CN109486303B - Washable self-luminous road sign coating composition and preparation method thereof - Google Patents
Washable self-luminous road sign coating composition and preparation method thereof Download PDFInfo
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D129/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal, or ketal radical; Coating compositions based on hydrolysed polymers of esters of unsaturated alcohols with saturated carboxylic acids; Coating compositions based on derivatives of such polymers
- C09D129/02—Homopolymers or copolymers of unsaturated alcohols
- C09D129/04—Polyvinyl alcohol; Partially hydrolysed homopolymers or copolymers of esters of unsaturated alcohols with saturated carboxylic acids
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/22—Luminous paints
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/20—Diluents or solvents
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/70—Additives characterised by shape, e.g. fibres, flakes or microspheres
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/221—Oxides; Hydroxides of metals of rare earth metal
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/221—Oxides; Hydroxides of metals of rare earth metal
- C08K2003/2213—Oxides; Hydroxides of metals of rare earth metal of cerium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2227—Oxides; Hydroxides of metals of aluminium
Abstract
The invention discloses a washable self-luminous road sign coating composition and a preparation method thereof. The invention has the following beneficial effects: compared with the traditional road sign coating, the self-luminous road sign coating is prepared by taking the water-soluble PVA resin as the matrix resin, the distilled water as the solvent and the rare earth luminescent material as well, can be directly washed and removed by water under a certain temperature condition, and solves the problems that the traditional road sign coating is difficult to remove and change and the like. The raw materials have wide sources and are environment-friendly, the operation process is simple, no toxic or harmful pollution is generated in the production process, and meanwhile, the materials can be recycled.
Description
Technical Field
The invention relates to a washable self-luminous road sign coating composition and a preparation method thereof, belonging to the technical field of novel environment-friendly road sign coatings.
Background
In recent years, with the increasing living standard of residents, automobiles become consumer goods for people to enter people, and the pavement marking lines are used as a part of road security facilities and mainly used for providing a visual guide mechanism for drivers, so that busy traffic can go on the road respectively, and the pavement marking lines are an important component part of road traffic safety and ensure that vehicles can run fast and safely.
The traditional pavement marking paint mainly takes a hot-melt pavement marking paint as a main component, and achieves the purpose of luminescence by adding reflective beads, and Chinese patent document CN106634310A discloses an environment-friendly water-based pavement marking paint and a preparation method thereof, wherein the paint consists of A, B two components, wherein the component A comprises 10-35% of epoxy modified acrylic emulsion in percentage by weight; 5-25% of fluorine-silicon emulsion; 0.1-0.5% of wetting agent; 0.1-0.5% of a dispersant; 0.1-0.5% of defoaming agent; 5-15% of pigment; 35-55% of a filler; 5-10% of cosolvent; film-forming auxiliary agent: 0 to 5 percent; 0-5% of an antifreezing agent; 0.05-0.5% of rheological additive; the balance of water; the component B is a water-based epoxy curing agent, and the road sign coating has excellent wear resistance, weather resistance, stain resistance and adhesive force, has excellent binding capacity with a cement road surface, and can not cause the corrosion and peeling of a paint film due to alkali resistance of the cement road surface. Chinese patent document CN104250489A discloses a weather-resistant reflective road sign coating, and Chinese patent document CN104250489A discloses a weather-resistant reflective road sign coating, but the traditional road sign coating is difficult to remove after being coated, and needs to be removed by adopting professional coating removing equipment, thereby wasting time and labor, and having great influence on the need of road modification or traffic route change.
Disclosure of Invention
The invention aims to overcome the problems of self-luminescence and subsequent removal of the traditional road sign coating, provides a washable self-luminescence road sign coating composition and a preparation method thereof, and provides an environment-friendly, quick and reliable solution for the problems.
The invention is realized by the following technical scheme:
the invention provides a washable self-luminous road sign coating composition which comprises the following components in parts by weight:
preferably, the polymerization degree of the PVA resin is 1600-1800, and the alcoholysis degree is 98-100%.
When the polymerization degree of the PVA resin is less than 1600, the material is easy to hydrolyze or swell at a lower temperature, which affects the bonding strength between the coating and the road surface, and when the polymerization degree of the PVA resin is more than 1800, the viscosity of the aqueous solution of the material is too high, which is not beneficial to the actual production.
Preferably, the alumina is in the shape of a sheet, has a particle diameter of 0.5 to 1.5 μm, and has a ratio of diameter to thickness of 3 to 8.
The aluminum oxide composite material is characterized in that the flaky alumina with the particle size of 0.5-1.5 mu m and the diameter-thickness ratio of 3-8 is used as a reinforcing material, the reinforcing effect is achieved by utilizing the 'sliding' characteristic between flaky alumina flake structures, and the reinforcing effect is not better than that of flaky alumina when spherical alumina or cubic alumina is used.
Preferably, the hydrophobic agent is a modified paraffin emulsion type hydrophobic agent.
Preferably, the rare earth luminescent material is at least one of cerium oxide, europium oxide and dysprosium oxide.
Preferably, the defoaming agent is at least one of water-soluble silicones and organic fluorides.
Preferably, the leveling agent is an alkyl modified organosiloxane leveling agent and/or a polyether modified organosiloxane leveling agent.
Preferably, the ultraviolet absorbent is one or two of 2-hydroxy-4-n-octoxybenzophenone and 2- (2' -hydroxy-3 ', 5' -di-tert-phenyl) -5-chlorinated benzotriazole.
Preferably, the antibacterial agent is one or two of a silver ion antibacterial agent and a quaternary ammonium salt antibacterial agent.
A method of preparing a washable self-luminous road marking coating composition as described above, comprising the steps of:
adding distilled water into a reaction kettle, heating to 90-100 ℃, starting a stirrer to stir, adding PVA resin, sequentially adding aluminum oxide, a hydrophobing agent, a rare earth luminescent material, a defoaming agent, a leveling agent, an ultraviolet absorbent and an antibacterial agent after the PVA resin is completely dissolved, uniformly stirring for 1-2 hours, standing, and discharging to obtain the washable self-luminous road sign coating composition.
Compared with the prior art, the invention has the following beneficial effects:
1. compared with the traditional road sign coating, the self-luminous road sign coating is prepared by taking the water-soluble PVA resin as the matrix resin, the distilled water as the solvent and the rare earth luminescent material as well, can be directly washed and removed by water under a certain temperature condition, and solves the problems that the traditional road sign coating is difficult to remove and change and the like.
2. The coating adopts water-soluble PVA resin as matrix resin, has certain hydrophilicity, is easy to swell due to long-time contact with moisture so as to be separated from a road surface, adopts a modified paraffin emulsion type hydrophobing agent as a coating hydrophobing agent, forms a hydrophobic layer on the surface of the coating, prevents the coating from being contacted with the moisture for a long time, prolongs the service life of the coating, and can be dissolved by self-heating melting under the hot water flushing condition so as to realize that the road marking coating can be flushed;
3. the rare earth luminescent material and the flaky alumina are added, so that the self-luminous time of the road marking paint is improved, and the wear resistance of the road marking paint is greatly improved.
4. The raw materials have wide sources and are environment-friendly, the operation process is simple, no toxic or harmful pollution is generated in the production process, and meanwhile, the materials can be recycled.
Drawings
Other features, objects and advantages of the invention will become more apparent upon reading of the detailed description of non-limiting embodiments with reference to the following drawings:
FIG. 1 is a graph showing the influence of the appearance of a non-washable self-luminous road marking paint of comparative example 1 on the surface of a road surface coated with the washable self-luminous road marking paint prepared in example 1 of the present invention washed with hot water at 90-100 ℃.
Detailed Description
The present invention will be described in detail with reference to specific examples. The following examples will assist those skilled in the art in further understanding the invention, but are not intended to limit the invention in any way. It should be noted that variations and modifications can be made by persons skilled in the art without departing from the spirit of the invention. All falling within the scope of the present invention.
The PVA resin types used in the embodiment of the invention are as follows: PVA 17-99 (L) selected from Anhui Uigai materials Co., Ltd, Anhui province;
the alumina used in the embodiment of the invention is flaky alumina with the grain diameter of 0.5-1.5 mu m and the aspect ratio of 3-8, and is selected from Shanghai crystal sharpening chemical company Limited, the type: JR-0845P;
the modified paraffin emulsion type hydrophobizing agent used in the embodiment of the invention is selected from the German keim-additec, model number: e-360;
rare earth cerium oxide (CeO) for use in examples of the present invention2) Europium oxide (Eu)2O3) Dysprosium oxide (Dy)2O3) The rare earth luminescent material is a commercial product;
the defoamer water-soluble organic silicon and organic fluorine defoamer used in the embodiment of the invention is Germany BYK-028 and Guangdong Nanhui New Material Co., Ltd, CI-1094;
the alkyl modified organosiloxane leveling agent used in the embodiment of the invention is TR-9323, a chemical company Limited in Senoll, Changzhou, and the polyether modified organosiloxane leveling agent is AKN-1131, a chemical company Limited in Qianzhiwan, a mountain.
The 2-hydroxy-4-n-octoxybenzophenone and the 2- (2' -hydroxy-3 ', 5' -di-tert-phenyl) -5-chlorinated benzotriazole ultraviolet absorbers used in the examples of the present invention are commercially available as UV-531 and UVP-327, respectively.
The silver ion antibacterial agent used in the embodiment of the invention is selected from ws-L05 of Wan New materials Co., Ltd, Guangzhou city, and the quaternary ammonium salt antibacterial agent is selected from DR-2141 of centurie macrographic chemical engineering science and technology Co., Ltd, Dongguan city.
Example 1
The embodiment relates to a washable self-luminous road sign coating which is prepared from the following raw materials in parts by weight:
example 2
The embodiment relates to a washable self-luminous road sign coating which is prepared from the following raw materials in parts by weight:
example 3
The embodiment relates to a washable self-luminous road sign coating which is prepared from the following raw materials in parts by weight:
example 4
The embodiment relates to a washable self-luminous road sign coating which is prepared from the following raw materials in parts by weight:
example 5
The embodiment relates to a preparation method of a washable self-luminous road sign coating, which comprises the following specific steps:
adding distilled water into a reaction kettle, heating to 90-100 ℃, starting a stirrer to stir, respectively adding PVA resin, and sequentially adding alumina, a hydrophobizing agent, a rare earth luminescent material, a defoaming agent, a surfactant,
And uniformly stirring the flatting agent, the ultraviolet absorbent and the antibacterial agent for 1-2 h, standing, and discharging to obtain the washable self-luminous road sign coating.
Comparative example 1
The comparative example relates to a non-washable self-luminous road sign coating, which is prepared from the following raw materials in parts by weight:
comparative example 2
The comparative example relates to a non-washable self-luminous road sign coating, which is prepared from the following raw materials in parts by weight:
comparative example 3
This comparative example relates to a washable self-luminous traffic marking paint having a formulation and method of preparation substantially the same as example 1 except that no tabular alumina was added.
Comparative example 4
The comparative example relates to a washable self-luminous road sign paint, the formula and the preparation method of which are basically the same as those of example 1, and the difference is only that the luminescent powder adopted in the comparative example is strontium carbonate luminescent powder.
Comparative example 5
This comparative example relates to a washable self-luminous road marking paint having a formulation and method of preparation substantially the same as example 1 except that the alumina used in this comparative example is spherical alumina.
Comparative example 6
This comparative example relates to a washable self-luminous road marking paint having a formulation and method of preparation substantially the same as example 1 except that the alumina used in this comparative example is cubic alumina. .
Performance testing
The performance tests were conducted on examples 1 to 4 and comparative examples 1 to 6, respectively, and the results are shown in Table 1.
TABLE 1 measurement results of Properties
As can be seen from the results of table 1:
(1) examples 1-4 and comparative examples 1-6, the afterglow time of examples 1-4 is significantly better than that of comparative examples 1-6, and the washable self-luminous road sign coating prepared in examples 1-4 can be washed by hot water at 90-100 ℃,
(2) the wear-resisting strength of the composite material is obviously better than that of the composite material of comparative examples 5-6, wherein the composite material of example 1 and comparative examples 5-6 adopts flake alumina as a reinforcing material, and the composite material adopts similar spherical alumina and cubic alumina as the reinforcing material.
(3) Fig. 1 is a graph showing the influence of hot water at 90-100 ℃ on the appearance of a road surface coated with the washable self-luminous road marking paint prepared in example 1 of the present invention and the non-washable self-luminous road marking paint prepared in comparative example 1, in which water-soluble PVA resin is used as a matrix resin, distilled water is used as a solvent, and a rare earth luminescent material is added, so that the washable self-luminous road marking paint can be prepared, and can be washed and removed by direct water under a certain temperature condition, while the road marking paint prepared in comparative example 1 by using a conventional non-water-soluble material is difficult to clean, so that the present invention has an important guiding significance for solving the problems that the conventional road marking paint is difficult to remove and change.
The foregoing description of specific embodiments of the present invention has been presented. It is to be understood that the present invention is not limited to the specific embodiments described above, and that various changes and modifications may be made by one skilled in the art within the scope of the appended claims without departing from the spirit of the invention.
Claims (8)
1. A washable self-luminous road sign coating composition is characterized by comprising the following components in parts by weight:
distilled water: 40-100 parts;
PVA resin: 20-50 parts of a solvent;
alumina: 10-20 parts;
a water repellent agent: 3-10 parts;
rare earth luminescent material: 5-10 parts;
defoaming agent: 0.3-1 part;
leveling agent: 0.5-1.5 parts;
ultraviolet absorber: 0.1-0.5 part;
antibacterial agents: 0.3-0.6 part;
the polymerization degree of the PVA resin is 1600-1800, and the alcoholysis degree is 98-100%; the hydrophobic agent is a modified paraffin emulsion type hydrophobic agent.
2. The washable self-luminous road marking coating composition of claim 1, wherein the aluminum oxide is in the form of flakes having a particle size of 0.5 to 1.5 μm and a aspect ratio of 3 to 8.
3. The flushable self-luminescent road marking coating composition of claim 1 wherein the rare earth luminescent material is at least one of cerium oxide, europium oxide, dysprosium oxide.
4. The washable self-luminous road marking coating composition of claim 1 wherein the defoamer is at least one of water soluble silicones and organofluorine based.
5. The washable self-luminous road marking coating composition of claim 1 wherein the leveling agent is an alkyl modified organosiloxane-based leveling agent and/or a polyether modified organosiloxane-based leveling agent.
6. The flushable self-luminous road marking coating composition of claim 1 wherein the ultraviolet absorber is one or both of 2-hydroxy-4-n-octoxybenzophenone and 2- (2' -hydroxy-3 ', 5' -di-t-phenyl) -5-chlorobenzotriazole.
7. The flushable self-luminous road marking coating composition of claim 1, wherein the antimicrobial agent is one or both of a silver ion-based antimicrobial agent and a quaternary ammonium salt-based antimicrobial agent.
8. A method of preparing a washable self-luminous road marking coating composition as defined in any one of claims 1 to 7, comprising the steps of:
adding distilled water into a reaction kettle, heating to 90-100 ℃, starting a stirrer to stir, adding PVA resin, sequentially adding aluminum oxide, a hydrophobing agent, a rare earth luminescent material, a defoaming agent, a leveling agent, an ultraviolet absorbent and an antibacterial agent after the PVA resin is completely dissolved, uniformly stirring for 1-2 hours, standing, and discharging to obtain the washable self-luminous road sign coating composition.
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Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1253976A (en) * | 1999-06-12 | 2000-05-24 | 徐克信 | Sierozem powder coating material |
| CN101585981A (en) * | 2009-03-27 | 2009-11-25 | 许庆华 | Attapulgite energy storage luminous paint |
| CN101585693A (en) * | 2009-03-27 | 2009-11-25 | 许庆华 | Attapulgite paste energy storage luminous paint |
| CN102239222A (en) * | 2008-10-10 | 2011-11-09 | 3M创新有限公司 | Silica coating for enhanced hydrophilicity |
| CN105038576A (en) * | 2015-07-28 | 2015-11-11 | 南京航空航天大学 | Abrasion resistant epoxy coating and preparation technology thereof |
| CN108003724A (en) * | 2017-12-11 | 2018-05-08 | 山西省交通科学研究院 | A kind of energy-accumulating luminous paint for highway anticollision wall and preparation method thereof |
| CN108003713A (en) * | 2017-12-13 | 2018-05-08 | 苏州拓博琳新材料科技有限公司 | A kind of waterborne road line paint and preparation method thereof and construction method |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US9023443B2 (en) * | 2009-09-25 | 2015-05-05 | Toray Plastics (America), Inc. | Multi-layer high moisture barrier polylactic acid film |
| KR20170048704A (en) * | 2015-10-27 | 2017-05-10 | 박희대 | Coating solution for masking shoes sole |
-
2018
- 2018-11-09 CN CN201811331432.5A patent/CN109486303B/en active Active
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1253976A (en) * | 1999-06-12 | 2000-05-24 | 徐克信 | Sierozem powder coating material |
| CN102239222A (en) * | 2008-10-10 | 2011-11-09 | 3M创新有限公司 | Silica coating for enhanced hydrophilicity |
| CN101585981A (en) * | 2009-03-27 | 2009-11-25 | 许庆华 | Attapulgite energy storage luminous paint |
| CN101585693A (en) * | 2009-03-27 | 2009-11-25 | 许庆华 | Attapulgite paste energy storage luminous paint |
| CN105038576A (en) * | 2015-07-28 | 2015-11-11 | 南京航空航天大学 | Abrasion resistant epoxy coating and preparation technology thereof |
| CN108003724A (en) * | 2017-12-11 | 2018-05-08 | 山西省交通科学研究院 | A kind of energy-accumulating luminous paint for highway anticollision wall and preparation method thereof |
| CN108003713A (en) * | 2017-12-13 | 2018-05-08 | 苏州拓博琳新材料科技有限公司 | A kind of waterborne road line paint and preparation method thereof and construction method |
Non-Patent Citations (1)
| Title |
|---|
| 《Biodegradation of poly (vinyl alcohol) based materials》;Emo Chiellini et.al.;《Progress in Polymer Science》;20030422;第28卷(第6期);第963-1014页 * |
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