CN109499286A - One kind administering vulcanization exhaust gas technique and device based on lower temperature plasma technology - Google Patents

One kind administering vulcanization exhaust gas technique and device based on lower temperature plasma technology Download PDF

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Publication number
CN109499286A
CN109499286A CN201811652716.4A CN201811652716A CN109499286A CN 109499286 A CN109499286 A CN 109499286A CN 201811652716 A CN201811652716 A CN 201811652716A CN 109499286 A CN109499286 A CN 109499286A
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China
Prior art keywords
temperature plasma
module
air
low temperature
downstream
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CN201811652716.4A
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Inventor
钱黎明
冮殿亮
桂旺胜
许福海
王尧
刘畅
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Zhongke Xintiandi (hefei) Environmental Protection Technology Co Ltd
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Zhongke Xintiandi (hefei) Environmental Protection Technology Co Ltd
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Priority to CN201811652716.4A priority Critical patent/CN109499286A/en
Publication of CN109499286A publication Critical patent/CN109499286A/en
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/32Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by electrical effects other than those provided for in group B01D61/00
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D46/00Filters or filtering processes specially modified for separating dispersed particles from gases or vapours
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/70Organic compounds not provided for in groups B01D2257/00 - B01D2257/602
    • B01D2257/702Hydrocarbons
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2259/00Type of treatment
    • B01D2259/80Employing electric, magnetic, electromagnetic or wave energy, or particle radiation
    • B01D2259/818Employing electrical discharges or the generation of a plasma

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Treating Waste Gases (AREA)
  • Physical Or Chemical Processes And Apparatus (AREA)

Abstract

The present invention relates to one kind to administer vulcanization exhaust gas technique and device based on lower temperature plasma technology, including pouring-in low temperature plasma waste gas pollution control and treatment complexes, pouring-in low temperature plasma waste gas pollution control and treatment complexes include injection blower, the downstream of injection blower is provided with pretreatment system, the downstream of pretreatment system is provided with discharge system, the downstream of discharge system is provided with injected system, injected system connects discharge system and mixed bellows, plasma generating region is independently of reaction zone, no security risk;Discharge module is pollution-free, long service life;Using double-dielectric barrier discharge, it is high to generate plasma density;Processing equipment is parallel with exhaust piping, reduces gas sampling and discharge blower, reduces the operation power of air-introduced machine;Operating cost is low;Examined by engineering test, treated vulcanization exhaust gas in non-methane hydrocarbon emission well below national requirements standard 10mg/m3, treatment effeciency is more than 60%;Odor concentration treatment effeciency is more than 80%.

Description

One kind administering vulcanization exhaust gas technique and device based on lower temperature plasma technology
Technical field
The present invention relates to waste gas treatment equipment technical fields, and in particular to one kind administers sulphur based on lower temperature plasma technology Change exhaust gas technique and device.
Background technique
With the continuous social and economic development, the continuous quickening of process of industrialization, environment and energy problem are increasingly subject to people Concern.Rubber industry sulfidation can generate a large amount of curing fume, which has low concentration, strong wind Amount, difficult separation, contains the features such as tar and dust at multicomponent, and traditional Processing tecchnics cannot reach improvement and require.
Traditional administering method includes absorption process, absorption method, condensation method and bioanalysis.The investment cost of activated carbon adsorption compared with It is low, and high treating effect, it is most common VOCs treatment engineering technology.But due to being needed after activated carbon adsorption saturation Regeneration, so the operating cost using activated carbon adsorption is higher, and operating process is complicated.Bioremediation investment and running cost It with lower, but runs complicated for operation, takes up a large area, a possibility that there are secondary pollutions.There is suctions for catalytic combustion method Attached concentration --- the process of burning is desorbed again, equipment volume is larger, and noble metal catalyst price is high, once invests the problems such as big.
In recent years, lower temperature plasma technology has caused more and more to pay close attention to, and plasma is referred to as removing solid-state, liquid The 4th kind of substance existing forms except state and gaseous state, are made of electronics, ion, free radical and neutral particle, whole to protect Hold electroneutral.In low-temperature plasma body, O, OH the isoreactivity particle for thering is a large amount of high energy electron and high energy electron to generate, Then physics, the chemical reaction for causing a series of complex, make complicated macromolecule contaminant be changed into simple small-molecule substance, Or poisonous and harmful substance is made to be changed into nontoxic or less toxic low harmful substance, to enable pollutant degradation removal.Low temperature etc. Ion body technique has simple process, process flow is short, small investment, take up little area, removal rate is high, operating cost is low (mainly to show For the electricity charge), it is applied widely the features such as.
For the flue gas that sulfidation generates, urgent need designs a kind of technique and device to handle vulcanization exhaust gas, avoids vulcanizing Exhaust gas enters directly into air, causes air pollution.
Summary of the invention
To solve the above problems, the present invention is intended to provide a kind of simple process, process flow are short, small investment, take up little area, go Except rate is high, operating cost is low, applied widely administered based on lower temperature plasma technology vulcanizes exhaust gas technique and device.
Purpose to realize the present invention, the technical solution adopted is that: one kind administering vulcanization based on lower temperature plasma technology and gives up Device of air, including pouring-in low temperature plasma waste gas pollution control and treatment complexes;
The pouring-in low temperature plasma waste gas pollution control and treatment complexes include injection blower, and injection blower is needed air Inside feed arrangement, to generate low temperature plasma, while inject blower provide power high concentration low temperature of generation etc. from It is internal that exhaust piping (reactor) is sent into daughter;
The downstream of the injection blower is provided with pretreatment system, and pretreatment system is internally provided with filtering module, warm and humid Control module, pressure monitoring module and flow monitoring module are spent, injection blower, which is sent into the air come, may contain some dusts, water Vapour or other sundries need to filter dust, steam and sundries by filtering module, while the system is furnished with Temperature and Humidity Control mould Block, pressure monitoring module and flow monitoring module, so that the gas into discharge system is all clean air, discharge gas pressure Power, temperature, humidity are in optimal discharge state, improve the discharging efficiency of discharge system;
The downstream of the pretreatment system is provided with discharge system, and discharge system is internally provided with low temperature plasma Module allows discharge space more compact, reduces the area of equipment, simultaneously since the gas of electric discharge is clean air The reduction of discharging gap can be such that discharge voltage reduces, and reduce the design requirement of matching power supply, improve the discharging efficiency of power supply, drop Low energy consumption;
The downstream of the discharge system is provided with injected system, and front end prevents useless inside exhaust piping there are check-valves Gas enters in discharge system, and exhaust gas is avoided low temperature plasma in discharge system to occur the corrosion of module;Using reasonable note Enter structure or matching device, the low temperature plasma including a large amount of active groups of generation is injected into exhaust piping, with exhaust gas Reaction is come into full contact with, so as to pollutant to be treated of quickly degrading, achievees the purpose that degradation of contaminant;
The pouring-in low temperature plasma waste gas pollution control and treatment complexes further include the control system packet by control system Sensor module and PLC module are included, sensor module is arranged inside discharge system, the downstream connection PLC of sensor module Module, the downstream connection pretreatment system of PLC module, discharge system, injection blower and injected system, system can realize it is local and By the matching low temperature plasma that automatically tracks that power supply may be implemented in live PLC module module occurs for long-range control, so that low Isothermal plasma generation module works long hours stable, safe, unattenuated;Sensor detection data is transmitted to PLC module simultaneously, PLC module can automatically the data detected compared with the parameter of setting, calculate, signal is then fed back into executing agency, from And realize closed-loop control, and the operation of equipment is controlled by output signal;
The pouring-in low temperature plasma waste gas pollution control and treatment complexes further include mixed bellows, injected system connection electric discharge system System and mixed bellows, inserted with discarded collection conduit in the mixed bellows, the discarded collection conduit connects mixed bellows and vulcanized vehicle Between, the downstream of the discarded collection conduit in the mixed bellows downstream is set as air-introduced machine, and the downstream of the air-introduced machine is provided with 15m row Inflator.
Preferably, the side of the injection blower is provided with sound arrester.
Preferably, the pouring-in low temperature plasma waste gas pollution control and treatment complexes connect injected system by connecting tube.
Preferably, the PLC module is directly connected to the check-valves and matching device of injected system.
Preferably, the PLC module is directly connected to temperature and Humidity Control module in pretreatment system, pressure monitoring module and stream Measure monitoring modular.
One kind based on lower temperature plasma technology administer vulcanization exhaust gas technique, the technique specifically includes the following steps:
(1) is pre-processed: air is sent into pretreatment system by injection blower, and air passes through the mistake inside pretreatment system Filter module is filtered dust, steam and sundries, while injecting the temperature of air and wet by temperature and Humidity Control module control Degree is passed through the pressure and flow of air by pressure monitoring module and flow monitoring module control injection blower, and passes through control PLC module in system carries out closed-loop control, so that clean air enters in discharge system;
(2) discharges: entering in discharge system when by the pretreated air of step 1, the low-temperature plasma of discharge system Body occurs module and works, and discharges air, generates low temperature plasma mixture largely including active group, Low temperature plasma mixture enters in injected system;
(3) reacts: the vulcanization exhaust gas come from curing department is introduced into mixed bellows by discarded collection conduit, step 2 To check-valves and matching device of the low temperature plasma mixture including active group Jing Guo injected system enter mixed bellows It is internal to be reacted with vulcanization exhaust gas, check-valves and matching device are adjusted by the PLC module in control system, fast degradation needs The pollutant of processing, and generate safe and environment-friendly exhaust gas;
(4) is discharged: the exhaust gas after step 3 reaction, degradation is passed into inside air-introduced machine by discarded collection conduit, Exhaust gas is delivered in 15m exhaust tube carries out safety dumping again by air-introduced machine, achievees the purpose that administer vulcanization exhaust gas.
The invention has the benefit that the device of the invention connects each member in tight, administered using low temperature plasma Vulcanize exhaust gas, has the advantage that
Plasma generating region is independently of reaction zone, no security risk;Discharge module is pollution-free, long service life;Using It is high to generate plasma density for double-dielectric barrier discharge;Processing equipment is parallel with exhaust piping, reduces gas sampling and discharge Blower reduces the operation power of air-introduced machine;Construction and operation expense is low;It is examined by engineering test, treated vulcanizes exhaust gas Standard 10mg/m of the middle non-methane hydrocarbon emission well below national requirements3, treatment effeciency is more than 60%;Odor concentration processing effect Rate is more than 80%.
Detailed description of the invention
Fig. 1 is that the present invention is based on the overall structure diagrams 1 that lower temperature plasma technology administers vulcanization exhaust device.
Fig. 2 is that the present invention is based on the overall structure diagrams 2 that lower temperature plasma technology administers vulcanization exhaust device.
In figure: 1, pouring-in low temperature plasma waste gas pollution control and treatment complexes;2, bellows are mixed;3, collection conduit is discarded;4, Inject blower;5, sound arrester;6, connecting tube;7, check-valves;8, matching device;9, air-introduced machine;10,15m exhaust tube;11, vulcanize Workshop.
Specific embodiment
Below in conjunction with the embodiment of the present invention, technical solution of the present invention is clearly and completely described, it is clear that Described embodiments are only a part of the embodiments of the present invention, instead of all the embodiments.Based on the implementation in the present invention Example, every other embodiment obtained by those of ordinary skill in the art without making creative efforts belong to The scope of protection of the invention.
Embodiment 1
As shown in Figs. 1-2, a kind of that vulcanization exhaust device, including pouring-in low temperature etc. are administered based on lower temperature plasma technology Gas ions waste gas pollution control and treatment complexes 1, the pouring-in low temperature plasma waste gas pollution control and treatment complexes 1 include injection blower 4, The downstream of the injection blower 4 is provided with pretreatment system, and the downstream of the pretreatment system is provided with discharge system, described to put The downstream of electric system is provided with injected system, and injected system connects discharge system and mixed bellows 2;
The pouring-in low temperature plasma waste gas pollution control and treatment complexes 1 further include the control system by control system It include sensor module and PLC module, sensor module is arranged inside discharge system, the downstream connection of sensor module PLC module, downstream connection pretreatment system, discharge system, injection blower 4 and the injected system of PLC module;
The pouring-in low temperature plasma waste gas pollution control and treatment complexes 1 further include mixed bellows 2, are inserted in the mixed bellows 2 Enter to have discarded collection conduit 3, the discarded collection conduit 3 connects mixed bellows 2 and curing department 11, mixed 2 downstream of bellows The downstream of discarded collection conduit 3 is set as air-introduced machine 9, and the downstream of the air-introduced machine 9 is provided with 15m exhaust tube 10.
Further, the side of the injection blower 4 is provided with sound arrester 5.
Further, the pouring-in low temperature plasma waste gas pollution control and treatment complexes 1 pass through the connection injection of connecting tube 6 system System.
Further, the injected system includes check-valves 7 and matching device 8.
Further, the PLC module is directly connected to the check-valves 7 and matching device 8 of injected system.
Further, the pretreatment system is internally provided with filtering module, temperature and Humidity Control module, pressure monitoring module With flow monitoring module.
Further, the PLC module be directly connected to temperature and Humidity Control module in pretreatment system, pressure monitoring module and Flow monitoring module.
Further, the discharge system is internally provided with low temperature plasma generation module.
One kind based on lower temperature plasma technology administer vulcanization exhaust gas technique, the technique specifically includes the following steps:
(1) is pre-processed: air is sent into pretreatment system by injection blower 4, and air passes through the mistake inside pretreatment system Filter module is filtered dust, steam and sundries, while injecting the temperature of air and wet by temperature and Humidity Control module control Degree is passed through the pressure and flow of air by pressure monitoring module and flow monitoring module control injection blower 4, and passes through control PLC module in system carries out closed-loop control, so that clean air enters in discharge system;
(2) discharges: entering in discharge system when by the pretreated air of step 1, the low-temperature plasma of discharge system Body occurs module and works, and discharges air, generates low temperature plasma mixture largely including active group, Low temperature plasma mixture enters in injected system;
(3) reacts: being introduced into mixed bellows 2, is walked by discarded collection conduit 3 from the vulcanization exhaust gas of curing department 11 Check-valves 7 and matching device 8 of the rapid 2 obtained low temperature plasma mixtures including active group Jing Guo injected system enter Mixed 2 inside of bellows is reacted with vulcanization exhaust gas, adjusts check-valves 7 and matching device 8 by the PLC module in control system, fastly Prompt drop solution pollutant to be treated, and generate safe and environment-friendly exhaust gas;
(4) is discharged: the exhaust gas after step 3 reaction, degradation is passed into air-introduced machine 9 by discarded collection conduit 3 Exhaust gas is delivered in 15m exhaust tube 10 carries out safety dumping again by portion, air-introduced machine 9, achievees the purpose that administer vulcanization exhaust gas.
In the present invention, plasma generating region is independently of reaction zone, no security risk;Discharge module is pollution-free, uses Service life is long;Using double-dielectric barrier discharge, it is high to generate plasma density;Processing equipment is parallel with exhaust piping, reduces useless Gas is collected and discharge blower, reduces the operation power of air-introduced machine;Construction and operation expense is low;It is examined, is handled by engineering test Standard 10mg/m of the non-methane hydrocarbon emission well below national requirements in vulcanization exhaust gas afterwards3, treatment effeciency is more than 60%;It is smelly Gas concentration treatment effeciency is more than 80%.
It although an embodiment of the present invention has been shown and described, for the ordinary skill in the art, can be with A variety of variations, modification, replacement can be carried out to these embodiments without departing from the principles and spirit of the present invention by understanding And modification, the scope of the present invention is defined by the appended.

Claims (8)

1. one kind administers vulcanization exhaust device, including pouring-in low temperature plasma waste gas pollution control and treatment based on lower temperature plasma technology Complexes (1), it is characterised in that: the pouring-in low temperature plasma waste gas pollution control and treatment complexes (1) include injection blower (4), the downstream of injection blower (4) is provided with pretreatment system, and the downstream of the pretreatment system is provided with discharge system, The downstream of the discharge system is provided with injected system, and injected system connects discharge system and mixed bellows (2);
The pouring-in low temperature plasma waste gas pollution control and treatment complexes (1) further include the control system packet by control system Sensor module and PLC module are included, sensor module is arranged inside discharge system, the downstream connection PLC of sensor module Module, downstream connection pretreatment system, discharge system, injection blower (4) and the injected system of PLC module;
The pouring-in low temperature plasma waste gas pollution control and treatment complexes (1) further include mixing bellows (2), in the mixed bellows (2) Inserted with discarded collection conduit (3), the discarded collection conduit (3) connects mixed bellows (2) and curing department (11), the mixed wind The downstream of the discarded collection conduit (3) in case (2) downstream is set as air-introduced machine (9), and the downstream of the air-introduced machine (9) is provided with 15m Exhaust tube (10).
2. a kind of administered based on lower temperature plasma technology according to claim 1 vulcanizes exhaust device, it is characterised in that: The side of injection blower (4) is provided with sound arrester (5).
3. a kind of administered based on lower temperature plasma technology according to claim 1 vulcanizes exhaust device, it is characterised in that: The pouring-in low temperature plasma waste gas pollution control and treatment complexes (1) connect injected system by connecting tube (6).
4. a kind of administered based on lower temperature plasma technology according to claim 1 vulcanizes exhaust device, it is characterised in that: The injected system includes check-valves (7) and matching device (8);
The PLC module is directly connected to the check-valves (7) and matching device (8) of injected system.
5. a kind of administered based on lower temperature plasma technology according to claim 1 vulcanizes exhaust device, it is characterised in that: The pretreatment system is internally provided with filtering module, temperature and Humidity Control module, pressure monitoring module and flow monitoring module.
6. a kind of according to claim 1 or 5 administer vulcanization exhaust device based on lower temperature plasma technology, feature exists In: the PLC module is directly connected to temperature and Humidity Control module in pretreatment system, pressure monitoring module and flow monitoring module.
7. a kind of administered based on lower temperature plasma technology according to claim 1 vulcanizes exhaust device, it is characterised in that: The discharge system is internally provided with low temperature plasma and module occurs.
8. one kind based on lower temperature plasma technology administer vulcanization exhaust gas technique, it is characterised in that: the technique specifically include with Lower step:
(1) is pre-processed: air is sent into pretreatment system by injection blower (4), and air passes through the filtering inside pretreatment system Module is filtered dust, steam and sundries, while the temperature and humidity of injection air is controlled by temperature and Humidity Control module, It is passed through the pressure and flow of air by pressure monitoring module and flow monitoring module control injection blower (4), and passes through control PLC module in system carries out closed-loop control, so that clean air enters in discharge system;
(2) discharges: entering in discharge system when by the pretreated air of step 1, the low temperature plasma hair of discharge system Raw module works, and discharges air, generates low temperature plasma mixture largely including active group, low temperature Plasma mixture enters in injected system;
(3) reacts: the vulcanization exhaust gas come from curing department (11) is introduced into mixed bellows (2) by discarded collection conduit (3), Check-valves (7) and matching device (8) of the low temperature plasma mixture including active group that step 2 obtains Jing Guo injected system Enter that mixed bellows (2) are internal to be reacted with vulcanization exhaust gas, by PLC module adjusting check-valves (7) in control system and Matching device (8), fast degradation pollutant to be treated, and generate safe and environment-friendly exhaust gas;
(4) is discharged: the exhaust gas after step 3 reaction, degradation is passed into air-introduced machine (9) by discarded collection conduit (3) Exhaust gas is delivered in 15m exhaust tube (10) carries out safety dumping again by portion, air-introduced machine (9), achievees the purpose that administer vulcanization exhaust gas.
CN201811652716.4A 2018-12-28 2018-12-28 One kind administering vulcanization exhaust gas technique and device based on lower temperature plasma technology Pending CN109499286A (en)

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CN201811652716.4A CN109499286A (en) 2018-12-28 2018-12-28 One kind administering vulcanization exhaust gas technique and device based on lower temperature plasma technology

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113713588A (en) * 2020-05-26 2021-11-30 台州国聪环保设备有限公司 Injection type plasma waste gas treatment device

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KR101567746B1 (en) * 2015-06-16 2015-11-09 박정봉 Apparatus for treating exhaust gas
CN105536454A (en) * 2016-01-22 2016-05-04 中科新天地(合肥)环保科技有限公司 Injection-type complete device for treating organic exhaust gas through low-temperature plasma
CN206064114U (en) * 2016-08-29 2017-04-05 江苏齐清环境科技有限公司 A kind of plasma purification processes the device of foul gass
CN207430002U (en) * 2017-10-18 2018-06-01 纳路(厦门)环保科技有限公司 A kind of pouring-in low-temperature plasma waste gas treatment device
CN209679835U (en) * 2018-12-28 2019-11-26 中科新天地(合肥)环保科技有限公司 One kind administering vulcanization exhaust device based on lower temperature plasma technology

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103055674A (en) * 2013-01-15 2013-04-24 上海慧丰环境工程有限公司 Injection type low-temperature plasma waste gas treatment system
KR101567746B1 (en) * 2015-06-16 2015-11-09 박정봉 Apparatus for treating exhaust gas
CN105536454A (en) * 2016-01-22 2016-05-04 中科新天地(合肥)环保科技有限公司 Injection-type complete device for treating organic exhaust gas through low-temperature plasma
CN206064114U (en) * 2016-08-29 2017-04-05 江苏齐清环境科技有限公司 A kind of plasma purification processes the device of foul gass
CN207430002U (en) * 2017-10-18 2018-06-01 纳路(厦门)环保科技有限公司 A kind of pouring-in low-temperature plasma waste gas treatment device
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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113713588A (en) * 2020-05-26 2021-11-30 台州国聪环保设备有限公司 Injection type plasma waste gas treatment device
CN113713588B (en) * 2020-05-26 2024-02-09 台州国聪环保设备有限公司 Injection type plasma waste gas treatment device

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Application publication date: 20190322