CN109569466A - A kind of temperature control system for automatic chemistry synthesis system - Google Patents
A kind of temperature control system for automatic chemistry synthesis system Download PDFInfo
- Publication number
- CN109569466A CN109569466A CN201910065855.5A CN201910065855A CN109569466A CN 109569466 A CN109569466 A CN 109569466A CN 201910065855 A CN201910065855 A CN 201910065855A CN 109569466 A CN109569466 A CN 109569466A
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- China
- Prior art keywords
- temperature control
- solenoid valve
- temperature
- upside
- control system
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Links
- 230000015572 biosynthetic process Effects 0.000 title claims abstract description 16
- 238000003786 synthesis reaction Methods 0.000 title claims abstract description 16
- 238000001816 cooling Methods 0.000 claims abstract description 32
- 238000010438 heat treatment Methods 0.000 claims abstract description 13
- 229910052710 silicon Inorganic materials 0.000 claims abstract description 6
- 239000010703 silicon Substances 0.000 claims abstract description 6
- NJPPVKZQTLUDBO-UHFFFAOYSA-N novaluron Chemical compound C1=C(Cl)C(OC(F)(F)C(OC(F)(F)F)F)=CC=C1NC(=O)NC(=O)C1=C(F)C=CC=C1F NJPPVKZQTLUDBO-UHFFFAOYSA-N 0.000 claims abstract description 3
- 238000009434 installation Methods 0.000 claims description 13
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 5
- 239000007788 liquid Substances 0.000 description 14
- 238000007710 freezing Methods 0.000 description 9
- 230000008014 freezing Effects 0.000 description 9
- 230000006870 function Effects 0.000 description 5
- 238000006243 chemical reaction Methods 0.000 description 4
- 239000002826 coolant Substances 0.000 description 4
- 239000000498 cooling water Substances 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 239000003507 refrigerant Substances 0.000 description 3
- 238000002791 soaking Methods 0.000 description 3
- 230000008859 change Effects 0.000 description 2
- 238000001514 detection method Methods 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000004973 liquid crystal related substance Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 208000027418 Wounds and injury Diseases 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 238000004891 communication Methods 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 238000005485 electric heating Methods 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 208000014674 injury Diseases 0.000 description 1
- 230000006855 networking Effects 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/0006—Controlling or regulating processes
- B01J19/0013—Controlling the temperature of the process
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00051—Controlling the temperature
- B01J2219/00074—Controlling the temperature by indirect heating or cooling employing heat exchange fluids
- B01J2219/00087—Controlling the temperature by indirect heating or cooling employing heat exchange fluids with heat exchange elements outside the reactor
- B01J2219/00092—Tubes
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Physical Or Chemical Processes And Apparatus (AREA)
Abstract
The present invention relates to a kind of automatic chemistry fields, specifically a kind of temperature control system for automatic chemistry synthesis system, including bottom plate, mounting base is provided on the upside of the bottom plate, Stm32 processor is provided on front side of the mounting base, silicon can be melted by being provided on the left of the Stm32 processor, cooling line is provided on the upside of the mounting base, connecting tube is provided on the left of the cooling line, the connecting tube left base, temperature control pot is installed on the upside of the pedestal, the temperature control pot inside lower end is provided with heating coil, cooling coil is provided on the upside of the heating coil, low-temperature solenoid valve with three solenoid valves and right side of left end respectively on rear side of the cooling line, gas solenoid valve is attached, the present invention can have effectively achieved the accurately heating and cooling of equipment, it can be convenient the temperature of control equipment in this way, side People use.
Description
Technical field
The present invention relates to a kind of automatic chemistry field, specifically a kind of temperature control system for automatic chemistry synthesis system
System.
Background technique
Chemistry is one kind of natural science, and composition, property, structure and the variation of substance are studied on molecule, atom level
Rule；Create the science of novel substance.The world is chemical then be the mankind to recognize and be transformed the main of the material world by material composition
One of ways and means.It is a subject with a long history and dynamic, its achievement is the important mark of social civilization
Will, chemistry in there is two kinds of versions of chemical change and physical change.
Chemical reaction temperature control pot on the market at present is divided into heated type and high/low temperature control formula.Heated type is to use electric heating
Silk heats conduction oil；High/low temperature formula is both existing heating wire and refrigerant condenser and cooling coil, both to conduction oil
Can heat can drop again.But the accurate heating of condition trigger pulse formula heating that heated type is silicon-controlled using tradition, there are also a kojis
Wire type adjustment voltage system changes solution thermal power accurately to be heated up；Although high/low temperature formula, which can heat, to cool down, in height
Cool down again under warm mode, greatly injury can be generated to compressor with the cooling of compressor refrigerant, or even compressor can be damaged, in addition
High temperature is undesirable with refrigerant cooling effect, and energy consumption is high.Therefore, those skilled in the art provide a kind of for automatic chemistry conjunction
At the temperature control system of system, to solve the problems mentioned in the above background technology.
Summary of the invention
The purpose of the present invention is to provide a kind of temperature control systems for automatic chemistry synthesis system, to solve above-mentioned back
The problem of being proposed in scape technology.
To achieve the above object, the invention provides the following technical scheme:
A kind of temperature control system for automatic chemistry synthesis system, including bottom plate, bottom plate upside left end are provided with
Installation part, the bottom plate upside are provided with mounting base, and Stm32 processor, the Stm32 processing are provided on front side of the mounting base
Silicon can be melted by being provided on the left of device, and opening is provided on the end cap on front side of the Stm32 processor, is provided on the upside of the mounting base
Cooling line, the cooling line left side are provided with connecting tube, muff are provided on the outside of the connecting tube, and the connecting tube is left
Wing base, the pedestal upside are equipped with temperature control pot, and the temperature control pot inside lower end is provided with heating coil, the heating coil
Upside is provided with cooling coil, on rear side of the cooling line respectively with three solenoid valves of left end and the low-temperature solenoid valve on right side,
Gas solenoid valve is attached.
As a further solution of the present invention: being provided with mounting hole on the installation part.
As a further solution of the present invention: the mounting hole surrounding is provided with installation bolt, can be convenient consolidating for equipment
It is fixed.
As further scheme of the invention: being provided on rear side of the solenoid valve, low-temperature solenoid valve and gas solenoid valve
Side plate can be convenient the installation of equipment.
As further scheme of the invention: being provided on the outside of the solenoid valve, low-temperature solenoid valve and gas solenoid valve
Shell is protected, a cabinet can be formed with bottom plate, side plate and end cap, internal equipment can be effectively protected in this way.
As further scheme of the invention: front end is provided with recess on the left of the protection shell, can be convenient pipeline
Discharge.
As further scheme of the invention: several exhaust windows are installed on the side plate and protection shell, it can
To facilitate the radiating treatment of equipment.
Compared with prior art, the beneficial effects of the present invention are: 1) Stm32 controller of the present invention has CAN communication function,
It can be realized with other equipment networkings and be automatically performed some chemical reactions；
2) outlet temperature is arranged by key in the present invention, and control system is heated according to the temperature of setting and cooled down function
Can, the soaking time of outlet temperature can be set, meet temperature environment required for chemically reacting；
3) cooling system of the invention is cooled down by freezing liquid and coolant liquid, and freezing liquid is followed by external sub-cooled
Ring pump provides, and coolant liquid is provided by external diaphragm pump；
4) the novel automatic switchover that freezing liquid and coolant liquid can may be implemented of this city, external air pump realize freezing liquid and cold
But the removing of the residual liquid of liquid；
5) SD card store function is had, the trackability of all operating process may be implemented.
Detailed description of the invention
Fig. 1 is a kind of structural schematic diagram of the temperature control system for automatic chemistry synthesis system of the present invention.
Fig. 2 is control system block diagram in a kind of temperature control system for automatic chemistry synthesis system of the present invention.
1- bottom plate, 2- mounting base, 3- opening, 4- connecting tube, 5- muff, 6- can melt silicon, 7- pedestal, 8- temperature control pot, 9-
Heating coil, 10- cooling coil, 11- cooling line, 12- solenoid valve, 13- low-temperature solenoid valve, 14- gas solenoid valve, 15- are protected
Protective case body, 16-Stm32 processor.
Specific embodiment
It should be noted that in the absence of conflict, the feature in embodiment and embodiment in the present invention can phase
Mutually combination.
In the description of the present invention, it is to be understood that, term " center ", " longitudinal direction ", " transverse direction ", "upper", "lower",
The orientation or positional relationship of the instructions such as "front", "rear", "left", "right", "vertical", "horizontal", "top", "bottom", "inner", "outside" is
It is based on the orientation or positional relationship shown in the drawings, is merely for convenience of description of the present invention and simplification of the description, rather than instruction or dark
Show that signified device or element must have a particular orientation, be constructed and operated in a specific orientation, therefore should not be understood as pair
Limitation of the invention.In addition, term " first ", " second " etc. are used for description purposes only, it is not understood to indicate or imply phase
To importance or implicitly indicate the quantity of indicated technical characteristic.The feature for defining " first ", " second " etc. as a result, can
To explicitly or implicitly include one or more of the features.In the description of the present invention, unless otherwise indicated, " multiple "
It is meant that two or more.
In the description of the present invention, it should be noted that unless otherwise clearly defined and limited, term " installation ", " phase
Even ", " connection " shall be understood in a broad sense, for example, it may be being fixedly connected, may be a detachable connection, or be integrally connected；It can
To be mechanical connection, it is also possible to be electrically connected；It can be directly connected, can also can be indirectly connected through an intermediary
Connection inside two elements.For the ordinary skill in the art, above-mentioned term can be understood by concrete condition
Concrete meaning in the present invention.
The present invention will be described in detail below with reference to the accompanying drawings and embodiments.
Embodiment one
Refering to fig. 1 and Fig. 2, in the embodiment of the present invention, a kind of temperature control system for automatic chemistry synthesis system, including
Bottom plate 1, the 1 upside left end of bottom plate are provided with installation part, convenient for the installation of equipment, are provided with mounting hole on the installation part,
The mounting hole surrounding is provided with installation bolt, can be convenient the fixation of equipment, mounting base 2, institute are provided on the upside of the bottom plate 1
It states and is provided with Stm32 processor 16 on front side of mounting base 2, can effectively control the work of whole equipment, to realize equipment
Temperature control effect, silicon 6 can be melted by being provided on the left of the Stm32 processor 16, be set on the end cap of 16 front side of Stm32 processor
It is equipped with opening 3, setting operation panel is can be convenient in this way, cooling line 11, a pair of left end is provided on the upside of the mounting base 2
Cooling line 11 is used to control the disengaging of cooling water, and two of three 11 left ends of cooling line of right end are for controlling freezing liquid
Disengaging, the cooling line 11 of the rightmost side is for emptying pipeline in cooling water and freezing liquid handoff procedure, the cooling line
11 left sides are provided with connecting tube 4, and muff 5,4 left base 7 of connecting tube, the bottom are provided on the outside of the connecting tube 4
7 upside of seat is equipped with temperature control pot 8, and 8 inside lower end of temperature control pot is provided with heating coil 9, is arranged on the upside of the heating coil 9
Have cooling coil 10, can effectively facilitate equipment to be heated up and cooled down, 11 rear side of the cooling line respectively with left end
Three solenoid valves 12 and the low-temperature solenoid valve 13 on right side, gas solenoid valve 14 are attached, two solenoid valves 12 of left end with most
The cooling line 11 of left end is attached, and can control the disengaging of cooling water, the solenoid valve 12 and low-temperature solenoid valve of right end in this way
13 are attached with left side a pair of cooling line 11 of right end, in this way for control the disengaging for controlling freezing liquid, gas solenoid valve
14 are attached with the cooling line 11 of right end, in this way for emptying in cooling water and freezing liquid handoff procedure to pipeline.
There are three solenoid valve 12, low-temperature solenoid valve 13, gas solenoid valve 14, temperature for the output end setting of Stm32 processor 16
Degree sensor, liquid crystal display, the end PC and SD card memory, the input terminal of Stm32 processor 16 are provided with temperature sensor, PC
End and SD card memory pass through the temperature and cooling system input in liquid crystal display display time, temperature control pot temperature, reaction flask
With the temperature of output, then by selecting temperature control pot 7 to make Nei Wen or outer temperature control system, by key assignments outlet temperature, then temperature
Control pot control system is compared according to detection temperature and set temperature, to determine that temperature control pot is heated or dropped
Temperature, the operation panel or the end PC being arranged by Stm32 processor 16 are configured heating and temperature fall time, realize to temperature control system
The soaking time of outlet temperature is arranged in the alarm function of system, soaking time required for can improving for chemical reaction environment, then
Cooling system control is realized by the control to temperature control pot solenoid valve, realizes cooling function, and detection temperature is beaten when being higher than 50 degree
Coolant system is opened, is lower than 50 degree of opening freezing liquid systems, to reach outlet temperature.
Embodiment two
Unlike embodiment one: being provided on rear side of the solenoid valve 12, low-temperature solenoid valve 13 and gas solenoid valve 14
Side plate, can effectively facilitate the installation of equipment in this way, outside the solenoid valve 12, low-temperature solenoid valve 13 and gas solenoid valve 14
Side is provided with protection shell 15, can form a cabinet with bottom plate, side plate and end cap, can be effectively protected inside in this way
Equipment, the 15 left side front end of protection shell are provided with recess, can be convenient putting for route, the side plate and protection shell 15
On several exhaust windows are installed, can be convenient equipment work during radiate.
It is obvious to a person skilled in the art that invention is not limited to the details of the above exemplary embodiments, Er Qie
In the case where without departing substantially from spirit or essential attributes of the invention, the present invention can be realized in other specific forms.Therefore, no matter
From the point of view of which point, the present embodiments are to be considered as illustrative and not restrictive, and the scope of the present invention is by appended power
Benefit requires rather than above description limits, it is intended that all by what is fallen within the meaning and scope of the equivalent elements of the claims
Variation is included within the present invention.Any reference signs in the claims should not be construed as limiting the involved claims.
In addition, it should be understood that although this specification is described in terms of embodiments, but not each embodiment is only wrapped
Containing an independent technical solution, this description of the specification is merely for the sake of clarity, and those skilled in the art should
It considers the specification as a whole, the technical solutions in the various embodiments may also be suitably combined, forms those skilled in the art
The other embodiments being understood that.
Claims (7)
1. a kind of temperature control system for automatic chemistry synthesis system, including bottom plate (1), bottom plate (1) upside left end is set
It is equipped with installation part, is provided with mounting base (2) on the upside of the bottom plate (1), is provided with Stm32 processor on front side of the mounting base (2)
(16), being provided on the left of the Stm32 processor (16) can melt silicon (6), set on the end cap on front side of the Stm32 processor (16)
It is equipped with opening (3), which is characterized in that be provided with cooling line (11) on the upside of the mounting base (2), the cooling line (11) is left
Side is provided with connecting tube (4), is provided with muff (5) on the outside of the connecting tube (4), connecting tube (4) left base (7),
It is equipped with temperature control pot (8) on the upside of the pedestal (7), temperature control pot (8) inside lower end is provided with heating coil (9), described to add
It is provided with cooling coil (10) on the upside of hot coil (9), three solenoid valves with left end respectively on rear side of the cooling line (11)
(12) it is attached with the low-temperature solenoid valve on right side (13), gas solenoid valve (14).
2. a kind of temperature control system for automatic chemistry synthesis system according to claim 1, which is characterized in that described
Mounting hole is provided on installation part.
3. a kind of temperature control system for automatic chemistry synthesis system according to claim 2, which is characterized in that described
Mounting hole surrounding is provided with installation bolt.
4. a kind of temperature control system for automatic chemistry synthesis system according to claim 1, which is characterized in that, institute
It states and is provided with side plate on rear side of solenoid valve (12), low-temperature solenoid valve (13) and gas solenoid valve (14).
5. a kind of temperature control system for automatic chemistry synthesis system according to claim 4, which is characterized in that described
Protection shell (15) is provided on the outside of solenoid valve (12), low-temperature solenoid valve (13) and gas solenoid valve (14).
6. a kind of temperature control system for automatic chemistry synthesis system according to claim 5, which is characterized in that described
Front end is provided with recess on the left of protection shell (15).
7. a kind of temperature control system for automatic chemistry synthesis system according to claim 6, which is characterized in that described
Several exhaust windows are installed in side plate and protection shell (15).
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910065855.5A CN109569466A (en) | 2019-01-23 | 2019-01-23 | A kind of temperature control system for automatic chemistry synthesis system |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910065855.5A CN109569466A (en) | 2019-01-23 | 2019-01-23 | A kind of temperature control system for automatic chemistry synthesis system |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN109569466A true CN109569466A (en) | 2019-04-05 |
Family
ID=65917274
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201910065855.5A Pending CN109569466A (en) | 2019-01-23 | 2019-01-23 | A kind of temperature control system for automatic chemistry synthesis system |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN109569466A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112557158A (en) * | 2021-02-28 | 2021-03-26 | 中国工程物理研究院核物理与化学研究所 | Separation, purification and collection device for xenon in air sample |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0833829A (en) * | 1994-07-25 | 1996-02-06 | Hitachi Ltd | Regeneration treating device for engine cooling antifreeze |
| CN202516542U (en) * | 2012-03-06 | 2012-11-07 | 美药星（南京）制药有限公司 | PH and temperature automatic control system for reaction kettle |
| CN103111248A (en) * | 2013-02-02 | 2013-05-22 | 济南联远实业有限公司 | Device and method for controlling heating temperature and cooling temperature of heat conduction oil reaction kettle |
| CN203291835U (en) * | 2013-04-25 | 2013-11-20 | 浙江枧洋化工有限公司 | Coil type heating reaction kettle |
| CN104501485A (en) * | 2014-12-23 | 2015-04-08 | 西北工业大学 | Equipment and method for recycling freon in refrigerators |
| CN109210825A (en) * | 2018-09-20 | 2019-01-15 | 吉林建筑大学 | A kind of intelligent type heat exchanger with adjusting temperature function |
-
2019
- 2019-01-23 CN CN201910065855.5A patent/CN109569466A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0833829A (en) * | 1994-07-25 | 1996-02-06 | Hitachi Ltd | Regeneration treating device for engine cooling antifreeze |
| CN202516542U (en) * | 2012-03-06 | 2012-11-07 | 美药星（南京）制药有限公司 | PH and temperature automatic control system for reaction kettle |
| CN103111248A (en) * | 2013-02-02 | 2013-05-22 | 济南联远实业有限公司 | Device and method for controlling heating temperature and cooling temperature of heat conduction oil reaction kettle |
| CN203291835U (en) * | 2013-04-25 | 2013-11-20 | 浙江枧洋化工有限公司 | Coil type heating reaction kettle |
| CN104501485A (en) * | 2014-12-23 | 2015-04-08 | 西北工业大学 | Equipment and method for recycling freon in refrigerators |
| CN109210825A (en) * | 2018-09-20 | 2019-01-15 | 吉林建筑大学 | A kind of intelligent type heat exchanger with adjusting temperature function |
Non-Patent Citations (1)
| Title |
|---|
| 沈建良等编著: "ARM微控制器入门与提高", 中国航空航天大学出版社, pages: 3 - 5 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112557158A (en) * | 2021-02-28 | 2021-03-26 | 中国工程物理研究院核物理与化学研究所 | Separation, purification and collection device for xenon in air sample |
| CN112557158B (en) * | 2021-02-28 | 2021-05-28 | 中国工程物理研究院核物理与化学研究所 | Separation, purification and collection device for xenon in air sample |
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