CN109553829A - A kind of antistatic elastic composition - Google Patents

A kind of antistatic elastic composition Download PDF

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Publication number
CN109553829A
CN109553829A CN201811245621.0A CN201811245621A CN109553829A CN 109553829 A CN109553829 A CN 109553829A CN 201811245621 A CN201811245621 A CN 201811245621A CN 109553829 A CN109553829 A CN 109553829A
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CN
China
Prior art keywords
parts
antistatic
elastic composition
antistatic elastic
volume resistivity
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201811245621.0A
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Chinese (zh)
Inventor
金建民
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
SHANGHAI WUTONG SYNCHRONOUS BELT CO Ltd
Original Assignee
SHANGHAI WUTONG SYNCHRONOUS BELT CO Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Publication date
Application filed by SHANGHAI WUTONG SYNCHRONOUS BELT CO Ltd filed Critical SHANGHAI WUTONG SYNCHRONOUS BELT CO Ltd
Priority to CN201811245621.0A priority Critical patent/CN109553829A/en
Publication of CN109553829A publication Critical patent/CN109553829A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L11/00Compositions of homopolymers or copolymers of chloroprene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2217Oxides; Hydroxides of metals of magnesium
    • C08K2003/222Magnesia, i.e. magnesium oxide
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2296Oxides; Hydroxides of metals of zinc
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/002Physical properties
    • C08K2201/003Additives being defined by their diameter
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/002Physical properties
    • C08K2201/004Additives being defined by their length
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/04Antistatic

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The invention discloses a kind of antistatic elastic compositions, which is characterized in that including following parts by weight of component: 70~80 parts of neoprene;20~30 parts of nitrile rubber;15~25 parts of filler;2.0~6. parts of multi-walled carbon nanotube;30 parts of acetylene carbon black;6 parts of zinc oxide;4 parts of magnesia;2 parts of stearic acid;3 parts of anti-aging agent;1.6~3.6 parts of vulcanizing agent;Wherein, it referring to the antistatic measurement standard with conductive articles resistance of GB/T 11210-2014 vulcanized rubber or thermoplastic elastomer, is detected using digital electrometer DDK59-T103, result is that volume resistivity is 105~150 Ω .cm.The present invention protects sensitive electronic components not by electrostatic damage;Risk of explosion is reduced when conveying explosive material;Exempt dust in the accumulation of synchronous belt surface;Keep working environment cleaner.Conductive material is evenly distributed in rubber, good antistatic property is reached.Its volume resistivity is 105~150 Ω .cm.It is that one kind is antistatic, wear-resisting, ageing-resistant elastomer can be applied to antistatic drive belt.

Description

A kind of antistatic elastic composition
Technical field
The present invention relates to field of material processings, and in particular to a kind of antistatic elastic composition.
Background technique
Currently, the existing coefficient of friction when being driven operation of the transmission belt for machine power transmitting is bigger, Er Qiehui Cause transmitting power heavy losses;And its because elasticity it is poor, after prolonged use, be easily broken off or further decrease and be driven Frictional force between mechanism, and further resulted in because of electrostatic accident occurs when the problem of electrostatic also results in transmission Production accident.
Summary of the invention
In order to overcome drawbacks described above present in the prior art, the purpose of the present invention is to provide a kind of antistatic elasticity Body composition.
In order to achieve the object of the present invention, used technical solution is:
A kind of antistatic elastic composition, including following parts by weight of component:
Wherein, referring to the antistatic survey with conductive articles resistance of GB/T 11210-2014 vulcanized rubber or thermoplastic elastomer Calibration is quasi-, is detected using digital electrometer DDK59-T103, result is that volume resistivity is 105~150 Ω .cm.
In a preferred embodiment of the invention, the neoprene is PM-40 type, and the nitrile rubber is 1502 Type.
In a preferred embodiment of the invention, the anti-aging agent is N (1,3- dimethylbutyl)-N/- phenyl to benzene Any one in diamines, 2,2,4- trimethyl -1,2- dihyaroquinoline condensate or two or more mixing.
In a preferred embodiment of the invention, the vulcanizing agent is sub- second epithio urea, N, N- dicyclohexyl -2- benzo Any one in thiazolesulfenamide, sulphur or two or more mixing.
In a preferred embodiment of the invention, the filler is that graphite plates nickel particle, silvered aluminum powder, silica 5: The mixture of 3:2.
In a preferred embodiment of the invention, the multi-walled carbon nanotube is GT-350, wherein purity 97%, Caliber is 12-15nm, and length is 0.5-5 μ, number of plies 8-15.
The beneficial effects of the present invention are:
Protect sensitive electronic components not by electrostatic damage;Risk of explosion is reduced when conveying explosive material;Exempt dust same Walk the accumulation of belt surface;Keep working environment cleaner.
Conductive material is evenly distributed in rubber, good antistatic property is reached.Its volume resistivity be 105~ 150Ω.cm.It is that one kind is antistatic, wear-resisting, ageing-resistant elastomer can be applied to antistatic drive belt.
Specific embodiment
The present invention is further illustrated by the following examples, but these embodiments must not be used to explain to the present invention Limitation.
Embodiment 1
Following raw material is weighed by weight:
Referring to the antistatic measurement mark with conductive articles resistance of GB/T 11210-2014 vulcanized rubber or thermoplastic elastomer Standard is detected using digital electrometer DDK59-T103, and result is that volume resistivity is 145.cm.
The testing result of embodiment 1 is referring to table 1.
Table 1
Project Actual measurement
Hardness (Shao Er A) 69
Tensile strength (mpa) 14.5
Extensibility (%) 373
Embodiment 2
Following raw material is weighed by weight:
Referring to the antistatic measurement mark with conductive articles resistance of GB/T 11210-2014 vulcanized rubber or thermoplastic elastomer Standard is detected using digital electrometer DDK59-T103, and result is that volume resistivity is 138 Ω .cm.
The testing result of embodiment 2 is referring to table 2.
Table 2
Project Actual measurement
Hardness (Shao Er A) 74
Tensile strength (mpa) 15.5
Extensibility (%) 322
Embodiment 3
Following raw material is weighed by weight:
Referring to the antistatic measurement mark with conductive articles resistance of GB/T 11210-2014 vulcanized rubber or thermoplastic elastomer Standard is detected using digital electrometer DDK59-T103, and result is that volume resistivity is 115 Ω .cm.
The testing result of embodiment 3 is referring to table 3.
Table 3
Project Actual measurement
Hardness (Shao Er A) 73
Tensile strength (mpa) 15.7
Extensibility (%) 335

Claims (6)

1. a kind of antistatic elastic composition, which is characterized in that including following parts by weight of component:
Wherein, referring to the antistatic measurement mark with conductive articles resistance of GB/T 11210-2014 vulcanized rubber or thermoplastic elastomer Standard is detected using digital electrometer DDK59-T103, and result is that volume resistivity is 105~150 Ω .cm.
2. a kind of antistatic elastic composition as described in claim 1, which is characterized in that the neoprene is PM- 40 types, the nitrile rubber are 1502 types.
3. a kind of antistatic elastic composition as described in claim 1, which is characterized in that the anti-aging agent is N (1,3- Dimethylbutyl)-N/- diphenyl-para-phenylene diamine, in 2,2,4- trimethyl -1,2- dihyaroquinoline condensate any one or two Kind or more mixing.
4. a kind of antistatic elastic composition as described in claim 1, which is characterized in that the vulcanizing agent is sub- second ring Thiocarbamide, N, any one in N- dicyclohexyl -2-[4-morpholinodithio sulfenamide, sulphur or two or more mixing.
5. a kind of antistatic elastic composition as described in claim 1, which is characterized in that the filler is graphite nickel plating Particle, silvered aluminum powder, silica 5:3:2 mixture.
6. antistatic elastic composition as described in claim 1 a kind of, which is characterized in that the multi-walled carbon nanotube is GT-350, wherein purity 97%, caliber 12-15nm, length are 0.5-5 μ, number of plies 8-15.
CN201811245621.0A 2018-10-24 2018-10-24 A kind of antistatic elastic composition Pending CN109553829A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201811245621.0A CN109553829A (en) 2018-10-24 2018-10-24 A kind of antistatic elastic composition

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201811245621.0A CN109553829A (en) 2018-10-24 2018-10-24 A kind of antistatic elastic composition

Publications (1)

Publication Number Publication Date
CN109553829A true CN109553829A (en) 2019-04-02

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CN201811245621.0A Pending CN109553829A (en) 2018-10-24 2018-10-24 A kind of antistatic elastic composition

Country Status (1)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115926469A (en) * 2022-04-01 2023-04-07 徐州市中心医院 Conductive silica gel plate and application thereof in nerve rehabilitation therapeutic apparatus

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1410475A (en) * 2002-03-14 2003-04-16 四川大学 Polymer/carbon nano pipe composite powder and its solid phase shear break up preparation method
JP2006083249A (en) * 2004-09-15 2006-03-30 National Institute Of Advanced Industrial & Technology Method for producing dispersed solution of rubber composition mixed with nano carbon
CN104098795A (en) * 2013-04-12 2014-10-15 中国石油化工股份有限公司 Conductive thermoplastic elastomer and preparation method thereof
CN104371153A (en) * 2014-12-08 2015-02-25 济宁利特纳米技术有限责任公司 Rubber composite modified by carbon nano tubes and graphene jointly
CN106496710A (en) * 2016-09-26 2017-03-15 北京化工大学 A kind of expanded graphite/carbon nanotube conducting dual network structure rubber composite and preparation method thereof
CN108178827A (en) * 2017-12-28 2018-06-19 山东诺威聚氨酯股份有限公司 Antistatic urethane elastomer and preparation method thereof

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1410475A (en) * 2002-03-14 2003-04-16 四川大学 Polymer/carbon nano pipe composite powder and its solid phase shear break up preparation method
JP2006083249A (en) * 2004-09-15 2006-03-30 National Institute Of Advanced Industrial & Technology Method for producing dispersed solution of rubber composition mixed with nano carbon
CN104098795A (en) * 2013-04-12 2014-10-15 中国石油化工股份有限公司 Conductive thermoplastic elastomer and preparation method thereof
CN104371153A (en) * 2014-12-08 2015-02-25 济宁利特纳米技术有限责任公司 Rubber composite modified by carbon nano tubes and graphene jointly
CN106496710A (en) * 2016-09-26 2017-03-15 北京化工大学 A kind of expanded graphite/carbon nanotube conducting dual network structure rubber composite and preparation method thereof
CN108178827A (en) * 2017-12-28 2018-06-19 山东诺威聚氨酯股份有限公司 Antistatic urethane elastomer and preparation method thereof

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115926469A (en) * 2022-04-01 2023-04-07 徐州市中心医院 Conductive silica gel plate and application thereof in nerve rehabilitation therapeutic apparatus
CN115926469B (en) * 2022-04-01 2023-10-13 徐州市中心医院 Conductive silica gel plate and application thereof in nerve rehabilitation therapeutic apparatus

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Application publication date: 20190402