CN109396156B - Harmless reduction treatment method for hazardous waste - Google Patents
Harmless reduction treatment method for hazardous waste Download PDFInfo
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- CN109396156B CN109396156B CN201811106827.5A CN201811106827A CN109396156B CN 109396156 B CN109396156 B CN 109396156B CN 201811106827 A CN201811106827 A CN 201811106827A CN 109396156 B CN109396156 B CN 109396156B
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- 239000002920 hazardous waste Substances 0.000 title claims abstract description 75
- 238000000034 method Methods 0.000 title claims abstract description 28
- 230000009467 reduction Effects 0.000 title claims abstract description 10
- 239000002699 waste material Substances 0.000 claims abstract description 83
- 238000006243 chemical reaction Methods 0.000 claims abstract description 40
- 239000003795 chemical substances by application Substances 0.000 claims description 45
- 239000000203 mixture Substances 0.000 claims description 12
- 238000002156 mixing Methods 0.000 claims description 8
- 238000003756 stirring Methods 0.000 claims description 7
- 239000007787 solid Substances 0.000 claims description 6
- 239000004568 cement Substances 0.000 claims description 5
- 239000000701 coagulant Substances 0.000 claims description 4
- 230000003472 neutralizing effect Effects 0.000 claims description 4
- 239000008394 flocculating agent Substances 0.000 claims description 3
- 238000011065 in-situ storage Methods 0.000 claims description 3
- 238000007711 solidification Methods 0.000 abstract description 4
- 230000008023 solidification Effects 0.000 abstract description 4
- 238000005192 partition Methods 0.000 abstract 1
- 230000008569 process Effects 0.000 description 6
- 238000010276 construction Methods 0.000 description 5
- 230000006378 damage Effects 0.000 description 4
- 238000004062 sedimentation Methods 0.000 description 3
- 239000002253 acid Substances 0.000 description 2
- 238000000280 densification Methods 0.000 description 2
- 239000003344 environmental pollutant Substances 0.000 description 2
- 229910001385 heavy metal Inorganic materials 0.000 description 2
- 238000002955 isolation Methods 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 231100000719 pollutant Toxicity 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 230000000087 stabilizing effect Effects 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 239000003513 alkali Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000011449 brick Substances 0.000 description 1
- 239000003518 caustics Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000009776 industrial production Methods 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 235000010446 mineral oil Nutrition 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229940124024 weight reducing agent Drugs 0.000 description 1
- 239000013585 weight reducing agent Substances 0.000 description 1
Images
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B09—DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
- B09B—DISPOSAL OF SOLID WASTE NOT OTHERWISE PROVIDED FOR
- B09B3/00—Destroying solid waste or transforming solid waste into something useful or harmless
- B09B3/20—Agglomeration, binding or encapsulation of solid waste
Landscapes
- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Processing Of Solid Wastes (AREA)
Abstract
The invention provides a harmless reduction treatment method of hazardous waste, which comprises the following steps: 1) the method comprises the following steps of (1) stacking dangerous wastes in a centralized manner, and arranging a reaction container for disposing the dangerous wastes; 2) the dangerous waste pile is separated, and a fixed dike is built between the area to be treated and the dangerous waste pile; 3) adding a harmless comprehensive treatment agent into the reaction container to realize harmless treatment of the hazardous waste and standing and solidifying; 4) building walls around the treated area to be treated to form a reaction enclosed area; 5) step 2) is repeatedly carried out on the other side of the partition wall of the reaction enclosed area, a new area to be treated is separated from the adjacent area of the reaction enclosed area, and harmless treatment and standing solidification of the hazardous waste are realized; 6) and (5) repeating the steps 4) to 5) until all the dangerous wastes in the dangerous waste pile are harmlessly treated and solidified. The invention can carry out harmless treatment on the hazardous waste and keep the hazardous waste stable.
Description
Technical Field
The invention relates to the field of hazardous waste environment-friendly treatment processes, in particular to a harmless reduction treatment method for hazardous waste.
Background
In the industrial production process, wastes which can pollute the environment are easily generated, and the wastes must be treated to avoid polluting the environment. The hazardous waste specified in the national standard has strong acid or strong alkalinity, and various harmful substances such as heavy metals which can harm the environment, and the hazardous waste has great harm to the environment; and the material state is extremely unstable, and the processing difficulty is extremely high.
In the prior art, dangerous waste is treated by intensively stacking and enclosing, and then adding a medicament into a specific container for reaction, so that the dangerous waste is harmless. The treatment mode is not only low in efficiency, but also easy to cause the dangerous waste to flow out due to extremely unstable physical state of the dangerous waste, difficult to control, easy to damage an operation site, and even cause personal damage to operators on the site in serious cases.
It is obvious that the prior art has certain defects.
Disclosure of Invention
The invention aims to provide a harmless reduction treatment method of hazardous waste, which carries out harmless treatment on the hazardous waste and keeps the hazardous waste stable.
In order to achieve the purpose, the invention adopts the following technical scheme:
a harmless reduction treatment method for hazardous waste comprises the following steps:
1) the method comprises the following steps of (1) stacking hazardous wastes in a centralized manner, and arranging a reaction container for disposing the hazardous wastes outside a hazardous waste pile;
2) separating the dangerous waste pile to enable the dangerous waste pile to be cleaned and divided into a block to be used as a to-be-treated area, judging the state of the dangerous waste in the to-be-treated area, and selecting one of the step 2A) or the step 2B) to implement;
2A) if the dangerous waste in the area to be treated is solid and stable enough, the dangerous waste is not isolated;
2B) if the dangerous waste in the area to be treated is in a liquid-like unstable state, building a fixed bank between the area to be treated and the dangerous waste pile;
3) adding a harmless comprehensive treatment agent into the reaction container in proportion, transferring the dangerous waste in the area to be treated into the reaction container, mixing and stirring the dangerous waste and the harmless comprehensive treatment agent, realizing the harmless treatment of the dangerous waste, and standing and curing;
4) building a wall body around the treated area to be treated to enclose, wherein the wall body is connected with the part of the dam to be bordered and enclosed to form a reaction enclosed area;
5) repeatedly carrying out the steps 2) to 2A) or the steps 2) to 2B) on adjacent areas of the reaction enclosed area, adding a harmless comprehensive treatment agent into the reaction enclosed area in proportion, transferring the dangerous waste in the area to be treated into the reaction enclosed area, mixing and stirring the dangerous waste with the harmless comprehensive treatment agent, realizing the harmless treatment of the dangerous waste, and standing and curing;
6) and (5) repeating the steps 4) to 5) until all the dangerous wastes in the dangerous waste pile are harmlessly treated and solidified.
Further, the step 2B) includes:
2B.1) digging a groove extending along a boundary line at the edge boundary line of the area to be processed;
2B.2) adding a mixture of the harmless comprehensive treatment agent and the hazardous waste after full mixing into the groove, and standing and curing the mixture in the groove to form a curing block with the shape matched with the groove;
2B.3) in-situ settling the solidified block obtained in the step 2B.2) and sinking to the bottom of a dangerous waste pile;
2B.4) repeating the steps 2B.1) to 2B.3), and constructing the bottom layer of the bank along the boundary;
2B.5) digging a groove extending along the boundary above the bottom layer of the dike in the step 2B.4), adding a mixture of the harmless comprehensive treatment agent and the dangerous waste into the groove, standing and curing the mixture in the groove to form a curing block with the shape matched with the groove, and sinking the curing block onto the bottom layer of the dike until a plurality of layers of curing blocks are stacked to form the complete dike.
Further, in the step 2b.1), the bottom of the groove is in a shape of a sharp blade.
Further, in the step 1), the reaction vessel is a reaction tank constructed of cement.
Further, in the step 1), the dangerous waste is relatively and intensively piled in the excavated stockpiling pit to be treated.
Further, in the step 2b.3) and the step 2b.5), the solidified blocks are settled down by digging the dangerous waste below the solidified blocks by an excavator.
Further, the harmless comprehensive treatment agent comprises a neutralizing agent, a coagulating agent and a comprehensive treatment agent.
Further, the harmless comprehensive treatment agent also comprises a flocculating agent.
Further, the harmless comprehensive treatment agent also comprises a compacting agent.
The harmless reduction treatment method for the hazardous waste provided by the invention has the following advantages:
firstly, the hazardous waste is subjected to large-scale centralized treatment in an operation site, the efficiency is high, and the hazardous waste can be harmlessly treated and stably solidified;
secondly, a stable structure is formed by unique construction operation, so that the stack of the dangerous waste is kept stable, the dangerous waste is prevented from being poured and diffused, and the field operation is facilitated;
the stable structure directly uses dangerous waste as raw material, and the curing operation is convenient;
and fourthly, the operation is performed in different areas, so that the harmless operation of the dangerous waste is more orderly.
Drawings
In order to make the objects, technical solutions and advantages of the embodiments of the present invention clearer, the technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the embodiments of the present invention and the accompanying drawings. It should be noted that the described embodiments are only a part of the embodiments of the present invention, and not all embodiments. All other embodiments, which can be obtained by a person skilled in the art without any inventive step based on the embodiments of the present invention, are within the scope of the present invention.
FIG. 1 is a schematic view of an initial state of a work site
FIG. 2 is a schematic flow chart of a method for harmless minimization of hazardous waste according to the present invention
FIG. 3 is a schematic flow chart of the process of constructing the bank by settling the solidified blocks in step 2)
Description of reference numerals:
1. hazardous waste 2 and reaction vessel
3. Dike 4 and wall
5. Reaction enclosed area 6, groove
7. Solidified block
Detailed Description
In order to make the objects, technical solutions and advantages of the embodiments of the present invention clearer, the technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the embodiments of the present invention and the accompanying drawings. It should be noted that the described embodiments are only a part of the embodiments of the present invention, and not all embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
Example one
Referring to fig. 1 to 2, the present embodiment discloses a method for harmless minimization of hazardous waste, which includes the following steps:
1) the dangerous waste 1 is piled up in a centralized way, and a reaction container 2 for disposing the dangerous waste 1 is arranged outside the pile of the dangerous waste 1;
2) separating the stack of the dangerous waste 1 to separate the stack of the dangerous waste 1 into a block serving as a to-be-treated area, judging the state of the dangerous waste 1 in the to-be-treated area, and selecting one of the step 2A) and the step 2B) to implement;
2A) if the dangerous waste 1 in the area to be treated is solid and stable enough, the isolation treatment is not carried out;
2B) if the dangerous waste 1 in the area to be treated is in a liquid-like unstable state, building a fixed bank 3 between the area to be treated and the pile of the dangerous waste 1;
3) adding a harmless comprehensive treatment agent into the reaction container 2 in proportion, transferring the dangerous waste 1 in the area to be treated into the reaction container 2, mixing and stirring the dangerous waste 1 with the harmless comprehensive treatment agent, realizing the harmless treatment of the dangerous waste 1, and standing and curing;
4) building a wall body 4 around the treated area to be treated to enclose, and connecting and enclosing the wall body 4 and the part of the dike 3 which is bordered to form a reaction enclosed area 5;
5) repeatedly carrying out the steps 2) to 2A) or the steps 2) to 2B) on the adjacent area of the reaction enclosed area 5, adding a harmless comprehensive treatment agent into the reaction enclosed area 5 in proportion, transferring the dangerous waste 1 in the area to be treated into the reaction enclosed area 5, mixing and stirring the dangerous waste 1 with the harmless comprehensive treatment agent, and realizing the harmless treatment and standing solidification of the dangerous waste 1;
6) and (5) repeatedly carrying out the steps 4) to 5) until all the dangerous waste 1 in the stack of the dangerous waste 1 is harmlessly treated and solidified.
The present invention is most characterized in that the hazardous waste 1 is not simply put in a container for reaction treatment, but the hazardous waste 1 is divided into a plurality of blocks for batch treatment by a construction method, and a bank 3 is built at a boundary to separate the blocks if necessary, thereby stabilizing the hazardous waste 1.
Aiming at the hazardous waste 1 to be treated, the invention has the characteristics of extremely strong acidity or alkalinity, and extremely low or high pH value in general; the physical state is between oil state and solid state, the physical state change between different blocks is complex, and the oily hazardous waste 1 has high viscosity and a large amount of components. If most of the hazardous waste 1 in the block is oily, once the construction work is carried out by the excavating machine to transfer the hazardous waste 1 to the container, the hazardous waste 1 is dumped and spread from the gap in a large amount, and the work site becomes difficult to control and even damaged. In view of the instability of the hazardous waste 1, the operation site is inconvenient to use heavy operation equipment, and the operation difficulty is increased.
Therefore, the operation scheme of the invention is to stabilize the stack of the hazardous waste 1 and control the flowing of the hazardous waste 1. Specifically, in the step 2), the hazardous waste 1 in the divided areas to be treated is judged, and whether the physical state is stable enough is judged. In general, if the temperature and the humidity of the site are appropriate, the state of the hazardous waste 1 tends to be a solid state relatively, and is stable; if the conditions in the field are severe, the hazardous waste 1 may be melted into an oil-like liquid state by the influence of temperature, humidity, etc., and its stability is insufficient for the field treatment work. If the state of the dangerous waste 1 is not stable enough, the flow of the dangerous waste 1 pile can be stopped by constructing the bank 3 to prevent the dumping, so that the dangerous waste 1 can be conveniently transferred and the harmless comprehensive treatment agent is added to carry out stirring reaction in the step 3). On the premise that the dangerous waste 1 in the area is separated stably, operation of the operation machine on the dangerous waste 1 pile can be even realized, operation difficulty is greatly reduced, and the utilization rate of the machine is improved. If the hazardous waste 1 itself in the area is relatively stable in physical state, the isolation measure can be omitted to further enhance the process of the harmless operation. Then, the invention adopts the operation mode of gradually separating the stack of the dangerous waste 1, and repeatedly implements the steps 4) to 5) to carry out the following steps on the dangerous waste 1 one by one: stabilization, harmless treatment and solidification. And (5) repeating the process from the step 4) to the step 5), namely, performing harmless treatment on the dangerous waste 1 by regional emptying and transferring to an adjacent region, and then changing the originally emptied region into a new reaction enclosed region 5, so that the operation can be continuously extended until all the dangerous waste 1 is completely subjected to harmless treatment.
Preferably, in the step 1), the reaction vessel 2 is a reaction tank made of cement. The reaction vessel 2 is not necessarily cement-based in principle, but since the amount of the hazardous waste 1 is large, it is preferable to construct a cement-based reaction tank on site to improve efficiency. In addition, in the step 1), the hazardous waste 1 is preferably relatively intensively piled in the dug stockpiling pit to be treated, so that the stability of the pile of the hazardous waste 1 can be further improved, and the operation is facilitated.
The present invention innovatively uses the hazardous waste 1 itself as a raw material for the construction method of the bank 3. Referring to fig. 3, preferably, the step 2B) includes:
2B.1) digging a groove 6 extending along the boundary at the edge of the area to be processed;
2B.2) adding a mixture of the harmless comprehensive treatment agent and the hazardous waste 1 into the groove 6, and standing and curing the mixture in the groove 6 to form a curing block 7 with the shape matched with that of the groove 6;
2B.3) in situ sedimentation of the solidified blocks 7 obtained in step 2B.2) into the pile of hazardous waste 1;
2b.4) repeating steps 2b.1) to 2b.3), constructing the bottom layer of the bank 3 along the boundary;
2B.5) digging a groove 6 extending along the boundary above the bottom layer of the bank 3 in the step 2B.4), adding a mixture of a harmless comprehensive treatment agent and the hazardous waste 1 which are fully mixed into the groove 6, standing and curing the mixture in the groove 6 to form a curing block 7 with the shape matched with the groove 6, and making the curing block 7 sink onto the bottom layer of the bank 3 until a plurality of layers of curing blocks 7 are stacked to form the complete bank 3.
When step 2b.1) is carried out, the recess 6 is excavated, which corresponds in practice to the creation of a "mould" at the parting line for the production of the solidified mass 7. Then step 2B.2) is carried out, because the hazardous waste 1 reacts with the harmless comprehensive treatment agent, the hazardous waste is finally solidified into a hard and stable solidified block 7 after being harmlessly treated, and the process of standing and solidifying is generally over 12 hours. The shape of the solidified blocks 7 corresponds to the shape of the recesses 6, which corresponds to the "bricks" used to form the banks 3. In step 2b.3) and step 2b.5), the solidified block 7 is settled due to its own weight because the exhaust gas reactant is not solid. In order to make the sedimentation smoother, in step 2b.1), the bottom of the groove 6 is preferably in a sharp knife edge shape, that is, the bottom of the bottom solidified block 7 is in a knife edge shape, and the bottom of the bottom solidified block 7 discharges the dangerous waste 1 during the sedimentation process. When the viscosity of the hazardous waste 1 below the solidified block 7 is too high to be settled, the solidified block 7 can be settled downwards by digging the hazardous waste 1 below the solidified block 7 through an excavator in the step 2B.3) and the step 2 B.5).
Specifically, the above-mentioned harmless comprehensive treating agent includes a neutralizing agent, a coagulating agent and a comprehensive treating agent. Since the hazardous waste 1 is a highly corrosive substance of strong acid or strong alkali, a neutralizing agent is required for the neutralization reaction. The coagulant can solidify the dangerous waste 1 into hard and stable solidified blocks 7, and is also an important ingredient of the harmless comprehensive treatment agent in the invention. The comprehensive treatment agent is mainly used for stabilizing heavy metals, mineral oil and the like in the hazardous waste 1.
As a further preference, the harmless comprehensive treatment agent can also be added with a flocculating agent. The flocculant is mainly applied to the treatment of polluted water bodies to remove harmful pollutants dissolved in polluted liquid, so that the harmful pollutants are gathered and solidified to be separated from the water bodies.
Furthermore, the harmless comprehensive treatment agent also comprises a compacting agent, and the compacting agent has the function of gathering and compacting the internal tissues of the dangerous waste 1, so that the solidified hazardous waste has smaller volume and lighter weight, and the storage space is saved. The densification agent is also called as a weight reducing agent, and has a certain shrinkage rate in a densification effect, so that the hazardous waste 1 stacked in a large area can be changed into a harmless condensate with a reduced volume proportion after being treated, and the hazardous waste can be conveniently stacked in a smaller occupied area.
Since the specific components of the harmless comprehensive treatment agent are prepared according to the needs and are not the technical key points of the invention, the specific components and the proportion of the harmless comprehensive treatment agent are not repeated.
According to the harmless reduction treatment method for the hazardous waste, provided by the invention, the hazardous waste 1 is subjected to large-scale centralized treatment on the operation site, the efficiency is high, and the hazardous waste 1 can be harmless and can be stably solidified. Unique construction operation forms stable structure, and this stable structure is built through the solidification piece 7 that hazardous waste 1 self innoxious formation forms, makes hazardous waste 1 pile keep stable, prevents that hazardous waste 1 from pouring and diffusing, the field operation of being convenient for.
The above-mentioned embodiments only express several embodiments of the present invention, and the description thereof is more specific and detailed, but not construed as limiting the scope of the present invention. It should be noted that, for a person skilled in the art, several variations and modifications can be made without departing from the inventive concept, which falls within the scope of the present invention. Therefore, the protection scope of the present patent shall be subject to the appended claims.
Claims (9)
1. A harmless quantitative reduction treatment method for hazardous waste is characterized by comprising the following steps:
1) the method comprises the following steps of (1) stacking hazardous wastes in a centralized manner, and arranging a reaction container for disposing the hazardous wastes outside a hazardous waste pile;
2) separating the dangerous waste pile to enable the dangerous waste pile to be cleaned and divided into a block to be used as a to-be-treated area, judging the state of the dangerous waste in the to-be-treated area, and selecting one of the step 2A) or the step 2B) to implement;
2A) if the dangerous waste in the area to be treated is solid and stable enough, the dangerous waste is not isolated;
2B) if the dangerous waste in the area to be treated is in a liquid-like unstable state, building a fixed bank between the area to be treated and the dangerous waste pile;
3) adding a harmless comprehensive treatment agent into the reaction container in proportion, transferring the dangerous waste in the area to be treated into the reaction container, mixing and stirring the dangerous waste and the harmless comprehensive treatment agent, realizing the harmless treatment of the dangerous waste, and standing and curing;
4) building a wall body around the treated area to be treated to enclose, wherein the wall body is connected with the part of the dam to be bordered and enclosed to form a reaction enclosed area;
5) repeatedly carrying out the steps 2) to 2A) or the steps 2) to 2B) on adjacent areas of the reaction enclosed area, adding a harmless comprehensive treatment agent into the reaction enclosed area in proportion, transferring the dangerous waste in the area to be treated into the reaction enclosed area, mixing and stirring the dangerous waste with the harmless comprehensive treatment agent, realizing the harmless treatment of the dangerous waste, and standing and curing;
6) and (5) repeating the steps 4) to 5) until all the dangerous wastes in the dangerous waste pile are harmlessly treated and solidified.
2. The method for harmless quantitative reduction of hazardous waste according to claim 1, wherein said step 2B) comprises:
2B.1) digging a groove extending along a boundary line at the edge boundary line of the area to be processed;
2B.2) adding a mixture of the harmless comprehensive treatment agent and the hazardous waste after full mixing into the groove, and standing and curing the mixture in the groove to form a curing block with the shape matched with the groove;
2B.3) in-situ settling the solidified block obtained in the step 2B.2) and sinking to the bottom of a dangerous waste pile;
2B.4) repeating the steps 2B.1) to 2B.3), and constructing the bottom layer of the bank along the boundary;
2B.5) digging a groove extending along the boundary above the bottom layer of the dike in the step 2B.4), adding a mixture of the harmless comprehensive treatment agent and the dangerous waste into the groove, standing and curing the mixture in the groove to form a curing block with the shape matched with the groove, and sinking the curing block onto the bottom layer of the dike until a plurality of layers of curing blocks are stacked to form the complete dike.
3. The method for harmless minimization of hazardous waste according to claim 2, wherein: in the step 2B.1), the bottom of the groove is in a sharp blade shape.
4. The method for harmless minimization of hazardous waste according to claim 1, wherein: in the step 1), the reaction vessel is a reaction tank constructed by cement.
5. The method for harmless minimization of hazardous waste according to claim 1, wherein: in the step 1), the dangerous wastes are relatively and intensively piled in a dug piling pit to be treated.
6. The method for harmless minimization of hazardous waste according to claim 2, wherein: in the step 2b.3) and the step 2b.5), the solidified block is settled downward by digging the dangerous waste below the solidified block with an excavator.
7. A method for the harmless abatement of hazardous waste according to any of the preceding claims, characterized by: the harmless comprehensive treatment agent comprises a neutralizing agent, a coagulating agent and a comprehensive treatment agent.
8. The method for harmless minimization of hazardous waste according to claim 7, wherein: the harmless comprehensive treatment agent also comprises a flocculating agent.
9. The method for harmless minimization of hazardous waste according to claim 7, wherein: the harmless comprehensive treatment agent also comprises a compacting agent.
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CN101254630A (en) * | 2008-03-17 | 2008-09-03 | 刘永定 | Stabilization and solidify method of dangerous wastes |
CN103718249A (en) * | 2012-07-17 | 2014-04-09 | 山本基础工业股份有限公司 | Waste burial method and waste storage container |
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