CN109487578A - Thief zone heat sublimation ink and preparation method thereof - Google Patents
Thief zone heat sublimation ink and preparation method thereof Download PDFInfo
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- CN109487578A CN109487578A CN201811470440.8A CN201811470440A CN109487578A CN 109487578 A CN109487578 A CN 109487578A CN 201811470440 A CN201811470440 A CN 201811470440A CN 109487578 A CN109487578 A CN 109487578A
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- Prior art keywords
- lignin
- thief zone
- zone heat
- disperse dyes
- heat sublimation
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- 238000000859 sublimation Methods 0.000 title claims abstract description 64
- 230000008022 sublimation Effects 0.000 title claims abstract description 64
- 238000002360 preparation method Methods 0.000 title claims abstract description 11
- 239000000986 disperse dye Substances 0.000 claims abstract description 42
- 239000000975 dye Substances 0.000 claims abstract description 31
- 239000003960 organic solvent Substances 0.000 claims abstract description 24
- 239000002270 dispersing agent Substances 0.000 claims abstract description 22
- 239000003755 preservative agent Substances 0.000 claims abstract description 18
- 230000002335 preservative effect Effects 0.000 claims abstract description 18
- 239000004094 surface-active agent Substances 0.000 claims abstract description 18
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 18
- 239000008367 deionised water Substances 0.000 claims abstract description 17
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 17
- 239000006185 dispersion Substances 0.000 claims abstract description 10
- 239000007788 liquid Substances 0.000 claims abstract description 7
- 238000000227 grinding Methods 0.000 claims abstract description 4
- 238000005374 membrane filtration Methods 0.000 claims abstract description 4
- 238000003756 stirring Methods 0.000 claims abstract description 4
- 229920005610 lignin Polymers 0.000 claims description 49
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 claims description 24
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical group OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 21
- NECRQCBKTGZNMH-UHFFFAOYSA-N 3,5-dimethylhex-1-yn-3-ol Chemical compound CC(C)CC(C)(O)C#C NECRQCBKTGZNMH-UHFFFAOYSA-N 0.000 claims description 18
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 18
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 15
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 12
- 230000000640 hydroxylating effect Effects 0.000 claims description 12
- -1 sulfonic acid sodium salt Chemical class 0.000 claims description 11
- LLEMOWNGBBNAJR-UHFFFAOYSA-N biphenyl-2-ol Chemical compound OC1=CC=CC=C1C1=CC=CC=C1 LLEMOWNGBBNAJR-UHFFFAOYSA-N 0.000 claims description 10
- 239000000463 material Substances 0.000 claims description 9
- 229920001732 Lignosulfonate Polymers 0.000 claims description 7
- YDEXUEFDPVHGHE-GGMCWBHBSA-L disodium;(2r)-3-(2-hydroxy-3-methoxyphenyl)-2-[2-methoxy-4-(3-sulfonatopropyl)phenoxy]propane-1-sulfonate Chemical group [Na+].[Na+].COC1=CC=CC(C[C@H](CS([O-])(=O)=O)OC=2C(=CC(CCCS([O-])(=O)=O)=CC=2)OC)=C1O YDEXUEFDPVHGHE-GGMCWBHBSA-L 0.000 claims description 7
- 239000000203 mixture Substances 0.000 claims description 7
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims description 7
- 239000008118 PEG 6000 Substances 0.000 claims description 6
- 229920002584 Polyethylene Glycol 6000 Polymers 0.000 claims description 6
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims description 6
- DMSMPAJRVJJAGA-UHFFFAOYSA-N benzo[d]isothiazol-3-one Chemical compound C1=CC=C2C(=O)NSC2=C1 DMSMPAJRVJJAGA-UHFFFAOYSA-N 0.000 claims description 6
- CDQSJQSWAWPGKG-UHFFFAOYSA-N butane-1,1-diol Chemical compound CCCC(O)O CDQSJQSWAWPGKG-UHFFFAOYSA-N 0.000 claims description 6
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 6
- 235000019387 fatty acid methyl ester Nutrition 0.000 claims description 6
- 150000002191 fatty alcohols Chemical class 0.000 claims description 6
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 6
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 6
- 229920000191 poly(N-vinyl pyrrolidone) Polymers 0.000 claims description 6
- 239000001044 red dye Substances 0.000 claims description 6
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 claims description 6
- 239000001043 yellow dye Substances 0.000 claims description 6
- 229910052726 zirconium Inorganic materials 0.000 claims description 6
- 239000002202 Polyethylene glycol Substances 0.000 claims description 5
- 239000001045 blue dye Substances 0.000 claims description 5
- 235000010292 orthophenyl phenol Nutrition 0.000 claims description 5
- 229920001223 polyethylene glycol Polymers 0.000 claims description 5
- 229940051841 polyoxyethylene ether Drugs 0.000 claims description 5
- 229920000056 polyoxyethylene ether Polymers 0.000 claims description 5
- 229920001451 polypropylene glycol Polymers 0.000 claims description 5
- VGKYEIFFSOPYEW-UHFFFAOYSA-N 2-methyl-4-[(4-phenyldiazenylphenyl)diazenyl]phenol Chemical compound Cc1cc(ccc1O)N=Nc1ccc(cc1)N=Nc1ccccc1 VGKYEIFFSOPYEW-UHFFFAOYSA-N 0.000 claims description 4
- 239000003795 chemical substances by application Substances 0.000 claims description 4
- 239000002736 nonionic surfactant Substances 0.000 claims description 4
- 239000002888 zwitterionic surfactant Substances 0.000 claims description 4
- 239000003945 anionic surfactant Substances 0.000 claims description 3
- 239000004576 sand Substances 0.000 claims description 2
- UHOVQNZJYSORNB-UHFFFAOYSA-N monobenzene Natural products C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims 2
- 239000002023 wood Substances 0.000 claims 2
- 241000158728 Meliaceae Species 0.000 claims 1
- 230000003213 activating effect Effects 0.000 claims 1
- 238000005260 corrosion Methods 0.000 claims 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims 1
- 150000003871 sulfonates Chemical class 0.000 claims 1
- 239000000835 fiber Substances 0.000 abstract description 24
- 239000004744 fabric Substances 0.000 abstract description 14
- 238000000034 method Methods 0.000 abstract description 6
- 230000035699 permeability Effects 0.000 abstract description 5
- 230000008569 process Effects 0.000 abstract description 4
- 230000001737 promoting effect Effects 0.000 abstract description 2
- 239000000976 ink Substances 0.000 description 33
- 230000000052 comparative effect Effects 0.000 description 7
- 239000004753 textile Substances 0.000 description 4
- 230000008595 infiltration Effects 0.000 description 3
- 238000001764 infiltration Methods 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 230000000740 bleeding effect Effects 0.000 description 2
- 125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 description 2
- 230000003020 moisturizing effect Effects 0.000 description 2
- AJDUTMFFZHIJEM-UHFFFAOYSA-N n-(9,10-dioxoanthracen-1-yl)-4-[4-[[4-[4-[(9,10-dioxoanthracen-1-yl)carbamoyl]phenyl]phenyl]diazenyl]phenyl]benzamide Chemical compound O=C1C2=CC=CC=C2C(=O)C2=C1C=CC=C2NC(=O)C(C=C1)=CC=C1C(C=C1)=CC=C1N=NC(C=C1)=CC=C1C(C=C1)=CC=C1C(=O)NC1=CC=CC2=C1C(=O)C1=CC=CC=C1C2=O AJDUTMFFZHIJEM-UHFFFAOYSA-N 0.000 description 2
- 229920000728 polyester Polymers 0.000 description 2
- 230000008961 swelling Effects 0.000 description 2
- 230000007306 turnover Effects 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 229920002334 Spandex Polymers 0.000 description 1
- 229920004933 Terylene® Polymers 0.000 description 1
- QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical compound C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 description 1
- 235000010358 acesulfame potassium Nutrition 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000002421 anti-septic effect Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 230000009477 glass transition Effects 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 230000003204 osmotic effect Effects 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 230000007928 solubilization Effects 0.000 description 1
- 238000005063 solubilization Methods 0.000 description 1
- 239000004759 spandex Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/16—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using dispersed, e.g. acetate, dyestuffs
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/46—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing natural macromolecular substances or derivatives thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/64—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
- D06P1/651—Compounds without nitrogen
- D06P1/65106—Oxygen-containing compounds
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/003—Transfer printing
- D06P5/004—Transfer printing using subliming dyes
- D06P5/006—Transfer printing using subliming dyes using specified dyes
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Dispersion Chemistry (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
- Coloring (AREA)
Abstract
The invention discloses a kind of Thief zone heat sublimation ink and preparation method thereof, technical problems to be solved are the permeabilities improved after transfer.Thief zone heat sublimation ink of the invention is made of following mass percent component: sublimation dye 20~40%, dispersing agent 1~10%, organic solvent 20~35%, deionized water 30~45%, surfactant 0.5~2%, preservative 0.05~0.2%, disperse dyes carrier 0.3~1.5%.For preparation method the following steps are included: by after sublimation dye and dispersant, grinding distribution obtains dispersion liquid；Addition organic solvent, deionized water, surfactant, preservative, disperse dyes carrier, stirring, membrane filtration obtain Thief zone heat sublimation ink.The present invention is compared with prior art, disperse dyes carrier is added, so that disperse dyes molecule easily enters fibrous inside in the disperse dyes for selecting molecular weight relatively low, it is easier to spread in the fiber molecule of fabric and combine with the fiber of fabric in transfer process, the permeability after promoting transfer.
Description
Technical field
The present invention relates to a kind of textile printing ink and preparation method thereof, especially a kind of heat sublimation ink and its system
Preparation Method.
Background technique
The textile printing of the prior art mainly uses heat sublimation ink-jet ink, is by the way that pattern is printed upon heat-transferring printing paper
Zhang Shang is then transferred to above textile fabric, has the advantages that bright-colored after simple process, environmental protection, transfer, while also being deposited
Having infiltration, not enough generation shows money or valuables one carries unintentionally, turns over the bigger defect of yarn, positive and negative color difference.For some high-end textiles, the heat of the prior art
Osmotic effect after distillation ink-jet ink transfer can not solve the problems, such as it is common show money or valuables one carries unintentionally, to turn over yarn, positive and negative color difference bigger, cannot
Meet the requirement of client.
Summary of the invention
The object of the present invention is to provide a kind of Thief zone heat sublimation inks and preparation method thereof, and technical problems to be solved are
Permeability after improving transfer.
The invention adopts the following technical scheme: a kind of Thief zone heat sublimation ink, is made of following mass percent component:
Sublimation dye 20~40%, dispersing agent 1~10%, organic solvent 20~35%, deionized water 30~45%, surfactant
0.5~2%, preservative 0.05~0.2%, disperse dyes carrier 0.3~1.5%.
Mass percent sublimation dye 25~40% of the invention, organic solvent 25~35%, deionized water 35~40%.
Mass percent deionized water 37.6~38.9% of the invention.
Sublimation dye molecular weight of the invention is less than 300.
The dispersed blue dye number of composition cyan of the invention is 14 and/or 359, forms the dispersion of magenta ink
Red dye number be formed in 4 and/or 15 yellow ink disperse yellow dye number be 4 and/or 13.
Dispersing agent of the invention use with the lignin of hydrophilic radical, hydroxylating lignin, lignin sulfonic acid sodium salt or
Lignosulfonates；The hydroxylating lignin is phenolic group lignin, hydroxyl lignin or carboxyl lignin；The sulfomethylated lignin
Acid sodium-salt is NP-6, NP-10, TX-4 or TX-10；The lignosulfonates are sodium lignin sulfonate；
Organic solvent of the invention is ethylene glycol, polyethylene glycol, diethylene glycol (DEG), butanediol, triethylene glycol, propylene glycol, poly- the third two
One or more of alcohol, glycerol, PEG2000 and PEG6000；The surfactant using nonionic surfactant, yin from
APEO, Surfynol 440, Surfynol 420, Surfynol in sub- surfactant and zwitterionic surfactant
465, fatty acid methyl ester ethoxylate sulfonate FMES, peregal, alkylphenol-polyethenoxy base ether OP-10 and fatty alcohol polyoxy
Any one of vinethene AEO or two kinds；The preservative uses Proxel GXL.
Disperse dyes carrier of the invention is received using o-phenyl phenol.
Sublimation dye of the invention, dispersing agent, organic solvent, surfactant, preservative, disperse dyes carrier industry
Pure raw material.
A kind of preparation method of Thief zone heat sublimation ink, comprising the following steps:
One, it after at room temperature, by mass percentage, sublimation dye 20~40% and dispersing agent 1~10% are mixed, is being sanded
The zirconium pearl of 0.25~0.35mm of diameter is used in machine, the volume ratio of the sum of sublimation dye and dispersing agent and zirconium pearl is 1:6, revolving speed
2200~2800r/min, grinding distribution for 24 hours, obtain dispersion liquid；
Two, dispersion liquid is put into reaction kettle, organic solvent 20~35%, deionized water 30~45% is added, surface is lived
Property agent 0.5~2%, preservative 0.05~0.2%, disperse dyes carrier 0.3~1.5%, 600~800r/min of revolving speed, stirring
After 60min, with 0.22u membrane filtration, heat sublimation ink is obtained；
For the sublimation dye molecular weight less than 300, the dispersed blue dye number for forming cyan is 14 and/or 359；Institute
The dispersive red dye number for stating composition magenta ink is in 4 and/or 15；The disperse yellow dye number of the composition yellow ink
It is 4 and/or 13；
The dispersing agent uses lignin, hydroxylating lignin, lignin sulfonic acid sodium salt or wooden with hydrophilic radical
Plain sulfonate；The hydroxylating lignin is phenolic group lignin, hydroxyl lignin or carboxyl lignin；The sodium lignin sulfonate
Salt is NP-6, NP-10, TX-4 or TX-10；The lignosulfonates are sodium lignin sulfonate；
The organic solvent is ethylene glycol, polyethylene glycol, diethylene glycol (DEG), butanediol, triethylene glycol, propylene glycol, polypropylene glycol, sweet
One or more of oil, PEG2000 and PEG6000；
The surfactant uses APEO, Surfynol 440, Surfynol 420, Surfynol 465, fatty acid
Methyl ester ethoxylates sulfonate FMES, peregal, alkylphenol-polyethenoxy base ether OP-10 and fatty alcohol polyoxyethylene ether AEO
Any one of or two kinds；
The preservative uses Proxel GXL；
The disperse dyes carrier is received using o-phenyl phenol.
Compared with prior art, the present invention the disperse dyes that Thief zone heat sublimation ink selects molecular weight relatively low, are added
Disperse dyes carrier is easier the fiber point in fabric so that disperse dyes molecule easily enters fibrous inside in transfer process
It spreads in son and is combined with the fiber of fabric, disperse dyes carrier can be adsorbed to fiber surface quickly, and constantly spread
To fibrous inside, plays the role of swelling fiber and carry disperse dyes, improve the diffusivity of disperse dyes molecule, promote dispersion dye
Material promotes the permeability after transferring in conjunction with fiber, solves after heat sublimation ink-jet ink transfers and shows money or valuables one carries unintentionally, turns over yarn, positive and negative color difference
Bigger problem.
Specific embodiment
Below with reference to embodiment, invention is further described in detail.
Thief zone heat sublimation ink of the invention is made of following mass percent component: sublimation dye 20~40%, point
Powder 1~10%, organic solvent 20~35%, deionized water 30~45%, surfactant 0.5~2%, preservative 0.05~
0.2%, disperse dyes carrier 0.3~1.5%.
It is preferred that are as follows: sublimation dye 25~40%, organic solvent 25~35%, deionized water 35~40%.
Further preferably are as follows: deionized water 37.6~38.9%.
Sublimation dye uses low molecular weight disperse dyes of the molecular weight less than 300, forms the dispersed blue dye of cyan
Number is 14 and/or 359.The dispersive red dye number for forming magenta ink is in 4 and/or 15.Form point of yellow ink
Dissipating yellow dye number is 4 and/or 13.
Dispersing agent uses lignin, hydroxylating lignin, lignin sulfonic acid sodium salt or sulfomethylated lignin with hydrophilic radical
Hydrochlorate.Hydroxylating lignin is phenolic group lignin, hydroxyl lignin or carboxyl lignin.Lignin sulfonic acid sodium salt is NP-6, NP-
10, TX-4 or TX-10.Lignosulfonates are sodium lignin sulfonate.
Organic solvent be ethylene glycol, polyethylene glycol, diethylene glycol (DEG), butanediol, triethylene glycol, propylene glycol, polypropylene glycol, glycerol,
One or more of PEG2000 and PEG6000.
Surfactant is using in nonionic surfactant, anionic surfactant and zwitterionic surfactant
It is any one or two kinds of.Such as: APEO, Surfynol 440, Surfynol 420, Surfynol 465, fatty acid methyl ester ethoxy
Glycolylate sulfonate FMES, peregal, any in alkylphenol-polyethenoxy base ether OP-10 and fatty alcohol polyoxyethylene ether AEO
Kind or two kinds.
Preservative uses Proxel GXL.
Disperse dyes carrier is received using o-phenyl phenol.
Sublimation dye, dispersing agent, organic solvent, surfactant, preservative, disperse dyes carrier industrial pure material.
The preparation method of Thief zone heat sublimation ink of the invention, comprising the following steps:
One, under room temperature (20 DEG C), by mass percentage, after sublimation dye 20~40% and dispersing agent 1~10% are mixed,
The zirconium pearl of 0.25~0.35mm of diameter is used in sand mill, the volume ratio of the sum of sublimation dye and dispersing agent and zirconium pearl is 1:6,
2200~2800r/min of revolving speed, grinding distribution for 24 hours, obtain dispersion liquid.
Two, dispersion liquid is put into reaction kettle, organic solvent 20~35%, deionized water 30~45% is added, surface is lived
Property agent 0.5~2%, preservative 0.05~0.2%, disperse dyes carrier 0.3~1.5%, 600~800r/min of revolving speed, stirring
After 60min, with 0.22u membrane filtration, Thief zone heat sublimation ink is obtained.
It is preferred that are as follows: sublimation dye 25~40%, organic solvent 25~35%, deionized water 35~40%.
Further preferably are as follows: water 37.6~38.9%.
Sublimation dye uses low molecular weight disperse dyes of the molecular weight less than 300, forms the dispersed blue dye of cyan
Number is 14 and/or 359.The dispersive red dye number for forming magenta ink is in 4 and/or 15.Form point of yellow ink
Dissipating yellow dye number is 4 and/or 13.
Dispersing agent uses lignin, hydroxylating lignin, lignin sulfonic acid sodium salt or sulfomethylated lignin with hydrophilic radical
Hydrochlorate.Hydroxylating lignin is phenolic group lignin, hydroxyl lignin or carboxyl lignin.Lignin sulfonic acid sodium salt is NP-6, NP-
10, TX-4 or TX-10.Lignosulfonates are sodium lignin sulfonate.
Organic solvent be ethylene glycol, polyethylene glycol, diethylene glycol (DEG), butanediol, triethylene glycol, propylene glycol, polypropylene glycol, glycerol,
One or more of PEG2000 and PEG6000.
Surfactant is using in nonionic surfactant, anionic surfactant and zwitterionic surfactant
It is any one or two kinds of.Such as: APEO, Surfynol 440, Surfynol 420, Surfynol 465, fatty acid methyl ester ethoxy
Glycolylate sulfonate FMES, peregal, any in alkylphenol-polyethenoxy base ether OP-10 and fatty alcohol polyoxyethylene ether AEO
Kind or two kinds.
Preservative uses Proxel GXL.
Disperse dyes carrier is received using o-phenyl phenol.
Sublimation dye, dispersing agent, organic solvent, surfactant, preservative, disperse dyes carrier industrial pure material.
The component of Examples 1 to 3 and the technological parameter of preparation method are shown in Table 1.
The Thief zone heat sublimation ink for the Examples 1 to 3 that the method for the present invention is prepared is sprayed using Epson F7080 type
Black printer prints 100% solid block of color on 45 grams of heat-transferring printing papers of Zhanjiang Guan Hao Paper Co., Ltd, setting of printing: precision
540dpi*720dpi, 3PASS are then transferred to above the suede of chemical fiber plus material Milan, fabric ingredient: 95% terylene and 5% spandex,
Grammes per square metre: 166g/ ㎡, 210 DEG C of transfer temperature, transfer time 30 seconds.It is divided after transfer with U.S. Ai Seli-EXACT type hand-held
Photometer tests the color density OD value of fabric back, and test result is shown in Table 2, and infiltration is more, and fabric back color is more bright-coloured, color
Density is higher.
Comparative example 1 is used using the red thermal transfer ink (Lan Yu M) of Zhejiang Lan Yu numeral science and technology limited liability company
Heat-transferring printing paper identical with Examples 1 to 3 and chemical fiber plus material Milan suede, identical printing and transfer parameter, printing, are surveyed at transfer
Examination, test result are shown in Table 2.
Comparative example 2, using the blue heat sublimation ink (ink of six generation of Epson head of Shenzhen Inkbank Digital Consumable Co., Ltd.
Library C), using heat-transferring printing paper identical with Examples 1 to 3 and chemical fiber plus material Milan suede, identical printing and transfer parameter are beaten
Print, transfer, test, test result are shown in Table 2.
From the comparison of table 2 as can be seen that fabric back color density is high compared to comparative example 1~2 after Examples 1 to 3 transfer, transfer
Infiltration color effect is more preferable afterwards.After illustrating that Thief zone heat sublimation ink of the invention is printed upon and is transferred to fabric on heat-transferring printing paper,
Fabric back color is more bright-coloured, and color bleeding effect is more preferable.
The component and technological parameter of 1 Examples 1 to 3 of table
Fabric back color density after heat sublimation ink and comparative example the 1-2 transfer of 2 embodiment 1-3 of table
| Embodiment and comparative example | Embodiment 1 | Embodiment 2 | Embodiment 3 | Comparative example 1 | Comparative example 2 |
| Color density OD value | 1.35 | 1.42 | 1.20 | 0.85 | 0.78 |
The present invention disperse dyes relatively low by selection molecular weight, and dispersion dye is added in Thief zone heat sublimation ink
Expect carrier.
Disperse dyes self-molecules present amount is lower, and diffusion and and face in the fiber molecule of fabric are easier in transfer process
The fiber of material combines.Gravitation between reaction force attenuation between disperse dyes carrier molecule and fiber fiber molecule, makes fibre
The glass transition temperature of dimension reduces, and causes polyester fiber to be plasticized extruding, fiber gap increases, so that disperse dyes molecule easily enters fibre
Dimension is internal.
Disperse dyes carrier has biggish affinity to polyester fabric fiber, fiber surface can be adsorbed to quickly, in fibre
Dimension table face forms a carrier layer, and is constantly diffused into fibrous inside, plays the role of swelling fiber and carries disperse dyes, improves
The diffusivity of disperse dyes molecule promotes disperse dyes in conjunction with fiber, the permeability after promoting transfer, meanwhile, and due to dividing
Dissipating dye carrier has solubilization to disperse dyes, improves the diffusivity of disperse dyes molecule, promotes disperse dyes and fiber
In conjunction with color bleeding effect after increase transfer, to show money or valuables one carries unintentionally after solving the transfer of heat sublimation ink-jet ink, turn over yarn, positive and negative color difference
Bigger problem.
For sublimation dye, dispersing agent, organic solvent, deionized water, surfactant, preservative, disperse dyes carrier
Value range, the content of sublimation dye represents the color of Thief zone heat sublimation ink, and dispersant, surfactant contain
Amount, antiseptic content, disperse dyes vector contg range allow for Thief zone heat sublimation ink stability, the material adds
More have an impact to formulation stability, and the content of organic solvent and deionized water allows for spray head itself to Thief zone heat sublimation
Requirement and the moisturizing requirement of ink viscosity, value range of the invention can not only guarantee there is preferable stability, can also expire
Requirement of the foot to printing head moisturizing.
Claims (10)
1. a kind of Thief zone heat sublimation ink, it is characterised in that: the Thief zone heat sublimation ink, by following mass percent group
Part composition: sublimation dye 20~40%, dispersing agent 1~10%, organic solvent 20~35%, deionized water 30~45%, surface
Activating agent 0.5~2%, preservative 0.05~0.2%, disperse dyes carrier 0.3~1.5%.
2. Thief zone heat sublimation ink according to claim 1, it is characterised in that: the mass percent sublimation dye 25
~40%, organic solvent 25~35%, deionized water 35~40%.
3. Thief zone heat sublimation ink according to claim 2, it is characterised in that: the mass percent deionized water
37.6~38.9%.
4. Thief zone heat sublimation ink according to claim 1,2 or 3, it is characterised in that: the sublimation dye molecular weight
Less than 300.
5. Thief zone heat sublimation ink according to claim 4, it is characterised in that: the disperse blue of the composition cyan
Dyestuff number is 14 and/or 359, and the dispersive red dye number for forming magenta ink is to form yellow ink in 4 and/or 15
Disperse yellow dye number be 4 and/or 13.
6. Thief zone heat sublimation ink according to claim 5, it is characterised in that: the dispersing agent, which uses, has hydrophilic group
Lignin, hydroxylating lignin, lignin sulfonic acid sodium salt or the lignosulfonates of group；The hydroxylating lignin is phenolic group wood
Quality, hydroxyl lignin or carboxyl lignin；The lignin sulfonic acid sodium salt is NP-6, NP-10, TX-4 or TX-10；The wood
Mahogany sulfonate is sodium lignin sulfonate.
7. Thief zone heat sublimation ink according to claim 5, it is characterised in that: the organic solvent is ethylene glycol, gathers
One of ethylene glycol, diethylene glycol (DEG), butanediol, triethylene glycol, propylene glycol, polypropylene glycol, glycerol, PEG2000 and PEG6000 with
On；The surfactant is using in nonionic surfactant, anionic surfactant and zwitterionic surfactant
APEO, Surfynol 440, Surfynol 420, Surfynol 465, fatty acid methyl ester ethoxylate sulfonate FMES,
Any one of peregal, alkylphenol-polyethenoxy base ether OP-10 and fatty alcohol polyoxyethylene ether AEO or two kinds；The anti-corrosion
Agent uses Proxel GXL.
8. Thief zone heat sublimation ink according to claim 5, it is characterised in that: the disperse dyes carrier is using adjacent benzene
Ji Benfenna.
9. Thief zone heat sublimation ink according to claim 5, it is characterised in that: the sublimation dye, dispersing agent, organic
Solvent, surfactant, preservative, disperse dyes carrier industrial pure material.
10. a kind of preparation method of Thief zone heat sublimation ink, comprising the following steps:
One, after at room temperature, by mass percentage, sublimation dye 20~40% and dispersing agent 1~10% are mixed, in sand mill
Using the zirconium pearl of 0.25~0.35mm of diameter, the volume ratio of the sum of sublimation dye and dispersing agent and zirconium pearl is 1:6, revolving speed 2200~
2800r/min, grinding distribution for 24 hours, obtain dispersion liquid；
Two, dispersion liquid is put into reaction kettle, organic solvent 20~35%, deionized water 30~45%, surfactant is added
0.5~2%, preservative 0.05~0.2%, disperse dyes carrier 0.3~1.5%, 600~800r/min of revolving speed, stirring 60min
Afterwards, with 0.22u membrane filtration, Thief zone heat sublimation ink is obtained；
For the sublimation dye molecular weight less than 300, the dispersed blue dye number for forming cyan is 14 and/or 359；Described group
It is in 4 and/or 15 at the dispersive red dye number of magenta ink；The disperse yellow dye number of the composition yellow ink is 4
And/or 13；
The dispersing agent uses lignin, hydroxylating lignin, lignin sulfonic acid sodium salt or sulfomethylated lignin with hydrophilic radical
Hydrochlorate；The hydroxylating lignin is phenolic group lignin, hydroxyl lignin or carboxyl lignin；The lignin sulfonic acid sodium salt is
NP-6, NP-10, TX-4 or TX-10；The lignosulfonates are sodium lignin sulfonate；
The organic solvent be ethylene glycol, polyethylene glycol, diethylene glycol (DEG), butanediol, triethylene glycol, propylene glycol, polypropylene glycol, glycerol,
One or more of PEG2000 and PEG6000；
The surfactant uses APEO, Surfynol 440, Surfynol 420, Surfynol 465, fatty acid methyl ester
Ethoxylate sulfonates FMES, peregal, in alkylphenol-polyethenoxy base ether OP-10 and fatty alcohol polyoxyethylene ether AEO
It is any one or two kinds of；
The preservative uses Proxel GXL；
The disperse dyes carrier is received using o-phenyl phenol.
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