CN109574326A - A kind of wind light mutual complementing formula electrodialytic desalination device - Google Patents

A kind of wind light mutual complementing formula electrodialytic desalination device Download PDF

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Publication number
CN109574326A
CN109574326A CN201811608173.6A CN201811608173A CN109574326A CN 109574326 A CN109574326 A CN 109574326A CN 201811608173 A CN201811608173 A CN 201811608173A CN 109574326 A CN109574326 A CN 109574326A
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China
Prior art keywords
water
wind
power supply
treatment facilities
electrodialysis plant
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Pending
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CN201811608173.6A
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Chinese (zh)
Inventor
程桂石
赵莹
张基龙
刘阳祥
赵嘉琪
董长青
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North China Electric Power University
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North China Electric Power University
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Priority to CN201811608173.6A priority Critical patent/CN109574326A/en
Publication of CN109574326A publication Critical patent/CN109574326A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/46Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/469Treatment of water, waste water, or sewage by electrochemical methods by electrochemical separation, e.g. by electro-osmosis, electrodialysis, electrophoresis
    • C02F1/4693Treatment of water, waste water, or sewage by electrochemical methods by electrochemical separation, e.g. by electro-osmosis, electrodialysis, electrophoresis electrodialysis
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/001Processes for the treatment of water whereby the filtration technique is of importance
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/08Seawater, e.g. for desalination

Abstract

The embodiment of the invention discloses a kind of wind light mutual complementing formula electrodialytic desalination devices, it mainly includes the power supply unit being made of Wind turbines, solar panel, voltage-stablizer and electricity accumulating unit, with the water treatment facilities of raw water pump, electrodialysis plant, more medium filter, accurate filter and water tank composition, wherein, power supply unit provides stable DC, the electric energy that Storage Unit storage, allotment Wind turbines and solar panels generate to electrodialysis plant;Seawater desalination is responsible for by electrodialysis plant, acid-base solution resource can also be made simultaneously using three compartment bipolar membrane electrodialysis technologies, by the large particulate matter in more medium filter filtering sea, accurate filter removes 1 degree of turbidity or more in water removal of fine particles.Apparatus of the present invention combine wind energy, solar energy with electrodialytic desalination technology, and natural energy resources are efficiently utilized, promote the comprehensive utilization ratio of water, can stablize and low cost fresh water is made in seawater, be easy to promote on a large scale.

Description

A kind of wind light mutual complementing formula electrodialytic desalination device
Technical field
The invention belongs to field of sea water desalting technology, in particular to a kind of wind light mutual complementing formula electrodialytic desalination device, Using wind energy and solar energy as the energy by seawater it is stable fresh water is made.
Background technique
Coastal area of china area and Island scarcity of fresh water resources generate fresh water using seawater, can effectively solve water money Source anxiety problem provides clean energy resource to the island far from continent.
Reverse osmosis technology is a kind of currently used desalination technology.The technology is penetrated using only permission solvent, is not permitted Perhaps the semi-permeable membrane that solute penetrates, by two kinds of different water of salt concentration, such as seawater and freshwater separates, adds outside high salt concentration side Pressure is allowed to the osmotic pressure difference greater than semi-permeable membrane two sides, and water is forced to be precipitated from highly concentrated solution and enter through semi-permeable membrane Low salt concn solution, and salt ion envelope stops and generates fresh water.Although Reverse-osmosis Seawater Desalination Technology is led in current sea water desalination Domain is quickly grown, but requirement of the technology to the energy is relatively high, and load is larger, far from continent island, not only fresh water be Valuable, electric energy is also valuable resource, while the comprehensive utilization ratio of water is relatively low, can only generally accomplish 65% or so, in addition, Existing Reverse-osmosis Seawater Desalination Technology still has project cost and the higher problem of operating cost, therefore reverse osmosis process is light Change seawater to be still difficult to obtain extensive popularize in the area such as remote island.
Summary of the invention
For using reverse osmosis technology to desalinize seawater in the prior art, existing energy consumption is high, water use efficiency is low, at high cost Problem provides a kind of wind light mutual complementing formula electrodialytic desalination device, can stablize and low cost seawater is made to fresh water, water Comprehensive utilization ratio it is high, moreover it is possible to desalinizing seawater while preparing acid-base solution, be greatly improved the level of resources utilization, be easy to big model Enclose popularization.
The embodiment provides a kind of wind light mutual complementing formula electrodialytic desalination device, including water treatment facilities and Power supply unit, water treatment facilities are desalinized seawater in a manner of electrodialysis, and power supply unit connection water treatment facilities are powered for it, and power supply is set Standby includes Wind turbines, solar panel and wind/light complementation controller, in which: Wind turbines and solar panel connect simultaneously Wind/light complementation controller inputing power is connect, water treatment facilities are connected to it for direct current by wind/light complementation controller.Due to sea Island wind resource is abundant, solar energy resources also very sufficiently, directly using Wind turbines, solar panel to water treatment facilities Direct current supply reduces the loss that previous alternating current is converted into direct current, substantially increases power consumption efficiency.
Preferably, water treatment facilities include raw water pump, electrodialysis plant and water tank, in which: raw water pump connects electrodialysis The seawater inlet of device, seawater are pumped into electrodialysis plant by raw water pump;Power supply unit connects electrodialysis plant as the confession of its electrode Electricity;In the electrodialysis plant anion enriched chamber is separated out by anion-exchange membrane and cation-exchange membrane respectively and cation is dense Contracting room is diluting compartment between the anion-exchange membrane and the cation-exchange membrane, and the outlet of diluting compartment connects water tank, will Fresh water after desalination is conveyed into water tank.
Preferably, the electrodialysis plant is the bipolar membranous type of three compartments, further includes two Bipolar Membranes, the Bipolar Membrane is used for Electrolysis water a, wherein Bipolar Membrane is set in anion enriched chamber, is separated out acid compartment, the acid compartment with the anion-exchange membrane It is provided with acid solution outlet;Another Bipolar Membrane is set in cationic enriched chamber, is separated out alkaline chamber with the cation-exchange membrane, institute It states alkaline chamber and is provided with aqueous slkali outlet.Under DC electric field effect, Bipolar Membrane electrolysis water generates hydrogen ion and hydroxide ion, point Acid-base solution can not be prepared in acid compartment and alkaline chamber.
Preferably, the electrode of electrodialysis plant is graphite electrode.
Preferably, water treatment facilities further include more medium filter, and more medium filter is set to the sea of electrodialysis plant Water inlet front end, for the particulate matter in filtering sea.The more medium filter is mainly used for the large particle in filtering sea Matter.
Preferably, water treatment facilities further include accurate filter, and the seawater that accurate filter is set to electrodialysis plant enters Mouthful front end or water outlet rear end are filled with anthracite and quartz sand in accurate filter, for going in water removal 1 degree of turbidity or more Particle.The accurate filter main filtration insolubility particulate matter, the quartz sand particle size of filling can be controlled in 10~20mm In range.
It further include electricity accumulating unit as the preferred of power supply unit, electricity accumulating unit is connected to wind/light complementation controller and water Power supply bypass is formed between processing equipment, wind/light complementation controller is stored in electricity accumulating unit to the remaining electric energy of water treatment facilities power supply In.Electric energy is matched come the up-regulation from the time using the electricity accumulating unit, the electric energy of fine day surplus can be stored, in night or cloudy day release It is used.
Preferably, electricity accumulating unit includes electrochemistry liquid phase energy storage battery.Using liquid phase energy storage battery, whole process is not Be related to solid phase reaction, reactants and products be it is soluble, electrode can bear bigger multiplying power quick charge electric discharge, have more preferable Cycle life, and it is safer.
Preferably, power supply unit further includes voltage-stablizer, and wind/light complementation controller passes through voltage-stablizer with electricity accumulating unit and connects Water treatment facilities are powered to it.
Wind light mutual complementing formula electrodialyzed drinking water processing unit described in above-mentioned technical proposal of the embodiment of the present invention, using wind energy Direct current is provided with solar energy, and electricity accumulating unit storage can be used as power supply bypass, realizes electric energy allotment;Water treatment portion is adopted Desalination is carried out to seawater with electrodialysis mode, in addition can obtain Seawater Treatment directly to drink fresh water after filter device;Using three compartments Water electrolysis can be generated hydrogen ion and hydroxide ion under electric field action by bipolar membrane electrodialysis technology, can also be respectively in acid compartment Acid-base solution is prepared into alkaline chamber.The technical solution has the beneficial effect that:
1. powering using wind energy and solar energy complementation, suitable for using on the island far from continent, natural energy can be made full use of Source, using energy source clean and effective;
2. wind light mutual complementing direct current supply can directly meet electrodialytic power reguirements, no longer need to convert alternating current to direct current Electricity avoids energy loss caused by previous alterating and direct current conversion, substantially increases power consumption efficiency;
3. acid-base solution resource can be made while seawater desalination using three compartment bipolar membrane electrodialysis technologies, effectively increase Add output, substantially increases efficiency of energy utilization;
4. electric energy is matched in up-regulation from the time using electricity accumulating unit, the electric energy of fine day surplus is stored, is released at night or cloudy day It puts and is used, further improve efficiency of energy utilization;
5. carrying out seawater desalination using electrodialysis mode, cost is relatively low, and the electric energy consumption of demand is smaller, the comprehensive utilization of water Rate can reach 95% or so, be easy to promote on a large scale, power in conjunction with wind energy and solar energy complementation, be particularly well suited for being used in far from continent Island carry out sea water desalination, the effective shortage of fresh water problem for alleviating island.
Detailed description of the invention
Fig. 1 is wind light mutual complementing formula electrodialytic desalination apparatus structure schematic diagram provided in an embodiment of the present invention;
Fig. 2 is the structural schematic diagram of electrodialysis plant in wind light mutual complementing formula electrodialytic desalination device shown in Fig. 1.
[main element symbol description]
1- water treatment facilities;11- raw water pump;12- electrodialysis plant;121- diluting compartment;122- acid compartment;123- alkaline chamber; 124- anion-exchange membrane;125- cation-exchange membrane;126- Bipolar Membrane;13- more medium filter;14- accurate filter; 15- water tank;2- power supply unit;21- Wind turbines;22- solar panel;23- wind/light complementation controller;24- electric power storage list Member;25- voltage-stablizer.
Specific embodiment
To keep the technical problem to be solved in the present invention, technical solution and advantage clearer, below in conjunction with attached drawing and tool Body embodiment is described in detail.
For problem of the prior art, a kind of wind light mutual complementing formula electrodialysis as depicted in figs. 1 and 2 is present embodiments provided Desalination plant, including water treatment facilities 1 and power supply unit 2, water treatment facilities 1 are desalinized seawater in a manner of electrodialysis, power supply Equipment 2 connects water treatment facilities 1 and powers for it, in which:
As shown in Figure 1, power supply unit 2 includes Wind turbines 21, solar panel 22 and wind/light complementation controller 23, wind Motor group 21 and solar panel 22 connect 23 inputing power of wind/light complementation controller simultaneously, pass through wind/light complementation controller 23 Water treatment facilities 1 are connected to it for direct current.
Wind energy and solar energy is utilized for more efficient allotment, power supply unit 2 further includes electricity accumulating unit 24, electricity accumulating unit 24 It is connected between wind/light complementation controller 23 and water treatment facilities 1 and forms power supply bypass, wind/light complementation controller 23 is set to water process The remaining electric energy of standby 1 power supply is stored in electricity accumulating unit 24, and electricity accumulating unit 24 is used to deploy electric energy, such as can be by mistake in fine day Surplus electric energy storage, is used at night or cloudy day release, guarantees that power supply is sufficient.As a kind of more preferably embodiment, Electrochemistry liquid phase energy storage battery can be selected in electricity accumulating unit 24, and liquid phase battery can bear bigger multiplying power quick charge electric discharge, There is better cycle life, and safer.
It further include voltage-stablizer 25, wind/light complementation controller 23 in the present embodiment power supply unit 2 to ensure that supply voltage is stablized Water treatment facilities 1 are connected by voltage-stablizer 25 with electricity accumulating unit 24.
As shown in Figure 1, water treatment facilities 1 include raw water pump 11, electrodialysis plant 12 and water tank 15, specifically, raw water The seawater inlet of 11 connection electrodialysis plant 12 of pump, seawater are pumped into electrodialysis plant 12 by raw water pump 11;Power supply unit 2 connects Electrodialysis plant 12 is the power supply of its electrode;It is separated out in electrodialysis plant 12 by anion-exchange membrane 124 and cation-exchange membrane 125 The outlet of intermediate diluting compartment 121, diluting compartment 121 connects water tank 15, and the fresh water after desalination is conveyed into water tank 15.Make Electrode for more preferably embodiment, electrodialysis plant 12 selects graphite electrode.Apparatus of the present invention are removed using electrodialytic technique Salinity in seawater.It is provided with anions and canons exchange membrane each one in chamber in electrodialysis plant 12, chamber is divided into three Part, wherein the compartment of two sides is respectively anions and canons enriched chamber, and intermediate compartment is diluting compartment 121;Cationic enriched chamber side Cathode is set, and anode is arranged in anion enriched chamber side, and the two poles of the earth form applying direct current electric field by direct current supply in the chamber;Composition The electrode movement that the anions and canons of salt can respectively round about under the action of DC electric field in seawater, due to ion exchange Film has selective penetrated property, i.e. cation-exchange membrane only allows cation to pass freely through, and anion-exchange membrane only allows anion To pass through, in this way in diluting compartment 121, the concentration of salt will because of ion directional migration and reduce, finally intermediate light Change in room 121 and achievees the purpose that desalination.
As a kind of preferable embodiment of electrodialysis plant 12, as shown in Fig. 2, electrodialysis plant 12 is that three compartments are double Pole membranous type, it is interior that anion enriched chamber and cation concentration are separated out by anion-exchange membrane 124 and cation-exchange membrane 125 respectively Room is diluting compartment 121 between anion-exchange membrane 124 and cation-exchange membrane 125;Two Bipolar Membrane 126 1 are set to yin In ion concentration room, it is separated out acid compartment 122 with anion-exchange membrane 124, another Bipolar Membrane 126 is set in cationic enriched chamber, It is separated out alkaline chamber 123 with cation-exchange membrane 125, under DC electric field effect, Bipolar Membrane 126 can electrolysis water generation hydrogen ion and hydrogen Oxygen radical ion.Chloride ion in seawater raw water enters acid compartment 122 through anion-exchange membrane 124, what 126 electrolysis water of Bipolar Membrane generated Hydrogen ion is mobile toward acid compartment 122, so that hydrogen ion and chloride binding generate hydrogen chloride, acid solution is made;Similarly in raw water Sodium ion enters alkaline chamber 123 through cation-exchange membrane 125, and the hydroxide ion that 126 electrolysis water of Bipolar Membrane generates is moved toward alkaline chamber 123 It is dynamic, so that hydroxide ion generates sodium hydroxide in conjunction with sodium ion, aqueous slkali is made.Acid compartment 122 is provided with acid solution outlet, Alkaline chamber 123 is provided with aqueous slkali outlet, and acid, aqueous slkali outlet are separately connected storage tank, acid, aqueous slkali are conveyed into storage tank respectively In, acid-base solution resource can be made while seawater desalination in this way, effectively increase output, substantially increase using energy source effect Rate.
It is the particulate matter before electrodialysis in preparatory filtering sea as preferable embodiment, it can in water treatment facilities 1 Including more medium filter 13, more medium filter 13 is set to the seawater inlet front end of electrodialysis plant 12.
It may also include accurate filter 14 in water treatment facilities 1, be filled with anthracite and quartz sand in accurate filter 14, For removing 1 degree of turbidity or more in water removal of particle.Accurate filter 14 may be disposed at the seawater inlet front end of electrodialysis plant 12, Refined filtration is first carried out before desalination, may also set up in the water outlet rear end of electrodialysis plant 12, and the purpose of refined filtration can be achieved, To obtain the fresh water for meeting straight drink standard;As more preferably embodiment, quartz sand particle size is controlled in 10~20mm.
Wind light mutual complementing formula electrodialytic desalination device provided by the above embodiment has using energy source efficient, the synthesis of water The high feature of utilization rate is suitably employed in the island far from continent and carries out sea water desalination, can effectively alleviate the freshwater resources on island Shortage problem.
In the description of the present invention, it is to be understood that, the positional relationship in term is merely for convenience of the description present invention It is described with simplifying, rather than the component or element of indication or suggestion meaning must have a particular orientation, with specific orientation structure It makes and operates, should not be construed as limiting the invention.Unless otherwise clearly defined and limited, term " installation ", " connected ", " connection " shall be understood in a broad sense, for example, it may be being fixedly connected, may be a detachable connection, or be integrally connected;It can be It is connected directly, the connection inside two elements can also be can be indirectly connected through an intermediary.For the common of this field For technical staff, the concrete meaning of above-mentioned term in the present invention can be understood with concrete condition.
For above-mentioned the embodiment of the present invention, the common sense such as well known specific structure and characteristic are not retouched excessively in scheme It states;Each embodiment is described in a progressive manner, and involved technical characteristic does not constitute punching between each other in each embodiment It can be combined with each other under the premise of prominent, same and similar part may refer to each other between each embodiment.
Present invention disclosed above preferred embodiment is only intended to help to illustrate the present invention, chooses and specifically describes these realities Example is applied, is principle and practical application in order to better explain the present invention, to keep skilled artisan fine Ground understands and utilizes the present invention.Obviously, the preferred embodiment above details all there is no detailed descriptionthe, does not limit the invention yet Only the specific embodiment is not departing from original of the present invention for those skilled in the art Under the premise of reason, it can also make several improvements and retouch, these improvements and modifications also should be regarded as falling into protection model of the invention It encloses.

Claims (9)

1. a kind of wind light mutual complementing formula electrodialytic desalination device, including water treatment facilities (1) and power supply unit (2), the water Processing equipment (1) is desalinized seawater in a manner of electrodialysis, and the power supply unit (2) connects the water treatment facilities (1) and powers for it, It is characterized in that, the power supply unit (2) includes Wind turbines (21), solar panel (22) and wind/light complementation controller (23), in which: it is defeated that the Wind turbines (21) and solar panel (22) connect the wind/light complementation controller (23) simultaneously Enter electric energy, connects the water treatment facilities (1) to it for direct current by the wind/light complementation controller (23).
2. the apparatus according to claim 1, which is characterized in that the water treatment facilities (1) include raw water pump (11), electric osmose Analysis apparatus (12) and water tank (15), in which: the raw water pump (11) connects the seawater inlet of the electrodialysis plant (12), sea Water is pumped into the electrodialysis plant (12) by the raw water pump (11);The power supply unit (2) connects the electrodialysis plant (12) it powers for its electrode;By anion-exchange membrane (124) and cation-exchange membrane (125) point in the electrodialysis plant (12) It is not separated out anion enriched chamber and cationic enriched chamber, the anion-exchange membrane (124) and the cation-exchange membrane (125) Between be diluting compartment (121), the outlet of the diluting compartment (121) connects the water tank (15), and the fresh water after desalination is conveyed Enter in the water tank (15).
3. the apparatus of claim 2, which is characterized in that the electrodialysis plant (12) further includes two Bipolar Membranes (126), in which:
One Bipolar Membrane (126) is set in anion enriched chamber, is separated out acid compartment (122), institute with the anion-exchange membrane (124) It states acid compartment (122) and is provided with acid solution outlet;Another Bipolar Membrane (126) is set in cationic enriched chamber, with the cation Exchange membrane (125) is separated out alkaline chamber (123), and the alkaline chamber (123) is provided with aqueous slkali outlet.
4. the apparatus of claim 2, which is characterized in that the electrode of the electrodialysis plant (12) is graphite electricity Pole.
5. the apparatus of claim 2, which is characterized in that the water treatment facilities (1) further include more medium filter (13), the more medium filter (13) is set to the seawater inlet front end of the electrodialysis plant (12), is used for filtering sea In particulate matter.
6. the apparatus of claim 2, which is characterized in that the water treatment facilities (1) further include accurate filter (14), the accurate filter (14) is set to the seawater inlet front end or water outlet rear end of the electrodialysis plant (12), Anthracite and quartz sand are filled in the accurate filter (14).
7. device according to any one of claims 1 to 6, which is characterized in that the power supply unit (2) further includes electric power storage list First (24), the electricity accumulating unit (24) are connected between the wind/light complementation controller (23) and the water treatment facilities (1) and are formed Power supply bypass, the remaining electric energy of wind/light complementation controller (23) Xiang Suoshu water treatment facilities (1) power supply are stored in the storage In electric unit (24).
8. device according to claim 7, which is characterized in that the electricity accumulating unit (24) includes that electrochemistry liquid phase energy storage stores Battery.
9. device according to claim 7, which is characterized in that the power supply unit (2) further includes voltage-stablizer (25), described Wind/light complementation controller (23) and the electricity accumulating unit (24) connect the water treatment facilities (1) by the voltage-stablizer (25) It powers to it.
CN201811608173.6A 2018-12-27 2018-12-27 A kind of wind light mutual complementing formula electrodialytic desalination device Pending CN109574326A (en)

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CN110668618A (en) * 2019-10-24 2020-01-10 山西云海川环保科技有限公司 System and method for extracting pure water and concentrating and desalting seawater
CN113003801A (en) * 2021-03-03 2021-06-22 浙江大学 Electrochemical treatment device and method for refractory organic wastewater powered by wind energy
GB2606488A (en) * 2021-05-06 2022-11-09 Achelous Energy Ltd Systems and devices for a floating renewable power station

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GB2606488A (en) * 2021-05-06 2022-11-09 Achelous Energy Ltd Systems and devices for a floating renewable power station
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Application publication date: 20190405