CN109517489A - Water-base epoxy anti-corrosion floor material - Google Patents

Water-base epoxy anti-corrosion floor material Download PDF

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Publication number
CN109517489A
CN109517489A CN201811378018.XA CN201811378018A CN109517489A CN 109517489 A CN109517489 A CN 109517489A CN 201811378018 A CN201811378018 A CN 201811378018A CN 109517489 A CN109517489 A CN 109517489A
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CN
China
Prior art keywords
parts
component
water
byk
floor material
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201811378018.XA
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Chinese (zh)
Inventor
陈亮
陈遵厚
谢桂秀
陈军军
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Fuzhou Royal Floor Co Ltd
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Fuzhou Royal Floor Co Ltd
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Priority to CN201811378018.XA priority Critical patent/CN109517489A/en
Publication of CN109517489A publication Critical patent/CN109517489A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D163/00Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08Anti-corrosive paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/20Diluents or solvents
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/30Sulfur-, selenium- or tellurium-containing compounds
    • C08K2003/3045Sulfates

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Floor Finish (AREA)

Abstract

The invention discloses a kind of water-base epoxy anti-corrosion floor materials, including component A and B component, raw materials used component A includes: 8-10 parts of distilled water, 85-90 parts of E-20 epoxy resin, 1-3 parts of propylene glycol monomethyl ether, 12 1-3 parts of alcohol ester, 1-5 parts of mill base, 40-50 parts of talcum powder, 10-15 parts of silica flour, 10-15 parts of barium sulfate, 0.1-0.5 parts of BYK-348,0.1-0.3 parts of BYK-024,0.2-0.6 parts of BYK-191 by weight;Raw materials used B component includes: 40-50 parts of water-base epoxy fatty amine curing agent, 1-5 parts of isothiazolinone, 0.1-0.5 parts of polyether polyurethane by weight.The water-base epoxy anti-corrosion floor material is using water as decentralized medium, environmentally protective, Diamond Search, in moist environment construction and solidification, has wearability good, and soft glossy has good antiseptic property.

Description

Water-base epoxy anti-corrosion floor material
Technical field
The invention belongs to floor material technical fields, and in particular to a kind of water-base epoxy anti-corrosion floor material.
Background technique
Aqueous epoxy floor is a kind of using epoxy resin as the floor material of raw material, and epoxy resin is with the shape of particle or drop Formula be dispersed in using water as in the decentralized medium of continuous phase and with stable dispersion system.It is aqueous compared with existing anti-corrosion terrace Epoxide terrace is environmentally protective using water as decentralized medium, Diamond Search, in moist environment construction and solidification, has wearability good, Soft glossy has good antiseptic property.On the basis of industry ground slab is obtained and is widely applied, floor paint has become China's hair Fastest one of industry is opened up, people is obtained and widely pays close attention to.Aqueous epoxy floor its as a kind of Novel terrace material, It manufactures and is widely used in industry, be primarily adapted for use in electroplate factory, Battery Plant, chemical plant, electrolytic cell, pharmaceutical factory, acid-base neutralization pond Ground, metope and the equipment surface in equal places.But often there is floor coatings material point in anti-corrosion terrace in the prior art Minor structure defective tightness leads to not reach ideal anti-corrosion effect.Aqueous epoxy resins refer to epoxy resin with particle or liquid The form of drop be dispersed in using water as in the decentralized medium of continuous phase and with stable dispersion system, particle surface in the system Curative concentration is relatively mild, and surface cure speed is slower, and solidification agent molecule has time enough to be diffused into entire epoxy resin Dispersed phase particles are allowed to completion of cure, thus can be formed uniformly, the film that is fully cured, with excellent corrosion-resistant Performance.Water-base epoxy anti-corrosion floor material of the present invention is using water as decentralized medium simultaneously, environmentally protective, Diamond Search, and existing anti- Rotten terrace generally contains volatile organic compounds, and smell is difficult to eliminate, dissolvent residual overlong time, and containing benzene has victimization The substance of body health.As the improvement of people's living standards, the quality and environmental protection standard requirement to terrace are higher, therefore aqueous ring Oxygen anti-corrosion terrace becomes the popular research direction of floor material.
Summary of the invention
The purpose of the present invention is to provide a kind of water-base epoxy anti-corrosion floor material, the property epoxy that the present invention is prepared is anti- Rotten terrace is environmentally protective using water as decentralized medium, Diamond Search, in moist environment construction and solidification, has wearability good, light Pool is soft, has good antiseptic property.
To achieve the above object, the present invention adopts the following technical scheme:
A kind of water-base epoxy anti-corrosion floor material, including component A and B component, raw materials used component A includes: to steam by weight 8-10 parts of distilled water, 85-90 parts of E-20 epoxy resin, 1-3 parts of propylene glycol monomethyl ether, 12 1-3 parts of alcohol ester, 1-5 parts of mill base, talcum powder 40-50 parts, 10-15 parts of silica flour, 10-15 parts of barium sulfate, 0.1-0.5 parts of BYK-348,0.1-0.3 parts of BYK-024, BYK- 191 0.2-0.6 parts.
Raw materials used B component includes: 40-50 parts of water-base epoxy fatty amine curing agent, isothiazolinone 1-5 by weight Part, 0.1-0.5 parts of polyether polyurethane.
The component A and the weight ratio of B component cooperation are 5:1.
A kind of water-base epoxy anti-corrosion floor material, preparation method the following steps are included:
(1) E-20 epoxy resin, propylene glycol monomethyl ether, alcohol ester 12, barium sulfate are uniformly mixed at normal temperature, at normal temperature 1500r/ Min is stirred 40 minutes;
(2) distilled water, mill base, talcum powder, silica flour, BYK-348, BYK-024, BYK- are added in the mixture of step (1) 191, it is uniformly mixed under room temperature, 1200r/min is stirred 30 minutes, obtains pretreated component A;
(3) pretreated component A is uniformly mixed to obtain water-base epoxy anti-corrosion floor material by weight 5:1 with B component.
The present invention has the advantages that
The present invention is mixed with to obtain water-base epoxy anti-corrosion floor material, using water as decentralized medium, green ring by two-component It protects, is free of volatile organic compounds, in moist environment construction and solidification, have wearability good, soft glossy has good Antiseptic property, meet the technical indicator of every aqueous epoxy floor.
Specific embodiment
Further to disclose rather than the present invention is limited, the present invention is described in further detail below in conjunction with example.
Embodiment 1
A kind of water-base epoxy anti-corrosion floor material, including component A and B component, it is characterised in that: component A is raw materials used by weight Part meter includes: 8 parts of distilled water, 85 parts of E-20 epoxy resin, 1 part of propylene glycol monomethyl ether, 12 parts of alcohol ester, 1 part of mill base, talcum powder 40 parts, 10 parts of silica flour, 10 parts of barium sulfate, 0.1 part of BYK-348,0.1 part of BYK-024,0.2 part of BYK-191.
It includes: 40 parts of water-base epoxy fatty amine curing agent that B component is raw materials used by weight, 1 part of isothiazolinone, is gathered 0.1 part of ether-based polyurethane.
Component A and the weight ratio of B component cooperation are 5:1
Embodiment 2
A kind of water-base epoxy anti-corrosion floor material, including component A and B component, it is characterised in that: component A is raw materials used by weight Part meter includes: 8 parts of distilled water, 88 parts of E-20 epoxy resin, 2 parts of propylene glycol monomethyl ether, 12 parts of alcohol ester, 3 parts of mill base, talcum powder 45 parts, 13 parts of silica flour, 13 parts of barium sulfate, 0.2 part of BYK-348,0.2 part of BYK-024,0.4 part of BYK-191.
It includes: 45 parts of water-base epoxy fatty amine curing agent that B component is raw materials used by weight, 3 parts of isothiazolinone, is gathered 0.3 part of ether-based polyurethane.
Component A and the weight ratio of B component cooperation are 5:1.
Embodiment 3
A kind of water-base epoxy anti-corrosion floor material, including component A and B component, it is characterised in that: component A is raw materials used by weight Part meter includes: 10 parts of distilled water, 90 parts of E-20 epoxy resin, 3 parts of propylene glycol monomethyl ether, 12 parts of alcohol ester, 5 parts of mill base, talcum powder 50 parts, 15 parts of silica flour, 15 parts of barium sulfate, 0.5 part of BYK-348,0.3 part of BYK-024,0.6 part of BYK-191.
It includes: 50 parts of water-base epoxy fatty amine curing agent that B component is raw materials used by weight, 5 parts of isothiazolinone, is gathered 0.5 part of ether-based polyurethane.
Component A and the weight ratio of B component cooperation are 5:1.
Comparative example
A kind of water-base epoxy anti-corrosion floor material, including component A and B component, it is characterised in that: component A is raw materials used by weight Part meter includes: 10 parts of distilled water, 90 parts of E-20 epoxy resin, 3 parts of propylene glycol monomethyl ether, 12 parts of alcohol ester, 5 parts of mill base, talcum powder 50 parts, 15 parts of silica flour, 15 parts of barium sulfate, 0.5 part of BYK-348,0.3 part of BYK-024,0.6 part of BYK-191.
Raw materials used B component includes: 50 parts of two diammonium hydrogen by weight.
Component A and the weight ratio of B component cooperation are 5:1.
Water-base epoxy anti-corrosion floor material in embodiment and comparative example, the preparation method is as follows:
(1) E-20 epoxy resin, propylene glycol monomethyl ether, alcohol ester 12, barium sulfate are uniformly mixed at normal temperature, at normal temperature 1500r/ Min is stirred 40 minutes;
(2) distilled water, mill base, talcum powder, silica flour, BYK-348, BYK-024, BYK- are added in the mixture of step (1) 191, it is uniformly mixed under room temperature, 1200r/min is stirred 30 minutes, obtains pretreated component A;
(3) pretreated component A is uniformly mixed to obtain water-base epoxy anti-corrosion floor material by weight 5:1 with B component.
The performance parameter for preparing obtained floor material is shown in Table 1:
The measured performance parameter of table 1 embodiment and comparative example terrace
The foregoing is merely presently preferred embodiments of the present invention, all equivalent changes done according to scope of the present invention patent with repair Decorations, are all covered by the present invention.

Claims (4)

1. a kind of water-base epoxy anti-corrosion floor material, including component A and B component, it is characterised in that: component A is raw materials used by weight Measuring part meter includes: 8-10 parts of distilled water, 85-90 parts of E-20 epoxy resin, 1-3 parts of propylene glycol monomethyl ether, 12 1-3 parts of alcohol ester, color Starch 1-5 parts, 40-50 parts of talcum powder, 10-15 parts of silica flour, 10-15 parts of barium sulfate, 0.1-0.5 parts of BYK-348, BYK-024 0.1-0.3 parts, 0.2-0.6 parts of BYK-191.
2. a kind of water-base epoxy anti-corrosion floor material according to claim 1, it is characterised in that: B component is raw materials used by weight Measuring part meter includes: 40-50 parts of water-base epoxy fatty amine curing agent, 1-5 parts of isothiazolinone, 0.1-0.5 parts of polyether polyurethane.
3. water-base epoxy anti-corrosion floor material according to claim 1, it is characterised in that: the weight of component A and B component cooperation Than for 5:1.
4. one kind as described in claim 1-3 is any water-base epoxy anti-corrosion floor material, which is characterized in that preparation method include with Lower step:
(1) E-20 epoxy resin, propylene glycol monomethyl ether, alcohol ester 12, barium sulfate are uniformly mixed at normal temperature, at normal temperature 1500r/ Min is stirred 40 minutes;
(2) distilled water, mill base, talcum powder, silica flour, BYK-348, BYK-024, BYK- are added in the mixture of step (1) 191, it is uniformly mixed under room temperature, 1200r/min is stirred 30 minutes, obtains pretreated component A;
(3) pretreated component A is uniformly mixed to obtain water-base epoxy anti-corrosion floor material by weight 5:1 with B component.
CN201811378018.XA 2018-11-19 2018-11-19 Water-base epoxy anti-corrosion floor material Pending CN109517489A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110028872A (en) * 2019-04-17 2019-07-19 广州百翼新材料有限公司 A kind of soft terrain paint and processing technology
CN110527399A (en) * 2019-08-29 2019-12-03 胡纹菲 A kind of preparation method of wear-resisting type epoxide terrace resistant to chemical etching
CN111763458A (en) * 2020-05-29 2020-10-13 英德市黑马涂料有限公司 High-gloss high-hardness water-based epoxy floor coating and preparation method thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1597812A (en) * 2004-08-20 2005-03-23 广州秀珀化工有限公司 Water epoxy paint for ground floor and its mfg. process and construction technology
CN101724332A (en) * 2009-12-30 2010-06-09 洛阳七维防腐工程材料有限公司 Waterborne epoxy self-leveling floor coating
CN107858072A (en) * 2017-11-17 2018-03-30 湖南太子化工涂料有限公司 A kind of water-based floor coatings
CN107868570A (en) * 2017-11-24 2018-04-03 福州皇家地坪有限公司 Water-base epoxy decorative pattern paint

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1597812A (en) * 2004-08-20 2005-03-23 广州秀珀化工有限公司 Water epoxy paint for ground floor and its mfg. process and construction technology
CN101724332A (en) * 2009-12-30 2010-06-09 洛阳七维防腐工程材料有限公司 Waterborne epoxy self-leveling floor coating
CN107858072A (en) * 2017-11-17 2018-03-30 湖南太子化工涂料有限公司 A kind of water-based floor coatings
CN107868570A (en) * 2017-11-24 2018-04-03 福州皇家地坪有限公司 Water-base epoxy decorative pattern paint

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110028872A (en) * 2019-04-17 2019-07-19 广州百翼新材料有限公司 A kind of soft terrain paint and processing technology
CN110527399A (en) * 2019-08-29 2019-12-03 胡纹菲 A kind of preparation method of wear-resisting type epoxide terrace resistant to chemical etching
CN111763458A (en) * 2020-05-29 2020-10-13 英德市黑马涂料有限公司 High-gloss high-hardness water-based epoxy floor coating and preparation method thereof

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Application publication date: 20190326