CN109562047A - Hair dyeing feed composition - Google Patents
Hair dyeing feed composition Download PDFInfo
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- CN109562047A CN109562047A CN201880003070.9A CN201880003070A CN109562047A CN 109562047 A CN109562047 A CN 109562047A CN 201880003070 A CN201880003070 A CN 201880003070A CN 109562047 A CN109562047 A CN 109562047A
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/49—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds
- A61K8/4973—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with oxygen as the only hetero atom
- A61K8/498—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with oxygen as the only hetero atom having 6-membered rings or their condensed derivatives, e.g. coumarin
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/49—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/06—Preparations for styling the hair, e.g. by temporary shaping or colouring
- A61Q5/065—Preparations for temporary colouring the hair, e.g. direct dyes
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/10—Preparations for permanently dyeing the hair
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/42—Colour properties
- A61K2800/43—Pigments; Dyes
- A61K2800/432—Direct dyes
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Abstract
A kind of hair dyeing feed composition is provided, although it has sufficient dyeability to hair, inhibits the dyeability to skin.A kind of hair dyeing feed composition contains ingredient A: alkali blue 124；Ingredient B: selected from by Basic Orange 31, the dyestuff of one or more of the group that alkalinity is red 51, alkalinity is red 76, basic yellow 87 and basic yellow 57 form；Ingredient C:HC indigo plant 2；And ingredient D: the dyestuff selected from one or more of the group being made of HC 4 and HC of Huang Huang 2.Preferably, the content of mentioned component A is 0.005~0.5 mass %, and the content of mentioned component B is 0.005~1.5 mass %, and the content of mentioned component C is 0.1~1.5 mass %, and the content of mentioned component D is 0.01~0.5 mass %.
Description
Technical field
The present invention relates to hair dyeing feed compositions.The Japanese Patent Application submitted this application claims on March 29th, 2017 in Japan
No. 2017-066453 priority, its contents are hereby incorporated herein by reference.
Background technique
In the past, the inorganic agent dyed as white hair hair dyeing, fashion hair dyeing etc. to hair, following oxide hair dyes etc. are
It is general, it is constituted by the 1st dose comprising alkaline reagent and oxidation hair-dye material, with the 2nd dose comprising hydrogen peroxide.But this
Although a little oxide hair dyes can play excellent dyeing effect, it can be coloured to desired color development, deposited but then
The shortcomings that generating damage to hair, scalp.It is simultaneously placed for a long time in addition, medicament must in operation stayed on hair, because
This oneself implementation not only very expends the time in the case where handling, but also there is the penetrating odor and skin for generating alkaline reagent
The shortcomings that stimulation.In addition, according to the means of operation, there is also coloration results to generate unevenness, is difficult to the shortcomings that equably dyeing.
In contrast, as damaging small inorganic agent to hair, scalp, it is known to use the hair dyeing of basic dye, HC dyestuff
Material.It, can be with the shampoo stain that be dyed simultaneously to hair of shampoo when hair washing in above-mentioned hair dye；Can with after hair washing
Rinsing, hair conditioner hair is dyed simultaneously Rinsing stain or hair care stain have an advantage that simplicity is excellent, into
And the uniformity dyed is also excellent (referring to patent document 1).
But there are following disadvantages for existing above-mentioned hair dye:, that is, when being attached to skin on face high to the dyeability of skin
Color tolerance is easily stained on skin, especially in the case where shampoo stain, Rinsing stain or hair care stain, due to not using when hair washing
Gloves etc. use, therefore there are problems that finger tip, scalp coloring.In order to inhibit above-mentioned coloring, the dye in hair dye is being reduced
In the case where expecting concentration, the dyeability of hair is reduced.Therefore, status is to need high for the dyeability of hair and inhibit
To the chromatic hair dye of skin.
It should be noted that in recent years, it is known that dye of the mixture as the alkali blue (Basic Blue) 124 of blue dyes
Material issuance composition (patent document 2,3).But the dyeability about above-mentioned hair dyeing feed composition, know nothing at present,
Existing technical literature
Patent document
Patent document 1: Japanese Unexamined Patent Publication 2014-101292 bulletin
Patent document 2: Japanese Unexamined Patent Publication 2015-17108 bulletin
Patent document 3: Japanese Unexamined Patent Publication 2015-17109 bulletin
Summary of the invention
Problems to be solved by the invention
The present invention is carried out in view of the above-mentioned prior art, and the purpose of the present invention is to provide a kind of combinations of hair dye
Object inhibits the dyeability to skin although having sufficient dyeability to hair.
Means for solving the problems
The present inventor has made intensive studies in order to achieve the above object, as a result, it has been found that: pass through following hair dyeing feed compositions
It is available although have to hair sufficient dyeability, inhibit chromatic hair dyeing feed composition to skin, the hair dyeing
Feed composition contains ingredient A: alkali blue 124；Ingredient B: selected from by Basic Orange 31, alkalinity is red 51, alkalinity is red 76, basic yellow 87 with
And the dyestuff of one or more of group of the composition of basic yellow 57；Ingredient C:HC indigo plant 2；Ingredient D: selected from being made of HC 4 and HC of Huang Huang 2
One or more of group dyestuff.The present invention is completed based on these technical ideas.
That is, the present invention provides a kind of hair dyeing feed composition, containing following compositions A, following compositions B, following compositions C and
Following compositions D.
Ingredient A: dyestuff shown in following formula (1)
[changing 1]
Ingredient B: selected from by Basic Orange 31, in the group that alkalinity is red 51, alkalinity is red 76, basic yellow 87 and basic yellow 57 form
More than one dyestuff
Ingredient C:HC indigo plant 2
Ingredient D: the dyestuff selected from one or more of the group being made of HC 4 and HC of Huang Huang 2
The content of mentioned component A is preferably 0.005~0.5 mass %, and the content of mentioned component B is preferably 0.005~1.5
Quality %, the content of mentioned component C are preferably 0.1~1.5 mass %, and the content of mentioned component D is preferably 0.01~0.5 matter
Measure %.
About above-mentioned hair dyeing feed composition, preferably mass ratio of the content of mentioned component B relative to the content of mentioned component A
Example [ingredient B/ ingredient A] is 0.1~10.0, the content of mentioned component D relative to the content of mentioned component C mass ratio [at
Point D/ ingredient C] it is 0.005~1.0, mass ratio [the ingredient C/ of the content of mentioned component C relative to the content of mentioned component A
Ingredient A] it is 1.5~70.0.
The content of above-mentioned HC Huang 2 in 100 mass % of mentioned component D is preferably 50.0 mass % or more.
Above-mentioned hair dyeing feed composition is preferably Rinsing stain or hair care stain.
Above-mentioned hair dyeing feed composition preferably further contains following compositions E.
Ingredient E: selected from one of the group being made of cationic surface active agent, cation property copolymer and silicone oil
Above ingredient
The effect of invention
Hair dyeing feed composition of the invention has sufficiently excellent dyeability to hair.Therefore, as shampoo stain, profit
In the case where silk stain, hair care stain use, the dyeing effect of hair can be fully played by the use of fewer number.
In addition, can also be obtained as hair maintenance agent (hair manicure) use with the operating time than the short period
Obtain sufficient dyeing effect.In addition, hair dyeing feed composition of the invention is low to the dyeability of skin, finger when use, scalp
Coloring is few.
Specific embodiment
Hair dyeing feed composition of the invention is used as the composition of hair dye.As above-mentioned hair dye, Rinsing can be enumerated
Stain, hair care stain, hair maintenance agent, shampoo stain etc..Wherein, from have can easily be had hair dyed, behaviour each time
From the aspect of making time short advantage, hair dyeing feed composition of the invention is preferably Rinsing stain or hair care stain or perfume (or spice)
Wave stain.
Hair dyeing feed composition of the invention at least contains: dyestuff shown in above-mentioned formula (1)；Selected from by Basic Orange 31, alkalinity
Red 51, the dyestuff of one or more of group that alkaline red 76, basic yellow 87 and basic yellow 57 form；HC indigo plant 2；And selected from by
The dyestuff of one or more of the group of 4 and HC of HC Huang Huang, 2 composition.In this specification, sometimes by above-mentioned " dyestuff shown in formula (1) "
Referred to as " ingredient A ".In addition, sometimes by it is above-mentioned " selected from by Basic Orange 31, alkalinity is red 51, alkalinity is red 76, basic yellow 87 and alkalinity
The dyestuff of one or more of the group of 57 composition of Huang " is known as " ingredient B ".In addition, above-mentioned " HC indigo plant 2 " is known as " ingredient C " sometimes.
In addition, above-mentioned " dyestuff selected from one or more of the group being made of HC 4 and HC of Huang Huang 2 " is known as " ingredient D " sometimes.
Hair dyeing feed composition of the invention includes at least ingredient A, ingredient B, ingredient C and ingredient D.Depending on the application, this hair
Bright hair dyeing feed composition can also further comprise as the ingredient other than mentioned component A~D of neccessary composition.Wherein, exist
In the case that hair dyeing feed composition of the invention is Rinsing stain or hair care stain, hair dyeing feed composition of the invention is preferably into one
Step comprising selected from one or more of group for being made of cationic surface active agent, cation property copolymer and silicone oil at
Point.In this specification, sometimes by above-mentioned " selected from being made of cationic surface active agent, cation property copolymer and silicone oil
One or more of group ingredient " be known as " ingredient E ".
Hair dyeing feed composition of the invention can further include the ingredient (other compositions) other than above-mentioned A~E.It is above-mentioned at
Divide, such as ingredient A, ingredient B, ingredient C, ingredient D, ingredient E, other compositions can also can be used two using only one kind respectively
Kind or more.
Hereinafter, being illustrated to ingredient A~D of the neccessary composition as hair dyeing feed composition of the invention.
[ingredient A: dyestuff shown in formula (1)]
Ingredient A is dyestuff shown in following formula (1).Although ingredient A is very excellent for the dyeability of hair, to skin
Dyeability it is extremely low.Therefore, available to have taken into account to the high dyeability of hair and to the dyeing of skin by using ingredient A
The hair dyeing feed composition of inhibition.
[changing 2]
Ingredient A is with INCI (international cosmetic ingredient dictionary and handbooks, the 15th edition, volume 1,2014, page 329):
Compound documented by BASIC BLUE 124 (alkali blue 124) is 3- amino -7- (dimethylamino) -2- methoxyl group phenoxazine
Piperazine -5- chloride: 3-Amino-7- (dimethylamino) -2-methoxyphenoxazin-5-ium chloride.
Commercially available product also can be used in ingredient A.As the commercially available product of ingredient A, it can be cited for example that the quotient of BASF AG's manufacture
The name of an article " Vibracolor Moonlight Blue ".
The content of ingredient A in 100 mass % of hair dyeing feed composition of the invention is not particularly limited, and preferably 0.005
~0.5 mass %, more preferably 0.01~0.2 mass %, further preferably 0.02~0.1 mass %.If above-mentioned content is
0.005 mass % or more then improves the dyeability of hair, particularly the effect dyed to white hair, therefore it is preferred that.On if
State content be 0.5 mass % hereinafter, then safety further increase, therefore it is preferred that.In addition, can further suppress because being dissolved out after washing
To the color transfer of towel or clothes etc. caused by dyestuff into water, therefore it is preferred that.
[ingredient B: selected from by Basic Orange 31, the group that alkalinity is red 51, alkalinity is red 76, basic yellow 87 and basic yellow 57 form
One or more of dyestuff]
Ingredient B be selected from by Basic Orange 31, the group that alkalinity is red 51, alkalinity is red 76, basic yellow 87 and basic yellow 57 form
One or more of dyestuff (at least one dyestuff).One kind can be used only in ingredient B, also can be used two or more.
Wherein, these dye combinations are preferably adjusted to the tone of Yellow Red by ingredient B.Specifically, it is preferable that orange list
Color and yellow and red combination.That is, the preferred Basic Orange 31 of ingredient B is monochromatic, alkalinity red 51 and the combination of basic yellow 87, alkalinity are red
51 with the combination of basic yellow 57, alkalinity red 76 and the combination of basic yellow 87 or the combination of alkalinity red 76 and basic yellow 57.It is more excellent
It is selected as monochromatic Basic Orange 31, alkalinity red 51 and the combination of basic yellow 87 or the combination of alkalinity red 76 and basic yellow 57.Wherein,
Ingredient B is particularly preferably the combination of Basic Orange 31, alkalinity red 51 and basic yellow 87.By will be prepared into the ingredient B of Yellow Red with
Blue ingredient A carry out mixture, hair dyeing feed composition in, only using the combination of the dyestuff of cationic can colour generation as grey.
In addition, aftermentioned ingredient C and ingredient D are the dyestuff of nonionic, using their combination can colour generation as grey.As a result, such as
Described afterwards, hair dyeing feed composition of the invention is using the dyestuff of cationic and the dyestuff of nonionic, and colour generation is grey respectively,
Discoloration when therefore can further improve dyeability, color keep, the standing time extension of short time inhibits, for through bleaching
The irregular colour of the hair equivalent damage hair of processing, therefore it is preferred that.
Above-mentioned Basic Orange 31 be with INCI (international cosmetic ingredient dictionary and handbook, the 15th edition, volume 1,2014,
331-332 pages): compound documented by BASIC ORANGE 31 (Basic Orange 31) is 2- [(4- aminophenyl) azo] -1,
3- dimethyl -1H- imidazolium chloride: 2- [(4-Aminophenyl) azo] -1,3-dimethyl-1H-imidazolium
chloride。
Above-mentioned alkalinity red 51 be with INCI (international cosmetic ingredient dictionary and handbook, the 15th edition, volume 1,2014,
Page 333): (compound documented by red 51) of alkalinity is 2- (4- (dimethyl-amino-phenyl azo) 1,3- to BASIC RED 51
Dimethyl -1,3- dimethyl -3H- imidazole radicals -1- chloride: 2- (4- (Dimethylamino-phenylazo) 1,3-
dimethyl-1,3-dimethyl-3H-imidazol-1-ium chloride.Above-mentioned alkalinity red 51 is also referred to as 2- [((4- bis-
Methylamino) phenyl) azo] -1,3- dimethyl -1H- imidazolium chloride: 2- [((4-Dimethylamino) phenyl)
azo]-1,3-dimethyl-1H-imidazolium chloride。
Above-mentioned alkalinity red 76 be with INCI (international cosmetic ingredient dictionary and handbook, the 15th edition, volume 1,2014,
333-334 pages): (compound documented by red 76) of alkalinity is that [(2- methoxyphenyl) is even by 7- hydroxyl -8- to BASIC RED 76
Nitrogen] N, N, N- trimethyl -2- naphthalene ammonium chloride: 7-Hydroxy-8- [(2-methoxyphenyl) azo] N, N, N-
trimethyl-2-naphthalenaminium chloride.Above-mentioned alkalinity red 76 is also referred to as [7- hydroxyl -8- [(2- methoxyl group
Phenyl) azo] -2- naphthalene]-trimethyl ammonium chloride: [7-Hydroxy-8- [(2-methoxyphenyl) azo] -2-
naphthyl]-trimethylammonium chloride。
Above-mentioned basic yellow 87 be with INCI (international cosmetic ingredient dictionary and handbook, the 15th edition, volume 1,2014,
337-338 pages): compound documented by BASIC YELLOW 87 (basic yellow 87) is pyridine, 1- methyl -4- [(methylbenzene
Base hydrazono-) methyl]-, Methylsulfate: Pyridinium, 1-methyl-4- [(methylphenylhydrazono)
methyl]-,methyl sulfate.Above-mentioned basic yellow 87 is also referred to as 1- methyl -4- [(aminomethyl phenyl hydrazono-) methyl] pyridine
Methylsulfate salt: 1-Methyl-4- [(methylphenylhydrazono) methyl] pyridinium
methylsulfate。
Above-mentioned basic yellow 57 be with INCI (international cosmetic ingredient dictionary and handbook, the 15th edition, volume 1,2014,
Page 337): compound documented by BASIC YELLOW 57 (basic yellow 57) is puratized agricultural spray, 3- [(4,5- dihydro -3- methyl -5-
Oxo -1- phenyl -1H- pyrazoles -4- base) azo]-N, N, N- trimethyl -, chloride: Benzenaminium, 3- [(4,5-
dihydro-3-methyl-5-oxo-1-phenyl-1H-pyrazol-4-yl)azo]-N,N,N-trimethyl-,
chloride.Above-mentioned basic yellow 57 is also referred to as 5- hydroxy-3-methyl -1- phenyl -4- (3 '-trimethyl ammonium phenylazo)-pyrrole
Azoles: 5-Hydroxy-3-methyl-1-phenyl-4- (3 '-trimethylammoniophenylazo)-pyrazol.
Commercially available product also can be used in ingredient B.As the commercially available product of Basic Orange 31, it can be cited for example that BASF AG manufactured
Trade name " Vibracolor Flame Orange ".As the commercially available product of alkalinity red 51, it can be cited for example that BASF AG manufactures
Trade name " Vibracolor Ruby Red ".As the commercially available product of alkalinity red 76, it can be cited for example that Sensient
The trade name " ARIANOR MADDER RED " of Technologies Japan Co., Ltd. manufacture.As the commercially available of basic yellow 87
Product, it can be cited for example that the trade name " Vibracolor Citrus Yellow " of BASF AG's manufacture.As basic yellow 57
Commercially available product the, it can be cited for example that trade name " ARIANOR of Sensient Technologies Japan Co., Ltd. manufacture
STRAW YELLOW”。
The content of ingredient B in 100 mass % of hair dyeing feed composition of the invention is not particularly limited, and preferably 0.005
~1.5 mass %, more preferably 0.01~1.0 mass %.If above-mentioned content is 0.005 mass % or more, for hair
Dyeability, particularly the effect dyed to white hair further increase, therefore it is preferred that.If above-mentioned content be 1.5 mass % hereinafter,
Then safety further increases, therefore it is preferred that.In addition, caused by can further suppressing because of dyestuff of the dissolution into water after washing to
The color transfer of towel or clothes etc., therefore it is preferred that.The content of mentioned component B be in hair dyeing feed composition of the invention all at
Divide the total amount of the content of B.
It should be noted that the content of the Basic Orange 31 in hair dyeing 100 mass % of feed composition of the invention is not special
It limits, preferably 0.005~0.5 mass %, more preferably 0.01~0.2 mass %.100 matter of hair dyeing feed composition of the invention
The content of alkalinity red 51 in amount % is not particularly limited, preferably 0.005~0.5 mass %, more preferably 0.01~0.2 matter
Measure %.The content of alkalinity red 76 in 100 mass % of hair dyeing feed composition of the invention is not particularly limited, preferably 0.01~
1.5 mass %, more preferably 0.05~1.0 mass %.Basic yellow 87 in hair dyeing 100 mass % of feed composition of the invention
Content is not particularly limited, preferably 0.005~0.5 mass %, more preferably 0.01~0.2 mass %.Hair dyeing of the invention
The content of basic yellow 57 in 100 mass % of feed composition is not particularly limited, preferably 0.01~1.5 mass %, more preferably
For 0.05~1.0 mass %.
Ingredient B is preferably only made of Basic Orange 31, ingredient B in hair dyeing 100 mass % of feed composition of the invention (that is,
Basic Orange 31) content be 0.005~0.5 mass % (especially 0.01~0.2 mass %).In addition, ingredient B is preferably only by alkali
Property red 51 and basic yellow 87 constitute, the content of the alkalinity red 51 in hair dyeing 100 mass % of feed composition of the invention for 0.005~
The content of 0.5 mass % (especially 0.01~0.2 mass %) and basic yellow 87 be 0.005~0.5 mass % (especially
0.01~0.2 mass %).In addition, ingredient B is preferably only made of alkalinity red 76 and basic yellow 57, hair dye combination of the invention
The content of alkalinity red 76 in 100 mass % of object is 0.01~1.5 mass % (especially 0.05~1.0 mass %) and alkalinity
The content of Huang 57 is 0.01~1.5 mass % (especially 0.05~1.0 mass %).
[ingredient C:HC indigo plant 2]
Ingredient C is HC indigo plant 2.Above-mentioned HC indigo plant 2 be with INCI (international cosmetic ingredient dictionary and handbook, the 15th edition, the 1st
Volume, 2014, page 1447): compound documented by HC BLUE NO.2 (HC indigo plant No.2) is 2,2 '-[[4- [(2- hydroxyl second
Base) amino] -3- nitrobenzophenone] imino group] di-methylcarbinol: 2,2 '-[[4- [(2-Hydroxyethyl) amino] -3-
nitrophenyl]imino]bisethanol。
Commercially available product also can be used in ingredient C.As the commercially available product of ingredient C, it can be cited for example that Teluca company manufactured
Trade name " COLOREX HCB2 ".
The content of ingredient C in 100 mass % of hair dyeing feed composition of the invention is not particularly limited, preferably 0.1~
1.5 mass %, more preferably 0.2~1.5 mass %, further preferably 0.5~1.0 mass %.If above-mentioned content is 0.1 matter
Measure % or more, then fastness further increases, therefore it is preferred that.If above-mentioned content be 1.5 mass % hereinafter, if safety further mention
Height, therefore it is preferred that.In addition, the face to towel or clothes etc. caused by can further suppressing because of dyestuff of the dissolution into water after washing
Color transfer, therefore it is preferred that.
[ingredient D: the dyestuff selected from one or more of the group being made of HC 4 and HC of Huang Huang 2]
Ingredient D is the dyestuff (at least one dyestuff) selected from one or more of the group being made of HC 4 and HC of Huang Huang 2, i.e.,
For HC 4 and/or HC of Huang Huang 2.Above-mentioned HC Huang 4 be with INCI (international cosmetic ingredient dictionary and handbook, the 15th edition, volume 1,
2014, page 1455): compound documented by HC YELLOW NO.4 (HC Huang No.4) is 2- [[2- (2- hydroxyl-oxethyl)-
4- nitrobenzophenone] amino] ethyl alcohol: 2- [[2- (2-Hydroxyethoxy) -4-nitrophenyl] amino] ethanol.It is above-mentioned
HC Huang 2 is with INCI (international cosmetic ingredient dictionary and handbooks, the 15th edition, volume 1,2014, page 1455): HC
Compound documented by YELLOW NO.2 (HC Huang No.2) is 2- [(2- nitrobenzophenone) amino] ethyl alcohol: 2- [(2-
Nitrophenyl)amino]ethanol.One kind can be used only in ingredient D, also can be used two or more.
Commercially available product also can be used in ingredient D.As the commercially available product of HC Huang 4, it can be cited for example that Teluca company manufactured
Trade name " COLOREX HCY4 ".As the commercially available product of HC Huang 2, it can be cited for example that the trade name of Teluca company manufacture
“COLOREX HCY2”。
The content of ingredient D in 100 mass % of hair dyeing feed composition of the invention is not particularly limited, preferably 0.01~
0.5 mass %, more preferably 0.01~0.2 mass %, further preferably 0.02~0.1 mass %.If above-mentioned content is
0.01 mass % or more, then fastness further increases, therefore it is preferred that.If above-mentioned content be 0.5 mass % hereinafter, if safety into
One step improves, therefore it is preferred that.In addition, caused by can further suppressing because of dyestuff of the dissolution into water after washing to towel or clothes
Deng color transfer, therefore it is preferred that.The content of mentioned component D is the content of the whole components D in hair dyeing feed composition of the invention
Total amount.
As ingredient D, from light resistance (photostability) it is superior from the aspect of, more preferable HC Huang 2.That is, ingredient D is preferred
Neccessary composition, more preferably HC Huang 2 are used as comprising HC Huang 2.The content of HC Huang 2 in 100 mass % of ingredient D is preferably 50.0
Quality % or more (that is, 50.0~100 mass %), more preferably 70.0 mass % or more, further preferably 90.0 mass %
More than.Ingredient D is most preferably only made of HC Huang 2.By making ingredient D include HC Huang 2 as neccessary composition, can further suppress
Yellow is faded, therefore it is preferred that.In particular, in the case where colour generation prepared by the dyestuff using yellow is the hair dye of grey, by
It is big in the variation for the tone that fading for yellow component, hair dye are integrally showed, therefore the use of HC Huang 2 is to have with above range
Effect.
In hair dyeing feed composition of the invention, ingredient A and ingredient B are the dyestuff of cationic, only with cationic
The combination of dyestuff can colour generation be grey.In addition, ingredient C and ingredient D are the dyestuff of nonionic, only with the dye of nonionic
The combination of material can colour generation be grey.Therefore, in hair dyeing feed composition of the invention, only the combination of the dyestuff of cationic and
The combination difference colour generation of the only dyestuff of nonionic is grey.The dyestuff of cationic has following characteristics: dyeing kinetics are fast,
Fastness is also excellent, but is easy to be adsorbed onto damage hair or damage location, and it is uneven to be easy to appear dyeing.On the other hand, nonionic
Property dyestuff have following characteristics: dyeing kinetics are slow, but no matter have it is not damaged, be easy equably adsorb.Therefore, in sun
In the case that the tone of the dyestuff of ionic dyestuff and nonionic is respectively different, according to caused by standing time or position
The difference etc. of degree of injury, is easy to happen irregular colour.In the present invention, as described above, using cationic dyestuff and it is non-from
The dyestuff of sub- property, colour generation is grey respectively, therefore can further improve the dyeability, color keep, standing time of short time
Discoloration when extension inhibits, for the irregular colour of the hair equivalent damage hair through bleaching, therefore it is preferred that.
In hair dyeing feed composition of the invention, mass ratio [the ingredient B/ of the content of ingredient B relative to the content of ingredient A
Ingredient A] it is not particularly limited, preferably 0.1~10.0, more preferably 0.5~8.0.By keeping above-mentioned mass ratio above-mentioned
In range, more particularly to which white hair to be coloured to more natural tone.When above-mentioned mass ratio is less than 0.1, in dyeing to hair
Tone becomes blue, if above-mentioned mass ratio is more than 10.0, dyeing to the tone on hair becomes red, especially in white hair
Become unnatural tone in dyeing sometimes.
In hair dyeing feed composition of the invention, mass ratio [the ingredient D/ of the content of ingredient D relative to the content of ingredient C
Ingredient C] it is not particularly limited, preferably 0.005~1.0, more preferably 0.01~0.5.By making on above-mentioned mass ratio
It states in range, more particularly to which white hair to be coloured to more natural tone.When above-mentioned mass ratio is less than 0.005, hair is arrived in dyeing
On tone become purple, if above-mentioned mass ratio is more than 1.0, dyeing to the tone on hair becomes yellow, especially exists
Become unnatural tone sometimes in white hair dyeing.
In hair dyeing feed composition of the invention, mass ratio [the ingredient C/ of the content of ingredient C relative to the content of ingredient A
Ingredient A] it is not particularly limited, preferably 1.5~70.0, more preferably 1.6~60.0.If above-mentioned mass ratio is 1.5 or more,
It then can suitably adjust dyeing kinetics, it is difficult to the irregular colour for the hair equivalent damage hair through bleaching occur.Separately
On the one hand, if above-mentioned mass ratio be 70.0 hereinafter, if dyeability and color keep it is excellent, therefore it is preferred that.
Hereinafter, being any in Rinsing stain, hair care stain and hair maintenance agent to hair dyeing feed composition of the invention
Preferred optional member when kind is illustrated.
[ingredient E: one in the group being made of cationic surface active agent, cation property copolymer and silicone oil
Kind or more ingredient]
The case where hair dyeing feed composition of the invention is any in Rinsing stain, hair care stain and hair maintenance agent
Under, hair dyeing feed composition of the invention preferably comprises ingredient E.Ingredient E is selected from by cationic surface active agent, cationic
The ingredient (at least one ingredient) of one or more of the group of polymer and silicone oil composition.If comprising ingredient E, hair dye group
The reducing effect for closing rough sense when washing caused by object improves, therefore it is preferred that.One kind can be used only in ingredient E, also can be used
It is two or more.
As above-mentioned cationic surface active agent (cationic surfactant), it can be cited for example that monoalkyl type quaternary ammonium
Salt, dioxane fundamental mode quaternary ammonium salt, trialkyl type quaternary ammonium salt, monoalkyl ether type quaternary ammonium salt, alkylamine, fatty acid amide amine etc..
As above-mentioned monoalkyl type quaternary ammonium salt, it can be cited for example that lauryl trimethyl ammonium chloride, myristyl trimonium
Ammonium chloride, hexadecyltrimethylammonium chloride, stearyl trimethyl ammonium chloride, behenyl base trimethyl ammonium chloride, alkyl (16,18)
Trimethyl ammonium chloride, alkyl (20~22) trimethyl ammonium chloride, stearalkonium chloride, myristyl dimethylbenzyl
Ammonium chloride, three (polyoxyethylene) stearyl ammonium chlorides, two (polyoxyethylene) oleyl ammonio methacrylates etc..
As above-mentioned fatty acid amide amine, it can be cited for example that myristic acid dimethyl aminoethyl amide, myristic acid
Dimethylaminopropyl amide, myristic acid diethylamino buserelin, myristic acid diethyl amino propyl amide, palm
Sour dimethyl aminoethyl amide, palmitinic acid dimethylaminopropyl amide, palmitinic acid diethylamino buserelin, palmitinic acid
Diethyl amino propyl amide, stearic acid dimethyl aminoethyl amide, stearic acid dimethylaminopropyl amide, stearic acid two
Ethylaminoethyl amide, stearic acid diethyl amino propyl amide, stearic acid dipropylamino buserelin, stearic acid dipropyl
Base aminopropyl amide, behenic acid dimethyl aminoethyl amide, behenic acid dimethylaminopropyl amide, behenic acid diethyl
Aminoethylamide, behenic acid diethyl amino propyl amide etc..
Above-mentioned fatty acid amide amine uses in a salt form preferably by organic and or inorganic acids.Have as above-mentioned
Machine acid, can enumerate lactic acid, malic acid, citric acid, tartaric acid, acetic acid etc..In addition, phosphorus can be enumerated as above-mentioned inorganic acid
Acid, hydrochloric acid, sulfuric acid etc..Wherein, preferred lactic acid.As long as the content of above-mentioned organic acid and inorganic acid can neutralize mixed rouge
The amount of fat acid amide amine is just not particularly limited.
As above-mentioned cationic surface active agent, it is above-mentioned among, preferably monoalkyl type quaternary ammonium salt, fatty acid amide amine,
More preferably stearyl trimethyl ammonium chloride, behenyl base trimethyl ammonium chloride, alkyl (16,18) trimethyl ammonium chloride, alkyl (20
~22) trimethyl ammonium chloride, stearic acid dimethylaminopropyl amide.
As above-mentioned cation property copolymer (cationic polymer), it can be cited for example that chlorination O- [2- hydroxyl -3- (three
Methyl ammonium) propyl] cellulose ether derivative containing quaternary nitrogen such as hydroxyethyl cellulose；Chlorination O- [2- hydroxyl -3- (trimethyl ammonium
Base) propyl] guar derivative containing quaternary nitrogen such as guar gum；Cationic starch, diallyl quaternary ammonium polymer, two allyls
Based quaternary ammonium salt/acrylamide copolymer, quaternised polyvinyl pyrrolidinone derivatives, polyglycols polyamine condensation object, oneself two
Sour dimethylamino hydroxypropyl ethylenetriamine copolymer, cationization dextran etc..Among above-mentioned, preferably chlorination O- [2-
Hydroxyl -3- (trimethyl ammonium) propyl] hydroxyethyl cellulose, diallyl quaternary ammonium polymer, diallyl quaternary ammonium/propylene
Amide copolymer, more preferably polychloride dimethylated methylene phenylpiperidines.
As above-mentioned silicone oil, it can be cited for example that the high polymerization first that methyl polysiloxane, average degree of polymerization are 650~7000
The chains silicone such as based polysiloxane, methyl phenyl silicone, methylhydrogenpolysi,oxane, dimethiconol；Methyl ring
The cyclic silicones such as polysiloxanes, octamethylcy-clotetrasiloxane, decamethylcyclopentaandoxane, ten diformazan basic rings, six siloxanes；Amino
Propylmethylsiloxane dimethylsiloxane copolymer, aminoethylaminopropyl siloxanes Dimethicone Copolyol
The amino modified silicone such as object, aminoethylaminopropyl methylsiloxane dimethylsiloxane copolymer, carboxy-modified silicone,
Fatty acid modified silicone, alcohol modified silicone, aliphatic alcohol modified silicone, epoxy-modified silicone, fluorine richness silicone, alkyl-modified silicon
Modified silicones such as ketone etc..Wherein, preferably chain silicone, amino modified silicone.
In the case that hair dyeing feed composition of the invention includes ingredient E, in 100 mass % of hair dyeing feed composition of the invention
The content of ingredient E be not particularly limited, preferably 0.5~10.0 mass %, more preferably 1.0~5.0 mass %.If above-mentioned
Content is 0.5 mass % or more, then rough sense further decreases when washing, therefore it is preferred that.Above-mentioned content is more than 10.0 mass %'s
In the case of, it can make ingredient E accumulation in hair due to continuous use, hair generates sometimes to harden.The content of mentioned component E
For the total amount of the content of the whole components E in hair dyeing feed composition of the invention.
The case where hair dyeing feed composition of the invention is any in Rinsing stain, hair care stain and hair maintenance agent
Under, hair dyeing feed composition of the invention preferably comprises polyalcohol.As above-mentioned polyalcohol, it can be cited for example that ethylene glycol, the third two
Alcohol, dipropylene glycol, polyethylene glycol, 1,3 butylene glycol, glycerol, concentrated glycerin, diglycerol, triglycerin, glucose, maltose, malt
Sugar alcohol, sucrose, mannitol, D-sorbite, 1,2- pentanediol, 1,2- hexylene glycol, 1,2- ethohexadiol etc..Hair dye group of the invention
Object is closed comprising in the case where polyalcohol, the content of the polyalcohol in hair dyeing 100 mass % of feed composition of the invention is not special
It limits, from the deliquescent aspect of dyestuff, preferably 0.5~10.0 mass %, more preferably 1.0~5.0 mass %.On
The content of polyalcohol is stated as the total amount of the content of whole polyalcohols in hair dyeing feed composition of the invention.
The case where hair dyeing feed composition of the invention is any in Rinsing stain, hair care stain and hair maintenance agent
Under, hair dyeing feed composition of the invention preferably comprises higher alcohol.As above-mentioned higher alcohol, it can be cited for example that carbon atom number is 16
~22 alcohol can enumerate cetanol, stearyl alcohol, isooctadecanol, 2- octyldodecanol, oleyl alcohol, docosyl alcohol etc..Of the invention
In the case that feed composition of having hair dyed includes higher alcohol, the content of the higher alcohol in hair dyeing 100 mass % of feed composition of the invention
It is not particularly limited, from ageing stability aspect, preferably 1.0~10.0 mass %, more preferably 3.0~8.0 matter
Measure %.The content of above-mentioned higher alcohol is the total amount of the content of whole higher alcohols in hair dyeing feed composition of the invention.
The case where hair dyeing feed composition of the invention is any in Rinsing stain, hair care stain and hair maintenance agent
Under, hair dyeing feed composition of the invention preferably comprises hydrocarbon ils.As above-mentioned hydrocarbon ils, it can be cited for example that alpha-olefin low polymers, light
Matter isoparaffin, light liquid isoparaffin, saualane, synthesis saualane, vegetalitas saualane, liquid isoparaffin, liquid
Paraffin etc..In the case that hair dyeing feed composition of the invention includes hydrocarbon ils, in 100 mass % of hair dyeing feed composition of the invention
The content of hydrocarbon ils is not particularly limited, the fusion easiness aspect for feed composition of having hair dyed when coating, preferably 0.5~
10.0 mass %, more preferably 1.0~5.0 mass %.The content of above-mentioned hydrocarbon ils is complete in hair dyeing feed composition of the invention
The total amount of the content of portion's hydrocarbon ils.
From further increase hair it is chromatic from the aspect of, hair dyeing feed composition of the invention may include fatty acid
Partial carbon atom number is 12 ester compounds below.As above-mentioned ester compounds, it can be cited for example that the last of the ten Heavenly stems such as glycerol decanoate
Acid esters, caprylate, 2-ethylhexanoic acid cetyl ester, isononyl isononanoate etc..Hair dyeing feed composition of the invention includes above-mentioned
In the case where ester compounds, the content of the above-mentioned ester compounds in hair dyeing 100 mass % of feed composition of the invention is not special
It limits, from chromatic aspect, preferably 0.5~5.0 mass %, more preferably 1.0~3.0 mass %.Above-mentioned esterification
The content of object is closed as the total amount of the content of the above-mentioned ester compounds of whole in hair dyeing feed composition of the invention.
The case where hair dyeing feed composition of the invention is any in Rinsing stain, hair care stain and hair maintenance agent
Under, from the aspect of ageing stability, hair dyeing feed composition of the invention may include nonionic surface active agent (it is non-from
Sub- surfactant).As above-mentioned nonionic surface active agent, it can be cited for example that polyoxyethylene fatty acid, glycerin fatty
Acid esters, polyglyceryl fatty acid ester, polyglyceryl fatty acid ester, sorbitan aliphatic ester, polyoxyethylenesorbitans rouge
Fat acid esters, sucrose fatty ester, polyoxyethylene alkyl ether, polyoxyethylene alkyl phenyl ether, polyglycerol alkyl ether, polyoxyethylene
(hydrogenation) castor oil, fatty acid alkanol amides etc..Hair dyeing feed composition of the invention includes the feelings of nonionic surface active agent
Under condition, the content of the nonionic surface active agent in 100 mass % of hair dyeing feed composition of the invention is not particularly limited, from
It sets out in terms of ageing stability, preferably 0.5~10.0 mass %, more preferably 1.0~5.0 mass %.Above-mentioned nonionic
The content of type surfactant is the total of the content of whole nonionic surface active agent in hair dyeing feed composition of the invention
Amount.
The case where hair dyeing feed composition of the invention is any in Rinsing stain, hair care stain and hair maintenance agent
Under, hair dyeing feed composition of the invention includes water.Water is not particularly limited, preferably pure water.Hair dyeing feed composition of the invention
The content of water in 100 mass % is not particularly limited, preferably 50.0~90.0 mass %, more preferably 60.0~80.0 matter
Measure %.
The case where hair dyeing feed composition of the invention is any in Rinsing stain, hair care stain and hair maintenance agent
Under, hair dyeing feed composition of the invention may include the fresheners such as l-menthol, 1,8- cineole, camphor；Phenoxetol etc.
Preservative；The vegetable oil such as olive oil, macadimia nut oil, argan oil；The hygroscopic agents such as silica；Hyaluronic acid or its spread out
Biology, collagen or derivatives thereof, amino acid or derivatives thereof, antioxidant, chelating agent, vitamins, animals and plants are extracted
Object, pearling agent, colorant, fragrance etc..
Hereinafter, being illustrated to preferred optional member when hair dyeing feed composition of the invention is shampoo stain.
In the case that hair dyeing feed composition of the invention is shampoo stain, from cleaning aspect, dye of the invention
Material issuance composition include selected from by anionic surfactant (anionic surfactant), cationic surface active agent,
The surfactant of one or more of the group of nonionic surface active agent and amphoteric surfactant composition is (at least one
Surfactant).Wherein, from from the aspect of remaining chromatic while improving cleaning, preferably non-ionic surface is living
Property agent and/or amphoteric surfactant.The content of surfactant in 100 mass % of hair dyeing feed composition of the invention does not have
It is particularly limited to, from dyeability and cleaning aspect, preferably 1.0~20.0 mass %, more preferably 5.0~15.0 matter
Measure %.The content of above-mentioned surfactant is the total of the content of all surfaces activating agent in hair dyeing feed composition of the invention
Amount.
As above-mentioned anionic surfactant, it can be cited for example that: lauryl sodium sulfate, dodecyl sulphate three
The alkyl sulfates such as ethanol amine, sodium tetradecyl sulfate, sodium stearyl sulfate, oleyl sodium sulphate, sodium hexadecyl sulfate
Salt；The polyoxyethylene alkyl ether sulfate salts such as sodium laureth sulfate, polyoxyethylene myristyl ether sodium sulfate；14
The alpha-alkene sulfonates such as carbene sodium sulfonate；Myristoyl methyl sodium taurocholate, palmitoyl methyl taurine sodium, stearoyl methyl ox
The N- acyl methyl taurine salts such as sodium sulfonate, oleoyl N-methyltaurine sodium, coconut fatty acid methyl sodium taurocholate；Sulfosuccinate
The sulfosuccinates alkyl ester salts such as dioctyl ester sodium salt, sulfosuccinate lauryl disodium salt；Sulfosuccinate polyoxyethylene laural
The sulfosuccinates polyxyethylated ester salt such as ester disodium salt；Ferric tri-dodecanesulfonate, cetyl sodium phosphate, cetyl phosphorus
The alkylphosphonates such as sour diethanol amine；Polyoxyethylene lauryl ether sodium phosphate, polyoxyethylene cetyl base ether sodium phosphate, polyoxy
Ethylene oleyl ether phosphoric acid sodium, polyoxyethylene alkyl phenyl ether sodium phosphate, polyoxyethylene alkyl phenyl ether nitranol etc.
Polyoxyethylene alkyl ether phosphate salt；Potassium lauroyl sarcosine, Hamposyl L triethanolamine, myristoyl-N-methylaminoacetic acid sodium,
The N- acyl sarcosinates such as fatty acid distribution of coconut oil sodium sarcosinate；Lauroyl methyl Sodium L-alaninate, three ethyl alcohol of lauroyl methyl alanine
The N- such as amine, myristoyl methyl Sodium L-alaninate, coconut fatty acid methyl Sodium L-alaninate acyl-N-methyl-Beta-alanine salt；Laurel
Acyl sodium glutamate, lauroyl glutamate triethanolamine, myristoyl glutamate sodium, stearoyl-glutamic acid potassium, stearoyl-glutamic acid
The N- acyl glutamates such as disodium, fatty acid distribution of coconut oil acyl glutamic acid sodium, fatty acid distribution of coconut oil acyl glutamic acid triethanolamine；Cocounut oil
The N- acylglycine salt such as fatty acid acyl glycine potassium, fatty acid distribution of coconut oil acylglycine sodium；Propylene glycol laurate sodium acetate (ten
Dioxane -1,2- glycol sodium acetate), Propylene glycol laurate potassium acetate, myristyl glycol sodium acetate, myristyl glycol potassium acetate,
Palmityl glycol sodium acetate, palmityl glycol potassium acetate, stearyl glycol sodium acetate, stearyl glycol potassium acetate, behenyl base two
Alkyl ethers glycol acetates such as alcohol sodium acetate, behenyl base glycol potassium acetate etc..Wherein, from chromatic aspect, preferably N-
The anionic surfactant of the origin of amino acid such as acyl-N-methyl-Beta-alanine salt, N- acyl glutamate.The present invention
Hair dyeing feed composition include anionic surfactant in the case where, in 100 mass % of hair dyeing feed composition of the invention
The content of anionic surfactant be not particularly limited, from dyeability and cleaning aspect, preferably 0.5~
5.0 mass %, more preferably 0.5~2.0 mass %.The content of above-mentioned anionic surfactant is hair dye of the invention
The total amount of the content of whole anionic surfactant in composition.
As above-mentioned amphoteric surfactant, it can be cited for example that: lauric amide propyl betaine, fatty acid distribution of coconut oil acyl
The alkyl amido betaines type amphoteric surfactant such as amine propyl betaine；Alkyl glycine salt, carboxymethyl glycinate, N- acyl
The glycine type amphoterics such as base amino-ethyl-N-2- hydroxyethyl glycinate；Alkyl aminopropionic acid salt, alkyl are sub-
The aminopropans acid type amphoteric surfactant such as amino dipropionate；Alkyl dimethyl oxyneurine, alkylamide propyl
The oxyneurines type amphoteric surface such as dimethylaminoethyl acid glycine betaine, alkyl dihydroxyethyl oxyneurine is living
Property agent；N- alkyl-N, N- dimethyl ammonium-N- propyl sulfonic acid salt, N- alkyl-N, N- dimethyl ammonium-N- (2- hydroxypropyl) sulfonic acid
The sulphurs such as salt and N- fatty acid amide propyl-N, N- dimethyl ammonium-N- (2- hydroxypropyl) sulfonate, alkyl hydroxy sulfobetaines
Base betaine type amphoteric surfac-tant；The imidazoline types amphoteric surfaces such as alkyl carboxy methyl hydroxyethyl imidazolinium betaine are living
Property agent etc..Wherein, from cleaning aspect, optimizing alkyl amide betaine type amphoteric surfactant.Dye of the invention
Both sexes table in the case that material issuance composition includes amphoteric surfactant, in hair dyeing 100 mass % of feed composition of the invention
The content of face activating agent is not particularly limited, and from cleaning aspect, preferably 1.0~20.0 mass %, is more preferably
5.0~15.0 mass %.The content of above-mentioned amphoteric surfactant is whole both sexes tables in hair dyeing feed composition of the invention
The total amount of the content of face activating agent.
As above-mentioned nonionic surface active agent, can enumerate as hair dyeing feed composition of the invention is Rinsing dye
Agent, hair care stain and hair maintenance agent in it is any when optional member illustrated by nonionic surface active agent.Its
In, from the aspect for assigning viscosity, preferred fatty acid alkanolamide.Hair dyeing feed composition of the invention includes non-ionic table
In the case where the activating agent of face, the content of the nonionic surface active agent in 100 mass % of hair dyeing feed composition of the invention does not have
It is particularly limited to, from the aspect for assigning viscosity, preferably 0.5~10.0 mass %, more preferably 1.0~5.0 mass %.
The content of above-mentioned nonionic surface active agent is whole nonionic surface active agent in hair dyeing feed composition of the invention
Content total amount.
As above-mentioned cationic surface active agent, can enumerate as cationic surfactant illustrated by ingredient E
Agent.Wherein, from the aspect of the hair texture after improving use, preferably stearyl trimethyl ammonium chloride, behenyl base trimethyl
Ammonium chloride, alkyl (16,18) trimethyl ammonium chloride, alkyl (20~22) trimethyl ammonium chloride.Hair dyeing feed composition of the invention
Cationic in the case where comprising cationic surface active agent, in hair dyeing 100 mass % of feed composition of the invention
The content of activating agent is not particularly limited, the texture aspect of the hair after using, preferably 0.1~5.0 mass %,
More preferably 0.5~3.0 mass %.The content of above-mentioned cationic surface active agent is in hair dyeing feed composition of the invention
The total amount of the content of whole cationic surface active agents.
In the case that hair dyeing feed composition of the invention is shampoo stain, hair dyeing feed composition of the invention includes water.Water
It is not particularly limited, preferably pure water.The content of water in 100 mass % of hair dyeing feed composition of the invention does not limit especially
It is fixed, preferably 50.0~90.0 mass %, more preferably 60.0~80.0 mass %.
In the case that hair dyeing feed composition of the invention is shampoo stain, hair dyeing feed composition of the invention may include l-
The fresheners such as menthol, 1,8- cineole, camphor；The preservatives such as phenoxetol；Olive oil, macadimia nut oil, Morocco are hard
The vegetable oil such as fruit oil；The hygroscopic agents such as silica；Hyaluronic acid or derivatives thereof, collagen or derivatives thereof, amino acid or
Its derivative, antioxidant, chelating agent, vitamins, animal and plant extracts, pearling agent, colorant, fragrance etc..
Hereinafter, the feature and manufacturing method to hair dyeing feed composition of the invention are illustrated.
The manufacturing method of hair dyeing feed composition of the invention is not particularly limited, and can be manufactured according to conventional methods.
Specifically, the following method etc. can be enumerated.For example, in the case where Rinsing stain or hair care stain, to be heated to 70~
90 DEG C and dissolve it sufficiently water phase in be slowly added into and be heated to 70~90 DEG C of oily phase, be sufficiently stirred 5 minutes, carry out cream
Change.It is cooled to 20~40 DEG C after emulsification, the dyestuff being dissolved in pure water is added, after full and uniform stirring, pH adjusting agent is added,
Full and uniform stirring obtains cream hair dyeing feed composition paste.In the case where shampoo stain, make dyestuff sufficiently molten at normal temperature
Solution, various surfactants are slowly added into obtained water phase and are stirred, and stabilizer, pH adjusting agent is added, fills
Divide uniform stirring, obtains the hair dyeing feed composition for having sticking liquid.
The pH of hair dyeing feed composition of the invention is not particularly limited, from chromatic aspect, preferably 4.0~
8.0,5.0~8.0 are more preferably.In addition, from hair dyeing feed composition stability aspect, above-mentioned pH be preferably 6.5 with
Under.In particular, pH is preferred in the case where hair dyeing feed composition of the invention is Rinsing stain, hair care stain, hair maintenance agent
It is 4.0~6.5, in the case where shampoo stain, pH is preferably 5.0~6.5.
The dosage form of hair dyeing feed composition of the invention is not particularly limited, it can be cited for example that liquid, viscous fluid, gel
Shape, emulsion form, emulsifiable paste shape etc..Wherein, from dyeability and texture aspect, preferably emulsifiable paste shape.
Hair dyeing feed composition of the invention can be by coloring hairs grey, black, brown, green, bluish violet etc..It is more excellent
It is selected as grey, black, brown, further preferably grey.It therefore, can be as the hair dye of white hair hair dyeing, fashion hair dyeing etc.
Composition comes using from tone aspect, preferably the hair dyeing feed composition of white hair hair dyeing.
Hair dyeing feed composition of the invention is preferably Rinsing stain or hair care stain, hair maintenance agent or shampoo stain.
Above-mentioned shampoo stain is the cleaning agent of the hair used in hair washing, and the dye of hair can be carried out while hair washing
Color.Above-mentioned shampoo stain with following application methods come using: be applied to hair and blister, hair is cleaned, clean it is laggard
Row rinses.
In addition, above-mentioned Rinsing stain and hair care stain are usually used in hair washing, it is to be applied on hair after having one's hair wash, later
The hair treating agent for rinsing and using.Above-mentioned Rinsing stain and hair care stain with following application methods come using: with shampoo to hair
Hair is cleaned, and Rinsing stain or hair care stain are applied on hair later, rinse immediately after coating or merge 3 with hair~
It is rinsed after 10 minutes or so.It should be noted that above-mentioned Rinsing stain and hair care stain can also be used before hair washing.It should
In the case of, above-mentioned Rinsing stain and hair care stain with following application methods come using: Rinsing stain is coated on wet hair
Or hair care stain, it rinses after coating or is rinsed after merging 3~10 minutes or so with hair immediately, and then washed with shampoo
Hair.
Above-mentioned hair maintenance agent is the hair treating agent for being typically applied to use on dry hair.Above-mentioned hair maintenance
Agent for example with following application methods come using: hair maintenance agent is applied on dry hair, is placed 5~30 minutes after coating
It is rinsed behind left and right, and then is had one's hair wash with shampoo.
Embodiment
Hereinafter, based on embodiment, the present invention will be described in more detail, but the present invention is not limited to these embodiments.
It should be noted that the blend amount recorded in table is the blend amount of each ingredient (that is, the blend amount of the effective component in each raw material.
So-called pure ingredient), unless otherwise specified, otherwise indicated with " quality % ".Wherein, the polychloride dimethylated methylene phenylpiperidines in table
The blend amount of liquid and aminoethylaminopropyl siloxanes dimethylsiloxane copolymer lotion is with the mixture of commodity itself
Amount is to indicate.
Embodiment 1-1~1-22, comparative example 1-1~1-9: Rinsing stain (or hair care stain)
According to the composition recorded in Tables 1 and 2, each hair dyeing feed composition is prepared, the evaluation examination for following tests 1~6
It tests.Above-mentioned each hair dyeing feed composition is Rinsing stain (or hair care stain).Evaluation result is remembered in table together.
Embodiment 2-1~2-3: shampoo stain
According to the composition recorded in table 3, each hair dyeing feed composition is prepared, the evaluation test for following tests 1~6.On
Stating each hair dyeing feed composition is shampoo stain.Evaluation result is remembered in table together.
The pH of each hair dyeing feed composition of embodiment and comparative example utilizes pH meter (Horiba Ltd's manufacture, quotient
The name of an article " desk-top pH meter F-74 ") it is measured.
[test 1: chromatic evaluation]
As test pieces, the scared beam of untreated white person (Co., Ltd. B eaulax manufacture, length have been used
10cm, weight 1g).
(the evaluation preparation of pieces: the case where Rinsing stain)
Test is cleaned with pieces with commercially available shampoo, slightly removes moisture later, is used for preparation below.It will
The feed composition 0.5g that respectively has hair dyed obtained in embodiment and comparative example after manufacture soon is applied on above-mentioned test pieces, is used
Comb makes it overall fusion 1 minute with pieces (hair).Next, placing after five minutes, combined hair dye with 40 DEG C of warm water
Object is fully rinsed out from pieces, sufficiently dry with hair dryer after towel, prepares evaluation pieces.
(the evaluation preparation of pieces: the case where shampoo stain)
After sufficiently cleaning test pieces with 40 DEG C of warm water, it to be used for preparation below.By the embodiment after manufacture soon
It is applied on above-mentioned test pieces with the feed composition 0.2g that respectively has hair dyed obtained in comparative example, so that it is blistered 1 minute with hand, into
Row fusion.Next, placing after five minutes, hair dyeing feed composition is fully rinsed out from pieces with 40 DEG C of warm water, with hair
It is sufficiently dry with hair dryer after towel is dried, prepare evaluation pieces.
Evaluation pieces obtained above is observed, according to benchmark evaluation dyeability below.It should be noted that dyeability
Evaluation carried out by 4 professional judging panels.
<chromatic evaluation criteria>
◎ (excellent): it dyes very densely.
Zero (good): sufficiently dyeing.
× (poor): dyeing is shallow.
In addition, the tone of evaluation pieces obtained in test 1 is shown in table.
[test 2: the evaluation of skin contamination (dyeability)]
By after manufacture soon embodiment and comparative example obtained in the feed composition 0.5g that respectively has hair dyed be respectively coated to forearm
The border circular areas of the diameter 1cm of inside portion.It places after five minutes, with warm water washing coating part, is then gently rubbed with the hands with soap 30 seconds, with temperature
Water rinses.
Above-mentioned coating part is observed, is evaluated according to benchmark below.It should be noted that the evaluation of skin contamination is by 4
Position professional judging panel carries out.
<evaluation criteria of skin contamination>
◎ (excellent): skin contamination does not remain completely.
Zero (good): skin contamination slightly remains.
× (poor): skin contamination obviously remains.
[test 3: the evaluation of fastness]
After the evaluation for testing 1 (chromatic evaluation), each evaluation pieces, Zhi Houyong are sufficiently cleaned with 40 DEG C of warm water
Commercially available shampoo is sufficiently cleaned 1 minute.In addition, the warm water with 40 DEG C is sufficiently rinsed, after towel, filled with hair dryer
Divide drying.
Evaluation pieces obtained above is observed, according to benchmark evaluation fastness below.It should be noted that fastness
Evaluation carried out by 4 professional judging panels.
<evaluation criteria of fastness>
Zero (good): the colour fading of hair is small after test.
× (poor): the colour fading of hair is big after test.
[test 4: the evaluation that discoloration when standing time extends inhibits]
In the preparation of evaluation pieces for testing 1 (chromatic evaluation), it " will place 5 minutes " and be changed to " place 30
Minute ", evaluation pieces has been prepared as with test 1 in addition to this.
For each embodiment, each comparative example, the evaluation prepared in the evaluation pieces prepared in test 4 and test 1 is used
Tone after the dyeing of pieces compares, the degree that discoloration when extending according to benchmark evaluation standing time below inhibits.
It should be noted that evaluation is carried out by 4 professional judging panels.
<evaluation criteria that discoloration when standing time extends inhibits>
Zero (good): compared with the tone of the evaluation pieces prepared in test 1, the evaluation pieces prepared in 4 is tested
Tone absolutely not change.
× (poor): compared with the tone of the evaluation pieces prepared in test 1, the evaluation pieces prepared in 4 is tested
Tone changes.
[table 3]
(table 3) shampoo stain
The blend amount of (*) citric acid is the amount being adjusted in such a way that hair dyeing feed composition is pH5.
[test 5: sunproof evaluation]
After the evaluation for testing 1 (chromatic evaluation), strong xenon fadometer (the SUGA TEST of the testing machine of resistance to fastness is used
The manufacture of INSTRUMENTS Co., Ltd., trade name " Xenon weather meter X-25 "), with 6300kJ/m2Condition pair
Each evaluation pieces irradiation light.
Evaluation pieces obtained above is observed, according to benchmark evaluation light resistance below.It should be noted that light resistance
Evaluation carried out by 4 professional judging panels.
<sunproof evaluation criteria>
Zero (good): compared with the tone of the evaluation pieces prepared in test 1, the evaluation pieces prepared in 5 is tested
Tone do not change completely or nearly.
Δ (slightly poor): compared with the tone of the evaluation pieces prepared in test 1, the evaluation pieces prepared in 5 is tested
Tone change significantly.
× (poor): compared with the tone of the evaluation pieces prepared in test 1, the evaluation pieces prepared in 5 is tested
Tone has very big variation.
Test 5 (sunproof evaluations) as a result, the light resistance of embodiment 1-19 is slightly poor (Δ), embodiment 1-12 and compare
The light resistance of example 1-9 is poor (×).Other embodiments, the light resistance of comparative example are good (〇).
[test 6: the evaluation for damaging the irregular colour of hair]
In the preparation of evaluation pieces for testing 1 (chromatic evaluation), by " the untreated scared beam (strain of white person
Formula commercial firm Beaulax manufacture, length 10cm, weight 1g) " it is changed to " pieces (Co., Ltd.'s STAFFS system through bleaching
Make, grade 14, length 10cm, weight 1g) ", evaluation pieces has been prepared as with test 1 in addition to this.
Evaluation pieces obtained above is observed, according to benchmark evaluation below for the irregular colour of damage hair.It needs
It is noted that the evaluation for the irregular colour for damaging hair is carried out by 4 professional judging panels.
<for damaging the evaluation criteria of the irregular colour of hair>
Zero (good): pieces integrally equably dyes.
× (poor): pieces does not dye equably integrally, and there are irregular colours.
Test 6 (for damaging the evaluations of the irregular colour of hair) as a result, in comparative example 1-1 and comparative example 1-2, for
The irregular colour for damaging hair is poor (×).It is good for the irregular colour for damaging hair in other embodiments, comparative example
(○)。
It should be noted that the ingredient recorded in table is as follows.
The manufacture of alkali blue 124:BASF company, trade name " Vibracolor Moonlight Blue "
Blue 75: Baotugu Chemical Industrial Co., Ltd's manufacture, trade name " AHC BLUE SP "
The manufacture of Basic Orange 31:BASF company, trade name " Vibracolor Flame Orange "
The red 51:BASF company manufacture of alkalinity, trade name " Vibracolor Ruby Red "
The red 76:Sensient Technologies Japan Co., Ltd. manufacture of alkalinity, trade name " ARIANOR
MADDER RED”
The manufacture of basic yellow 87:BASF company, trade name " Vibracolor Citrus Yellow "
The manufacture of basic yellow 57:Sensient Technologies Japan Co., Ltd., trade name " ARIANOR STRAW
YELLOW”
The manufacture of HC indigo plant 2:Teluca company, trade name " COLOREX HCB2 "
The manufacture of HC Huang 2:Teluca company, trade name " COLOREX HCY2 "
The manufacture of HC Huang 4:Teluca company, trade name " COLOREX HCY4 "
Stearyl alcohol: Kao Corp's manufacture, trade name " KALCOL 8688 "
Cetanol: Kao Corp's manufacture, trade name " KALCOL 6870 "
Alkyl trimethyl ammonium chloride: the manufacture of Clariant Amada Co., Ltd., trade name " GENAMIN KDMP-J "
Stearyl trimethyl ammonium chloride: Kao Corp's manufacture, trade name " QUARTAMIN 86W "
Stearic acid dimethylaminopropyl amide: Nikko Chemicals Co., Ltd's manufacture, trade name " NIKKOL amide amine MPS "
Polyoxyethylene cetyl ether (5E.O.): the manufacture of green wood oil rouge Industrial Co., Ltd, trade name " Blaunon CH-
305”
Polyoxyethylene cetyl ether (20E.O.): the manufacture of green wood oil rouge Industrial Co., Ltd, trade name " Blaunon
CH-320L”
Atoleine: Sonneborn Inc manufacture, trade name " CARNATION "
Dipropylene glycol: Asahi Glass Co., Ltd's manufacture, trade name " dipropylene glycol DPG-FC "
Polypropylene glycol: Sanyo Chemical Industries, Ltd.'s manufacture, trade name " Sanix PP-400 "
2- ethyl hexyl olefin(e) acid cetyl ester: the manufacture of Nihon surfactant kogyo Co., Ltd., trade name " CIO-
N”
Glycerol decanoate: Sun Chemical Co., Ltd.'s manufacture, trade name " Sunsoft 760-C "
Polychloride dimethylated methylene phenylpiperidines liquid: the manufacture of NALCO company, trade name " マ ー U ー ト 100 ", pure ingredient
40 mass %
Chlorination O- [2- hydroxyl -3- (trimethyl ammonium) propyl] hydroxyethyl cellulose: Toho Chemical Industry Co., Ltd.'s system
It makes, trade name " Catinal HC-100 "
Methyl polysiloxane: the manufacture of Dow Corning Toray Co., Ltd., trade name " DOW CORNING TORAY
SH200 C FLUID 20CS”
Aminoethylaminopropyl siloxanes dimethylsiloxane copolymer lotion: Toray plants of formulas of Dow Corning
Commercial firm's manufacture, trade name " DOW CORNING TORAY SM8704C ", 40 mass % of pure ingredient
Lauroyl methyl-Beta-alanine sodium: Kawaken Fine Chemicals Co., Ltd. manufacture, trade name
“ALANON ALE”
N- fatty acid distribution of coconut oil acyl group-Pidolidone triethanolamine: Asahi Chemical Corp's manufacture, trade name
“AMINOSURFACT ACMT-L”
Lauric amide propyl betaine: New Japan Chem Co., Ltd's manufacture, trade name " RIKABION B-300 "
Fatty acid distribution of coconut oil amido propyl betaine: New Japan Chem Co., Ltd's manufacture, trade name " RIKABION B-
200”
Fatty acid distribution of coconut oil N- methyl ethanol amide: Kao Corp's manufacture, trade name " AMINON C-11S "
In addition, the Formulation Example of hair dyeing feed composition of the invention described below.
(Formulation Example 1) Rinsing stain (emulsifiable paste)
(Formulation Example 2) Rinsing stain (lotion)
(Formulation Example 3) hair maintenance agent (gel)
(Formulation Example 4) shampoo stain
(Formulation Example 5) shampoo stain
(Formulation Example 6) Rinsing stain (emulsifiable paste)
(Formulation Example 7) Rinsing stain (emulsifiable paste)
Industrial applicibility
Hair dyeing feed composition of the invention is the composition used as hair dye.As above-mentioned hair dye, can enumerate
Rinsing stain, hair care stain, hair maintenance agent, shampoo stain etc..
Claims (6)
1. a kind of hair dyeing feed composition, containing following compositions A, following compositions B, following compositions C and following compositions D,
Ingredient A: dyestuff shown in following formula (1)；
[changing 1]
Ingredient B: selected from one by Basic Orange 31, in the group that alkalinity is red 51, alkalinity is red 76, basic yellow 87 and basic yellow 57 form
Kind or more dyestuff；
Ingredient C:HC indigo plant 2；
Ingredient D: the dyestuff selected from one or more of the group being made of HC 4 and HC of Huang Huang 2.
2. hair dyeing feed composition as described in claim 1, wherein
The content of the ingredient A is 0.005~0.5 mass %,
The content of the ingredient B is 0.005~1.5 mass %,
The content of the ingredient C is 0.1~1.5 mass %,
The content of the ingredient D is 0.01~0.5 mass %.
3. hair dyeing feed composition as claimed in claim 1 or 2, wherein
The content of the ingredient B is 0.1~10.0 relative to the mass ratio of the content of the ingredient A, i.e. ingredient B/ ingredient A,
The content of the ingredient D is 0.005~1.0 relative to the mass ratio of the content of the ingredient C, i.e. ingredient D/ ingredient C,
The content of the ingredient C is 1.5~70.0 relative to the mass ratio of the content of the ingredient A, i.e. ingredient C/ ingredient A.
4. hair dyeing feed composition according to any one of claims 1 to 3, wherein the institute in the 100 mass % of ingredient D
The content for stating HC Huang 2 is 50.0 mass % or more.
5. hair dyeing feed composition as described in any one of claims 1 to 4 is Rinsing stain or hair care stain.
6. hair dyeing feed composition as claimed in claim 5, further contains following compositions E,
Ingredient E: selected from one or more of the group being made of cationic surface active agent, cation property copolymer and silicone oil
Ingredient.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2017066453 | 2017-03-29 | ||
| JP2017-066453 | 2017-03-29 | ||
| PCT/JP2018/010099 WO2018180515A1 (en) | 2017-03-29 | 2018-03-15 | Hair dye composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN109562047A true CN109562047A (en) | 2019-04-02 |
| CN109562047B CN109562047B (en) | 2021-12-14 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201880003070.9A Active CN109562047B (en) | 2017-03-29 | 2018-03-15 | Hair dye composition |
Country Status (4)
| Country | Link |
|---|---|
| JP (1) | JP6800313B2 (en) |
| KR (1) | KR102195213B1 (en) |
| CN (1) | CN109562047B (en) |
| WO (1) | WO2018180515A1 (en) |
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|---|---|---|---|---|
| JP7213533B2 (en) * | 2018-12-27 | 2023-01-27 | 日本メナード化粧品株式会社 | hair dye composition |
| JP7244057B2 (en) * | 2019-01-31 | 2023-03-22 | ホーユー株式会社 | Hair dye composition and hair dyeing method |
| JP7181599B2 (en) * | 2019-02-25 | 2022-12-01 | 株式会社ダリヤ | hair dye composition |
| JP2021134210A (en) | 2020-02-27 | 2021-09-13 | 保土谷化学工業株式会社 | Dye for hair coloration, composition for hair coloration containing the dye, and method for producing the dye |
| JP7504548B2 (en) | 2021-02-15 | 2024-06-24 | 株式会社マンダム | Hair dye composition |
Citations (4)
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|---|---|---|---|---|
| CN102333515A (en) * | 2009-02-25 | 2012-01-25 | 巴斯夫欧洲公司 | Hair dyeing composition |
| JP2012246284A (en) * | 2011-05-30 | 2012-12-13 | Japan Biochemical Co Ltd | Hairdye |
| WO2016026710A1 (en) * | 2014-08-21 | 2016-02-25 | Alfa Parf Group S.P.A. | Cosmetic composition for keratin fibres |
| US20160122546A1 (en) * | 2014-11-04 | 2016-05-05 | The Procter & Gamble Company | Azo direct dyes and method for dyeing hair using these dyes |
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|---|---|---|---|---|
| DE102005013488A1 (en) * | 2005-03-21 | 2006-09-28 | Henkel Kgaa | Agent, useful for simultaneous dyeing and brightening of human hair, comprises a direct dye comprising e.g. thionin, 4-amino-2-nitrophenol, 1,5-diphenylthiocarbazone and 4-(2-thiazolylazo)resorcinol, and a carbonate and/or its precursor |
| JP2009073773A (en) * | 2007-09-21 | 2009-04-09 | Alpen Sogo Kenkyusho:Kk | Composition for hair-scalp and hair treatment, color treatment, pore-cleaning agent, shampoo and soap comprising the same composition for hair-scalp |
| CN102333516A (en) | 2009-02-25 | 2012-01-25 | 巴斯夫欧洲公司 | Hair dyeing composition |
| JP5981317B2 (en) | 2012-11-16 | 2016-08-31 | ホーユー株式会社 | Hair dye composition |
| ITUB20151795A1 (en) * | 2015-07-02 | 2017-01-02 | Alfa Parf Group Spa | METHOD FOR COLORING KERATINIC FIBERS |
| JP2017031085A (en) * | 2015-07-31 | 2017-02-09 | 株式会社Ｂｅｒｒｙ２ | Hair brightness improving agents and hair color adjusting agents using hair brightness improving agents, as well as methods for improving hair brightness and methods for adjusting hair color |
| JP6846900B2 (en) * | 2015-09-25 | 2021-03-24 | 株式会社マンダム | Wool dye composition |
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2018
- 2018-03-15 WO PCT/JP2018/010099 patent/WO2018180515A1/en active Application Filing
- 2018-03-15 KR KR1020197003416A patent/KR102195213B1/en active IP Right Grant
- 2018-03-15 CN CN201880003070.9A patent/CN109562047B/en active Active
- 2018-03-15 JP JP2019509234A patent/JP6800313B2/en active Active
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| CN102333515A (en) * | 2009-02-25 | 2012-01-25 | 巴斯夫欧洲公司 | Hair dyeing composition |
| JP2012246284A (en) * | 2011-05-30 | 2012-12-13 | Japan Biochemical Co Ltd | Hairdye |
| WO2016026710A1 (en) * | 2014-08-21 | 2016-02-25 | Alfa Parf Group S.P.A. | Cosmetic composition for keratin fibres |
| US20160122546A1 (en) * | 2014-11-04 | 2016-05-05 | The Procter & Gamble Company | Azo direct dyes and method for dyeing hair using these dyes |
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Also Published As
| Publication number | Publication date |
|---|---|
| JP6800313B2 (en) | 2020-12-16 |
| JPWO2018180515A1 (en) | 2019-11-07 |
| WO2018180515A1 (en) | 2018-10-04 |
| KR20190027850A (en) | 2019-03-15 |
| KR102195213B1 (en) | 2020-12-24 |
| CN109562047B (en) | 2021-12-14 |
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