CN109502971A - A kind of ultraviolet ray intercepting glass and preparation method thereof - Google Patents
A kind of ultraviolet ray intercepting glass and preparation method thereof Download PDFInfo
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- CN109502971A CN109502971A CN201811158553.4A CN201811158553A CN109502971A CN 109502971 A CN109502971 A CN 109502971A CN 201811158553 A CN201811158553 A CN 201811158553A CN 109502971 A CN109502971 A CN 109502971A
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- ray intercepting
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- 239000011521 glass Substances 0.000 title claims abstract description 87
- 238000002360 preparation method Methods 0.000 title claims abstract description 19
- 229910052751 metal Inorganic materials 0.000 claims abstract description 32
- 239000002184 metal Substances 0.000 claims abstract description 32
- 238000010792 warming Methods 0.000 claims abstract description 28
- 239000000203 mixture Substances 0.000 claims abstract description 22
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 claims abstract description 20
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 20
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims abstract description 20
- FGIUAXJPYTZDNR-UHFFFAOYSA-N potassium nitrate Chemical compound [K+].[O-][N+]([O-])=O FGIUAXJPYTZDNR-UHFFFAOYSA-N 0.000 claims abstract description 20
- 239000000835 fiber Substances 0.000 claims abstract description 18
- 238000002844 melting Methods 0.000 claims abstract description 15
- 230000008018 melting Effects 0.000 claims abstract description 15
- 229910052581 Si3N4 Inorganic materials 0.000 claims abstract description 10
- 239000000919 ceramic Substances 0.000 claims abstract description 10
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 claims abstract description 10
- 229910052943 magnesium sulfate Inorganic materials 0.000 claims abstract description 10
- 235000019341 magnesium sulphate Nutrition 0.000 claims abstract description 10
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 claims abstract description 10
- 229920000515 polycarbonate Polymers 0.000 claims abstract description 10
- 239000004417 polycarbonate Substances 0.000 claims abstract description 10
- 229920000728 polyester Polymers 0.000 claims abstract description 10
- 235000010333 potassium nitrate Nutrition 0.000 claims abstract description 10
- 239000004323 potassium nitrate Substances 0.000 claims abstract description 10
- 239000000843 powder Substances 0.000 claims abstract description 10
- 239000002994 raw material Substances 0.000 claims abstract description 10
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000004408 titanium dioxide Substances 0.000 claims abstract description 10
- 239000011787 zinc oxide Substances 0.000 claims abstract description 10
- 229910001928 zirconium oxide Inorganic materials 0.000 claims abstract description 10
- 238000000137 annealing Methods 0.000 claims abstract description 8
- 229910001570 bauxite Inorganic materials 0.000 claims abstract description 8
- 238000005352 clarification Methods 0.000 claims abstract description 8
- 238000001816 cooling Methods 0.000 claims abstract description 8
- MRNHPUHPBOKKQT-UHFFFAOYSA-N indium;tin;hydrate Chemical compound O.[In].[Sn] MRNHPUHPBOKKQT-UHFFFAOYSA-N 0.000 claims abstract description 8
- 238000000465 moulding Methods 0.000 claims abstract description 8
- 238000005498 polishing Methods 0.000 claims abstract description 8
- 238000010438 heat treatment Methods 0.000 claims description 14
- 238000002156 mixing Methods 0.000 claims description 9
- RHZWSUVWRRXEJF-UHFFFAOYSA-N indium tin Chemical compound [In].[Sn] RHZWSUVWRRXEJF-UHFFFAOYSA-N 0.000 claims description 2
- 230000006750 UV protection Effects 0.000 abstract 1
- 238000003756 stirring Methods 0.000 description 5
- 206010042496 Sunburn Diseases 0.000 description 4
- 239000007788 liquid Substances 0.000 description 3
- 230000005855 radiation Effects 0.000 description 3
- 210000003491 skin Anatomy 0.000 description 3
- 229940037003 alum Drugs 0.000 description 2
- 239000004411 aluminium Substances 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 230000035699 permeability Effects 0.000 description 2
- 239000002689 soil Substances 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 241000127225 Enceliopsis nudicaulis Species 0.000 description 1
- 208000027418 Wounds and injury Diseases 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 210000002615 epidermis Anatomy 0.000 description 1
- 238000005816 glass manufacturing process Methods 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 208000014674 injury Diseases 0.000 description 1
- 230000001795 light effect Effects 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C1/00—Ingredients generally applicable to manufacture of glasses, glazes, or vitreous enamels
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C14/00—Glass compositions containing a non-glass component, e.g. compositions containing fibres, filaments, whiskers, platelets, or the like, dispersed in a glass matrix
- C03C14/002—Glass compositions containing a non-glass component, e.g. compositions containing fibres, filaments, whiskers, platelets, or the like, dispersed in a glass matrix the non-glass component being in the form of fibres, filaments, yarns, felts or woven material
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C4/00—Compositions for glass with special properties
- C03C4/08—Compositions for glass with special properties for glass selectively absorbing radiation of specified wave lengths
- C03C4/085—Compositions for glass with special properties for glass selectively absorbing radiation of specified wave lengths for ultraviolet absorbing glass
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2214/00—Nature of the non-vitreous component
- C03C2214/02—Fibres; Filaments; Yarns; Felts; Woven material
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2214/00—Nature of the non-vitreous component
- C03C2214/30—Methods of making the composites
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Ceramic Engineering (AREA)
- Dispersion Chemistry (AREA)
- Glass Compositions (AREA)
Abstract
The invention discloses a kind of ultraviolet ray intercepting glass and preparation method thereof, glass raw material includes following component: glass powder, zirconium oxide, potassium nitrate, magnesium sulfate, polycarbonate, polyester fiber, copper sulphate, titanium dioxide, ceramic fibre, bauxite, zinc oxide, tin indium oxide, silicon nitride.Preparation process is to obtain mixture after being first stirred each component, then heat to 160-180 DEG C, holding is warming up to melting again after a certain period of time, form glass metal, then by glass metal homogenizing, clarification, discharge bubble, treated glass metal is formed, it finally will treated glass metal molding, annealing, cooling, polishing, obtains ultraviolet ray intercepting glass.Glass provided by the invention has good ultraviolet resistance.
Description
Technical field
The invention belongs to glass making techniques fields, and in particular to a kind of ultraviolet ray intercepting glass and preparation method thereof.
Background technique
Ultraviolet radiation refers to solar radiation of the wavelength between 200nm~400nm, generally includes following three
Class: UV-A wavelength be 315nm~380nm, UV-B wavelength be 280nm~315nm, UV-C wavelength 200nm~
280nm.Sunray (290nm~2000nm) middle-ultraviolet lamp for reaching earth surface accounts for about 13%, and wherein UV-A is accounted for
97%, UV-B account for 3%, UV-C close to 0.Ultraviolet light is very important to the adverse effect of human body, and ultraviolet energy causes
It burns, wherein UV-A sections are known as tanned section, it is caused by accumulating over a long period to the injury of skin；UV-B sections are known as sunburn section,
Penetration power can make skin sunburn up to epidermis, and clinical manifestation is flush, cusalgia is obvious, may occur in which vesicle, after 1 week
Start to peel, this is the main wave band that people prevent sunburn.With the improvement of living standards, people more aggravate image and health
Depending on protectiving ultraviolet radiation avoids skin also more more and more intense by tanned or even sunburn demand.
Glass is a kind of a kind of non-crystalline solids (from microcosmic, glass is also liquid) of random structure, molecule
There is unlike crystal in space the arrangement of long-range order, and be similar to liquid has shortrange order like that.Glass is as solid
Specific shape is equally kept, is flowed unlike liquid with gravity.Common glass does not shield ultraviolet light
Effect, therefore, it is necessary to develop a kind of ultraviolet ray intercepting glass, to meet application requirement.
Summary of the invention
The present invention is directed to the above the deficiencies in the prior art, provides a kind of ultraviolet ray intercepting glass and preparation method thereof, improves anti-
Ultraviolet performance.
The technical solution adopted by the invention is as follows:
A kind of ultraviolet ray intercepting glass, raw material include the component of following parts by weight meter:
80-100 parts of glass powder, 0.5-2 parts of zirconium oxide, 2-6 parts of potassium nitrate, 1-3 parts of magnesium sulfate, 3-5 parts of polycarbonate, polyester is fine
2-4 parts, 1-3 parts of copper sulphate are tieed up, 1-3 parts of titanium dioxide, 2-4 parts of ceramic fibre, 1-3 parts of bauxite, 2-4 parts of zinc oxide, are aoxidized
2-4 parts of indium tin, 3-6 parts of silicon nitride.
Further, the ultraviolet ray intercepting glass, raw material include the component of following parts by weight meter: 90-96 parts of glass powder,
1-1.5 parts of zirconium oxide, 3-5 parts of potassium nitrate, 1-3 parts of magnesium sulfate, 4-5 parts of polycarbonate, 2-3 parts of polyester fiber, copper sulphate 2-3
Part, 2-3 parts of titanium dioxide, 3-4 parts of ceramic fibre, 1-3 parts of bauxite, 2-4 parts of zinc oxide, 2-4 parts of tin indium oxide, silicon nitride 4-
6 parts.
The preparation method of above-described ultraviolet ray intercepting glass, includes the following steps:
Step 1 obtains mixture after being stirred each component；
Mixture is warming up to 160-180 DEG C, is kept for 60-80 minutes, be then warming up to melting again, forms glass metal by step 2；
Glass metal homogenizing, clarification, discharge bubble are formed treated glass metal by step 3；
Step 4, will treated glass metal molding, annealing, cooling, polishing obtains ultraviolet ray intercepting glass.
Further, the preparation method of the ultraviolet ray intercepting glass, the mixing speed being stirred in step 1 are
150-180 revs/min, mixing time 30-40 minutes.
Further, mixture is warming up to 160-180 DEG C in step 2 by the preparation method of the ultraviolet ray intercepting glass
Heating rate be 1-2 DEG C/min.
Further, the preparation method of the ultraviolet ray intercepting glass, the heating rate that melting is warming up in step 2 are
4-5 DEG C/min.
Ultraviolet ray intercepting glass provided by the invention can be good at preventing UV light permeability, with good antiultraviolet
Performance.
Specific embodiment:
Embodiment 1
A kind of ultraviolet ray intercepting glass, raw material include the component of following parts by weight meter:
80 parts of glass powder, 0.5 part of zirconium oxide, 2 parts of potassium nitrate, 1 part of magnesium sulfate, 3 parts of polycarbonate, 2 parts of polyester fiber, copper sulphate
1 part, 1 part of titanium dioxide, 2 parts of ceramic fibre, 1 part of bauxite, 2 parts of zinc oxide, 2 parts of tin indium oxide, 3 parts of silicon nitride.
The preparation method of above-described ultraviolet ray intercepting glass, includes the following steps:
Step 1 obtains mixture after being stirred each component, and the mixing speed being stirred is 150 revs/min, when stirring
Between 30 minutes；
Mixture is warming up to 160 DEG C, is kept for 60 minutes, be then warming up to melting again, forms glass metal by step 2, wherein will
The heating rate that mixture is warming up to 160 DEG C is 1-2 DEG C/min, and the heating rate for being warming up to melting is 4-5 DEG C/min；
Glass metal homogenizing, clarification, discharge bubble are formed treated glass metal by step 3；
Step 4, will treated glass metal molding, annealing, cooling, polishing obtains ultraviolet ray intercepting glass.
Embodiment 2
A kind of ultraviolet ray intercepting glass, raw material include the component of following parts by weight meter: 90 parts of glass powder, 1 part of zirconium oxide, and potassium nitrate 3
Part, 1 part of magnesium sulfate, 4 parts of polycarbonate, 2 parts of polyester fiber, 2 parts of copper sulphate, 2 parts of titanium dioxide, 3 parts of ceramic fibre, bauxite
1 part, 2 parts of zinc oxide, 2 parts of tin indium oxide, 4 parts of silicon nitride.
The preparation method of above-described ultraviolet ray intercepting glass, includes the following steps:
Step 1 obtains mixture after being stirred each component, and the mixing speed being stirred is 160 revs/min, when stirring
Between 35 minutes；
Mixture is warming up to 165 DEG C, is kept for 67 minutes, be then warming up to melting again, forms glass metal by step 2, wherein will
The heating rate that mixture is warming up to 165 DEG C is 1-2 DEG C/min, and the heating rate for being warming up to melting is 4-5 DEG C/min；
Glass metal homogenizing, clarification, discharge bubble are formed treated glass metal by step 3；
Step 4, will treated glass metal molding, annealing, cooling, polishing obtains ultraviolet ray intercepting glass.
Embodiment 3
A kind of ultraviolet ray intercepting glass, raw material include the component of following parts by weight meter: 95 parts of glass powder, 1.3 parts of zirconium oxide, and potassium nitrate
4 parts, 2 parts of magnesium sulfate, 5 parts of polycarbonate, 3 parts of polyester fiber, 3 parts of copper sulphate, 2 parts of titanium dioxide, 4 parts of ceramic fibre, aluminium alum
2 parts, 3 parts of zinc oxide, 3 parts of tin indium oxide, 5 parts of silicon nitride of soil.
The preparation method of above-described ultraviolet ray intercepting glass, includes the following steps:
Step 1 obtains mixture after being stirred each component, and the mixing speed being stirred is 170 revs/min, when stirring
Between 38 minutes；
Mixture is warming up to 175 DEG C, is kept for 70 minutes, be then warming up to melting again, forms glass metal by step 2, wherein will
The heating rate that mixture is warming up to 175 DEG C is 1-2 DEG C/min, and the heating rate for being warming up to melting is 4-5 DEG C/min；
Glass metal homogenizing, clarification, discharge bubble are formed treated glass metal by step 3；
Step 4, will treated glass metal molding, annealing, cooling, polishing obtains ultraviolet ray intercepting glass.
Embodiment 4
A kind of ultraviolet ray intercepting glass, raw material include the component of following parts by weight meter: 96 parts of glass powder, 1.5 parts of zirconium oxide, and potassium nitrate
5 parts, 3 parts of magnesium sulfate, 5 parts of polycarbonate, 3 parts of polyester fiber, 3 parts of copper sulphate, 3 parts of titanium dioxide, 4 parts of ceramic fibre, aluminium alum
3 parts, 4 parts of zinc oxide, 4 parts of tin indium oxide, 6 parts of silicon nitride of soil.
The preparation method of above-described ultraviolet ray intercepting glass, includes the following steps:
Step 1 obtains mixture after being stirred each component, and the mixing speed being stirred is 175 revs/min, when stirring
Between 38 minutes；
Mixture is warming up to 178 DEG C, is kept for 75 minutes, be then warming up to melting again, forms glass metal by step 2, wherein will
The heating rate that mixture is warming up to 178 DEG C is 1-2 DEG C/min, and the heating rate for being warming up to melting is 4-5 DEG C/min；
Glass metal homogenizing, clarification, discharge bubble are formed treated glass metal by step 3；
Step 4, will treated glass metal molding, annealing, cooling, polishing obtains ultraviolet ray intercepting glass.
Embodiment 5
A kind of ultraviolet ray intercepting glass, raw material include the component of following parts by weight meter:
100 parts of glass powder, 2 parts of zirconium oxide, 6 parts of potassium nitrate, 3 parts of magnesium sulfate, 5 parts of polycarbonate, 4 parts of polyester fiber, copper sulphate 3
Part, 3 parts of titanium dioxide, 4 parts of ceramic fibre, 3 parts of bauxite, 4 parts of zinc oxide, 4 parts of tin indium oxide, 6 parts of silicon nitride.
The preparation method of above-described ultraviolet ray intercepting glass, includes the following steps:
Step 1 obtains mixture after being stirred each component, and the mixing speed being stirred is 180 revs/min, when stirring
Between 40 minutes；
Mixture is warming up to 180 DEG C, is kept for 80 minutes, be then warming up to melting again, forms glass metal by step 2, wherein will
The heating rate that mixture is warming up to 180 DEG C is 1-2 DEG C/min, and the heating rate for being warming up to melting is 4-5 DEG C/min；
Glass metal homogenizing, clarification, discharge bubble are formed treated glass metal by step 3；
Step 4, will treated glass metal molding, annealing, cooling, polishing obtains ultraviolet ray intercepting glass.
Anti-UV performance test is carried out to the ultraviolet ray intercepting glass that above embodiments obtain, as a result as follows:
Result above, which can be seen that ultraviolet ray intercepting glass provided by the invention, can be good at preventing UV light permeability, have good
The performance of good antiultraviolet.
Claims (6)
1. a kind of ultraviolet ray intercepting glass, which is characterized in that raw material includes the component of following parts by weight meter:
80-100 parts of glass powder, 0.5-2 parts of zirconium oxide, 2-6 parts of potassium nitrate, 1-3 parts of magnesium sulfate, 3-5 parts of polycarbonate, polyester is fine
2-4 parts, 1-3 parts of copper sulphate are tieed up, 1-3 parts of titanium dioxide, 2-4 parts of ceramic fibre, 1-3 parts of bauxite, 2-4 parts of zinc oxide, are aoxidized
2-4 parts of indium tin, 3-6 parts of silicon nitride.
2. ultraviolet ray intercepting glass according to claim 1, which is characterized in that raw material includes the component of following parts by weight meter:
90-96 parts of glass powder, 1-1.5 parts of zirconium oxide, 3-5 parts of potassium nitrate, 1-3 parts of magnesium sulfate, 4-5 parts of polycarbonate, polyester fiber 2-3
Part, 2-3 parts of copper sulphate, 2-3 parts of titanium dioxide, 3-4 parts of ceramic fibre, 1-3 parts of bauxite, 2-4 parts of zinc oxide, tin indium oxide 2-
4 parts, 4-6 parts of silicon nitride.
3. the preparation method of ultraviolet ray intercepting glass described in claim 1, which comprises the steps of:
Step 1 obtains mixture after being stirred each component；
Mixture is warming up to 160-180 DEG C, is kept for 60-80 minutes, be then warming up to melting again, forms glass metal by step 2；
Glass metal homogenizing, clarification, discharge bubble are formed treated glass metal by step 3；
Step 4, will treated glass metal molding, annealing, cooling, polishing obtains ultraviolet ray intercepting glass.
4. the preparation method of ultraviolet ray intercepting glass according to claim 3, which is characterized in that be stirred in step 1
Mixing speed is 150-180 revs/min, mixing time 30-40 minutes.
5. the preparation method of ultraviolet ray intercepting glass according to claim 3, which is characterized in that by mixture liter in step 2
The heating rate of temperature to 160-180 DEG C is 1-2 DEG C/min.
6. the preparation method of ultraviolet ray intercepting glass according to claim 3, which is characterized in that be warming up to melting in step 2
Heating rate be 4-5 DEG C/min.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811158553.4A CN109502971A (en) | 2018-09-30 | 2018-09-30 | A kind of ultraviolet ray intercepting glass and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811158553.4A CN109502971A (en) | 2018-09-30 | 2018-09-30 | A kind of ultraviolet ray intercepting glass and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN109502971A true CN109502971A (en) | 2019-03-22 |
Family
ID=65746233
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201811158553.4A Pending CN109502971A (en) | 2018-09-30 | 2018-09-30 | A kind of ultraviolet ray intercepting glass and preparation method thereof |
Country Status (1)
| Country | Link |
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| CN (1) | CN109502971A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111018349A (en) * | 2019-12-17 | 2020-04-17 | 安徽凤阳玻璃有限公司 | Ultraviolet-proof plate glass and preparation method thereof |
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2018
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| CN111018349A (en) * | 2019-12-17 | 2020-04-17 | 安徽凤阳玻璃有限公司 | Ultraviolet-proof plate glass and preparation method thereof |
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Application publication date: 20190322 |