CN109482334A - A kind of flotation combined beneficiation method of colour sorting-of mica containing rubidium-feldspar ore - Google Patents

A kind of flotation combined beneficiation method of colour sorting-of mica containing rubidium-feldspar ore Download PDF

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Publication number
CN109482334A
CN109482334A CN201811415765.6A CN201811415765A CN109482334A CN 109482334 A CN109482334 A CN 109482334A CN 201811415765 A CN201811415765 A CN 201811415765A CN 109482334 A CN109482334 A CN 109482334A
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China
Prior art keywords
ore
colour
kinds
sorting
mineral
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CN201811415765.6A
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Chinese (zh)
Inventor
王雷
郑其
车小奎
段锦
赵航
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GRIMN Engineering Technology Research Institute Co Ltd
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GRIMN Engineering Technology Research Institute Co Ltd
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Priority to CN201811415765.6A priority Critical patent/CN109482334A/en
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B03SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03BSEPARATING SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS
    • B03B7/00Combinations of wet processes or apparatus with other processes or apparatus, e.g. for dressing ores or garbage

Abstract

The invention discloses a kind of flotation combined ore-dressing techniques of mica containing rubidium-feldspar ore colour sorting-, comprising the following steps: (1) crushing raw ore, screening preselect two kinds of color ores of the suitable coarse fraction depth;(2) colour sorting: feeding colour sorter for ore obtained in step (1), separates two kinds of color ores of the depth using colour sorter.(3) it according to two kinds of ore valuable element content differences obtained by step (2), is crushed again, ore grinding, flotation sort different valuable elements respectively, obtains two kinds of product concentrate by de slime flotation process integration.The present invention can effectively promote raw ore Beneficiation Feed Grade, carry out pre-separation processing to mineral using physical method.

Description

A kind of flotation combined beneficiation method of colour sorting-of mica containing rubidium-feldspar ore
Technical field
The invention belongs to technical field of beneficiation, in particular to the colour sorting-of a kind of mica containing rubidium-feldspar ore is flotation combined Beneficiation method.
Background technique
Rubidium is a kind of yttrium, since it is with special photoelectric properties, is referred to as the gold of " long eyes " Belong to.Which are mainly applied to the fields such as new and high technology exploitation and electronic device, special glass.It is independent not yet to find that there are rubidiums at present Mineral, and it is often present in mica in the form of isomorphous.Mica in ore often with adapt to the close symbiosis such as feldspar. Because of the easy argillization of mica and feldspar, quartzy harder characteristic, ore grinding is meticulous to will lead to a large amount of mica minerals losses.It is therefore desirable to It is proposed that effective scheme solves the above problems.Through research investigation discovery, the color of mineral containing rubidium and gangue mineral (quartz) have larger area Not, gangue mineral quartz is often the light color such as white, and the dark system such as black can be presented in mica containing rubidium etc., therefore according to colors of mineral Composition can be pre-processed, and select valuable rock part in advance, reduce gangue treating capacity, improve operating efficiency.
Summary of the invention
To overcome the defects of above-mentioned background technique, the present invention is according to the colour-difference of mica containing rubidium and feldspar, quartz mineral It is different, a kind of beneficiation method of environment-friendly high-efficiency is provided.
To achieve the goals above, technical solution of the present invention is specific as follows:
A kind of flotation combined beneficiation method of colour sorting-of mica containing rubidium-feldspar ore, includes the following steps:
Step 1, it is crushed: the ore of extraction being spared to and is crushed to 0-20mm or so into jaw crusher, wherein being greater than 20mm part pass through sieve classification be back to crushing circuit formed it is closed circuit, less than 20mm part enter colour sorter be subsequent point Choosing is prepared.
Step 2, colour sorting: step 1 products obtained therefrom is sent into colour sorter, sorting machine makes according to mineral color difference Two different colors of ore is sub-elected with air cannon.The sorting machine is mainly by feeding system, Systems for optical inspection, signal processing System and separation execution system composition.Mineral are evenly supplied to optical detecting parts by belt feeder, are sorted by computer settings Color gamut;When mineral region after testing, according to range is preset, dark mine will be hit by air cannon and sort out Come, light-colored part is directly entered in next splicing storehouse, realizes two parts separation.
Step 3, it is crushed ore grinding: by useful part in the product of step 2 (dark mine) even feeding into jaw crusher, Broken product carries out sieve classification, wherein the part greater than 2mm is back to and continues to be crushed in crusher, particle size after cracking is made to exist 2mm or less.
Step 4, step 3 gained fragment is fed into ball mill, is milled to -200 mesh contents 70% or so.Production after ore grinding Since wherein mica content is relatively high in product, it is easy to produce argillization phenomenon;After hydrocyclone desliming, into roughing process Operation.
Step 5, use sulfuric acid to be inhibitor and amine as collecting agent as pH regulator, waterglass to sequentially add In flotation cell, dosage distinguishes pH regulator (sulfuric acid) 300-500g/t, inhibitor (waterglass) 50-2000g/ with raw ore meter T, amine collector (20-800g/t);After roughing twice, concentrate enters subsequent fine and is elected to be industry, and tailing is scanned, and scans Appropriate collecting agent is added in part, and dosage halves, and scavenger concentrate returns to roughing operation, and tailing is as true tailings.
Step 6, a small amount of sulfuric acid acidification adjustment pH is added in rougher concentration before carrying out selected operation, and cleaning technological flowasheet is divided into Two sections, selected gained concentrate enters next section of cleaning technological flowasheet for the first time, and tailing is back to roughing.
Step 7, second of selected operation mainly carries out step 6 product selected in the case where being added without any medicament Processing, gained concentrate product is as final concentrate.
Step 8, it scans, tailing addition collecting agent is scanned, closed circuit flow is formed.
Beneficial effects of the present invention, the present invention provide one kind according to the color difference of mica containing rubidium and feldspar, quartz mineral The beneficiation method of environment-friendly high-efficiency can be pre-processed according to colors of mineral composition, be divided using physical method mineral From processing, valuable rock part is selected in advance, promotes raw ore Beneficiation Feed Grade, reduces gangue treating capacity, improves operating efficiency.
Detailed description of the invention
Fig. 1 is the process flow chart of the method for the present invention.
Specific embodiment
The present invention is described in detail with reference to the accompanying drawing, by taking the Mica Mine containing rubidium oxide 0.91% as an example, using such as Process flow of the invention shown in Fig. 1.
The mineral that the present embodiment uses are fairly simple, the mineral main component be mica, feldspar, quartz and it is a small amount of other Mineral.Through analyzing, Rb is averagely contained in the mineral2O 0.91%, wherein melanocratic mineral is higher by about 1.5% or so containing rubidium.
After optimizing engineer testing, on the basis of Best experimental condition, closed-circuit test is carried out according to Fig. 1 technique, Include the following steps:
Step 1, be crushed: ore reduction being less than 20mm or so using jaw crusher, the particle greater than 20mm return after It is continuous broken, 2, which are entered step, less than the part 2mm is further processed.
Step 2, colour sorting: step 1 products obtained therefrom is uniformly sent into colour sorter by belt-conveying, is adjusted COMPUTER PARAMETER, control detection system select wherein melanocratic mineral, make it according to different minerals color difference, will using air cannon Melanocratic mineral therefrom separates, and the melanocratic mineral and leucocratic mineral after choosing respectively enter in two splicing storehouses.
Step 3, melanocratic mineral obtained in step 2 is continued to be crushed using jaw crusher, and carries out sieve classification Processing, wherein the part return greater than 2mm is crushed to process and continues to be crushed to 2mm or less;Part less than 2mm adds water to goal Ball milling operation is carried out in grinding machine.
Step 4, ore grinding, by -2mm product ball mill ore grinding obtained by step 3, it is desirable that product -0.074mm content is 70%, the product after ore grinding enters hydrocyclone and carries out desliming process.
Step 5, flotation: the product after desliming successively carries out roughing twice, once purging selection and selected twice;In terms of raw ore, 460g/t pH regulator, 1600g/t inhibitor, 400g/t and 100g/t amine collector are added when roughing I;Roughing II is added 200g/t and 50g/t amine collector;180g/t inhibitor is added in selected I;It scans I and the collecting of 100g/t and 25g/t amine is added Agent;
The results are shown in Table 1 for the present embodiment closed-circuit test
1 closed-circuit test result of table
Technical solution of the present invention is described in detail in above-described embodiment.It is apparent that the present invention is not limited being retouched The embodiment stated.Based on the embodiments of the present invention, those skilled in the art can also make a variety of variations accordingly, but appoint What is equal with the present invention or similar variation shall fall within the protection scope of the present invention.

Claims (7)

1. a kind of flotation combined beneficiation method of mica containing rubidium-feldspar ore colour sorting-, which comprises the following steps:
Step 1, muck, by crushing raw ore to less than the primary breakup product of 20mm;
Step 2, step 1 products obtained therefrom is uniformly sent into colour sorter, COMPUTER PARAMETER is adjusted, by dark mine by colour sorting Hit with air cannon sort out come;
Step 3, closed circuit crushing is carried out to the melanocratic mineral after sorting, makes particle size after cracking in 2mm or less;
Step 4, step 3 gained fragment is subjected to ore grinding and desliming process;The ore grinding is milled to -200 mesh contents 70%, described Desliming is carried out using hydrocyclone;
Step 5, step 4 gains are added collecting agent and carry out roughing twice by roughing;
Step 6, pH is adjusted, sulfuric acid acidification adjustment pH is added in step 5 gains;
Step 7, selected, step 6 gains are carried out selected twice;
Step 8, it scans, tailing addition collecting agent is scanned, closed circuit flow is formed.
2. method as described in claim 1, which is characterized in that dark and light two kinds of colour systems are substantially presented in raw ore described in step 1, Its valuable element content can be measured by color difference.
3. method as described in claim 1, which is characterized in that be crushed described in muck described in step 1 and step 3 and use jaw Crusher carries out.
4. method as described in claim 1, which is characterized in that colour sorter described in step 2 includes feeding system, optics inspection Examining system, signal processing system and separation execution system.
5. method as described in claim 1, which is characterized in that collecting agent described in step 5 includes pressing raw ore meter, sulfuric acid 300- 500g/t, waterglass 50-2000g/t, amine collector 20-800gt.
6. method as described in claim 1, which is characterized in that selected described in step 7, first time selected addition waterglass 180g/t, it is selected for the second time to be added without any medicament.
7. method as claimed in claim 5, which is characterized in that collecting agent described in step 8 is collector dosage described in step 4 Half.
CN201811415765.6A 2018-11-26 2018-11-26 A kind of flotation combined beneficiation method of colour sorting-of mica containing rubidium-feldspar ore Pending CN109482334A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110369164A (en) * 2019-07-31 2019-10-25 湖南柿竹园有色金属有限责任公司 A kind of beneficiation method of the preenrichment of rubidium
CN112958276A (en) * 2021-03-18 2021-06-15 广东省科学院资源综合利用研究所 Treatment method for solid waste of sapphire processing laponite
CN114798157A (en) * 2022-04-29 2022-07-29 有研资源环境技术研究院(北京)有限公司 Method for recovering pollucite from pegmatite type tailings

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CN104475339A (en) * 2014-12-11 2015-04-01 江西一元再生资源有限公司 Method for comprehensively recovering lead, zinc, lithium, niobium and rubidium from tailings
CN104805311A (en) * 2015-03-24 2015-07-29 中国地质科学院矿产综合利用研究所 Method for extracting rubidium from rubidium-containing feldspar and co-producing silicon fertilizer
CN105209645A (en) * 2013-03-05 2015-12-30 卡博特公司 Methods to recover cesium or rubidium from secondary ore
CN105597926A (en) * 2015-12-29 2016-05-25 中国地质科学院郑州矿产综合利用研究所 Beneficiation method for rubidium-containing feldspar quarry
CN106179716A (en) * 2016-07-09 2016-12-07 中国地质科学院郑州矿产综合利用研究所 Sorting process for lithium rubidium rare metal ore
CN108624765A (en) * 2018-06-14 2018-10-09 中南大学 A kind of technique from the low-grade high efficiente callback of tailing containing rubidium rubidium
CN108816499A (en) * 2018-06-14 2018-11-16 中南大学 A kind of Combination of magnetic separation flotation beneficiation method of black clouds parent form ore containing rubidium

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105209645A (en) * 2013-03-05 2015-12-30 卡博特公司 Methods to recover cesium or rubidium from secondary ore
CN104475339A (en) * 2014-12-11 2015-04-01 江西一元再生资源有限公司 Method for comprehensively recovering lead, zinc, lithium, niobium and rubidium from tailings
CN104805311A (en) * 2015-03-24 2015-07-29 中国地质科学院矿产综合利用研究所 Method for extracting rubidium from rubidium-containing feldspar and co-producing silicon fertilizer
CN105597926A (en) * 2015-12-29 2016-05-25 中国地质科学院郑州矿产综合利用研究所 Beneficiation method for rubidium-containing feldspar quarry
CN106179716A (en) * 2016-07-09 2016-12-07 中国地质科学院郑州矿产综合利用研究所 Sorting process for lithium rubidium rare metal ore
CN108624765A (en) * 2018-06-14 2018-10-09 中南大学 A kind of technique from the low-grade high efficiente callback of tailing containing rubidium rubidium
CN108816499A (en) * 2018-06-14 2018-11-16 中南大学 A kind of Combination of magnetic separation flotation beneficiation method of black clouds parent form ore containing rubidium

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110369164A (en) * 2019-07-31 2019-10-25 湖南柿竹园有色金属有限责任公司 A kind of beneficiation method of the preenrichment of rubidium
CN110369164B (en) * 2019-07-31 2021-09-14 湖南柿竹园有色金属有限责任公司 Beneficiation method for pre-enrichment of rubidium
CN112958276A (en) * 2021-03-18 2021-06-15 广东省科学院资源综合利用研究所 Treatment method for solid waste of sapphire processing laponite
CN112958276B (en) * 2021-03-18 2022-11-22 广东省科学院资源综合利用研究所 Treatment method for solid waste of sapphire processing laponite
CN114798157A (en) * 2022-04-29 2022-07-29 有研资源环境技术研究院(北京)有限公司 Method for recovering pollucite from pegmatite type tailings

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Application publication date: 20190319