CN109437566A - The formula and preparation method thereof of green glaze - Google Patents

The formula and preparation method thereof of green glaze Download PDF

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Publication number
CN109437566A
CN109437566A CN201811646336.XA CN201811646336A CN109437566A CN 109437566 A CN109437566 A CN 109437566A CN 201811646336 A CN201811646336 A CN 201811646336A CN 109437566 A CN109437566 A CN 109437566A
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China
Prior art keywords
parts
raw material
dolomite
mass fraction
albite
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CN201811646336.XA
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袁留福
袁伟瀚
袁淼娟
黄四海
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Lushan Mountain Duan Hua Hua Intangible Cultural Heritage Development Co Ltd
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Lushan Mountain Duan Hua Hua Intangible Cultural Heritage Development Co Ltd
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Publication of CN109437566A publication Critical patent/CN109437566A/en
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    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C8/00Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Glass Compositions (AREA)

Abstract

The invention discloses a kind of formula and preparation method thereof of green glaze, the blueness glaze includes following raw material: potassium feldspar, albite, quartz, dolomite, kaolin and talcum;By above-mentioned grinding raw material at powder, the time of grinding is 48 hours;It is filtered after the completion of grinding, is subsequently placed in shady place and dries up to green glaze.It is excessively high to solve the firing temperature that existing green glaze needs, and burns out the typically more dim problem of rear color.

Description

The formula and preparation method thereof of green glaze
Technical field
The present invention relates to ceramic fields, and in particular to a kind of formula and preparation method thereof of blueness glaze.
Background technique
Green glaze is the famous conventional color glaze of Chinese porcelain, and also known as " celadon glaze ", the green glaze in ancient times south, is the earliest face of porcelain Color glaze, so-called " green glaze ", color is not pure blueness, is had: bluish white, reddish black, pale blue, plum green, pea green, pea green, emerald green blueness etc., But some dark greens how much can be glowed, meanwhile, often by green, green, blue three-color, one is referred to as " cyan " ancients, such as Perhaps weighing apparatus " drink stream vegetarian say porcelain " claims: " old china is still green, it is all it is green also, Lan Ye, it is all included with blueness." in Liu Zifen " bamboo plantation Tao Shuo " Say: " cyan is a kind of, often with it is blue mutually mixed, the sun shines again after the rain, the blueness of an ancient unit of weight kiln, first kiln, all close blue " " only thousand peaks in emerald colour, plum green, It is pea green, be for pure green ear.This indigo plant of the colour of sky is sometimes blueness ".
But present porcelain green glaze for using when firing usually requires higher temperature and could be burnt into, and fires simultaneously Green glaze color out is generally all dimer.
Summary of the invention
The purpose of the present invention is to provide a kind of formulas and preparation method thereof of green glaze, solve the firing that existing green glaze needs Temperature is excessively high, and burns out the typically more dim problem of rear color.
In order to solve the above technical problems, the invention adopts the following technical scheme:
A kind of formula of blueness glaze, including following raw material: potassium feldspar, albite, quartz, dolomite, kaolin and talcum.
It is fired using dolomite, since dolomite is compared to calcite, contains magnesium elements, and magnesium is having oxygen In the case where be easy to generate magnesia, fluxing agent can be played the role of, therefore it is lower to make to fire required temperature, using potassium feldspar With two kinds of feldspar mixing of albite, the transparency of albite is good, solution high temperature viscosity is small, varies with temperature fastly, and potassium feldspar is burnt It is wider at temperature range, can make after the two mixing glaze when firing variation more evenly, after firing, glaze colours just more evenly, and color More highlighted, the effect burnt out is good.
As present invention further optimization, the mass fraction of the raw material is as follows: 23-28 parts of potassium feldspar, albite 15-22 parts, 23-28 parts of quartz, 15-20 parts of dolomite, 5-10 parts of kaolin, 3-7 parts of talcum.
As present invention further optimization, the mass fraction of the raw material is as follows: 24-27 parts of potassium feldspar, albite 17-21 parts, 23.5-26.5 parts of quartz, 16-19 parts of dolomite, 7-9 parts of kaolin, 3.5-6.5 parts of talcum.
As present invention further optimization, the mass fraction of the raw material is as follows: 24.5-26 parts of potassium feldspar, sodium are long 18-20.5 parts of stone, 24-26 parts of quartz, 16.5-18.5 parts of dolomite, 7.5-8.8 parts of kaolin, 4-6 parts of talcum.
As present invention further optimization, the mass fraction of the raw material is as follows: 24.8-25.5 parts of potassium feldspar, sodium 19-20.4 parts of feldspar, 24.5-25.5 parts of quartz, 16.6-18 parts of dolomite, 7.7-8.5 parts of kaolin, 4.5-5.6 parts of talcum.
As present invention further optimization, the mass fraction of the raw material is as follows: 25 parts of potassium feldspar, albite 20 Part, quartzy 25 parts, 17 parts of dolomite, 8 parts of kaolin, 5 parts of talcum.
Further include as present invention further optimization, in the raw material 2-4 parts of mass fractions chrome ore, 1-3 parts The plant ash of mass fraction.
Joined chrome ore is because containing Cr2O2 in chrome ore, and Cr2O2 can be used as colorant under high temperature, instead of Fe2O3 reduces the use of colorant, while the plant ash calcium P elements rich in being added in this way, can be used as fluxing agent, The suspension having in glaze slip can reduce the high temperature viscosity of glaze and the melting temperature of further reduction glaze, but also have Opaque has facilitation to chun glaze split-phase.
A method of green glaze is prepared by any of the above-described green glaze formula, includes the following steps: a, grind raw material Grinds, the time of grinding are 48 hours;B, it is filtered after the completion of grinding, is subsequently placed in shady place and dries.
Grinding 48 hours is to adequately grind uniformly, and In Shade to dry rather than dry be then in order to prevent Ingredient in raw material occurs oxidation reaction in drying and generates impurity, reduces the quality burnt out.
Compared with prior art, the present invention can at least reach one in following beneficial effect:
1. melting temperature is lower, 1290 DEG C can be reduced to from 1400 DEG C, the green glaze color burnt out be evenly distributed and brightness more It is high.
2. joined chrome ore and plant ash in raw material, the melting temperature of glaze can be further reduced, and can be reduced The use of colorant.
3. the green glaze quality that grinding sufficiently, is burnt out is high.
Specific embodiment
In order to make the objectives, technical solutions, and advantages of the present invention clearer, with reference to embodiments, to the present invention It is further elaborated.It should be appreciated that the specific embodiments described herein are merely illustrative of the present invention, it is not used to Limit the present invention.
Specific embodiment 1:
A kind of formula of blueness glaze, including following raw material: potassium feldspar, albite, quartz, dolomite, kaolin and talcum.
It is fired using dolomite, since dolomite is compared to calcite, contains magnesium elements, and magnesium is having oxygen In the case where be easy to generate magnesia, fluxing agent can be played the role of, therefore it is lower to make to fire required temperature, using potassium feldspar With two kinds of feldspar mixing of albite, the transparency of albite is good, solution high temperature viscosity is small, varies with temperature fastly, and potassium feldspar is burnt It is wider at temperature range, can make after the two mixing glaze when firing variation more evenly, after firing, glaze colours just more evenly, and color More highlighted, the effect burnt out is good.
Specific embodiment 2:
The present embodiment is to have carried out further instruction to the mass fraction of raw material on the basis of specific embodiment 1, described The mass fraction of raw material is as follows: 23-28 parts of potassium feldspar, 15-22 parts of albite, 23-28 parts of quartz, 15-20 parts of dolomite, height Soil 5-10 parts of ridge, 3-7 parts of talcum.
Specific embodiment 3:
The present embodiment is to have carried out further instruction to the mass fraction of raw material on the basis of specific embodiment 2, described The mass fraction of raw material is as follows: 23 parts of potassium feldspar, 16 parts of albite, quartzy 28 parts, 15 parts of dolomite, 8 parts of kaolin, talcum 3 parts.
Specific embodiment 4:
The present embodiment is to have carried out further instruction to the mass fraction of raw material on the basis of specific embodiment 2, described The mass fraction of raw material is as follows: 28 parts of potassium feldspar, 22 parts of albite, quartzy 23 parts, 16 parts of dolomite, 5 parts of kaolin, talcum 5 parts.
Specific embodiment 5:
The present embodiment is to have carried out further instruction to the mass fraction of raw material on the basis of specific embodiment 2, described The mass fraction of raw material is as follows: 26 parts of potassium feldspar, 27 parts of quartz, 20 parts of dolomite, 10 parts of kaolin, is slided 15 parts of albite 7 parts of stone.
Specific embodiment 6:
The present embodiment is to have carried out further instruction to the mass fraction of raw material on the basis of specific embodiment 1, described The mass fraction of raw material is as follows: 24-27 parts of potassium feldspar, 17-21 parts of albite, 23.5-26.5 parts of quartz, dolomite 16-19 Part, 7-9 parts of kaolin, 3.5-6.5 parts of talcum.
Specific embodiment 7:
The present embodiment is to have carried out further instruction to the mass fraction of raw material on the basis of specific embodiment 6, described The mass fraction of raw material is as follows: 25 parts of potassium feldspar, 23.5 parts of quartz, 16 parts of dolomite, 9 parts of kaolin, is slided 20 parts of albite 5 parts of stone.
Specific embodiment 8:
The present embodiment is to have carried out further instruction to the mass fraction of raw material on the basis of specific embodiment 6, described The mass fraction of raw material is as follows: 27 parts of potassium feldspar, 17 parts of albite, quartzy 25 parts, 19 parts of dolomite, 8 parts of kaolin, talcum 6.5 part.
Specific embodiment 9:
The present embodiment is to have carried out further instruction to the mass fraction of raw material on the basis of specific embodiment 6, described The mass fraction of raw material is as follows: 24 parts of potassium feldspar, 26.5 parts of quartz, 17 parts of dolomite, 7 parts of kaolin, is slided 21 parts of albite 3.5 parts of stone.
Specific embodiment 10:
The present embodiment is to have carried out further instruction to the mass fraction of raw material on the basis of specific embodiment 1, described The mass fraction of raw material is as follows: 24.5-26 parts of potassium feldspar, 18-20.5 parts of albite, 24-26 parts of quartz, dolomite 16.5- 18.5 parts, 7.5-8.8 parts of kaolin, 4-6 parts of talcum.
Specific embodiment 11:
The present embodiment is to have carried out further instruction to the mass fraction of raw material on the basis of specific embodiment 10, described The mass fraction of raw material is as follows: 26 parts of potassium feldspar, 26 parts of quartz, 17 parts of dolomite, 8 parts of kaolin, is slided 20.5 parts of albite 6 parts of stone.
Specific embodiment 12:
The present embodiment is to have carried out further instruction to the mass fraction of raw material on the basis of specific embodiment 10, described The mass fraction of raw material is as follows: 24.5 parts of potassium feldspar, 19 parts of albite, quartzy 25.5 parts, 16.5 parts of dolomite, kaolin 8.8 parts, 4 parts of talcum.
Specific embodiment 13:
The present embodiment is to have carried out further instruction to the mass fraction of raw material on the basis of specific embodiment 10, described The mass fraction of raw material is as follows: 25.5 parts of potassium feldspar, 18 parts of albite, quartzy 24 parts, 18.5 parts of dolomite, kaolin 7.5 Part, 5 parts of talcum.
Specific embodiment 14:
The present embodiment is to have carried out further instruction to the mass fraction of raw material on the basis of specific embodiment 1, described The mass fraction of raw material is as follows: 24.8-25.5 parts of potassium feldspar, 19-20.4 parts of albite, quartz 24.5-25.5 parts, dolomite 16.6-18 parts, 7.7-8.5 parts of kaolin, 4.5-5.6 parts of talcum.
Specific embodiment 15:
The present embodiment is to have carried out further instruction to the mass fraction of raw material on the basis of specific embodiment 14, described The mass fraction of raw material is as follows: 24.8 parts of potassium feldspar, 20 parts of albite, quartzy 25.5 parts, 17 parts of dolomite, kaolin 7.7 Part, 5 parts of talcum.
Specific embodiment 16:
The present embodiment is to have carried out further instruction to the mass fraction of raw material on the basis of specific embodiment 14, described The mass fraction of raw material is as follows: 25.5 parts of potassium feldspar, 20.4 parts of albite, quartzy 24.5 parts, 16.6 parts of dolomite, kaolin 8.5 parts, 5.6 parts of talcum.
Specific embodiment 17:
The present embodiment is to have carried out further instruction to the mass fraction of raw material on the basis of specific embodiment 14, described The mass fraction of raw material is as follows: 25.4 parts of potassium feldspar, 19 parts of albite, quartz 25 parts, 18 parts of dolomite, 7.9 parts of kaolin, 4.5 parts of talcum.
Specific embodiment 18:
The present embodiment is to have carried out further instruction to the mass fraction of raw material on the basis of specific embodiment 1, described The mass fraction of raw material is as follows: 25 parts of potassium feldspar, 20 parts of albite, quartzy 25 parts, 17 parts of dolomite, 8 parts of kaolin, talcum 5 parts.
Specific embodiment 19:
It further include the chrome ores of 2-4 parts of mass fractions, 1-3 parts of quality as present invention further optimization, in the raw material The plant ash of number.
Joined chrome ore is because containing Cr2O2 in chrome ore, and Cr2O2 can be used as colorant under high temperature, instead of Fe2O3 reduces the use of colorant, while the plant ash calcium P elements rich in being added in this way, can be used as fluxing agent, The suspension having in glaze slip can reduce the high temperature viscosity of glaze and the melting temperature of further reduction glaze, but also have Opaque has facilitation to chun glaze split-phase.
Specific embodiment 20:
A method of green glaze is prepared by any of the above-described green glaze formula, include the following steps: a, by grinding raw material at Powder, the time of grinding are 48 hours;B, it is filtered after the completion of grinding, is subsequently placed in shady place and dries.
Grinding 48 hours is to adequately grind uniformly, and In Shade to dry rather than dry be then in order to prevent Ingredient in raw material occurs oxidation reaction in drying and generates impurity, reduces the quality burnt out.
Although reference be made herein to invention has been described for multiple explanatory embodiments of the invention, however, it is to be understood that Those skilled in the art can be designed that a lot of other modification and implementations, these modifications and implementations will fall in this Shen It please be within disclosed scope and spirit.It more specifically, within the scope of the present disclosure and claims, can be to master The building block and/or layout for inscribing composite configuration carry out a variety of variations and modifications.In addition to what is carried out to building block and/or layout Outside modification and improvement, to those skilled in the art, other purposes also be will be apparent.

Claims (8)

1. a kind of formula of blueness glaze, it is characterised in that: including following raw material: potassium feldspar, albite, quartz, dolomite, kaolinite Soil and talcum.
2. blueness glaze formula according to claim 1, it is characterised in that: the mass fraction of the raw material is as follows: potassium feldspar 23-28 parts, 15-22 parts of albite, 23-28 parts of quartz, 15-20 parts of dolomite, 5-10 parts of kaolin, 3-7 parts of talcum.
3. blueness glaze formula according to claim 1, it is characterised in that: the mass fraction of the raw material is as follows: potassium feldspar 24-27 parts, 17-21 parts of albite, 23.5-26.5 parts of quartz, 16-19 parts of dolomite, 7-9 parts of kaolin, talcum 3.5-6.5 Part.
4. blueness glaze formula according to claim 1, it is characterised in that: the mass fraction of the raw material is as follows: potassium feldspar 24.5-26 parts, 18-20.5 parts of albite, 24-26 parts of quartz, 16.5-18.5 parts of dolomite, 7.5-8.8 parts of kaolin, talcum 4-6 parts.
5. blueness glaze formula according to claim 1, it is characterised in that: the mass fraction of the raw material is as follows: potassium feldspar 24.8-25.5 parts, 19-20.4 parts of albite, 24.5-25.5 parts of quartz, 16.6-18 parts of dolomite, 7.7-8.5 parts of kaolin, 4.5-5.6 parts of talcum.
6. blueness glaze formula according to claim 1, it is characterised in that: the mass fraction of the raw material is as follows: potassium feldspar 25 parts, 20 parts of albite, quartzy 25 parts, 17 parts of dolomite, 8 parts of kaolin, 5 parts of talcum.
7. blueness glaze formula according to claim 1, it is characterised in that: further include 2-4 parts of mass fractions in the raw material Chrome ore, 1-3 parts of mass fractions plant ash.
8. a kind of method for preparing green glaze by green glaze formula of any of claims 1-7, it is characterised in that: including such as Lower step: a, by grinding raw material at powder, the time of grinding is 48 hours;B, it is filtered after the completion of grinding, is subsequently placed in shady place It dries.
CN201811646336.XA 2018-12-30 2018-12-30 The formula and preparation method thereof of green glaze Pending CN109437566A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112209619A (en) * 2020-11-24 2021-01-12 禹州大唐钧瓷文化有限公司 Secret color porcelain glaze and preparation method thereof

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CN104016723A (en) * 2014-06-16 2014-09-03 广东尚高科技有限公司 Method for improving glaze slurry stability

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112209619A (en) * 2020-11-24 2021-01-12 禹州大唐钧瓷文化有限公司 Secret color porcelain glaze and preparation method thereof

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Address after: Unit 1-102, Building 6, South Oriental International Garden, East Section of Luping Avenue, Huiyuan Office, Lushan County, Pingdingshan City, Henan Province

Applicant after: Lushan Duandian Flower Porcelain Technology Development Co.,Ltd.

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Application publication date: 20190308