CN109518467A - Ultralow pyrocondensation polyurethane superfine fiber fabric and preparation method thereof - Google Patents

Ultralow pyrocondensation polyurethane superfine fiber fabric and preparation method thereof Download PDF

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Publication number
CN109518467A
CN109518467A CN201811324859.2A CN201811324859A CN109518467A CN 109518467 A CN109518467 A CN 109518467A CN 201811324859 A CN201811324859 A CN 201811324859A CN 109518467 A CN109518467 A CN 109518467A
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pyrocondensation
ultralow
superfine fiber
fabric
upper oil
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CN201811324859.2A
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CN109518467B (en
Inventor
于晓成
张水观
韩芹
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Jiangsu Huafeng Microfiber Material Co Ltd
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Jiangsu Huafeng Microfiber Material Co Ltd
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    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/643Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
    • D06M15/6436Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain containing amino groups
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06BTREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
    • D06B3/00Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating
    • D06B3/10Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating of fabrics
    • D06B3/18Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating of fabrics combined with squeezing, e.g. in padding machines
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06CFINISHING, DRESSING, TENTERING OR STRETCHING TEXTILE FABRICS
    • D06C23/00Making patterns or designs on fabrics
    • D06C23/04Making patterns or designs on fabrics by shrinking, embossing, moiréing, or crêping
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/165Ethers
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/53Polyethers
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/16Synthetic fibres, other than mineral fibres
    • D06M2101/18Synthetic fibres consisting of macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M2101/20Polyalkenes, polymers or copolymers of compounds with alkenyl groups bonded to aromatic groups
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/16Synthetic fibres, other than mineral fibres
    • D06M2101/30Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M2101/32Polyesters
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/16Synthetic fibres, other than mineral fibres
    • D06M2101/30Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M2101/34Polyamides
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/16Synthetic fibres, other than mineral fibres
    • D06M2101/30Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M2101/38Polyurethanes

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Synthetic Leather, Interior Materials Or Flexible Sheet Materials (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Abstract

The invention discloses a kind of ultralow pyrocondensation polyurethane superfine fiber fabrics and preparation method thereof, the preparation side of ultralow pyrocondensation polyurethane superfine fiber fabric includes the following steps: nylon 6 or polyester, with fabric of island-in-sea type staple fiber that polyethylene or styrene are raw material through needling shape at non-woven fabrics, it is immersed in wet process slurry, then through supersolidification and washing, decrement extraction polyethylene or styrene in hot toluene again, obtain wet cloth, then wet cloth is impregnated in upper oil liquid, continuously rub line, drying, can be obtained the ultralow pyrocondensation polyurethane superfine fiber fabric;The upper oil liquid contains amido silicon oil, heterogeneous ten alcohol polyoxyethylene ether, isomerous tridecanol polyoxyethylene ether, diethylene glycol monobutyl ether and water.The present invention has ultralow dimensional stability to heating in house, and base fabric finished product pyrocondensation value is 0.1-1.5%, and folding line exquisiteness feature can satisfy applied at elevated temperature requirement, can satisfy high-temperature dry veneer requirement.

Description

Ultralow pyrocondensation polyurethane superfine fiber fabric and preparation method thereof
Technical field
The present invention relates to polyurethane superfine fiber base fabric and preparation method thereof.
Background technique
In recent years, environmental protection was increasingly paid attention to country, and put into effect severeer environmental protection policy, Dao Bi enterprise increases ring Facility is protected, is adopted new technology, new equipment carrys out energy-saving and emission-reduction.
Before, dry method veneer uses DMF/TOL, DMF/MEK equal solvent system, although DMF recovery technology is mature, mixes Bonding solvent recovery technology difficulty is big, at high cost, causes the low boiling point solvents such as TOL, MEK that cannot recycle, and therefore, someone uses pure The mixed solvent systems such as DMF/TOL, DMF/MEK DMF instead preceding as solvent carrier, reduce VOC emission, since DMF boils Point is high, needs to improve veneer oven temperature, since base fabric pyrocondensation leads to greatly veneer release paper crimping, market needs low-heat to contract Base fabric.It has been proposed that with organic siliconresin veneer, it is solvent-free in production process, it is environmentally friendly, but veneer processing is also required to height Temperature also needs lower shrinkage base fabric.
Existing routine superfine fiber fabric, tests thermal shrinkage method according to industry and client, in 140 degree of environment of constant temperature oven It places 10 minutes, tests shrinking percentage.Shoes leather base cloth pyrocondensation is required less than 3%, and portions of client is required less than 2.5%;Sofa artificial leather base Cloth pyrocondensation is required less than 4%.
In order to reach pyrocondensation requirement, someone uses and adjusts expanding setting temperature to 170-180 degree, but has the disadvantage that: First, it needs to select special fire resistant resin;Second, if there is baking oven failure, base fabric is stopped in an oven, will cause base Cloth seriously damages.After someone rubs skin processing using base fabric, then preliminary drying one time, pyrocondensation value can reduce, but will increase 0.5 yuan/meter Cloth cost is dried, and pyrocondensation value still cannot fully meet the requirement of client's high temperature process between 1.0-2.5%.
Summary of the invention
The purpose of the present invention is to provide a kind of ultralow pyrocondensation polyurethane superfine fiber fabrics and preparation method thereof, to overcome Defect of the existing technology.
Method of the invention, includes the following steps:
By nylon 6 perhaps polyester and polyethylene or styrene be raw material fabric of island-in-sea type staple fiber through needling shape at nothing Woven fabric is immersed in wet process slurry, then through supersolidification and washing, then decrement extraction polyethylene or benzene second in hot toluene Alkene obtains wet cloth, wet cloth is then impregnated in upper oil liquid, continuously rubs line, dries, can be obtained the ultralow pyrocondensation polyurethane Superfine fiber fabric;
The upper oil liquid is compound organosilicon finish, is made of the component of following mass percent:
The oiling method is to pad processing, and preferably three leachings three are rolled;
After oiling, base fabric liquid carrying rate is 60-120%;It is preferred that 70-110%
It is described that continuously to rub line technological parameter as follows:
The continuous boarding machine baking oven length is 25-35 meters, preferably 35 meters;
Drying temperature is 60-170 DEG C, preferably 120-160 DEG C;
Rubbing the positive and negative rotation time is 15-35s, and rubbing a positive and negative rotation interval time is 3-6s;
The spinning, non-woven fabrics needling process, dipping sizing agent ingredient, dipping, solidification and washing process, and decrement work Skill is this field common process, can refer to document: Qu Jianbo: Beijing synthetic leather technology [M]: Chemical Industry Press .2015.P18-P211 the processing technology reported in.
Term: dimensional stability to heating in house is dry shinkage.Dimensional stability to heating in house test method is as follows:
1, purpose
Xeothermic contraction is to set corresponding temperature for different product, carrys out the contraction feelings of test product under this condition Condition.
2 instruments
Vernier caliper, ruler
Constant temperature oven: 140 DEG C ± 2 DEG C are maintained the temperature at, band blower device;Stopwatch: it is accurate to 0.01 second.
3 specimen shapes and size
150mm × 150mm square sample (precise measurement)
4 test conditions
Thermal contraction test condition: 140 DEG C or client's assigned temperature.
5, dry-hot shrinkage
2 pieces of samples are cut, two mutually perpendicular center lines is drawn at the center of sample, marks, surveyed with vernier caliper Measure its length A0(B0).It is placed in 10min in constant temperature oven, uses manual time-keeping.Sample is taken out, is measured at 3 respectively through broadwise length simultaneously Take arithmetic mean of instantaneous value.
If client has particular/special requirement to temperature or time, executed according to the requirement of client.
6 results calculate
In formula: for W-portraitlandscape to shrinking percentage, unit is percentage (%);
A0Length before-sample dries, unit mm;
A1Length after-sample dries, unit mm.
The beneficial effects of the present invention are:
The polyurethane superfine fiber base fabric of acquisition, has ultralow dimensional stability to heating in house, and base fabric finished product pyrocondensation value is 0.1-1.5%, folding Trace exquisiteness feature, can satisfy applied at elevated temperature requirement, can satisfy high-temperature dry veneer requirement.
Specific embodiment
Present invention is further described in detail With reference to embodiment, it should be appreciated that these embodiments are only used for Illustrate the present invention rather than limits the scope of the invention.
Embodiment 1
By fabric of island-in-sea type staple fiber that nylon 6 and polyethylene are raw material through needling shape at non-woven fabrics be immersed in wet process slurry In, then through supersolidification and washing, then the decrement extraction polyethylene in hot toluene, wet cloth oil, continuously rub line, obtain ultralow heat Polycondensation urethane superfine fiber fabric;
The spinning, non-woven fabrics needling process, dipping sizing agent ingredient, dipping, solidification and washing process, and decrement work Skill is this field common process, can refer to document: Qu Jianbo: Beijing synthetic leather technology [M]: Chemical Industry Press .2015.P18-P211 the processing technology reported in.
Wherein, the wet cloth oiling process parameter includes:
The oiling method is to pad processing, and three leachings three are rolled;
Upper oil liquid is made of the component of following mass percent:
Upper oil liquid concentration is 2.5%;
Base fabric liquid carrying rate is 110% after oiling;
Wherein, affiliated continuously to rub line technological parameter and include:
The continuous boarding machine baking oven length is 35 meters;
The oven temperature is 120 DEG C;
The positive and negative rotation time of rubbing is 15s;
A positive and negative rotation interval time of rubbing is 6s;
It is 1.5% by base fabric finished product pyrocondensation value prepared by this method
Embodiment 2
By fabric of island-in-sea type staple fiber that polyester and polyethylene are raw material through needling shape at non-woven fabrics be immersed in wet process slurry, Then through supersolidification and washing, then the decrement extraction polyethylene in hot toluene, wet cloth oil, continuously rub line, obtain ultralow pyrocondensation Polyurethane superfine fiber base fabric;
The spinning, non-woven fabrics needling process, dipping sizing agent ingredient, dipping, solidification and washing process, and decrement work Skill is this field common process, can refer to document: Qu Jianbo: Beijing synthetic leather technology [M]: Chemical Industry Press .2015.P18-P211 the processing technology reported in.
Wherein, the wet cloth oiling process parameter includes:
The oiling method is to pad processing, and preferably three leachings three are rolled;
Upper oil liquid is made of the component of following mass percent:
The upper oil liquid concentration is 10%;
It is described oil after base fabric liquid carrying rate be 70%;
Wherein, affiliated continuously to rub line technological parameter and include:
The continuous boarding machine baking oven length is 35 meters;
The oven temperature is 160 DEG C;
The positive and negative rotation time of rubbing is 35s;
A positive and negative rotation interval time of rubbing is 3s;
It is 0.10% by base fabric finished product pyrocondensation value prepared by this method
Embodiment 3
By fabric of island-in-sea type staple fiber that nylon 6 and styrene are raw material through needling shape at non-woven fabrics be immersed in wet process slurry In, then through supersolidification and washing, then the decrement extraction polyethylene in hot toluene, wet cloth oil, continuously rub line, obtain ultralow heat Polycondensation urethane superfine fiber fabric;
The spinning, non-woven fabrics needling process, dipping sizing agent ingredient, dipping, solidification and washing process, and decrement work Skill is this field common process, can refer to document: Qu Jianbo: Beijing synthetic leather technology [M]: Chemical Industry Press .2015.P18-P211 the processing technology reported in.
Wherein, the wet cloth oiling process parameter includes:
The oiling method is to pad processing, and preferably three leachings three are rolled;
Upper oil liquid is made of the component of following mass percent:
The upper oil liquid concentration is 5%;
It is described oil after base fabric liquid carrying rate be 90%;
Wherein, affiliated continuously to rub line technological parameter and include:
The continuous boarding machine baking oven length is 35 meters;
The oven temperature is 150 DEG C;
The positive and negative rotation time of rubbing is 25s;
A positive and negative rotation interval time of rubbing is 5s;
It is 0.5% by base fabric finished product pyrocondensation value prepared by this method.

Claims (6)

1. the preparation method of ultralow pyrocondensation polyurethane superfine fiber fabric, which comprises the steps of:
By nylon 6 perhaps polyester and polyethylene or styrene be raw material fabric of island-in-sea type staple fiber through needling shape at non-woven fabrics, It is immersed in wet process slurry, then through supersolidification and washing, then decrement extraction polyethylene or styrene in hot toluene, it obtains Then wet cloth is impregnated in upper oil liquid by wet cloth, continuously rub line, and drying can be obtained the ultralow ultra-fine fibre of pyrocondensation polyurethane Wiki cloth;
The upper oil liquid contains amido silicon oil, heterogeneous ten alcohol polyoxyethylene ether, isomerous tridecanol polyoxyethylene ether, diethylene glycol Monobutyl ether and water.
2. the method according to claim 1, wherein component group of the upper oil liquid by following mass percent At:
3. method according to claim 1 or 2, which is characterized in that the oiling method is to pad processing.
4. according to the method described in claim 3, it is characterized in that, base fabric liquid carrying rate is 60-120% after oiling.
5. according to the method described in claim 4, it is characterized in that, above-mentioned continuously to rub line technological parameter as follows:
Continuous boarding machine baking oven length is 25-35 meters;
Drying temperature is 60-170 DEG C;
Rubbing the positive and negative rotation time is 15-35s, and rubbing a positive and negative rotation interval time is 3-6s.
6. the ultralow pyrocondensation polyurethane superfine fiber fabric of any one the method preparation according to claim 1~5.
CN201811324859.2A 2018-11-08 2018-11-08 Ultralow-heat polycondensation polyurethane superfine fiber base cloth and preparation method thereof Active CN109518467B (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111074626A (en) * 2019-12-25 2020-04-28 江苏华峰超纤材料有限公司 Ultra-low fixed-load elongation rate microfiber base cloth and preparation method thereof

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CN101929083A (en) * 2009-06-19 2010-12-29 上海华峰超纤材料股份有限公司 Superfine fiber polyurethane leather and base cloth as well as preparation method and application
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CN105064064A (en) * 2015-08-07 2015-11-18 无锡双象超纤材料股份有限公司 Preparation method of microfiber soft leather sofa leather
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CN111074626A (en) * 2019-12-25 2020-04-28 江苏华峰超纤材料有限公司 Ultra-low fixed-load elongation rate microfiber base cloth and preparation method thereof

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Denomination of invention: Ultra low heat shrink polyurethane ultrafine fiber base fabric and its preparation method

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