CN109517458A - A kind of preparation method of the light laminated type multicolor finish of material-saving - Google Patents
A kind of preparation method of the light laminated type multicolor finish of material-saving Download PDFInfo
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- CN109517458A CN109517458A CN201811380262.XA CN201811380262A CN109517458A CN 109517458 A CN109517458 A CN 109517458A CN 201811380262 A CN201811380262 A CN 201811380262A CN 109517458 A CN109517458 A CN 109517458A
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- deionized water
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D183/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
- C09D183/04—Polysiloxanes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/29—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for multicolour effects
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Plant Pathology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses a kind of preparation methods of the light laminated type multicolor finish of material-saving.Preparation including protecting sol solution, the preparation of base paint, continuous phase preparation and the preparation of finished product paint.The present invention is mainly with the reaction of a variety of special chemicals and process means; with colloid protection technique; change surface state; the water-base resin coating refinement of liquid is rolled into gelatinous various hydrate colour coating particles; and it is uniform and stable be suspended in special coating, form the liquid colloidal polymer of colourful different size particle.Pass through the artificial grantie series of products of spray mo(u)lding of spray gun special.
Description
Technical field
The present invention relates to paint field more particularly to the preparation methods of aqueous plane multicolor finish.
Background technique
The most consumption of multicolor finish is differed in 0.3 ~ 1kg/ ㎡ currently on the market, to reach full spray, smooth face must lead to
It crosses after manual polishing, consumptive material consumption is artificial.The present invention is a kind of preparation method of the light laminated type multicolor finish of material-saving, it is
On the basis of preparing water paint with special system, after mixing colours, takes off in dust gelatin solution, be made big in the extraordinary synthesis nano Chinese
Small and variform colorful particle is mixed into package continuous phase, and the suspended dispersed particle of composition is sprayed by spray gun special
One-pass molding forms rich in color, the strong imitation stone effect of visual stereoscopic sense.
Summary of the invention
The present invention is exactly in order to improve the defects of above-mentioned technical background, and it is colorful to provide a kind of light laminated type of material-saving
The preparation method of coating, it includes the preparation for protecting sol solution, the preparation of base paint, continuous phase preparation and the preparation of finished product paint.
Protection glue is made of deionized water, protective glue, auxiliary agent；Base paint is filled out by deionized water, cellulose, auxiliary agent, lotion, face
The composition such as material, quartz sand and protective glue；Continuous phase is made of organic silicon emulsion, deionized water, auxiliary agent.It will be adjusted by finished product proportion
Base paint after color, be added premix after protection sol solution in be granulated, then be added continuous phase carry out it is hybrid packed.
The water is deionized water.
The protective glue is the de- soil of the extraordinary synthesis nano Chinese.
The wetting dispersing agent is anionic.
The cellulose is hydrophobically modified hydroxyethyl cellulose.
The coalescing agent 12- ester alcohol.
The PH regulator is the moisture content 2-amino-2-methyl-1-propanol containing 5%.
The base paint lotion is pure C class lotion, and continuous phase emulsion is modified organic silicon emulsion.
The preservative is the isothiazolinone biocide agent of Diamond Search (organic volatile).
Specific embodiment:
More detailed elaboration is carried out to the present invention below, in order to be understood by industry field technical staff, thus to the present invention
Protection scope be bound.
Embodiment one,
It is as follows for the preparation ratio of each section in the present invention.
Protect the preparation of sol solution: deionized water 95%, protective glue 5%, preservative 0.3%；
Production explanation: weighing deionized water in formula, and modified synthesis silicate be added, and it is small that half is dispersed under 800-1000 revolving speed
When, it is spare to add preservative placement 12h or more.
The preparation of base paint: deionized water 50.55%, wetting agent 0.05%, powder 0.1%, 0.2 % of defoaming agent, ethoxy are fine
Dimension element 0.8%, rutile type titanium white 0.5%, superfine calcined kaolin 6%, multifunctional assistant 0.1%, coalescing agent 0.3%, the third two
0.8 % of alcohol, lotion 30%, thickener 0.6 protect solution 10%；
Production explanation: weighing deionized water in formula, successively sequentially add wetting agent in the case where mixing slowly, dispersing agent, defoaming agent,
Then hydroxyethyl cellulose is added to stir 3-5 minutes, improves revolving speed to 800 turns, improves revolving speed extremely after paint filler is added
1500-1800 turns of dispersion stirrings 30 minutes or so, fineness control reduce and successively add under revolving speed to 500-800 revolving speeds in≤50um
Enter multifunctional assistant, propylene glycol, coalescing agent, lotion, thickener and protection sol solution etc., place after mixing evenly 12 hours with
It is upper spare.
The preparation of continuous phase: deionized water 28.3%, preservative agent 0.2%, propylene glycol 1%, coalescing agent 4%, lotion 65%,
Defoaming agent 0.2%, multifunctional assistant 0.1%, thickener 1.2%.；
Production explanation: deionized water in formula is weighed, component below is successively sequentially added in the case where mixing slowly, 800 turns of revolving speed are stirred
Mix uniformly, reduce and be slowly added to thickener under revolving speed to 300-500 revolving speeds, place after mixing evenly 12 hours or more it is spare.
The preparation of finished product paint: protection sol solution 25%, deionized water 10%, base paint color tablets 40%, continuous phase 25%.
Production explanation: weigh formula in protection sol solution, deionized water low speed 300-500 turn premix uniformly after, sequentially add
Each base paint after toning carries out color spot dispersion and is granulated, adjusts mechanical separator speed according to required color spot size and jitter time is long
It is short, it is eventually adding continuous phase and stirs evenly.
Embodiment two,
It is as follows for the preparation ratio of each section in the present invention.
Protect the preparation of sol solution: deionized water 93.5%, protective glue 6.5%, preservative 0.3%；
Production explanation: weighing deionized water in formula, and modified synthesis silicate be added, and it is small that half is dispersed under 800-1000 revolving speed
When, it is spare to add preservative placement 12h or more.
The preparation of base paint: deionized water 51.7%, wetting agent 0.1%, dispersing agent 0.2%, 0.35 % of defoaming agent, ethoxy
Cellulose 1%, rutile type titanium white 0.8%, superfine calcined kaolin 11%, 0.15 % of multifunctional assistant, coalescing agent 0.4%,
0.9 % of propylene glycol, lotion 25%, thickener 0.4 protect solution 8%；
Production explanation: weighing deionized water in formula, successively sequentially add wetting agent in the case where mixing slowly, dispersing agent, defoaming agent,
Then hydroxyethyl cellulose is added to stir 3-5 minutes, improves revolving speed to 800 turns, improves revolving speed extremely after paint filler is added
1500-1800 turns of dispersion stirrings 30 minutes or so, fineness control reduce and successively add under revolving speed to 500-800 revolving speeds in≤50um
Enter multifunctional assistant, propylene glycol, coalescing agent, lotion, thickener and protection sol solution etc., place after mixing evenly 12 hours with
It is upper spare.
The preparation of continuous phase: deionized water 22.35%, preservative agent 0.3%, propylene glycol 1.5%, coalescing agent 4.5%, lotion
70 defoaming agents 0.3%, multifunctional assistant 0.15%, thickener 0.9%；
Production explanation: deionized water in formula is weighed, component below is successively sequentially added in the case where mixing slowly, 800 turns of revolving speed are stirred
Mix uniformly, reduce and be slowly added to thickener under revolving speed to 300-500 revolving speeds, place after mixing evenly 12 hours or more it is spare.
The preparation of finished product paint: protection sol solution 22%, deionized water 6%, base paint color tablets 50%, continuous phase 22%；
Production explanation: weigh formula in protection sol solution, deionized water low speed 300-500 turn premix uniformly after, sequentially add
Each base paint after toning carries out color spot dispersion and is granulated, adjusts mechanical separator speed according to required color spot size and jitter time is long
It is short, it is eventually adding continuous phase and stirs evenly.
Embodiment three,
It is as follows for the preparation ratio of each section in the present invention.
Protect the preparation of sol solution: deionized water 92%, protective glue 8%, preservative 0.3%；
Production explanation: weighing deionized water in formula, and modified synthesis silicate be added, and it is small that half is dispersed under 800-1000 revolving speed
When, it is spare to add preservative placement 12h or more.
The preparation of base paint: deionized water 56%, wetting agent 0.2%, dispersing agent 0.3%, 0.4 % of defoaming agent, hydroxy ethyl fiber
Element 1.2%, rutile type titanium white 1%, superfine calcined kaolin 13%, 0.2 % of multifunctional assistant, coalescing agent 0.5%, propylene glycol
1 %, lotion 20%, thickener 0.2 protect solution 6%；
Production explanation: weighing deionized water in formula, successively sequentially add wetting agent in the case where mixing slowly, dispersing agent, defoaming agent,
Then hydroxyethyl cellulose is added to stir 3-5 minutes, improves revolving speed to 800 turns, improves revolving speed to 1500- after pigments and fillers are added
1800 turns of dispersions are stirred 30 minutes or so, and fineness control sequentially adds more at≤50um, reduction revolving speed to 500-800 revolving speeds
Function additive, propylene glycol, coalescing agent, lotion, thickener and protection sol solution etc. are placed 12 hours or more standby after mixing evenly
With.
The preparation of continuous phase: deionized water 11.3%, preservative agent 0.4%, propylene glycol 2%, coalescing agent 5%, lotion 80%,
Defoaming agent 0.4%, multifunctional assistant 0.2%, thickener 0.7%；
Production explanation: deionized water in formula is weighed, component below is successively sequentially added in the case where mixing slowly, 800 turns of revolving speed are stirred
Mix uniformly, reduce and be slowly added to thickener under revolving speed to 300-500 revolving speeds, place after mixing evenly 12 hours or more it is spare.
The preparation of finished product paint: protection sol solution 18%, deionized water 4%, base paint color tablets 60%, continuous phase 18%；
Production explanation: weigh formula in protection sol solution, deionized water low speed 300-500 turn premix uniformly after, sequentially add
Each base paint after toning carries out color spot dispersion and is granulated, adjusts mechanical separator speed according to required color spot size and jitter time is long
It is short, it is eventually adding continuous phase and stirs evenly.
The present invention is not limited to the above embodiments, can be implemented described in the content of present invention and has the good result.
Claims (8)
1. a kind of preparation method of the light laminated type multicolor finish of material-saving, the preparation comprising protecting sol solution: deionized water 92-
95%, protective glue 5-8%, the preparation of 0.3% base paint of preservative: deionized water 50-56%, hydroxyethyl cellulose 0.8-1.2%,
Rutile type titanium white 0.5-1%, superfine calcined kaolin 6-13%, wetting agent 0.05-0.2%, multifunctional assistant 0.1-0.2 %,
Dispersing agent 0.1-0.3%, defoaming agent 0.2-0.4 %, coalescing agent 0.3-0.5%, propylene glycol 0.8-1 %, colorful lotion 20-30%,
Thick dose of 0.2-0.6 protects solution 6-10%.
2. the preparation of continuous phase: deionized water 11-28.5%, preservative agent 0.2-0.4%, propylene glycol 1-2%, coalescing agent 4-
The preparation of thickener 0.5-1%. finished product paint: 5%, lotion 65-80%, defoaming agent 0.2-0.4%, multifunctional assistant 0.1-0.2% are protected
Protect sol solution 18-25%, deionized water 4-10%, base paint color tablets 40-60%, continuous phase 18-25%.
3. meeting water according to the method described in claim 1, the protective glue is the de- soil of the extraordinary synthesis nano Chinese and forming gel
Shape provides steric hindrance in multi-color.
4. meet environmental requirement according to the method described in claim 1, the wetting dispersing agent is anionic and be free of APEO,
Make in colorful color tablets import negative electricity layer to repel each other, glue connection can be generated with hydroxyethyl cellulose and react, " hydrophilic " color dot turn is made
Turn to " hydrophobic " color dot.
5. making basis in colorful according to the method described in claim 1, the cellulose is hydrophobically modified hydroxyethyl cellulose
Qi Wending provides the low-shear viscosity of base paint, facilitates granulation.
6. according to the method described in claim 1, the base paint lotion is pure C class lotion, in colorful middle raising water resistance and
Hydrophobicity；Continuous phase emulsion then selects modified organic silicon emulsion, improves water resistance and anti-pollution characteristic.
7. according to the method described in claim 1, the coalescing agent 12- ester alcohol；PH regulator is the moisture content -2- ammonia containing 5%
Base-2- methyl-1-propyl alcohol.
8. Diamond Search is (organic according to the method described in claim 1, the preservative is that one kind with univalent metal salt makees stabilizer
Volatile matter) isothiazolinone biocide agent.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811380262.XA CN109517458A (en) | 2018-11-20 | 2018-11-20 | A kind of preparation method of the light laminated type multicolor finish of material-saving |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811380262.XA CN109517458A (en) | 2018-11-20 | 2018-11-20 | A kind of preparation method of the light laminated type multicolor finish of material-saving |
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| Publication Number | Publication Date |
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| CN109517458A true CN109517458A (en) | 2019-03-26 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201811380262.XA Pending CN109517458A (en) | 2018-11-20 | 2018-11-20 | A kind of preparation method of the light laminated type multicolor finish of material-saving |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112812595A (en) * | 2021-01-21 | 2021-05-18 | 四川华邦保和涂料有限公司 | Inorganic magic color liquid particle and preparation method thereof |
| CN115678372A (en) * | 2022-10-14 | 2023-02-03 | 江西易必居新型建材有限公司 | Novel colorful stone-like paint and preparation method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3058932A (en) * | 1958-04-21 | 1962-10-16 | Sherwin Williams Co | Multicolor coating composition and method for preparation thereof |
| CN103333566A (en) * | 2013-06-05 | 2013-10-02 | 新疆屯河涂料有限公司 | Environmentally-friendly waterborne multicolor paint, preparation method and application method thereof |
-
2018
- 2018-11-20 CN CN201811380262.XA patent/CN109517458A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3058932A (en) * | 1958-04-21 | 1962-10-16 | Sherwin Williams Co | Multicolor coating composition and method for preparation thereof |
| CN103333566A (en) * | 2013-06-05 | 2013-10-02 | 新疆屯河涂料有限公司 | Environmentally-friendly waterborne multicolor paint, preparation method and application method thereof |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112812595A (en) * | 2021-01-21 | 2021-05-18 | 四川华邦保和涂料有限公司 | Inorganic magic color liquid particle and preparation method thereof |
| CN115678372A (en) * | 2022-10-14 | 2023-02-03 | 江西易必居新型建材有限公司 | Novel colorful stone-like paint and preparation method thereof |
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Application publication date: 20190326 |