CN109423345A - A kind of clean fuel oil preparation method peculiar to vessel - Google Patents

A kind of clean fuel oil preparation method peculiar to vessel Download PDF

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Publication number
CN109423345A
CN109423345A CN201710778452.6A CN201710778452A CN109423345A CN 109423345 A CN109423345 A CN 109423345A CN 201710778452 A CN201710778452 A CN 201710778452A CN 109423345 A CN109423345 A CN 109423345A
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CN
China
Prior art keywords
vessel
fuel oil
accounts
clean fuel
peculiar
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710778452.6A
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Chinese (zh)
Inventor
罗卫城
张强
刘香亭
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shenzhen Hualian Century Bioengineering Ltd By Share Ltd
Original Assignee
Shenzhen Hualian Century Bioengineering Ltd By Share Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shenzhen Hualian Century Bioengineering Ltd By Share Ltd filed Critical Shenzhen Hualian Century Bioengineering Ltd By Share Ltd
Priority to CN201710778452.6A priority Critical patent/CN109423345A/en
Publication of CN109423345A publication Critical patent/CN109423345A/en
Pending legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/02—Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/12—Inorganic compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/12—Inorganic compounds
    • C10L1/1233—Inorganic compounds oxygen containing compounds, e.g. oxides, hydroxides, acids and salts thereof
    • C10L1/125—Inorganic compounds oxygen containing compounds, e.g. oxides, hydroxides, acids and salts thereof water
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/12—Inorganic compounds
    • C10L1/1266—Inorganic compounds nitrogen containing compounds, (e.g. NH3)
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/1802—Organic compounds containing oxygen natural products, e.g. waxes, extracts, fatty oils
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/182—Organic compounds containing oxygen containing hydroxy groups; Salts thereof
    • C10L1/1822—Organic compounds containing oxygen containing hydroxy groups; Salts thereof hydroxy group directly attached to (cyclo)aliphatic carbon atoms
    • C10L1/1824—Organic compounds containing oxygen containing hydroxy groups; Salts thereof hydroxy group directly attached to (cyclo)aliphatic carbon atoms mono-hydroxy
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/182—Organic compounds containing oxygen containing hydroxy groups; Salts thereof
    • C10L1/1822—Organic compounds containing oxygen containing hydroxy groups; Salts thereof hydroxy group directly attached to (cyclo)aliphatic carbon atoms
    • C10L1/1826—Organic compounds containing oxygen containing hydroxy groups; Salts thereof hydroxy group directly attached to (cyclo)aliphatic carbon atoms poly-hydroxy
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/185—Ethers; Acetals; Ketals; Aldehydes; Ketones
    • C10L1/1857—Aldehydes; Ketones
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/22—Organic compounds containing nitrogen
    • C10L1/222—Organic compounds containing nitrogen containing at least one carbon-to-nitrogen single bond

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Liquid Carbonaceous Fuels (AREA)

Abstract

A kind of clean fuel oil method peculiar to vessel, formula are made of following weight ratio component.Methanol accounts for 35-40%, and water accounts for 20-30%, and emulsifier accounts for 20-30%, and polyalcohol accounts for 10-15%.Preparation method sequentially puts into the high-speed shearing machine with heating stirring by above-mentioned each component raw material, shears 20-30 minutes, and static reaction 24-48 hours, that is, form product.Product of the present invention, calorific value is high, at low cost, reaches five standard of state without paraffin, sulfur content, emission compliance can be applied to diesel ship and dynamic power machine.

Description

A kind of clean fuel oil preparation method peculiar to vessel
Technical field
The present invention relates to a kind of method of fuel oil preparation, in particular to a kind of clean fuel oil preparation methods peculiar to vessel.
Background technique
Currently, disclosed diesel oil emulsification and combined diesel oil patented technology, used diesel oil, consider that economy is all often Nonstandard diesel oil.Nonstandard diesel oil sulfur-bearing, paraffin are high, and unstable, are not suitable with the requirement of industrialization and application.For overcome it is above-mentioned not Foot, through experimental study in a few years, releases a kind of clean fuel oil preparation method peculiar to vessel.The cleaning peculiar to vessel combustion produced with the present invention Oil is free of petrochemical material and paraffin using biomass material, and sulfur content reaches five standard of state.Calorific value is high, power foot, at low cost, Emission compliance.Not only alternative marine diesel oil, can also be applied to dynamic power machine.
Summary of the invention
The present invention is made of following formula and preparation method.
Recipe ingredient weight ratio
Methanol accounts for 30-40%
Water accounts for 20-30%
Emulsifier accounts for 20-30%
Polyalcohol accounts for 10-15%
90-99.99% can be used in methanol purity of the present invention；Water uses pure water.
Emulsifier oil following weight ratio group of the invention is grouped as.
Gutter oil or palmitoleic acid account for 60-80%
Concentrated ammonia liquor accounts for 15-20%
Monoethanolamine accounts for 5-8%
Lysine accounts for 2-3%
Fumed silica accounts for 0.5-1%
Polyalcohol used in the present invention is made of following composition by weight.
Clean fuel oil peculiar to vessel is prepared by following procedure.
Firstly, the emulsifier each component for accounting for clean fuel oil weight ratio 20-30% peculiar to vessel is added to the height with heating stirring In fast cutter, it is heated to 90-100 DEG C, stirring shearing uniformly, cools down and keeps to 40-50 DEG C of
Secondly, polyol is added in the high-speed shearing machine of unlatching.
Again, the methanol of clean fuel oil 30-40% peculiar to vessel will be accounted for, the water of 20-30% is added in high-speed shearing machine.Stirring Shearing 20-30 minutes.As clear as crystal clean fuel oil peculiar to vessel can be become within static reaction 24-48 hours again.
Specific embodiment
Embodiment 1
Prepare its component weight ratio of clean fuel oil 50kg peculiar to vessel
Methanol accounts for 35% 17.5kg
Water accounts for 20%, 10kg
Emulsifier accounts for 30% 15kg
Polyalcohol accounts for 15% 7.5kg
Emulsifier 15kg is prepared first,
Its component weight ratio
Gutter oil accounts for 75% 11.25kg
Concentrated ammonia liquor accounts for 15% 2.25kg
Lysine accounts for 2% 0.3kg
Fumed silica accounts for 1% 0.15kg
It puts by mentioned emulsifier component in heating, the high-speed shearing machine stirred, being heated to 95 DEG C, stirring shearing is equal It is even, cool down and keeps 40 DEG C of
Secondly, the polyalcohol of 15kg is put into the high-speed shearing machine of unlatching,
Polyol weight ratio
N-butanol accounts for 33.5%, 5kg
Isobutanol accounts for 33.5%, 5kg
Acetone accounts for 20%, 3kg
Ethylene glycol accounts for 13%, 2kg
Again, by the methanol of 17.5kg, the water of 10kg is added to high-speed shearing machine, shears 30 minutes, and static reaction 24 Hour, as clear as crystal clean fuel oil peculiar to vessel can be obtained.

Claims (5)

1. a kind of clean fuel oil preparation method peculiar to vessel, which is characterized in that its formula is made of the component of following weight ratio.
2. spy is according to claim one, methanol purity 90-99.99%, water uses pure water.
3. according to claim one, which is characterized in that emulsifier is made of the component of following weight ratio.
4. according to claim one, which is characterized in that polyalcohol is made of following weight ratio component.
5. according to claim one, which is characterized in that preparation method is carried out by following procedure.
It is cut firstly, the emulsifier each component for accounting for clean fuel oil weight ratio 20-30% peculiar to vessel is added to the high speed with heating stirring It cuts in machine, is heated to 90-100 DEG C, shearing uniformly, cools down and remains to 40-50 DEG C.
Secondly, being added to polyol is accounted in the stirring cutter of unlatching.
Again, the methanol of clean fuel oil 30-40% peculiar to vessel will be accounted for, the water of 20-30% is added in high-speed shearing machine, stirring shearing 20-30 minutes, then static reaction 24-48 hours, as clear as crystal clean fuel oil peculiar to vessel can be become.
CN201710778452.6A 2017-08-24 2017-08-24 A kind of clean fuel oil preparation method peculiar to vessel Pending CN109423345A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710778452.6A CN109423345A (en) 2017-08-24 2017-08-24 A kind of clean fuel oil preparation method peculiar to vessel

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710778452.6A CN109423345A (en) 2017-08-24 2017-08-24 A kind of clean fuel oil preparation method peculiar to vessel

Publications (1)

Publication Number Publication Date
CN109423345A true CN109423345A (en) 2019-03-05

Family

ID=65512832

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201710778452.6A Pending CN109423345A (en) 2017-08-24 2017-08-24 A kind of clean fuel oil preparation method peculiar to vessel

Country Status (1)

Country Link
CN (1) CN109423345A (en)

Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US11124714B2 (en) 2020-02-19 2021-09-21 Marathon Petroleum Company Lp Low sulfur fuel oil blends for stability enhancement and associated methods
US11802257B2 (en) 2022-01-31 2023-10-31 Marathon Petroleum Company Lp Systems and methods for reducing rendered fats pour point
US11860069B2 (en) 2021-02-25 2024-01-02 Marathon Petroleum Company Lp Methods and assemblies for determining and using standardized spectral responses for calibration of spectroscopic analyzers
US11891581B2 (en) 2017-09-29 2024-02-06 Marathon Petroleum Company Lp Tower bottoms coke catching device
US11898109B2 (en) 2021-02-25 2024-02-13 Marathon Petroleum Company Lp Assemblies and methods for enhancing control of hydrotreating and fluid catalytic cracking (FCC) processes using spectroscopic analyzers
US11905468B2 (en) 2021-02-25 2024-02-20 Marathon Petroleum Company Lp Assemblies and methods for enhancing control of fluid catalytic cracking (FCC) processes using spectroscopic analyzers
US11970664B2 (en) 2021-10-10 2024-04-30 Marathon Petroleum Company Lp Methods and systems for enhancing processing of hydrocarbons in a fluid catalytic cracking unit using a renewable additive
US11975316B2 (en) 2019-05-09 2024-05-07 Marathon Petroleum Company Lp Methods and reforming systems for re-dispersing platinum on reforming catalyst
US12000720B2 (en) 2018-09-10 2024-06-04 Marathon Petroleum Company Lp Product inventory monitoring
US12031094B2 (en) 2021-02-25 2024-07-09 Marathon Petroleum Company Lp Assemblies and methods for enhancing fluid catalytic cracking (FCC) processes during the FCC process using spectroscopic analyzers
US12031676B2 (en) 2019-03-25 2024-07-09 Marathon Petroleum Company Lp Insulation securement system and associated methods

Cited By (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US11891581B2 (en) 2017-09-29 2024-02-06 Marathon Petroleum Company Lp Tower bottoms coke catching device
US12000720B2 (en) 2018-09-10 2024-06-04 Marathon Petroleum Company Lp Product inventory monitoring
US12031676B2 (en) 2019-03-25 2024-07-09 Marathon Petroleum Company Lp Insulation securement system and associated methods
US11975316B2 (en) 2019-05-09 2024-05-07 Marathon Petroleum Company Lp Methods and reforming systems for re-dispersing platinum on reforming catalyst
US11667858B2 (en) 2020-02-19 2023-06-06 Marathon Petroleum Company Lp Low sulfur fuel oil blends for stability enhancement and associated methods
US11920096B2 (en) 2020-02-19 2024-03-05 Marathon Petroleum Company Lp Low sulfur fuel oil blends for paraffinic resid stability and associated methods
US11352577B2 (en) 2020-02-19 2022-06-07 Marathon Petroleum Company Lp Low sulfur fuel oil blends for paraffinic resid stability and associated methods
US11352578B2 (en) 2020-02-19 2022-06-07 Marathon Petroleum Company Lp Low sulfur fuel oil blends for stabtility enhancement and associated methods
US11384301B2 (en) 2020-02-19 2022-07-12 Marathon Petroleum Company Lp Low sulfur fuel oil blends for stability enhancement and associated methods
US11124714B2 (en) 2020-02-19 2021-09-21 Marathon Petroleum Company Lp Low sulfur fuel oil blends for stability enhancement and associated methods
US11905479B2 (en) 2020-02-19 2024-02-20 Marathon Petroleum Company Lp Low sulfur fuel oil blends for stability enhancement and associated methods
US11906423B2 (en) 2021-02-25 2024-02-20 Marathon Petroleum Company Lp Methods, assemblies, and controllers for determining and using standardized spectral responses for calibration of spectroscopic analyzers
US11905468B2 (en) 2021-02-25 2024-02-20 Marathon Petroleum Company Lp Assemblies and methods for enhancing control of fluid catalytic cracking (FCC) processes using spectroscopic analyzers
US11921035B2 (en) 2021-02-25 2024-03-05 Marathon Petroleum Company Lp Methods and assemblies for determining and using standardized spectral responses for calibration of spectroscopic analyzers
US12031094B2 (en) 2021-02-25 2024-07-09 Marathon Petroleum Company Lp Assemblies and methods for enhancing fluid catalytic cracking (FCC) processes during the FCC process using spectroscopic analyzers
US11898109B2 (en) 2021-02-25 2024-02-13 Marathon Petroleum Company Lp Assemblies and methods for enhancing control of hydrotreating and fluid catalytic cracking (FCC) processes using spectroscopic analyzers
US11885739B2 (en) 2021-02-25 2024-01-30 Marathon Petroleum Company Lp Methods and assemblies for determining and using standardized spectral responses for calibration of spectroscopic analyzers
US11860069B2 (en) 2021-02-25 2024-01-02 Marathon Petroleum Company Lp Methods and assemblies for determining and using standardized spectral responses for calibration of spectroscopic analyzers
US11970664B2 (en) 2021-10-10 2024-04-30 Marathon Petroleum Company Lp Methods and systems for enhancing processing of hydrocarbons in a fluid catalytic cracking unit using a renewable additive
US11802257B2 (en) 2022-01-31 2023-10-31 Marathon Petroleum Company Lp Systems and methods for reducing rendered fats pour point

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