CN109423606A - Focusing ring and its corrosion-resistant means of defence - Google Patents

Focusing ring and its corrosion-resistant means of defence Download PDF

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Publication number
CN109423606A
CN109423606A CN201710736818.3A CN201710736818A CN109423606A CN 109423606 A CN109423606 A CN 109423606A CN 201710736818 A CN201710736818 A CN 201710736818A CN 109423606 A CN109423606 A CN 109423606A
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CN
China
Prior art keywords
electrostatic chuck
focusing ring
ring
plasma
coating
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710736818.3A
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Chinese (zh)
Inventor
倪图强
贺小明
左涛涛
陈星建
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Advanced Micro Fabrication Equipment Inc Shanghai
Advanced Micro Fabrication Equipment Inc
Original Assignee
Advanced Micro Fabrication Equipment Inc Shanghai
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Advanced Micro Fabrication Equipment Inc Shanghai filed Critical Advanced Micro Fabrication Equipment Inc Shanghai
Priority to CN201710736818.3A priority Critical patent/CN109423606A/en
Publication of CN109423606A publication Critical patent/CN109423606A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/06Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the coating material
    • C23C14/08Oxides
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/02Pretreatment of the material to be coated
    • C23C14/021Cleaning or etching treatments
    • C23C14/022Cleaning or etching treatments by means of bombardment with energetic particles or radiation

Abstract

The invention discloses a kind of focusing ring and its corrosion-resistant means of defences, its peripheral side for being located at ceramic electrostatic chuck and the electrostatic chuck middle layer for being equipped with electrostatic chuck side seal circle, electrostatic chuck ceramic layer is located above the electrostatic chuck middle layer, electrostatic chuck middle layer is located above the matrix for the electrostatic chuck being arranged in plasma etch chamber, the matrix peripheral side of electrostatic chuck is equipped with dead ring, and focusing ring is located at the top of dead ring;Wafer is arranged in electrostatic chuck ceramic layer, covers a part of upper surface of the extended loop of focusing ring, and the focusing ring is equipped with main ring and extended loop;Focusing ring is deposited with the coating of resisting plasma corrosion in whole or in part.The present invention has the service life for increasing focusing ring, and stable plasma etching technics protects electrostatic chuck, the advantages of increasing electrostatic chuck and the service life of other components, reduce production cost.

Description

Focusing ring and its corrosion-resistant means of defence
Technical field
The present invention relates to semiconductor processing equipment fields, and in particular to a kind of focusing ring, the electrostatic card including the focusing ring Disk and its corrosion-resistant means of defence.
Background technique
In the prior art, in plasma etch chamber, the focusing ring (focus that is directly exposed in plasma Ring) generally can preferred high-purity material be made, such as silicon or silicon carbide etc..When etching (ETCH) board is to wafer When carrying out plasma treatment, it can usually encounter focusing ring and larger, the short problem of service life is lost;And especially to electrostatic card When disk (Electrostatic chuck, abbreviation ESC) carries out clearing up (waferless clean) without wafer, as shown in Figure 1, by In not placing wafer (wafer) in electrostatic chuck ceramic layer 3, at this time since focusing ring 1 is fully exposed in etching environment 7, The loss to focusing ring 1 is then increased, it has been speeded and rate is lost;Due to the transition loss of focusing ring, electrostatic chuck will lead to Gap 8 between focusing ring 1, cause to make etching gas (process gases) more with corrosivity and pollution, Between between the electrostatic chuck and focusing ring that the gases such as free radical (radicals), plasma (plasma) pass through above-mentioned increase Gap, Corrosive attack electrostatic chuck side wall (ESC sidewall), electrostatic chuck side wall sealing ring (ESC side sealing) with And other components;The service life of above-mentioned electrostatic chuck is reduced, and causes electrostatic chuck arc extinguishing discharge failure (ESC Arcing fail) while, also cause to cause undesirable influence to the processing of wafer, such as its particle for releasing (particle) a series of problems, such as pollution wafer, electrostatic chuck.
In existing coating (Coating) application technology, yttrium oxide (Y2O3) etc. ceramics be anti-plasma etching painting Layer.However, at present using the Y of plasma spray coating (plasma spray, PS) preparation2O3Equal coatings have high surface roughness The tissue of (Ra is greater than 4 microns) and high porosity (volume fraction is greater than 3%), are also easy to produce particle dirt in plasma etch process Dye.Other yttria coating preparation processes, as chemical vapor deposition (chemical vapor deposition, CVD) usually exists Y is made on high temperature (> 600 DEG C) matrix2O3Coating, and physical vapour deposition (PVD) (physical vapor deposition, PVD) Deposition rate is low, high production cost.These technology defects, which limit, prepares high-densit Y2O3Coating and at 16 nanometers or less Application in the high-accuracy chip plasma etching processing technology of scale.
Summary of the invention
It is an object of the present invention to provide a kind of focusing rings, utilize coating technique, plasma enhancing physical vapour deposition (PVD) (Plasma enhanced physical vapour deposition, PEPVD) is realized on focusing ring to high-densit Y2O3It applies The deposition of layer reaches stable plasma etching technics to overcome the problems, such as that focusing ring is lost by plasma etching, protects quiet Electric card disk reduces a series of purpose of production problems such as cost.
In order to achieve the goal above, the invention is realized by the following technical scheme:
A kind of focusing ring for plasma treatment, the focusing ring are made of ceramic materials, and the focusing ring includes one A main ring, wherein the first upper surface at the top of main ring has the first height, is the extension protruded to focusing ring center on the inside of main ring Ring, the second upper surface at the top of the extended loop have the second height, and the second height is less than first height,
Wherein the second upper surface inside region is coated with plasma resistant coating, and extended loop inside side walls are coated with anti-etc. simultaneously Ionic coating.
Preferably, the surface coated with the plasma resistant coating, comprising at the top of main ring the first upper surface and extended loop Second upper surface at top.
Preferably, the ceramic material of first upper surface and main ring inside side walls is directly exposed to the plasma.
The material for being preferably made from the coating includes yttrium oxide, yttrium fluoride, erbium oxide, silicon carbide, silicon nitride, oxidation Zirconium, any one or their combination among aluminium oxide.
Preferably, the thickness range of the coating is 2 μm~200 μm.
Preferably, the range of the consistency of the coating is 0~10%.
Second technical solution of the present invention is a kind of plasma reactor, includes a pedestal in the plasma reactor, It is provided with an electrostatic chuck above pedestal, the peripheral side of electrostatic chuck, the matrix of electrostatic chuck are set according to above-mentioned focusing ring Peripheral side is equipped with dead ring, and the top of the dead ring is arranged in the focusing ring;Above the matrix of the electrostatic chuck according to Secondary setting electrostatic chuck middle layer and electrostatic chuck ceramic layer, the electrostatic chuck middle layer are equipped with electrostatic chuck side seal outside Circle;Wafer to be processed is arranged on the extended loop of the electrostatic chuck ceramic layer and the focusing ring, and is in the focusing In the inside circumference of ring main ring.
Preferably, the side and institute of the extended loop inside circumferential surface of the focusing ring and the electrostatic chuck side seal circle It states and is equipped with gap between the side of electrostatic chuck ceramic layer, the gap width is in the numberical range of setting.
Third technical solution of the present invention is a kind of corrosion-resistant means of defence based on above-mentioned focusing ring, a wafer to be processed It is arranged on the electrostatic chuck, and edge of the edge of wafer beyond the electrostatic chuck and covers at the top of the focusing ring the Two upper surface inside regions, so that the plasma resistant coating of the second upper surface inside region coating will not be by plasma bombardment.
Compared with the prior art, the present invention has the following advantages:
The present invention is by using plasma enhancing physical vapour deposition (PVD) (Plasma enhanced physical Vapour deposition, PEPVD) realize high-densit Y is deposited on focusing ring2O3Coating, to overcome focusing ring by plasma The problem of body etching loss, increase the service life of focusing ring, stable plasma etching technics, maintain focusing ring with it is quiet The gap width set between electric card disk is constant, and then protects electrostatic chuck, increases electrostatic chuck and the use of other components Service life reduces production cost.
Detailed description of the invention
Fig. 1 is a kind of focusing ring damaged structure schematic diagram of the present invention;
Fig. 2 is a kind of focusing ring structural schematic diagram of the present invention;
Fig. 3 is a kind of coating range schematic diagram in any one section of embodiment one of focusing ring of the present invention;,
Fig. 4 is the structural schematic diagram that wafer is had on a kind of focusing ring of the present invention;
Fig. 5 is a kind of coating range schematic diagram in any one section of embodiment two of focusing ring of the present invention;
Fig. 6 is that a kind of coating of focusing ring of the present invention uses PS Y2O3and PEPVD Y2O3The surface topography of two kinds of technique The contrast schematic diagram of tissue.
Specific embodiment
The present invention is further elaborated by the way that a preferable specific embodiment is described in detail below in conjunction with attached drawing.
As shown in Fig. 2, a kind of focusing ring of the present invention, the focusing ring are located at electrostatic chuck peripheral side, make pottery with electrostatic chuck Enamel coating 3 and 5 position of electrostatic chuck middle layer for being equipped with electrostatic chuck side seal circle 4 are corresponding;The electrostatic chuck ceramic layer 3 Above the electrostatic chuck middle layer 5, the electrostatic chuck middle layer 5 is quiet in plasma etch chamber positioned at being arranged in 6 top of matrix of electric card disk;6 peripheral side of matrix of the electrostatic chuck is equipped with dead ring 2, and the focusing ring 1 is located at described exhausted The top of edge ring 2.
The focusing ring 1 includes main ring 10, and the extended loop that lateral 1 center of focusing ring is protruded in the main ring 10 11.The focusing ring 1 generally can preferred high purity ceramic material be made, such as silicon or silicon carbide etc..The extended loop 11 Upper surface be slightly below the upper surface of the electrostatic chuck ceramic layer 3;11 inside circumferential surface of extended loop and the electrostatic Gap is equipped between the side of chuck side seal circle and the side of the electrostatic chuck ceramic layer 3, the gap width is in and sets In fixed numberical range.
As shown in figure 4, the wafer 12 is in institute when placing wafer 12 to be processed on the electrostatic chuck ceramics 3 It states in 10 inside circumference of main ring, 10 upper surface of main ring etc. of 12 upper surface of wafer and focusing ring 1 is more or less than the main ring 10 upper surfaces.
The electrostatic chuck ceramic layer 3 is an insulating layer, for carrying workpiece to be added, such as wafer 12;The electrostatic card It is equipped with electrode inside disk ceramic layer 3, adsorbs the workpiece to be added for connecting a controllable direct current power supply to generate electrostatic force;Electrostatic Chuck middle layer 5 is another insulating layer, and heater, the heat that the heater generates are equipped with inside the electrostatic chuck middle layer 5 Amount is transferred to the electrostatic chuck ceramic layer 3 by the electrostatic chuck middle layer 5 to heat the workpiece to be added;Electrostatic chuck Matrix 6, be used to support the electrostatic chuck ceramic layer 3 and electrostatic chuck middle layer 5.It is set inside the matrix 6 of electrostatic chuck There is at least one cooling liquid flowing channel, the electrostatic chuck is cooled down for injecting coolant liquid.
Embodiment one, in conjunction with shown in Fig. 2 and Fig. 3, for the wafer of the corrosion resistancies element no requirement (NR) such as yttrium oxide, i.e., for The insensitive wafer of the material granule for the coating that plasma exciatiaon goes out, or when not placing wafer on electrostatic chuck, to quiet When electric card disk is made without wafer cleaner processing, optional all surfaces are sprayed with the focusing ring 1 of corrosion resistance coating, that is, pass through plasma The coating process of body enhancing physical vapour deposition (PVD) the main ring 10 of the focusing ring 1 upper surface and inside circumferential surface and prolong The upper surface and inside circumferential surface of stretching ring 11 all deposit the coating of high-densit resisting plasma corrosion.
Embodiment two, in conjunction with shown in Fig. 2 and Fig. 5, for the wafer that the corrosion resistancies element such as yttrium oxide requires, i.e., for The wafer of the material granule sensitivity for the coating that plasma exciatiaon goes out, if 1 coating material of focusing ring described in plasma exciatiaon, It can be mixed into the particle containing coating material element such as yttrium etc. in the plasma, polluting etc. on processed wafer influences.
To avoid the problem, the local focusing ring for being sprayed with corrosion resistance coating is then selected for such wafer in the present embodiment 1.When brilliant diameter of a circle is greater than the internal diameter of the extended loop 11 of the focusing ring 1, wafer setting is made pottery in the electrostatic chuck On enamel coating 3, the marginal portion of wafer is made to cover the upper surface of the extended loop 11 close to one of 1 center of focusing ring Point;By the coating process of plasma enhancing physical vapour deposition (PVD) the extended loop 11 inside circumferential surface with it is described The upper surface portion for the extended loop 11 that wafer covers deposits the coating that high-densit plasma resistant 7 corrodes.
Embodiment three is equipped with the gap of setting width range, the gap between the focusing ring and the electrostatic chuck Width is too small, then causes in assembling process, dirty since the mechanical friction between electrostatic chuck and focusing ring generates a large amount of particles Plasma gas is contaminated, and then influences the wafer for needing to etch;As focusing ring inner sidewall will lead to gap by plasma gas corrosion Width becomes larger, and gap express delivery, which becomes larger, can generate electrical breakdown, and electrical breakdown can damage electrostatic chuck, generates a large amount of particles, pollution etc. from Sub- gas is splashed to crystal column surface, pollutes wafer;Therefore the present embodiment three provides a kind of corrosion-resistant means of defence of focusing ring, I.e. focusing ring and be arranged on the focusing ring on electrostatic chuck deposit resisting plasma corrosion coating.Pass through the coating The loss for slowing down control focusing ring, extends the service life of focusing ring, between making between the focusing ring and the electrostatic chuck Gap width maintains in the numberical range of setting, extends the service life of electrostatic chuck, and electrostatic chuck side wall electric arc is avoided to put Electricity issues particulate matter.
Coating described in above-described embodiment one to embodiment three, including but not limited to: yttrium oxide (Y2O3), yttrium fluoride (YF3), erbium oxide (ErO2), silicon carbide (SiC), silicon nitride (Si3N4), zirconium oxide (ZrO2), aluminium oxide (Al2O3) among appoint The combination of meaning one or their combination or they and other compositions;The thickness range of the coating is, for example, 2 μm~200 μ m;The range of the consistency of the coating is, for example, 0~10%.
As shown in fig. 6, the coating of focusing ring into embodiment three of the embodiment of the present invention one is all made of plasma enhancing object Physical vapor deposition (Plasma enhanced physical vapour deposition, PEPVD) is realized to sink on focusing ring The coating of the high-densit resisting plasma corrosion of product, such as Y2O3Coating;To overcome focusing ring key position plasma etching to be lost Problem reaches stable plasma etching technics, solves protection electrostatic chuck, reduces a series of production problems such as cost.It is described PEPVD technique can prepare the controllable high-densit Y of thickness on cryogenic material surface2O3Equal ceramic coatings, the cryogenic material is such as 200 DEG C, for the coating layer thickness up to 0.1 millimeter or more, the coating consistency can reach imporosity rate;It overcomes aforementioned various The deficiency of preparation technology of coating, it is thus achieved that production application target of the invention.
It is discussed in detail although the contents of the present invention have passed through above preferred embodiment, but it should be appreciated that above-mentioned Description is not considered as limitation of the present invention.After those skilled in the art have read above content, for of the invention A variety of modifications and substitutions all will be apparent.Therefore, protection scope of the present invention should be limited to the appended claims.

Claims (9)

1. a kind of focusing ring for plasma treatment, which is characterized in that the focusing ring is made of ceramic materials, the focusing Ring includes a main ring, and wherein the first upper surface at the top of main ring has the first height, is the cardiac prominence into focusing ring on the inside of main ring Extended loop out, the second upper surface at the top of the extended loop have the second height, and the second height is less than first height,
Wherein the second upper surface inside region is coated with plasma resistant coating, and extended loop inside side walls are coated with plasma resistant simultaneously Coating.
2. a kind of focusing ring as described in claim 1, which is characterized in that
Surface coated with the plasma resistant coating, comprising on the first upper surface at the top of main ring and second at the top of extended loop Surface.
3. a kind of focusing ring as described in claim 1, which is characterized in that
The ceramic material of first upper surface and main ring inside side walls is directly exposed to the plasma.
4. a kind of focusing ring as described in claim 1, which is characterized in that the material that the coating is made includes yttrium oxide, fluorination Yttrium, erbium oxide, silicon carbide, silicon nitride, zirconium oxide, any one or their combination among aluminium oxide.
5. a kind of focusing ring as described in claim 1, which is characterized in that
The thickness range of the coating is 2 μm~200 μm.
6. a kind of focusing ring as described in claim 1, which is characterized in that
The range of the consistency of the coating is 0~10%.
7. a kind of plasma reactor, includes a pedestal in the plasma reactor, is provided with an electrostatic chuck above pedestal, It is characterized in that, the peripheral side of electrostatic chuck, the matrix peripheral side of electrostatic chuck is arranged in focusing ring according to claim 1 Equipped with dead ring, the top of the dead ring is arranged in the focusing ring;It is sequentially arranged above in the matrix of the electrostatic chuck Electrostatic chuck middle layer and electrostatic chuck ceramic layer, the electrostatic chuck middle layer are equipped with electrostatic chuck side seal circle outside;To The wafer of processing is arranged on the extended loop of the electrostatic chuck ceramic layer and the focusing ring, and is in the focusing ring main ring Inside circumference in.
8. a kind of plasma reactor as claimed in claim 7, which is characterized in that the extended loop inside circumference table of the focusing ring Gap, the gap are equipped between the side of the side and the electrostatic chuck ceramic layer of face and the electrostatic chuck side seal circle Width is in the numberical range of setting.
9. a kind of corrosion-resistant means of defence based on focusing ring described in claim 1~8, which is characterized in that a wafer to be processed It is arranged on the electrostatic chuck, and edge of the edge of wafer beyond the electrostatic chuck and covers at the top of the focusing ring the Two upper surface inside regions, so that the plasma resistant coating of the second upper surface inside region coating will not be by plasma bombardment.
CN201710736818.3A 2017-08-24 2017-08-24 Focusing ring and its corrosion-resistant means of defence Pending CN109423606A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112652511A (en) * 2019-10-12 2021-04-13 中微半导体设备(上海)股份有限公司 Plasma etching device and edge ring therein
CN113802094A (en) * 2020-06-16 2021-12-17 中微半导体设备(上海)股份有限公司 Coating method of corrosion-resistant coating, plasma etching part and reaction device

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CN103187232A (en) * 2011-12-28 2013-07-03 中微半导体设备(上海)有限公司 Focusing ring for reducing polymer generated on back of chip
CN103903948A (en) * 2012-12-27 2014-07-02 中微半导体设备(上海)有限公司 Focusing ring improving uniformity of wafer edge etching rate
CN104241069A (en) * 2013-06-13 2014-12-24 中微半导体设备(上海)有限公司 Component with yttrium oxide coating layer in plasma device and manufacturing method of component
CN104715997A (en) * 2015-03-30 2015-06-17 上海华力微电子有限公司 Focusing ring and plasma processing device provided with same
CN105552014A (en) * 2014-10-28 2016-05-04 北京北方微电子基地设备工艺研究中心有限责任公司 Support device and plasma etching equipment

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CN1489779A (en) * 2000-12-29 2004-04-14 ��ķ�о����޹�˾ Zirconia toughtened ceramic components and coatings in semiconductor processing equipment and method of manufacturing thereof
CN1489641A (en) * 2000-12-29 2004-04-14 ��ķ�о����޹�˾ Low Contamination plasma chamber components and method for making same
CN1643178A (en) * 2002-03-21 2005-07-20 兰姆研究公司 Low contamination components for semiconductor processing apparatus and methods for making components
CN101989543A (en) * 2009-08-07 2011-03-23 中微半导体设备(上海)有限公司 Device for reducing polymers at back side of substrate
CN103187232A (en) * 2011-12-28 2013-07-03 中微半导体设备(上海)有限公司 Focusing ring for reducing polymer generated on back of chip
CN103903948A (en) * 2012-12-27 2014-07-02 中微半导体设备(上海)有限公司 Focusing ring improving uniformity of wafer edge etching rate
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* Cited by examiner, † Cited by third party
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CN112652511A (en) * 2019-10-12 2021-04-13 中微半导体设备(上海)股份有限公司 Plasma etching device and edge ring therein
CN112652511B (en) * 2019-10-12 2023-10-20 中微半导体设备(上海)股份有限公司 Plasma etching device and edge ring therein
CN113802094A (en) * 2020-06-16 2021-12-17 中微半导体设备(上海)股份有限公司 Coating method of corrosion-resistant coating, plasma etching part and reaction device
CN113802094B (en) * 2020-06-16 2024-04-05 中微半导体设备(上海)股份有限公司 Coating method of corrosion-resistant coating, plasma etched part and reaction device

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Application publication date: 20190305