CN109438918A - 一种纤维增强复合材料及其制备方法 - Google Patents
一种纤维增强复合材料及其制备方法 Download PDFInfo
- Publication number
- CN109438918A CN109438918A CN201811013055.0A CN201811013055A CN109438918A CN 109438918 A CN109438918 A CN 109438918A CN 201811013055 A CN201811013055 A CN 201811013055A CN 109438918 A CN109438918 A CN 109438918A
- Authority
- CN
- China
- Prior art keywords
- parts
- epoxy resin
- reinforced composites
- fibre reinforced
- fiber
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000835 fiber Substances 0.000 title claims abstract description 88
- 239000002131 composite material Substances 0.000 title claims abstract description 70
- 238000002360 preparation method Methods 0.000 title claims abstract description 18
- 229920000647 polyepoxide Polymers 0.000 claims abstract description 71
- 239000003822 epoxy resin Substances 0.000 claims abstract description 70
- 239000003063 flame retardant Substances 0.000 claims abstract description 57
- 239000012745 toughening agent Substances 0.000 claims abstract description 23
- 239000012783 reinforcing fiber Substances 0.000 claims abstract description 20
- 230000000979 retarding effect Effects 0.000 claims abstract description 16
- -1 glycidyl ester Chemical class 0.000 claims description 36
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 26
- 229920005989 resin Polymers 0.000 claims description 26
- 239000011347 resin Substances 0.000 claims description 26
- 239000004114 Ammonium polyphosphate Substances 0.000 claims description 20
- 235000019826 ammonium polyphosphate Nutrition 0.000 claims description 20
- 229920001276 ammonium polyphosphate Polymers 0.000 claims description 20
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 15
- DWSWCPPGLRSPIT-UHFFFAOYSA-N benzo[c][2,1]benzoxaphosphinin-6-ium 6-oxide Chemical compound C1=CC=C2[P+](=O)OC3=CC=CC=C3C2=C1 DWSWCPPGLRSPIT-UHFFFAOYSA-N 0.000 claims description 14
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 12
- ZQKXQUJXLSSJCH-UHFFFAOYSA-N melamine cyanurate Chemical compound NC1=NC(N)=NC(N)=N1.O=C1NC(=O)NC(=O)N1 ZQKXQUJXLSSJCH-UHFFFAOYSA-N 0.000 claims description 12
- 229910019142 PO4 Inorganic materials 0.000 claims description 11
- 239000005062 Polybutadiene Substances 0.000 claims description 11
- 229910052760 oxygen Inorganic materials 0.000 claims description 11
- 239000001301 oxygen Substances 0.000 claims description 11
- 239000010452 phosphate Substances 0.000 claims description 11
- 229920002857 polybutadiene Polymers 0.000 claims description 11
- 229920000049 Carbon (fiber) Polymers 0.000 claims description 10
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 10
- 239000004917 carbon fiber Substances 0.000 claims description 10
- 238000006243 chemical reaction Methods 0.000 claims description 10
- 239000003795 chemical substances by application Substances 0.000 claims description 10
- 238000007598 dipping method Methods 0.000 claims description 10
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 10
- 229920001971 elastomer Polymers 0.000 claims description 9
- 238000006735 epoxidation reaction Methods 0.000 claims description 9
- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 claims description 9
- 239000005060 rubber Substances 0.000 claims description 9
- 229910052782 aluminium Inorganic materials 0.000 claims description 8
- 229920002748 Basalt fiber Polymers 0.000 claims description 7
- 229920006231 aramid fiber Polymers 0.000 claims description 7
- LNDKRVOOYMEYTC-UHFFFAOYSA-N buta-1,3-dien-1-ol Chemical compound OC=CC=C LNDKRVOOYMEYTC-UHFFFAOYSA-N 0.000 claims description 7
- 239000003365 glass fiber Substances 0.000 claims description 7
- KWSLGOVYXMQPPX-UHFFFAOYSA-N 5-[3-(trifluoromethyl)phenyl]-2h-tetrazole Chemical compound FC(F)(F)C1=CC=CC(C2=NNN=N2)=C1 KWSLGOVYXMQPPX-UHFFFAOYSA-N 0.000 claims description 6
- 229920000459 Nitrile rubber Polymers 0.000 claims description 6
- 239000011353 cycloaliphatic epoxy resin Substances 0.000 claims description 6
- 229920001778 nylon Polymers 0.000 claims description 6
- 229910001379 sodium hypophosphite Inorganic materials 0.000 claims description 6
- 239000004734 Polyphenylene sulfide Substances 0.000 claims description 5
- 239000004699 Ultra-high molecular weight polyethylene Substances 0.000 claims description 5
- MYOXMAQGEINAEF-UHFFFAOYSA-N [C].N1=NN=CC=C1 Chemical compound [C].N1=NN=CC=C1 MYOXMAQGEINAEF-UHFFFAOYSA-N 0.000 claims description 5
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 claims description 5
- 229910021502 aluminium hydroxide Inorganic materials 0.000 claims description 5
- NTXGQCSETZTARF-UHFFFAOYSA-N buta-1,3-diene;prop-2-enenitrile Chemical compound C=CC=C.C=CC#N NTXGQCSETZTARF-UHFFFAOYSA-N 0.000 claims description 5
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 claims description 5
- 239000000347 magnesium hydroxide Substances 0.000 claims description 5
- 229910001862 magnesium hydroxide Inorganic materials 0.000 claims description 5
- 229920000069 polyphenylene sulfide Polymers 0.000 claims description 5
- 229920000785 ultra high molecular weight polyethylene Polymers 0.000 claims description 5
- CTKINSOISVBQLD-UHFFFAOYSA-N Glycidol Chemical compound OCC1CO1 CTKINSOISVBQLD-UHFFFAOYSA-N 0.000 claims description 4
- 150000003839 salts Chemical group 0.000 claims description 4
- 239000004845 glycidylamine epoxy resin Substances 0.000 claims description 3
- PNDPGZBMCMUPRI-UHFFFAOYSA-N iodine Chemical compound II PNDPGZBMCMUPRI-UHFFFAOYSA-N 0.000 claims description 3
- RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 claims description 3
- XFZRQAZGUOTJCS-UHFFFAOYSA-N phosphoric acid;1,3,5-triazine-2,4,6-triamine Chemical compound OP(O)(O)=O.NC1=NC(N)=NC(N)=N1 XFZRQAZGUOTJCS-UHFFFAOYSA-N 0.000 claims description 3
- RYDVBNBVYVMEDT-UHFFFAOYSA-N n-carbamoyl-2-hydroxyacetamide Chemical group NC(=O)NC(=O)CO RYDVBNBVYVMEDT-UHFFFAOYSA-N 0.000 claims description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims 1
- 239000004952 Polyamide Substances 0.000 claims 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims 1
- 239000005864 Sulphur Substances 0.000 claims 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims 1
- 150000001412 amines Chemical class 0.000 claims 1
- 239000004327 boric acid Substances 0.000 claims 1
- 125000005619 boric acid group Chemical group 0.000 claims 1
- 239000011575 calcium Substances 0.000 claims 1
- 229910052791 calcium Inorganic materials 0.000 claims 1
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 claims 1
- ACVYVLVWPXVTIT-UHFFFAOYSA-N phosphinic acid Chemical compound O[PH2]=O ACVYVLVWPXVTIT-UHFFFAOYSA-N 0.000 claims 1
- 229920002647 polyamide Polymers 0.000 claims 1
- 239000011701 zinc Substances 0.000 claims 1
- 229910052725 zinc Inorganic materials 0.000 claims 1
- 239000000463 material Substances 0.000 description 22
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 17
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 12
- 230000000694 effects Effects 0.000 description 12
- 239000007788 liquid Substances 0.000 description 12
- 239000011159 matrix material Substances 0.000 description 9
- YJTKZCDBKVTVBY-UHFFFAOYSA-N 1,3-Diphenylbenzene Chemical group C1=CC=CC=C1C1=CC=CC(C=2C=CC=CC=2)=C1 YJTKZCDBKVTVBY-UHFFFAOYSA-N 0.000 description 8
- 150000002148 esters Chemical class 0.000 description 8
- 238000002156 mixing Methods 0.000 description 8
- DGUJJOYLOCXENZ-UHFFFAOYSA-N 4-[2-[4-(oxiran-2-ylmethoxy)phenyl]propan-2-yl]phenol Chemical compound C=1C=C(OCC2OC2)C=CC=1C(C)(C)C1=CC=C(O)C=C1 DGUJJOYLOCXENZ-UHFFFAOYSA-N 0.000 description 7
- 230000002708 enhancing effect Effects 0.000 description 7
- 229910052757 nitrogen Inorganic materials 0.000 description 7
- 229910052698 phosphorus Inorganic materials 0.000 description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
- 229910001868 water Inorganic materials 0.000 description 7
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 6
- BDAGIHXWWSANSR-UHFFFAOYSA-N Formic acid Chemical class OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 6
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 6
- 238000005452 bending Methods 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 6
- 150000001875 compounds Chemical class 0.000 description 6
- 239000011574 phosphorus Substances 0.000 description 6
- ORTMHVMCRHIAHL-UHFFFAOYSA-N 4-methyl-5-(7-oxabicyclo[4.1.0]heptan-4-yl)-7-oxabicyclo[4.1.0]heptane-4-carboxylic acid Chemical class C1CC2OC2CC1C1C2OC2CCC1(C)C(O)=O ORTMHVMCRHIAHL-UHFFFAOYSA-N 0.000 description 5
- 239000004593 Epoxy Substances 0.000 description 5
- 238000001723 curing Methods 0.000 description 5
- 238000005516 engineering process Methods 0.000 description 5
- WJRBRSLFGCUECM-UHFFFAOYSA-N hydantoin Chemical compound O=C1CNC(=O)N1 WJRBRSLFGCUECM-UHFFFAOYSA-N 0.000 description 5
- 238000000034 method Methods 0.000 description 5
- AFEQENGXSMURHA-UHFFFAOYSA-N oxiran-2-ylmethanamine Chemical compound NCC1CO1 AFEQENGXSMURHA-UHFFFAOYSA-N 0.000 description 5
- FAUAZXVRLVIARB-UHFFFAOYSA-N 4-[[4-[bis(oxiran-2-ylmethyl)amino]phenyl]methyl]-n,n-bis(oxiran-2-ylmethyl)aniline Chemical compound C1OC1CN(C=1C=CC(CC=2C=CC(=CC=2)N(CC2OC2)CC2OC2)=CC=1)CC1CO1 FAUAZXVRLVIARB-UHFFFAOYSA-N 0.000 description 4
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical class OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 4
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 4
- 239000004642 Polyimide Substances 0.000 description 4
- 239000002253 acid Substances 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 4
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 4
- 238000011161 development Methods 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 229920001721 polyimide Polymers 0.000 description 4
- ISIJQEHRDSCQIU-UHFFFAOYSA-N tert-butyl 2,7-diazaspiro[4.5]decane-7-carboxylate Chemical compound C1N(C(=O)OC(C)(C)C)CCCC11CNCC1 ISIJQEHRDSCQIU-UHFFFAOYSA-N 0.000 description 4
- BIKXLKXABVUSMH-UHFFFAOYSA-N trizinc;diborate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]B([O-])[O-].[O-]B([O-])[O-] BIKXLKXABVUSMH-UHFFFAOYSA-N 0.000 description 4
- OTEKOJQFKOIXMU-UHFFFAOYSA-N 1,4-bis(trichloromethyl)benzene Chemical compound ClC(Cl)(Cl)C1=CC=C(C(Cl)(Cl)Cl)C=C1 OTEKOJQFKOIXMU-UHFFFAOYSA-N 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- 229920000877 Melamine resin Polymers 0.000 description 3
- YSMRWXYRXBRSND-UHFFFAOYSA-N TOTP Chemical compound CC1=CC=CC=C1OP(=O)(OC=1C(=CC=CC=1)C)OC1=CC=CC=C1C YSMRWXYRXBRSND-UHFFFAOYSA-N 0.000 description 3
- 239000000654 additive Substances 0.000 description 3
- 230000000996 additive effect Effects 0.000 description 3
- 229910001382 calcium hypophosphite Inorganic materials 0.000 description 3
- 229940064002 calcium hypophosphite Drugs 0.000 description 3
- 229910052799 carbon Inorganic materials 0.000 description 3
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 3
- 239000003610 charcoal Substances 0.000 description 3
- 239000000571 coke Substances 0.000 description 3
- GYZLOYUZLJXAJU-UHFFFAOYSA-N diglycidyl ether Chemical compound C1OC1COCC1CO1 GYZLOYUZLJXAJU-UHFFFAOYSA-N 0.000 description 3
- 229910052736 halogen Inorganic materials 0.000 description 3
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 description 3
- 238000000465 moulding Methods 0.000 description 3
- 238000000016 photochemical curing Methods 0.000 description 3
- 229920000642 polymer Polymers 0.000 description 3
- 229920000137 polyphosphoric acid Polymers 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- 239000000779 smoke Substances 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- CNALVHVMBXLLIY-IUCAKERBSA-N tert-butyl n-[(3s,5s)-5-methylpiperidin-3-yl]carbamate Chemical compound C[C@@H]1CNC[C@@H](NC(=O)OC(C)(C)C)C1 CNALVHVMBXLLIY-IUCAKERBSA-N 0.000 description 3
- PLIKAWJENQZMHA-UHFFFAOYSA-N 4-aminophenol Chemical compound NC1=CC=C(O)C=C1 PLIKAWJENQZMHA-UHFFFAOYSA-N 0.000 description 2
- GBRSPKXOFRTAHS-UHFFFAOYSA-N 5-(4-nitrophenyl)-1,2-oxazole-3-carboxylic acid Chemical compound O1N=C(C(=O)O)C=C1C1=CC=C([N+]([O-])=O)C=C1 GBRSPKXOFRTAHS-UHFFFAOYSA-N 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerol Natural products OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- HSRJKNPTNIJEKV-UHFFFAOYSA-N Guaifenesin Chemical compound COC1=CC=CC=C1OCC(O)CO HSRJKNPTNIJEKV-UHFFFAOYSA-N 0.000 description 2
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 2
- 229920000388 Polyphosphate Polymers 0.000 description 2
- 208000037656 Respiratory Sounds Diseases 0.000 description 2
- YUWBVKYVJWNVLE-UHFFFAOYSA-N [N].[P] Chemical compound [N].[P] YUWBVKYVJWNVLE-UHFFFAOYSA-N 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 150000001336 alkenes Chemical group 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 239000004411 aluminium Substances 0.000 description 2
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 2
- 239000010426 asphalt Substances 0.000 description 2
- YKGYQYOQRGPFTO-UHFFFAOYSA-N bis(8-methylnonyl) hexanedioate Chemical compound CC(C)CCCCCCCOC(=O)CCCCC(=O)OCCCCCCCC(C)C YKGYQYOQRGPFTO-UHFFFAOYSA-N 0.000 description 2
- PXKLMJQFEQBVLD-UHFFFAOYSA-N bisphenol F Chemical compound C1=CC(O)=CC=C1CC1=CC=C(O)C=C1 PXKLMJQFEQBVLD-UHFFFAOYSA-N 0.000 description 2
- 229940106691 bisphenol a Drugs 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 238000002485 combustion reaction Methods 0.000 description 2
- 238000004132 cross linking Methods 0.000 description 2
- 125000004122 cyclic group Chemical group 0.000 description 2
- 238000005265 energy consumption Methods 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 125000003700 epoxy group Chemical group 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 150000002367 halogens Chemical class 0.000 description 2
- 229910000039 hydrogen halide Inorganic materials 0.000 description 2
- 239000012433 hydrogen halide Substances 0.000 description 2
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 2
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 2
- 230000003287 optical effect Effects 0.000 description 2
- 125000002467 phosphate group Chemical group [H]OP(=O)(O[H])O[*] 0.000 description 2
- 208000034301 polycystic dysgenetic disease of parotid salivary glands Diseases 0.000 description 2
- 239000001205 polyphosphate Substances 0.000 description 2
- 235000011176 polyphosphates Nutrition 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 description 2
- 230000004044 response Effects 0.000 description 2
- PNGLEYLFMHGIQO-UHFFFAOYSA-M sodium;3-(n-ethyl-3-methoxyanilino)-2-hydroxypropane-1-sulfonate;dihydrate Chemical compound O.O.[Na+].[O-]S(=O)(=O)CC(O)CN(CC)C1=CC=CC(OC)=C1 PNGLEYLFMHGIQO-UHFFFAOYSA-M 0.000 description 2
- 238000007711 solidification Methods 0.000 description 2
- 230000008023 solidification Effects 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- AYEKOFBPNLCAJY-UHFFFAOYSA-O thiamine pyrophosphate Chemical compound CC1=C(CCOP(O)(=O)OP(O)(O)=O)SC=[N+]1CC1=CN=C(C)N=C1N AYEKOFBPNLCAJY-UHFFFAOYSA-O 0.000 description 2
- STCOOQWBFONSKY-UHFFFAOYSA-N tributyl phosphate Chemical compound CCCCOP(=O)(OCCCC)OCCCC STCOOQWBFONSKY-UHFFFAOYSA-N 0.000 description 2
- HVLLSGMXQDNUAL-UHFFFAOYSA-N triphenyl phosphite Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)OC1=CC=CC=C1 HVLLSGMXQDNUAL-UHFFFAOYSA-N 0.000 description 2
- QGLWBTPVKHMVHM-KTKRTIGZSA-N (z)-octadec-9-en-1-amine Chemical compound CCCCCCCC\C=C/CCCCCCCCN QGLWBTPVKHMVHM-KTKRTIGZSA-N 0.000 description 1
- JYEUMXHLPRZUAT-UHFFFAOYSA-N 1,2,3-triazine Chemical compound C1=CN=NN=C1 JYEUMXHLPRZUAT-UHFFFAOYSA-N 0.000 description 1
- GRZJZRHVJAXMRR-UHFFFAOYSA-N 1-cyclohexyl-2-phenylbenzene Chemical group C1CCCCC1C1=CC=CC=C1C1=CC=CC=C1 GRZJZRHVJAXMRR-UHFFFAOYSA-N 0.000 description 1
- BSYJHYLAMMJNRC-UHFFFAOYSA-N 2,4,4-trimethylpentan-2-ol Chemical compound CC(C)(C)CC(C)(C)O BSYJHYLAMMJNRC-UHFFFAOYSA-N 0.000 description 1
- SQKUFYLUXROIFM-UHFFFAOYSA-N 2-[2-[carboxymethyl-[[3-hydroxy-2-methyl-5-(phosphonooxymethyl)pyridin-4-yl]methyl]amino]ethyl-[[3-hydroxy-2-methyl-5-(phosphonooxymethyl)pyridin-4-yl]methyl]amino]acetic acid Chemical compound CC1=NC=C(COP(O)(O)=O)C(CN(CCN(CC(O)=O)CC=2C(=C(C)N=CC=2COP(O)(O)=O)O)CC(O)=O)=C1O SQKUFYLUXROIFM-UHFFFAOYSA-N 0.000 description 1
- SLJFKNONPLNAPF-UHFFFAOYSA-N 3-Vinyl-7-oxabicyclo[4.1.0]heptane Chemical compound C1C(C=C)CCC2OC21 SLJFKNONPLNAPF-UHFFFAOYSA-N 0.000 description 1
- VPWNQTHUCYMVMZ-UHFFFAOYSA-N 4,4'-sulfonyldiphenol Chemical compound C1=CC(O)=CC=C1S(=O)(=O)C1=CC=C(O)C=C1 VPWNQTHUCYMVMZ-UHFFFAOYSA-N 0.000 description 1
- DPTGFYXXFXSRIR-UHFFFAOYSA-N 7-oxabicyclo[4.1.0]heptan-4-ylmethyl prop-2-enoate Chemical compound C1C(COC(=O)C=C)CCC2OC21 DPTGFYXXFXSRIR-UHFFFAOYSA-N 0.000 description 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- 239000004254 Ammonium phosphate Substances 0.000 description 1
- LCFVJGUPQDGYKZ-UHFFFAOYSA-N Bisphenol A diglycidyl ether Chemical class C=1C=C(OCC2OC2)C=CC=1C(C)(C)C(C=C1)=CC=C1OCC1CO1 LCFVJGUPQDGYKZ-UHFFFAOYSA-N 0.000 description 1
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 description 1
- BRLQWZUYTZBJKN-UHFFFAOYSA-N Epichlorohydrin Chemical compound ClCC1CO1 BRLQWZUYTZBJKN-UHFFFAOYSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- 229920002430 Fibre-reinforced plastic Polymers 0.000 description 1
- 239000004705 High-molecular-weight polyethylene Substances 0.000 description 1
- 229920002121 Hydroxyl-terminated polybutadiene Polymers 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004820 Pressure-sensitive adhesive Substances 0.000 description 1
- LEHOTFFKMJEONL-UHFFFAOYSA-N Uric Acid Chemical compound N1C(=O)NC(=O)C2=C1NC(=O)N2 LEHOTFFKMJEONL-UHFFFAOYSA-N 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- 125000003342 alkenyl group Chemical group 0.000 description 1
- 229910000148 ammonium phosphate Inorganic materials 0.000 description 1
- 235000019289 ammonium phosphates Nutrition 0.000 description 1
- 239000012298 atmosphere Substances 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000001588 bifunctional effect Effects 0.000 description 1
- SNAMIIGIIUQQSP-UHFFFAOYSA-N bis(6-methylheptyl) hydrogen phosphate Chemical compound CC(C)CCCCCOP(O)(=O)OCCCCCC(C)C SNAMIIGIIUQQSP-UHFFFAOYSA-N 0.000 description 1
- KIKYOFDZBWIHTF-UHFFFAOYSA-N bis(oxiran-2-ylmethyl) cyclohex-3-ene-1,2-dicarboxylate Chemical compound C1CC=CC(C(=O)OCC2OC2)C1C(=O)OCC1CO1 KIKYOFDZBWIHTF-UHFFFAOYSA-N 0.000 description 1
- 125000006226 butoxyethyl group Chemical group 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 1
- 238000006757 chemical reactions by type Methods 0.000 description 1
- 235000019504 cigarettes Nutrition 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 235000009508 confectionery Nutrition 0.000 description 1
- 239000004035 construction material Substances 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000018044 dehydration Effects 0.000 description 1
- 238000006297 dehydration reaction Methods 0.000 description 1
- MNNHAPBLZZVQHP-UHFFFAOYSA-N diammonium hydrogen phosphate Chemical compound [NH4+].[NH4+].OP([O-])([O-])=O MNNHAPBLZZVQHP-UHFFFAOYSA-N 0.000 description 1
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 201000010099 disease Diseases 0.000 description 1
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 239000002305 electric material Substances 0.000 description 1
- 230000032050 esterification Effects 0.000 description 1
- 238000005886 esterification reaction Methods 0.000 description 1
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000011151 fibre-reinforced plastic Substances 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 239000012757 flame retardant agent Substances 0.000 description 1
- 239000003546 flue gas Substances 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 125000004836 hexamethylene group Chemical group [H]C([H])([*:2])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[*:1] 0.000 description 1
- TVHALOSDPLTTSR-UHFFFAOYSA-H hexasodium;[oxido-[oxido(phosphonatooxy)phosphoryl]oxyphosphoryl] phosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O TVHALOSDPLTTSR-UHFFFAOYSA-H 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 150000002440 hydroxy compounds Chemical class 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 239000002085 irritant Substances 0.000 description 1
- 231100000021 irritant Toxicity 0.000 description 1
- 238000002955 isolation Methods 0.000 description 1
- NUHSROFQTUXZQQ-UHFFFAOYSA-N isopentenyl diphosphate Chemical compound CC(=C)CCO[P@](O)(=O)OP(O)(O)=O NUHSROFQTUXZQQ-UHFFFAOYSA-N 0.000 description 1
- 239000002648 laminated material Substances 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 210000003041 ligament Anatomy 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229940074869 marquis Drugs 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 239000012567 medical material Substances 0.000 description 1
- VUZPPFZMUPKLLV-UHFFFAOYSA-N methane;hydrate Chemical compound C.O VUZPPFZMUPKLLV-UHFFFAOYSA-N 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 229920003986 novolac Polymers 0.000 description 1
- 229920000620 organic polymer Polymers 0.000 description 1
- MEFUMNTZTUDUBG-UHFFFAOYSA-N oxalonitrile 1,3,5-triazine-2,4,6-triamine Chemical compound N#CC#N.N1=C(N)N=C(N)N=C1N MEFUMNTZTUDUBG-UHFFFAOYSA-N 0.000 description 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical class OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
- YNPNZTXNASCQKK-UHFFFAOYSA-N phenanthrene Chemical group C1=CC=C2C3=CC=CC=C3C=CC2=C1 YNPNZTXNASCQKK-UHFFFAOYSA-N 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- ROMWNDGABOQKIW-UHFFFAOYSA-N phenyliodanuidylbenzene Chemical compound C=1C=CC=CC=1[I-]C1=CC=CC=C1 ROMWNDGABOQKIW-UHFFFAOYSA-N 0.000 description 1
- HVLBHJWRJSDHBW-UHFFFAOYSA-N phosphane;1,3,5-triazine-2,4,6-triamine Chemical compound P.NC1=NC(N)=NC(N)=N1 HVLBHJWRJSDHBW-UHFFFAOYSA-N 0.000 description 1
- IBIRZFNPWYRWOG-UHFFFAOYSA-N phosphane;phosphoric acid Chemical compound P.OP(O)(O)=O IBIRZFNPWYRWOG-UHFFFAOYSA-N 0.000 description 1
- XYFCBTPGUUZFHI-UHFFFAOYSA-O phosphonium Chemical compound [PH4+] XYFCBTPGUUZFHI-UHFFFAOYSA-O 0.000 description 1
- 125000002743 phosphorus functional group Chemical group 0.000 description 1
- 238000006068 polycondensation reaction Methods 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000003340 retarding agent Substances 0.000 description 1
- 238000009738 saturating Methods 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 229920006250 telechelic polymer Polymers 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 238000005979 thermal decomposition reaction Methods 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 238000001721 transfer moulding Methods 0.000 description 1
- DQWPFSLDHJDLRL-UHFFFAOYSA-N triethyl phosphate Chemical compound CCOP(=O)(OCC)OCC DQWPFSLDHJDLRL-UHFFFAOYSA-N 0.000 description 1
- WVLBCYQITXONBZ-UHFFFAOYSA-N trimethyl phosphate Chemical compound COP(=O)(OC)OC WVLBCYQITXONBZ-UHFFFAOYSA-N 0.000 description 1
- XZZNDPSIHUTMOC-UHFFFAOYSA-N triphenyl phosphate Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)(=O)OC1=CC=CC=C1 XZZNDPSIHUTMOC-UHFFFAOYSA-N 0.000 description 1
- WTLBZVNBAKMVDP-UHFFFAOYSA-N tris(2-butoxyethyl) phosphate Chemical compound CCCCOCCOP(=O)(OCCOCCCC)OCCOCCCC WTLBZVNBAKMVDP-UHFFFAOYSA-N 0.000 description 1
- 238000004804 winding Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/04—Reinforcing macromolecular compounds with loose or coherent fibrous material
- C08J5/0405—Reinforcing macromolecular compounds with loose or coherent fibrous material with inorganic fibres
- C08J5/043—Reinforcing macromolecular compounds with loose or coherent fibrous material with inorganic fibres with glass fibres
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/04—Reinforcing macromolecular compounds with loose or coherent fibrous material
- C08J5/0405—Reinforcing macromolecular compounds with loose or coherent fibrous material with inorganic fibres
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/04—Reinforcing macromolecular compounds with loose or coherent fibrous material
- C08J5/0405—Reinforcing macromolecular compounds with loose or coherent fibrous material with inorganic fibres
- C08J5/042—Reinforcing macromolecular compounds with loose or coherent fibrous material with inorganic fibres with carbon fibres
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/04—Reinforcing macromolecular compounds with loose or coherent fibrous material
- C08J5/046—Reinforcing macromolecular compounds with loose or coherent fibrous material with synthetic macromolecular fibrous material
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2363/00—Characterised by the use of epoxy resins; Derivatives of epoxy resins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2423/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2423/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2423/04—Homopolymers or copolymers of ethene
- C08J2423/06—Polyethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2463/00—Characterised by the use of epoxy resins; Derivatives of epoxy resins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2477/00—Characterised by the use of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2477/00—Characterised by the use of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Derivatives of such polymers
- C08J2477/10—Polyamides derived from aromatically bound amino and carboxyl groups of amino carboxylic acids or of polyamines and polycarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2217—Oxides; Hydroxides of metals of magnesium
- C08K2003/2224—Magnesium hydroxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2227—Oxides; Hydroxides of metals of aluminium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/32—Phosphorus-containing compounds
- C08K2003/321—Phosphates
- C08K2003/322—Ammonium phosphate
- C08K2003/323—Ammonium polyphosphate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/38—Boron-containing compounds
- C08K2003/387—Borates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/32—Phosphorus-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/3467—Heterocyclic compounds having nitrogen in the ring having more than two nitrogen atoms in the ring
- C08K5/3477—Six-membered rings
- C08K5/3492—Triazines
- C08K5/34928—Salts
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/51—Phosphorus bound to oxygen
- C08K5/52—Phosphorus bound to oxygen only
- C08K5/521—Esters of phosphoric acids, e.g. of H3PO4
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K7/00—Use of ingredients characterised by shape
- C08K7/02—Fibres or whiskers
- C08K7/04—Fibres or whiskers inorganic
- C08K7/06—Elements
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K7/00—Use of ingredients characterised by shape
- C08K7/02—Fibres or whiskers
- C08K7/04—Fibres or whiskers inorganic
- C08K7/10—Silicon-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K7/00—Use of ingredients characterised by shape
- C08K7/02—Fibres or whiskers
- C08K7/04—Fibres or whiskers inorganic
- C08K7/14—Glass
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
本发明公开了一种纤维增强复合材料及其制备方法,该纤维增强复合材料包括如下重量份数的组分:环氧树脂10~50份;光引发剂0.1~2份;增韧剂5~10份;阻燃剂10~25份;阻燃协效剂0~15份;增强纤维15~35份。该纤维增强复合材料力学性能和阻燃性能优良。
Description
技术领域
本发明涉及纤维增强复合材料技术领域,尤其涉及一种纤维增强复合材料及其制备方法。
背景技术
纤维增强复合材料是由高强度、高模量、连续纤维或者不连续纤维与树脂基体复合而成。树脂基体的作用是通过界面将载荷有效的传递到增强相,增强相可以是晶须、纤维等,树脂基体不是主承力相。纤维的作用是承受由树脂基体传递来的有效载荷,是属于主承力相。当材料收到较大的应力时,一些有裂纹的纤维可能先短,但是树脂基体能阻碍裂纹扩展病改变裂纹扩展方向。增强纤维材料,如玻璃纤维、碳纤维、玄武岩纤维、芳纶纤维、尼龙纤维、聚苯硫醚纤维、超高分子量聚乙烯纤维、聚酰亚胺纤维中的至少一种等,与树脂基体经过手糊、真空导流、树脂传递模塑成型、缠绕、拉挤、模压、真空袋压、热压罐等成型工艺而形成的复合材料。由于纤维增强复合材料具有如下特点:(1)比重小、重量轻;(2)比强度比模量高;(3)可设计性强,加工工艺性好;(4)抗疲劳断裂性能好;(5)耐久性、抗腐蚀与辐射性能好;(6)低热膨胀系数;(7)热容量小;(8)破坏安全性高。这些特点使得FRP材料是发展现代工业、国防和科学技术不可缺少的基础材料,也是新技术革命赖以发展的重要物质基础,复合材料已成为新材料领域的重要主导材料。航天飞行器的重量每减少1公斤,就可使运载火箭减轻500公斤。现在的F1(世界一级方程锦标赛)赛车,车身大部分结构都用纤维增强复合材料,顶级跑车的一大卖点也是周身使用碳纤维,用以提高气动性和结构强度。还可用作飞机结构材料、电磁屏蔽除电材料、人工韧带等身体代用材料,以及用于制造火箭外壳、机动船、工业机器人、汽车板簧和驱动轴等核心组成部件。
光固化复合材料以其固化速度快、节能、污染少等优点已被用于各个领域。光固化材料的适用范围广泛,已应用于层压材料、航空玻璃、压敏胶、光学材料的粘结、封装材料等,还可用于信息技术领域,如光纤保护与着色、磁介质、光介质等,以及光固化补牙等生物及医学应用医疗材料等领域。随着光固化材料和技术的发展,光固化复合材料的应用范围会继续扩大。
纤维增强树脂基复合材料中树脂基体的主要性能与作用为:1.将纤维粘合成整体并使纤维位置固定,在纤维之间传递载荷,并使载荷均衡;2.决定复合材料的一些性能,如复合材料的耐热性、剪切性能、耐介质性能等;3.决定复合材料的成型工艺方法和工艺参数的选择;4.保护纤维免受各种损伤;5.树脂基体对复合材料如横向性能、纵向性能、压缩性能、疲劳性能、断裂韧性等力学性能也有一定的影响。所以开发合适的树脂基体材料非常关键。
一般高分子复合材料的阻燃性能比较差,复合材料的燃烧性能是指材料燃烧的热量释放和火焰延伸情况。随着飞机、高铁、客车等于人民生活非常贴近的交通工具的发展,以及复合材料在交通工具上的内外饰以及受力件的应用,对复合材料的阻燃性能要求越来越高,其关键评价指标包括:表面火焰延伸、火势扩展(热量释放)、烟密度、烟气毒性等。复合材料的阻燃性能主要是通过添加阻燃剂来获得。目前我国使用的阻燃剂主要以有机卤系阻燃剂为主,尽管它与有机高聚物相容性好,阻燃效果好,添加量很少,对材料的其它性能影响很小,但在燃烧过程中发烟量较大,且释放出有毒性、腐蚀性的卤化氢气体。为了防止燃烧产生的烟雾所带来的二次灾害,人们对无卤阻燃材料的使用愈来愈重视,寻求综合性能好的高效无卤阻燃体系,对开发无卤阻燃复合材料是极为重要的问题。
因此,开发出具有良好阻燃防火性能并且制备工艺简单、低能耗、高效环保的纤维增强复合材料是一个很重要的研究方向。
发明内容
为了克服现有技术的不足,本发明的目的在于提供一种纤维增强复合材料及其制备方法,该纤维增强复合材料力学性能和阻燃性能优良。
本发明的目的采用如下技术方案实现:
一种纤维增强复合材料,包括如下重量份数的组分:
环氧树脂10~50份;
光引发剂0.1~2份;
增韧剂5~10份;
阻燃剂10~25份;
阻燃协效剂0~15份;
增强纤维15~35份。
进一步地,所述纤维增强复合材料包括如下重量份数的组分:环氧树脂20份,光引发剂0.15份,增韧剂5份,阻燃剂15份,增强纤维15份;或者,
环氧树脂40份,光引发剂0.45份,增韧剂5份,阻燃剂15份,增强纤维15份;或者,
环氧树脂30份,光引发剂0.33份,增韧剂5份,阻燃剂10份,阻燃协效剂5份,增强纤维15份;或者,
环氧树脂20份,光引发剂0.15份,增韧剂5份,阻燃剂10份,阻燃协效剂5份,增强纤维15份。
进一步地,所述环氧树脂为缩水甘油醚类环氧树脂、缩水甘油酯类环氧树脂、缩水甘油胺类环氧树脂、脂环族环氧树脂、海因环氧树脂中的至少一种。
进一步地,所述光引发剂为碘鎓盐、硫鎓盐、茂铁盐中的至少一种。
进一步地,所述增韧剂为环氧化端羟基聚丁二烯、端羟基聚丁二烯丙烯腈、端羟基聚丁二烯、端羟基液体丁腈橡胶中的至少一种。
进一步地,所述阻燃剂为磷酸酯、DOPO型含磷环氧树脂、三聚氰胺磷酸盐、聚磷酸铵、三聚氰胺氰尿酸盐、次磷酸铝、次磷酸钙、次磷酸钠中的至少一种。
进一步地,所述阻燃协效剂为硼酸锌、三嗪成炭剂、氢氧化镁、氢氧化铝中的至少一种。
进一步地,所述增强纤维为玻璃纤维、玄武岩纤维、碳纤维、芳纶纤维、尼龙纤维、聚苯硫醚纤维、超高分子量聚乙烯纤维、聚酰亚胺纤维中的至少一种。
本发明还提供一种如上所述纤维增强复合材料的制备方法,包括如下步骤:
将环氧树脂、光引发剂、增韧剂、阻燃剂和阻燃协效剂按重量份数比例投入反应容器内,在预设转速条件下搅拌第一预设时间至混合均匀,得到第一中间体,所述预设转速为2000~5000转/分钟,所述第一预设时间为15~45分钟;
将所述增强纤维与所述第一中间体进行浸渍第二预设时间,得到第二中间体,所述第二预设时间为5~20分钟;
将所述第二中间体置于紫外光下照射、固化,得到所述纤维增强复合材料。
进一步地,所述预设转速为2500~3500转/分钟,所述第一预设时间为30分钟;且/或,
所述第二预设时间为8分钟。
相比现有技术,本发明的有益效果在于:
(1)本发明制备得到的纤维增强复合材料的物理力学性能、加工性能、表面外观性能良好、阻燃性能优良。断裂伸长率可达3.5%,拉伸强度可达69MPa,冲击强度可达70MPa,弯曲强度可达135MPa,弯曲模量可达7.1MPa,阻燃性能满足UL94-V0等级。
(2)本发明的纤维增强复合材料的制备工艺简单,低能耗,高效环保。可广泛地应用于各种复合材料电线槽、建筑装饰板、轨道交通内饰件、游艇内饰件、飞机内部复合材料管道以及各个领域的结构件等。
具体实施方式
下面,结合具体实施方式,对本发明做进一步描述,需要说明的是,在不相冲突的前提下,以下描述的各实施例之间或各技术特征之间可以任意组合形成新的实施例。
本发明实施例提供的纤维增强复合材料包括如下重量份数的组分:环氧树脂10~50份;光引发剂0.1~2份;增韧剂5~10份;阻燃剂10~25份;阻燃协效剂0~15份;增强纤维15~35份。
作为优选的实施方式,所述纤维增强复合材料包括如下重量份数的组分:环氧树脂20份,光引发剂0.15份,增韧剂5份,阻燃剂15份,增强纤维15份。
环氧树脂40份,光引发剂0.45份,增韧剂5份,阻燃剂15份,增强纤维15份。
环氧树脂30份,光引发剂0.33份,增韧剂5份,阻燃剂10份,阻燃协效剂5份,增强纤维15份。
环氧树脂20份,光引发剂0.15份,增韧剂5份,阻燃剂10份,阻燃协效剂5份,增强纤维15份。
作为优选的实施方式,所述环氧树脂为缩水甘油醚类环氧树脂、缩水甘油酯类环氧树脂、缩水甘油胺类环氧树脂、脂环族环氧树脂、海因环氧树脂中的至少一种。
脂环族环氧树脂包括3,4-环氧环己基甲基3,4-环氧环己基甲酸酯、双((3,4-环氧环己基)甲基)己二酸酯、3,4-环氧环己基甲基丙烯酸酯、1,2-环氧-4-乙烯基环己烷、4-乙烯基-1-环己烯二环氧化物、双环戊二烯二环氧化物等其中的一种或多种的混合。缩水甘油醚环氧树脂包括双酚A缩水甘油醚环氧树脂、氢化双酚A二缩水甘油醚环氧树脂、双酚F缩水甘油醚环氧树脂、间苯二酚缩水甘油醚环氧树脂、线型酚醛缩水甘油醚环氧树脂、双酚S缩水甘油醚环氧树脂、双酚AD缩水甘油醚环氧树脂等中的至少一种。缩水甘油酯环氧树脂包括四氢邻苯二甲酸双缩水甘油酯、环己烷-1,2-二羧酸二缩水甘油酯、4,5-环氧环己烷-1,2-二甲酸二缩水甘油酯中的至少一种。缩水甘油胺类环氧树脂包括4.4-二氨基二苯甲烷四缩水甘油胺(TGDDM)、三缩水甘油基对氨基苯酚(TGPAP)中的至少一种。海因环氧树脂是分子结构中含有海因环(五元二氮杂环)的一类缩水甘油胺型环氧树脂,最常见的是二甲基海因环氧树脂。
作为优选的实施方式,所述光引发剂为碘鎓盐、硫鎓盐、茂铁盐中的至少一种。
作为优选的实施方式,所述增韧剂为环氧化端羟基聚丁二烯、端羟基聚丁二烯丙烯腈、端羟基聚丁二烯、端羟基液体丁腈橡胶中至少一种。环氧化端羟基液体聚丁二烯,英文缩写为EHTPB,其是在端羟基聚丁二烯大分子上引入环氧基团,不但有效提高大分子极性,而且引入的环氧基团作为反应性官能团,可以与环氧树脂交联固化过程中产生的活泼氢发生进一步交联,提高环氧树脂固化物的力学性能,粘合强度和耐热性。此外,因引入环氧基团,使增韧剂EHTPB常温下就可以直接与环氧树脂混合,无需预反应就有非常好的相容性。
端羟基聚丁二烯丙烯腈,英文缩写HTBN,由于分子链中引入了腈基,因而丁腈羟液体橡胶除了具有端羟基聚丁二烯的一般特性外,还具有良好的耐油性、粘接性、耐老化性、耐低温性能。端羟基聚丁二烯丙烯腈主要是利用端羟基特性与双官能团的分子反应进行链的延伸,进而交联,生成有弹性的长链聚合物。
端羟基液体聚丁二烯,英文缩写为HTPB,是一种液体遥爪聚合物,是一种新型液体橡胶。反应可以生成三维网络结构的固化物。该固化物具有优异的力学性能,特别具有耐水解、耐酸碱、耐磨、耐低温和优异电绝缘性。
端羧基液态丁腈橡胶,英文缩写为CTBN,其分子链的两端是活性官能团羧基,通过羧基与环氧树脂发生反应,从而实现对环氧树脂的改性,增韧改性效果显著。在一定相对分子质量范围内,CTBN的相对分子质量越大,其增韧效果越佳。
作为优选的实施方式,所述的阻燃剂为磷酸酯、DOPO型含磷环氧树脂、三聚氰胺磷酸盐、聚磷酸铵、三聚氰胺氰尿酸盐、次磷酸铝、次磷酸钙、次磷酸钠中的至少一种。可以理解的,DOPO型含磷环氧树脂为9,10-二氢-9-氧杂-10-磷杂菲-10-氧化物改性环氧树脂。
磷酸酯应用于环氧树脂中,具有良好的相容性、并可降低树脂粘度,使得树脂体系对纤维的浸润性好,同时由于磷酸酯高纯度,透明性,单独使用时可以制作阻燃透明环氧树脂体系,提升树脂的透光性,提高固化速度。磷酸酯阻燃剂可以是:磷酸三乙酯(英文缩写为TEP)、磷酸三丁酯(英文缩写为TBP)、磷酸三(丁氧基乙基)酯(英文缩写为TBEP)、磷酸三异丙基苯酯(英文缩写为IPPP)、磷酸二异辛酯(英文缩写为P204)、磷酸三苯酯(英文缩写为TPP)、亚磷酸三苯酯(英文缩写为TPP)、磷酸三甲苯酯(英文缩写为TCP)、磷酸三甲酯(英文缩写为TMP)、亚磷酸一苯二异癸酯(英文缩写为PDDP)、亚磷酸二苯一异癸酯(英文缩写为DPDP)、亚磷酸一苯二异辛酯(英文缩写为PDOP)、亚磷酸一苯二异辛酯(英文缩写为PDOP)、亚磷酸二苯一异辛酯(英文缩写为DPOP)、亚磷酸一苯二异癸酯(英文缩写为PDDP)中至少一种。
DOPO是新型阻燃剂中间体,其结构中含有P-H键,对烯烃、环氧键和羰基极具活性,可反应生成许多衍生物。DOPO及其衍生物由于分子结构中含有联苯环和菲环结构,特别是侧磷基团以环状O=P-O键的方式引入,比一般的、未成环的有机磷酸酯热稳定性和化学稳定性高,阻燃性能更好。DOPO及DOPO与环氧树脂预反应的衍生物可作为反应型和添加型阻燃剂,合成的阻燃剂无卤、无烟、无毒,不迁移,阻燃性能持久。当该种环氧树脂被引燃时,其分解产生磷的含氧酸,这类酸能催化含羟基化合物发生吸热脱水成碳反应,生成水和焦炭,含羟基化合物炭化的结果是在其表面生成石墨状焦炭层,该炭层难燃、隔热、隔氧。同时,由于焦炭层的导热性差,使传递至基材的热量减少,基材热分解减缓。此外,羟基化合物的脱水系吸热反应,且脱水形成的水蒸汽又能稀释大气中的氧气及可燃性气体的浓度,有助于中断燃烧。磷酸还可以进一步脱水酯化形成聚磷酸,聚磷酸为一玻璃状熔融体,覆盖于燃烧物体表面,阻止氧气接近及挥发性物质释放来阻止燃烧。本发明的一个实施例中,使用DOPO时将DOPO与环氧氯丙烷反应,然后与对苯二酚反应,添加到环氧树脂中形成反应型含磷阻燃剂,具有低挥发性,低污染性,与环氧树脂都有良好的相溶性,添加后形成反应型阻燃透明树脂体系,不影响透光性,由于阻燃剂参与反应固保持了树脂体系良好的力学性能。
三聚氰胺磷酸盐是一种含氮磷结构的膨胀型阻燃剂。该阻燃剂高温下(例如300度)分解释放出来的磷酸可以在易燃聚合物的表面形成保护膜的覆盖作用,减少氧气的进入。利用氮磷协同阻燃,通过调整单体阻燃分子内N含量和磷含量,满足不同阻燃等级对氮和磷的不同含量的要求。三聚氰胺磷酸盐不同于以往的含卤型阻燃剂,在环氧树脂加工过程中对设备和模具无腐蚀;燃烧时产生致密的膨胀碳层达到隔热隔绝空气阻燃的性能,不会产生有刺激性卤化氢气体以及燃烧黑烟,是一种理想的环保型的阻燃剂。
聚磷酸铵又称多聚磷酸铵或缩聚磷酸铵(简称APP),是一种含N和P的聚磷酸盐。其分子中同时含有磷、氮两种元素,在阻燃过程中,磷、氮具有协同阻燃效应,因而阻燃效果优于单含磷阻燃剂或单含氮阻燃剂。聚磷酸铵添加到环氧树脂中具有含磷量大、含氮量高、热稳定性好、吸湿性小、分散性好、毒性低、抑烟等特点。
三聚氰胺氰尿酸盐(MCA)是一种含氮的高效无卤环保阻燃剂。在300℃以下受热时非常稳定,350℃左右开始升华,约440~450℃时开始分解。含氮量高,高温时脱水成炭,燃烧时释放氮气、二氧化碳和水。其阻燃机理为:升华吸热及气相阻燃。
次磷酸铝、次磷酸钙和次磷酸钠阻燃剂是以磷酸盐为基的一种新型的阻燃剂,具有较高的热稳定性,在加工过程中具有较好的机械性能和较好的抗侯性,含有磷酸盐的环氧树脂组合物呈现较高的阻燃性,由于磷酸盐含磷量高,添加后放热率和燃烧时产生的热量急剧减少,燃烧后的成炭量增加,具有热稳定性好、水溶性小、阻燃效力大等优点,能够取得很高的阻燃效果。
作为优选的实施方式,所述的阻燃协效剂为硼酸锌、三嗪成炭剂、氢氧化镁、氢氧化铝中的至少一种。三嗪成炭剂主要用于无卤膨胀型阻燃剂的炭源。与传统的季戊四醇类成炭剂相比,其水溶性极低,不迁移,且成炭性能优异,可与其他助剂复配成无卤膨胀阻燃剂。
作为优选的实施方式,所述增强纤维为玻璃纤维、玄武岩纤维、碳纤维、芳纶纤维、尼龙纤维、聚苯硫醚纤维、超高分子量聚乙烯纤维、聚酰亚胺纤维中的至少一种。可以理解的,增强纤维是指由玻璃纤维、玄武岩纤维、碳纤维、芳纶纤维、尼龙纤维、聚苯硫醚纤维、超高分子量聚乙烯纤维、聚酰亚胺纤维中的至少一种等所制成的短切纤维纱、连续纤维纱、纤维编织布、纤维毡及表面毡中的至少一种。
本发明还提供一种如上所述纤维增强复合材料的制备方法,包括如下步骤:
将环氧树脂、光引发剂、增韧剂、阻燃剂和阻燃协效剂按重量份数比例投入反应容器内,在预设转速条件下搅拌第一预设时间至混合均匀,得到第一中间体,所述预设转速为2000~5000转/分钟,所述第一预设时间为15~45分钟;
将所述增强纤维与所述第一中间体进行浸渍第二预设时间,得到第二中间体,所述第二预设时间为5~20分钟;
将所述第二中间体置于紫外光下照射、固化,得到所述纤维增强复合材料。
作为优选的实施方式,所述预设转速为2500~3500转/分钟,所述第一预设时间为30分钟。所述第二预设时间为8分钟。
实施例1
该实施例的所述纤维增强复合材料包括如下重量份数的组分:双酚A缩水甘油醚环氧树脂(E51)15份,3,4-环氧环己基甲基-3,4-环氧环己基甲酸酯(2021P)5份,4,4-二甲基-二苯基碘翁六氟磷酸0.15份,环氧化端羟基液体聚丁二烯(EHTPB)5份,DOPO型含磷环氧树脂10份,三聚氰胺氰尿酸盐(MCA)5份,玻璃纤维15份。
本实施例的纤维增强复合材料的制备方法如下:将双酚A缩水甘油醚环氧树脂、3,4-环氧环己基甲基-3,4-环氧环己基甲酸酯、4,4-二甲基-二苯基碘翁六氟磷酸、环氧化端羟基液体聚丁二烯、DOPO型含磷环氧树脂、三聚氰胺氰尿酸盐按重量份数比例投入带有盘式高速分散机搅拌器的混合容器中,在3000转/分钟条件下搅拌30分钟至混合均匀,得到第一中间体。按重量份数比例将所述玻璃纤维与所述第一中间体进行浸渍8分钟,得到第二中间体。将所述第二中间体取出后挤出多余的树脂沥干,在紫外光下照射、固化,得到所述纤维增强复合材料。
实施例2
该实施例的所述纤维增强复合材料包括如下重量份数的组分:4.4-二氨基二苯甲烷四缩水甘油胺(TGDDM)20份,3,4-环氧环己基甲基-3,4-环氧环己基甲酸酯(2021P)20份,三苯基硫鎓盐0.45份,端羟基液体丁腈橡胶(CTBN)5份,磷酸酯5份,聚磷酸铵5份,次磷酸铝5份,玄武岩纤维15份。
本实施例的纤维增强复合材料的制备方法如下:将4.4-二氨基二苯甲烷四缩水甘油胺、3,4-环氧环己基甲基-3,4-环氧环己基甲酸酯、三苯基硫鎓盐按重量份数比例投入带有盘式高速分散机搅拌器的混合容器中,然后按重量份数比例投入端羟基液体丁腈橡胶、磷酸酯、聚磷酸铵、次磷酸铝,在3000转/分钟条件下搅拌30分钟至混合均匀,得到第一中间体。按重量份数比例将所述玄武岩纤维与所述第一中间体进行浸渍8分钟,得到第二中间体。将所述第二中间体取出后挤出多余的树脂沥干,在紫外光下照射、固化,得到所述纤维增强复合材料。
实施例3
该实施例的所述纤维增强复合材料包括如下重量份数的组分:3,4-环氧环己基甲基-3,4-环氧环己基甲酸酯(2021P)20份,聚[(2-环氧乙烷基)-1,2-环己二醇]2-乙基-2-(羟甲基)-1,3-丙二醇醚(3:1)(3150)30份,二苯基碘鎓六氟磷酸盐0.33份,端羟基聚丁二烯丙烯腈5份,聚磷酸铵5份,三聚氰胺氰尿酸盐5份,氢氧化铝5份,碳纤维15份。
本实施例的纤维增强复合材料的制备方法如下:将3,4-环氧环己基甲基-3,4-环氧环己基甲酸酯(2021P)、聚[(2-环氧乙烷基)-1,2-环己二醇]2-乙基-2-(羟甲基)-1,3-丙二醇醚(3:1)(3150)、二苯基碘鎓六氟磷酸盐按重量份数比例投入带有盘式高速分散机搅拌器的混合容器中,按重量份数比例再加入端羟基聚丁二烯丙烯腈、聚磷酸铵、三聚氰胺氰尿酸盐、氢氧化铝,在3000转/分钟条件下搅拌30分钟至混合均匀,得到第一中间体。按重量份数比例将所述碳纤维与所述第一中间体进行浸渍8分钟,得到第二中间体。将所述第二中间体取出后挤出多余的树脂沥干,在紫外光下照射、固化,得到所述纤维增强复合材料。
实施例4
该实施例的所述纤维增强复合材料包括如下重量份数的组分:4,5-环氧环己烷-1,2-二甲酸二缩水甘油酯(186)10份,3,4-环氧环己基甲基-3,4-环氧环己基甲酸酯(2021P)10份,三苯基硫鎓盐0.15份,环氧化端羟基液体聚丁二烯(EHTPB)5份,聚磷酸铵5份,三聚氰胺聚磷酸盐5份,氢氧化镁5份,芳纶纤维15份。
本实施例的纤维增强复合材料的制备方法如下:将4,5-环氧环己烷-1,2-二甲酸二缩水甘油酯(186)、3,4-环氧环己基甲基-3,4-环氧环己基甲酸酯(2021P)、三苯基硫鎓盐按重量份数比例投入带有盘式高速分散机搅拌器的混合容器中,按重量份数比例再加入环氧化端羟基液体聚丁二烯(EHTPB)、聚磷酸铵5份、三聚氰胺聚磷酸盐、氢氧化镁,在3000转/分钟条件下搅拌30分钟至混合均匀,得到第一中间体。按重量份数比例将所述芳纶纤维与所述第一中间体进行浸渍8分钟,得到第二中间体。将所述第二中间体取出后挤出多余的树脂沥干,在紫外光下照射、固化,得到所述纤维增强复合材料。
实施例5
该实施例的所述纤维增强复合材料包括如下重量份数的组分:海因环氧树脂10份,3,4-环氧环己基甲基-3,4-环氧环己基甲酸酯(2021P)10份、二苯基碘鎓六氟磷酸盐0.1份、二苯基-(4-苯基硫)苯基锍六氟磷酸盐0.05份,端羟基液体丁腈橡胶(CTBN)5份及DOPO型含磷环氧树脂5份,聚磷酸铵(APP)5份,硼酸锌5份,尼龙纤维15份。
本实施例的纤维增强复合材料的制备方法如下:将海因环氧树脂、3,4-环氧环己基甲基-3,4-环氧环己基甲酸酯(2021P)、二苯基碘鎓六氟磷酸盐、二苯基-(4-苯基硫)苯基锍六氟磷酸盐按重量份数比例投入带有盘式高速分散机搅拌器的混合容器中。按重量份数比例再投入端羟基液体丁腈橡胶(CTBN)及DOPO型含磷环氧树脂,聚磷酸铵(APP)、硼酸锌,在3000转/分钟条件下搅拌30分钟至混合均匀,得到第一中间体。按重量份数比例将所述尼龙纤维与所述第一中间体进行浸渍8分钟,得到第二中间体。将所述第二中间体取出后挤出多余的树脂沥干,在紫外光下照射、固化,得到所述纤维增强复合材料。
实施例6
该实施例的所述纤维增强复合材料包括如下重量份数的组分:3,4-环氧环己基甲基-3,4-环氧环己基甲酸酯(2021P)10份,4.4-二氨基二苯甲烷四缩水甘油胺(TGDDM)AG805份,双酚A缩水甘油醚环氧树脂(128)5份、三苯基硫鎓盐0.3份及二苯基-(4-苯基硫)苯基锍六氟磷酸盐0.5份,环氧化端羟基液体聚丁二烯(EHTPB)5份,聚磷酸铵(APP)5份,三聚氰胺氰尿酸盐(MCA)5份,次磷酸钠3份,三嗪成炭剂2份,超高分子量聚乙烯纤维15份。
本实施例的纤维增强复合材料的制备方法如下:将3,4-环氧环己基甲基-3,4-环氧环己基甲酸酯(2021P)、4.4-二氨基二苯甲烷四缩水甘油胺(TGDDM)AG80、双酚A缩水甘油醚环氧树脂(128)、三苯基硫鎓盐及二苯基-(4-苯基硫)苯基锍六氟磷酸盐按重量份数比例投入带有盘式高速分散机搅拌器的混合容器中,按重量份数比例再加入环氧化端羟基液体聚丁二烯(EHTPB)、聚磷酸铵(APP)、三聚氰胺氰尿酸盐(MCA)、次磷酸钠、三嗪成炭剂,在3000转/分钟条件下搅拌30分钟至混合均匀,得到第一中间体。按重量份数比例将所述超高分子量聚乙烯纤维与所述第一中间体进行浸渍8分钟,得到第二中间体。将所述第二中间体取出后挤出多余的树脂沥干,在紫外光下照射、固化,得到所述纤维增强复合材料。
对比例
该实施例的所述纤维增强复合材料包括如下重量份数的组分:双酚A缩水甘油醚环氧树脂(128)30份,脂环族环氧树脂(6110)10份,三苯基硫鎓盐0.3份,磷酸酯10份,氢氧化铝5份,碳纤维15份。
本实施例的纤维增强复合材料的制备方法如下:将双酚A缩水甘油醚环氧树脂(128)、脂环族环氧树脂(6110)、三苯基硫鎓盐按重量份数比例投入带有盘式高速分散机搅拌器的混合容器中,按重量份数比例再加入磷酸酯、氢氧化铝,在3000转/分钟条件下搅拌30分钟至混合均匀,得到第一中间体。按重量份数比例将所述碳纤维与所述第一中间体进行浸渍8分钟,得到第二中间体。将所述第二中间体取出后挤出多余的树脂沥干,在紫外光下照射、固化,得到所述纤维增强复合材料。
按照GBT 1449-2005纤维增强塑料弯曲性能试验方法来对实施例1-6和对比例中弯曲性能进行测试。实施例1-6和对比例中的纤维增强复合材料的综合性能见表1。
表1为实施例1-6和对比例的维增强复合材料的综合性能测试数据
样品编号 | 1 | 2 | 3 | 4 | 5 | 6 | 对比例 |
固化时间(min) | 30 | 20 | 20 | 15 | 15 | 15 | 20 |
断裂伸长率 | 3.3% | 3.5% | 3.6% | 3.8% | 3.2% | 3.5% | 2% |
拉伸强度 | 69 | 68 | 67 | 65 | 65 | 69 | 52 |
冲击强度 | 65 | 67 | 69 | 68 | 66 | 70 | 59 |
弯曲强度 | 130 | 135 | 132 | 130 | 124 | 128 | 105 |
弯曲模量 | 6.3 | 6.6 | 6.2 | 7.1 | 5.8 | 6.5 | 5.8 |
阻燃性 | V-0 | V-0 | V-0 | V-0 | V-0 | V-0 | V-0 |
由上表可以看出,实施例1-6的纤维增强复合材料的综合性能明显高于对比例,表现出较好的力学性能和阻燃性能。
上述实施方式仅为本发明的优选实施方式,不能以此来限定本发明保护的范围,本领域的技术人员在本发明的基础上所做的任何非实质性的变化及替换均属于本发明所要求保护的范围。
Claims (10)
1.一种纤维增强复合材料,其特征在于,包括如下重量份数的组分:
环氧树脂10~50份;
光引发剂0.1~2份;
增韧剂5~10份;
阻燃剂10~25份;
阻燃协效剂0~15份;
增强纤维15~35份。
2.如权利要求1所述的纤维增强复合材料,其特征在于,包括如下重量份数的组分:环氧树脂20份,光引发剂0.15份,增韧剂5份,阻燃剂15份,增强纤维15份;或者,
环氧树脂40份,光引发剂0.45份,增韧剂5份,阻燃剂15份,增强纤维15份;或者,
环氧树脂30份,光引发剂0.33份,增韧剂5份,阻燃剂10份,阻燃协效剂5份,增强纤维15份;或者,
环氧树脂20份,光引发剂0.15份,增韧剂5份,阻燃剂10份,阻燃协效剂5份,增强纤维15份。
3.如权利要求1或2所述的纤维增强复合材料,其特征在于,所述环氧树脂为缩水甘油醚类环氧树脂、缩水甘油酯类环氧树脂、缩水甘油胺类环氧树脂、脂环族环氧树脂、海因环氧树脂中的至少一种。
4.如权利要求1或2所述的纤维增强复合材料,其特征在于,所述光引发剂为碘鎓盐、硫鎓盐、茂铁盐中的至少一种。
5.如权利要求1或2所述的纤维增强复合材料,其特征在于,所述增韧剂为环氧化端羟基聚丁二烯、端羟基聚丁二烯丙烯腈、端羟基聚丁二烯、端羟基液体丁腈橡胶中至少一种。
6.如权利要求1或2所述的纤维增强复合材料,其特征在于,所述的阻燃剂为磷酸酯、DOPO型含磷环氧树脂、三聚氰胺磷酸盐、聚磷酸铵、三聚氰胺氰尿酸盐、次磷酸铝、次磷酸钙、次磷酸钠中的至少一种。
7.如权利要求1或2所述的纤维增强复合材料,其特征在于,所述的阻燃协效剂为硼酸锌、三嗪成炭剂、氢氧化镁、氢氧化铝中的至少一种。
8.如权利要求1或2所述的纤维增强复合材料,其特征在于,所述增强纤维为玻璃纤维、玄武岩纤维、碳纤维、芳纶纤维、尼龙纤维、聚苯硫醚纤维、超高分子量聚乙烯纤维、聚酰亚胺纤维中的至少一种。
9.一种如权利要求1-8任一项所述纤维增强复合材料的制备方法,其特征在于,包括如下步骤:
将环氧树脂、光引发剂、增韧剂、阻燃剂和阻燃协效剂按重量份数比例投入反应容器内,在预设转速条件下搅拌第一预设时间至混合均匀,得到第一中间体,所述预设转速为2000~5000转/分钟,所述第一预设时间为15~45分钟;
将所述增强纤维与所述第一中间体进行浸渍第二预设时间,得到第二中间体,所述第二预设时间为5~20分钟;
将所述第二中间体置于紫外光下照射、固化,得到所述纤维增强复合材料。
10.如权利要求9所述的纤维增强复合材料的制备方法,其特征在于,所述预设转速为2500~3500转/分钟,所述第一预设时间为30分钟;且/或,
所述第二预设时间为8分钟。
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201811013055.0A CN109438918A (zh) | 2018-08-31 | 2018-08-31 | 一种纤维增强复合材料及其制备方法 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201811013055.0A CN109438918A (zh) | 2018-08-31 | 2018-08-31 | 一种纤维增强复合材料及其制备方法 |
Publications (1)
Publication Number | Publication Date |
---|---|
CN109438918A true CN109438918A (zh) | 2019-03-08 |
Family
ID=65533204
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201811013055.0A Pending CN109438918A (zh) | 2018-08-31 | 2018-08-31 | 一种纤维增强复合材料及其制备方法 |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN109438918A (zh) |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN110540707A (zh) * | 2019-09-14 | 2019-12-06 | 福建师范大学 | 一种多元阻燃聚丙烯材料及其制备方法 |
CN110713697A (zh) * | 2019-09-26 | 2020-01-21 | 江苏恒神股份有限公司 | 一种满足EN45545阻燃标准的OoA工艺用预浸料 |
CN114957919A (zh) * | 2022-06-13 | 2022-08-30 | 广州睿洁科技有限公司 | 一种高反射隔热玻璃钢及其制备方法 |
CN115011018A (zh) * | 2022-06-23 | 2022-09-06 | 青岛优派普环保科技股份有限公司 | 一种pe燃气管及其制备方法 |
CN115893342A (zh) * | 2022-11-30 | 2023-04-04 | 国网重庆市电力公司电力科学研究院 | 一种次磷酸铝改性聚磷酸铵核壳的方法 |
PL442733A1 (pl) * | 2022-11-03 | 2024-05-06 | Centralny Instytut Ochrony Pracy - Państwowy Instytut Badawczy | Hybrydowy kompozyt epoksydowy o zmniejszonej palności i dymotwórczości |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104177781A (zh) * | 2014-08-23 | 2014-12-03 | 青岛优维奥信息技术有限公司 | 一种阻燃环氧预浸料复合材料 |
CN104945857A (zh) * | 2015-06-18 | 2015-09-30 | 石狮华宝新材料工程有限公司 | 光固化纤维增强复合片材的配方及生产工艺 |
CN106995583A (zh) * | 2016-01-22 | 2017-08-01 | 北京化工大学常州先进材料研究院 | 一种光固化快速制备纤维增强树脂基复合材料的方法 |
CN107880487A (zh) * | 2016-09-29 | 2018-04-06 | 北京化工大学常州先进材料研究院 | 一种光固化无卤阻燃纤维增强复合材料及其制备方法 |
-
2018
- 2018-08-31 CN CN201811013055.0A patent/CN109438918A/zh active Pending
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104177781A (zh) * | 2014-08-23 | 2014-12-03 | 青岛优维奥信息技术有限公司 | 一种阻燃环氧预浸料复合材料 |
CN104945857A (zh) * | 2015-06-18 | 2015-09-30 | 石狮华宝新材料工程有限公司 | 光固化纤维增强复合片材的配方及生产工艺 |
CN106995583A (zh) * | 2016-01-22 | 2017-08-01 | 北京化工大学常州先进材料研究院 | 一种光固化快速制备纤维增强树脂基复合材料的方法 |
CN107880487A (zh) * | 2016-09-29 | 2018-04-06 | 北京化工大学常州先进材料研究院 | 一种光固化无卤阻燃纤维增强复合材料及其制备方法 |
Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN110540707A (zh) * | 2019-09-14 | 2019-12-06 | 福建师范大学 | 一种多元阻燃聚丙烯材料及其制备方法 |
CN110713697A (zh) * | 2019-09-26 | 2020-01-21 | 江苏恒神股份有限公司 | 一种满足EN45545阻燃标准的OoA工艺用预浸料 |
CN110713697B (zh) * | 2019-09-26 | 2022-05-31 | 江苏恒神股份有限公司 | 一种满足EN45545阻燃标准的OoA工艺用预浸料 |
CN114957919A (zh) * | 2022-06-13 | 2022-08-30 | 广州睿洁科技有限公司 | 一种高反射隔热玻璃钢及其制备方法 |
CN115011018A (zh) * | 2022-06-23 | 2022-09-06 | 青岛优派普环保科技股份有限公司 | 一种pe燃气管及其制备方法 |
CN115011018B (zh) * | 2022-06-23 | 2022-11-29 | 青岛优派普环保科技股份有限公司 | 一种pe燃气管及其制备方法 |
PL442733A1 (pl) * | 2022-11-03 | 2024-05-06 | Centralny Instytut Ochrony Pracy - Państwowy Instytut Badawczy | Hybrydowy kompozyt epoksydowy o zmniejszonej palności i dymotwórczości |
CN115893342A (zh) * | 2022-11-30 | 2023-04-04 | 国网重庆市电力公司电力科学研究院 | 一种次磷酸铝改性聚磷酸铵核壳的方法 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN109438918A (zh) | 一种纤维增强复合材料及其制备方法 | |
Liu et al. | Preparation, thermal properties, and flame retardance of epoxy–silica hybrid resins | |
CN100343336C (zh) | 一种含磷和环氧基的有机硅阻燃剂及其制备方法 | |
KR102309169B1 (ko) | 에폭시 수지 조성물, 경화물, 섬유 강화 복합 재료, 섬유 강화 수지 성형품, 및 섬유 강화 수지 성형품의 제조 방법 | |
CN108997714B (zh) | 用于环氧树脂的反应型阻燃剂及其阻燃环氧树脂 | |
CN106589314B (zh) | 一种二氧化硅与环氧树脂共聚的与液氧相容的复合树脂体系的制备方法 | |
JP5544184B2 (ja) | リン含有エポキシ樹脂の製造方法、エポキシ樹脂組成物及びその硬化物 | |
CN105037723B (zh) | 一种无卤阻燃预聚物及使用其制作的半固化片及层压板 | |
CN113956614A (zh) | 一种低发烟阻燃环氧树脂组成物 | |
Greiner et al. | Prevention of the formation of respirable fibers in carbon fiber reinforced epoxy resins during combustion by phosphorus or silicon containing flame retardants | |
EP3708600B1 (en) | Curable composition and fiber-reinforced composite material | |
CN113881192A (zh) | 一种低烟阻燃的环氧树脂复合材料及其制备方法 | |
WO2011031421A1 (en) | Hydroxyphenyl phosphine oxide mixtures and their use as flame retardants for epoxy resins | |
CN101274998A (zh) | 一种耐热阻燃环氧型电子聚合物材料用含磷硅杂化固化剂及其制备方法 | |
CN103709374A (zh) | 阻燃硅烷偶联剂的制备方法 | |
Greiner et al. | Phosphorylated salicylic acid as flame retardant in epoxy resins and composites | |
JP2002020588A (ja) | 非ハロゲン系でかつ非リン系の難燃剤を含むエポキシ樹脂組成物 | |
CN108485193B (zh) | 一种可用于电子封装材料的阻燃型环氧树脂组合物及其制备方法 | |
CN109401707B (zh) | 一种单组份高耐温抗冲击阻燃型结构胶黏剂及其制备方法 | |
WO2014206487A1 (en) | A halogen free flame retardant epoxy resin composition | |
CN103073585B (zh) | 磷硅氮三元协同阻燃剂及其制备方法与应用 | |
Pack | A review of non-halogen flame retardants in epoxy-based composites and nanocomposites: Flame retardancy and rheological properties | |
JP3354594B2 (ja) | アミノホスファゼン系エポキシ樹脂硬化剤 | |
CN103102471B (zh) | 含磷酚醛树脂及其制造方法、该树脂组合物、固化物 | |
KR20100021409A (ko) | 신규 난연성 에폭시 수지와 그 에폭시 수지를 필수성분으로 하는 에폭시 수지조성물 및 그 경화물 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PB01 | Publication | ||
PB01 | Publication | ||
SE01 | Entry into force of request for substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
RJ01 | Rejection of invention patent application after publication |
Application publication date: 20190308 |
|
RJ01 | Rejection of invention patent application after publication |