CN109537304A - A kind of interior decoration antistatic PPS base fabric coating and preparation method thereof - Google Patents
A kind of interior decoration antistatic PPS base fabric coating and preparation method thereof Download PDFInfo
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- CN109537304A CN109537304A CN201811393482.6A CN201811393482A CN109537304A CN 109537304 A CN109537304 A CN 109537304A CN 201811393482 A CN201811393482 A CN 201811393482A CN 109537304 A CN109537304 A CN 109537304A
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- base fabric
- interior decoration
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- silicon
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/12—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0056—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the compounding ingredients of the macro-molecular coating
- D06N3/0061—Organic fillers or organic fibrous fillers, e.g. ground leather waste, wood bark, cork powder, vegetable flour; Other organic compounding ingredients; Post-treatment with organic compounds
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0056—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the compounding ingredients of the macro-molecular coating
- D06N3/0063—Inorganic compounding ingredients, e.g. metals, carbon fibres, Na2CO3, metal layers; Post-treatment with inorganic compounds
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/12—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins
- D06N3/128—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins with silicon polymers
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2209/00—Properties of the materials
- D06N2209/04—Properties of the materials having electrical or magnetic properties
- D06N2209/046—Anti-static
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2209/00—Properties of the materials
- D06N2209/10—Properties of the materials having mechanical properties
- D06N2209/103—Resistant to mechanical forces, e.g. shock, impact, puncture, flexion, shear, compression, tear
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2209/00—Properties of the materials
- D06N2209/14—Properties of the materials having chemical properties
- D06N2209/143—Inert, i.e. inert to chemical degradation, corrosion resistant
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2209/00—Properties of the materials
- D06N2209/16—Properties of the materials having other properties
- D06N2209/165—Odour absorbing, deodorizing ability
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2209/00—Properties of the materials
- D06N2209/16—Properties of the materials having other properties
- D06N2209/1685—Wear resistance
Abstract
The invention discloses a kind of interior decoration antistatic PPS base fabric coating, belong to base fabric paint field, it is intended to provide a kind of PPS base fabric coating for effectivelying prevent electrostatic effect to generate, its drip irrigation device is as follows, a kind of interior decoration antistatic PPS base fabric coating, according to parts by weight, it is made of the following components: PPS, magnetic metal compound, carbon nano-fiber, organic-silicon-modified resin, solvent；The object of the present invention is to provide it is a kind of can be by magnetic material in air and electrostatic charge absorption that the ground friction such as metope generates, to effectively avoid the electrostatic effect generated in fitment process and in the use process in later period, fire caused by electrostatic is avoided to occur, preparation cost is low simultaneously, manufacture craft is simple, has industrial value.
Description
Technical field
The present invention relates to base fabric paint field, in particular to a kind of interior decoration antistatic PPS base fabric coating.
Background technique
Existing PPS dust removal by filtration material is generally made into base fabric use, and after use dipping, coating and overlay film etc.
Finishing technique, the surface layer of Lai Gaishan polyphenylene sulfide filter material and internal structure, thus obtain structure uniformly, the PPS material of dimensionally stable
Material, but this base fabric complex manufacturing technology, and higher cost, extensive promote the use of are restricted.
Magnetic metal compound has unique the structure and magnetic properties, obtains in fields such as catalysis, bio-separation and medicine
It is widely applied.In recent years, functional magnetic metallic compound is in analytical chemistry field such as pollutant removal and extracting and purifying side
Face shows huge application potential, simultaneously because magnetic material has excellent electromagnetic performance, is capable of adsorption electrostatic generation
Mobile charge, to avoid the generation of electrostatic effect.
Indoors in fitment process, electrostatic effect is easy to cause dust in air and the burning of other combustibles that fire occurs
Huge threat is caused to the lives and properties of people, in the prior art, the anti-static precautions taken for base fabric coating is still
More fall behind, it is impossible to meet current society needs.
Summary of the invention
The object of the present invention is to provide it is a kind of can be by magnetic material in air and the ground friction such as metope generates
Electrostatic charge absorption, to effectively avoid the electrostatic effect generated in fitment process and in the use process in later period, avoids quiet
Fire caused by electricity occurs, while preparation cost is low, and manufacture craft is simple, has industrial value.
Above-mentioned technical purpose of the invention has the technical scheme that
A kind of interior decoration antistatic is made of the following components according to parts by weight with PPS base fabric coating:
Further, magnetic metal compound is high-spin manganese cluster compound.
Further, high-spin manganese cluster compound is Mn3(FcCOO)6(phen)2、Mn2(Pic)4(DMF)8Or [Mn4
(O2CH)4(phen)8](ClO4)4·6H2Any one in O.
Further, organic-silicon-modified resin is modifying epoxy resin by organosilicon, organosilicon modified crylic acid resin or has
Any one in machine silicon modified polyurethane or two kinds of mixtures.
Further, the fibre diameter of carbon nano-fiber is 10-30nm.
Further, solvent is appointing in ethylene glycol monoethyl ether, ethylene glycol monobutyl ether, methylisobutylketone or toluene cyclohexanone
It anticipates one kind.
Further, a kind of interior decoration antistatic is included the following steps: with the preparation method of PPS base fabric coating
(1) by PPS and organic-silicon-modified resin, stirring is melted under the conditions of temperature is 200-220 DEG C, is obtained organosilicon and is changed
Property resin combination；
(2) organic-silicon-modified resin combination obtained in step (1) is down to room temperature, solvent is added under agitation
It stirs evenly, obtains organic-silicon-modified resin combination lotion；
(3) magnetic metal oxide stirring is added into organic-silicon-modified resin combination lotion obtained in step (2)
Uniformly, emulsion is obtained；
(4) carbon nano-fiber is added to emulsion obtained in step (3) and persistently stirs 1.0-2.5h at room temperature, obtain institute
State interior decoration antistatic PPS base fabric coating.
By using above-mentioned technical proposal,
In conclusion the invention has the following advantages:
1. using material of the high-spin manganese cluster compound in magnetic material as adsorption electrostatic charge, high-spin manganese cluster
Compound, can be by special constructions such as its big pi bond, conjugated bonds to generating in fitment process absorb electrostatic charge while
Acid small molecule is adsorbed, thus while antistatic, it is therefore prevented that acid small molecule is dissolved in the generations such as the water in air
Corrosion of the sour corrosion agent to the other materials in ambient enviroment；
2. using organic-silicon-modified resin is used as adhesive, organic-silicon-modified adhesive is with good toughness and wear-resisting
Performance, while the cohesive force between high-spin manganese cluster compound and base fabric is enhanced, it is more anti-while improving the wearability of coating
Stop and having been separated between magnetic compound and base fabric, has extended the service life of base fabric coating；
3. using carbon nano-fiber as additive, carbon nano-fiber has high-modulus and amount of tension, wear-resisting property
It is preferable with tearing-resistant performance, while carbon nano-fiber can adsorb magnetic compound by nano aperture, and hydrogen bond is generated
Equal bond energys are greater than the chemical bond of Van der Waals force, avoid falling off for magnetic compound.
4. since carbon nano-fiber has micropore and mesoporous duct, can dust to surrounding, pernicious gas carry out
Effective absorption, is effectively improved environment, reduces the release of pernicious gas.
Specific embodiment
Invention is further described in detail below.
A kind of interior decoration antistatic is made of the following components according to parts by weight with PPS base fabric coating:
As a preferred embodiment, magnetic metal compound is high-spin manganese cluster compound.
As a preferred embodiment, high-spin manganese cluster compound is Mn3(FcCOO)6(phen)2、Mn2(Pic)4(DMF)8Or
[Mn4(O2CH)4(phen)8](ClO4)4·6H2Any one in O.
As a preferred embodiment, organic-silicon-modified resin is modifying epoxy resin by organosilicon, organosilicon-modified acrylic
Any one in resin or organic silicon modified polyurethane or two kinds of mixtures.
As a preferred embodiment, the fibre diameter of carbon nano-fiber is 10-30nm.
As a preferred embodiment, solvent is ethylene glycol monoethyl ether, ethylene glycol monobutyl ether, methylisobutylketone or toluene hexamethylene
Any one in ketone.
As a preferred embodiment, a kind of preparation method of interior decoration antistatic PPS base fabric coating includes following step
It is rapid:
(1) by PPS and organic-silicon-modified resin, stirring is melted under the conditions of temperature is 200-220 DEG C, is obtained organosilicon and is changed
Property resin combination；
(2) organic-silicon-modified resin combination obtained in step (1) is down to room temperature, solvent is added under agitation
It stirs evenly, obtains organic-silicon-modified resin combination lotion；
(3) magnetic metal oxide stirring is added into organic-silicon-modified resin combination lotion obtained in step (2)
Uniformly, emulsion is obtained；
(4) carbon nano-fiber is added to emulsion obtained in step (3) and persistently stirs 1.0-2.5h at room temperature, obtain institute
State interior decoration antistatic PPS base fabric coating.
Embodiment 1
By 60 parts of PPS and organosilicon epoxy modified resin, stirring under the conditions of temperature is 200 DEG C melts step 1., is had
Machine silicon modified epoxy resin composition；
Modifying epoxy resin by organosilicon composition obtained in step 1 is down to room temperature by step 2., under agitation plus
Enter 45 portions of ethylene glycol monoethyl ethers to stir evenly, obtains modifying epoxy resin by organosilicon composition emulsion；
15 parts of Mn are added into organic-silicon-modified resin combination lotion obtained in step 2 for step 3.3(FcCOO)6
(phen)2It stirs evenly, obtains emulsion；
Step 4. is added 10 parts of carbon nano-fibers to emulsion obtained in step 3 and persistently stirs 1.0h at room temperature, obtains
Interior decoration antistatic PPS base fabric coating.
Embodiment 2
By 70 parts of PPS and 25 part of organic silicon modified polyurethane resins, stirring under the conditions of temperature is 220 DEG C melts step 1.,
Obtain organic silicon modified polyurethane resin composition；
Modifying epoxy resin by organosilicon composition obtained in step 1 is down to room temperature by step 2., under agitation plus
Enter 55 parts of butyl acetates to stir evenly, obtains organic silicon modified polyurethane resin composition emulsion；
20 parts of Mn are added into 23 parts of organic silicon modified polyurethane resin composition emulsions obtained in step 2 for step 3.2
(Pic)4(DMF)8It stirs evenly, obtains emulsion；
Step 4. is added 15 parts of carbon nano-fibers to emulsion obtained in step 3 and persistently stirs 2.5h at room temperature, obtains
Interior decoration antistatic PPS base fabric coating.
Embodiment 3
By 65 parts of PPS and 26 part of organosilicon modified crylic acid resins, stirring under the conditions of temperature is 200 DEG C melts step 1.,
Obtain organosilicon modified crylic acid resin composition；
Modifying epoxy resin by organosilicon composition obtained in step 1 is down to room temperature by step 2., under agitation plus
Enter 50 parts of methylisobutylketones to stir evenly, obtains organosilicon modified crylic acid resin composition emulsion；
15 parts of [Mn are added into organic-silicon-modified resin combination lotion obtained in step 2 for step 3.4(O2CH)4
(phen)8](ClO4)4·6H2O is stirred evenly, and obtains emulsion；
Step 4. is added 12 parts of carbon nano-fibers to emulsion obtained in step 3 and persistently stirs 1.0h at room temperature, obtains
Interior decoration antistatic PPS base fabric coating.
Embodiment 4
By 60 parts of PPS and 26 part of organosilicon epoxy modified resins, stirring under the conditions of temperature is 210 DEG C melts step 1., obtains
To modifying epoxy resin by organosilicon composition；
Modifying epoxy resin by organosilicon composition obtained in step 1 is down to room temperature by step 2., under agitation plus
Enter 45 parts of toluene cyclohexanone to stir evenly, obtains modifying epoxy resin by organosilicon composition emulsion；
15 parts of Mn are added into organic-silicon-modified resin combination lotion obtained in step 2 for step 3.3(FcCOO)6
(phen)2It stirs evenly, obtains emulsion；
Step 4. is added 10 parts of carbon nano-fibers to emulsion obtained in step 3 and persistently stirs 2.0h at room temperature, obtains
Interior decoration antistatic PPS base fabric coating.
After being coated on PET sheet surface by the anti-static coatings in embodiment 1-4 and form coating, surveyed using sheet resistance
Try the sheet resistance value of instrument (Si Naide SL-030 sheet resistance tester) measurement coating；Specific measurement result is shown in Table 1.
1 electrostatic test result of table
According to the definition of anti-static product, resistance value is less than 1011The product of Ω is anti-static product, resistance value 106
Ω to 109The anti-static product of Ω has better conducting function, i.e. anti-static function then because sheet resistance value is lower.From table 1
Measurement result can be seen that, low, the of the invention anti-static coatings of the preparation-obtained anti-static coatings sheet resistance value of the present invention
With good anti-static effect.
This specific embodiment is only explanation of the invention, is not limitation of the present invention, those skilled in the art
Member can according to need the modification that not creative contribution is made to the present embodiment after reading this specification, but as long as at this
All by the protection of Patent Law in the scope of the claims of invention.
Claims (7)
1. a kind of interior decoration antistatic PPS base fabric coating, which is characterized in that according to parts by weight, be made of the following components:
60-70 parts of PPS；
15-20 parts of magnetic metal compound；
10-15 parts of carbon nano-fiber；
Organic-silicon-modified resin 23-26 parts；
45-55 parts of solvent.
2. a kind of interior decoration antistatic PPS base fabric coating according to claim 1, which is characterized in that the magnetism
Metallic compound is high-spin manganese cluster compound.
3. a kind of interior decoration antistatic PPS base fabric pan feeding according to claim 2, which is characterized in that the height is certainly
Revolving manganese cluster compound is Mn3(FcCOO)6(phen)2、Mn2(Pic)4(DMF)8Or [Mn4(O2CH)4(phen)8](ClO4)4·
6H2Any one in O.
4. a kind of interior decoration antistatic PPS base fabric coating according to claim 1, which is characterized in that described organic
Si modification resin is any in modifying epoxy resin by organosilicon, organosilicon modified crylic acid resin or organic silicon modified polyurethane
One or two kinds of mixtures.
5. a kind of interior decoration antistatic PPS base fabric coating according to claim 1, which is characterized in that the carbon is received
The fibre diameter of rice fiber is 10-30nm.
6. a kind of interior decoration antistatic PPS base fabric coating according to claim 1, which is characterized in that the solvent
It is any one in ethylene glycol monoethyl ether, ethylene glycol monobutyl ether, methylisobutylketone or toluene cyclohexanone.
7. a kind of preparation method of interior decoration antistatic PPS base fabric coating, which comprises the steps of:
(1) by PPS and organic-silicon-modified resin, stirring is melted under the conditions of temperature is 200-220 DEG C, obtains organic-silicon-modified tree
Oil/fat composition；
(2) organic-silicon-modified resin combination obtained in step (1) is down to room temperature, stirring solvent is added under agitation
Uniformly, organic-silicon-modified resin combination lotion is obtained；
(3) magnetic metal oxide is added into organic-silicon-modified resin combination lotion obtained in step (2) to stir evenly,
Obtain emulsion；
(4) carbon nano-fiber is added to emulsion obtained in step (3) and persistently stirs 1.0-2.5h at room temperature, obtain the room
Interior decoration antistatic PPS base fabric coating.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811393482.6A CN109537304A (en) | 2018-11-21 | 2018-11-21 | A kind of interior decoration antistatic PPS base fabric coating and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811393482.6A CN109537304A (en) | 2018-11-21 | 2018-11-21 | A kind of interior decoration antistatic PPS base fabric coating and preparation method thereof |
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| CN109537304A true CN109537304A (en) | 2019-03-29 |
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Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6281450A (en) * | 1985-10-04 | 1987-04-14 | Toray Ind Inc | Polyphenylene sulfide resin composition |
| US6528572B1 (en) * | 2001-09-14 | 2003-03-04 | General Electric Company | Conductive polymer compositions and methods of manufacture thereof |
| CN102120891A (en) * | 2009-12-31 | 2011-07-13 | 第一毛织株式会社 | Thermoplastic resin composition with EMI shielding properties and EMI shielding product prepared thereby |
| CN102254584A (en) * | 2011-05-12 | 2011-11-23 | 中国科学院宁波材料技术与工程研究所 | General electronic paste based on graphene filler |
| CN102559043A (en) * | 2010-11-15 | 2012-07-11 | 长濑化成株式会社 | Conductive coating composition and laminate |
| CN103030138A (en) * | 2012-12-17 | 2013-04-10 | 鸿纳（东莞）新材料科技有限公司 | Folding preventing less-layer graphene powder, components of composite material thereof, and application |
-
2018
- 2018-11-21 CN CN201811393482.6A patent/CN109537304A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6281450A (en) * | 1985-10-04 | 1987-04-14 | Toray Ind Inc | Polyphenylene sulfide resin composition |
| US6528572B1 (en) * | 2001-09-14 | 2003-03-04 | General Electric Company | Conductive polymer compositions and methods of manufacture thereof |
| CN102120891A (en) * | 2009-12-31 | 2011-07-13 | 第一毛织株式会社 | Thermoplastic resin composition with EMI shielding properties and EMI shielding product prepared thereby |
| CN102559043A (en) * | 2010-11-15 | 2012-07-11 | 长濑化成株式会社 | Conductive coating composition and laminate |
| CN102254584A (en) * | 2011-05-12 | 2011-11-23 | 中国科学院宁波材料技术与工程研究所 | General electronic paste based on graphene filler |
| CN103030138A (en) * | 2012-12-17 | 2013-04-10 | 鸿纳（东莞）新材料科技有限公司 | Folding preventing less-layer graphene powder, components of composite material thereof, and application |
Non-Patent Citations (1)
| Title |
|---|
| 黄伯云等: "《纤维复合材料》", 31 December 2017, 中国铁道出版社 * |
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Effective date of registration: 20190708 Address after: 046000 East Street Steel City New Area, Guxian County, Changzhi Suburb, Shanxi Province, 1 Building, 4 Units and 9 Households Applicant after: Li Guosheng Address before: 214174 No. 15 Yanjin Road, Yanqiao Street, Huishan District, Wuxi City, Jiangsu Province Applicant before: Wuxi High Strength Special Textile Co., Ltd. |
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Application publication date: 20190329 |