CN109504562A - A kind of cleaning agent for kitchen and preparation method thereof - Google Patents

A kind of cleaning agent for kitchen and preparation method thereof Download PDF

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Publication number
CN109504562A
CN109504562A CN201811382502.XA CN201811382502A CN109504562A CN 109504562 A CN109504562 A CN 109504562A CN 201811382502 A CN201811382502 A CN 201811382502A CN 109504562 A CN109504562 A CN 109504562A
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parts
kitchen
cleaning agent
alkaline water
sodium
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CN109504562B (en
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台明栋
池天能
周信健
莫树艺
莫火旺
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Foshan Health Care Technology Co Ltd
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Foshan Health Care Technology Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/50Solvents
    • C11D7/5004Organic solvents
    • C11D7/5022Organic solvents containing oxygen
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005Other compounding ingredients characterised by their effect
    • C11D3/0073Anticorrosion compositions
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/02Inorganic compounds
    • C11D7/04Water-soluble compounds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/02Inorganic compounds
    • C11D7/04Water-soluble compounds
    • C11D7/10Salts
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/02Inorganic compounds
    • C11D7/04Water-soluble compounds
    • C11D7/10Salts
    • C11D7/12Carbonates bicarbonates
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/02Inorganic compounds
    • C11D7/04Water-soluble compounds
    • C11D7/10Salts
    • C11D7/14Silicates
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/02Inorganic compounds
    • C11D7/04Water-soluble compounds
    • C11D7/10Salts
    • C11D7/16Phosphates including polyphosphates
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/22Organic compounds
    • C11D7/26Organic compounds containing oxygen
    • C11D7/261Alcohols; Phenols
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/22Organic compounds
    • C11D7/32Organic compounds containing nitrogen
    • C11D7/3218Alkanolamines or alkanolimines
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/22Organic compounds
    • C11D7/40Products in which the composition is not well defined
    • C11D7/44Vegetable products

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Detergent Compositions (AREA)

Abstract

The invention belongs to daily chemicals fields, specifically disclose a kind of cleaning agent for kitchen, are mainly made of the raw material of following portions by weight: 90~100 parts of electrolyzed alkaline water, 0.1~5 part of corrosion inhibiter, 0.1~3 part of ethanol amine, 2~15 parts of alcohols solvent, 2~5 parts of sodium metasilicate, 1~5 part of coconut oil;Wherein, the pH of the electrolyzed alkaline water is 11.5-13.0, and oxidation-reduction potential is -500~-1500mV.Cleaning agent for kitchen property in the present invention is mild, can be suitable for the cleaning of the kitchen utensils of various materials;And by being reasonably formulated, cleaning effect is improved;Meanwhile the invention also discloses the preparation methods of above-mentioned cleaning agent for kitchen.

Description

A kind of cleaning agent for kitchen and preparation method thereof
Technical field
The invention belongs to daily chemicals fields, and in particular to a kind of cleaning agent for kitchen and preparation method thereof.
Background technique
Common cleaning agent for kitchen is broadly divided into strong base, solvent type and surfactant type.Wherein, strong base greasy dirt is clear Highly basic, such as caustic alkali, potassium hydroxide are often added in lotion, such cleaning agent has good dissolution to greasy dirt, but rotten Corrosion is stronger, will cause stimulation and injury particularly with the skin of user;The solvent of solvent type greasy dirt detergent early application For the stronger organic solvent of the solvabilities such as acetone, but acetone is volatile solvent, in the production and transportation of greasy dirt detergent It will form some potential safety problems in the process, manufacturing condition is also more complicated.Ethers is commonly used in later period improved technology to make For organic solvent, but the boiling point of ethyl alcohol is also relatively low, and the smell is awful for ether organic solvent, pungent, and some is even prolonged Use process will cause phenomena such as dizzy number of people, vomiting;Surfactant type greasy dirt detergent action temperature and, but the removal to the heavy scale Effect is not satisfactory, needs substrate product to be immersed in the solution containing cleaning agent the long period in actual use.In addition, The greasy dirt detergent waste liquid of first two type contains a small amount of alkali and organic solvent, and direct emission is unfavorable for environmental protection.
Surfactant type cleaning agent is cleaning agent most promising at present, in order to improve it for kitchen spot Cleaning ability, often need make improvements.A kind of improved method is the surfactant that selection is more suitable for, such as starch base Surfactant;Chinese patent application 201410554381.8 is to disclose a kind of kitchen cleaning of starch based surfactants Agent, but this starch based surfactants preparation cost is high.Another improved mode is in surfactant type cleaning agent Add alkaline matter, such as sodium hydroxide, sodium carbonate: Chinese patent application 201110132810.9 is added in cleaning agent Sodium hydroxide or potassium hydroxide;But this cleaning agent is strong to some substance corrosivity, and use scope is smaller.
On the other hand, with the increasingly raising of people's living standard, kitchen utensils etc. it is more and more using artificial quartz stone, The materials such as lithotome, resin are made;By taking artificial quartz stone as an example, preparing raw material is mostly unsaturated polyester resin, using mesh Preceding cleaning agent tends to corrosion artificial quartz stone.Therefore, it is necessary to develop a kind of novel cleaning agent, it is adaptable to current kitchen Room environment.
Summary of the invention
Technical problem to be solved by the present invention lies in, a kind of cleaning agent for kitchen is provided, action temperature and, cleaning effect is good It is good, it is non-corrosive, it is applied widely.
The present invention also technical problems to be solved are that provide a kind of preparation method of cleaning agent for kitchen, method is simple, Preparation cost is low.
In order to solve the above technical problem, the present invention provides a kind of cleaning agent for kitchen, mainly by following portions by weight Raw material is made: 90~100 parts of electrolyzed alkaline water, 0.1~5 part of corrosion inhibiter, and 0.1~3 part of ethanol amine, 2~15 parts of alcohols solvent, silicon 2~5 parts of sour sodium, 1~5 part of coconut oil;
The electrolyzed alkaline water the preparation method comprises the following steps:
(1) sodium carbonate or solution of potassium carbonate, pure water are prepared;
(2) circulation is passed through sodium carbonate liquor or solution of potassium carbonate in the anode compartment, and circulation is passed through pure water in the cathodic compartment;
(3) it is powered after electrolysis and obtains electrolyzed alkaline water finished product in the cathode chamber;
The pH of the electrolyzed alkaline water is 11.5-13.0, and oxidation-reduction potential is -500~-1500mV.
As an improvement of the above technical solution, the alcohols solvent is in propylene glycol, isopropanol, n-butanol, menthol One kind or combination.
As an improvement of the above technical solution, the alcohols solvent is the mixture of propylene glycol and menthol;Propylene glycol with The weight ratio of menthol is 1:(3~5).
As an improvement of the above technical solution, the corrosion inhibiter is selected from sodium tetraborate, sodium chromate, sodium tripolyphosphate, benzo One of triazole, methyl benzotriazazole or combination;
The ethanol amine selects monoethanolamine, diethanol amine or triethanolamine.
As an improvement of the above technical solution, the modulus of the sodium metasilicate is 2.2~3.4, and density is 1.32~1.48g/ cm3
As an improvement of the above technical solution, it is mainly made of the raw material of following weight parts: electrolyzed alkaline water 95~100 Part, 0.2~1 part of benzotriazole, 0.5~1 part of sodium tetraborate, 0.1~1 part of monoethanolamine, 3~5 parts of sodium metasilicate, coconut oil 1 ~3 parts, 0.5~2 part of propylene glycol, 2~10 parts of menthol;
Wherein, the pH of the electrolyzed alkaline water is 12.3~12.8, and oxidation-reduction potential is -500~-1000mV.
As an improvement of the above technical solution, it is made of the raw material of following weight parts: 97 parts of electrolyzed alkaline water, benzo three 0.4 part of nitrogen azoles, 0.6 part of sodium tetraborate, 0.4 part of monoethanolamine, 3.5 parts of sodium metasilicate, 3 parts of coconut oil, 1.5 parts of propylene glycol, peppermint 5 parts of alcohol;
Wherein, the modulus of the sodium metasilicate is 2.8, density 1.42g/cm3
The pH of the electrolyzed alkaline water is 12.5, and oxidation-reduction potential is -800mV.
As an improvement of the above technical solution, diaphragm is equipped between the anode chamber and cathode chamber, the diaphragm can pass through Na+、K+
As an improvement of the above technical solution, the mass concentration of the sodium carbonate liquor is 10-40%, and conductivity is 5000-10000mS/m;Or
The mass concentration of the solution of potassium carbonate is 5-20%, conductivity 12000-50000mS/m;
The total dissolved solid < 12mg/L of the pure water.
Correspondingly, the invention also discloses a kind of preparation methods of above-mentioned cleaning agent for kitchen comprising:
One, electrolyzed alkaline water is prepared
Two, by 90~100 parts of electrolyzed alkaline water, 2~15 parts of alcohols solvent mixing, it is added 1~5 part of coconut oil;It is warming up to It 50-70 DEG C, reacts 30-60 minutes;
Three, 0.1~5 part of corrosion inhibiter of addition in the solution obtained in step 2,0.1~3 part of ethanol amine, sodium metasilicate 2~5 Part;It is uniformly mixed and obtains cleaning agent for kitchen finished product.
The invention discloses a kind of cleaning agent for kitchen, use electrolyzed alkaline water, corrosion inhibiter, ethanol amine, alcohols solvent, silicon Sour sodium, coconut oil are that cleaning agent for kitchen has been prepared in raw material, and the beneficial effects of the practice of the present invention is as follows:
1. the present invention uses electrolyzed alkaline water for primary raw material, cleaning agent for kitchen is prepared, due to electrolyzed alkaline water In contain a large amount of small-micelle water, it is strong to the penetrating power of various kitchen dirts;And in alkaline electrolysis water energy and kitchen dirt Greasy dirt saponification occurs at normal temperature, accelerate solution rate;Further, pass through electrolyzed alkaline water and corrosion inhibiter, second The comprehensive function of hydramine, solvent, sodium metasilicate, coconut oil etc., effectively improves cleaning effect, enables cleaning agent in the present invention It is enough quickly to remove all kinds of kitchen spots at normal temperature.
2. the cleaning agent for kitchen formula in the present invention does not rationally contain strong alkaline substance, without containing having with irritating Solvent;Its property is mild, will not corrode all kinds of kitchen utensils, especially novel artificial quartz stone, lithotome, resinae Equal kitchen utensils.Meanwhile this cleaning agent for kitchen free from extraneous odour, it is environmental-friendly, to no damage to human body.
3. cleaning agent for kitchen in the present invention, as solvent, is greatly improved pair using the mixture of propylene glycol and menthol The removal effect of kitchen spot;Menthol is commonly used for fragrance, and unexpected good result is achieved after mixed with propylene glycol.
4. not containing surfactant in the cleaning agent in the present invention, without rinsing, cleaning step is simple.Contain in cleaning agent There is release sustaining component, corrosion of the cleaning agent for all kinds of kitchen utensils can be effectively prevent.
Specific embodiment
To make the object, technical solutions and advantages of the present invention clearer, the present invention will be made below further detailed Description.
The invention discloses a kind of cleaning agent for kitchen, are mainly made of the raw material of following portions by weight: electrolyzed alkaline water 90~100 parts, 0.1~5 part of corrosion inhibiter, 0.1~3 part of ethanol amine, 2~15 parts of alcohols solvent, 2~5 parts of sodium metasilicate, coconut oil 1 ~5 parts;
Existing surfactant type cleaning agent for kitchen needs to clean at relatively high temperatures, and cleaning effect is poor;And due to Ingredient relationship, can not be suitable for the cleaning of resinae, the kitchen utensils of natural stone class, artificial quartz stone class.It is asked to solve this Topic, cleaning agent for kitchen has been prepared as primary raw material using electrolyzed alkaline water in the present invention, due to containing in electrolyzed alkaline water A large amount of small-micelle water is strong to the penetrating power of various kitchen dirts;And the greasy dirt in alkaline electrolysis water energy and kitchen dirt Saponification occurs at normal temperature, accelerates solution rate;Further, by electrolyzed alkaline water and corrosion inhibiter, ethanol amine, molten The comprehensive function of agent, sodium metasilicate, coconut oil etc., effectively improves cleaning effect, enables the cleaning agent in the present invention normal All kinds of kitchen spots are quickly removed under temperature;Meanwhile the cleaning agent for kitchen property in the present invention is mild, and is reproducibility, it will not be rotten Kitchen utensils are lost, all kinds of kitchen utensils can be suitable for, be particularly suitable for the kitchen of resinae, natural stone class, artificial quartz stone class Room apparatus.
Wherein, electrolyzed alkaline water the preparation method comprises the following steps:
(1) sodium carbonate or solution of potassium carbonate, pure water are prepared;
(2) circulation is passed through sodium carbonate liquor or solution of potassium carbonate in the anode compartment, and circulation is passed through pure water in the cathodic compartment;
(3) it is powered after electrolysis and obtains electrolyzed alkaline water finished product in the cathode chamber;
The pH of the electrolyzed alkaline water is 11.5-13.0, and oxidation-reduction potential is -500~-1500mV.
Due to using the preferable sodium carbonate of electric conductivity or solution of potassium carbonate in anode chamber, alkaline electrolysis is significantly reduced The preparation cost of water;Pure water is used in cathode chamber, improves the properties of electrolyzed alkaline water.
On the basis of using this cleaning agent for kitchen, the cleaning process of various kitchen utensils has been significantly simplified, as long as The cleaning agent in the present invention is sprayed at kitchen utensils surface to be cleaned at room temperature, after waiting 2-5 minutes, directly cleaning can have Effect removes various kitchen spots.Further, since this cleaning agent wetting action, solvability are strong, and it is living without containing surface Property agent also further simplifies cleaning process without being rinsed subsequent, shortens scavenging period.
Wherein, alcohols solvent is selected from one of propylene glycol, isopropanol, n-butanol, menthol or combination.Alcohols solvent is not With penetrating odor, property is mild, and cost is relatively low.The addition parts by weight of alcohols solvent are 2~15 parts, further preferably 2.5~12 parts, further preferably 6.5 parts.
Preferably, the alcohols solvent is the mixture of propylene glycol and menthol;Menthol is a kind of important fragrance, this Inventive technique personnel are found through experiments that, menthol and mixed with propylene glycol are used, the removal to kitchen spot can be substantially improved Effect shortens scavenging period, achieves unexpected good result.Preferably, propylene glycol and the weight ratio of menthol are 1: (3~5), further preferably 1:(3-3.5), further preferably 1:(3-3.1-3.4);The propylene glycol of this weight ratio and peppermint The mixture of alcohol has most good cleaning effect.
Wherein, sodium metasilicate has good wetting and emulsifiability, can effectively prevent soil redeposition, and have anticorrosion Effect.Preferably, the modulus of the sodium metasilicate is 2.2~3.4, and density is 1.32~1.48g/cm3, the silicic acid of this modulus range Sodium has suitable density and viscosity, can be effectively compound with the other components in the present invention, promotes the cleaning for kitchen spot Effect.It is further preferred that the modulus of the sodium metasilicate is 2.2~3.0, further preferably 2.6~2.9.Sodium metasilicate adds Entering parts by weight is 2~5 parts, preferably 3~5 parts.
Wherein, corrosion inhibiter is in sodium tetraborate, sodium chromate, sodium tripolyphosphate, benzotriazole, methyl benzotriazazole One kind or combination.These substances all have good corrosion inhibition for materials such as metal, ceramics, natural stone, resins.It is preferred that , the corrosion inhibiter selects one of sodium tetraborate, benzotriazole, methyl benzotriazazole or combination, these types of inhibition Agent is small for the pollution of environment, and does not have peculiar smell;It is further preferred that the corrosion inhibiter selects sodium tetraborate and three nitrogen of benzo The mixture of azoles;And sodium tetraborate: benzotriazole=1:(0.5~1.5);Sodium tetraborate, benzotriazole, sodium metasilicate, alkali Under the collective effect of property electrolysis water, the effect of sustained release, passive metal wrist-watch can be realized.The addition parts by weight of corrosion inhibiter are 0.5 ~3 parts, preferably 0.5~1.5 part.
Wherein, ethanol amine is organic base, and buffer capacity is strong, and property is mild;Ethanol amine can match with alcohols solvent simultaneously Position promotes the removal power for kitchen spot;Preferably, the ethanol amine is selected from monoethanolamine, diethanol amine or triethanolamine, Further preferred is monoethanolamine;The addition parts by weight of ethanol amine are 0.1~3 part, further preferably 0.1~1 part.
In addition, also containing a small amount of coconut oil among the formula of cleaning agent for kitchen of the invention, during the preparation process may be used It reacts with super buck, forms a small amount of surfactant, by the synergistic effect with other components, effectively promote the present invention Removal ability of the middle cleaning agent to various kitchen spots.
In order to preferably play the effect of cleaning agent in the present invention, the cleaning agent in the present invention is preferably formulated as follows: alkali 95~100 parts of electrolysis water of property, 0.2~1 part of benzotriazole, 0.5~1 part of sodium tetraborate, 0.1~1 part of monoethanolamine, sodium metasilicate 3~5 parts, 1~3 part of coconut oil, 0.5~2 part of propylene glycol, 2~10 parts of menthol;
Wherein, the pH of the electrolyzed alkaline water is 12.3~12.8, and oxidation-reduction potential is -500~-1000mV.
It is further preferred that the cleaning agent for kitchen in the present invention is made of the raw material of following weight parts: electrolyzed alkaline water 97 Part, 0.4 part of benzotriazole, 0.6 part of sodium tetraborate, 0.4 part of monoethanolamine, 3.5 parts of sodium metasilicate, 3 parts of coconut oil, propylene glycol 1.5 parts, 5 parts of menthol;
Wherein, the modulus of the sodium metasilicate is 2.8, density 1.42g/cm3
The pH of the electrolyzed alkaline water is 12.5, and oxidation-reduction potential is -800mV.
Electrolyzed alkaline water is most important for the effect of cleaning agent in the present invention, in order to which kitchen of good performance is prepared Cleaning agent, it is necessary to the relevant nature of strict control electrolyzed alkaline water.
The present invention prepares electrolyzed alkaline water by the way of electrolysis sodium carbonate or solution of potassium carbonate, in order to optimize alkaline electrolysis Every property of water needs to control the various properties of raw material.Preferably, the mass concentration of the sodium carbonate liquor is 10-40%, conductivity 5000-10000mS/m;Or the mass concentration of the solution of potassium carbonate is 5-20%, conductivity For 12000-50000mS/m;The total dissolved solid < 12mg/L of the pure water.Meanwhile in the electrolysis installation of use, in sun Diaphragm is equipped between pole room and cathode chamber, the diaphragm can pass through Na+、K+
Correspondingly, the invention also discloses a kind of preparation methods of above-mentioned cleaning agent for kitchen comprising:
One, electrolyzed alkaline water is prepared
Two, by 90~100 parts of electrolyzed alkaline water, 2~15 parts of alcohols solvent mixing, it is added 1~5 part of coconut oil;It is warming up to It 50-70 DEG C, reacts 30-60 minutes;
The electrolyzed alkaline water prepared in the present invention, reactivity is strong, can occur at a lower temperature with coconut oil anti- It answers, forms a small amount of surfactant, promote cleaning effect.
Three, 0.1~5 part of corrosion inhibiter of addition in the solution obtained in step 2,0.1~3 part of ethanol amine, sodium metasilicate 2~5 Part;It is uniformly mixed and obtains cleaning agent for kitchen finished product.
The preparation method of cleaning agent of the present invention is simple, and preparation cost is low.
With specific embodiment, the present invention is further explained below:
Embodiment 1
Formula:
100 parts of electrolyzed alkaline water, 0.5 part of corrosion inhibiter, 0.1 part of ethanol amine, 1 part of coconut oil, 2 parts of sodium metasilicate, 2 parts of solvent;
Wherein, it is -500mV that the pH of electrolyzed alkaline water, which is 11.5, ORP,;Corrosion inhibiter is sodium tetraborate;Ethanol amine is monoethanol Amine;Solvent is ethyl alcohol;Sodium silicate modulus is 2.2, and sodium metasilicate density is 1.32g/cm3
Preparation method:
One, electrolyzed alkaline water is prepared
(1) sodium carbonate liquor, pure water are prepared;
Wherein, the mass concentration of sodium carbonate liquor is 10%, conductivity 5000mS/m;The TDS of pure water is 8mg/ L;
(2) circulation is passed through sodium carbonate liquor in the anode compartment, and circulation is passed through pure water in the cathodic compartment;
(3) it is powered after electrolysis and obtains electrolyzed alkaline water finished product in the cathode chamber;
Two, electrolyzed alkaline water, alcohols solvent are mixed, coconut oil is added;50 DEG C are warming up to, is reacted 60 minutes;
Three, corrosion inhibiter, ethanol amine, sodium metasilicate is added, is uniformly mixed and obtains cleaning agent for kitchen finished product.
Embodiment 2
Formula:
90 parts of electrolyzed alkaline water, 3 parts of corrosion inhibiter, 3 parts of ethanol amine, 5 parts of coconut oil, 5 parts of sodium metasilicate, 15 parts of solvent;
The pH of electrolyzed alkaline water is that 13, ORP is -1500mV;Corrosion inhibiter is sodium tripolyphosphate;Ethanol amine is diethanol amine; The modulus of sodium metasilicate is 3.4, density 1.48g/cm3;Solvent is n-butanol.
Preparation method:
One, electrolyzed alkaline water is prepared
(1) sodium carbonate liquor, pure water are prepared;
Wherein, the mass concentration of sodium carbonate liquor is 40%, conductivity 10000mS/m;The TDS of pure water is 10%;
(2) circulation is passed through sodium carbonate liquor in the anode compartment, and circulation is passed through pure water in the cathodic compartment;
(3) it is powered after electrolysis and obtains electrolyzed alkaline water finished product in the cathode chamber;
Two, electrolyzed alkaline water, alcohols solvent are mixed, coconut oil is added;70 DEG C are warming up to, is reacted 30 minutes;
Three, corrosion inhibiter, ethanol amine, sodium metasilicate is added, is uniformly mixed and obtains cleaning agent for kitchen finished product.
Embodiment 3
Formula
95 parts of electrolyzed alkaline water, 0.7 part of corrosion inhibiter, 1 part of ethanol amine, 3 parts of coconut oil, 2 parts of sodium metasilicate, 2.5 parts of solvent;
The pH of electrolyzed alkaline water is that 12.6, ORP is -850mV;Corrosion inhibiter is benzotriazole;Ethanol amine is monoethanolamine; The modulus of sodium metasilicate is 2.6, density 1.4g/cm3;Solvent is the mixture of propylene glycol and menthol, and wherein propylene glycol is 5 Part, menthol is 1.5 parts.
Preparation method:
One, electrolyzed alkaline water is prepared
(1) solution of potassium carbonate, pure water are prepared;
Wherein, the mass concentration of solution of potassium carbonate is 5%, conductivity 15000mS/m;The TDS of pure water is 5mg/ L;
(2) circulation is passed through solution of potassium carbonate in the anode compartment, and circulation is passed through pure water in the cathodic compartment;
(3) it is powered after electrolysis and obtains electrolyzed alkaline water finished product in the cathode chamber;
Two, electrolyzed alkaline water, alcohols solvent are mixed, coconut oil is added;65 DEG C are warming up to, is reacted 35 minutes;
Three, corrosion inhibiter, ethanol amine, sodium metasilicate is added, is uniformly mixed and obtains cleaning agent for kitchen finished product.
Embodiment 4
Formula
96 parts of electrolyzed alkaline water, 1.8 parts of corrosion inhibiter, 0.6 part of ethanol amine, 2 parts of coconut oil, 3.5 parts of sodium metasilicate, solvent 12 Part;
The pH of electrolyzed alkaline water is that 12.7, ORP is -1000mV;Corrosion inhibiter is the mixing of benzotriazole and sodium tetraborate Object, 0.8 part of benzotriazole, 1 part of sodium tetraborate;Ethanol amine is monoethanolamine;The modulus of sodium metasilicate is 3.2, and density is 1.44g/cm3;Solvent is the mixture of propylene glycol and menthol, and wherein propylene glycol is 2 parts, and menthol is 10 parts.
Preparation method:
One, electrolyzed alkaline water is prepared
(1) solution of potassium carbonate, pure water are prepared;
Wherein, the mass concentration of solution of potassium carbonate is 15%, conductivity 13000mS/m;The TDS of pure water is 4%;
(2) circulation is passed through solution of potassium carbonate in the anode compartment, and circulation is passed through pure water in the cathodic compartment;
(3) it is powered after electrolysis and obtains electrolyzed alkaline water finished product in the cathode chamber;
Two, electrolyzed alkaline water, alcohols solvent are mixed, coconut oil is added;65 DEG C are warming up to, is reacted 35 minutes;
Three, corrosion inhibiter, ethanol amine, sodium metasilicate is added, is uniformly mixed and obtains cleaning agent for kitchen finished product.
Embodiment 5
Formula
97 parts of electrolyzed alkaline water, 0.5 part of benzotriazole, 0.5 part of sodium tetraborate, 0.8 part of monoethanolamine, 4 parts of coconut oil, 4 parts of sodium metasilicate, 2 parts of menthol, 8 parts of propylene glycol;
The pH of electrolyzed alkaline water is that 12.65, ORP is -900mV;The modulus of sodium metasilicate is 2.8, density 1.42g/cm3
Preparation method:
One, electrolyzed alkaline water is prepared
(1) sodium carbonate liquor, pure water are prepared;
Wherein, the mass concentration of sodium carbonate liquor is 15%, conductivity 6000mS/m;The TDS of pure water is 5%;
(2) circulation is passed through sodium carbonate liquor in the anode compartment, and circulation is passed through pure water in the cathodic compartment;
(3) it is powered after electrolysis and obtains electrolyzed alkaline water finished product in the cathode chamber;
Two, electrolyzed alkaline water, alcohols solvent are mixed, coconut oil is added;60 DEG C are warming up to, is reacted 40 minutes;
Three, corrosion inhibiter, ethanol amine, sodium metasilicate is added, is uniformly mixed and obtains cleaning agent for kitchen finished product.
Embodiment 6
Formula
97 parts of electrolyzed alkaline water, 0.4 part of benzotriazole, 0.6 part of sodium tetraborate, 0.4 part of monoethanolamine, 3 parts of coconut oil, 3.5 parts of sodium metasilicate, 1.5 parts of menthol, 5 parts of propylene glycol;
The pH of electrolyzed alkaline water is that 12.5, ORP is -800mV;The modulus of sodium metasilicate is 2.8, density 1.42g/cm3
Preparation method:
One, electrolyzed alkaline water is prepared
(1) sodium carbonate liquor, pure water are prepared;
Wherein, the mass concentration of sodium carbonate liquor is 20%, conductivity 7000mS/m;The TDS of pure water is 3%;
(2) circulation is passed through sodium carbonate liquor in the anode compartment, and circulation is passed through pure water in the cathodic compartment;
(3) it is powered after electrolysis and obtains electrolyzed alkaline water finished product in the cathode chamber;
Two, electrolyzed alkaline water, alcohols solvent are mixed, coconut oil is added;60 DEG C are warming up to, is reacted 40 minutes;
Three, corrosion inhibiter, ethanol amine, sodium metasilicate is added, is uniformly mixed and obtains cleaning agent for kitchen finished product.
As a comparison using commercially available cleaning agent, it is tested using the correlation technique in 4348 standard of QB/T, wherein with Artificial quartz stone is matrix, test result is as follows table:
Cleaning agent for kitchen it can be seen from table in the present invention has good removal effect for kitchen spot.Its Decontamination can be high by 15% or so than common cleaning agent.
The above disclosure is only the preferred embodiments of the present invention, cannot limit the right model of the present invention with this certainly It encloses, therefore equivalent changes made in accordance with the claims of the present invention, is still within the scope of the present invention.

Claims (10)

1. a kind of cleaning agent for kitchen, which is characterized in that be mainly made of the raw material of following portions by weight: electrolyzed alkaline water 90~ 100 parts, 0.1~5 part of corrosion inhibiter, 0.1~3 part of ethanol amine, 2~15 parts of alcohols solvent, 2~5 parts of sodium metasilicate, coconut oil 1~5 Part;
The electrolyzed alkaline water the preparation method comprises the following steps:
(1) sodium carbonate or solution of potassium carbonate, pure water are prepared;
(2) circulation is passed through sodium carbonate liquor or solution of potassium carbonate in the anode compartment, and circulation is passed through pure water in the cathodic compartment;
(3) it is powered after electrolysis and obtains electrolyzed alkaline water finished product in the cathode chamber;
The pH of the electrolyzed alkaline water is 11.5-13.0, and oxidation-reduction potential is -500~-1500mV.
2. cleaning agent for kitchen as described in claim 1, which is characterized in that the alcohols solvent is selected from propylene glycol, isopropanol, just One of butanol, menthol or combination.
3. cleaning agent for kitchen as claimed in claim 2, which is characterized in that the alcohols solvent is the mixed of propylene glycol and menthol Close object;Propylene glycol and the weight ratio of menthol are 1:(3~5).
4. cleaning agent for kitchen as described in claim 1, which is characterized in that the corrosion inhibiter is selected from sodium tetraborate, sodium chromate, three One of polyphosphate sodium, benzotriazole, methyl benzotriazazole or combination;
The ethanol amine selects monoethanolamine, diethanol amine or triethanolamine.
5. cleaning agent for kitchen as described in claim 1, which is characterized in that the modulus of the sodium metasilicate is 2.2~3.4, density For 1.32~1.48g/cm3
6. cleaning agent for kitchen as described in claim 1, which is characterized in that be mainly made of the raw material of following weight parts: alkalinity 95~100 parts of electrolysis water, 0.2~1 part of benzotriazole, 0.5~1 part of sodium tetraborate, 0.1~1 part of monoethanolamine, sodium metasilicate 3 ~5 parts, 1~3 part of coconut oil, 0.5~2 part of propylene glycol, 2~10 parts of menthol;
Wherein, the pH of the electrolyzed alkaline water is 12.3~12.8, and oxidation-reduction potential is -500~-1000mV.
7. cleaning agent for kitchen as claimed in claim 6, which is characterized in that it is made of the raw material of following weight parts: alkaline electro 97 parts of water of solution, 0.4 part of benzotriazole, 0.6 part of sodium tetraborate, 0.4 part of monoethanolamine, 3.5 parts of sodium metasilicate, 3 parts of coconut oil, third 1.5 parts of glycol, 5 parts of menthol;
Wherein, the modulus of the sodium metasilicate is 2.8, density 1.42g/cm3
The pH of the electrolyzed alkaline water is 12.5, and oxidation-reduction potential is -800mV.
8. cleaning agent for kitchen as described in claim 1, which is characterized in that diaphragm is equipped between the anode chamber and cathode chamber, The diaphragm can pass through Na+、K+
9. cleaning agent for kitchen as described in claim 1, which is characterized in that the mass concentration of the sodium carbonate liquor is 10- 40%, conductivity 5000-10000mS/m;Or
The mass concentration of the solution of potassium carbonate is 5-20%, conductivity 12000-50000mS/m;
The total dissolved solid < 12mg/L of the pure water.
10. such as the preparation method of the described in any item cleaning agent for kitchen of claim 1-9 characterized by comprising
One, electrolyzed alkaline water is prepared
Two, by 90~100 parts of electrolyzed alkaline water, 2~15 parts of alcohols solvent mixing, it is added 1~5 part of coconut oil;It is warming up to 50-70 DEG C, it reacts 30-60 minutes;
Three, 0.1~5 part of corrosion inhibiter, 0.1~3 part of ethanol amine, 2~5 parts of sodium metasilicate is added in the solution obtained in step 2; It is uniformly mixed and obtains cleaning agent for kitchen finished product.
CN201811382502.XA 2018-11-20 2018-11-20 Kitchen cleaning agent and preparation method thereof Active CN109504562B (en)

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Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104031755A (en) * 2014-06-12 2014-09-10 王希贵 Oil stain cleaning agent and preparation method thereof
CN106544180A (en) * 2016-10-27 2017-03-29 中扶当代建筑(北京)有限公司 The method that a kind of micro- electric water of use subset carries out household cleaning and sterilizing
CN106566712A (en) * 2016-10-27 2017-04-19 中扶当代建筑(北京)有限公司 Method for conducting oil dirt cleaning through small molecular group micro electrolysis water
CN106833914A (en) * 2017-01-25 2017-06-13 王敏芳 A kind of stain removal bactericidal agent based on small-micelle water
CN106893645A (en) * 2016-12-27 2017-06-27 广州舒泰生物技术有限公司 A kind of method of electrolysis production small-micelle water and in household detergent application
CN108485850A (en) * 2018-04-09 2018-09-04 广州市浪奇实业股份有限公司 A kind of kitchen greasy dirt cleaning agent and preparation method thereof

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104031755A (en) * 2014-06-12 2014-09-10 王希贵 Oil stain cleaning agent and preparation method thereof
CN106544180A (en) * 2016-10-27 2017-03-29 中扶当代建筑(北京)有限公司 The method that a kind of micro- electric water of use subset carries out household cleaning and sterilizing
CN106566712A (en) * 2016-10-27 2017-04-19 中扶当代建筑(北京)有限公司 Method for conducting oil dirt cleaning through small molecular group micro electrolysis water
CN106893645A (en) * 2016-12-27 2017-06-27 广州舒泰生物技术有限公司 A kind of method of electrolysis production small-micelle water and in household detergent application
CN106833914A (en) * 2017-01-25 2017-06-13 王敏芳 A kind of stain removal bactericidal agent based on small-micelle water
CN108485850A (en) * 2018-04-09 2018-09-04 广州市浪奇实业股份有限公司 A kind of kitchen greasy dirt cleaning agent and preparation method thereof

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