroid Pending CN109581572A (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
CN201811544611.7A CN109581572A (en) 2018-12-17 2018-12-17 A kind of quantum dot polaroid
PCT/CN2019/081171 WO2020124865A1 (en) 2018-12-17 2019-04-03 Quantum dot polarizer

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201811544611.7A CN109581572A (en) 2018-12-17 2018-12-17 A kind of quantum dot polaroid

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WO (1) WO2020124865A1 (en)

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CN110471207A (en) * 2019-07-19 2019-11-19 苏州星烁纳米科技有限公司 Quantum dot polaroid and backlight module
CN110794503A (en) * 2019-11-25 2020-02-14 Tcl华星光电技术有限公司 Quantum dot polaroid, manufacturing method thereof and display device
CN110888254A (en) * 2019-11-15 2020-03-17 Tcl华星光电技术有限公司 Quantum dot substrate, liquid crystal display panel and double-sided liquid crystal display panel

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CN107807471A (en) * 2017-11-13 2018-03-16 深圳市华星光电技术有限公司 Quantum dot polaroid and liquid crystal display
CN108459435A (en) * 2018-01-19 2018-08-28 精电(河源)显示技术有限公司 A kind of liquid crystal display using quantum dot light emitting
CN108780167A (en) * 2016-03-18 2018-11-09 日东电工株式会社 Optical component and the back light unit and liquid crystal display device for using the optical component

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CN108780167A (en) * 2016-03-18 2018-11-09 日东电工株式会社 Optical component and the back light unit and liquid crystal display device for using the optical component
CN107315219A (en) * 2017-08-31 2017-11-03 深圳市华星光电技术有限公司 Quantum dot polaroid
CN107807471A (en) * 2017-11-13 2018-03-16 深圳市华星光电技术有限公司 Quantum dot polaroid and liquid crystal display
CN108459435A (en) * 2018-01-19 2018-08-28 精电(河源)显示技术有限公司 A kind of liquid crystal display using quantum dot light emitting

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110471207A (en) * 2019-07-19 2019-11-19 苏州星烁纳米科技有限公司 Quantum dot polaroid and backlight module
CN110471207B (en) * 2019-07-19 2023-02-28 苏州星烁纳米科技有限公司 Quantum dot polaroid and backlight module
CN110888254A (en) * 2019-11-15 2020-03-17 Tcl华星光电技术有限公司 Quantum dot substrate, liquid crystal display panel and double-sided liquid crystal display panel
CN110794503A (en) * 2019-11-25 2020-02-14 Tcl华星光电技术有限公司 Quantum dot polaroid, manufacturing method thereof and display device

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