CN109456844A - A kind of preparation and application of paintbrush brush cleaning solution and cleaning solution - Google Patents
A kind of preparation and application of paintbrush brush cleaning solution and cleaning solution Download PDFInfo
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- CN109456844A CN109456844A CN201811258358.9A CN201811258358A CN109456844A CN 109456844 A CN109456844 A CN 109456844A CN 201811258358 A CN201811258358 A CN 201811258358A CN 109456844 A CN109456844 A CN 109456844A
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- Prior art keywords
- cleaning solution
- paintbrush
- preparation
- isopropanol
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/825—Mixtures of compounds all of which are non-ionic
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B43—WRITING OR DRAWING IMPLEMENTS; BUREAU ACCESSORIES
- B43K—IMPLEMENTS FOR WRITING OR DRAWING
- B43K13/00—Devices for removing nibs; Devices for cleaning nibs, e.g. by wiping
- B43K13/02—Devices for removing nibs; Devices for cleaning nibs, e.g. by wiping for cleaning nibs, e.g. ink reservoirs therein
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2006—Monohydric alcohols
- C11D3/2017—Monohydric alcohols branched
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2086—Hydroxy carboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/30—Amines; Substituted amines ; Quaternized amines
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/33—Amino carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/008—Polymeric surface-active agents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/82—Compounds containing silicon
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Inorganic Chemistry (AREA)
- Detergent Compositions (AREA)
Abstract
The invention discloses a kind of paintbrush brush cleaning solutions, it is characterized in that, it is composed of the following raw materials by weight: triethanolamine: 20-25 parts, citric acid: 2-20 parts, amino silicone oil emulsifying agent: 5-12 parts, isomeric alcohol polyethenoxy ether: 5-15 parts, nonylphenol polyoxyethylene ether: 8-12 parts, isopropanol: 15-30 parts, tetrasodium ethylenediamine tetraacetate: 4-9 parts, strontium titanates: 10-20 parts.Using technical solution of the present invention, not only cleaning effect is clean, also has self-cleaning function, effectively drop environmental pollution.
Description
Technical field
The present invention relates to the preparation of cleaning solution technical field more particularly to a kind of paintbrush brush cleaning solution and cleaning solution and make
Use method.
Background technique
Writing brush, oil painting brush are indispensable tool in calligraphy and paintings, and impurity is contained inside prepared Chinese ink, pigment and is had viscous
Property, pen milli can be made to gather a large amount of impurity over time, pen is made to lose toughness, pen milli also becomes black because containing prepared Chinese ink, pigment
Color or other colors, therefore need thoroughly to be cleaned after use every time.However after existing cleaning solution has cleaned paintbrush,
Often there is a small amount of residual on paintbrush, use next time is impacted.In addition, containing pigment in cleaning solution after use, without place
Reason will cause pollution after pouring into lower pond, also beautiful to cause pond dyeing to influence after accumulating over a long period.
Summary of the invention
Technical problems based on background technology, the invention proposes the systems of a kind of paintbrush brush cleaning solution and cleaning solution
Standby and application method, not only cleaning effect is clean, also has self-cleaning function, effectively drop environmental pollution.
A kind of paintbrush brush cleaning solution proposed by the present invention, is composed of the following raw materials by weight:
A kind of preparation method of paintbrush brush cleaning solution, comprising the following steps:
(1) by isopropanol, triethanolamine, isomeric alcohol polyethenoxy ether, nonylphenol polyoxyethylene ether and ethylenediamine tetra-acetic acid
Four sodium are once added to the mixer, and are uniformly mixed；
(2) citric acid is added dropwise dropwise into mixing machine, obtains mixed liquor, adjusting ph value of mixture is 6.5-7；
(3) by strontium titanates in isopropanol ultrasound 30-60min, obtain dispersion liquid, then the dispersion liquid is added to described mixed
It closes in liquid, stirs evenly；
(4) amino silicone oil emulsifying agent is finally added into mixing machine, continues to stir, the final cleaning solution.
Preferably, the cleaning solution is composed of the following raw materials by weight:
Preferably, the strontium titanates partial size is 10-100nm.
Preferably, the strontium titanates is the modified strontium titanates of sulfur doping.
Preferably, the volume ratio of isopropanol is 2-10 in isopropanol and step (3) in step (1).
A kind of application method of paintbrush brush cleaning solution, comprising the following steps: by the cleaning solution and water with 0.01-0.5
Volume ratio be uniformly mixing to obtain dilution after cleaning solution, by the brush of paintbrush to be cleaned in interior be put into dilution after cleaning solution
Middle immersion 1-30min, is cleaned, and then the cleaning solution after paintbrush and dilution is moved on to sun-drenched outdoor together, stood
30-90min, the cleaning of paintbrush brush are completed.
Preferably, the water is deionized water.
Cleaning solution clean and effective obtained by technical solution of the present invention can effectively remove the organic pigment on paintbrush.?
Strontium titanates is added in cleaning solution and makees photochemical catalyst, light source deficiency catalytic activity is low almost without reaction indoors, and cleaning terminates
It moves back the sufficient place of outdoor solar light and stands irradiation, strontium titanates remain on photocatalytic degradation brush organic pigment and clear
Pigment in washing lotion waste liquid substantially reduces the pigment content in cleaning solution waste liquid, reduces dirty to the dip dyeing degree and environment in pond
Dye, while the efficient cleaning capacity of cleaning solution and low-residual characteristic avoid color residual accumulation on brush and excessively have to more
The problem of changing improves the service life of brush.Strontium titanates is modified through sulfur doping, and the strontium titanates energy band on the one hand changed increases
Its light absorption range improves sun light utilization efficiency, and on the other hand, sulfur doping leads to a large amount of defects of strontium titanate crystals Surface Creation and oxygen
Vacancy greatly improves the catalytic activity of strontium titanates, is conducive to the degradation of organic pigment.System is steady in technical solution of the present invention
Fixed, without side reaction between each component, the modified strontium titanates of sulfur doping is to remaining each component without degradation, wherein triethanolamine
It is both the sacrifice agent of organic solvent and light degradation reaction, citric acid regulating solution pH value while also has the work of sacrifice agent
With triethanolamine and being used cooperatively for citric acid have effectively facilitated photocatalytic activity.
Specific embodiment
In the following, technical solution of the present invention is described in detail by specific embodiment.Agents useful for same is equal in embodiment
For routine test or commercially available gained.
Embodiment 1:
A kind of paintbrush brush cleaning solution, is composed of the following raw materials by weight:
A kind of preparation method of paintbrush brush cleaning solution, comprising the following steps:
(1) by isopropanol, triethanolamine, isomeric alcohol polyethenoxy ether, nonylphenol polyoxyethylene ether and ethylenediamine tetra-acetic acid
Four sodium are once added to the mixer, and are uniformly mixed；
(2) citric acid is added dropwise dropwise into mixing machine, obtains mixed liquor, adjusting ph value of mixture is 7；
(3) by the modified strontium titanates ultrasound 60min in isopropanol of sulfur doping that partial size is 10-100nm, dispersion liquid is obtained, then
The dispersion liquid is added in the mixed liquor, is stirred evenly；
(4) amino silicone oil emulsifying agent is finally added into mixing machine, continues to stir, the final cleaning solution；Wherein, it walks
Suddenly the volume ratio of isopropanol is 10 in isopropanol and step (3) in (1).
A kind of application method of paintbrush brush cleaning solution, comprising the following steps: by the cleaning solution and deionized water with 0.5
Volume ratio be uniformly mixing to obtain dilution after cleaning solution, by the brush of paintbrush to be cleaned in interior be put into dilution after cleaning solution
Middle immersion 30min, is cleaned, and then the cleaning solution after paintbrush and dilution is moved on to sun-drenched outdoor together, stood
90min, the cleaning of paintbrush brush are completed.
Embodiment 2:
A kind of paintbrush brush cleaning solution, is composed of the following raw materials by weight:
A kind of preparation method of paintbrush brush cleaning solution, comprising the following steps:
(1) by isopropanol, triethanolamine, isomeric alcohol polyethenoxy ether, nonylphenol polyoxyethylene ether and ethylenediamine tetra-acetic acid
Four sodium are once added to the mixer, and are uniformly mixed；
(2) citric acid is added dropwise dropwise into mixing machine, obtains mixed liquor, adjusting ph value of mixture is 6.5；
(3) by the modified strontium titanates ultrasound 30min in isopropanol of sulfur doping that partial size is 10-100nm, dispersion liquid is obtained, then
The dispersion liquid is added in the mixed liquor, is stirred evenly；
(4) amino silicone oil emulsifying agent is finally added into mixing machine, continues to stir, the final cleaning solution；Wherein, it walks
Suddenly the volume ratio of isopropanol is 2 in isopropanol and step (3) in (1).
A kind of application method of paintbrush brush cleaning solution, comprising the following steps: by the cleaning solution and deionized water with
0.01 volume ratio is uniformly mixing to obtain the cleaning solution after dilution, and the brush of paintbrush to be cleaned is clear after interior is put into dilution
1min is impregnated in washing lotion, is cleaned, and then the cleaning solution after paintbrush and dilution is moved on into sun-drenched outdoor together, stood
30min, the cleaning of paintbrush brush are completed.
Embodiment 3:
A kind of paintbrush brush cleaning solution, is composed of the following raw materials by weight:
A kind of preparation method of paintbrush brush cleaning solution, comprising the following steps:
(1) by isopropanol, triethanolamine, isomeric alcohol polyethenoxy ether, nonylphenol polyoxyethylene ether and ethylenediamine tetra-acetic acid
Four sodium are once added to the mixer, and are uniformly mixed；
(2) citric acid is added dropwise dropwise into mixing machine, obtains mixed liquor, adjusting ph value of mixture is 6.4；
(3) by the modified strontium titanates ultrasound 40min in isopropanol of sulfur doping that partial size is 10-100nm, dispersion liquid is obtained, then
The dispersion liquid is added in the mixed liquor, is stirred evenly；
(4) amino silicone oil emulsifying agent is finally added into mixing machine, continues to stir, the final cleaning solution；Wherein, it walks
Suddenly the volume ratio of isopropanol is 6 in isopropanol and step (3) in (1).
A kind of application method of paintbrush brush cleaning solution, comprising the following steps: by the cleaning solution and deionized water with
0.05 volume ratio is uniformly mixing to obtain the cleaning solution after dilution, and the brush of paintbrush to be cleaned is clear after interior is put into dilution
20min is impregnated in washing lotion, is cleaned, and the cleaning solution after paintbrush and dilution is then moved on into sun-drenched outdoor together, it is quiet
50min is set, the cleaning of paintbrush brush is completed.
Test case:
A kind of random commercially available cleaning solution is chosen to make to ratio, Example 1, embodiment 2 and 3 gained cleaning solution of embodiment into
Row test, prepares certain density methyl orange solution, and four identical paintbrushes take out after being immersed in methyl orange solution same time,
It is cleaned respectively with embodiment 1, embodiment 2, embodiment 3 and commercially available cleaning solution with identical cleaning method, is demarcated respectively
Methyl orange concentration, and methyl orange concentration is demarcated within 1 hour again in sun-drenched outdoor standing, methyl orange degradation rate is calculated, together
When compare the cleannes of four paintbrush brushes, obtained result is as shown in the table:
The foregoing is only a preferred embodiment of the present invention, but scope of protection of the present invention is not limited thereto,
Anyone skilled in the art in the technical scope disclosed by the present invention, according to the technique and scheme of the present invention and its
Inventive concept is subject to equivalent substitution or change, should be covered by the protection scope of the present invention.
Claims (8)
1. a kind of paintbrush brush cleaning solution, which is characterized in that be composed of the following raw materials by weight:
2. a kind of preparation method of paintbrush brush cleaning solution, which comprises the following steps:
(1) by isopropanol, triethanolamine, isomeric alcohol polyethenoxy ether, nonylphenol polyoxyethylene ether and tetrasodium ethylenediamine tetraacetate
It is once added to the mixer, is uniformly mixed；
(2) citric acid is added dropwise dropwise into mixing machine, obtains mixed liquor, adjusting ph value of mixture is 6.5-7；
(3) by strontium titanates in isopropanol ultrasound 30-60min, obtain dispersion liquid, then the dispersion liquid is added to the mixed liquor
In, it stirs evenly；
(4) amino silicone oil emulsifying agent is finally added into mixing machine, continues to stir, the final cleaning solution.
3. the preparation method of paintbrush brush cleaning solution according to claim 2, which is characterized in that the cleaning solution is by following
Raw material composition:
4. the preparation method of paintbrush brush cleaning solution according to claim 2 or 3, which is characterized in that the strontium titanates grain
Diameter is 10-100nm.
5. the preparation method of paintbrush brush cleaning solution according to claim 4, which is characterized in that the strontium titanates is mixed for sulphur
Miscellaneous modified strontium titanates.
6. the preparation method of paintbrush brush cleaning solution according to claim 4, which is characterized in that isopropanol in step (1)
Volume ratio with isopropanol in step (3) is 2-10.
7. a kind of application method of paintbrush brush cleaning solution according to claim 1, which is characterized in that including following step
It is rapid: the cleaning solution and water to be uniformly mixing to obtain the cleaning solution after dilution with the volume ratio of 0.01-0.5, by paintbrush to be cleaned
Brush in interior be put into dilution after cleaning solution in impregnate 1-30min, cleaned, then by paintbrush and dilution after cleaning
Liquid moves on to sun-drenched outdoor together, stands 30-90min, and the cleaning of paintbrush brush is completed.
8. the application method of paintbrush brush cleaning solution according to claim 7, which is characterized in that the water is deionization
Water.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811258358.9A CN109456844A (en) | 2018-10-26 | 2018-10-26 | A kind of preparation and application of paintbrush brush cleaning solution and cleaning solution |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811258358.9A CN109456844A (en) | 2018-10-26 | 2018-10-26 | A kind of preparation and application of paintbrush brush cleaning solution and cleaning solution |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN109456844A true CN109456844A (en) | 2019-03-12 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201811258358.9A Pending CN109456844A (en) | 2018-10-26 | 2018-10-26 | A kind of preparation and application of paintbrush brush cleaning solution and cleaning solution |
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| CN (1) | CN109456844A (en) |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20070225185A1 (en) * | 2006-03-22 | 2007-09-27 | Fujifilm Corporation | Ink washing liquid and cleaning method |
| CN103080293A (en) * | 2010-07-23 | 2013-05-01 | 中村正一 | Detergent |
| CN103756400A (en) * | 2014-01-10 | 2014-04-30 | 戴新育 | Quick cleaning fluid for writing brush |
| CN104307538A (en) * | 2014-10-13 | 2015-01-28 | 东南大学 | Preparation and application methods of high-efficiency composite photocatalytic material |
| CN107502463A (en) * | 2017-08-03 | 2017-12-22 | 广东富利达羽绒制品有限公司 | A kind of feather cleaning agent and its application method |
-
2018
- 2018-10-26 CN CN201811258358.9A patent/CN109456844A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20070225185A1 (en) * | 2006-03-22 | 2007-09-27 | Fujifilm Corporation | Ink washing liquid and cleaning method |
| CN103080293A (en) * | 2010-07-23 | 2013-05-01 | 中村正一 | Detergent |
| CN103756400A (en) * | 2014-01-10 | 2014-04-30 | 戴新育 | Quick cleaning fluid for writing brush |
| CN104307538A (en) * | 2014-10-13 | 2015-01-28 | 东南大学 | Preparation and application methods of high-efficiency composite photocatalytic material |
| CN107502463A (en) * | 2017-08-03 | 2017-12-22 | 广东富利达羽绒制品有限公司 | A kind of feather cleaning agent and its application method |
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Application publication date: 20190312 |