CN109504521A - A kind of precision copper fitting capillary drawing coolant liquid - Google Patents
A kind of precision copper fitting capillary drawing coolant liquid Download PDFInfo
- Publication number
- CN109504521A CN109504521A CN201811640397.5A CN201811640397A CN109504521A CN 109504521 A CN109504521 A CN 109504521A CN 201811640397 A CN201811640397 A CN 201811640397A CN 109504521 A CN109504521 A CN 109504521A
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- parts
- coolant liquid
- minutes
- copper fitting
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M173/00—Lubricating compositions containing more than 10% water
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/06—Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/08—Resistance to extreme temperature
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/24—Metal working without essential removal of material, e.g. forming, gorging, drawing, pressing, stamping, rolling or extruding; Punching metal
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/244—Metal working of specific metals
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Lubricants (AREA)
Abstract
The invention discloses a kind of accurate copper fitting capillary drawing coolant liquids, it is formulated by formula as below according to following parts by weight: 13 ~ 20 parts of base oil, 15 ~ 25 parts of composite calcium sulfonate grease lubricant, 2 ~ 5 parts of triethanolamine borate, 50 ~ 80 parts of distilled water, 3 ~ 9 parts of surfactant, 1 ~ 3 part and 1 ~ 5 part of oiliness improver of antiwear additive can effectively reduce the friction of accurate copper fitting capillary and mold, the abrasion for reducing workpiece, effectively reduce scratch, rupture phenomena such as generation.
Description
Technical field
The present invention relates to drawing liquid fields, and in particular to a kind of precision copper fitting capillary drawing coolant liquid.
Background technique
Drawing is to be drawn metal stock from the die hole for being less than blank section in the front end belonged to by lashing wire with external force
Out, to obtain a kind of plastic processing method of the product of corresponding shape and size, metalwork is during the drawing process, it will usually make
With the lotion being made of soap base, borax, polyethylene glycol (PEG) oleate and water or by mineral oil, fatty acid, dodecanol, oleic acid polyoxy
Vinyl acetate and the lotion of water composition can reduce the mechanical strength of drawbench, improve drawing speed and product quality as lubricant,
Therefore dedicated drawing coolant liquid is preferably selected.
Summary of the invention
Technical problem to be solved by the invention is to provide a kind of accurate copper fitting capillary drawing coolant liquids, can be effective
Reduction accurate copper fitting capillary and mold friction, phenomena such as reducing the abrasion of workpiece, effectively reduce scratch, rupture
Generation.
To solve the above-mentioned problems, the present invention provides following technical schemes: a kind of precision copper fitting capillary drawing is cold
But liquid is formulated by formula as below according to following parts by weight: 13 ~ 20 parts of base oil, 15 ~ 25 parts of composite calcium sulfonate grease lubricant,
2 ~ 5 parts of triethanolamine borate, 50 ~ 80 parts of distilled water, 3 ~ 9 parts of surfactant, 1 ~ 3 part and 1 ~ 5 part of oiliness improver of antiwear additive, institute
Stating base oil is paraffin oil, and the surfactant is at least one of fatty glyceride or neopelex, institute
Stating antiwear additive is at least one of di-n-butyl phosphite, tricresyl phosphate, sulfurized olefin cotton oil, and the oiliness improver is acid
At least two in formula phosphoric acid oleoyl ester, butyl stearate, laruyl alcohol or oleic acid；
A kind of accurate copper fitting capillary drawing coolant liquid, the preparation method the following steps are included:
(1) distilled water is poured into reaction vessel, successively adds base oil, composite calcium sulfonate grease lubricant, triethanolamine borate
Enter into distilled water, be heated to 85 ~ 90 DEG C, start to stir, 90 ~ 105r/min of stirring rate mixing time 25 ~ 40 minutes, is obtained
To mixed solution A；
(2) surfactant is added to mixed solution A obtained in step (1), is allowed to warm to 95 ~ 100 DEG C, start to stir
It mixes, 75 ~ 80r/min of stirring rate, mixing time 30 ~ 45 minutes, until stirring evenly, antiwear additive, heating temperature to 110 is added
It ~ 120 DEG C, stirs evenly, 100 ~ 120r/min of stirring rate, mixing time 10 ~ 15 minutes, oiliness improver is then added, continues to stir
It mixes, 115 ~ 125r/min of stirring rate, mixing time 60 ~ 90 minutes, is cooled to room temperature, can be obtained into until stirring evenly
Product.
Beneficial effect
A kind of accurate copper fitting capillary drawing coolant liquid of the present invention, can effectively reduce accurate copper fitting capillary and mold
Friction, reduce the abrasion of workpiece, effectively reduce scratch, rupture phenomena such as generation, the invention belongs to medium viscosity, viscosity
It is moderate, it is easy to use, there is good thermal stability under the working environment of high temperature in time, while there is good bright and clean function
Can, machining accuracy is improved, plays the role of protecting mold.
Specific embodiment
It is carried out below with reference to technical effect of the embodiment to design of the invention, specific structure and generation clear, complete
Ground description, to be completely understood by the purpose of the present invention, feature and effect.Obviously, described embodiment is of the invention one
Section Example, rather than whole embodiments, based on the embodiment of the present invention, those skilled in the art are not paying creativeness
Other embodiments obtained, belong to the scope of protection of the invention under the premise of labour.
Embodiment 1
A kind of precision copper fitting capillary drawing coolant liquid, is formulated by formula as below according to following parts by weight: base oil 13
Part, 15 parts of composite calcium sulfonate grease lubricant, 2 parts of triethanolamine borate, 50 parts of distilled water, 3 parts of surfactant, 1 part of antiwear additive
With 1 part of oiliness improver, the base oil be paraffin oil, the surfactant be fatty glyceride, the antiwear additive be phosphorous
Sour di-n-butyl, the oiliness improver are mixed together by acid phosphate oleoyl ester with butyl stearate, the acid phosphate oil
The weight ratio of acyl ester and butyl stearate be 0.8:1, mixing time 6 minutes, stirring rate 80r/min；
A kind of accurate copper fitting capillary drawing coolant liquid, the preparation method the following steps are included:
(1) distilled water is poured into reaction vessel, successively adds base oil, composite calcium sulfonate grease lubricant, triethanolamine borate
Enter into distilled water, be heated to 85 DEG C, start to stir, stirring rate 90r/min mixing time 40 minutes, obtains mixed solution
A；
(2) surfactant is added to mixed solution A obtained in step (1), is allowed to warm to 95 DEG C, started to stir, stir
Rate 75r/min is mixed, mixing time 45 minutes, until stirring evenly, antiwear additive is added, for heating temperature to 110 DEG C, stirring is equal
Even, stirring rate 100r/min mixing time 15 minutes, is then added oiliness improver, continues to stir, stirring rate 115r/min,
It mixing time 90 minutes, is cooled to room temperature until stirring evenly, finished product can be obtained.
Embodiment 2
A kind of precision copper fitting capillary drawing coolant liquid, is formulated by formula as below according to following parts by weight: base oil 15
Part, 16 parts of composite calcium sulfonate grease lubricant, 3 parts of triethanolamine borate, 55 parts of distilled water, 4 parts of surfactant, 2 parts of antiwear additive
With 2 parts of oiliness improver, the base oil is paraffin oil, and the surfactant is neopelex, and the antiwear additive is
Tricresyl phosphate, the oiliness improver in acid phosphate oleoyl ester and laruyl alcohol by mixing together, the acid phosphate oil
The weight ratio of acyl ester and laruyl alcohol be 1:1.05, mixing time 8 minutes, stirring rate 70r/min；
A kind of accurate copper fitting capillary drawing coolant liquid, the preparation method the following steps are included:
(1) distilled water is poured into reaction vessel, successively adds base oil, composite calcium sulfonate grease lubricant, triethanolamine borate
Enter into distilled water, be heated to 86 DEG C, start to stir, stirring rate 95r/min mixing time 30 minutes, obtains mixed solution
A；
(2) surfactant is added to mixed solution A obtained in step (1), is allowed to warm to 95 DEG C, started to stir, stir
Rate 75r/min is mixed, mixing time 35 minutes, until stirring evenly, antiwear additive is added, for heating temperature to 110 DEG C, stirring is equal
Even, stirring rate 100r/min mixing time 15 minutes, is then added oiliness improver, continues to stir, stirring rate 115r/min,
It mixing time 90 minutes, is cooled to room temperature until stirring evenly, finished product can be obtained.
Embodiment 3
A kind of precision copper fitting capillary drawing coolant liquid, is formulated by formula as below according to following parts by weight: base oil 17
Part, 18 parts of composite calcium sulfonate grease lubricant, 4 parts of triethanolamine borate, 60 parts of distilled water, 6 parts of surfactant, 2 parts of antiwear additive
With 3 parts of oiliness improver, the base oil be paraffin oil, the surfactant is by fatty glyceride and neopelex
It mixes together, the weight ratio of the fatty glyceride and neopelex is 0.4:1, stirring rate 65r/
Min, mixing time 9 minutes, the antiwear additive was sulfurized olefin cotton oil, and the oiliness improver is by acid phosphate oleoyl ester and oleic acid
It mixes together, the weight ratio of the acid phosphate oleoyl ester and oleic acid is 1:0.9, stirring rate, 90r/min, when stirring
Between 5 minutes；
A kind of accurate copper fitting capillary drawing coolant liquid, the preparation method the following steps are included:
(1) distilled water is poured into reaction vessel, successively adds base oil, composite calcium sulfonate grease lubricant, triethanolamine borate
Enter into distilled water, be heated to 90 DEG C, start to stir, stirring rate 105r/min mixing time 25 minutes, obtains mixed solution
A；
(2) surfactant is added to mixed solution A obtained in step (1), is allowed to warm to 95 DEG C, started to stir, stir
Rate 75r/min is mixed, mixing time 45 minutes, until stirring evenly, antiwear additive is added, for heating temperature to 110 DEG C, stirring is equal
Even, stirring rate 100r/min mixing time 15 minutes, is then added oiliness improver, continues to stir, stirring rate 115r/min,
It mixing time 90 minutes, is cooled to room temperature until stirring evenly, finished product can be obtained.
Embodiment 4
A kind of precision copper fitting capillary drawing coolant liquid, is formulated by formula as below according to following parts by weight: base oil 18
Part, 20 parts of composite calcium sulfonate grease lubricant, 4 parts of triethanolamine borate, 70 parts of distilled water, 7 parts of surfactant, 3 parts of antiwear additive
With 4 parts of oiliness improver, the base oil be paraffin oil, the surfactant is by fatty glyceride and neopelex
It mixes together, the weight ratio of the fatty glyceride and neopelex is 0.4:1, stirring rate 65r/
Min, mixing time 9 minutes, the antiwear additive was mixed together by di-n-butyl phosphite and tricresyl phosphate, the Asia
The weight ratio of phosphoric acid di-n-butyl and tricresyl phosphate be 0.8:1.25, stirring rate 78r/min, mixing time 8 minutes, institute
Oiliness improver is stated to be mixed together by acid phosphate oleoyl ester, butyl stearate and laruyl alcohol, it is the acid phosphate oleoyl ester, hard
The weight ratio of resin acid butyl ester and laruyl alcohol be 1:1:1.25, stirring rate 90r/min, mixing time 10 minutes；
A kind of accurate copper fitting capillary drawing coolant liquid, the preparation method the following steps are included:
(1) distilled water is poured into reaction vessel, successively adds base oil, composite calcium sulfonate grease lubricant, triethanolamine borate
Enter into distilled water, be heated to 90 DEG C, start to stir, stirring rate 105r/min mixing time 25 minutes, obtains mixed solution
A；
(2) surfactant is added to mixed solution A obtained in step (1), is allowed to warm to 95 DEG C, started to stir, stir
Rate 75r/min is mixed, mixing time 45 minutes, until stirring evenly, antiwear additive is added, for heating temperature to 120 DEG C, stirring is equal
Even, stirring rate 120r/min mixing time 15 minutes, is then added oiliness improver, continues to stir, stirring rate 125r/min,
It mixing time 60 minutes, is cooled to room temperature until stirring evenly, finished product can be obtained.
Embodiment 5
A kind of precision copper fitting capillary drawing coolant liquid, is formulated by formula as below according to following parts by weight: base oil 20
Part, 25 parts of composite calcium sulfonate grease lubricant, 5 parts of triethanolamine borate, 80 parts of distilled water, 9 parts of surfactant, 3 parts of antiwear additive
With 5 parts of oiliness improver, the base oil be paraffin oil, the surfactant is by fatty glyceride and neopelex
It mixes together, the weight ratio of the fatty glyceride and neopelex is 0.4:1, stirring rate 65r/
Min, mixing time 9 minutes, the antiwear additive was mixed together by di-n-butyl phosphite and sulfurized olefin cotton oil, described
The weight ratio of di-n-butyl phosphite and sulfurized olefin cotton oil be 1:1, stirring rate 55r/min, mixing time 12 minutes, institute
It states oiliness improver to be mixed together by acid phosphate oleoyl ester, butyl stearate, laruyl alcohol and oleic acid, the acid phosphate oleoyl
Ester, butyl stearate, laruyl alcohol and oleic acid weight ratio be 0.9:1:0.75:1, stirring rate, 90r/min, mixing time 15
Minute；
A kind of accurate copper fitting capillary drawing coolant liquid, the preparation method the following steps are included:
(1) distilled water is poured into reaction vessel, successively adds base oil, composite calcium sulfonate grease lubricant, triethanolamine borate
Enter into distilled water, be heated to 90 DEG C, start to stir, stirring rate 105r/min mixing time 30 minutes, obtains mixed solution
A；
(2) surfactant is added to mixed solution A obtained in step (1), is allowed to warm to 100 DEG C, started to stir, stir
Rate 80r/min is mixed, mixing time 30 minutes, until stirring evenly, antiwear additive is added, for heating temperature to 120 DEG C, stirring is equal
Even, stirring rate 120r/min mixing time 15 minutes, is then added oiliness improver, continues to stir, stirring rate 125r/min,
It mixing time 60 minutes, is cooled to room temperature until stirring evenly, finished product can be obtained.
In above-described embodiment, the paraffin oil is purchased from Suzhou He Sen specialty oil Co., Ltd, the complex calcium sulfonate profit
Consistent lubricant is purchased from Wuxi City Yi Jiade lubricating oil Co., Ltd, the triethanolamine borate, di-n-butyl phosphite, tripotassium phosphate
Phenolic ester, acid phosphate oleoyl ester, butyl stearate are purchased from Shanghai shriek Chemical Co., Ltd., and the surfactant is purchased from Changzhou
Xin Lun Chemical Co., Ltd., the sulfurized olefin cotton oil are purchased from Jinan Fleder Chemical Co., Ltd., and the laruyl alcohol is purchased from
Jiangsu Hai'an Petrochemical Plant, the oleic acid are purchased from Shanghai Jin Yue Chemical Co., Ltd..
The foregoing is only a preferred embodiment of the present invention, but scope of protection of the present invention is not limited thereto,
In the technical scope disclosed by the present invention, any changes or substitutions that can be easily thought of by anyone skilled in the art,
It should be covered by the scope of protection of the present invention.Therefore, protection scope of the present invention should be with the protection scope of claims
Subject to.
Claims (6)
1. a kind of precision copper fitting capillary drawing coolant liquid, which is characterized in that prepared by formula as below according to following parts by weight
It forms: 13 ~ 20 parts of base oil, 15 ~ 25 parts of composite calcium sulfonate grease lubricant, 2 ~ 5 parts of triethanolamine borate, 50 ~ 80 parts of distilled water,
3 ~ 9 parts of surfactant, 1 ~ 3 part and 1 ~ 5 part of oiliness improver of antiwear additive.
2. a kind of accurate copper fitting capillary drawing coolant liquid according to claim 1, which is characterized in that the base oil is
Paraffin oil.
3. a kind of accurate copper fitting capillary drawing coolant liquid according to claim 1, which is characterized in that the surface-active
Agent is at least one of fatty glyceride or neopelex.
4. a kind of accurate copper fitting capillary drawing coolant liquid according to claim 1, which is characterized in that the antiwear additive is
At least one of di-n-butyl phosphite, tricresyl phosphate, sulfurized olefin cotton oil.
5. a kind of accurate copper fitting capillary drawing coolant liquid according to claim 1, which is characterized in that the oiliness improver is
At least two in acid phosphate oleoyl ester, butyl stearate, laruyl alcohol or oleic acid.
6. a kind of accurate copper fitting capillary drawing coolant liquid according to claim 1, which is characterized in that the preparation method packet
Include following steps:
(1) distilled water is poured into reaction vessel, successively adds base oil, composite calcium sulfonate grease lubricant, triethanolamine borate
Enter into distilled water, be heated to 85 ~ 90 DEG C, start to stir, 90 ~ 105r/min of stirring rate mixing time 25 ~ 40 minutes, is obtained
To mixed solution A；
(2) surfactant is added to mixed solution A obtained in step (1), is allowed to warm to 95 ~ 100 DEG C, start to stir
It mixes, 75 ~ 80r/min of stirring rate, mixing time 30 ~ 45 minutes, until stirring evenly, antiwear additive, heating temperature to 110 is added
It ~ 120 DEG C, stirs evenly, 100 ~ 120r/min of stirring rate, mixing time 10 ~ 15 minutes, oiliness improver is then added, continues to stir
It mixes, 115 ~ 125r/min of stirring rate, mixing time 60 ~ 90 minutes, is cooled to room temperature, can be obtained into until stirring evenly
Product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811640397.5A CN109504521A (en) | 2018-12-29 | 2018-12-29 | A kind of precision copper fitting capillary drawing coolant liquid |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811640397.5A CN109504521A (en) | 2018-12-29 | 2018-12-29 | A kind of precision copper fitting capillary drawing coolant liquid |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN109504521A true CN109504521A (en) | 2019-03-22 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201811640397.5A Pending CN109504521A (en) | 2018-12-29 | 2018-12-29 | A kind of precision copper fitting capillary drawing coolant liquid |
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Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101747987A (en) * | 2009-12-21 | 2010-06-23 | 克拉玛依市金山石油化工有限公司 | Water-based copper and aluminum wiredrawing oil composite and preparation method thereof |
| CN103666660A (en) * | 2012-09-20 | 2014-03-26 | 中国石油化工股份有限公司 | Automobile part drawing oil composition and use thereof |
| CN108467770A (en) * | 2018-05-09 | 2018-08-31 | 安徽润藤电缆材料科技有限公司 | A kind of quick drawing wire drawing liquid of copper wire |
-
2018
- 2018-12-29 CN CN201811640397.5A patent/CN109504521A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101747987A (en) * | 2009-12-21 | 2010-06-23 | 克拉玛依市金山石油化工有限公司 | Water-based copper and aluminum wiredrawing oil composite and preparation method thereof |
| CN103666660A (en) * | 2012-09-20 | 2014-03-26 | 中国石油化工股份有限公司 | Automobile part drawing oil composition and use thereof |
| CN108467770A (en) * | 2018-05-09 | 2018-08-31 | 安徽润藤电缆材料科技有限公司 | A kind of quick drawing wire drawing liquid of copper wire |
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Application publication date: 20190322 |
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