CN109453612A - A kind of preparation method of air cleaning sponge - Google Patents

A kind of preparation method of air cleaning sponge Download PDF

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Publication number
CN109453612A
CN109453612A CN201810433982.1A CN201810433982A CN109453612A CN 109453612 A CN109453612 A CN 109453612A CN 201810433982 A CN201810433982 A CN 201810433982A CN 109453612 A CN109453612 A CN 109453612A
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air cleaning
cleaning sponge
preparation
carbon
air
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CN201810433982.1A
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胡朝霞
袁定胜
韦丽成
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Foshan City Hi Tech Dhc Technology Co Ltd
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Foshan City Hi Tech Dhc Technology Co Ltd
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Priority to CN201810433982.1A priority Critical patent/CN109453612A/en
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D46/00Filters or filtering processes specially modified for separating dispersed particles from gases or vapours
    • B01D46/0027Filters or filtering processes specially modified for separating dispersed particles from gases or vapours with additional separating or treating functions
    • B01D46/0036Filters or filtering processes specially modified for separating dispersed particles from gases or vapours with additional separating or treating functions by adsorption or absorption
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D46/00Filters or filtering processes specially modified for separating dispersed particles from gases or vapours
    • B01D46/10Particle separators, e.g. dust precipitators, using filter plates, sheets or pads having plane surfaces
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/40Nitrogen compounds
    • B01D2257/406Ammonia
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/70Organic compounds not provided for in groups B01D2257/00 - B01D2257/602
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/70Organic compounds not provided for in groups B01D2257/00 - B01D2257/602
    • B01D2257/702Hydrocarbons
    • B01D2257/7027Aromatic hydrocarbons
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/70Organic compounds not provided for in groups B01D2257/00 - B01D2257/602
    • B01D2257/708Volatile organic compounds V.O.C.'s
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2258/00Sources of waste gases
    • B01D2258/06Polluted air
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A50/00TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
    • Y02A50/20Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters
    • Y02A50/2351Atmospheric particulate matter [PM], e.g. carbon smoke microparticles, smog, aerosol particles, dust

Abstract

The invention belongs to air purification fields, specifically disclose a kind of preparation method of air cleaning sponge, by the way that polyether polyol, water, tertiary amine compounds, silicone oil, plant essence, active powdered carbon, toluene di-isocyanate(TDI), tin catalyst are stirred foaming by a certain percentage, required size is sliced into after curing, obtain air cleaning sponge, can be in fields such as fresh air system, air purifier, car filters system, air-conditionings as air purifying filter mesh application, PARA FORMALDEHYDE PRILLS(91,95), toluene, ammonia, TVOC and particulate matter have good clean-up effect.Air cleaning sponge prepared by the present invention, while the detergent power for giving full play to active carbon, with smaller windage, overcome that existing active carbon filling filter screen column-shaped active carbon hole utilization rate is not high and folder carbon cloth strainer activated carbon content lacks the big disadvantage of windage.

Description

A kind of preparation method of air cleaning sponge
Technical field
The invention belongs to air purification fields, and in particular to a kind of preparation method of air cleaning sponge.
Background technique
This problem of indoor pollution causes the attention of people in recent years, and room air pollution refers to be led due to various reasons Harmful substance is exceeded in the room air of cause, and then influences the indoor environmental pollution behavior of human health.Nuisance include formaldehyde, Benzene, ammonia, radioactive radon etc..As pollution level is aggravated, human body can generate inferior health reaction or even threaten life security.It is day One of human body harm that benefit is taken seriously.
People daily an average of about 80% or more time spend indoors.It is more existing with life style with producing Dai Hua, more work and sports entertainment can all carry out indoors, and shopping need not also go into the street daily, suitable indoor small Weather makes people that need not often arrive outdoor de-regulation fuel factor, in this way, the indoor activity time of people with regard to more, even as high as 93% or more.Therefore, indoor air quality just seems more closely more important to the relationship of human health.Indoor pollution source is very It is more, such as wallpaper, family property, furniture, solid wooden floor board etc., although the concentration of indoor pollutant is often lower, when due to contact Between it is very long, therefore its accumulate exposure it is very high.Especially the elderly, young, sick, disabled and other frail people, Abwehrkraft des Koepers be lower, outdoor activities Chance is less, and therefore, the fine or not relationship with them of indoor air quality is particularly important.In addition to indoor pollution, in automobile Automotive air pollution also can not be ignored, and the toxic and harmful gas such as formaldehyde, toluene, ammonia that new car is discharged are often exceeded.
For indoor and auto-pollution gas purification, a product of comparative maturity is air purifier, air at present The strainer that clarifier uses is active carbon filling filter screen or folder carbon cloth filter screen.The scavenging material that filled type filter screen uses It is mostly column-shaped active carbon, column-shaped active carbon is can not to play activity completely by the way that Powdered Activated Carbon kneading to be granulated The high-specific surface area of charcoal and high porosity, thus purification efficiency is caused to reduce.What folder carbon cloth filter screen used is mostly 60 mesh The active carbon particle of left and right is got up by upper layer and lower layer electrostatic cotton cladding, and every square metre of activated carbon content is few, and windage mistake Greatly, clean-up effect is influenced.
Summary of the invention
To overcome existing active carbon to fill, filter screen column-shaped active carbon hole utilization rate is not high and folder carbon cloth strainer is active Carbon content lacks the big disadvantage of windage, the primary purpose of the present invention is that providing a kind of preparation method of air cleaning sponge.The sky Gas, which purifies sponge PARA FORMALDEHYDE PRILLS(91,95), toluene, ammonia, TVOC and particulate matter, has good clean-up effect, is giving full play to active carbon While detergent power, there is smaller windage.
The present invention be solve the problems, such as it is set forth above used by technical solution are as follows:
A kind of preparation method of air cleaning sponge, the technical scheme comprises the following steps:
(1) it by polyethers ethylene glycol, water, triethylene diamine, silicone oil, plant essence, active powdered carbon, is stirred in mold Uniformly, referred to as the first component;
(2) it by toluene di-isocyanate(TDI), stannous octoate, stirs evenly, referred to as the second component;
(3) the second component is poured into rapidly in the first component mold and is mixed, high-speed stirred 5-15s, the foam-in-mould time 1min or so cures 0.5-2h, is cut into required size then to get air cleaning sponge is arrived.
In the present invention, various raw materials its parts by weight in step (1) are respectively: polyether polyol dosage is 80-120 Part, water consumption are 2-8 parts, tertiary amine compounds dosage is 0.1-0.5 parts, silicon oil dosage is 0.5-3 parts, plant essence dosage is 0.1-4 parts, active powdered carbon dosage be 5-50 parts, toluene di-isocyanate(TDI) dosage is 30-90 parts, the dosage of tin catalyst is 0.1-0.5 parts.Preferably, polyethers ethylene glycol, water, triethylene diamine, silicone oil, plant essence, active powdered carbon, in step (2) Toluene di-isocyanate(TDI), stannous octoate optimum weight number ratio be 100 parts: 5 parts: 0.22 part: 1.52 parts: 1 part: 25 Part: 60 parts: 0.24 parts.
In the present invention, the polyethers ethylene glycol in step (1) can be replaced by polyethers glycerine etc., and the degree of functionality of the two is in 2- Between 3, molecular weight is between 2800-3200, between hydroxyl value 54-58.
In the present invention, the triethylene diamine in step (1) can be by the tertiary amine compounds generation such as triethanolamine, triethylamine It replaces.
In the present invention, it includes cocoanut active charcoal, ring that the active carbon in step (1), which is the active carbon powder of 150-200 mesh, Active carbon, coaly activated carbon, active fruit shell carbon etc., can by graphene oxide, graphene, tourmaline, sepiolite, photocatalyst, Diatom ooze etc. is one such or a variety of replacements.
In the present invention, mixing time described in step (1) is 10-30s.
In the present invention, mixing time described in step (2) is 5-15s.
In the present invention, stannous octoate described in step (2) can be replaced by dibutyl tin.
In the present invention, high-speed stirred described in step (3), mixing speed 800-1000r/min, mixing time 5- 15s;The foam-in-mould time be 30-90s.
In the present invention, polyethers ethylene glycol, water, triethylene diamine, silicone oil, toluene di-isocyanate(TDI), stannous octoate are poly- The various raw materials of urethane sponge production, creative addition activity powdered carbon during production can be by active powdered carbon and poly- ammonia Ester sponge is effectively compound, and active powdered carbon is evenly distributed in the porous structure of sponge, further increase active carbon with The contact area of air, thus its clean-up effect to toxic and harmful gas in air can be improved.In addition, the air after compound is net Changing sponge aperture can be controlled by feed ratio, to have the function that purify solid particulate matter in air.
Compared with prior art, the present invention has the following advantages and beneficial effects:
Firstly, air cleaning sponge prepared by the present invention has more while the detergent power for giving full play to active carbon Small windage, overcomes that existing active carbon filling filter screen column-shaped active carbon hole utilization rate is not high and folder carbon cloth strainer activity Carbon content lacks the big disadvantage of windage.
Secondly, compared with existing filled type active carbon filter screen and folder carbon cloth strainer, in the activity using phase homogenous quantities When charcoal, air cleaning sponge prepared by the present invention can not only efficiently use the high porosity of active carbon, guarantee activated carbon content Also there is lower windage, PARA FORMALDEHYDE PRILLS(91,95), toluene, ammonia, TVOC and particulate matter have good clean-up effect, substantially while high The purification efficiency of active carbon is improved, it can be in fields such as fresh air system, air purifier, car filters system, air-conditionings as empty Gas purifies strainer application.
Detailed description of the invention
Fig. 1 is air cleaning sponge pictorial diagram made from embodiment 1.
Fig. 2 is active carbon filled type filter screen pictorial diagram made from comparative example 1.
Fig. 3, which is that comparative example 2 is obtained, presss from both sides carbon cloth filter screen pictorial diagram.
Fig. 4 is air cleaning sponge made from embodiment 1, active carbon filled type filter screen, comparative example made from comparative example 1 The adsorption rate curve of 2 folder carbon cloth filter screen PARA FORMALDEHYDE PRILLS(91,95)s obtained compares figure.
Fig. 5 is air cleaning sponge made from embodiment 1, active carbon filled type filter screen, comparative example made from comparative example 1 2 folder carbon cloth filter screens obtained compare figure to the adsorption rate curve of toluene.
Fig. 6 is air cleaning sponge made from embodiment 1, active carbon filled type filter screen, comparative example made from comparative example 1 The windage of 2 folder carbon cloth filter screens obtained compares figure.
Specific embodiment
For a better understanding of the present invention, below with reference to the embodiment content that the present invention is furture elucidated, but the present invention is not It is limited only to the following examples.
The degree of functionality of polyethers ethylene glycol, polyethers glycerine employed in following embodiments is in 2-3, and molecular weight is in 2800- Between 3200, between hydroxyl value 54-58.
Active carbon in following embodiments is the active carbon powder of 150-200 mesh, includes cocoanut active charcoal, ring activity Charcoal, coaly activated carbon, active fruit shell carbon etc., can be by graphene oxide, graphene, tourmaline, sepiolite, photocatalyst, diatom Mud etc. is one such or a variety of replacements.
Embodiment 1
A kind of preparation method of air cleaning sponge, comprising the following steps:
(1) it by polyethers ethylene glycol, water, triethylene diamine, silicone oil, plant essence, the coconut activated powdered carbon of 200 mesh, is stirring 20s, referred to as the first component are stirred in machine;By toluene di-isocyanate(TDI), stannous octoate, stirred in another blender 10s, referred to as the second component;Wherein, polyethers ethylene glycol, water, triethylene diamine, silicone oil, plant essence, active powdered carbon, toluene Diisocyanate, stannous octoate weight part ratio be 100 parts: 5 parts: 0.22 part: 1.52 parts: 1 part: 25 part: 60 parts: 0.24 Part;
(2) the second component is poured into rapidly the first component stirrer for mixing, with mixing speed for 800-1000r/min high Speed stirring 10s, is then transferred into foamed time 1min in foaming mould, cures 2h, be then cut into required size using slicer, Obtain the air cleaning sponge.
Cut size are as follows: length × width × height=30cm × 20cm × 3cm air cleaning sponge (is calculated active carbon to contain Measure about 100g), as shown in Figure 1.It places it on and is provided by Shunde joint Huang Shi Science and Technology Ltd., model KB818 Air purifier in, PARA FORMALDEHYDE PRILLS(91,95), toluene purification efficiency tested, test chamber 30m3Standard test cabin;Meanwhile to sky Gas purifies sponge and carries out windage test.Using gas chromatography test result show the sponge 10min, 20min, 30min, When 40min, 50min, 60min, the concentration of formaldehyde is respectively by 1.00mg/m3Drop to 0.52mg/m3、0.32mg/m3、0.18mg/ m3、0.10mg/m3、0.06mg/m3、0.04mg/m3;The concentration of toluene is respectively from 1.00mg/m3Drop to 0.49mg/m3、0.29mg/ m3、0.18mg/m3、0.12mg/m3、0.08mg/m3、0.07mg/m3;Windage is 4.5Pa.
Comparative example 1: the column cocoanut active charcoal of 100g is weighed, is filled in size are as follows: length × width × height=30cm × In the cellular board of 20cm × 3cm, it is made into filled type filter screen, as shown in Figure 2.PARA FORMALDEHYDE PRILLS(91,95), first under the conditions of same as Example 1 The purification efficiency and windage of benzene are tested.Using gas chromatography test result show the sponge 10min, 20min, When 30min, 40min, 50min, 60min, the concentration of formaldehyde is respectively by 1.00mg/m3Drop to 0.87mg/m3、0.71mg/m3、 0.55mg/m3、0.51mg/m3、0.47mg/m3、0.43mg/m3;The concentration of toluene is respectively by 1.00mg/m3Drop to 0.80mg/m3、 0.62mg/m3、0.54mg/m3、0.47mg/m3、0.43mg/m3、0.40mg/m3;Windage is 3.0Pa.
Comparative example 2: cutting length × width × height=30cm × 20cm × 3cm folder carbon cloth 20, and every phosphorus content is about 5g, It is as shown in Figure 3 to press from both sides carbon cloth.PARA FORMALDEHYDE PRILLS(91,95), the purification efficiency of toluene and windage are tested under the conditions of same as Example 1.It adopts With gas chromatography test result show the sponge in 10min, 20min, 30min, 40min, 50min, 60min, formaldehyde Concentration is respectively by 1.00mg/m3Drop to 0.92mg/m3、0.85mg/m3、0.81mg/m3、0.77mg/m3、0.76mg/m3、 0.75mg/m3;The concentration of toluene is respectively by 1.00mg/m3Drop to 0.93mg/m3、0.88mg/m3、0.84mg/m3、0.83mg/m3、 0.81mg/m3、0.78mg/m3;Windage is 18.5Pa.
The above air cleaning sponge, filled type filter screen, press from both sides three kinds of filter screens of carbon cloth formaldehyde removal rate compare such as Fig. 4 institute Show, formaldehyde removal rate is air cleaning sponge strainer, active carbon filled type strainer, folder respectively from high to low as we can see from the figure Carbon cloth filter screen, wherein for air cleaning sponge filter screen in 60min, concentration of formaldehyde is from 1.00mg/m3Fall below 0.04mg/m3, Removal rate has reached 96%, significantly larger than active carbon filled type strainer and folder carbon cloth filter screen.
The above air cleaning sponge, filled type filter screen, press from both sides three kinds of filter screens of carbon cloth toluene removal rate compare such as Fig. 5 institute Show, toluene removal rate is air cleaning sponge strainer, activity respectively from high to low as we can see from the figure Charcoal filled type strainer, folder carbon cloth filter screen, wherein for air cleaning sponge filter screen in 60min, toluene concentration is from 1.00mg/m3 Drop to 0.07mg/m3, removal rate reached 93%, significantly larger than active carbon filled type strainer and folder carbon cloth filter screen.
The above air cleaning sponge (embodiment 1), filled type filter screen (comparative example 1), folder carbon cloth (comparative example 2) three kinds of mistakes The windage of strainer compares as shown in fig. 6, windage size is folder carbon cloth filter screen, air respectively from high to low as we can see from the figure Purify sponge strainer, active carbon filled type strainer.The windage for wherein pressing from both sides carbon cloth filter screen has reached 18.5Pa, therefore air can not Quickly circulation, thus its clean-up effect is poor;Column-shaped active carbon filled type strainer windage is minimum, and only 3.0Pa, air can be fast Speed flowing, but since column-shaped active carbon is unable to give full play the suction-operated of active carbon, thus influence its clean-up effect;This hair The windage of the bright air cleaning sponge is 4.5Pa, and air can normally circulate, because active carbon powder is attached on sponge, sponge Pore structure greatly increase the contact area of active carbon, and there is lesser windage, thus there is very high clean-up effect.
Embodiment 2
A kind of preparation method of air cleaning sponge, comprising the following steps:
(1) it by polyethers ethylene glycol, water, triethylene diamine, silicone oil, plant essence, the coconut activated powdered carbon of 100 mesh, is stirring 20s, referred to as the first component are stirred in machine;By toluene di-isocyanate(TDI), stannous octoate, stirred in another blender 10s, referred to as the second component.Wherein polyethers ethylene glycol, water, triethylene diamine, silicone oil, plant essence, active powdered carbon, toluene two Isocyanates, stannous octoate weight part ratio be 100 parts: 5 parts: 0.22 part: 1.52 parts: 1 part: 25 part: 60 parts: 0.24 Part;
(2) the second component is poured into rapidly the first component stirrer for mixing, with mixing speed for 800-1000r/min high Speed stirring 10s, is then transferred into foamed time 1min in foaming mould, cures 2h, be then cut into required size using slicer, That is the air cleaning sponge.
Under the conditions of same as Example 1, the air cleaning sponge properties of embodiment 2 are tested.The air Sponge is purified in 60min, the concentration of formaldehyde is respectively by 1.00mg/m3Drop to 0.14mg/m3;The concentration of toluene respectively from 1.00mg/m3Drop to 0.16mg/m3;Windage is 4.2Pa.
Embodiment 3
A kind of preparation method of air cleaning sponge, comprising the following steps:
(1) by polyethers ethylene glycol, water, triethylene diamine, silicone oil, plant essence, the coconut activated powdered carbon of 60 mesh, in blender Inside it is stirred 20s, referred to as the first component;By toluene di-isocyanate(TDI), stannous octoate, 10s is stirred in another blender, Referred to as the second component.Wherein polyethers ethylene glycol, water, triethylene diamine, silicone oil, plant essence, active powdered carbon, toluene diisocyanate Acid esters, stannous octoate weight part ratio be 100 parts: 5 parts: 0.22 part: 1.52 parts: 1 part: 25 part: 60 parts: 0.24 parts;
(2) the second component is poured into rapidly the first component stirrer for mixing, high-speed stirred 10s is then transferred into foaming Foam-in-mould time 1min cures 2h, is then cut into required size using slicer to get extra large to the air cleaning It is continuous.
Under the conditions of same as Example 1, the air cleaning sponge properties of embodiment 3 are tested.The air Sponge is purified in 60min, the concentration of formaldehyde is respectively by 1.00mg/m3Drop to 0.18mg/m3;The concentration of toluene respectively from 1.00mg/m3Drop to 0.22mg/m3;Windage is 3.8Pa.
Embodiment 4
A kind of preparation method of air cleaning sponge, comprising the following steps:
(1) it by polyethers ethylene glycol, water, triethylene diamine, silicone oil, plant essence, the coconut activated powdered carbon of 200 mesh, is stirring 20s, referred to as the first component are stirred in machine;By toluene di-isocyanate(TDI), stannous octoate, stirred in another blender 10s, referred to as the second component.Wherein polyethers ethylene glycol, water, triethylene diamine, silicone oil, plant essence, active powdered carbon, toluene two Isocyanates, stannous octoate weight part ratio be 100 parts: 5 parts: 0.22 part: 1.52 parts: 1 part: 50 part: 60 parts: 0.24 Part;
(2) the second component is poured into rapidly the first component stirrer for mixing, with mixing speed for 800-1000r/min high Speed stirring 10s, is then transferred into foamed time 1min in foaming mould, cures 2h, be then cut into required size using slicer, Obtain the air cleaning sponge.
Under the conditions of same as Example 1, the air cleaning sponge properties of embodiment 4 are tested.The air Sponge is purified in 60min, the concentration of formaldehyde is respectively by 1.00mg/m3Drop to 0.12mg/m3;The concentration of toluene respectively from 1.00mg/m3Drop to 0.13mg/m3;Windage is 7.8Pa.
Embodiment 5
A kind of preparation method of air cleaning sponge, comprising the following steps:
(1) it by polyethers ethylene glycol, water, triethylene diamine, silicone oil, plant essence, the coconut activated powdered carbon of 200 mesh, is stirring 20s, referred to as the first component are stirred in machine;By toluene di-isocyanate(TDI), stannous octoate, stirred in another blender 10s, referred to as the second component.Wherein polyethers ethylene glycol, water, triethylene diamine, silicone oil, plant essence, active powdered carbon, toluene two Isocyanates, stannous octoate weight part ratio be 100 parts: 5 parts: 0.22 part: 1.52 parts: 1 part: 5 part: 60 parts: 0.24 parts
(2) the second component is poured into rapidly the first component stirrer for mixing, with mixing speed for 800-1000r/min high Speed stirring 10s, is then transferred into foamed time 1min in foaming mould, cures 2h, be then cut into required size using slicer, Obtain the air cleaning sponge.
Under the conditions of same as Example 1, the air cleaning sponge properties of embodiment 5 are tested.The air Sponge is purified in 60min, the concentration of formaldehyde is respectively by 1.00mg/m3Drop to 0.28mg/m3;The concentration of toluene respectively from 1.00mg/m3Drop to 0.30mg/m3;Windage is 3.1Pa.
The above embodiment is a preferred embodiment of the present invention, and wherein embodiment (1) is preferred embodiment, but reality of the invention Apply mode and be not restricted to the described embodiments, it is other it is any without departing from the spirit and principles of the present invention made by change Become, modification, substitution, combination, simplify, should be equivalent substitute mode, be included within the scope of the present invention.

Claims (10)

1. a kind of preparation method of air cleaning sponge, which comprises the following steps:
(1) it by polyether polyol, water, tertiary amine compounds, silicone oil, plant essence, active powdered carbon, is stirred in mold, Referred to as the first component;
(2) toluene di-isocyanate(TDI), tin catalyst are stirred evenly, referred to as the second component;
(3) the second component is poured into rapidly in the first component mold and is mixed, after high-speed stirred, through foam-in-mould and cured Obtain air cleaning sponge.
2. a kind of preparation method of air cleaning sponge according to claim 1, which is characterized in that poly- in step (1) Ethoxylated polyhydric alcohol mainly includes one or both of polyethers ethylene glycol, polyethers glycerine.
3. a kind of preparation method of air cleaning sponge according to claim 1, which is characterized in that the uncle in step (1) Aminated compounds mainly includes one of triethylene diamine, triethanolamine, triethylamine or a variety of.
4. a kind of preparation method of air cleaning sponge according to claim 1, which is characterized in that the work in step (1) Property charcoal be 150-200 mesh active carbon powder, include cocoanut active charcoal, ring active carbon, coaly activated carbon, active fruit shell carbon Deng;Active carbon or by one of graphene oxide, graphene, tourmaline, sepiolite, photocatalyst, diatom ooze or a variety of generations It replaces.
5. a kind of preparation method of air cleaning sponge according to claim 1, which is characterized in that described in step (1) Mixing time is 10-30s;Mixing time described in step (2) is 5-15s.
6. a kind of preparation method of air cleaning sponge according to claim 1, which is characterized in that described in step (2) Tin catalyst mainly includes one or both of stannous octoate, dibutyl tin.
7. a kind of preparation method of air cleaning sponge according to claim 1, which is characterized in that described in step (3) High-speed stirred, mixing time 5-15s, mixing speed 800-1000r/min, foam-in-mould time are 30-90s.
8. a kind of preparation method of air cleaning sponge according to claim 1, which is characterized in that described in step (3) Curing time is 0.5-5h.
9. a kind of preparation method of air cleaning sponge according to claim 1, which is characterized in that its weight of a variety of materials Number is respectively: polyether polyol dosage is 80-120 parts, water consumption is 2-8 parts, tertiary amine compounds dosage is 0.1-0.5 Part, silicon oil dosage are 0.5-3 parts, plant essence dosage is 0.1-4 parts, active powdered carbon dosage is 5-50 parts, toluene diisocynate Ester dosage is 30-90 parts, the dosage of tin catalyst is 0.1-0.5 parts.
10. application of the air cleaning sponge as air purifying filter mesh prepared by claim 1.
CN201810433982.1A 2018-05-08 2018-05-08 A kind of preparation method of air cleaning sponge Pending CN109453612A (en)

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Cited By (1)

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Publication number Priority date Publication date Assignee Title
CN113912816A (en) * 2021-11-13 2022-01-11 深圳前海石墨烯产业有限公司 Graphene polyurethane composite sponge material and preparation method and application thereof

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