Mild inirritative makeup remover and preparation method thereof
Technical field
The present invention relates to cosmetic fields, in particular to a kind of mild inirritative makeup remover and preparation method thereof.
Background technique
With the development of make-up technique, cosmetics play increasingly important role in people's daily life.But
It is after face makeup, if do not removed thoroughly, remaining cosmetics can cause the pore of skin of face to block, and lead to skin oil and fat
Water oil dyssecretosis makes us the skin problem of puzzlement so as to cause acne, acne and blackhead etc..Meanwhile the residual pair of cosmetics
There is a great harm for skin, if cannot clean out in time, asking for tumour can be formed into hair follicle with the breathing of pore
Topic, long-term existence are just difficult to clear up away again in skin surface.So the makeup removing link of skin is particularly significant, makeup removal products
Selection be at this moment just particularly important.
Makeup removal products are mainly include the following types: 1, bubble face facial cleanser: relying primarily on the clear of surfactant component therein
Clean ability is removed ornaments and formal dress;2, makeup remover: using the similar principle to mix, pass through vegetable oil (such as olive oil) or other shapes phase
As grease type remove ornaments and formal dress, the disadvantage is that the phenomenon that being not thorough and causing quick-fried acne that may remove ornaments and formal dress;3, make-up remover: make-up remover is applied to face
Mixture is formed with cosmetics behind portion, after adding water gently to rub emulsification, emulsifier can allow the make-up remover for being mixed with cosmetics to be dissolved in water;4,
Makeup removing breast: blending to obtain by emulsifier and surfactant by water phase and oil, and the cleaning force of makeup removing breast depends on formula;5,
Makeup remover: it is removed ornaments and formal dress by the principle of Micellar Solubilization.
Wherein, makeup remover is becoming the selection of more and more consumers, and the quality of makeup remover is all relatively salubriouser, there is side taste
Profit, the feeling of side makeup removing, are suitble to large area makeup removing.Makeup remover is by the dirt on the water insoluble ingredients and skin in product
In conjunction with achieving the purpose that quickly to remove ornaments and formal dress.Compared to other products, most of moisture in makeup remover can also guarantee the aqueous of skin
Amount, enables the salubrious water of skin tender.
The evaluation index of makeup removal products essentially consists in makeup removing ability and mild degree the two indexs, and current makeup remover is more
Using raw materials systems such as olive oil PEG-7 esters, propylene glycol, PEG-6 caprylic/capric glyceride type, PEG-7 glyceryl cocoates
Make, the enough mild but makeup removing effects of the makeup remover or product for being applied alone these raw materials to make are bad or product makeup removing effect can
It is larger still to stimulate.
In view of this, the present invention is specifically proposed.
Summary of the invention
The first object of the present invention is to provide a kind of makeup remover, to alleviate makeup remover makeup removing ability and temperature in the prior art
The technical issues of cannot being combined with degree.
The second object of the present invention is to provide a kind of preparation method of above-mentioned makeup remover.
In order to realize above-mentioned purpose of the invention, the following technical scheme is adopted:
A kind of mild inirritative makeup remover, includes: preservative A0.05%-0.5%, preservative B by weight percentage
0.05%-0.3%, permeation enhancers 0.1%-2%, detergent 1%-10%, moisturizer 1%-10% and emollient 0.5%-
5%, surplus is water.
Further, by weight percentage include: preservative A 0.1%-0.4%, preservative B0.1%-0.3%, promote
Bleeding agent 0.5%-2%, detergent 2%-9%, moisturizer 2%-9% and emollient 1%-4%, surplus are water.
Further, by weight percentage include: preservative A 0.1%-0.3%, preservative B0.1%-0.2%, promote
Bleeding agent 1%-2%, detergent 3%-8%, moisturizer 3%-8% and emollient 1%-3%, surplus are water.
Further, the preservative A includes at least one of methyl hydroxybenzoate or parahydroxyacet-ophenone, preferably oxybenzene
Methyl esters.
Further, the preservative B include in Chlorphenesin, cetrimonium chloride, cetrimonium bromide or Cetylpyridinium Chloride at least
One kind, preferably Chlorphenesin.
Further, the permeation enhancers include at least one of sodium chloride or potassium chloride, preferably sodium chloride.
Further, the detergent includes poloxamer 184, PLURONICS F87, poloxamer 237, poloxamer
At least one of 338 or poloxamer188, preferably poloxamer 184.
Further, the moisturizer includes at least one of D-sorbite, glycerol, propylene glycol or butanediol, preferably
For D-sorbite.
Further, the emollient include PEG-6 caprylic/capric glyceride type, PEG-7 caprylic/capric glyceride type,
PEG-8 caprylic/capric glyceride type, olive oil PEG-7 esters, olive oil PEG-6 esters, olive oil PEG-8 esters or PEG-7
At least one of glyceryl cocoate, preferably PEG-6 caprylic/capric glyceride type.
The preparation method of above-mentioned makeup remover, according to weight percent by preservative A, preservative B, permeation enhancers, detergent,
Moisturizer and emollient are added in aqueous solvent, are uniformly mixed and are obtained the makeup remover.
Compared with prior art, the invention has the benefit that
Mild inirritative makeup remover provided by the invention, includes: preservative A0.05%- by weight percentage
0.5%, preservative B 0.05%-0.3%, permeation enhancers 0.1%-2%, detergent 1%-10%, moisturizer 1%-10% and
Emollient 0.5%-5%, surplus are water.Detergent and emollient coordinated use in the makeup remover, can be to oiliness, aqueous
Optimal removal effect is played with the cosmetics of powder;Permeation enhancers and the rational proportion of moisturizer are added can be good to skin
Skin moisturizing adjusts the osmotic pressure of makeup remover simultaneously, reduces detergent and emollient to the stimulation of skin;Two kinds of preservative associations
The usage amount of preservative can be reduced with use, while guaranteeing effective anti-corrosion, improves the stability of makeup remover, reduces makeup remover pair
The stimulation of skin.It is thorough, right to have reached makeup removing by the effect of rational proportion and synergy between each component for the makeup remover
The small good result of skin irritatin, suitable for the crowd of all kinds of skin, even sensitive flesh is also suitable.In addition, the makeup remover
Raw material is easy to get extensively, and preparation is simple, significantly reduces production cost.
The preparation method of makeup remover provided by the invention is simple to operation, complicated process flow, the cost such as does not heat
It is low, it is easy to large-scale production.
Specific embodiment
Embodiment of the present invention is described in detail below in conjunction with embodiment, but those skilled in the art will
Understand, the following example is merely to illustrate the present invention, and is not construed as limiting the scope of the invention.It is not specified in embodiment specific
Condition person carries out according to conventional conditions or manufacturer's recommended conditions.
A kind of mild inirritative makeup remover, includes: preservative A0.05%-0.5%, preservative B by weight percentage
0.05%-0.3%, permeation enhancers 0.1%-2%, detergent 1%-10%, moisturizer 1%-10% and emollient 0.5%-
5%, surplus is water.
Detergent and emollient coordinated use in the makeup remover, can rise to oiliness, aqueous and powder cosmetics
To optimal removal effect;Permeation enhancers and the rational proportion of moisturizer are added good to adjust simultaneously to skin moisture-keeping and unload
The osmotic pressure of adornment water reduces detergent and emollient to the stimulation of skin;Two kinds of preservative collaboration uses can reduce anti-
The usage amount of rotten agent, while guaranteeing effective anti-corrosion, the stability of makeup remover is improved, stimulation of the makeup remover to skin is reduced.This is unloaded
Adornment water by rational proportion between each component and synergistic effect, reached makeup removing thoroughly, it is small to skin irritatin good
Good effect, suitable for the crowd of all kinds of skin, even sensitive flesh is also suitable.In addition, the raw material of the makeup remover is easy to get extensively, system
It is standby simple, significantly reduce production cost.Wherein, water is deionized water.
It should be noted that by weight percentage, it is 0.05% that preservative A is typical but non-limiting, 0.1%,
0.2%, 0.3%, 0.4% or 0.5%;It is 0.05% that preservative B is typical but non-limiting, 0.1%, 0.2%, 0.3%,
0.4% or 0.5%;Typical but non-limiting permeation enhancers are 0.1%, 0.5%, 1%, 1.5% or 2%;Detergent is typical
But unrestricted is 1%, 2%, 3%, 4%, 5%, 6%, 7%, 8%, 9% or 10%;Moisturizer is typical but non-limiting
It is 1%, 2%, 3%, 4%, 5%, 6%, 7%, 8%, 9% or 10%;It is 0.5% that emollient is typical but non-limiting,
1%, 1.5%, 2%, 3%, 4% or 5%.
In the present invention, one is preferably carried out in mode, by weight percentage includes: preservative A0.1%-0.4%, anti-
Rotten agent B 0.1%-0.3%, permeation enhancers 0.5%-2%, detergent 2%-9%, moisturizer 2%-9% and emollient 1%-
4%, surplus is water.
At the present invention one more preferably in embodiment, include: by weight percentage preservative A0.1%-0.3%,
Preservative B 0.1%-0.2%, permeation enhancers 1%-2%, detergent 3%-8%, moisturizer 3%-8% and emollient 1%-
3%, surplus is water.Component and proportion to makeup remover are further optimized and are limited, so that the makeup removing ability of makeup remover
It is further improved with two performances of mild degree, collaboration is optimal effect.
In certain embodiments of the present invention, preservative A includes at least one in methyl hydroxybenzoate or parahydroxyacet-ophenone
Kind, preferably methyl hydroxybenzoate.
In certain embodiments of the present invention, preservative B includes Chlorphenesin, cetrimonium chloride, cetrimonium bromide or western pyrrole
At least one of oronain, preferably Chlorphenesin.
The makeup remover reaches collaboration corrosion-resistant purpose by the way that two kinds of preservatives are added, and is unlikely to deteriorate, compared to largely adding
Add a kind of preservative, not only reduced the usage amount of preservative but also improve the stability of makeup remover, in addition, also reducing makeup remover
To the stimulation of skin.Wherein the coordinated of methyl hydroxybenzoate and Chlorphenesin uses, and anti-corrosion effect is best, the product of makeup remover
Matter is best, simultaneously because the price of the two is more cheap, production cost is relatively low.
In certain embodiments of the present invention, detergent includes poloxamer 184, PLURONICS F87, poloxamer
237, at least one of Pluronic/Lutrol F 108 or poloxamer188, preferably poloxamer 184.
In certain embodiments of the present invention, emollient include PEG-6 caprylic/capric glyceride type, PEG-7 octanoic acid/
Glycerol decanoate class, PEG-8 caprylic/capric glyceride type, olive oil PEG-7 esters, olive oil PEG-6 esters, olive oil
At least one of PEG-8 esters or PEG-7 glyceryl cocoate, preferably PEG-6 caprylic/capric glyceride type.
The rational proportion of detergent and emollient is added, by the two coordinated, so that the makeup remover is to cosmetics
It unloads removing solid capacity to reach most preferably, all has for oiliness, aqueous and mealiness all kinds of cosmetics and good unload removing solid capacity.Especially moor
Luo Shamu 184 and PEG caprylic/capric glyceride type are used cooperatively, and the ideal cost simultaneously of makeup removing effect is controllable.
In certain embodiments of the present invention, permeation enhancers include at least one of sodium chloride or potassium chloride, preferably
For sodium chloride.The addition of permeation enhancers can effectively adjust the osmotic pressure of makeup remover, so that makeup remover is milder, to skin
Irritation greatly reduce.
In certain embodiments of the present invention, moisturizer include in D-sorbite, glycerol, propylene glycol or butanediol extremely
Few one kind, preferably D-sorbite.Moisturizer is a kind of hydrophilic Emollient materials, has in lower humidity range and combines water
Ability, keep the skin wet to skin, by control product and surrounding air between moisture exchange make skin maintain be higher than just
The equilibrium state of ordinary water content plays the role of mitigating dry skin.The addition of moisturizer can reduce makeup remover to skin
Stimulation.
In the present invention, one is preferably carried out in mode, and a kind of mild inirritative makeup remover is wrapped by weight percentage
It includes: methyl hydroxybenzoate 0.05%-0.5%, Chlorphenesin 0.05%-0.3%, sodium chloride 0.1%-2%, 184 1%- of poloxamer
10%, D-sorbite 1%-10% and PEG-6 caprylic/capric glyceride type 0.5%-5%, surplus is water.The group of the makeup remover
Divide and proportion is rationally scientific, makeup removing ability and mild degree are taken into account, and have reached good effect, while cost is controllable, cost performance
It is high.
A kind of preparation method of mild inirritative makeup remover seeps preservative A, preservative B, rush according to weight percent
Saturating agent, detergent, moisturizer and emollient are added in aqueous solvent, are uniformly mixed and are obtained makeup remover.The preparation method is simply easy
Operation such as does not heat at the complicated process flow, at low cost, is easy to large-scale production.
The technical solution provided to facilitate the understanding of the present invention, below with reference to embodiment to technical solution provided by the invention
It is further described.
Embodiment 1
The present embodiment provides a kind of mild inirritative makeup removers, by weight percentage include: parahydroxyacet-ophenone
0.05%, cetrimonium chloride 0.3%, potassium chloride 0.1%, PLURONICS F87 10%, glycerol 1% and PEG-7 caprylic/capric glycerol
Esters 5%, surplus are water.
Embodiment 2
The present embodiment provides a kind of mild inirritative makeup remover, include: by weight percentage methyl hydroxybenzoate 0.5%,
Cetrimonium bromide 0.05%, sodium chloride 2%, poloxamer 237 1%, propylene glycol 10% and PEG-8 caprylic/capric glyceride type
0.5%, surplus is water.
Embodiment 3
The present embodiment provides a kind of mild inirritative makeup remover, include: by weight percentage methyl hydroxybenzoate 0.1%,
Cetylpyridinium Chloride 0.3%, potassium chloride 0.5%, Pluronic/Lutrol F 108 9%, butanediol 2% and olive oil PEG-7 esters 4%, surplus
For water.
Embodiment 4
The present embodiment provides a kind of mild inirritative makeup remover, include: by weight percentage methyl hydroxybenzoate 0.4%,
Chlorphenesin 0.1%, sodium chloride 2%, poloxamer188 2%, glycerol 9% and olive oil PEG-6 esters 1%, surplus is water.
Embodiment 5
The present embodiment provides a kind of mild inirritative makeup remover, include: by weight percentage methyl hydroxybenzoate 0.1%,
Chlorphenesin 0.2%, sodium chloride 1%, poloxamer 184 8%, D-sorbite 3% and olive oil PEG-8 esters 3%, surplus
For water.
Embodiment 6
The present embodiment provides a kind of mild inirritative makeup remover, include: by weight percentage methyl hydroxybenzoate 0.3%,
Chlorphenesin 0.1%, sodium chloride 2%, poloxamer 184 3%, D-sorbite 8% and PEG-7 glyceryl cocoate 1%, it is remaining
Amount is water.
Embodiment 7
The present embodiment provides a kind of mild inirritative makeup remover, include: by weight percentage methyl hydroxybenzoate 0.2%,
Chlorphenesin 0.15%, sodium chloride 1.5%, poloxamer 184 5%, D-sorbite 6% and PEG-6 caprylic/capric glyceride
Class 2%, surplus are water.
Comparative example 1
This comparative example provides a kind of makeup remover, by weight percentage includes: methyl hydroxybenzoate 0.2%, Chlorphenesin
0.15%, poloxamer 184 5%, D-sorbite 6% and PEG-6 caprylic/capric glyceride type 2%, surplus is water.
Compared with Example 7, lack sodium chloride.
Comparative example 2
This comparative example provides a kind of makeup remover, include: by weight percentage Chlorphenesin 0.15%, sodium chloride 1.5%,
Poloxamer 184 5%, D-sorbite 6% and PEG-6 caprylic/capric glyceride type 2%, surplus is water.
Compared with Example 7, lack methyl hydroxybenzoate.
Comparative example 3
This comparative example provides a kind of makeup remover, include: by weight percentage methyl hydroxybenzoate 0.2%, sodium chloride 1.5%,
Poloxamer 184 5%, D-sorbite 6% and PEG-6 caprylic/capric glyceride type 2%, surplus is water.
Compared with Example 7, lack Chlorphenesin.
Comparative example 4
This comparative example provides a kind of makeup remover, by weight percentage includes: methyl hydroxybenzoate 0.2%, Chlorphenesin
0.15%, sodium chloride 1.5%, D-sorbite 6% and PEG-6 caprylic/capric glyceride type 2%, surplus is water.
Compared with Example 7, lack poloxamer 184.
Comparative example 5
This comparative example provides a kind of makeup remover, by weight percentage includes: methyl hydroxybenzoate 0.2%, Chlorphenesin
0.15%, sodium chloride 1.5%, poloxamer 184 5% and PEG-6 caprylic/capric glyceride type 2%, surplus is water.
Compared with Example 7, lack D-sorbite.
Comparative example 6
This comparative example provides a kind of makeup remover, by weight percentage includes: methyl hydroxybenzoate 0.2%, Chlorphenesin
0.15%, sodium chloride 1.5%, poloxamer 184 5% and D-sorbite 6%, surplus are water.
Compared with Example 7, lack PEG-6 caprylic/capric glyceride type.
Comparative example 7
This comparative example provides a kind of makeup remover, by weight percentage includes: methyl hydroxybenzoate 0.01%, Chlorphenesin
0.4%, sodium chloride 0.15%, poloxamer 184 12%, D-sorbite 0.2% and PEG-6 caprylic/capric glyceride type 7%,
Surplus is water.
The component proportion of this comparative example is different from embodiment 7.
Comparative example 8
This comparative example provides a kind of makeup remover, by weight percentage includes: methyl hydroxybenzoate 0.7%, Chlorphenesin
0.03%, sodium chloride 5%, poloxamer 184 0.3%, D-sorbite 15% and PEG-6 caprylic/capric glyceride type 0.4%,
Surplus is water.
The component proportion of this comparative example is different from embodiment 7.
Comparative example 9
This comparative example provides a kind of makeup remover, according to parts by weight includes: polyoxyethylene (4) sorbitan monolaurate 30
Part, 25 parts of sorbierite, 0.5 part of sodium chloride, to 12 parts of methylparaben, 7 parts of citric acid, 400 parts of deionized water, ethylenediamine tetraacetic
2 parts of acetic acid disodium.
Comparative example 10
This comparative example provides a kind of makeup remover, by weight percentage includes: poloxamer 184 5%, glycerol 8%, β-
1,3-D- glucan 3%, polyaminopropyl biguanide 0.2%, essence 0.01%, water surplus.
Comparative example 11
This comparative example provides a kind of makeup remover, by weight percentage includes: Natrulon H-10 laurate 10%, two
(PPG-2 nutmeg oleth -10) adipate ester 2.5%, 1,3- propylene glycol 7%, EDETATE SODIUM 0.05%, allantoin
0.12%, dipropylene glycol 2.5%, glycerol 2.5%, polyaminopropyl biguanide 0.2%, water surplus.
1 physical and chemical testing of test example
Physical and chemical testing is carried out according to common detection methods in row to the makeup remover in each embodiment, the results showed that the present invention is each
Makeup remover items physical and chemical index in embodiment is qualified.
The mild degree of test example 2 and makeup removing aptitude tests
100 testers, including oiliness, stemness, Combination and sensitive flesh crowd are randomly selected, everyone is to embodiment
Makeup remover in 1-7 and comparative example 1-11 carry out it is applicable, using interval one week between each product, to each makeup remover according to unloading
Adornment effect is good, makeup removing effect is general and makeup removing effect is bad;It does not stimulate mildly, medium stimulation (can endure) and serious stimulation
(being impatient at) is evaluated, and result on trial is counted, and statistics is as shown in the table:
Makeup remover in 1-7 of the embodiment of the present invention it can be seen from the data in upper table is in makeup removing ability and mild degree
Good affirmative has all been obtained in two performances, there is good effect.It is compared, compares with the makeup remover in embodiment 7
Lack sodium chloride in example 1, although the makeup removing ability of makeup remover can achieve preferable effect, but strong to the irritation of skin;
Comparative example 2 has lacked methyl hydroxybenzoate, and although the makeup removing ability of makeup remover can achieve preferable effect, but the stabilization of makeup remover
Property reduce, therefore mild degree reduces;Comparative example 3 has lacked Chlorphenesin, and the stability of same makeup remover reduces, and influences mild
Degree;Poloxamer 184 is lacked in comparative example 4, ability of removing ornaments and formal dress and all different degrees of variation of mild degree;In comparative example 5
D-sorbite is lacked, makeup remover enhances the irritation of skin, and makeup removing ability also declines;It is pungent PEG-6 has been lacked in comparative example 6
Acid/glycerol decanoate class, the makeup removing ability and mild degree of makeup remover all decline;The compositional range and embodiment of comparative example 7 and 8
7 is different, and two performances are also affected.The combination and its proportion for illustrating each component in makeup remover of the invention are all scientific and reasonable
, common coordinative role obtains the good result that makeup removing ability and mild degree are taken into account.
Further analysis shows that makeup remover performance of the makeup remover of the embodiment of the present invention 1-7 than comparative example 9-11 will
It is good, illustrate that makeup remover of the invention has certain advantage, it is applied widely, while component is common, it is at low cost.
Although illustrate and describing the present invention with specific embodiment, it will be appreciated that without departing substantially from of the invention
Many other change and modification can be made in the case where spirit and scope.It is, therefore, intended that in the following claims
Including belonging to all such changes and modifications in the scope of the invention.