CN109499359A - Photocatalysis flue gas mercury removal device in a kind of chimney of electric plant - Google Patents
Photocatalysis flue gas mercury removal device in a kind of chimney of electric plant Download PDFInfo
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- CN109499359A CN109499359A CN201811612959.5A CN201811612959A CN109499359A CN 109499359 A CN109499359 A CN 109499359A CN 201811612959 A CN201811612959 A CN 201811612959A CN 109499359 A CN109499359 A CN 109499359A
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- flue gas
- photocatalysis
- shell
- chimney
- removal device
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- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 title claims abstract description 61
- 239000003546 flue gas Substances 0.000 title claims abstract description 61
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 title claims abstract description 36
- 229910052753 mercury Inorganic materials 0.000 title claims abstract description 36
- 238000007146 photocatalysis Methods 0.000 title claims abstract description 27
- 230000001699 photocatalysis Effects 0.000 title claims abstract description 27
- 229910052751 metal Inorganic materials 0.000 claims abstract description 34
- 239000002184 metal Substances 0.000 claims abstract description 34
- 241000239290 Araneae Species 0.000 claims abstract description 15
- 239000003054 catalyst Substances 0.000 claims abstract description 14
- 238000013032 photocatalytic reaction Methods 0.000 claims abstract description 10
- 150000002739 metals Chemical class 0.000 claims abstract description 4
- 239000011941 photocatalyst Substances 0.000 claims abstract description 4
- 229910001385 heavy metal Inorganic materials 0.000 claims description 28
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical group O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 10
- 238000006555 catalytic reaction Methods 0.000 claims description 6
- 238000012544 monitoring process Methods 0.000 claims description 6
- 238000009434 installation Methods 0.000 claims description 4
- 239000003795 chemical substances by application Substances 0.000 claims description 3
- 239000007769 metal material Substances 0.000 claims description 3
- 239000012780 transparent material Substances 0.000 claims description 3
- 239000000463 material Substances 0.000 claims description 2
- 239000003517 fume Substances 0.000 abstract description 7
- 238000007254 oxidation reaction Methods 0.000 description 7
- 238000000034 method Methods 0.000 description 6
- 230000003647 oxidation Effects 0.000 description 6
- 239000003245 coal Substances 0.000 description 5
- 239000003344 environmental pollutant Substances 0.000 description 5
- 231100000719 pollutant Toxicity 0.000 description 5
- 238000010521 absorption reaction Methods 0.000 description 4
- 238000002485 combustion reaction Methods 0.000 description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 3
- 239000000835 fiber Substances 0.000 description 3
- MWUXSHHQAYIFBG-UHFFFAOYSA-N nitrogen oxide Inorganic materials O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 description 3
- -1 oxycarbide Substances 0.000 description 3
- 235000008645 Chenopodium bonus henricus Nutrition 0.000 description 2
- 244000138502 Chenopodium bonus henricus Species 0.000 description 2
- 239000003463 adsorbent Substances 0.000 description 2
- 230000003197 catalytic effect Effects 0.000 description 2
- 229910052681 coesite Inorganic materials 0.000 description 2
- 229910052906 cristobalite Inorganic materials 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 239000000779 smoke Substances 0.000 description 2
- 238000001179 sorption measurement Methods 0.000 description 2
- 229910052682 stishovite Inorganic materials 0.000 description 2
- 239000010936 titanium Substances 0.000 description 2
- 229910052719 titanium Inorganic materials 0.000 description 2
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 2
- 229910052905 tridymite Inorganic materials 0.000 description 2
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 1
- 235000011941 Tilia x europaea Nutrition 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 239000001110 calcium chloride Substances 0.000 description 1
- 229910001628 calcium chloride Inorganic materials 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000003610 charcoal Substances 0.000 description 1
- 235000019504 cigarettes Nutrition 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 238000005286 illumination Methods 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 238000001727 in vivo Methods 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 239000004571 lime Substances 0.000 description 1
- 210000003739 neck Anatomy 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 238000005192 partition Methods 0.000 description 1
- 238000007781 pre-processing Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- XTQHKBHJIVJGKJ-UHFFFAOYSA-N sulfur monoxide Chemical compound S=O XTQHKBHJIVJGKJ-UHFFFAOYSA-N 0.000 description 1
- 230000009897 systematic effect Effects 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/86—Catalytic processes
- B01D53/8665—Removing heavy metals or compounds thereof, e.g. mercury
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/007—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by irradiation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/60—Heavy metals or heavy metal compounds
- B01D2257/602—Mercury or mercury compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2258/00—Sources of waste gases
- B01D2258/02—Other waste gases
- B01D2258/0283—Flue gases
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2259/00—Type of treatment
- B01D2259/80—Employing electric, magnetic, electromagnetic or wave energy, or particle radiation
- B01D2259/804—UV light
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- Health & Medical Sciences (AREA)
- Analytical Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Biomedical Technology (AREA)
- Toxicology (AREA)
- Catalysts (AREA)
- Exhaust Gas Treatment By Means Of Catalyst (AREA)
Abstract
The present invention relates to photocatalysis flue gas mercury removal devices in a kind of chimney of electric plant, including shell, the UV UV lamp unit set on shell and the photocatalytic reaction unit that is set in the housing, the photocatalytic reaction unit is made of multiple sheet metals, the sheet metal is radially arranged to " spider reticulation " structure, the catalyst supported on surface of the sheet metal centered on the axle center of shell.Compared with prior art, the present apparatus has the contact area bigger with flue gas, and flue gas and nano-photocatalyst can have more time haptoreactions, can effectively improve fume treatment efficiency.
Description
Technical field
The present invention relates to a kind of photocatalysis flue gas mercury removal devices, and in particular to photocatalysis flue gas demercuration in a kind of chimney of electric plant
Device.
Background technique
The fast development of human society be unable to do without the supply consumption of the energy, in the energy consumption structure in China, coal-fired number
Amount about accounts for the 70% of non-renewable energy, and plurality of heavy metal is inevitably generated during the energy-consumings such as fire coal
(Hg0) etc. pollutants cause environment to break ring.Heavy metal Hg etc. has the characteristics such as strong toxicity, volatility and biological accumulation,
It is serious for breaking circumpolar to environment.In recent years, the heavy metal (Hg in coal-fired flue-gas is controlled0) etc. pollutants discharge increasingly by
Concern, China also put into effect relevant national standard in 2011, it is desirable that Mercury In Coal Combustion Flue Gas discharge amount is strictly less than 0.03mg/
m3, therefore the task of top priority is to find a reliable removing heavy metal (Hg0) etc. pollutants method.
Pollutant mainly includes the substances such as oxycarbide, nitrogen oxides, oxysulfide, mercury and other heavy metals in flue gas.
Heavy metal such as mercury highly volatile after fired coal combustion enters flue gas.For example, there are three types of existence form, nonvalent mercury, bivalent mercuries for mercury
And particulate Hg, wherein nonvalent mercury almost all after fired coal combustion is discharged into the atmosphere, and can be enriched in vivo, is caused
The serious broken ring of ecological environment.
There are mainly three types of modes for coal-fired flue-gas removing heavy metal: pre-processing before burning, controls after control, burning in burning.
The present domestic and international research for burning removing heavy metal is less, lacks systematic further investigation and technological achievement.At present
The main methods such as removing heavy metal Hg still utilize active carbon, and the adsorbents such as calcium chloride inhale heavy metal in flue gas mercury etc.
Attached removing, but removal efficiency is not high, and the research of new adsorbent also lacks breakthrough achievement.Another method is to pass through power plant
Fume treatment auxiliary heavy metal Hg etc. is removed, but power-plant flue gas processing equipment be difficult heavy metal Hg etc. is effectively de-
It removes, therefore, it is very necessary to solve heavy metal in flue gas pollution problem to invent a kind of novel photocatalysis fume treatment structure.
Device and its application of a kind of removing gas mercury by photo-catalysis are disclosed in Chinese patent (CN102430328A), wherein
It is supported on the method that titanium silk fiber is online, and UV ultraviolet source is installed in centre using nano TiO 2-SiO2, is segmented by multiple branch
Detachable binocular tube is arranged in flue, will be oxidized to Hg by gaseous mercury in the flue gas in titanium wire network fiber2+, then pass through reality
It sends out the lime slurry of desulphurization plant and removes, but the device takes off in such a way that nano TiO 2-SiO2 is supported on titanium silk fiber net
Mercury efficiency is lower, and there are still certain gaseous mercuries in flue gas.It is disclosed in a kind of chimney in Chinese patent (CN107694334A)
Photocatalysis mercury removal device, wherein using the corrugated metal thin plate of rotatable carried titanium dioxide/charcoal, UV lamp unit is set to
Upper part or lower part, it is smaller with active catalyst time of contact and area increase when flue gas passes through, the raising of demercuration efficiency also compared with
It is limited.
Summary of the invention
The purpose of the present invention is to solve the above-mentioned problems and provides photocatalysis flue gas demercuration dress in a kind of chimney of electric plant
It sets.
The purpose of the present invention is achieved through the following technical solutions:
Photocatalysis flue gas mercury removal device in a kind of chimney of electric plant, including shell, set on shell UV UV lamp unit and
The photocatalytic reaction unit being set in the housing, the photocatalytic reaction unit are made of multiple sheet metals, the sheet metal
" spider reticulation " structure, the catalyst supported on surface of the sheet metal are radially arranged to centered on the axle center of shell.
Further, the shell is cylindrical shape, is made of inner shell and outer shell, and the inner shell is transparent
Material, the outer shell are metal material, and the UV UV lamp unit is set between the inner shell and outer shell.
Further, the UV UV lamp unit is equipped with multiple, is equally spaced around in housing sidewall.
Further, the UV UV lamp unit includes UV ultraviolet lamp and conducting wire.
Further, the outside of the outer shell is equipped with the fixed ring for installation, and the fixed ring is equipped with a pair.
Further, the enclosure interior is equipped with multiple for installing the fixation demarcation plate of sheet metal, the fixation point
Enclosure interior is divided into the sector of area equation by partition, and the sheet metal is mounted between adjacent fixed demarcation plate.
Further, the sheet metal has different length, and the sheet metal length of inside is longer than outside.
Further, the sheet metal is equipped with multilayer, is equally spaced from the radial direction of interior past outer shell.
Further, the catalyst is TiO2/BiOIO3Nano-photocatalyst material.
Further, which is equipped with the flue gas monitoring instrument for monitoring heavy metal in flue gas content.
The present invention is difficult to remove for the heavy metal in coal-fired flue-gas, such as gaseous mercury, and it is anti-that photocatalysis is arranged in shell
Unit is answered, the unit is using load TiO2/BiOIO3Sheet metal constitute " spider reticulation " structure, chimney smoke by should
When " spider reticulation " structure, barrier, shunting function through " spider reticulation " structural metal thin slice can more effectively capture cigarette
Gas increases the contact area on flue gas and photocatalytic reaction unit and residence time.Loading in " spider reticulation " structure has
The catalyst of absorption and catalysis double action, when flue gas passes through, can effectively contact with catalyst, and absorption occurs and light is urged
Oxidation, advantageous to increase absorption and light-catalyzed reaction efficiency, UV UV lamp unit makes light source full of fume treatment structure, and
And " spider reticulation " structure is somebody's turn to do to smoke flow resistance very little.Under the irradiation of UV lamp, when flue gas with this configuration when, photocatalysis
Agent carries out more thorough catalysis oxidation to flue gas and gaseous mercury is such as oxidized to bivalent mercury by the heavy metal oxidation in flue gas.
The invention has the benefit that
1, " spider reticulation " structure that sheet metal is constituted, is effectively increased the time of contact of flue gas and catalyst and connects
Contacting surface product, can significantly improve the efficiency of absorption and light-catalyzed reaction, be conducive to the further catalysis oxygen of heavy metal in flue gas
Change, gaseous mercury is such as oxidized to bivalent mercury, the efficiency of heavy metal removing can significantly then be increased by adsorption treatment again.
2, inner shell is thermostable transparent quartz glass, can effectively make light source full of fume treatment structure, can
So that catalyst in " spider reticulation " structure is effectively received UV ultraviolet lamp strong illumination, makes flue gas and photochemical catalyst under ultraviolet strong light
Catalytic oxidation effectively occurs.
3, the configuration of the present invention is simple, mounting arrangements are convenient, operating cost is low, have the characteristics that dismantle, replace it is convenient.It can answer
For related necks such as power-plant flue gas removing heavy metal, coal combustion equipment flue gas removing heavy metal, Industrial Boiler flue gas removing heavy metals
Domain promotes in flue gas heavy metal Pollutant Control Technology and has broad prospects with application aspect.
Detailed description of the invention
Fig. 1 is the cross-sectional view of apparatus of the present invention；
Fig. 2 is the vertical section schematic diagram of apparatus of the present invention；
In figure: 1-UV ultraviolet lamp conducting wire；2- outer shell；3- fixed ring；4-UV ultraviolet lamp；5- inner shell；6- metal
Thin slice；7- fixes demarcation plate.
Specific embodiment
The present invention is described in detail with specific embodiment below in conjunction with the accompanying drawings.
Embodiment
As shown in Figure 1, 2, photocatalysis flue gas mercury removal device in a kind of chimney of electric plant, including shell, set on the UV purple of shell
Outer lamp unit and the photocatalytic reaction unit being set in the housing, photocatalytic reaction unit are made of multiple sheet metals 6, metal
Thin slice 6 is radially arranged to " spider reticulation " structure, the catalyst supported on surface of sheet metal 6, sheet centered on the axle center of shell
Embodiment uses photochemical catalyst for TiO2/BiOIO3, specifically, different metal thin slice 6 is connected, and centered on the shell center of circle
Symmetrically be arranged to " spider reticulation " irradiation structure, can make flue gas with this configuration when time of contact and contact area significantly
Increase, and is somebody's turn to do " spider reticulation " structure to the flow resistance very little of flue gas.
Shell is cylindrical shape, is made of inner shell 5 and outer shell 2, and inner shell 5 is transparent material, using resistance to height
Warm transparency silica glass can make UV ultraviolet light sufficiently irradiate photocatalysis unit, be conducive to flue gas and active photocatalyst is adsorbed
And catalytic oxidation sufficiently occurs.Outer shell 2 is metal material, and UV UV lamp unit is set to inner shell 5 and outer shell
Between body 2.UV UV lamp unit be equipped with it is multiple, be equally spaced around in housing sidewall, UV UV lamp unit includes UV ultraviolet
Lamp 4 and conducting wire 1, UV ultraviolet lamp tube unit are arranged symmetrically 10 between double Shell, and UV ultraviolet lamp position is reasonable, makes
Light source is effectively full of fume treatment structure, reaches it most preferably to photocatalysis efficiency, and the outside of outer shell 2 is equipped with for installing
Fixed ring 3, fixed ring 3 be equipped with a pair.Enclosure interior is equipped with multiple fixation demarcation plates 7 for being used to install sheet metal 6, fixed
Enclosure interior is divided into the sector of area equation by demarcation plate 7, and sheet metal 6 is mounted between adjacent fixed demarcation plate 7.Metal
Thin slice 6 have different length, 6 length of sheet metal of inside is longer than outside, sheet metal 6 be equipped with multilayer, from it is interior outward
Radial direction along shell is equally spaced.
In addition, the device upper end is equipped with the flue gas monitoring instrument for monitoring heavy metal in flue gas content, to monitor in flue gas
Heavy metal Hg equal size needs to carry out photocatalytic reaction unit the operation such as to replace when content exceeds critical field.
This example working principle is as follows:
Device cloth in chimney is fixed setting in the middle position of entire chimney height by installation fixed ring installation,
Photochemical catalyst when flue gas passes through the fume treatment structure below chimney, on flue gas and photocatalysis unit " spider reticulation " structure
It sufficiently contacts for a long time, is somebody's turn to do " spider reticulation " irradiation structure, be conducive to capture flue gas, increase the light that flue gas is loaded with it and urge agent
Time of contact and contact area are conducive to the progress of photocatalysis oxidation reaction, improve the removal efficiency of the heavy metals such as mercury in flue gas.
By the bivalent mercury of heavy metal such as gaseous state mercury oxidation by adsorption treatment, the pollution to atmospheric environment can be reduced.And at the same time setting
Flue gas on-Line Monitor Device is set, which samples in chimney outlet, to monitor heavy metal in flue gas such as mercury content,
When content exceeds critical field, need to replace sheet metal and photochemical catalyst, regenerate etc. operation.
The above description of the embodiments is intended to facilitate ordinary skill in the art to understand and use the invention.
Person skilled in the art obviously easily can make various modifications to these embodiments, and described herein general
Principle is applied in other embodiments without having to go through creative labor.Therefore, the present invention is not limited to the above embodiments, ability
Field technique personnel announcement according to the present invention, improvement and modification made without departing from the scope of the present invention all should be of the invention
Within protection scope.
Claims (10)
1. photocatalysis flue gas mercury removal device in a kind of chimney of electric plant, including shell, set on shell UV UV lamp unit and set
In the intracorporal photocatalytic reaction unit of shell, which is characterized in that the photocatalytic reaction unit is made of multiple sheet metals (6),
The sheet metal (6) is radially arranged to " spider reticulation " structure, the table of the sheet metal (6) centered on the axle center of shell
Face supported catalyst.
2. photocatalysis flue gas mercury removal device in a kind of chimney of electric plant according to claim 1, which is characterized in that the shell
It for cylindrical shape, is made of inner shell (5) and outer shell (2), the inner shell (5) is transparent material, the outer shell
Body (2) is metal material, and the UV UV lamp unit is set between the inner shell (5) and outer shell (2).
3. photocatalysis flue gas mercury removal device in a kind of chimney of electric plant according to claim 1, which is characterized in that the UV is purple
Outer lamp unit be equipped with it is multiple, be equally spaced around in housing sidewall.
4. photocatalysis flue gas mercury removal device in a kind of chimney of electric plant according to claim 3, which is characterized in that the UV is purple
Outer lamp unit includes UV ultraviolet lamp (4) and conducting wire (1).
5. photocatalysis flue gas mercury removal device in a kind of chimney of electric plant according to claim 2, which is characterized in that the outer layer
The outside of shell (2) is equipped with the fixed ring (3) for installation, and the fixed ring (3) is equipped with a pair.
6. photocatalysis flue gas mercury removal device in a kind of chimney of electric plant according to claim 1, which is characterized in that the shell
Inside is equipped with multiple fixation demarcation plates (7) for being used to install sheet metal (6), and the fixed demarcation plate (7) divides enclosure interior
It is segmented into the sector of area equation, the sheet metal (6) is mounted between adjacent fixed demarcation plate (7).
7. photocatalysis flue gas mercury removal device in a kind of chimney of electric plant according to claim 6, which is characterized in that the metal
Thin slice (6) has different length, and sheet metal (6) length of inside is longer than outside.
8. photocatalysis flue gas mercury removal device in a kind of chimney of electric plant according to claim 7, which is characterized in that the metal
Thin slice (6) is equipped with multilayer, is equally spaced from the radial direction of interior past outer shell.
9. photocatalysis flue gas mercury removal device in a kind of chimney of electric plant according to claim 1, which is characterized in that the catalysis
Agent is TiO2/BiOIO3Nano-photocatalyst material.
10. photocatalysis flue gas mercury removal device in a kind of chimney of electric plant according to claim 1, which is characterized in that the device
Upper end is equipped with the flue gas monitoring instrument for monitoring heavy metal in flue gas content.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811612959.5A CN109499359A (en) | 2018-12-27 | 2018-12-27 | Photocatalysis flue gas mercury removal device in a kind of chimney of electric plant |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811612959.5A CN109499359A (en) | 2018-12-27 | 2018-12-27 | Photocatalysis flue gas mercury removal device in a kind of chimney of electric plant |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN109499359A true CN109499359A (en) | 2019-03-22 |
Family
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201811612959.5A Pending CN109499359A (en) | 2018-12-27 | 2018-12-27 | Photocatalysis flue gas mercury removal device in a kind of chimney of electric plant |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112827351A (en) * | 2020-12-25 | 2021-05-25 | 李红霞 | Spraying line VOCs exhaust treatment device |
| CN112844037A (en) * | 2020-12-25 | 2021-05-28 | 李红霞 | Organic waste gas treatment device of paint spraying line |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102430328A (en) * | 2011-09-26 | 2012-05-02 | 上海电力学院 | Device for removing gas mercury by photo-catalysis and application thereof |
| CN106731821A (en) * | 2017-02-28 | 2017-05-31 | 诺曼利尔（青岛）环境能源技术有限公司 | The device of photochemical catalytic oxidation cleaning of off-gas |
| CN107694334A (en) * | 2017-11-15 | 2018-02-16 | 上海电力学院 | Photocatalysis mercury removal device in a kind of chimney |
| CN107694247A (en) * | 2017-11-13 | 2018-02-16 | 安徽工业大学 | A kind of air purification method based on water mist sprinkling and photocatalysis technology |
| JP2018047439A (en) * | 2016-09-23 | 2018-03-29 | 株式会社エッチ・ケー・エス | Catalytic metal carrier |
| CN209848674U (en) * | 2018-12-27 | 2019-12-27 | 上海电力学院 | Photocatalysis flue gas demercuration device in power plant's chimney |
-
2018
- 2018-12-27 CN CN201811612959.5A patent/CN109499359A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102430328A (en) * | 2011-09-26 | 2012-05-02 | 上海电力学院 | Device for removing gas mercury by photo-catalysis and application thereof |
| JP2018047439A (en) * | 2016-09-23 | 2018-03-29 | 株式会社エッチ・ケー・エス | Catalytic metal carrier |
| CN106731821A (en) * | 2017-02-28 | 2017-05-31 | 诺曼利尔（青岛）环境能源技术有限公司 | The device of photochemical catalytic oxidation cleaning of off-gas |
| CN107694247A (en) * | 2017-11-13 | 2018-02-16 | 安徽工业大学 | A kind of air purification method based on water mist sprinkling and photocatalysis technology |
| CN107694334A (en) * | 2017-11-15 | 2018-02-16 | 上海电力学院 | Photocatalysis mercury removal device in a kind of chimney |
| CN209848674U (en) * | 2018-12-27 | 2019-12-27 | 上海电力学院 | Photocatalysis flue gas demercuration device in power plant's chimney |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112827351A (en) * | 2020-12-25 | 2021-05-25 | 李红霞 | Spraying line VOCs exhaust treatment device |
| CN112844037A (en) * | 2020-12-25 | 2021-05-28 | 李红霞 | Organic waste gas treatment device of paint spraying line |
| CN112827351B (en) * | 2020-12-25 | 2022-12-30 | 日照职业技术学院 | Spraying line VOCs exhaust treatment device |
| CN112844037B (en) * | 2020-12-25 | 2023-01-03 | 日照职业技术学院 | Organic waste gas treatment device of paint spraying line |
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