CN109431831A - A kind of gold nano-negative ion facial mask liquid of Whitening, spot, facial mask and preparation method thereof - Google Patents

A kind of gold nano-negative ion facial mask liquid of Whitening, spot, facial mask and preparation method thereof Download PDF

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Publication number
CN109431831A
CN109431831A CN201811602344.4A CN201811602344A CN109431831A CN 109431831 A CN109431831 A CN 109431831A CN 201811602344 A CN201811602344 A CN 201811602344A CN 109431831 A CN109431831 A CN 109431831A
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facial mask
whitening
gold
negative ion
skin
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CN201811602344.4A
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Chinese (zh)
Inventor
裴东杰
龚朝臣
吴佳骏
陆雨荷
刘刚
胡金萍
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Zhengzhou Science And Technology Co Ltd Bracket
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    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/02Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/0212Face masks
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/31Hydrocarbons
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/34Alcohols
    • A61K8/345Alcohols containing more than one hydroxy group
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/35Ketones, e.g. benzophenone
    • A61K8/355Quinones
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/49Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds
    • A61K8/494Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with more than one nitrogen as the only hetero atom
    • A61K8/4946Imidazoles or their condensed derivatives, e.g. benzimidazoles
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/63Steroids; Derivatives thereof
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/64Proteins; Peptides; Derivatives or degradation products thereof
    • A61K8/65Collagen; Gelatin; Keratin; Derivatives or degradation products thereof
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00Preparations for care of the skin
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00Preparations for care of the skin
    • A61Q19/005Preparations for sensitive skin
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00Preparations for care of the skin
    • A61Q19/02Preparations for care of the skin for chemically bleaching or whitening the skin
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00Preparations for care of the skin
    • A61Q19/08Anti-ageing preparations
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/41Particular ingredients further characterized by their size
    • A61K2800/413Nanosized, i.e. having sizes below 100 nm
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/59Mixtures
    • A61K2800/592Mixtures of compounds complementing their respective functions

Abstract

The invention discloses a kind of gold nano-negative ion facial mask liquids of Whitening, spot, facial mask and preparation method thereof, the facial mask liquid comprises the following raw materials by weight percent: nanometer gold 0.1-2%, collagen 1-10%, butanediol 3-6%, glycerol 2-4%, allantoin 3-6%, saualane 5-8%, dipotassium glycyrrhizinate 1-3%, ubiquinone 3-6%, tripotassium phosphate 1-3%, essence 1-3%, surplus are water.Nanometer gold has the function of very strong cell activation in raw material of the present invention, and anion can be released by touching skin, and the free radical in scavenger-cell promotes blood circulation.Collagen can go directly the skin corium of skin, and skin is helped to form the moisture film of high-moisture, the ability nourished with depth water lock and deep layer.Effect altogether is cooperateed in facial mask between each ingredient, can quickly enhance Skin Cell vigor, whitening, light spot, moisturizing, nutrition and maintenance are carried out to face skin, allows face skin taking on a new look again, soft and smooth water is tender, and it is pale compact, it is beautiful moving.

Description

A kind of gold nano-negative ion facial mask liquid of Whitening, spot, facial mask and preparation method thereof
Technical field
The present invention relates to a kind of skin care item facial masks, and in particular to a kind of gold nano-negative ion facial mask liquid of Whitening, spot, Facial mask and preparation method thereof.
Background technique
Pursuit with people to beauty with the continuous improvement of people's living standards, skin care item and cosmetics are in people's lives In occupation of increasingly consequence.Gold facial mask has become a kind of common mask product.It is well known that nanometer gold is same Nano silver is the same, all has the function of good broad-spectrum sterilization.Nanometer gold be added facial mask be in can be used in skin cleaning and Moisturizing, antibacterial, beautification function.After being applied on the surface using the facial mask containing nanometer gold, skin and outside air completely cut off, and can inhibit The evaporation of skin surface moisture keeps horny layer of epidermis soft, and skin surface temperature increases, and blood circulation is improved, and can be expanded Pore, enhancing skin achieve the effect that the physiological function for promoting skin to the absorption of effective components various in facial mask.
Various gold facial masks have been had already appeared on the market at present, are broadly divided into two kinds: first is that in facial mask liquid In containing 24K gold, also have certain manufacturers declare containing nanotechnology make nanometer grade gold particle;Second is that so-called gold tinfoil Facial mask.But the effect of these gold facial masks be difficult to achieve the effect that it is intended that or even some gold facial masks there is no any Effect generates certain damage to skin instead.
Summary of the invention
In view of the deficiencies of the prior art, the object of the present invention is to provide a kind of gold nano-negative ion facial masks of Whitening, spot Liquid, facial mask and preparation method thereof, the facial mask have whitening spot-removing, anti-aging, moisturizing water lock, tender skin lightening, balanced grease, town It is quiet releive, antianaphylactic effect.
To achieve the goals above, the technical scheme adopted by the invention is that:
A kind of gold nano-negative ion facial mask liquid of Whitening, spot, comprises the following raw materials by weight percent: nanometer is yellow Golden 0.1-2%, collagen 1-10%, butanediol 3-6%, glycerol 2-4%, allantoin 3-6%, saualane 5-8%, glycyrrhizic acid Dipotassium 1-3%, ubiquinone 3-6%, tripotassium phosphate 1-3%, essence 1-3%, surplus are water.
Collagen is cow leather collagen, pigskin collagen, collagen.
Essence is flavoring rose essence, cream jasmin france.
Nanometer gold is oil-soluble gold nano rod-shpaed particle, diameter 10-50nm.
Nanometer gold the preparation method comprises the following steps: 10mg β-CD-g- [PAA-b-Ps] is dissolved in 10mL DMF, be made single point Sub- Micellar Gel solution;0.1179g HAuCl4Nanometer gold particle is obtained in 60 DEG C of reaction 10h with ethyl alcohol 2mL.
" a kind of oil is molten with reference to entitled for the preparation method of multi-arm star block copolymer β-CD-g- [PAA-b-Ps] The patent of invention of the preparation method of property silver nano-grain " (application number: CN2017111933345).
Preferably, the gold nano-negative ion facial mask liquid of Whitening, spot, comprises the following raw materials by weight percent: nanometer Gold 0.1%, collagen 10%, butanediol 5%, glycerol 3%, allantoin 5%, saualane 7%, dipotassium glycyrrhizinate 2%, ubiquinone 4%, tripotassium phosphate 2.5%, essence 2.5%, surplus are water.
A kind of preparation method of the gold nano-negative ion facial mask liquid of Whitening, spot, collagen is added to the water, mixing Uniformly;Then nanometer gold is added, is uniformly mixed;Add surplus stock, be uniformly mixed to get.
A kind of gold nano-negative ion facial mask of Whitening, spot immerses non-woven cotton facial mask substrate in facial mask liquid, and beauty is made The gold nano-negative ion facial mask of white moisturizing.
The invention has the advantages that:
1, nanometer gold facial mask of the invention is mainly used for substituting the product of gold light whitening spot-removing golden light plate, there is whitening Nti-freckle, the effect of delaying senescence, also containing ingredients such as whitening, moisturizings in facial mask.Wherein, gold nanometer is by surface modification The nanoscale molecule of 99.999% proof gold material, a diameter of 10-50nm have high electron density, dielectric property and urge Change effect is added into the anion that can use itself in skin care item with biological big in skin care item after nanotechnology treatments Molecule combines well, enhances its bioactivity, can activated fiber cell, moment, which wakes up, is sunk into sleep cell, strengthens collagen and fine The tightness of dimension repairs scar, smooth out wrinkles, consolidation skin, improves cell tissue activation, and anti-oxidant and anti-aging enables skin The spontaneous contraction for showing rhythmic nature rule, keeps skin closely sealed, and can reduce pore, desalination pigment, resists external infringement, resists It is bacterium, antibacterial, enable skin moist.
2, since the conductance of gold is strong, performance is stablized, the skin for being not easy to cause human body repels, and gold can decompose very The residual toxin of heavy metal in cortex decomposes subcutaneous tissue chemical residue toxin, captures free radical, enhances the immunity of skin, Therefore after gold being carried out nanosizing processing, the gold with anion can generate micro- reason circulating energy, thoroughly clean skin accumulation Dirt, import nutriment preferably in skin, the metabolism of Cucumber Extract, the generation of stimulation collagen delays Wrinkle generates, and resists ultraviolet light, and whitening makes skin health, moistens.
3, in raw material of the present invention, inside the deep enough skin of aqueous moisturizing ingredient (butanediol, glycerol, allantoin) energy, reach Replenishing water and preserving moisture effect, moist type lubricant component (saualane, dipotassium glycyrrhizinate) can reinforce soothing effect, improve water lock ability, Enhance moisture retention;Skin conditioning agent (ubiquinone) can releive Lavender Extract, prevent skin allergy, further enhance the antiallergic of facial mask Effect and antioxidation.Effect altogether is cooperateed between each ingredient of the present invention, can reach good moisturizing, whitening, light spot, anti-aging And anti-allergic effects.
4, when facial mask of the invention sticks on skin surface, there is the effective of the functions such as moisturizing, whitening and anti-aging in skin care item Ingredient can also be sent to skin bottom, and very good with the compatibility of surrounding tissue, and skin can be enabled sufficiently to moisten, more can be profound Lighten the stain, dim heavy and yellowing phenomenon, the delicate water that shows from inside to outside for improving skin have moistened the colour of skin, only need 30 points Clock quickly enhances Skin Cell vigor, carries out whitening, light spot, moisturizing, nutrition and maintenance to face skin, allows face skin weight New taking on a new look, soft and smooth water is tender, pale compact, beautiful moving.
Detailed description of the invention
Fig. 1 is the XRD spectrum of nanometer gold particle made from the embodiment of the present invention 1.
Fig. 2 is the transmission electron microscope picture of nanometer gold particle made from the embodiment of the present invention 1.
Specific embodiment
Specific embodiments of the present invention will be described in further detail with reference to embodiments.
Embodiment 1
Nanometer gold the preparation method comprises the following steps: 10mg β-CD-g- [PAA-b-Ps] is dissolved in 10mL DMF, be made single point Sub- Micellar Gel solution;0.1179g HAuCl4Nanometer gold particle is obtained in 60 DEG C of reaction 10h with ethyl alcohol 2mL.
Fig. 1 be preparation particle XRD diagram, through with JCPDF card check analysis, 2 θ be 38.20 °, 44.40 °, At 64.50 °, 77.50 °, there are 4 diffraction maximums, is the characteristic diffraction peak of gold, (111), (200), (220), (222) four Crystal face is corresponding with the crystal face of gold of face-centred cubic structure respectively, it is possible thereby to determine that the granular product of preparation is elemental gold.
Fig. 2 is the transmission electron microscope picture for preparing nanometer gold particle.Nanogold is rodlike knot it can be seen from transmission electron microscope picture The particle of structure, average diameter 30nm.
Embodiment 2
A kind of gold nano-negative ion facial mask liquid of Whitening, spot, comprises the following raw materials by weight percent: nanometer is yellow Gold 0.1%, collagen 10%, butanediol 5%, glycerol 3%, allantoin 5%, saualane 7%, dipotassium glycyrrhizinate 2%, Ubiquinone 4%, tripotassium phosphate 2.5%, cream jasmin france 2.5%, surplus are water.
Preparation method is, comprising the following steps:
(1) collagen is added to the water, is uniformly mixed, collagen aqueous solution is made;
(2) nanometer gold is added in collagen aqueous solution, is heated to 60 DEG C, stirs;
(3) butanediol, glycerol, allantoin, saualane are added in the mixed liquor of step (2), stirring cooling;It is cooled to 40 DEG C, dipotassium glycyrrhizinate, ubiquinone is added, is sufficiently mixed, stirs evenly, be cooled to 30 DEG C, it is fragrant to add tripotassium phosphate, lavender Essence, be sufficiently mixed, stir evenly to get.
Embodiment 3
A kind of gold nano-negative ion facial mask liquid of Whitening, spot, comprises the following raw materials by weight percent: nanometer is yellow Gold 0.5%, cow leather collagen 2%, butanediol 6%, glycerol 2%, allantoin 4%, saualane 8%, dipotassium glycyrrhizinate 1%, Ubiquinone 3%, tripotassium phosphate 3%, flavoring rose essence 1%, surplus are water.
Preparation method is the same as embodiment 2.
Embodiment 4
A kind of gold nano-negative ion facial mask liquid of skin whitening, moisturizing, comprises the following raw materials by weight percent: nanometer is yellow It is gold 1%, pigskin collagen 5%, butanediol 4%, glycerol 4%, allantoin 3%, saualane 6%, dipotassium glycyrrhizinate 3%, general Quinone 5%, tripotassium phosphate 1%, cream jasmin france 3%, surplus are water.
Preparation method is the same as embodiment 2.
Embodiment 5
A kind of gold nano-negative ion facial mask liquid of Whitening, spot, comprises the following raw materials by weight percent: nanometer is yellow It is gold 2%, pigskin collagen 4%, butanediol 3%, glycerol 3%, allantoin 6%, saualane 5%, dipotassium glycyrrhizinate 2%, general Quinone 6%, tripotassium phosphate 2%, cream jasmin france 2%, surplus are water.
Preparation method is the same as embodiment 2.
Embodiment 6
One kind containing gold nano-negative ion collagen protein face, preparation method are as follows: immerses non-woven cotton facial mask substrate In the facial mask liquid of embodiment 2, it is made and contains gold nano-negative ion collagen protein face.
Control group 1
The facial mask liquid ingredient of 1 facial mask of control group does not add nanometer gold, remaining ingredient is same as Example 2.
Control group 2
The facial mask liquid ingredient of 2 facial mask of control group does not add collagen, remaining ingredient is same as Example 2.
Control group 3
The facial mask liquid of 3 facial mask of control group, comprises the following raw materials by weight percent: nanometer gold 2%, pigskin collagen egg White 4%, allantoin 0.3%, triethanolamine 0.2%, xanthan gum 0.5%, carbomer 0.4%, dipotassium glycyrrhizinate 0.5%, lecithin Rouge 5%, Phenoxyethanol 6%, vitamin B5 0.6%, surplus are water.
Measure of merit:
1, facial mask performance of keeping humidity is tested:
The facial mask of Example 6 and control group 1-3, respectively to three age levels (19-28 years old, 29-38 years old, 39-48 years old) Women carry out the test of facial mask performance of keeping humidity, each age level randomly chooses 20 people, and totally 60 people are divided into one group, totally 4 groups.Facial mask with Facial mask is pasted on facial 30min at 9 points at night as judgment criteria by moisturizing effect, is tested and second having applied in half an hour Its morning, 7 points of test datas of getting up, as a result see the table below.
Group Moisture content of skin before face mask film Face mask film half an hour moisture content of skin Next day gets up moisture content of skin
Embodiment 6 30.0% 56.2% 47.5%
Control group 1 30.4% 43.8% 31.7%
Control group 2 32.6% 40.9% 33.5%
Control group 3 30.9% 49.9% 41.5%
As can be seen from the above table, facial mask of the invention has good moisturizing water lock function.
2, facial mask Whitening, spot performance test
The facial mask of Example 6 and control group 1-3 carries out the performance test of facial mask Whitening, spot.400 skins are selected to exist It is obscure it is unglazed, pore is coarse, has acne print, 25-45 years old women of color spot to carry out skin test, every group of 100 people stick facial mask It is removed after facial 30min, is sticked once before sleep daily, continuously stick 100 days, observe the skin degree of absorption of tested women With improvement situation, as a result see the table below.
As can be seen from the above table, facial mask of the invention has the function of good Whitening, spot.
4, facial mask smoothing wrinkle performance test
The facial mask of Example 6 and control group 1-3 carries out the performance test of facial mask smoothing wrinkle.Selecting 400 skins, there are wrinkles 35-45 years old women carry out skin test, every group of 100 people remove after facial mask is pasted on facial 30min, daily before sleep It sticks once, continuously sticks 100 days, the wrinkle of skin for observing tested women improves situation, as a result see the table below.
As can be seen from the above table, facial mask of the invention can compact skin, smoothing wrinkle, anti-aging.

Claims (8)

1. a kind of gold nano-negative ion facial mask liquid of Whitening, spot, which is characterized in that by the raw material group of following weight percent At: nanometer gold 0.1-2%, collagen 1-10%, butanediol 3-6%, glycerol 2-4%, allantoin 3-6%, saualane 5- 8%, dipotassium glycyrrhizinate 1-3%, ubiquinone 3-6%, tripotassium phosphate 1-3%, essence 1-3%, surplus are water.
2. the gold nano-negative ion facial mask liquid of Whitening, spot according to claim 1, which is characterized in that the collagen Albumen is cow leather collagen, pigskin collagen, collagen.
3. the gold nano-negative ion facial mask liquid of Whitening, spot according to claim 1, which is characterized in that the essence For flavoring rose essence, cream jasmin france.
4. the gold nano-negative ion facial mask liquid of Whitening, spot according to claim 1, which is characterized in that the nanometer Gold is oil-soluble gold nano rod-shpaed particle, diameter 10-50nm.
5. the gold nano-negative ion facial mask liquid of Whitening, spot according to claim 1, which is characterized in that the nanometer Gold the preparation method comprises the following steps: 10mg β-CD-g- [PAA-b-Ps] is dissolved in 10mL DMF, it is molten that unimolecular micelle template is made Liquid;0.1179g HAuCl4Nanometer gold particle is obtained in 60 DEG C of reaction 10h with ethyl alcohol 2mL.
6. the gold nano-negative ion facial mask liquid of Whitening, spot according to claim 1, which is characterized in that it is preferred, by The raw material of following weight percent forms: nanometer gold 0.1%, collagen 10%, butanediol 5%, glycerol 3%, urine Bursin 5%, saualane 7%, dipotassium glycyrrhizinate 2%, ubiquinone 4%, tripotassium phosphate 2.5%, essence 2.5%, surplus are water.
7. a kind of preparation method of the gold nano-negative ion facial mask liquid of Whitening, spot as claimed in any one of claims 1 to 6, It is characterized in that, collagen is added to the water, it is uniformly mixed;Then nanometer gold is added, is uniformly mixed;Add remaining original Material, be uniformly mixed to get.
8. a kind of gold nano-negative ion facial mask of Whitening, spot, which is characterized in that non-woven cotton facial mask substrate immersion right It asks in the described in any item facial mask liquids of 1-6, the gold nano-negative ion facial mask of Whitening, spot is made.
CN201811602344.4A 2018-12-26 2018-12-26 A kind of gold nano-negative ion facial mask liquid of Whitening, spot, facial mask and preparation method thereof Withdrawn CN109431831A (en)

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CN107929119A (en) * 2017-11-24 2018-04-20 广州市梦采生物科技有限公司 A kind of composition with Whitening, spot
CN108125802A (en) * 2018-01-16 2018-06-08 广州市美姿贺化妆品有限公司 Application of the nanometer gold in eye cream and the eye cream that is made from it and preparation method thereof

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102181959A (en) * 2011-04-07 2011-09-14 北京服装学院 Fish collagen composite fibers and preparation method thereof
CN105596243A (en) * 2014-11-20 2016-05-25 龚䶮 Essence liquid containing nano-gold and thermal spring water and mask
CN105748367A (en) * 2016-04-01 2016-07-13 中山森谱生物科技有限公司 Dendrobium officinale small-molecular peptide facial mask based on gold-nano rod composite material
CN105853250A (en) * 2016-05-13 2016-08-17 诺斯贝尔化妆品股份有限公司 Cosmetic composition containing gold collagen
CN107552807A (en) * 2016-06-30 2018-01-09 郑州科斗创客科技有限公司 It is a kind of to prepare the preparation method with the size gold nanorods controllable with dispersiveness on a large scale
CN106880580A (en) * 2017-02-28 2017-06-23 广州诚予化妆品有限公司 A kind of nm of gold repairs facial mask and its production technology
CN107855540A (en) * 2017-11-24 2018-03-30 洛阳量子纳米科技有限公司 A kind of preparation method of Properties of Oil-Soluble Ag Nanoparticles
CN107900376A (en) * 2017-11-24 2018-04-13 洛阳量子纳米科技有限公司 A kind of preparation method of water-soluble silver nano particle
CN107929119A (en) * 2017-11-24 2018-04-20 广州市梦采生物科技有限公司 A kind of composition with Whitening, spot
CN108125802A (en) * 2018-01-16 2018-06-08 广州市美姿贺化妆品有限公司 Application of the nanometer gold in eye cream and the eye cream that is made from it and preparation method thereof

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