CN109480387A - A kind of ecological bacteriostatic shoes with temperature adjusting devices - Google Patents
A kind of ecological bacteriostatic shoes with temperature adjusting devices Download PDFInfo
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- CN109480387A CN109480387A CN201811346397.4A CN201811346397A CN109480387A CN 109480387 A CN109480387 A CN 109480387A CN 201811346397 A CN201811346397 A CN 201811346397A CN 109480387 A CN109480387 A CN 109480387A
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- molecular sieve
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- shoes
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- 230000003385 bacteriostatic effect Effects 0.000 title claims abstract description 15
- 239000002808 molecular sieve Substances 0.000 claims abstract description 70
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 claims abstract description 70
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical group [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims abstract description 38
- 229910052709 silver Inorganic materials 0.000 claims abstract description 38
- 239000004332 silver Substances 0.000 claims abstract description 38
- 230000000844 anti-bacterial effect Effects 0.000 claims abstract description 34
- 239000000835 fiber Substances 0.000 claims abstract description 31
- 239000004744 fabric Substances 0.000 claims abstract description 29
- 239000004745 nonwoven fabric Substances 0.000 claims abstract description 27
- 239000003242 anti bacterial agent Substances 0.000 claims abstract description 22
- 238000011049 filling Methods 0.000 claims abstract description 20
- 239000000126 substance Substances 0.000 claims abstract description 19
- 239000003292 glue Substances 0.000 claims abstract description 15
- 239000000839 emulsion Substances 0.000 claims abstract description 12
- 238000013016 damping Methods 0.000 claims abstract description 7
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical class [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 48
- MTHSVFCYNBDYFN-UHFFFAOYSA-N anhydrous diethylene glycol Natural products OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 claims description 47
- 239000002131 composite material Substances 0.000 claims description 42
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 27
- 238000002156 mixing Methods 0.000 claims description 22
- SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(1+) nitrate Chemical class [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 claims description 21
- 235000011121 sodium hydroxide Nutrition 0.000 claims description 20
- 125000001820 oxy group Chemical group [*:1]O[*:2] 0.000 claims description 19
- 239000002253 acid Substances 0.000 claims description 18
- 238000006243 chemical reaction Methods 0.000 claims description 18
- 239000012530 fluid Substances 0.000 claims description 17
- 238000001035 drying Methods 0.000 claims description 16
- ZPFAVCIQZKRBGF-UHFFFAOYSA-N 1,3,2-dioxathiolane 2,2-dioxide Chemical compound O=S1(=O)OCCO1 ZPFAVCIQZKRBGF-UHFFFAOYSA-N 0.000 claims description 14
- 239000004831 Hot glue Substances 0.000 claims description 14
- 239000002202 Polyethylene glycol Substances 0.000 claims description 14
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 14
- BOTDANWDWHJENH-UHFFFAOYSA-N Tetraethyl orthosilicate Chemical class CCO[Si](OCC)(OCC)OCC BOTDANWDWHJENH-UHFFFAOYSA-N 0.000 claims description 14
- 229920001223 polyethylene glycol Polymers 0.000 claims description 14
- 229920001169 thermoplastic Polymers 0.000 claims description 14
- 239000004416 thermosoftening plastic Substances 0.000 claims description 14
- 238000005406 washing Methods 0.000 claims description 14
- 239000000843 powder Substances 0.000 claims description 13
- 229910001961 silver nitrate Inorganic materials 0.000 claims description 13
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 claims description 12
- 238000004519 manufacturing process Methods 0.000 claims description 12
- 238000010438 heat treatment Methods 0.000 claims description 10
- 239000004816 latex Substances 0.000 claims description 10
- 229920000126 latex Polymers 0.000 claims description 10
- DHAHRLDIUIPTCJ-UHFFFAOYSA-K aluminium metaphosphate Chemical compound [Al+3].[O-]P(=O)=O.[O-]P(=O)=O.[O-]P(=O)=O DHAHRLDIUIPTCJ-UHFFFAOYSA-K 0.000 claims description 8
- 150000001875 compounds Chemical class 0.000 claims description 8
- PQDJYEQOELDLCP-UHFFFAOYSA-N trimethylsilane Chemical compound C[SiH](C)C PQDJYEQOELDLCP-UHFFFAOYSA-N 0.000 claims description 8
- 229940094989 trimethylsilane Drugs 0.000 claims description 8
- BOXSVZNGTQTENJ-UHFFFAOYSA-L zinc dibutyldithiocarbamate Chemical compound [Zn+2].CCCCN(C([S-])=S)CCCC.CCCCN(C([S-])=S)CCCC BOXSVZNGTQTENJ-UHFFFAOYSA-L 0.000 claims description 8
- NSJUABOWQSLBEJ-UHFFFAOYSA-N [Na].[Na].[Na].B(O)(O)O Chemical compound [Na].[Na].[Na].B(O)(O)O NSJUABOWQSLBEJ-UHFFFAOYSA-N 0.000 claims description 7
- 238000013461 design Methods 0.000 claims description 7
- 238000001914 filtration Methods 0.000 claims description 7
- 238000005470 impregnation Methods 0.000 claims description 7
- 238000002803 maceration Methods 0.000 claims description 7
- 239000000463 material Substances 0.000 claims description 7
- 238000002360 preparation method Methods 0.000 claims description 7
- 229910000029 sodium carbonate Inorganic materials 0.000 claims description 7
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 6
- 239000004411 aluminium Substances 0.000 claims description 6
- 229910052782 aluminium Inorganic materials 0.000 claims description 6
- 238000001354 calcination Methods 0.000 claims description 6
- 239000008367 deionised water Substances 0.000 claims description 6
- 229910021641 deionized water Inorganic materials 0.000 claims description 6
- -1 diethylene glycol ethers Chemical class 0.000 claims description 6
- RSIHJDGMBDPTIM-UHFFFAOYSA-N ethoxy(trimethyl)silane Chemical compound CCO[Si](C)(C)C RSIHJDGMBDPTIM-UHFFFAOYSA-N 0.000 claims description 6
- 239000000203 mixture Substances 0.000 claims description 6
- 239000002994 raw material Substances 0.000 claims description 6
- 230000035484 reaction time Effects 0.000 claims description 6
- 239000011701 zinc Substances 0.000 claims description 6
- 229910052725 zinc Inorganic materials 0.000 claims description 6
- RPNUMPOLZDHAAY-UHFFFAOYSA-N Diethylenetriamine Chemical compound NCCNCCN RPNUMPOLZDHAAY-UHFFFAOYSA-N 0.000 claims description 5
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 5
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 5
- 239000011734 sodium Substances 0.000 claims description 5
- 229910052708 sodium Inorganic materials 0.000 claims description 5
- 239000003643 water by type Substances 0.000 claims description 5
- DJMIKAGANCZWLL-UHFFFAOYSA-N dihydroxy hydrogen phosphate Chemical compound OOP(O)(=O)OO DJMIKAGANCZWLL-UHFFFAOYSA-N 0.000 claims description 4
- 238000000926 separation method Methods 0.000 claims description 4
- 238000000034 method Methods 0.000 claims description 3
- 239000000047 product Substances 0.000 claims 2
- KZJRKRQSDZGHEC-UHFFFAOYSA-N 2,2,2-trifluoro-1-phenylethanone Chemical class FC(F)(F)C(=O)C1=CC=CC=C1 KZJRKRQSDZGHEC-UHFFFAOYSA-N 0.000 claims 1
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims 1
- 239000006227 byproduct Substances 0.000 claims 1
- 239000006071 cream Substances 0.000 claims 1
- 238000007654 immersion Methods 0.000 claims 1
- 229920001206 natural gum Polymers 0.000 claims 1
- 210000004243 sweat Anatomy 0.000 abstract description 11
- 241000894006 Bacteria Species 0.000 abstract description 8
- 239000011148 porous material Substances 0.000 abstract description 7
- 238000010521 absorption reaction Methods 0.000 abstract description 5
- 230000035699 permeability Effects 0.000 abstract description 4
- 206010040007 Sense of oppression Diseases 0.000 abstract description 3
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 10
- 238000005516 engineering process Methods 0.000 description 10
- 239000003513 alkali Substances 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 6
- 230000000694 effects Effects 0.000 description 6
- 229910052710 silicon Inorganic materials 0.000 description 6
- 239000010703 silicon Substances 0.000 description 6
- 239000000243 solution Substances 0.000 description 6
- 239000002585 base Substances 0.000 description 5
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 4
- 238000004140 cleaning Methods 0.000 description 4
- 238000002474 experimental method Methods 0.000 description 4
- NVSKOJZXIQFFBQ-UHFFFAOYSA-N 2,2,2-trifluoro-1-(2-fluorophenyl)ethanone Chemical compound FC1=CC=CC=C1C(=O)C(F)(F)F NVSKOJZXIQFFBQ-UHFFFAOYSA-N 0.000 description 3
- FOIXSVOLVBLSDH-UHFFFAOYSA-N Silver ion Chemical compound [Ag+] FOIXSVOLVBLSDH-UHFFFAOYSA-N 0.000 description 3
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 3
- 229910021536 Zeolite Inorganic materials 0.000 description 3
- 230000003115 biocidal effect Effects 0.000 description 3
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical group O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 3
- 239000007789 gas Substances 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- 239000010457 zeolite Substances 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 2
- 230000000845 anti-microbial effect Effects 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 239000012752 auxiliary agent Substances 0.000 description 2
- 239000003599 detergent Substances 0.000 description 2
- 239000012153 distilled water Substances 0.000 description 2
- 238000001027 hydrothermal synthesis Methods 0.000 description 2
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
- 239000012046 mixed solvent Substances 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 125000000962 organic group Chemical group 0.000 description 2
- 229910052698 phosphorus Inorganic materials 0.000 description 2
- 239000011574 phosphorus Substances 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 239000011780 sodium chloride Substances 0.000 description 2
- 230000002195 synergetic effect Effects 0.000 description 2
- KOUONPVXNPOEHQ-UHFFFAOYSA-N 2-[dimethoxy(propyl)silyl]oxyacetamide Chemical compound CCC[Si](OC)(OC)OCC(N)=O KOUONPVXNPOEHQ-UHFFFAOYSA-N 0.000 description 1
- 235000017166 Bambusa arundinacea Nutrition 0.000 description 1
- 235000017491 Bambusa tulda Nutrition 0.000 description 1
- 241001330002 Bambuseae Species 0.000 description 1
- 208000014770 Foot disease Diseases 0.000 description 1
- AVXURJPOCDRRFD-UHFFFAOYSA-N Hydroxylamine Chemical compound ON AVXURJPOCDRRFD-UHFFFAOYSA-N 0.000 description 1
- 235000015334 Phyllostachys viridis Nutrition 0.000 description 1
- 241000191940 Staphylococcus Species 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 239000011425 bamboo Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 229960000541 cetyl alcohol Drugs 0.000 description 1
- 239000003610 charcoal Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 230000009514 concussion Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 125000004177 diethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 239000012634 fragment Substances 0.000 description 1
- 230000001408 fungistatic effect Effects 0.000 description 1
- BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 description 1
- DKAGJZJALZXOOV-UHFFFAOYSA-N hydrate;hydrochloride Chemical compound O.Cl DKAGJZJALZXOOV-UHFFFAOYSA-N 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000008223 sterile water Substances 0.000 description 1
- 210000000106 sweat gland Anatomy 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A43—FOOTWEAR
- A43B—CHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
- A43B17/00—Insoles for insertion, e.g. footbeds or inlays, for attachment to the shoe after the upper has been joined
- A43B17/003—Insoles for insertion, e.g. footbeds or inlays, for attachment to the shoe after the upper has been joined characterised by the material
- A43B17/006—Insoles for insertion, e.g. footbeds or inlays, for attachment to the shoe after the upper has been joined characterised by the material multilayered
-
- A—HUMAN NECESSITIES
- A43—FOOTWEAR
- A43B—CHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
- A43B17/00—Insoles for insertion, e.g. footbeds or inlays, for attachment to the shoe after the upper has been joined
- A43B17/08—Insoles for insertion, e.g. footbeds or inlays, for attachment to the shoe after the upper has been joined ventilated
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Footwear And Its Accessory, Manufacturing Method And Apparatuses (AREA)
Abstract
The invention discloses a kind of ecological bacteriostatic shoes with temperature adjusting devices, including insole, the insole is made of three-decker, first layer is antibacterial nonwoven cloth layer, the second layer is filling emulsion layer, third layer is balancing damping layer, the antibacterial nonwoven cloth layer includes following parts by weight substance: 75-80 parts of PBT, 15-25 parts of PLA, 5-10 parts of antibacterial agents, 8-15 parts of aqueous PU glues, the antibacterial agent is silver molecular sieve, in the present invention, what antibacterial agent was selected is silver molecular sieve, so that the aperture quantity of nonwoven surface increases, and improve the regularity of fiber in non-woven fabrics, uniform pore size, improve the gas permeability of non-woven fabrics, it reduces and gives human body bring feeling of oppression and heat in the excessively high shoes of environment temperature, simultaneously, the porous structure of silver molecular sieve assigns insole superpower absorption property, adsorb the peculiar smell and sweat in shoes, it protects Witness's body foot dry, to effectively prevent the growth of bacterium.
Description
Technical field
The present invention relates to a kind of shoes, more particularly to a kind of ecological bacteriostatic shoes with temperature adjusting devices.
Background technique
Shoes are earliest people in order to overcome special circumstances, and foot is not allowed to be felt bad or household goods that are injured and inventing.
During wearing shoes walking, since human foot's sweat gland is relatively abundant, human body can be discharged sweat by foot, and most of shoes
Gas permeability is bad, so that foot is in a humidity, sultry environment, bacterium easy to breed causes foot's disease.Market is upper
Though capable medical shoe pad or Bamboo charcoal shoe-pad has the effect of antibacterial, in the case where repeatedly being cleaned with detergent, it can be gradually lost
Bacteriostasis, in addition, faintly acid is presented in the sweat of human body discharge, sweat will affect the fungistatic effect of a part of insole.
Summary of the invention
In view of the deficiencies of the prior art, the present invention intends to provide a kind of ecological bacteriostatic shoes with temperature adjusting devices.
To achieve the above object, the present invention provides the following technical scheme that a kind of ecological bacteriostatic shoes with temperature adjusting devices, including insole,
The insole is made of three-decker, and first layer is antibacterial nonwoven cloth layer, and the second layer is filling emulsion layer, and third layer is that balance subtracts
Layer is shaken, the antibacterial nonwoven cloth layer includes following parts by weight substance:
75-80 parts of PBT；
15-25 parts of PLA；
5-10 parts of antibacterial agents；
8-15 parts of aqueous PU glues；
The antibacterial agent is silver molecular sieve.
The production technology following steps of the antibacterial nonwoven cloth layer:
S1: PBT fiber and PLA fiber are subjected to shredding, mixing, smart shredding, filtering and combing, obtain composite fibre；
S2: silver molecular sieve being uniformly mixed with aqueous PU glue, obtains maceration extract, carries out impregnation to composite fibre
30-50h；, obtain non-woven fabrics to be processed；
S3: it by non-woven fabrics drying obtained in S2, bakes, cool down and reel rewinding obtains finished product non-woven fabrics.The load
Silver-colored molecular sieve includes following parts by weight substance:
4 parts of tetraethyl orthosilicates；
1 part of 2- acryloyl group oxygroup ethoxytrimethylsilane；
5 parts of sodium hydroxides；
90 parts of pure water；
1 part of zinc dibutyl dithiocarbamate；
3 parts of aluminium metaphosphates；
2 parts of lauryl alcohol polyethylene glycol sulfate ammonium salts；
75 parts of deionized waters；
15 parts of diethylene glycol ethers；
10 parts of silver nitrates；
2 parts of DPM dpm,dipivalomethane acid groups are silver-colored (I)；
3 parts of regulators.
The production technology following steps of the silver molecular sieve:
Step 1: it is equipped with raw material according to the weight percent of setting, first by tetraethyl orthosilicate, 2- acryloyl group oxygroup second
Oxygroup trimethyl silane, sodium hydroxide and pure water are added in reaction vessel, are stirred；Again by dibutyl dithio amino first
Mixing in reactor is added in sour zinc, aluminium metaphosphate and lauryl alcohol polyethylene glycol sulfate ammonium salt, and mixed liquor is made；It will be in mixed liquor
It is put into the baking oven that temperature is 120-150 DEG C and carries out heating reaction, reaction time 3-5h；After reaction, product is separated,
Carrier original powder is obtained after washing, drying, carrier original powder is subjected to calcination again later, obtains micro porous molecular sieve；
Step 2: micro porous molecular sieve being placed in treatment fluid and impregnates 30-50min, and treatment fluid temperature is 60-80 DEG C, is impregnated
After washed, dry, obtain micropore-mesopore complex type molecular sieve.
Step 3: deionized water and diethylene glycol ether being added in reactor and are stirred, silver nitrate and 2 are subsequently added into,
2,6,6- tetramethyl -3,5- heptadione acid group silver-colored (I) mixing, add regulator and composite molecular screen after mixing, carry out
It is stirred, mixed liquor is made；Mixed liquor is put into 80-100 DEG C of baking oven and is heat-treated, heat treatment time is that 4-6 is small
When；Product separation, washing, drying are obtained silver molecular sieve by after treatment.
The treatment fluid is sodium hydroxide, sodium carbonate, boric acid trisodium, pure water, and the ratio between parts by weight are 5:3:2:50.
The regulator is the fluoro- 2,2,2- trifluoroacetophenone of the chloro- 5- of 3-, dihydroxy Phosphoric acid monohexadecyl ester sodium and diethylenetriamine
The mixture of base propyl trimethoxy silicane, the ratio between parts by weight are 3:2:1.
The filling latex selects Heveatex.
The buffer layer uses TPU foamed material.
Steps are as follows for the insole preparation method:
(1) between antibacterial nonwoven cloth layer and filling emulsion layer, pass through the ventilative hot-melt adhesive film of 0.3-0.75UM thermoplastics type, warp
Plane abutted equipment is heated to 130-150 DEG C of fitting, forms the first composite structure；
(2) first compound layers and balance buffer layer are again by the ventilative hot-melt adhesive film of 0.3-0.75UM thermoplastics type, warp
Plane abutted equipment is heated to 130-150 DEG C of fitting, forms the second composite structure；
(3) second composite structures cut into insole sample according to design requirement prepared by insole.
Beneficial effects of the present invention, the present invention in, antibacterial agent select be silver molecular sieve so that the hole of nonwoven surface
Diameter quantity increases, and improves the regularity of fiber, uniform pore size in non-woven fabrics, improves the gas permeability of non-woven fabrics, reduces
The excessively high shoes of environment temperature give human body bring feeling of oppression and heat, meanwhile, the porous structure of silver molecular sieve assigns insole superpower suction
Attached performance adsorbs peculiar smell and sweat in shoes, guarantees human body foot dry, to effectively prevent the growth of bacterium.
As one of new wound point of the invention, first pass through with ethyl orthosilicate and 2- acryloyl group oxygroup ethyoxyl trimethyl
Silane is as silicon source, using aluminium metaphosphate as silicon source and phosphorus source, while being also added into zinc dibutyl dithiocarbamate and ten
The substances such as glycol polyethylene glycol sulfate ammonium salt carry out pore type molecular sieve with hydro-thermal method, under the collective effect of above-mentioned substance, this
When molecular sieve there is certain resistance to acid and alkali, but since aperture quantity is few, and pore size is smaller, adsorbs the energy of silver ion
Power is very weak, by being handled with the alkaline aqueous solution containing sodium hydroxide, sodium carbonate and boric acid trisodium.During processing,
Silicon on micro porous molecular sieve edge can be taken off by alkali soluble, to produce mesoporous, after treatment fluid is handled, micro porous molecular sieve is just
Become micropore-mesopore complex type molecular sieve, improve acid-proof alkaline, and has and preferably carry silver-colored ability.Silver-colored source is silver nitrate
With 2,2,6,6- tetramethyl -3,5- heptadione acid groups are silver-colored (I), and since silver nitrate is inorganic matter, 2,2,6,6- tetramethyls -3,5-
Containing organic groups such as methyl in heptadione acid group silver-colored (I), therefore using deionized water and diethylene glycol ether as mixed solvent, with
This is as the medium reacted.
It joined adjusting as another new wound point of the invention in order to further strengthen the load silver ability of the molecular sieve
The chloro- 5- of 3- fluoro- 2,2,2- trifluoroacetophenones, dihydroxy Phosphoric acid monohexadecyl ester sodium and diethyl have been selected in agent in the selection of regulator
The mixture of three aminocarbonyl propyl trimethoxy silane of alkene, so that micropore-mesopore complex type molecular sieve has very strong load silver
Ability；In addition to this, which can also improve the synergistic effect between antibacterial agent and other auxiliary agents, and bad shadow will not occur
It rings.
Specific embodiment
Below with reference to embodiment, the present invention is described in more detail.Substance used in the present invention without specified otherwise,
It purchases to obtain by market.
Embodiment one:
Including insole, the insole is made of three-decker, and first layer is antibacterial nonwoven cloth layer, and the second layer is filling latex
Layer, third layer are balancing damping layer, and the antibacterial nonwoven cloth layer includes following parts by weight substance:
80 parts of PBT；
20 parts of PLA；
10 parts of antibacterial agents；
15 parts of aqueous PU glues；
The antibacterial agent is silver molecular sieve.
The production technology following steps of the antibacterial nonwoven cloth layer:
S1: PBT fiber and PLA fiber are subjected to shredding, mixing, smart shredding, filtering and combing, obtain composite fibre；
S2: silver molecular sieve being uniformly mixed with aqueous PU glue, obtains maceration extract, carries out impregnation to composite fibre
30-50h；, obtain non-woven fabrics to be processed；
S3: it by non-woven fabrics drying obtained in S2, bakes, cool down and reel rewinding obtains finished product non-woven fabrics.The load
Silver-colored molecular sieve includes following parts by weight substance:
4 parts of tetraethyl orthosilicates；
1 part of 2- acryloyl group oxygroup ethoxytrimethylsilane；
5 parts of sodium hydroxides；
90 parts of pure water；
1 part of zinc dibutyl dithiocarbamate；
3 parts of aluminium metaphosphates；
2 parts of lauryl alcohol polyethylene glycol sulfate ammonium salts；
75 parts of deionized waters；
15 parts of diethylene glycol ethers；
10 parts of silver nitrates；
2 parts of DPM dpm,dipivalomethane acid groups are silver-colored (I)；
3 parts of regulators.
The production technology following steps of the silver molecular sieve:
Step 1: it is equipped with raw material according to the weight percent of setting, first by tetraethyl orthosilicate, 2- acryloyl group oxygroup second
Oxygroup trimethyl silane, sodium hydroxide and pure water are added in reaction vessel, are stirred；Again by dibutyl dithio amino first
Mixing in reactor is added in sour zinc, aluminium metaphosphate and lauryl alcohol polyethylene glycol sulfate ammonium salt, and mixed liquor is made；It will be in mixed liquor
It is put into the baking oven that temperature is 120-150 DEG C and carries out heating reaction, reaction time 3-5h；After reaction, product is separated,
Carrier original powder is obtained after washing, drying, carrier original powder is subjected to calcination again later, obtains micro porous molecular sieve；
Step 2: micro porous molecular sieve being placed in treatment fluid and impregnates 30-50min, and treatment fluid temperature is 60-80 DEG C, is impregnated
After washed, dry, obtain micropore-mesopore complex type molecular sieve.
Step 3: deionized water and diethylene glycol ether being added in reactor and are stirred, silver nitrate and 2 are subsequently added into,
2,6,6- tetramethyl -3,5- heptadione acid group silver-colored (I) mixing, add regulator and composite molecular screen after mixing, carry out
It is stirred, mixed liquor is made；Mixed liquor is put into 80-100 DEG C of baking oven and is heat-treated, heat treatment time is that 4-6 is small
When；Product separation, washing, drying are obtained silver molecular sieve by after treatment.
The treatment fluid is sodium hydroxide, sodium carbonate, boric acid trisodium, pure water, and the ratio between parts by weight are 5:3:2:50.
The regulator is the fluoro- 2,2,2- trifluoroacetophenone of the chloro- 5- of 3-, dihydroxy Phosphoric acid monohexadecyl ester sodium and diethylenetriamine
The mixture of base propyl trimethoxy silicane, the ratio between parts by weight are 3:2:1.
The filling latex selects Heveatex.
The buffer layer uses TPU foamed material.
Steps are as follows for the insole preparation method:
(1) between antibacterial nonwoven cloth layer and filling emulsion layer, pass through the ventilative hot-melt adhesive film of 0.3-0.75UM thermoplastics type, warp
Plane abutted equipment is heated to 130-150 DEG C of fitting, forms the first composite structure；
(2) first compound layers and balance buffer layer are again by the ventilative hot-melt adhesive film of 0.3-0.75UM thermoplastics type, warp
Plane abutted equipment is heated to 130-150 DEG C of fitting, forms the second composite structure；
(3) second composite structures cut into insole sample according to design requirement prepared by insole.
Comparative example one: including insole, the insole is made of three-decker, and first layer is antibacterial nonwoven cloth layer, the second layer
To fill emulsion layer, third layer is balancing damping layer, and the antibacterial nonwoven cloth layer includes following parts by weight substance:
80 parts of PBT；
20 parts of PLA；
10 parts of antibacterial agents；
15 parts of aqueous PU glues；
The antibacterial agent is micro porous molecular sieve.
The production technology following steps of the antibacterial nonwoven cloth layer:
S1: PBT fiber and PLA fiber are subjected to shredding, mixing, smart shredding, filtering and combing, obtain composite fibre；
S2: micro porous molecular sieve being uniformly mixed with aqueous PU glue, obtains maceration extract, carries out impregnation to composite fibre
30-50h；, obtain non-woven fabrics to be processed；
S3: it by non-woven fabrics drying obtained in S2, bakes, cool down and reel rewinding obtains finished product non-woven fabrics.It is described micro-
Porous molecular sieve includes following parts by weight substance:
4 parts of tetraethyl orthosilicates；
1 part of 2- acryloyl group oxygroup ethoxytrimethylsilane；
5 parts of sodium hydroxides；
90 parts of pure water.
1 part of zinc dibutyl dithiocarbamate；
3 parts of aluminium metaphosphates；
2 parts of lauryl alcohol polyethylene glycol sulfate ammonium salts；
The production technology following steps of the micro porous molecular sieve:
Step 1: it is equipped with raw material according to the weight percent of setting, first by tetraethyl orthosilicate, 2- acryloyl group oxygroup second
Oxygroup trimethyl silane, sodium hydroxide and pure water are added in reaction vessel, are stirred；Again by dibutyl dithio amino first
Mixing in reactor is added in sour zinc, aluminium metaphosphate and lauryl alcohol polyethylene glycol sulfate ammonium salt, and mixed liquor is made；It will be in mixed liquor
It is put into the baking oven that temperature is 120-150 DEG C and carries out heating reaction, reaction time 3-5h；After reaction, product is separated,
Carrier original powder is obtained after washing, drying, carrier original powder is subjected to calcination again later, obtains micro porous molecular sieve；
The filling latex selects Heveatex.
The buffer layer uses TPU foamed material.
Steps are as follows for the insole preparation method:
(1) between antibacterial nonwoven cloth layer and filling emulsion layer, pass through the ventilative hot-melt adhesive film of 0.3-0.75UM thermoplastics type, warp
Plane abutted equipment is heated to 130-150 DEG C of fitting, forms the first composite structure；
(2) first compound layers and balance buffer layer are again by the ventilative hot-melt adhesive film of 0.3-0.75UM thermoplastics type, warp
Plane abutted equipment is heated to 130-150 DEG C of fitting, forms the second composite structure；
(3) second composite structures cut into insole sample according to design requirement prepared by insole.
Comparative example two: including insole, the insole is made of three-decker, and first layer is antibacterial nonwoven cloth layer, the second layer
To fill emulsion layer, third layer is balancing damping layer, and the antibacterial nonwoven cloth layer includes following parts by weight substance:
80 parts of PBT；
20 parts of PLA；
10 parts of antibacterial agents；
15 parts of aqueous PU glues；
The antibacterial agent is composite molecular screen.
The production technology following steps of the antibacterial nonwoven cloth layer:
S1: PBT fiber and PLA fiber are subjected to shredding, mixing, smart shredding, filtering and combing, obtain composite fibre；
S2: composite molecular screen being uniformly mixed with aqueous PU glue, obtains maceration extract, carries out impregnation to composite fibre
30-50h；, obtain non-woven fabrics to be processed；
S3: it by non-woven fabrics drying obtained in S2, bakes, cool down and reel rewinding obtains finished product non-woven fabrics.It is described multiple
Closing molecular sieve includes following parts by weight substance:
4 parts of tetraethyl orthosilicates；
1 part of 2- acryloyl group oxygroup ethoxytrimethylsilane；
5 parts of sodium hydroxides；
90 parts of pure water.
1 part of zinc dibutyl dithiocarbamate；
3 parts of aluminium metaphosphates；
2 parts of lauryl alcohol polyethylene glycol sulfate ammonium salts；
75 parts of deionized waters；
15 parts of diethylene glycol ethers；
10 parts of silver nitrates；
2 parts of DPM dpm,dipivalomethane acid groups are silver-colored (I)；
3 parts of regulators.
The production technology following steps of the composite molecular screen:
Step 1: it is equipped with raw material according to the weight percent of setting, first by tetraethyl orthosilicate, 2- acryloyl group oxygroup second
Oxygroup trimethyl silane, sodium hydroxide and pure water are added in reaction vessel, are stirred；Again by dibutyl dithio amino first
Mixing in reactor is added in sour zinc, aluminium metaphosphate and lauryl alcohol polyethylene glycol sulfate ammonium salt, and mixed liquor is made；It will be in mixed liquor
It is put into the baking oven that temperature is 120-150 DEG C and carries out heating reaction, reaction time 3-5h；After reaction, product is separated,
Carrier original powder is obtained after washing, drying, carrier original powder is subjected to calcination again later, obtains micro porous molecular sieve；
Step 2: micro porous molecular sieve being placed in treatment fluid and impregnates 30-50min, and treatment fluid temperature is 60-80 DEG C, is impregnated
After washed, dry, obtain micropore-mesopore complex type molecular sieve.
The treatment fluid is sodium hydroxide, sodium carbonate, boric acid trisodium, pure water, and the ratio between parts by weight are 5:3:2:50.
The filling latex selects Heveatex.
The buffer layer uses TPU foamed material.
Steps are as follows for the insole preparation method:
(1) between antibacterial nonwoven cloth layer and filling emulsion layer, pass through the ventilative hot-melt adhesive film of 0.3-0.75UM thermoplastics type, warp
Plane abutted equipment is heated to 130-150 DEG C of fitting, forms the first composite structure；
(2) first compound layers and balance buffer layer are again by the ventilative hot-melt adhesive film of 0.3-0.75UM thermoplastics type, warp
Plane abutted equipment is heated to 130-150 DEG C of fitting, forms the second composite structure；
(3) second composite structures cut into insole sample according to design requirement prepared by insole.
Comparative example three:
Including insole, the insole is made of three-decker, and first layer is antibacterial nonwoven cloth layer, and the second layer is filling latex
Layer, third layer are balancing damping layer, and the antibacterial nonwoven cloth layer includes following parts by weight substance:
80 parts of PBT；
20 parts of PLA；
10 parts of antibacterial agents；
15 parts of aqueous PU glues；
The antibacterial agent is silver molecular sieve.
The production technology following steps of the antibacterial nonwoven cloth layer:
S1: PBT fiber and PLA fiber are subjected to shredding, mixing, smart shredding, filtering and combing, obtain composite fibre；
S2: silver molecular sieve being uniformly mixed with aqueous PU glue, obtains maceration extract, carries out impregnation to composite fibre
30-50h；, obtain non-woven fabrics to be processed；
S3: it by non-woven fabrics drying obtained in S2, bakes, cool down and reel rewinding obtains finished product non-woven fabrics.The load
Silver-colored molecular sieve includes following parts by weight substance:
4 parts of tetraethyl orthosilicates；
1 part of 2- acryloyl group oxygroup ethoxytrimethylsilane；
5 parts of sodium hydroxides；
90 parts of pure water；
1 part of zinc dibutyl dithiocarbamate；
3 parts of aluminium metaphosphates；
2 parts of lauryl alcohol polyethylene glycol sulfate ammonium salts；
75 parts of deionized waters；
15 parts of diethylene glycol ethers；
10 parts of silver nitrates；
2 parts of DPM dpm,dipivalomethane acid groups are silver-colored (I)；
3 parts of regulators.
The production technology following steps of the silver molecular sieve:
Step 1: it is equipped with raw material according to the weight percent of setting, first by tetraethyl orthosilicate, 2- acryloyl group oxygroup second
Oxygroup trimethyl silane, sodium hydroxide and pure water are added in reaction vessel, are stirred；Again by dibutyl dithio amino first
Mixing in reactor is added in sour zinc, aluminium metaphosphate and lauryl alcohol polyethylene glycol sulfate ammonium salt, and mixed liquor is made；It will be in mixed liquor
It is put into the baking oven that temperature is 120-150 DEG C and carries out heating reaction, reaction time 3-5h；After reaction, product is separated,
Carrier original powder is obtained after washing, drying, carrier original powder is subjected to calcination again later, obtains micro porous molecular sieve；
Step 2: micro porous molecular sieve being placed in treatment fluid and impregnates 30-50min, and treatment fluid temperature is 60-80 DEG C, is impregnated
After washed, dry, obtain micropore-mesopore complex type molecular sieve.
Step 3: deionized water and diethylene glycol ether being added in reactor and are stirred, silver nitrate and 2 are subsequently added into,
2,6,6- tetramethyl -3,5- heptadione acid group silver-colored (I) mixing, add regulator and composite molecular screen after mixing, carry out
It is stirred, mixed liquor is made；Mixed liquor is put into 80-100 DEG C of baking oven and is heat-treated, heat treatment time is that 4-6 is small
When；Product separation, washing, drying are obtained silver molecular sieve by after treatment.
The treatment fluid is sodium hydroxide, sodium carbonate, boric acid trisodium, pure water, and the ratio between parts by weight are 5:3:2:50.
The regulator is the fluoro- 2,2,2- trifluoroacetophenone of the chloro- 5- of 3- and diethylenetriamine base propyl trimethoxy silicane
Mixture, the ratio between parts by weight be 3:1.
The filling latex selects Heveatex.
The buffer layer uses TPU foamed material.
Steps are as follows for the insole preparation method:
(1) between antibacterial nonwoven cloth layer and filling emulsion layer, pass through the ventilative hot-melt adhesive film of 0.3-0.75UM thermoplastics type, warp
Plane abutted equipment is heated to 130-150 DEG C of fitting, forms the first composite structure；
(2) first compound layers and balance buffer layer are again by the ventilative hot-melt adhesive film of 0.3-0.75UM thermoplastics type, warp
Plane abutted equipment is heated to 130-150 DEG C of fitting, forms the second composite structure；
(3) second composite structures cut into insole sample according to design requirement prepared by insole.
Comparative example four:
Including insole, the insole is made of three-decker, and first layer is antibacterial nonwoven cloth layer, and the second layer is filling latex
Layer, third layer are balancing damping layer, and the antibacterial nonwoven cloth layer includes following parts by weight substance:
80 parts of PBT；
20 parts of PLA；
10 parts of antibacterial agents；
15 parts of aqueous PU glues；
The antibacterial agent is zeolite with carrying silver.
S1: PBT fiber and PLA fiber are subjected to shredding, mixing, smart shredding, filtering and combing, obtain composite fibre；
S2: zeolite with carrying silver being uniformly mixed with aqueous PU glue, obtains maceration extract, carries out impregnation 30- to composite fibre
50h；, obtain non-woven fabrics to be processed；
S3: it by non-woven fabrics drying obtained in S2, bakes, cool down and reel rewinding obtains finished product non-woven fabrics.
The filling latex selects Heveatex.
The buffer layer uses TPU foamed material.
Steps are as follows for the insole preparation method:
(1) between antibacterial nonwoven cloth layer and filling emulsion layer, pass through the ventilative hot-melt adhesive film of 0.3-0.75UM thermoplastics type, warp
Plane abutted equipment is heated to 130-150 DEG C of fitting, forms the first composite structure；
(2) first compound layers and balance buffer layer are again by the ventilative hot-melt adhesive film of 0.3-0.75UM thermoplastics type, warp
Plane abutted equipment is heated to 130-150 DEG C of fitting, forms the second composite structure；
(3) second composite structures cut into insole sample according to design requirement prepared by insole.
One: the measurement of bacteriostasis rate
Insole is cut into the fragment of about 1cmx1cm, 2.0g is taken to be fitted into the sterile conical flask of 100ml, adds 19.8ml
Sterile saline and 0.2ml for trying bacterium solution, the examination bacterium solution include staphylococcus, 200r/min in 30 DEG C of water-bath oscillators
Shake 2h.0.5ml concussion 0h is taken respectively and shakes the sample liquid of 2h, after doing appropriate dilution with sterile water, takes out 0.1ml sterile flat
On plate, viable bacteria culture is carried out using the method for plate culture count and is counted, and calculates antibiotic rate.
Two, water-wash resistance
GB8629-2001 according to national standards is found white washing powder and is made into the cleaning solution that mass concentration is 3g/L with commercially available,
At normal temperature, by washings quality and cleaning solution mass ratio 1:30, insole is put into agitator treating 15min in washing machine, so
It rinses in clear water, is washed as 1 time afterwards, after insole carries out 5 times and 10 times washings respectively, then take out and dry, test sample is anti-
Bacterium effect.
Three, absorption of perspiration
GB/T3903.11-2005 carries out absorption of perspiration test, the formula of synthetic perspiration are as follows: a water hydrochloric acid according to national standards
Azanol 5.00g, sodium chloride 5.00g, phosphate dihydrate disodium hydrogen 2.50g, distilled water 1L, and with the sodium hydroxide of 0.1mol/L and
It is 4.5 that the hydrochloric acid of 0.1mol, which adjusts PH,.Insole is put into the 1000ml beaker of synthetic perspiration, by being added additionally on insole
Weight is fully immersed in insole in synthetic perspiration, and then beaker is placed in 35 DEG C of insulating boxs and stands 12h, takes out insole
It is washed with distilled water and dries, tested as 1 sweat proof.Insole carries out 3 times and 6 sweat proof experiments respectively, dries rear test sample
Antibacterial effect.
Conclusion: it can show that the insole that joined silver molecular sieve or zeolite with carrying silver is antibacterial from the data of initial bacteriostasis rate
Effect is better than joined the insole for the molecular sieve for not carrying silver, embodies the excellent bacteriostasis property of silver ion, compares three He of comparative example
The initial bacteriostasis rate of comparative example four, under the collective effect of a variety of regulators, the load silver content of micropore-mesopore complex type molecular sieve
Increase, good antimicrobial effect；In water-fastness experiment, cleaning solution is in alkalescent, joined silver molecular sieve or micropore-mesopore is compound
The antibacterial fall of the insole of type molecular sieve is smaller, and in absorption of perspiration experiment, sweat is weakly acidic, joined silver molecular sieve
Or the antibacterial fall of the insole of micropore-mesopore complex type molecular sieve is smaller, comprehensive two experiments as above obtain of the invention
The silver molecular sieve of middle addition has resistance to acid and alkali, and insole of the invention still has preferable after multiple washing or sweat dipping
Biocidal property.
In the present invention, what antibacterial agent was selected is silver molecular sieve, so that the aperture quantity of nonwoven surface increases, and is improved
Regularity, the uniform pore size of fiber in non-woven fabrics, improve the gas permeability of non-woven fabrics, and reduction is given in the excessively high shoes of environment temperature
Human body bring feeling of oppression and heat, meanwhile, the porous structure of silver molecular sieve assigns insole superpower absorption property, adsorbs different in shoes
Taste and sweat guarantee human body foot dry, to effectively prevent the growth of bacterium.
As one of new wound point of the invention, first pass through with ethyl orthosilicate and 2- acryloyl group oxygroup ethyoxyl trimethyl
Silane is as silicon source, using aluminium metaphosphate as silicon source and phosphorus source, while being also added into zinc dibutyl dithiocarbamate and ten
The substances such as glycol polyethylene glycol sulfate ammonium salt carry out pore type molecular sieve with hydro-thermal method, under the collective effect of above-mentioned substance, this
When molecular sieve there is certain resistance to acid and alkali, but since aperture quantity is few, and pore size is smaller, adsorbs the energy of silver ion
Power is very weak, by being handled with the alkaline aqueous solution containing sodium hydroxide, sodium carbonate and boric acid trisodium.During processing,
Silicon on micro porous molecular sieve edge can be taken off by alkali soluble, to produce mesoporous, after treatment fluid is handled, micro porous molecular sieve is just
Become micropore-mesopore complex type molecular sieve, improve acid-proof alkaline, and has and preferably carry silver-colored ability.Silver-colored source is silver nitrate
With 2,2,6,6- tetramethyl -3,5- heptadione acid groups are silver-colored (I), and since silver nitrate is inorganic matter, 2,2,6,6- tetramethyls -3,5-
Containing organic groups such as methyl in heptadione acid group silver-colored (I), therefore using deionized water and diethylene glycol ether as mixed solvent, with
This is as the medium reacted.
Increase to further increase the load silver ability of molecular sieve as another new wound point of the invention and carry silver content,
It joined regulator, the chloro- 5- of 3- fluoro- 2,2,2- trifluoroacetophenones, dihydroxy cetanol phosphoric acid selected in the selection of regulator
The mixture of ester sodium and diethylenetriamine base propyl trimethoxy silicane, so that micropore-mesopore complex type molecular sieve carries silver
Content increases；In addition to this, which can also improve the synergistic effect between antibacterial agent and other auxiliary agents, will not occur bad
It influences.
The antibacterial agent that the present invention prepares has very strong antibiotic property and resistance to acid and alkali, and insole is by weak base such as suds
Property detergent cleaning after or insole immersed in sweat for a long time, anti-microbial property is still very strong；
The above is only a preferred embodiment of the present invention, protection scope of the present invention is not limited merely to above-mentioned implementation
Example, all technical solutions belonged under thinking of the present invention all belong to the scope of protection of the present invention.It should be pointed out that for the art
Those of ordinary skill for, several improvements and modifications without departing from the principles of the present invention, these improvements and modifications
It should be regarded as protection scope of the present invention.
Claims (9)
1. a kind of ecological bacteriostatic shoes with temperature adjusting devices, it is characterised in that: including insole, the insole is made of three-decker, and first layer is
Antibacterial nonwoven cloth layer, the second layer are filling emulsion layer, and third layer is balancing damping layer, and the antibacterial nonwoven cloth layer includes following weight
Measure part substance:
70-80 parts of PBT；
15-20 parts of PLA；
5-10 parts of antibacterial agents；
10-15 parts of aqueous PU glues；
The antibacterial agent is silver molecular sieve.
2. a kind of ecological bacteriostatic shoes with temperature adjusting devices according to claim 1, it is characterised in that: the production of the antibacterial nonwoven cloth layer
Technique following steps:
S1: PBT fiber and PLA fiber are subjected to shredding, mixing, smart shredding, filtering and combing, obtain composite fibre；
S2: silver molecular sieve being uniformly mixed with aqueous PU glue, obtains maceration extract, carries out impregnation 30- to composite fibre
50h；, obtain non-woven fabrics to be processed；
S3: it by non-woven fabrics drying obtained in S2, bakes, cool down and reel rewinding obtains finished product non-woven fabrics.
3. a kind of ecological bacteriostatic shoes with temperature adjusting devices according to claim 1 or 2, it is characterised in that: the silver molecular sieve includes
Following parts by weight substance:
4 parts of tetraethyl orthosilicates；
1 part of 2- acryloyl group oxygroup ethoxytrimethylsilane；
5 parts of sodium hydroxides；
90 parts of pure water；
1 part of zinc dibutyl dithiocarbamate；
3 parts of aluminium metaphosphates；
2 parts of lauryl alcohol polyethylene glycol sulfate ammonium salts；
75 parts of deionized waters；
15 parts of diethylene glycol ethers；
10 parts of silver nitrates；
2 parts of DPM dpm,dipivalomethane acid groups are silver-colored (I)；
3 parts of regulators.
4. a kind of ecological bacteriostatic shoes with temperature adjusting devices according to claim 1 or 2, it is characterised in that: the life of the silver molecular sieve
Production. art following steps:
Step 1: it is equipped with raw material according to the weight percent of setting, first by tetraethyl orthosilicate, 2- acryloyl group oxygroup ethyoxyl
Trimethyl silane, sodium hydroxide and pure water are added in reaction vessel, are stirred；Again by dibutyl dithiocaarbamate
Mixing in reactor is added in zinc, aluminium metaphosphate and lauryl alcohol polyethylene glycol sulfate ammonium salt, and mixed liquor is made；It will be put in mixed liquor
Enter in the baking oven that temperature is 120-150 DEG C and carries out heating reaction, reaction time 3-5h；After reaction, product separated, washed
Wash, dry after obtain carrier original powder, later again by carrier original powder carry out calcination, obtain micro porous molecular sieve；
Step 2: micro porous molecular sieve being placed in treatment fluid and impregnates 30-50min, and treatment fluid temperature is 60-80 DEG C, and immersion terminates
After washed, dry, obtain micropore-mesopore complex type molecular sieve.
Step 3: deionized water and diethylene glycol ether being added in reactor and are stirred, and are subsequently added into silver nitrate and 2, and 2,6,
6- tetramethyl -3,5- heptadione acid group silver-colored (I) mixing, adds regulator and composite molecular screen after mixing, is stirred
Mixed liquor is made in mixing；Mixed liquor is put into 80-100 DEG C of baking oven and is heat-treated, heat treatment time is 4-6 hours；Place
After reason, by product separation, washing, drying, silver molecular sieve is obtained.
5. a kind of ecological bacteriostatic shoes with temperature adjusting devices according to claim 4, it is characterised in that: the treatment fluid be sodium hydroxide,
Sodium carbonate, boric acid trisodium, pure water, the ratio between parts by weight are 5:3:2:50.
6. a kind of ecological bacteriostatic shoes with temperature adjusting devices according to claim 4, it is characterised in that: the regulator is that the chloro- 5- of 3- is fluoro-
The mixture of 2,2,2- trifluoroacetophenones, dihydroxy Phosphoric acid monohexadecyl ester sodium and diethylenetriamine base propyl trimethoxy silicane,
The ratio between parts by weight are 3:2:1.
7. a kind of ecological bacteriostatic shoes with temperature adjusting devices according to claim 1, it is characterised in that: the filling latex selects natural gum
Cream.
8. a kind of ecological bacteriostatic shoes with temperature adjusting devices according to claim 1, it is characterised in that: the buffer layer is foamed using TPU
Material.
9. a kind of ecological bacteriostatic shoes with temperature adjusting devices according to claim 1, it is characterised in that: the insole preparation method step is such as
Under:
(1) between antibacterial nonwoven cloth layer and filling emulsion layer, by the ventilative hot-melt adhesive film of 0.3-0.75UM thermoplastics type, through plane
Abutted equipment is heated to 130-150 DEG C of fitting, forms the first composite structure；
(2) first compound layers and balance buffer layer are again by the ventilative hot-melt adhesive film of 0.3-0.75UM thermoplastics type, through plane
Abutted equipment is heated to 130-150 DEG C of fitting, forms the second composite structure；
(3) second composite structures cut into insole sample according to design requirement prepared by insole.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201811346397.4A CN109480387A (en) | 2018-11-13 | 2018-11-13 | A kind of ecological bacteriostatic shoes with temperature adjusting devices |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201811346397.4A CN109480387A (en) | 2018-11-13 | 2018-11-13 | A kind of ecological bacteriostatic shoes with temperature adjusting devices |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112898692A (en) * | 2021-01-21 | 2021-06-04 | 福建五持恒科技发展有限公司 | Graphene-containing H1N1 virus-resistant shoe material |
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|---|---|---|---|---|
| US4015347A (en) * | 1974-12-28 | 1977-04-05 | Kazuyoshi Morishita | Insoles effective for curing and preventing athlete's foot |
| CN102100422A (en) * | 2009-10-13 | 2011-06-22 | 金猴集团有限公司 | Spring moving type purification shoes |
| CN106048894A (en) * | 2016-08-12 | 2016-10-26 | 温州新宇无纺布有限公司 | Nonwoven fabric and production process and application thereof |
| CN106360880A (en) * | 2016-08-28 | 2017-02-01 | 杭州锴越新材料有限公司 | Bacteriostatic negative ion shoe pad and preparation method thereof |
| CN107266914A (en) * | 2017-07-27 | 2017-10-20 | 合肥远科服装设计有限公司 | A kind of anti-tinea pedis Chinese medicine air permeable health-care shoe pad and preparation method thereof |
-
2018
- 2018-11-13 CN CN201811346397.4A patent/CN109480387A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4015347A (en) * | 1974-12-28 | 1977-04-05 | Kazuyoshi Morishita | Insoles effective for curing and preventing athlete's foot |
| CN102100422A (en) * | 2009-10-13 | 2011-06-22 | 金猴集团有限公司 | Spring moving type purification shoes |
| CN106048894A (en) * | 2016-08-12 | 2016-10-26 | 温州新宇无纺布有限公司 | Nonwoven fabric and production process and application thereof |
| CN106360880A (en) * | 2016-08-28 | 2017-02-01 | 杭州锴越新材料有限公司 | Bacteriostatic negative ion shoe pad and preparation method thereof |
| CN107266914A (en) * | 2017-07-27 | 2017-10-20 | 合肥远科服装设计有限公司 | A kind of anti-tinea pedis Chinese medicine air permeable health-care shoe pad and preparation method thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112898692A (en) * | 2021-01-21 | 2021-06-04 | 福建五持恒科技发展有限公司 | Graphene-containing H1N1 virus-resistant shoe material |
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