CN109497094A - A kind of footgear deodorizing antibiotic composition and preparation method thereof containing zinc ricinate - Google Patents
A kind of footgear deodorizing antibiotic composition and preparation method thereof containing zinc ricinate Download PDFInfo
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- CN109497094A CN109497094A CN201811326712.7A CN201811326712A CN109497094A CN 109497094 A CN109497094 A CN 109497094A CN 201811326712 A CN201811326712 A CN 201811326712A CN 109497094 A CN109497094 A CN 109497094A
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N33/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic nitrogen compounds
- A01N33/02—Amines; Quaternary ammonium compounds
- A01N33/12—Quaternary ammonium compounds
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
- A01N65/08—Magnoliopsida [dicotyledons]
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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- B01D53/38—Removing components of undefined structure
- B01D53/44—Organic components
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
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Abstract
The present invention provides a kind of footgear deodorizing antibiotic composition containing zinc ricinate, including deodorant and antibacterial agent;The deodorant includes following parts by weight material: 1-5% zinc ricinate;The antibacterial agent includes following parts by weight material: 0.1-0.5% chlorocarbon base dimethyl-benzyl amine, 0.1-5% lupulus extract, 0.1-5% Pelargonium roseum extract, 0.1-5% north Chinese mugwort extract.The present invention prepares a kind of footgear deodorizing antibiotic composition containing zinc ricinate, it can be sprayed directly on at foot and footgear, the normal perspiration functions of foot are not influenced, it is smelly foot odour caused by foot sweat, tinea pedis, shoes can be decomposed rapidly, mitigate footgear peculiar smell makes persistently to keep pure and fresh in shoes to footgear stink deodorizing rate up to 92%, with good environmental safety, increases the social confidence of consumer and slow down damage of the foot stench to wearer's footgear.
Description
Technical field
The present invention relates to household chemicals technical fields, and in particular to a kind of footgear deodorizing antibiotic group containing zinc ricinate
Close object and preparation method thereof.
Background technique
The microorganism of research and development centre, Uniliver and University of Nottingham's joint study foot odour and biochemical origin (James A G,
Cox D, Worrall K.Microbiological and biochemical origins of human foot
2013,28 (4): malodour [J] .Flavour&Fragrance Journal 231-237.) studies foot ageing tissues
The organism of degradation production stench and metabolic pathway, develop external " foot stench model ", consumer are helped to more fully understand
How resident microorganism on the skin generates crucial smell.Foot organic matter, callus group are woven in corynebacteria and sit skin ball
Under bacterium effect, it is metabolized as valine, leucine, isoleucine, these amino acid are the substrate for generating odorant.Golden yellow Portugal
These amino acid of the further catabolism of grape coccus form foot stench key chemical components, i.e. volatile fatty acid, such as isobutyl
Acid, isovaleric acid, 2-Methyl Butyric Acid.Research finds that foot microorganism staphylococcus aureus is the main producers of isovaleric acid.And
Some brevibacterium Brevibacterium spp., Coccus kytococcus spp., Micrococcus spp. micrococcus luteus
Complete catabolism leucine generates CO2And moisture.Compared with the dry crowd of those foots, those wear the shoes of deadend
Sub and foot sweat secretes more crowd, and toe clearance is compressed when wearing shoes and sweat evaporation is hindered, and is mentioned to greatest extent
For the water source of support bacteria growth, a possibility that foot total number of bacteria is higher than normal value, bacterium and fungal infection, is bigger.Phase
Instead, those barefoot people problem related to bacterial multiplication is less.This is research shows that the dynamic mistake that foot foul odour generates
Journey.
Empress dowager university, Thailand carries out body malodor and its (Kanlayavattanakul, M.and are studied in local treatment agent
Lourith, N.Body malodours and their topical treatment agents [J] .International
Journal ofCosmetic Science, 2011,33:298-311.), discuss the effective component packet for treating body odour
It includes: aluminium antiperspirant salts (most significant is polymeric aluminum chloride ACH, aluminum sulfate and aluminium chloride);Water-soluble zinc salt (zinc gluconate,
Zinc acetate, zinc oxide, zinc citrate, zinc chloride, zinc pyrrolidones, zinc lactate and zinc sulfate);Manganous salt (manganese chloride, acetic acid
Manganese and manganese sulfate);Antimicrobial (antimicrobial ceramics, silver zeolite, triclosan, azole antifungal agent);Odor neutralizer
(NaHCO3, silicate);Odour absorbents (cyclodextrin, silicate and silica) etc..For treating the novel components of body malodor
Include: the inhibitor of expression of androgen receptor, bacteriotrophy deprive agent, ectoenzyme, processed fabric, essential oil, herbal medicine extraction
Object etc..Research short summary sweat, the relationship between skin bacterium and body odor, wherein generating foot smell bacterial flora and including
Staphylococcus, corynebacteria and Propionibacterium.
So make full use of referred in document treatment body odour effective component, develop a kind of deodouring effect it is excellent, at
The footgear deodorizing antibiotic foodcare product for dividing source natural, can be sprayed directly on at foot and footgear, not influence foot and normally arrange
Sweat function, is harmful to human health, and on footgear material and quality without influence, has good environmental safety, increases consumer
Social activity is self-confident and slows down damage of the foot stench to wearer's footgear.
Lupulus extract main component is humulus grass ketone and golden hop ketone;Xanthohumol, Isoxanthohumol;Terpenes and terpenes
Type oxide;Hops is recorded in " food Chinese medicine with just side " has an inhibiting effect to various bacteria, lupulones contained by hops,
The chemical components such as humulone have inhibiting effect to tubercle bacillus, staphylococcus aureus, hay bacillus etc..In Compendium of Material Medica
A kind of Chinese medicine " top must be colored " have the effects that calm, tranquilizings the mind, hypnosis, sterilization, anti-inflammatory and diuresis, also with anti-oxidant, disease-resistant
Poison, antitumor efficacy.
Pelargonium roseum extract main component is spiceleaf grass alcohol, citronellol, linalool, the Lv Hui etc. of Northeast Forestry University
People studies floral extract to the biocidal property of 3 kinds of bacteriums, finds Pelargonium roseum flower extract to staphylococcus saprophyticus and gamboge
Staphylococcus is inhibited, to the bacteriostasis rate of staphylococcus saprophyticus up to 96% or more.
North Chinese mugwort is recorded in " Mingyi Bielu " earliest, and Traditional Chinese Medicine thinks that argy wormwood has warming channel for arresting bleeding, eliminating cold to stop pain, antibechic flat
Asthma, eliminating dampness are antipruritic and other effects, and main chemical compositions may be borneol, caryophyllene oxide, australene, amphene, camphanone etc..Greatly
Even medical university Zhao Ning et al. research discovery folium artemisiae argyi extract is equal to staphylococcus aureus, Escherichia coli and bacillus subtilis
There is apparent inhibiting effect, it is especially best to the fungistatic effect of staphylococcus aureus.
Patent document US20170196296A1 discloses a kind of micro- life that can prevent skin microbial from generating foot stench
Object.Microorganism is selected from propionibacterium freudenreichii lactobacillus plantarum, lactobacillus curvatus, Bacillus acidi lactici, lactobacillus plantarum, De Shi cream bar
Bacterium, the microorganism of the inactive form of any one of Lactobacillus delbrueckii, lactobacillus plantarum and Lactobacillus brevis.To the micro- life of dermal administration
Object or its deactivated form are able to suppress the growth for generating the skin microbial of foot stench, may be implemented effectively to prevent foot stench
Generation.
2016/0067.173 A1 of patent document US discloses 0.1%-1% winter savory oil as deodorant active agent,
Comprise more than 60% geraniol and more than 5% trans--β-carypohyllene.Winter savory oil is capable of providing fragrance and/or antibacterial action,
The smell generated is decomposed by sweat for treating.Deodorant compositions may include any other be capable of providing fragrance and/or it is anti-
The essential oil of bacterium effect, including sweet basil, lemongrass, cloves, fish pelargonium, lemon grass (Cymbopogon citratus), the fruit of a cubeb litsea tree, wild marjoram and thyme.The composition mentions
For armpit or the beauty method of the bad smell of foot.
Patent document CN102406920A mixes combined oxidation component and talcum powder, borneol powder and silk peptide powder, forms energy
The combination drug of foot odour is enough treated, wherein combined oxidation component includes zinc sulfate, alumen, silica, titanium dioxide, three oxidations
Two aluminium, magnesia, boric acid, the composition can effectively treat the various pedopathys such as tinea pedis, foot odour, foot sweat and rotten foot bifurcation, have fine
Clinical effectiveness.
9,358,191 B2 of patent document US is disclosed through polyphenol and amino acid in pH=6.5 or higher oxygen molecule
It coexists down, the deodorant compositions to obtain is reacted in basic solvent.Polyphenol is preferably flavone compound, such as quercitrin
Element, epicatechin and epigallocatechin;Polyphenol with adjacent diphenol structure, such as gallic acid, chlorogenic acid, caffeic acid.
The socks worn one day are immersed in the deodorant compositions containing gallic acid, washs 5 minutes and rinses, You Wuwei at room temperature
Panellists carry out sensory evaluation to socks, and odour intensity score value from 5 is down to 1.2 after deodorization as the result is shown, deodorization
Excellent effect.
But the above patent does not provide a kind of footgear deodorizing antibiotic comprising water-soluble zinc ricinate as deodorant
Foodcare composition.
Summary of the invention
The object of the present invention is to provide a kind of footgear deodorizing antibiotic composition and preparation method thereof containing zinc ricinate, energy
Acid type malodors gas is effectively removed, it is smelly to decompose foot odour caused by foot sweat, tinea pedis, shoes rapidly, mitigates footgear peculiar smell.
The present invention solves above-mentioned technical problem using following technical scheme:
A kind of footgear deodorizing antibiotic composition containing zinc ricinate, which is characterized in that including deodorant and antibacterial agent;Institute
Stating deodorant includes following parts by weight material: 1-5% zinc ricinate;The antibacterial agent includes following parts by weight material: 0.1-
0.5% chlorocarbon base dimethyl-benzyl amine, 0.1-5% lupulus extract, 0.1-5% Pelargonium roseum extract and 0.1-5%
North Chinese mugwort extract.
Further, the composition includes the chelating agent of 0.1-0.5% parts by weight and the anti-corrosion of 0.5-1% parts by weight
Agent.
Further, the composition includes the essence of 0.001-0.05% parts by weight and the increasing of 1.5-7.5% parts by weight
Solvent.
Further, the chelating agent includes four sodium of hydroxy ethylene diphosphonic acid.
Further, the preservative is Phenoxyethanol.
Further, the solubilizer includes Cremophor RH40.
The preparation method of this composition, mainly comprises the steps that
(1) zinc ricinate is configured to aqueous solution under stirring conditions;
(2) lupulus extract is added into the mixed solution of step (1) under stirring conditions, Pelargonium roseum is extracted
Object and north Chinese mugwort extract;Chelating agent is added under agitation, and preservative is then added;
(3) by essence using solubilizer it is pre- solubilising after be added step (2) to mixed solution in and stir;In stirring bar
Under part, be slowly added to chlorocarbon base dimethyl-benzyl amine, and the pH value of pH adjusting agent regulation system is added, after the completion of preparation to get
To a kind of footgear deodorizing antibiotic composition containing zinc ricinate.
Further, the mixing speed is 300-500rpm.
Further, the pH adjusting agent is Citric Acid Mono.
Further, the pH value of the system is 8.0-9.0.
The present invention has the advantages that
1, a kind of footgear deodorizing antibiotic composition containing zinc ricinate provided by the invention includes water solubility in composition
Zinc ricinate deodorant, fatty acid source are based on zinc ricinate and stench chemical substance in natural castor oil, taste removal mechanism
Irreversible chemical bonding reaction occurs, acid type malodors gas can be effectively removed, foot caused by foot sweat, tinea pedis can be decomposed rapidly
It is smelly, shoes are smelly, mitigate footgear peculiar smell make persistently to keep pure and fresh in shoes, can trust and take off to footgear stink deodorizing rate up to 92%
Shoes are carried out.
2, the composition selects natural origin deodorant, plant extracts antibacterial agent, and product safety is nontoxic, environmentally protective;
The pH=8.0-9.0 of system, and not spirituosity, it is nonirritant.
Detailed description of the invention
Fig. 1 is different samples to odor strength scoring figure after footgear deodorization;
Fig. 2 is different samples to deodorizing rate figure after footgear deodorization;
Fig. 3 is that Escherichia coli viable bacteria result for 24 hours is cultivated in 37 DEG C of incubators after 2 sample amounts of the embodiment of the present invention are sterilized
Figure;
Fig. 4 is to cultivate staphylococcus aureus for 24 hours after 2 sample amounts of the embodiment of the present invention are sterilized in 37 DEG C of incubators to live
Bacterium result figure.
Specific embodiment
The present invention will be further described with reference to the accompanying drawings and detailed description, and following embodiment is intended to illustrate hair
Bright rather than limitation of the invention further.
The conventional means that technological means used in following embodiment is well known to those skilled in the art, all raw materials are equal
For versatile material.
A kind of footgear deodorizing antibiotic composition containing zinc ricinate of the present invention, including deodorant, antibacterial agent and water;It is described
Deodorant includes following material: zinc ricinate;The antibacterial agent includes following material: chlorocarbon base dimethyl-benzyl amine, beer
Flower extract, Pelargonium roseum extract and north Chinese mugwort extract.
This composition can be made including gel, liquid (such as liquid detergent), aqueous solution is spraying, waits products.
It is illustrated for aqueous solution is made by spraying in composition.
The weight ratio of the raw material of embodiment 1-3 and comparative example 1-2 is as shown in the table:
The preparation method of footgear deodorizing antibiotic foodcare composition in embodiment 1-3, comprising the following steps:
(1) zinc ricinate is added to the water by precise secondary water in beaker under conditions of revolving speed is 400rpm,
Stir 3min;
(2) lupulus extract, Pelargonium roseum extract and north are sequentially added under conditions of 400rmp revolving speed stirs
Artemisiae argyi extract stirs 3min, and four sodium of chelating agent hydroxy ethylene diphosphonic acid and preservative Phenoxyethanol is then added;
(3) it by the pre- solubilising of essence, is placed in small beaker specifically, weighing essence, addition solubilizer PEG-40 hydrogenation
Castor oil stirs 3min under conditions of the stirring of 400rmp revolving speed;Mixed liquor after solubilising is added to the mixing arrived of step (2)
In solution and stir 10min;
(4) chlorocarbon base dimethyl-benzyl amine, addition are added in batches and slowly under conditions of 400rmp revolving speed stirs
Local over-concentration in the process, solution become cloudy, slightly blue light-emitting, become transparent clarified solution after lasting stirring;Then in stirring ground condition
Solution ph is adjusted to 8.6 by lower addition Citric Acid Mono solid, arrives a kind of footgear containing zinc ricinate after the completion of preparation
Deodorizing antibiotic composition.
Comparative example 1
Unlike embodiment, step is not added with zinc ricinate in (1);Step (2) directly are carried out, in step (4)
Using alkaline pH adjusting agent, step (4) specifically step are as follows:
Triethanolamine is added under conditions of the stirring of 400rmp revolving speed, solution ph is adjusted to 8.6, after the completion of preparation to get
To a kind of footgear deodorizing antibiotic composition containing zinc ricinate.
Comparative example 2
Unlike embodiment, step is not added with zinc ricinate in (1);Step (2) directly are carried out, in step (3)
Essence concentration is improved to 0.2%, uses alkaline pH adjusting agent in step (4), step (4) specifically step are as follows:
Triethanolamine is added under conditions of the stirring of 400rmp revolving speed, solution ph is adjusted to 8.6, after the completion of preparation to get
To a kind of footgear deodorizing antibiotic composition containing zinc ricinate.
It is as follows that deodorization test is carried out for product preparation-obtained in embodiment and comparative example:
Footgear deodorization evaluating in vitro model and deodouring effect verification method are established:
(1) prepare footgear and simulate smelly source: fatty acid mixt aqueous solution each component content is as shown in table 2.
(2) by people from South Pole man's pure cotton socks (brand: people from South Pole, money number: N728X22631-09, fabric material composition:
Cotton 100%) it is cut into 3 × 3cm sliver.
(3) sliver is put into 500mL beaker, accurately weighs 2.5g footgear and simulate smelly source aqueous solution, sufficiently soaks sliver,
Obtain the duplication smelly source of footgear.
(4) different deodorization samples are contained in the plastic mist spray bottle (material: poly terephthalic acid class PET, rule of same size
Lattice: 120mL) in, pressing 8 times (pressing sprays amount of composition about 0.31g every time), deodorization example weight about 2.5g is with spraying shape
Formula acts on entire beaker and has adsorbed footgear and simulates on the experiment cotton in smelly source.Entire external model makes close to consumer is practical
Use scene.
Table 2: footgear simulates smelly source-fatty acid mixt aqueous solution each component
The content and manufacturer's information that above-mentioned footgear simulates raw material in smelly source-fatty acid mixt aqueous solution are as follows:
Acetic acid (AR, content: >=99.5%, manufacturer: Sinopharm Chemical Reagent Co., Ltd., lot number: 20170106);
N-butyric acie (CP, content: >=99.0%, manufacturer: Sinopharm Chemical Reagent Co., Ltd., lot number: 20140929);Isobutyric acid
(CP, content: >=99.5%, manufacturer: Sinopharm Chemical Reagent Co., Ltd., lot number: 20160803);Isovaleric acid (isomery
Body mixture) (content: 99%, manufacturer: Sinopharm Chemical Reagent Co., Ltd., lot number: 20180621).Other commercially available tools
There is the raw material of identical parameters also to can achieve equivalent effect.
Blank control is set by the sliver being not processed, is set as negative control with the sliver of purifying water process, and will
Embodiment 1-3, comparative example 1-2 and existing product are respectively acting on smelly source 1min, 3min, 10min, 30min, 3h and carry out deodorization
Test selectes assessment experts with osmatic according to 6 grades of representations (as shown in table 3) of stench intensity for condition, men and women each 5
People carries out odor strength sensory evaluation;
Deodorizing rate %=(odor strength score value after 5- deodorization)/5*100;
Existing product includes:Except the smelly pure and fresh spraying (Dr. of shoesOdourControlShoeSpray is produced
Ground: Poland), holt pharmacy sport footwear deodorization spraying (KOBAYASHI, the place of production: Japan) and Little Touch footgear degerming remove
Taste is spraying (place of production: China).
Table 3 stench intensity, 6 grades of representations
Sample scores as shown in table 4 to odor strength after footgear deodorization, is drawn to obtain Fig. 1 and Fig. 2 according to data.
Odor strength scores after 4 deodorant of table is sprayed deodorization to footgear
Fig. 1 shows different samples to odor strength scoring figure after footgear deodorization, and every group of histogram from left to right divide by side
It Biao Shi not odor strength scoring after deodorization 1min, 3min, 10min, 30min and 3h;Fig. 2 indicates different samples to footgear
Deodorizing rate figure after deodorization, according to data in figure:
Blank control group footgear simulates smelly source and generates strong smelly foot smell, people can not endure, deodorizing rate 0.
The negative control group handled with the water of equivalent can not eliminate the strong unhappy smell that footgear simulates smelly source, remove
Smelly rate is 0.
Except essence excessive concentration in the smelly pure and fresh spray formula of shoes, evaluator, which feeds back sucking, pierces bronchia mucosal
Swash, it is uncomfortable.There is less malodor after deodorization 1min, 3min, 30min, stench intensity ratings are respectively 1.8,1.4,1.4.Deodorization
Almost without obvious smell after 10min, stench intensity ratings are 0.9.It is easy to feel less malodor, stench intensity ratings after deodorization 3h
Respectively 1.7.It is 71% to deodorizing rate after footgear deodorization.
It can feel that stink, stench intensity ratings are 1.1 after holt pharmacy sport footwear deodorization spraying deodorization 1min reluctantly.
Almost without obvious smell, stench intensity ratings < 1 after deodorization 3min, 10min, 30min, 3h.To deodorizing rate after footgear deodorization
It is 86%.
Little Touch footgear degerming taste removal can feel stink or appearance after being sprayed deodorization 1min, 30min, 3h reluctantly
Susceptible to arrive less malodor, stench intensity ratings are respectively 1.5,1.1 and 1.3.Almost without obvious smell after deodorization 10min is smelly, dislike
Smelly intensity ratings 0.8.It is 76% to deodorizing rate after footgear deodorization.
After comparative example 1 sample deodorization 1min, 3min, 10min, 30min, 3h, hence it is evident that feel stink, stench intensity ratings point
Not Wei 2.9,3.0,2.8,2.7,3.0, to deodorizing rate after footgear deodorization be 42%, the results showed that, 1 deodorizing effect of comparative example
It is very poor, footgear fetor can not be eliminated without zinc ricinate formula.
After comparative example 2 sample deodorization 1min, 3min, 10min, 30min, 3h, hence it is evident that feel stink, stench intensity ratings point
Not Wei 2.0,3.0,2.5,2.7,2.8, to deodorizing rate after footgear deodorization be 48%, the results showed that, 2 deodorizing effect of comparative example
It is poor, zinc ricinate is free of, while being formulated essence concentration and improving from 0.01% to 0.2%, deodorizing effect is still very poor.Essence
Smell can only slightly cover fetor taste, can not thoroughly eliminate footgear stench.
After embodiment 1 sample deodorization 1min, 3min, 10min, 30min, 3h, stink, stench intensity can be felt reluctantly
Scoring is respectively 1.1,0.5,1.2,0.8,1.1, is 81% to deodorizing rate after footgear deodorization, deodorizing effect is substantially better than
Little Touch andCommercial product formula.The result shows that being imitated containing 1% zinc ricinate formula with certain deodorization
Fruit.
After embodiment 2 sample deodorization 1min, 3min, 10min, 30min, 3h, almost without obvious smell or free from extraneous odour, stench
Intensity ratings are respectively 0.7,0.3,0.2,0.4,0.5, are 92% to deodorizing rate after footgear deodorization < 1, deodorizing effect
It is substantially better than other commercial product formula.The result shows that more excellent containing 2.5% zinc ricinate formula deodorizing effect.Improve castor
Sesame oil acid Zn content, deodorizing effect are promoted.
After embodiment 3 sample deodorization 1min, 3min, 10min, 30min, 3h, almost without obvious smell or free from extraneous odour, stench
Intensity ratings are respectively 0.2,0.4,0.5,0.2,0.2, are 94% to deodorizing rate after footgear deodorization < 0.5, deodorization effect
Fruit is substantially better than other commercial product formula.The result shows that excellent containing 5% zinc ricinate formula deodorizing effect.Castor oil
Sour zinc and footgear simulate fatty acid in smelly source and irreversible chemical bonding reaction occur, and can effectively remove acid type malodors gas, improve
Ricinoleic acid Zn content, deodorizing effect are promoted.
The case where 2 sample of the embodiment of the present invention carries out sterilization test, and sample inoculation plate is sterilized is as shown in Figure 3 and Figure 4, figure
After 3 indicate quantitative sterilization, Escherichia coli viable bacteria result for 24 hours is cultivated in 37 DEG C of incubators;After Fig. 4 indicates quantitative sterilization, in temperature
Degree carries out staphylococcus aureus viable bacteria result for culture in 37 DEG C of incubators afterwards for 24 hours.According to China " disinfection technology standard "
(2002 editions), with Escherichia coli (Escherichia coli) 8099, staphylococcus aureus (StapHylococcus
Aureus) ATCC 6538 is that test organisms identifies the Disinfection Effect of 1 sample of embodiment using quantitative bacteric idal experiment, real
Applying 2 sample of example is respectively 100%, 99.9999% to the killing rate of Escherichia coli and staphylococcus aureus effect 20min, is disappeared
It is malicious qualified.
Finally, it should be noted that above embodiments are only to illustrate the present invention and not limit technology described in the invention
Scheme;Those skilled in the art should understand that still can modify to the present invention or equivalent replacement;And all are not
It is detached from the technical solution and its improvement of the spirit and scope of the present invention, should all be covered within the scope of the claims of the present invention.
Claims (10)
1. a kind of footgear deodorizing antibiotic composition containing zinc ricinate, which is characterized in that including deodorant and antibacterial agent;It is described
Deodorant includes following parts by weight material: 1-5% zinc ricinate;The antibacterial agent includes following parts by weight material: 0.1-
0.5% chlorocarbon base dimethyl-benzyl amine, 0.1-5% lupulus extract, 0.1-5% Pelargonium roseum extract and 0.1-5%
North Chinese mugwort extract.
2. composition according to claim 1, which is characterized in that the composition includes the chela of 0.1-0.5% parts by weight
The preservative of mixture and 0.5-1% parts by weight.
3. composition according to claim 2, which is characterized in that the composition includes 0.001-0.05% parts by weight
The solubilizer of essence and 1.5-7.5% parts by weight.
4. composition according to claim 2, which is characterized in that the chelating agent includes hydroxy ethylene diphosphonic acid four
Sodium.
5. composition according to claim 2, which is characterized in that the preservative is Phenoxyethanol.
6. composition according to claim 3, which is characterized in that the solubilizer includes Cremophor RH40.
7. the preparation method of composition as claimed in claim 3, which comprises the following steps:
(1) zinc ricinate is configured to aqueous solution under stirring conditions;
(2) under stirring conditions into the mixed solution of step (1) be added lupulus extract, Pelargonium roseum extract and
North Chinese mugwort extract;Chelating agent is added under agitation, and preservative is then added;
(3) by essence using solubilizer it is pre- solubilising after be added step (2) to mixed solution in and stir;In stirring condition
Under, it is slowly added to chlorocarbon base dimethyl-benzyl amine, and the pH value of pH adjusting agent regulation system is added, is arrived after the completion of preparation
A kind of footgear deodorizing antibiotic composition containing zinc ricinate.
8. preparation method according to claim 7, which is characterized in that the mixing speed is 300-500rpm.
9. preparation method according to claim 7, which is characterized in that the pH adjusting agent is Citric Acid Mono.
10. preparation method according to claim 7, which is characterized in that the pH value of the system is 8.0-9.0.
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