CN109439461B - Preparation and application of special washing-free decontamination product for fluffy fabric - Google Patents
Preparation and application of special washing-free decontamination product for fluffy fabric Download PDFInfo
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- CN109439461B CN109439461B CN201811295117.1A CN201811295117A CN109439461B CN 109439461 B CN109439461 B CN 109439461B CN 201811295117 A CN201811295117 A CN 201811295117A CN 109439461 B CN109439461 B CN 109439461B
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- polyoxyethylene ether
- fluffy
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- 239000004744 fabric Substances 0.000 title claims abstract description 79
- 238000005202 decontamination Methods 0.000 title claims abstract description 18
- 230000003588 decontaminative effect Effects 0.000 title claims abstract description 18
- 238000002360 preparation method Methods 0.000 title claims abstract description 18
- 239000003599 detergent Substances 0.000 claims abstract description 49
- 238000004140 cleaning Methods 0.000 claims abstract description 32
- 229920000742 Cotton Polymers 0.000 claims abstract description 25
- 108090000790 Enzymes Proteins 0.000 claims abstract description 19
- 102000004190 Enzymes Human genes 0.000 claims abstract description 19
- 239000002904 solvent Substances 0.000 claims abstract description 15
- 239000002216 antistatic agent Substances 0.000 claims abstract description 13
- 239000004067 bulking agent Substances 0.000 claims abstract description 4
- 229940051841 polyoxyethylene ether Drugs 0.000 claims description 53
- 229920000056 polyoxyethylene ether Polymers 0.000 claims description 53
- XFRVVPUIAFSTFO-UHFFFAOYSA-N 1-Tridecanol Chemical compound CCCCCCCCCCCCCO XFRVVPUIAFSTFO-UHFFFAOYSA-N 0.000 claims description 36
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 33
- 229920002545 silicone oil Polymers 0.000 claims description 33
- XMGQYMWWDOXHJM-JTQLQIEISA-N (+)-α-limonene Chemical compound CC(=C)[C@@H]1CCC(C)=CC1 XMGQYMWWDOXHJM-JTQLQIEISA-N 0.000 claims description 32
- 239000003795 chemical substances by application Substances 0.000 claims description 23
- 238000003756 stirring Methods 0.000 claims description 23
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 21
- 239000000203 mixture Substances 0.000 claims description 20
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 19
- 239000004367 Lipase Substances 0.000 claims description 17
- 102000004882 Lipase Human genes 0.000 claims description 17
- 108090001060 Lipase Proteins 0.000 claims description 17
- 229920002678 cellulose Polymers 0.000 claims description 17
- 239000001913 cellulose Substances 0.000 claims description 17
- 125000005456 glyceride group Chemical group 0.000 claims description 17
- POOYFSLWYLDQMD-UHFFFAOYSA-N heptacalcium;zinc Chemical compound [Ca+2].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[Zn+2] POOYFSLWYLDQMD-UHFFFAOYSA-N 0.000 claims description 17
- 235000019421 lipase Nutrition 0.000 claims description 17
- 238000000034 method Methods 0.000 claims description 17
- 230000007935 neutral effect Effects 0.000 claims description 17
- 239000001397 quillaja saponaria molina bark Substances 0.000 claims description 17
- 229930182490 saponin Natural products 0.000 claims description 17
- 150000007949 saponins Chemical class 0.000 claims description 17
- 229950000112 serrapeptase Drugs 0.000 claims description 17
- 108010038132 serratiopeptidase Proteins 0.000 claims description 17
- BWDBEAQIHAEVLV-UHFFFAOYSA-N 6-methylheptan-1-ol Chemical compound CC(C)CCCCCO BWDBEAQIHAEVLV-UHFFFAOYSA-N 0.000 claims description 16
- 241001122767 Theaceae Species 0.000 claims description 16
- VUFOSBDICLTFMS-UHFFFAOYSA-M ethyl-hexadecyl-dimethylazanium;bromide Chemical compound [Br-].CCCCCCCCCCCCCCCC[N+](C)(C)CC VUFOSBDICLTFMS-UHFFFAOYSA-M 0.000 claims description 16
- 239000004902 Softening Agent Substances 0.000 claims description 14
- OCBHHZMJRVXXQK-UHFFFAOYSA-M benzyl-dimethyl-tetradecylazanium;chloride Chemical group [Cl-].CCCCCCCCCCCCCC[N+](C)(C)CC1=CC=CC=C1 OCBHHZMJRVXXQK-UHFFFAOYSA-M 0.000 claims description 14
- 238000005507 spraying Methods 0.000 claims description 10
- WWZKQHOCKIZLMA-UHFFFAOYSA-N octanoic acid Chemical compound CCCCCCCC(O)=O WWZKQHOCKIZLMA-UHFFFAOYSA-N 0.000 claims description 8
- 230000000149 penetrating effect Effects 0.000 claims description 8
- 230000007480 spreading Effects 0.000 claims description 8
- 238000003892 spreading Methods 0.000 claims description 8
- 238000005406 washing Methods 0.000 claims description 7
- 239000000853 adhesive Substances 0.000 claims description 6
- 230000001070 adhesive effect Effects 0.000 claims description 6
- 239000002245 particle Substances 0.000 claims description 4
- 230000008569 process Effects 0.000 claims description 2
- 239000002689 soil Substances 0.000 claims description 2
- 230000000052 comparative effect Effects 0.000 description 30
- 239000008367 deionised water Substances 0.000 description 15
- 229910021641 deionized water Inorganic materials 0.000 description 15
- 238000012360 testing method Methods 0.000 description 12
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 6
- 230000000694 effects Effects 0.000 description 6
- 238000004806 packaging method and process Methods 0.000 description 6
- 238000007789 sealing Methods 0.000 description 6
- 230000035699 permeability Effects 0.000 description 5
- 239000012496 blank sample Substances 0.000 description 4
- 239000000945 filler Substances 0.000 description 4
- 230000035515 penetration Effects 0.000 description 4
- 239000012792 core layer Substances 0.000 description 3
- 239000012466 permeate Substances 0.000 description 3
- 229920002635 polyurethane Polymers 0.000 description 3
- 239000004814 polyurethane Substances 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 238000004383 yellowing Methods 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 230000009471 action Effects 0.000 description 2
- 239000004480 active ingredient Substances 0.000 description 2
- 239000003125 aqueous solvent Substances 0.000 description 2
- 239000012752 auxiliary agent Substances 0.000 description 2
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 2
- DLFDEDJIVYYWTB-UHFFFAOYSA-N dodecyl(dimethyl)azanium;bromide Chemical compound Br.CCCCCCCCCCCCN(C)C DLFDEDJIVYYWTB-UHFFFAOYSA-N 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 230000036541 health Effects 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000002357 osmotic agent Substances 0.000 description 2
- 238000001179 sorption measurement Methods 0.000 description 2
- 230000002195 synergetic effect Effects 0.000 description 2
- 238000010998 test method Methods 0.000 description 2
- 239000004642 Polyimide Substances 0.000 description 1
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 1
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 1
- 102100035329 WD repeat and SOCS box-containing protein 2 Human genes 0.000 description 1
- 101710182039 WD repeat and SOCS box-containing protein 2 Proteins 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000003373 anti-fouling effect Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000003115 biocidal effect Effects 0.000 description 1
- 239000012459 cleaning agent Substances 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 238000004332 deodorization Methods 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- 239000008157 edible vegetable oil Substances 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 238000007667 floating Methods 0.000 description 1
- 235000012041 food component Nutrition 0.000 description 1
- 239000005417 food ingredient Substances 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000002085 irritant Substances 0.000 description 1
- 231100000021 irritant Toxicity 0.000 description 1
- 239000010410 layer Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000002052 molecular layer Substances 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920001721 polyimide Polymers 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 230000002335 preservative effect Effects 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 239000000523 sample Substances 0.000 description 1
- 229910000077 silane Inorganic materials 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 235000019333 sodium laurylsulphate Nutrition 0.000 description 1
- 235000013555 soy sauce Nutrition 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/835—Mixtures of non-ionic with cationic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/04—Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
- C11D17/049—Cleaning or scouring pads; Wipes
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/18—Hydrocarbons
- C11D3/188—Terpenes
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2006—Monohydric alcohols
- C11D3/201—Monohydric alcohols linear
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/373—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicones
- C11D3/3742—Nitrogen containing silicones
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
- C11D3/38627—Preparations containing enzymes, e.g. protease or amylase containing lipase
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
- C11D3/38645—Preparations containing enzymes, e.g. protease or amylase containing cellulase
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/008—Polymeric surface-active agents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/62—Quaternary ammonium compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/662—Carbohydrates or derivatives
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/667—Neutral esters, e.g. sorbitan esters
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
- C11D2111/10—Objects to be cleaned
- C11D2111/12—Soft surfaces, e.g. textile
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Detergent Compositions (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The invention discloses preparation and application of a special washing-free decontamination article for fluffy fabrics, and belongs to the field of detergents. The no-clean detergent prepared by the invention comprises 45-55 parts of penetrant, 15-25 parts of softener, 8-16 parts of bulking agent, 10-20 parts of enzyme preparation, 4-12 parts of antistatic agent and 872-918 parts of solvent, wherein the softness and bulkiness of the detergent are both more than 4.5 grades, and the detergent can be used together with cleaning cotton to clean bulky fabrics without damaging whiteness of the bulky fabrics.
Description
Technical Field
The invention relates to preparation and application of a special washing-free decontamination article for fluffy fabrics, and belongs to the field of detergents.
Background
In modern life, people often neglect the internal cleaning of a large class of fabrics when washing clothes, cloth and other household articles. Especially for bulky fabrics such as fluffy fabrics with an inner core layer, such as sofas, pillows, bedding, plush toys, etc., people are used to wash only the outer covers, but rarely care about cleaning the pillow core layer, the sofa core layer, the insides of the bedding and the toy fillings. This operation, which only focuses on "surface engineering", leaves a great risk. Because the inside of the fluffy fabric is loose and porous, the fluffy fabric can easily absorb some harmful substances, stains, peculiar smell and the like, and obviously influences the use experience of people and is more harmful to the body health of people if the fluffy fabric is left without being subjected to decontamination and odor removal treatment.
However, if the internal filler of the bulky fabric is washed by water in a common household, the operation is inconvenient, the bulky fabric is ineffective for large sofa fillers, bedding fillers and the like, and the bulky fabric is easy to shrink and lose the bulky feeling after being dried. Therefore, if a washing-free detergent for fluffy fabrics exists, the problems can be well solved by applying the detergent only externally regardless of the size of the fabrics or even without detaching the outer sleeves of the fabrics, namely, the detergent can permeate into the fluffy fabrics and can completely clean the fluffy fabrics from inside to outside.
Disclosure of Invention
In order to achieve the purpose, the invention provides a special washing-free decontamination article for fluffy fabrics, which consists of a special washing-free decontamination agent for the fluffy fabrics and cleaning cotton. When the detergent is used, the detergent is sprayed on surface stains, and after 10-30 seconds, the surface stains of the fabric are removed by wiping and adsorbing with cleaning cotton; and then continuously spraying the detergent at the original position, covering the original spot position with the spraying range, placing another piece of clean cleaning cotton at the corresponding position on the back of the fabric, and gradually absorbing the detergent by the cleaning cotton. After the product is used, the fabric is fragrant and free from peculiar smell, and is softer and fluffy.
The invention provides a washing-free detergent which comprises 45-55 parts of penetrating agent, 15-25 parts of softening agent, 8-16 parts of bulking agent, 10-20 parts of enzyme preparation, 4-12 parts of antistatic agent and 872-918 parts of solvent, wherein the penetrating agent comprises isooctanol polyoxyethylene ether JFC-3, isomeric tridecanol polyoxyethylene ether TO-6, isomeric tridecanol polyoxyethylene ether E-1005 and tea saponin; the softening agent comprises polyether-amino modified silicone oil and hexadecyl dimethyl ethyl ammonium bromide; the fluffing agent is fluffy smooth silicone oil; the enzyme preparation comprises neutral lipase, serrapeptase and cellulose complex enzyme; the antistatic agent is tetradecyl dimethyl benzyl ammonium chloride; the solvent comprises hydrophilic caprylic capric glyceride, water, d-limonene and ethanol.
In one embodiment of the invention, 16-19 parts of isooctanol polyoxyethylene ether JFC-3, 11.5-14 parts of isomeric tridecanol polyoxyethylene ether TO-6, 10-12.5 parts of isomeric tridecanol polyoxyethylene ether E-1005 and 7.5-9.5 parts of tea saponin in the penetrant respectively.
In one embodiment of the present invention, the softening agent contains 6 to 11 parts of polyether-amino modified silicone oil and 9 to 14 parts of hexadecyl dimethyl ethyl ammonium bromide.
In one embodiment of the invention, the enzyme preparation comprises 5.5-10.5 parts of neutral lipase, 2.5-5.5 parts of serrapeptase and 2-4 parts of cellulose complex enzyme.
In one embodiment of the present invention, the solvent comprises 80 to 88 parts of hydrophilic caprylic/capric glyceride, 530 to 545 parts of hydrophilic caprylic/capric glyceride, 117 to 128 parts of hydrophilic d-limonene and 145 to 157 parts of hydrophilic ethanol.
Secondly, the invention also provides a preparation method of the no-clean detergent, which comprises the following steps: adding 45-55 parts of penetrating agent, 15-25 parts of softening agent and 8-16 parts of bulking agent into a container, adding 872-918 parts of solvent, uniformly stirring, adding 10-20 parts of enzyme preparation and 4-12 parts of antistatic agent, and homogenizing at the rotating speed of 600-1000 rpm for 2-5 min to obtain the no-clean detergent.
Thirdly, the invention also provides a special washing-free stain removal article for fluffy fabrics, which comprises the washing-free stain removal agent and cleaning cotton, wherein the cleaning cotton is prepared by the following method: respectively spreading activated carbon particles on one surface of each of the two super sponge pieces with the groove to ensure that the spreading density is 350-450 g/m2And bonding the surfaces of the two sponges paved with the activated carbon together by using an adhesive.
In one embodiment of the present invention, the super sponge is a sponge made of polyurethane or polyimide plastic with a molecular layer of amphiphilic silane attached to the surface.
In one embodiment of the invention, the adhesive is a polyurethane adhesive.
Fourthly, the invention provides a method for washing-free decontamination of fluffy fabrics, which comprises the following steps: spraying the no-clean detergent on surface stains, wiping and adsorbing the no-clean detergent by using cleaning cotton after 10-30 s, and removing the stains on the surface of the fabric; and then continuously spraying the non-washing detergent to enable the spraying range to cover the position where the original stain is located, placing another piece of clean cleaning cotton on the corresponding position of the back of the fabric, and obtaining the fabric after the detergent is completely absorbed by the cleaning cotton.
In one embodiment of the invention, the cleaning cotton is prepared by the following method: are respectively atUniformly spreading activated carbon particles on one surface of the two super sponge pieces with the groove to ensure that the spreading density is 350-450 g/m2And bonding the surfaces of the two sponges paved with the activated carbon together by using an adhesive.
In one embodiment of the invention, the fluffy fabric comprises a pillow, a sofa, a bedding, a plush toy and the like, and also comprises a relatively light and thin fabric such as a down jacket, a sweater, a scarf and the like.
In one embodiment of the present invention, the water is preferably deionized water.
The invention has the following beneficial effects:
1. the special washing-free decontamination article for the fluffy fabric has wide application range, and has good decontamination and deodorization effects on relatively light and thin fabrics such as down jackets, sweaters, scarves and the like besides fluffy fabrics such as pillows, sofas, bedding, plush toys and the like.
2. The solvent in the detergent is mainly low-viscosity aqueous solvent, and the penetrant is fixedly mixed, so that the detergent is endowed with excellent permeability; the penetrant mainly comprises isomeric alcohol polyoxyethylene ether, the carbon chain length of the penetrant is 8-12, the molecular weight is small, the EO number is small, so the penetrant is rapid in penetration and layered, and can be suitable for fluffy fabrics made of various materials; in addition, the permeability of the detergent is improved due to the coordination of the proportions of the penetrants, the uniformity and stability of the solvent environment and the synergistic effect of other additives, so that the detergent can quickly permeate through the outer fabric, can permeate down in the inner fluffy filler quickly and intensively, and ensures that cleaning cotton can accurately absorb stains above the fabric to spray the permeated detergent, so that the effects of decontamination and odor removal are more targeted and thorough; the detergent does not need to be pressed on the fabric in the downward penetration process, and the detergent has the penetration speed of 5-8cm/min in the fluffy fabric through testing, so that the detergent can penetrate very quickly.
3. The main components in the cleaning cotton of the washing-free decontamination article special for the fluffy fabric are the activated carbon and the super sponge, so the washing-free decontamination article has strong adsorption force on decontaminating agents, stains, peculiar smell and the like, and has large adsorption capacity, and tests show that about 1g of cleaning cotton can absorb more than 50g of decontamination solvent, so the decontamination capability is strong.
4. According to the special washing-free decontamination article for the fluffy fabric, a proper amount of fluffy agent and softening agent are added into the decontaminating agent, so that the cleaned fabric can be endowed with fluffy hand feeling and good elasticity after being thoroughly dried, and the original appearance can be kept and even the elasticity and softness of the fabric can be restored to the original state no matter the surface of the fabric is a fluffy structure or the internal fluffy structure; the detergent of the no-clean detergent article specially used for the fluffy fabric is also added with a proper amount of antistatic agent, and the antistatic agent has a strong antistatic effect on the outer cover of the fabrics such as chemical fibers, cotton and linen, and the like, which are commonly adopted by the fluffy fabric, so that the surface of the fabric is not easily stained by dirt and other stains, and a certain antifouling effect is achieved.
5. The special washing-free decontamination article for the fluffy fabric has remarkable synergy among the fluffy agent, the softening agent and the antistatic agent, because the softening agent reduces the friction among fibers, yarns and even the whole fabric in the fabric, the pores on the surface of the fabric are completely opened, the fluffy agent plays a role in fluffing and fluffing on the basis, the flexibility and the thickness of the fabric are enhanced, and the resistance of the antistatic agent to external stains and the like is added, so that the fluffy and soft performance of the fabric is kept for a longer time, and the functions of the fluffy agent, the softening agent and the antistatic agent jointly play a role in promoting the excellent fluffy and soft effect of the washing-free finishing of the decontaminating agent.
6. The cleaning capacity of the special washing-free cleaning article for the fluffy fabric depends on the combined action of the solvent, the penetrating agent, the enzyme preparation, the softening agent, the fluffy agent and the antistatic agent, on one hand, the active enzyme, the surfactant, the aqueous solvent and the like in the cleaning-free cleaning article strip, decompose and dissolve stains, and on the other hand, the penetration, fluffy, antistatic and other actions of other auxiliary agents enable the stains to be more conveniently removed and prevent the stains from being polluted again, so the high-efficiency cleaning capacity of the cleaning agent is endowed by the synergistic effect of the components. In addition, no irritant components such as preservative, essence and the like are added, and the effects of antibiosis, anticorrosion and the like are achieved by virtue of the excellent proportion of the auxiliary agents, so that the method is more in line with the concept of environmental protection and health.
Detailed Description
Tea saponin: provided by Xian Heng chemical Co., Ltd;
polyether-amino modified silicone oil: the tin-free market provides by creative chemical technology, Inc.;
fluffy smooth silicon: offered by Taiyang textile products of Dongguan city, Inc.;
the neutral lipase, the serrapeptase and the cellulose complex enzyme are all provided by Nanning Dong Henghuadao biological science and technology limited;
hydrophilic caprylic capric acid glyceride: shenzhen yinuo food ingredients, Inc.
Example 1
Adding 17.5 parts of isooctanol polyoxyethylene ether JFC-3, 12.5 parts of isomeric tridecanol polyoxyethylene ether TO-6, 12 parts of isomeric tridecanol polyoxyethylene ether E-1005, 8 parts of tea saponin, 8.5 parts of polyether-amino modified silicone oil, 11.5 parts of hexadecyl dimethyl ethyl ammonium bromide and 12 parts of fluffy smooth silicone oil in turn into a container, then adding 85 parts of hydrophilic caprylic-capric glyceride, 540 parts of deionized water, 120 parts of d-limonene and 150 parts of ethanol in turn, stirring while adding, then adding 8 parts of neutral lipase, 4 parts of serrapeptase, 3 parts of cellulose and 8 parts of tetradecyl dimethyl benzyl ammonium chloride in turn after stirring uniformly, finally homogenizing at the rotating speed of 800rpm for 2.5min, sealing and packaging.
Example 2
Adding 17 parts of isooctanol polyoxyethylene ether JFC-3, 13 parts of isomeric tridecanol polyoxyethylene ether TO-6, 11.5 parts of isomeric tridecanol polyoxyethylene ether E-1005, 8.5 parts of tea saponin, 8.5 parts of polyether-amino modified silicone oil, 12 parts of hexadecyl dimethyl ethyl ammonium bromide and 12 parts of fluffy smooth silicone oil in sequence into a container, then adding 85 parts of hydrophilic caprylic/capric glyceride, 538 parts of deionized water, 122 parts of d-limonene and 150 parts of ethanol in sequence, stirring while adding, then adding 7.5 parts of neutral lipase, 4 parts of serrapeptase, 3.5 parts of cellulose and 7.5 parts of tetradecyl dimethyl benzyl ammonium chloride in sequence after stirring uniformly, finally homogenizing at the rotating speed of 800rpm for 2.5min, sealing and packaging.
Example 3
Adding 17.5 parts of isooctanol polyoxyethylene ether JFC-3, 13 parts of isomeric tridecanol polyoxyethylene ether TO-6, 11 parts of isomeric tridecanol polyoxyethylene ether E-1005, 8.5 parts of tea saponin, 9 parts of polyether-amino modified silicone oil, 12 parts of hexadecyl dimethyl ethyl ammonium bromide and 11 parts of fluffy smooth silicone oil into a container in sequence, then adding 82 parts of hydrophilic caprylic capric glyceride, 533 parts of deionized water, 125 parts of d-limonene and 155 parts of ethanol into the container in sequence, stirring the mixture while adding, then adding 7.5 parts of neutral lipase, 4 parts of serrapeptase, 3.5 parts of cellulose and 8 parts of tetradecyl dimethyl benzyl ammonium chloride into the container in sequence, finally homogenizing the mixture at the rotating speed of 1000rpm for 2min, sealing and packaging the mixture.
Comparative example 1
Adding 17 parts of isooctanol polyoxyethylene ether JFC-3, 13 parts of isomeric tridecanol polyoxyethylene ether TO-6, 11.5 parts of isomeric tridecanol polyoxyethylene ether E-1005, 8.5 parts of tea saponin, 8.5 parts of polyether-amino modified silicone oil, 12 parts of hexadecyl dimethyl ethyl ammonium bromide and 12 parts of fluffy smooth silicone oil in sequence into a container, then adding 120 parts of hydrophilic caprylic-capric glyceride, 400 parts of deionized water, 300 parts of d-limonene and 75 parts of ethanol in sequence, stirring while adding, then adding 7.5 parts of neutral lipase, 4 parts of serrapeptase, 3.5 parts of cellulose and 7.5 parts of tetradecyl dimethyl benzyl ammonium chloride in sequence after stirring uniformly, finally homogenizing at the rotating speed of 800rpm for 2.5min, and sealing and packaging (compared with the embodiment 2, the proportion of the solvent is different, and the other parts are the same).
Comparative example 2
17 parts of isooctanol polyoxyethylene ether JFC-3, 13 parts of isomeric tridecanol polyoxyethylene ether TO-6, 11.5 parts of isomeric tridecanol polyoxyethylene ether E-1005, 8.5 parts of tea saponin, 8.5 parts of polyether-amino modified silicone oil, 12 parts of hexadecyl dimethyl ethyl ammonium bromide and 12 parts of fluffy smooth silicone oil are sequentially added into a container, 85 parts of hydrophilic caprylic-capric glyceride, 538 parts of deionized water, 122 parts of d-limonene and 150 parts of glycerol are sequentially added into the container while stirring, 7.5 parts of neutral lipase, 4 parts of serrapeptase, 3.5 parts of cellulose complex enzyme and 7.5 parts of tetradecyl dimethyl benzyl ammonium chloride are sequentially added after stirring uniformly, and finally the mixture is homogenized at the rotating speed of 800rpm for 2.5min and sealed and packaged (compared with the example 2, ethanol is changed into glycerol, and the rest are the same).
Comparative example 3
Adding 12 parts of isooctanol polyoxyethylene ether JFC-3, 18 parts of isomeric tridecanol polyoxyethylene ether TO-6, 6.5 parts of isomeric tridecanol polyoxyethylene ether E-1005, 13.5 parts of tea saponin, 8.5 parts of polyether-amino modified silicone oil, 12 parts of hexadecyl dimethyl ethyl ammonium bromide and 12 parts of fluffy smooth silicone oil into a container in sequence, then adding 85 parts of hydrophilic caprylic-capric glyceride, 538 parts of deionized water, 122 parts of d-limonene and 150 parts of ethanol into the container in sequence, stirring the mixture while adding the deionized water, 7.5 parts of neutral lipase, 4 parts of serrapeptase, 3.5 parts of cellulose and 7.5 parts of tetradecyl dimethyl benzyl ammonium chloride into the container, finally homogenizing the mixture at the rotating speed of 800rpm for 2.5min, and sealing and packaging the mixture (compared with the example 2, the penetrant is different in proportion, and the rest are the same).
Comparative example 4
Adding 17 parts of isooctanol polyoxyethylene ether JFC-3, 13 parts of isomeric tridecanol polyoxyethylene ether TO-10, 11.5 parts of isomeric tridecanol polyoxyethylene ether E-1005, 8.5 parts of tea saponin, 8.5 parts of polyether-amino modified silicone oil, 12 parts of hexadecyl dimethyl ethyl ammonium bromide and 12 parts of fluffy smooth silicone oil into a container in sequence, then adding 85 parts of hydrophilic caprylic/capric glyceride, 538 parts of deionized water, 122 parts of d-limonene and 150 parts of ethanol into the container in sequence, stirring the mixture while adding the deionized water, 7.5 parts of neutral lipase, 4 parts of serrapeptase, 3.5 parts of cellulose and 7.5 parts of tetradecyl dimethyl benzyl ammonium chloride into the container, finally homogenizing the mixture at the rotating speed of 800rpm for 2.5min, sealing and packaging (compared with the example 2, the isomeric tridecanol polyoxyethylene ether TO-6 is changed into the isomeric tridecanol polyoxyethylene ether TO-10, the other is the same).
Comparative example 5
17 parts of isooctanol polyoxyethylene ether JFC-3, 13 parts of isomeric tridecanol polyoxyethylene ether TO-6, 11.5 parts of isomeric tridecanol polyoxyethylene ether E-1005, 8.5 parts of tea saponin, 14 parts of polyether-amino modified silicone oil, 6.5 parts of hexadecyl dimethyl ethyl ammonium bromide and 12 parts of fluffy smooth silicone oil are sequentially added into a container, 85 parts of hydrophilic caprylic-capric glyceride, 538 parts of deionized water, 122 parts of d-limonene and 150 parts of ethanol are sequentially added into the container while stirring, 7.5 parts of neutral lipase, 4 parts of serrapeptase, 3.5 parts of cellulose and 7.5 parts of tetradecyl dimethyl benzyl ammonium chloride are sequentially added after stirring uniformly, and finally the mixture is homogenized at the rotating speed of 800rpm for 2.5min and sealed and packaged (compared with the example 2, the mixture ratio of the softening agent is different, and the other parts are the same).
Comparative example 6
17 parts of isooctanol polyoxyethylene ether JFC-3, 13 parts of isomeric tridecanol polyoxyethylene ether TO-6, 11.5 parts of isomeric tridecanol polyoxyethylene ether E-1005, 8.5 parts of tea saponin, 8.5 parts of dimethyl silicone oil, 12 parts of hexadecyl dimethyl ethyl ammonium bromide and 12 parts of fluffy smooth silicone oil are sequentially added into a container, 85 parts of hydrophilic caprylic capric glyceride, 538 parts of deionized water, 122 parts of d-limonene and 150 parts of ethanol are sequentially added while stirring, 7.5 parts of neutral lipase, 4 parts of serrapeptase, 3.5 parts of cellulose complex enzyme and 7.5 parts of tetradecyl dimethyl benzyl ammonium chloride are sequentially added after stirring uniformly, and finally the mixture is homogenized for 2.5min at the rotating speed of 800rpm, and the mixture is sealed and packaged (compared with the example 2, the polyether-amino modified silicone oil is changed into dimethyl silicone oil, and the other parts are the same).
Comparative example 7
17 parts of isooctanol polyoxyethylene ether JFC-3, 13 parts of isomeric tridecanol polyoxyethylene ether TO-6, 11.5 parts of isomeric tridecanol polyoxyethylene ether E-1005, 8.5 parts of tea saponin, 8.5 parts of polyether-amino modified silicone oil, 12 parts of hexadecyl dimethyl ethyl ammonium bromide and 6 parts of fluffy smooth silicone oil are sequentially added into a container, 86 parts of hydrophilic caprylic-capric glyceride, 540 parts of deionized water, 123 parts of d-limonene and 152 parts of ethanol are sequentially added while stirring, 7.5 parts of neutral lipase, 4 parts of serrapeptase, 3.5 parts of cellulose and 7.5 parts of tetradecyl dimethyl benzyl ammonium chloride are sequentially added after stirring uniformly, and finally the mixture is homogenized at the rotating speed of 800rpm for 2.5min and is sealed and packaged (compared with the embodiment 2, the dosage of the fluffy agent is reduced, and the rest is supplemented by the solvent, and the rest is the same).
Comparative example 8
17 parts of isooctanol polyoxyethylene ether JFC-3, 13 parts of isomeric tridecanol polyoxyethylene ether TO-6, 11.5 parts of isomeric tridecanol polyoxyethylene ether E-1005, 8.5 parts of tea saponin, 8.5 parts of polyether-amino modified silicone oil, 12 parts of hexadecyl dimethyl ethyl ammonium bromide and 12 parts of fluffy smooth silicone oil are sequentially added into a container, 85 parts of hydrophilic caprylic-capric glyceride, 538 parts of deionized water, 122 parts of d-limonene and 150 parts of ethanol are sequentially added into the container while stirring, 3.5 parts of neutral lipase, 5 parts of serrapeptase, 6.5 parts of cellulose and 7.5 parts of tetradecyl dimethyl benzyl ammonium chloride are sequentially added after stirring uniformly, and finally the mixture is homogenized at the rotating speed of 800rpm for 2.5min and sealed and packaged (compared with the example 2, the enzyme preparation is different in proportion and the other parts are the same).
Comparative example 9
17 parts of isooctanol polyoxyethylene ether JFC-3, 13 parts of isomeric tridecanol polyoxyethylene ether TO-6, 11.5 parts of isomeric tridecanol polyoxyethylene ether E-1005, 8.5 parts of tea saponin, 8.5 parts of polyether-amino modified silicone oil, 12 parts of hexadecyl dimethyl ethyl ammonium bromide and 12 parts of fluffy smooth silicone oil are sequentially added into a container, 85 parts of hydrophilic caprylic-capric glyceride, 538 parts of deionized water, 122 parts of d-limonene and 150 parts of ethanol are sequentially added while stirring, 7.5 parts of neutral lipase, 4 parts of serrapeptase, 3.5 parts of cellulose and 7.5 parts of dodecyl dimethyl ammonium bromide are sequentially added after stirring uniformly, and finally the mixture is homogenized for 2.5min at the rotating speed of 800rpm, and sealed and packaged (compared with the example 2, tetradecyl dimethyl benzyl ammonium chloride is changed into dodecyl dimethyl ammonium bromide, and the other parts are the same).
Comparative example 10
Certain commercially available concentrated laundry detergent with 45% of active ingredient content.
Comparative example 11
A commercially available softener having an active ingredient content of 30%.
Comparative example 12
Sodium lauryl sulfate.
And (3) performance testing:
1. and (3) permeability test:
the method adopts a canvas settlement method (GB 5557-85), and comprises the following specific steps:
(1) 800mL of a 2.5g/L osmotic agent (detergent) solution is measured by a measuring cylinder, the solution is transferred into a 1000mL beaker, and the temperature is adjusted to 25 +/-1 ℃ (note: the concentration of the detergent is the concentration when the concentration of the effective component is equal to 2.5g/L, in the example 1, the content of the osmotic agent is 5%, so the concentration of the 20-fold diluent, namely 40g/L, is adopted in the example 1).
(2) Cutting the standard fine canvas into circular pieces with the diameter of 35mm, ensuring that the weight of each piece is between 0.38 and 0.39g, and preparing 20 to 40mg fishhooks.
(3) The tip end of the fishhook is hooked at a position 2-3 mm away from the edge of the canvas wafer, the other end of the fishhook is tied with a silk thread, and the tail end of the silk thread is connected to a small hook at the tail of the iron wire frame. The frame was moved into the beaker and placed on the edge of the beaker, with the canvas disc floating in the solution, with its apex approximately 10mm below the liquid, and the stopwatch was immediately started.
(4) And (3) wetting the canvas wafer by using the penetrating agent, and when the specific gravity is greater than that of the solution, beginning to settle the canvas wafer until the lower end of the fishhook touches the cup bottom, namely the end point, and recording the settling time. The test was repeated 10 times and averaged, the shorter the time, the better the permeability of the solution.
The test results are shown in table 1 below:
table 1: results of permeation Performance test of detergents of examples 1 to 3 and comparative examples 1 to 12
As can be seen from the results in the table, the detergent of each example showed a settling time of less than 3s, which is much faster than that of each control example, and the excellent permeability of the present invention is fully demonstrated.
2. Softness and bulk, detergency and anti-yellowing test:
testing materials: the small cloth with the same specification (6cm multiplied by 4cm multiplied by 2cm) is wrapped in a plurality of blocks, the outer layer is white polyester cotton, and the inner lining is polyurethane sponge.
The treatment method comprises the following steps: the surface stains of all the small cloth bags are a mixture of 1mL of soy sauce and edible oil (the ratio is 1:1), and the small cloth bags are uniformly paved on one surface of the small cloth bags with the length of 6cm multiplied by 4cm as much as possible. In each embodiment and comparative examples 1 to 9, the small cloth bags are cleaned according to the method for cleaning-free cleaning of the fluffy fabric, namely the cleaning-free detergent is sprayed on surface stains, and after 10 to 30 seconds, the surface stains of the fabric are cleaned by wiping and adsorbing with cleaning cotton; then continuously spraying the non-washing detergent to enable the spraying range to cover the position where the original stain is located, placing another piece of clean cleaning cotton on the corresponding position of the back of the fabric, and obtaining the non-washing detergent after the detergent is absorbed by the cleaning cotton; the blank sample is a small cloth bag without stains; the blank sample is not cleaned, namely a small uncleaned cloth bag after stains are added; comparative example 10 drying after washing; "comparative example 11+ 12" means that the cleaning was carried out by washing with water in comparative example 11 and then the drying was carried out after finishing in comparative example 12.
The method for testing softness and bulkiness comprises the following steps: the evaluation group consisted of five or more persons, and was rated as closed-eye tactile, with 5 being the best and 1 being the worst. Firstly, all the small cloth bags which are cleaned are put together for primary selection, one part of the cloth bags which are worst is removed is evaluated as level 1, after the primary selection, one round of cloth bags is selected again and evaluated as level 2, the rest small cloth bags are arranged in sequence to obtain level 3 to 5, and finally, the average value is calculated.
Detergency test method: whiteness Test fabric whiteness was measured using a "WSB-2" whiteness meter, in accordance with AATCC Test Method 110-2005 standard.
The test results are given in table 2 below:
table 2 softness and bulk, detergency and anti-yellowing test results for each sample
| Group of | Softness/grade | Bulk/grade | Whiteness/% |
| Blank sample | 1.2 | 1.5 | 74.6 |
| Uncleaned blank | 1.0 | 1.2 | 29.5 |
| Example 1 | 4.6 | 5.0 | 73.9 |
| Example 2 | 4.8 | 4.8 | 74.2 |
| Example 3 | 5.0 | 4.5 | 74.0 |
| Comparative example 1 | 3.0 | 2.8 | 70.5 |
| Comparative example 2 | 3.3 | 3.0 | 71.1 |
| Comparative example 3 | 2.3 | 2.6 | 48.3 |
| Comparative example 4 | 3.5 | 3.2 | 56.7 |
| Comparative example 5 | 1.6 | 1.5 | 63.4 |
| Comparative example 6 | 2.5 | 2.2 | 68.5 |
| Comparative example 7 | 3.0 | 2.5 | 69.2 |
| Comparative example 8 | 3.5 | 3.8 | 52.8 |
| Comparative example 9 | 3.3 | 3.0 | 69.0 |
| Comparative example 10 | 1.0 | 1.5 | 45.9 |
| Comparative example 11+12 | 3.2 | 2.8 | 57.3 |
As can be seen from the results in the table, the grade of softness and bulkiness of the soil release agent in each example is more than 4.5, which is much better than that of each control example, and the outstanding soft and fluffy effect of the no-wash finish of the invention is fully shown; the whiteness of the detergent in each example is also close to that of a blank sample, is much better than that of each comparative example, and fully shows the excellent performance of strong detergency and yellowing resistance of the detergent.
Although the present invention has been described with reference to the preferred embodiments, it should be understood that various changes and modifications can be made therein by those skilled in the art without departing from the spirit and scope of the invention as defined in the appended claims.
Claims (6)
1. The washing-free detergent is characterized by comprising 45-55 parts by weight of penetrating agent, 15-25 parts by weight of softening agent, 8-16 parts by weight of fluffing agent, 10-20 parts by weight of enzyme preparation, 4-12 parts by weight of antistatic agent and 872-918 parts by weight of solvent, wherein the penetrating agent comprises isooctanol polyoxyethylene ether JFC-3, isomeric tridecanol polyoxyethylene ether TO-6, isomeric tridecanol polyoxyethylene ether E-1005 and tea saponin; the softening agent comprises polyether-amino modified silicone oil and hexadecyl dimethyl ethyl ammonium bromide; the fluffing agent is fluffy smooth silicone oil; the enzyme preparation comprises neutral lipase, serrapeptase and cellulose complex enzyme; the antistatic agent is tetradecyl dimethyl benzyl ammonium chloride; the solvent comprises hydrophilic caprylic capric glyceride, water, d-limonene and ethanol;
wherein in the penetrant, 16-19 parts of isooctanol polyoxyethylene ether JFC-3, 11.5-14 parts of isomeric tridecanol polyoxyethylene ether TO-6, isomeric tridecanol polyoxyethylene ether E-1005 and tea saponin respectively, 10-12.5 parts of isomeric tridecanol polyoxyethylene ether and 7.5-9.5 parts of isomeric tridecanol polyoxyethylene ether;
in the softening agent, 6-11 parts of polyether-amino modified silicone oil and 9-14 parts of hexadecyl dimethyl ethyl ammonium bromide are respectively used;
in the enzyme preparation, the neutral lipase, the serrapeptase and the cellulose complex enzyme account for 5.5-10.5 parts, 2.5-5.5 parts and 2-4 parts respectively;
in the solvent, the hydrophilic caprylic-capric glyceride, the water, the d-limonene and the ethanol respectively account for 80-88 parts, 530-545 parts, 117-128 parts and 145-157 parts.
2. A method of preparing a leave-in detergent according to claim 1, said method comprising: adding 45-55 parts of penetrating agent, 15-25 parts of softening agent and 8-16 parts of bulking agent into a container, adding 872-918 parts of solvent, uniformly stirring, adding 10-20 parts of enzyme preparation and 4-12 parts of antistatic agent, and homogenizing at the rotating speed of 600-1000 rpm for 2-5 min to obtain the no-clean detergent.
3. A special washing-free stain removal article for fluffy fabrics, which is characterized in that the article comprises cleaning cotton and washing-free stain remover as claimed in claim 1 or prepared by the preparation method of washing-free stain remover as claimed in claim 2, wherein the cleaning cotton is prepared by the following method: respectively spreading activated carbon particles on one surface of each of the two super sponge pieces with the groove to ensure that the spreading density is 350-450 g/m2And bonding the surfaces of the two sponges paved with the activated carbon together by using an adhesive.
4. A method for washing-free decontamination of fluffy fabrics is characterized by comprising the following steps: spraying the no-clean detergent prepared by the no-clean detergent of claim 1 or the preparation method of the no-clean detergent of claim 2 on stains on the surface of fluffy fabric, wiping and adsorbing the stains by using cleaning cotton after 10-30 s, and removing the stains on the surface of the fabric; and then continuously spraying the non-washing detergent to enable the spraying range to cover the position where the original stain is located, placing another piece of clean cleaning cotton on the corresponding position of the back of the fabric, and after the detergent is absorbed by the cleaning cotton completely.
5. The method for removing soil from bulky fabrics in a washing-free way specially used for the bulky fabrics according to claim 4,the cleaning cotton is prepared by the following method: respectively spreading activated carbon particles on one surface of each of the two super sponge pieces with the groove to ensure that the spreading density is 350-450 g/m2And bonding the surfaces of the two sponges paved with the activated carbon together by using an adhesive.
6. A detergent or cleaning article comprising the detergent-free composition according to claim 1 or the detergent-free composition prepared by the process for producing a detergent-free composition according to claim 2.
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| CN105780496A (en) * | 2016-05-12 | 2016-07-20 | 于文 | Anti-static softening spray composition |
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| CN105780496A (en) * | 2016-05-12 | 2016-07-20 | 于文 | Anti-static softening spray composition |
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Effective date of registration: 20211011 Address after: 200120 seat 199, 3 / F, 989 Dongfang Road, China (Shanghai) pilot Free Trade Zone, Pudong New Area, Shanghai Patentee after: SHANGHAI SHENGJIE CHEMICAL TECHNOLOGY Co.,Ltd. Address before: 510630 room 101-2, building 2, No. 95, Daguan Middle Road, Tianhe District, Guangzhou City, Guangdong Province (office only) Patentee before: Guangzhou shengxia Intellectual Property Operation Co.,Ltd. Effective date of registration: 20211011 Address after: 510630 room 101-2, building 2, No. 95, Daguan Middle Road, Tianhe District, Guangzhou City, Guangdong Province (office only) Patentee after: Guangzhou shengxia Intellectual Property Operation Co.,Ltd. Address before: 214000 No. 1800, Lihu Avenue, Wuxi City, Jiangsu Province Patentee before: Jiangnan University |
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Effective date of registration: 20230718 Address after: Room 605-606, No. 22, Lane 373, Fushun Road, Yangpu District, Shanghai, 200120 Patentee after: Hao Junwei Address before: 200120 seat 199, 3 / F, 989 Dongfang Road, China (Shanghai) pilot Free Trade Zone, Pudong New Area, Shanghai Patentee before: SHANGHAI SHENGJIE CHEMICAL TECHNOLOGY Co.,Ltd. |