CN109536000A - 一种红外阻隔功能聚氨酯涂料的制备方法 - Google Patents

一种红外阻隔功能聚氨酯涂料的制备方法 Download PDF

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CN109536000A
CN109536000A CN201811371853.0A CN201811371853A CN109536000A CN 109536000 A CN109536000 A CN 109536000A CN 201811371853 A CN201811371853 A CN 201811371853A CN 109536000 A CN109536000 A CN 109536000A
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汪元元
张春明
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Abstract

本发明提供一种红外阻隔功能聚氨酯涂料的制备方法，其特征在于，包括如下步骤：(1)将铯钨青铜粉体、分散剂加入甲基异丁酮中，搅拌均匀后泵入砂磨机中研磨分散，直至平均粒径80～100纳米，得到浆料；在浆料中加入蓖麻油和异佛尔酮二异氰酸酯，60～90℃下预聚2.5～3小时，得到A组分；(2)将对二邻氯苯胺甲烷和3‑氨基丙基三甲氧基硅烷和加入甲基异丁酮中，加热到40～50℃溶解，得到B组分；(3)将步骤(1)和(2)的AB两组分混合，1小时内刷涂成膜。

Description

一种红外阻隔功能聚氨酯涂料的制备方法
技术领域
本发明属于纳米材料和光学领域，涉及一种红外阻隔功能聚氨酯涂料的制备方法。
背景技术
红外光特别是近红外具有明显的热效应，易导致温度升温，从而造成如室内或车内的温度升高。目前公开的红外阻隔材料一般是指具有较强吸收或反射红外光而又不影响其可见光透过的一类功能性材料。已经报道的具有较强红外吸收或反射性能的无机材料主要有ATO、ITO、AZO和LaB6等。铯钨青铜可以阻隔波长大于900nm的近红外光，因而具有优异的近红外阻隔性能。
自然光辐射中约50％的热量来自红外线，在节能建筑领域，外墙玻璃既需要保证光线有效透过，又需要有效阻隔内外热量传递。在可见光透明载体上进行红外阻隔可有效实现节能降耗。基于铯钨青铜纳米粉体开发性能稳定、耐候性好的玻璃红外阻隔涂料具有重要的现实意义。
本发明重点在于配方的开发及原位自聚形成聚氨酯，可以极大的提高整个涂料体系的匹配性。
发明内容
本发明的目的在于提供一种红外阻隔功能聚氨酯涂料的制备方法，其特征在于，包括如下步骤：
(1)将铯钨青铜粉体、分散剂加入甲基异丁酮中，搅拌均匀后泵入砂磨机中研磨分散，直至平均粒径80～100纳米，得到浆料；在浆料中加入蓖麻油和异佛尔酮二异氰酸酯，60～90℃下预聚2.5～3小时，得到A组分；
(2)将对二邻氯苯胺甲烷和3-氨基丙基三甲氧基硅烷和加入甲基异丁酮中，加热到40～50℃溶解，得到B组分；
(3)将步骤(1)和(2)的AB两组分混合，1小时内刷涂成膜。
各成分体积比为：
甲基异丁酮 150份
铯钨青铜粉体 80～130份
分散剂 3～8份
蓖麻油 40～50份
异佛尔酮二异氰酸酯 50～65份
对二邻氯苯胺甲烷 20～30份
3-氨基丙基三甲氧基硅烷 20～30份
各组分的体积计算方式为：体积＝称重/理论密度。
所述分散剂包括聚乙烯胺、聚乙烯亚胺、聚脒中的一种或其组合。
本发明工艺简单，适用性强。通过原位聚合方式生成铯钨青铜-聚氨酯红外阻隔功能涂料，玻璃表面匹配性好，具有优良的成膜性和耐候性，铯钨青铜功能成分良好分散，涂膜后可见光光透过率好，红外线阻隔率高，A、B两组分利于提升分散稳定性，适用于长时间保存。
本发明的内容和特点已揭示如上，然而前面叙述的本发明仅仅简要地或只涉及本发明的特定部分，本发明的特征可能比在此公开的内容涉及的更多。因此，本发明的保护范围应不限于实施例所揭示的内容，而应该包括在不同部分中所体现的所有内容的组合，以及各种不背离本发明的替换和修饰，并为本发明的权利要求书所涵盖。
具体实施方式
实施例1：
(1)将铯钨青铜粉体、聚乙烯胺加入甲基异丁酮中，搅拌均匀后泵入砂磨机中研磨分散，直至平均粒径80～100纳米，得到浆料；在浆料中加入蓖麻油和异佛尔酮二异氰酸酯，60℃下预聚3小时，得到A组分；
(2)将对二邻氯苯胺甲烷和3-氨基丙基三甲氧基硅烷和加入甲基异丁酮中，加热到40～50℃溶解，得到B组分；
各成分体积比为：
甲基异丁酮 150份
铯钨青铜粉体 80份
聚乙烯胺 3份
蓖麻油 45份
异佛尔酮二异氰酸酯 60份
对二邻氯苯胺甲烷 25份
3-氨基丙基三甲氧基硅烷 25份
(3)将步骤(1)和(2)的AB两组分混合，1小时内刷涂成膜。
实施例2：
(1)将铯钨青铜粉体、聚乙烯亚胺加入甲基异丁酮中，搅拌均匀后泵入砂磨机中研磨分散，直至平均粒径80～100纳米，得到浆料；在浆料中加入蓖麻油和异佛尔酮二异氰酸酯，60℃下预聚3小时，得到A组分；
(2)将对二邻氯苯胺甲烷和3-氨基丙基三甲氧基硅烷和加入甲基异丁酮中，加热到40～50℃溶解，得到B组分；
各成分体积比为：
甲基异丁酮 150份
铯钨青铜粉体 100份
聚乙烯亚胺 5份
蓖麻油 40份
异佛尔酮二异氰酸酯 65份
对二邻氯苯胺甲烷 20份
3-氨基丙基三甲氧基硅烷 30份
(3)将步骤(1)和(2)的AB两组分混合，1小时内刷涂成膜。
实施例3：
(1)将铯钨青铜粉体、聚脒加入甲基异丁酮中，搅拌均匀后泵入砂磨机中研磨分散，直至平均粒径80～100纳米，得到浆料；在浆料中加入蓖麻油和异佛尔酮二异氰酸酯，90℃下预聚2.5小时，得到A组分；
(2)将对二邻氯苯胺甲烷和3-氨基丙基三甲氧基硅烷和加入甲基异丁酮中，加热到40～50℃溶解，得到B组分；
各成分体积比为：
甲基异丁酮 150份
铯钨青铜粉体 130份
聚脒 8份
蓖麻油 40份
异佛尔酮二异氰酸酯 65份
对二邻氯苯胺甲烷 30份
3-氨基丙基三甲氧基硅烷 20份
(3)将步骤(1)和(2)的AB两组分混合，1小时内刷涂成膜。
表1 实施例1-3中聚氨酯涂料涂敷成膜后的性能
实施例 膜厚(μm) 红外阻隔率 可见光透过率
1 12 80％ 80％
2 21 91％ 71％
3 30 96％ 65％

Claims (3)

1.一种红外阻隔功能聚氨酯涂料的制备方法，其特征在于，包括如下步骤：
(1)将铯钨青铜粉体、分散剂加入甲基异丁酮溶剂中，搅拌均匀后泵入砂磨机中研磨分散，直至平均粒径达到80～100纳米，得到纳米功能浆料；在浆料中加入蓖麻油和异佛尔酮二异氰酸酯，60～90℃下预聚2.5～3小时，得到A组分；
(2)将对二邻氯苯胺甲烷和3-氨基丙基三甲氧基硅烷和加入甲基异丁酮中，加热到40～50℃溶解，得到B组分；
(3)将步骤(1)和(2)的A、B两组分混合，制成具有红外阻隔功能的聚氨酯涂料，可刷涂成膜。
各成分体积比为：
甲基异丁酮 150份
铯钨青铜粉体 80～130份
分散剂 3～8份
蓖麻油 40～50份
异佛尔酮二异氰酸酯 50～65份
对二邻氯苯胺甲烷 20～30份
3-氨基丙基三甲氧基硅烷 20～30份
各组分的体积计算方式为：体积＝称重/理论密度。
所述分散剂包括聚乙烯胺、聚乙烯亚胺、聚脒中的一种或其组合。
2.根据权利要求1所述一种红外阻隔功能聚氨酯涂料的制备方法，其特征在于，步骤(3)中两组分混合后，1小时内刷涂成膜。
3.一种如权利要求1～2任意一项所述的红外阻隔功能聚氨酯涂料的制备方法所制备的红外阻隔功能聚氨酯涂料。
CN201811371853.0A 2018-11-12 2018-11-12 一种红外阻隔功能聚氨酯涂料的制备方法 Withdrawn CN109536000A (zh)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113528002A (zh) * 2021-08-12 2021-10-22 佛山市佳世达薄膜科技有限公司 一种透明隔热纳米保护膜

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101108946A (zh) * 2007-07-12 2008-01-23 深圳清华大学研究院 纳米透明隔热涂料及其制备方法
US20100167209A1 (en) * 2007-06-05 2010-07-01 Zwadlo Gregory L Method of using mask film to form relief images
CN102471090A (zh) * 2009-07-07 2012-05-23 巴斯夫欧洲公司 钾铯钨青铜颗粒
CN102876220A (zh) * 2011-07-14 2013-01-16 何誉良 玻璃透明隔热涂料
CN104726040A (zh) * 2015-04-14 2015-06-24 魏勇 一种含有钨青铜的pvb浆料及其制备方法

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20100167209A1 (en) * 2007-06-05 2010-07-01 Zwadlo Gregory L Method of using mask film to form relief images
CN101108946A (zh) * 2007-07-12 2008-01-23 深圳清华大学研究院 纳米透明隔热涂料及其制备方法
CN102471090A (zh) * 2009-07-07 2012-05-23 巴斯夫欧洲公司 钾铯钨青铜颗粒
CN102876220A (zh) * 2011-07-14 2013-01-16 何誉良 玻璃透明隔热涂料
CN104726040A (zh) * 2015-04-14 2015-06-24 魏勇 一种含有钨青铜的pvb浆料及其制备方法

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
劳动部培训司: "《油漆工工艺学 第2版》", 29 February 1992, 中国劳动出版社 *
程侣柏等编译: "《精细化工产品的合成及应用 第2版》", 30 April 1999, 大连理工大学出版社 *
陈小勇等: "几种纳米隔热浆料近红外阻隔的分析比较", 《广东化工》 *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113528002A (zh) * 2021-08-12 2021-10-22 佛山市佳世达薄膜科技有限公司 一种透明隔热纳米保护膜

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