CN109372217A - A kind of polymer nano-floor and its production method - Google Patents
A kind of polymer nano-floor and its production method Download PDFInfo
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- CN109372217A CN109372217A CN201811253609.4A CN201811253609A CN109372217A CN 109372217 A CN109372217 A CN 109372217A CN 201811253609 A CN201811253609 A CN 201811253609A CN 109372217 A CN109372217 A CN 109372217A
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- floor
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- cavity
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- 229920000642 polymer Polymers 0.000 title claims abstract description 25
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 14
- 239000000463 material Substances 0.000 claims abstract description 36
- 239000002086 nanomaterial Substances 0.000 claims abstract description 31
- 239000000758 substrate Substances 0.000 claims abstract description 26
- 239000003063 flame retardant Substances 0.000 claims abstract description 10
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 claims abstract description 5
- 230000000903 blocking effect Effects 0.000 claims abstract description 4
- 238000011049 filling Methods 0.000 claims abstract description 4
- 230000000844 anti-bacterial effect Effects 0.000 claims description 29
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 15
- 239000003973 paint Substances 0.000 claims description 15
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N titanium dioxide Inorganic materials O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 13
- 239000002245 particle Substances 0.000 claims description 10
- 230000000694 effects Effects 0.000 claims description 9
- 238000002156 mixing Methods 0.000 claims description 9
- 239000000843 powder Substances 0.000 claims description 9
- 238000003756 stirring Methods 0.000 claims description 9
- 239000003381 stabilizer Substances 0.000 claims description 8
- 239000000377 silicon dioxide Substances 0.000 claims description 7
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 6
- 238000001816 cooling Methods 0.000 claims description 6
- 238000000465 moulding Methods 0.000 claims description 6
- 235000010215 titanium dioxide Nutrition 0.000 claims description 6
- SOQBVABWOPYFQZ-UHFFFAOYSA-N oxygen(2-);titanium(4+) Chemical class [O-2].[O-2].[Ti+4] SOQBVABWOPYFQZ-UHFFFAOYSA-N 0.000 claims description 5
- 238000000034 method Methods 0.000 claims description 4
- 239000000203 mixture Substances 0.000 claims description 4
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 claims description 3
- 239000004925 Acrylic resin Substances 0.000 claims description 3
- 229920000178 Acrylic resin Polymers 0.000 claims description 3
- 239000006057 Non-nutritive feed additive Substances 0.000 claims description 3
- 238000001035 drying Methods 0.000 claims description 3
- 239000003822 epoxy resin Substances 0.000 claims description 3
- 238000001914 filtration Methods 0.000 claims description 3
- 230000001678 irradiating effect Effects 0.000 claims description 3
- 239000000314 lubricant Substances 0.000 claims description 3
- 239000003607 modifier Substances 0.000 claims description 3
- 239000012188 paraffin wax Substances 0.000 claims description 3
- 229920001568 phenolic resin Polymers 0.000 claims description 3
- 239000005011 phenolic resin Substances 0.000 claims description 3
- -1 phosphorous acid lipid Chemical class 0.000 claims description 3
- 229920000647 polyepoxide Polymers 0.000 claims description 3
- 230000008569 process Effects 0.000 claims description 3
- 239000011347 resin Substances 0.000 claims description 3
- 229920005989 resin Polymers 0.000 claims description 3
- 239000000344 soap Substances 0.000 claims description 3
- 238000003860 storage Methods 0.000 claims description 3
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 2
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims description 2
- 229910052791 calcium Inorganic materials 0.000 claims description 2
- 239000011575 calcium Substances 0.000 claims description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 claims description 2
- 229910052761 rare earth metal Inorganic materials 0.000 claims description 2
- 150000002910 rare earth metals Chemical class 0.000 claims description 2
- 229910052710 silicon Inorganic materials 0.000 claims description 2
- 239000010703 silicon Substances 0.000 claims description 2
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical group [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims 1
- 239000010931 gold Substances 0.000 claims 1
- 229910052737 gold Inorganic materials 0.000 claims 1
- 229920002521 macromolecule Polymers 0.000 abstract description 9
- 239000007787 solid Substances 0.000 abstract description 5
- 238000011161 development Methods 0.000 abstract description 3
- 239000011797 cavity material Substances 0.000 description 12
- 230000006872 improvement Effects 0.000 description 11
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 8
- 230000036541 health Effects 0.000 description 6
- 239000002105 nanoparticle Substances 0.000 description 6
- NDVLTYZPCACLMA-UHFFFAOYSA-N silver oxide Chemical compound [O-2].[Ag+].[Ag+] NDVLTYZPCACLMA-UHFFFAOYSA-N 0.000 description 6
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 5
- 239000002131 composite material Substances 0.000 description 5
- 229910052709 silver Inorganic materials 0.000 description 5
- 239000004332 silver Substances 0.000 description 5
- 241000238631 Hexapoda Species 0.000 description 4
- 239000006261 foam material Substances 0.000 description 4
- 238000009413 insulation Methods 0.000 description 4
- 230000002265 prevention Effects 0.000 description 4
- 239000004408 titanium dioxide Substances 0.000 description 4
- 239000011787 zinc oxide Substances 0.000 description 4
- PTFCDOFLOPIGGS-UHFFFAOYSA-N Zinc dication Chemical compound [Zn+2] PTFCDOFLOPIGGS-UHFFFAOYSA-N 0.000 description 3
- 238000013461 design Methods 0.000 description 3
- 229910001923 silver oxide Inorganic materials 0.000 description 3
- 235000017166 Bambusa arundinacea Nutrition 0.000 description 2
- 235000017491 Bambusa tulda Nutrition 0.000 description 2
- 241001330002 Bambuseae Species 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 2
- 235000015334 Phyllostachys viridis Nutrition 0.000 description 2
- 208000027418 Wounds and injury Diseases 0.000 description 2
- 239000000956 alloy Substances 0.000 description 2
- 229910045601 alloy Inorganic materials 0.000 description 2
- 239000011425 bamboo Substances 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L calcium carbonate Substances [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- 239000003610 charcoal Substances 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- 230000006378 damage Effects 0.000 description 2
- 239000002657 fibrous material Substances 0.000 description 2
- 238000005187 foaming Methods 0.000 description 2
- 208000014674 injury Diseases 0.000 description 2
- 239000004922 lacquer Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 238000010422 painting Methods 0.000 description 2
- 238000004321 preservation Methods 0.000 description 2
- 241000894006 Bacteria Species 0.000 description 1
- JPVYNHNXODAKFH-UHFFFAOYSA-N Cu2+ Chemical compound [Cu+2] JPVYNHNXODAKFH-UHFFFAOYSA-N 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- FOIXSVOLVBLSDH-UHFFFAOYSA-N Silver ion Chemical compound [Ag+] FOIXSVOLVBLSDH-UHFFFAOYSA-N 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 235000010216 calcium carbonate Nutrition 0.000 description 1
- 229910001431 copper ion Inorganic materials 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 238000004079 fireproofing Methods 0.000 description 1
- 238000009408 flooring Methods 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000000016 photochemical curing Methods 0.000 description 1
- 230000000979 retarding effect Effects 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 239000000741 silica gel Substances 0.000 description 1
- 229910002027 silica gel Inorganic materials 0.000 description 1
- 230000001629 suppression Effects 0.000 description 1
Classifications
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
- E04F15/00—Flooring
- E04F15/02—Flooring or floor layers composed of a number of similar elements
- E04F15/02038—Flooring or floor layers composed of a number of similar elements characterised by tongue and groove connections between neighbouring flooring elements
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D127/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers
- C09D127/02—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
- C09D127/04—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C09D127/06—Homopolymers or copolymers of vinyl chloride
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
- C09D7/62—Additives non-macromolecular inorganic modified by treatment with other compounds
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
- E04F15/00—Flooring
- E04F15/18—Separately-laid insulating layers; Other additional insulating measures; Floating floors
- E04F15/181—Insulating layers integrally formed with the flooring or the flooring elements
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2286—Oxides; Hydroxides of metals of silver
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2296—Oxides; Hydroxides of metals of zinc
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Architecture (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Civil Engineering (AREA)
- Plant Pathology (AREA)
- Inorganic Chemistry (AREA)
- Floor Finish (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
A kind of polymer nano-floor and its production method, including floor body, transversely section is equipped at least one cavity inside the floor body, the cavity penetrates through the floor body, light filling foamed material in the cavity, the two ends of the cavity are equipped with the plug for blocking cavity, the floor body successively includes top layer from top to down, substrate layer and bottom, high molecule nano material layer is equipped between the top layer and the substrate layer, the high molecule nano material layer upper and lower surface is equipped with link block, the top layer and the substrate layer are equipped with and the mutually matched link slot of the link block, wearing layer is equipped with above the top layer, it is successively arranged waterproof layer from top to bottom between the substrate layer and the bottom, flame-retardant layer and buffer layer.Solid wooden floor board is replaced using macromolecule, realizes and recycles, the trees of country is protected, walks sustainable development route.
Description
Technical field
The present invention relates to floor manufacture fields, and in particular to a kind of polymer nano-floor and its production method.
Background technique
In recent years, as the improvement of people's living standards, house fitting product is rapidly developed, to offer floor base material
The product demand of protection increasing fast therewith, meanwhile, people have higher more urgent demand to environmental protection and health.In family wear
In repairing, solid wooden floor board is had been favored by people.But most easy shape between solid wooden floor board surface, floor and below floor
At the pollution sources of indoor environment, such as germ, worm, ant, the health of people is directly threaten, and floor mildew can also subtract
The service life on few floor.
Macromolecule composite floor has the characteristics that dicoration is strong, feel is good, light, and people usually select these macromolecules multiple
Floor is closed to decorate flooring.Polymer floor be mixed by ingredients such as resin, filler, auxiliary agents one kind easily again
Raw based plate, with the scarcity of timber resources, the usage amount of polymer floor is continuously increased, though existing polymer floor in the presence of
Good overall characteristic, but most heatproofs, wearability are poor.With these macromolecule composite floors use it is increasingly wide
General, people more wish that these macromolecule composite floors have heatproof, wear-resisting, antibacterial, antibacterial action, and have certain health care
Function, but there is clearly disadvantageous in this respect on the floor of the prior art
Therefore, the above problem should be paid attention to and be solved the problems, such as during the design and use to polymer floor.
Summary of the invention
In view of the above problems, the present invention provides a kind of polymer nano-floor and its production method, solves existing
The problem of with the presence of technique center.
The technical solution of the invention is as follows: a kind of polymer nano-floor, including floor body, in the floor body
Transversely section is equipped at least one cavity in portion, and the cavity penetrates through the floor body, light filling foaming in the cavity
Material, the two ends of the cavity are equipped with the plug for blocking cavity, and the floor body successively includes top layer from top to down,
Substrate layer and bottom are equipped with high molecule nano material layer, the high molecule nano material between the top layer and the substrate layer
Layer upper and lower surface is equipped with link block, and the top layer and the substrate layer are equipped with and the mutually matched connection of the link block
Slot is equipped with wearing layer above the top layer, is successively arranged waterproof layer, fire-retardant between the substrate layer and the bottom from top to bottom
Layer and buffer layer.
A further improvement of the present invention is that: the wearing layer upper surface coats one layer of base paint special, the base paint special
Top showering has one layer of ultraviolet light cured paint.
A further improvement of the present invention is that: it is that 8-15um is far red that wavelength is uniformly provided in the high molecule nano material layer
The nano material particle of outside line and with antibacterial, antibacterial functions inorganic nano material particle.
The wavelength is that the nano material particle of 8- 15um far infrared is selected from titanium dioxide, zinc oxide and silica,
It is described with antibacterial, antibacterial functions inorganic nano material particle be selected from silver, silver oxide and silver ion nanoparticle,
It may include or do not include copper ions or the nanoparticle with zinc ion.
A further improvement of the present invention is that: the upper surface on the floor sets indent and convex non-slip texture.
A further improvement of the present invention is that: one layer of sealing is covered on the outer surface of the link block or the link slot
Elastic layer.
A further improvement of the present invention is that: a kind of production method of high molecule nano material layer is provided, it is specific to walk
It is rapid as follows:
S1: material mixture ratio, the component including following parts by weight are made, 70-80 parts of Corvics, 30-40 parts of acetic acid second
Olefine resin, 10-15 parts of epoxy resin, 20-30 parts of acrylic resins, 15-20 parts of phenolic resin, the 30-60 parts of fine carbonic acid of activity
Calcium, 5-10 parts of fire retardants, 0.5-1 parts of paraffin, 4-6 parts of nano-titanium dioxides, 4-6 parts of nano zine oxides, 2-4 parts of nanometer titanium dioxides
Silicon, 2-4 parts of nano phase ag_2 os, 1-3 parts of processing aids, 1-3 parts of plasticized modifiers, 1-2 parts of stabilizers, 0.5-1 parts of lubricants；
S2: by nano-titanium dioxide, nano zine oxide is ground into 60-80nm after nano silica and nano phase ag_2 o mixing
Powder it is spare；
S3: gained powder in S2 being put into after irradiating 25-30min under the conditions of the far infrared of wavelength 8-15um and taken out, then by its
It is placed in methyl methacrylate solution and impregnates 20-30min, drying for standby after filtering；
S4: powder obtained in proportioned material and S3 is mixed to be added in high temperature pot and be stirred by mixing material, and high temperature pot exists
Material is stirred in unit time, the temperature in high temperature pot is maintained at 150 DEG C or more by whipping process, right after the completion of stirring
Material is cooled down rapidly, then material is being carried out storage placement, until its temperature reaches room temperature；
S5: squeezing out substrate, puts the material that mixing is completed into extruder and handles, and is simultaneously squeezed material using molding die
High molecule nano material layer is obtained out.
A further improvement of the present invention is that: the high molecule nano material layer with a thickness of 2 ~ 8mm.
A further improvement of the present invention is that: the stabilizer is metal soap, in phosphorous acid lipid, rare-earth stabilizer
It is at least one.
A further improvement of the present invention is that: temperature cooling rapidly is carried out not to the material after stirring in the step S4
More than 45 DEG C, to the material progress after stirring, standing time after cooling is 15- 20h rapidly.
A further improvement of the present invention is that: the temperature of the extruding zone of the extruder in the step S5 is at 150-200 DEG C
Between, the temperature of molding die is between 180-220 DEG C.
The present invention provides a kind of polymer nano-floor, uses hollow design, and add lightweight foam material wherein,
Heat insulation effect is enhanced, intensity and elasticity are increased, soundproof effect is good.Increase between floor body and ultraviolet light cured paint
One layer of base paint special, lacquer painting are not easily to fall off.Titanium dioxide, zinc oxide and silica nanoparticles can absorb and reflect people
The most desirable wavelength of body is 8-15 um far infrared, and far infrared is referred to as " sunlight lifeline " in foreign countries, makes tool of the present invention
There is preferable infrared health function, and silver-colored, silver oxide and silver, copper, zinc ion have the antibacterial and antibacterial action of broad spectrum activity, receive
Rice particle is antibacterial, antibacterial action is stronger, so that the present invention has stronger antibacterial, antibacterial functions.Plate film can be effectively protected
Floor base material plays the role of insect prevention antibacterial.Wherein the bottom be high polymer alloy composite layer, the wearing layer be for
Transparent antibacterial wearing layer, the waterproof layer are made of bamboo charcoal fiber material, and the flame-retardant layer is high molecular nanometer flame retarding material.
Non-slip texture is set in floor surface, improves safety, avoids tumble injury.
The beneficial effects of the present invention are: using macromolecule replaces solid wooden floor board, realize and recycle, protects country
Trees walk sustainable development route, and the cooperation of concaveconvex structure, effective solution are used between macromolecule layer and substrate layer and top layer
Timber and it is resin-bonded loosely the problem of.The floor efficiently uses various nano materials, plays insect prevention antibacterial and health-care effect,
And there is good heat preservation, thermal insulation guarantees the comfortable and safe of indoor environment.
Detailed description of the invention
Fig. 1 is structural front view of the invention；
Fig. 2 is substrate layer cross-sectional view in the present invention；
Wherein, 1- floor body, 2- cavity, 3- lightweight foam material, 31- through-hole, 4- plug, 5- top layer, 6- substrate layer, the bottom 7-
Layer, 8- high molecule nano material layer, 9- link block, 10- link slot, 11- wearing layer, 12- waterproof layer, 13- flame-retardant layer, 14- are slow
Rush layer, 15- base paint special, 16- ultraviolet light cured paint, 17- non-slip texture, 18- sealed elastic layer.
Specific embodiment
In order to deepen the understanding of the present invention, the present invention is done below in conjunction with drawings and examples and is further retouched in detail
It states, the embodiment is only for explaining the present invention, does not constitute and limits to protection scope of the present invention.
A kind of polymer nano-floor, including floor body 1, transversely section sets that there are two empty inside the floor body
Chamber 2, cavity 2 are arranged inside substrate layer 6, and the cavity 2 penetrates through the substrate layer 1, light filling foaming material in the cavity 2
Expect 3, several through-holes 31 are evenly distributed on the lightweight foam material, the two ends of the cavity 2 are equipped with for blocking cavity
Plug 4, the floor body 1 successively includes top layer 5, substrate layer 6 and bottom 7, the top layer 5 and the substrate from top to down
The high molecule nano material layer 8 with a thickness of 5mm is equipped between layer 6,8 upper and lower surface of high molecule nano material layer is equipped with company
Connect block 9, the top layer 5 and substrate layer 6 is equipped with and the mutually matched link slot 10 of the link block 9, on the top layer 5
Side is equipped with wearing layer 11, is successively arranged waterproof layer 12,13 and of flame-retardant layer between the substrate layer 6 and the bottom 7 from top to bottom
Buffer layer 14.11 upper surface of wearing layer coats one layer of base paint special 15, and the 15 top showering of base paint special has one layer of purple
Outer photocuring paint 16.The nano material that wavelength is 8-15um far infrared is uniformly provided in the high molecule nano material layer 8
Particle and with antibacterial, antibacterial functions inorganic nano material particle.The wavelength is that the nano material of 10um far infrared is micro-
Grain-by-grain seed selection is from titanium dioxide, zinc oxide and silica, and described to have antibacterial, antibacterial functions inorganic nano material particle be to be selected from
Aoxidize silver nano-particle.
The upper surface on the floor 1 sets indent and convex non-slip texture 17, is covered with one on the inner surface of the link slot
Layer sealed elastic layer 18.
A kind of production method of high molecule nano material layer is provided, the specific steps are as follows:
S1: material mixture ratio, the component including following parts by weight are made, 75 parts of Corvics, 35 parts of vinyl acetate trees
Rouge, 13 parts of epoxy resin, 25 parts of acrylic resins, 17 parts of phenolic resin, 45 parts of active fine calcium carbonates, 8 parts of fire retardants, 1 part
Paraffin, 5 parts of nano-titanium dioxides, 5 parts of nano zine oxides, 3 parts of nano silicas, 3 parts of nano phase ag_2 os, 2 parts of processing aids,
2 parts of plasticized modifiers, 1 part of stabilizer, 0.8 part of lubricant；
S2: by nano-titanium dioxide, nano zine oxide is ground into the powder of 70nm after nano silica and nano phase ag_2 o mixing
End is spare；
S3: gained powder in S2 is put into after irradiating 26min under the conditions of the far infrared of wavelength 10um and is taken out, then place it in first
25min, drying for standby after filtering are impregnated in base methyl acrylate solution；
S4: powder obtained in proportioned material and S3 is mixed to be added in high temperature pot and be stirred by mixing material, and high temperature pot exists
Material is stirred in unit time, the temperature in high temperature pot is maintained at 150 DEG C or more by whipping process, right after the completion of stirring
Material is cooled down rapidly, then material is being carried out storage placement, until its temperature reaches room temperature, to the material progress after stirring
Cooling temperature is no more than 45 DEG C rapidly, and to the material progress after stirring, standing time after cooling is 18h rapidly；
S5: squeezing out substrate, puts the material that mixing is completed into extruder and handles, and is simultaneously squeezed material using molding die
High molecule nano material layer is obtained out, the temperature of the extruding zone of the extruder is at 180 DEG C, and the temperature of molding die is 200
℃。
Wherein the stabilizer is the mixture of metal soap and phosphorous acid lipid.
Originally it implements and a kind of polymer nano-floor is provided, answered each laminate by adhesive resistant to high temperature
It closes, the cooperation of concaveconvex structure is used between the high molecule nano material layer 8 and substrate layer 6 and top layer 5, connect more secured.
Floor body 1 uses hollow design, inside setting cavity 2, and adds lightweight foam material 3 wherein, enhances heat insulation effect,
Intensity and elasticity are increased, soundproof effect is good.One layer of special bottom is increased between floor body 1 and ultraviolet light cured paint 16
Paint 15, lacquer painting is not easily to fall off.Titanium dioxide, zinc oxide and silica nanoparticles can absorb and to reflect human body most desirable
Wavelength is 8-15 um far infrared, and far infrared is referred to as " sunlight lifeline " in foreign countries, and making originally to implement has preferably
Infrared health function, and the antibacterial and antibacterial action of silver, silver oxide and silver, copper, zinc ion with broad spectrum activity, nanoparticle suppression
Bacterium, antibacterial action are stronger, so that originally implementing with stronger antibacterial, antibacterial functions.Floor base can be effectively protected in plate film
Material plays the role of insect prevention antibacterial.Wherein the bottom 7 is high polymer alloy composite layer, and the wearing layer 11 is
Bright antibacterial wearing layer, the waterproof layer 12 are made of bamboo charcoal fiber material, and the flame-retardant layer 13 is high molecular nanometer fire proofing
Layer, the buffer layer 14 are soft silica gel.Non-slip texture 17 is set in floor surface, improves safety, avoids tumble injury.
Originally the beneficial effect implemented is: it uses macromolecule and replaces solid wooden floor board, realize and recycle, protection country
Trees, walk sustainable development route, the cooperation of concaveconvex structure used between macromolecule layer and substrate layer and top layer, it is effective to solve
Determined timber and it is resin-bonded loosely the problem of.The floor efficiently uses various nano materials, plays insect prevention antibacterial and health care is made
With, and there is good heat preservation, thermal insulation guarantees the comfortable and safe of indoor environment.
It should be understood by those skilled in the art that the present invention is not limited to the above embodiments, above-described embodiment and explanation
It is merely illustrated the principles of the invention described in book, without departing from the spirit and scope of the present invention, the present invention also has
Various changes and modifications, these changes and improvements all fall within the protetion scope of the claimed invention.The claimed scope of the invention
It is defined by the appending claims and its equivalent thereof.
Claims (10)
1. a kind of polymer nano-floor, it is characterised in that: including floor body, transversely section is set inside the floor body
There is at least one cavity, the cavity penetrates through the floor body, light filling foamed material in the cavity, the cavity
Two ends are equipped with the plug for blocking cavity, and the floor body successively includes top layer, substrate layer and bottom, institute from top to down
It states and is equipped with high molecule nano material layer between top layer and the substrate layer, the high molecule nano material layer upper and lower surface is equipped with
Link block, the top layer and the substrate layer are equipped with and the mutually matched link slot of the link block, sets above the top layer
There is wearing layer, is successively arranged waterproof layer, flame-retardant layer and buffer layer between the substrate layer and the bottom from top to bottom.
2. a kind of polymer nano-floor as described in claim 1, it is characterised in that: the wearing layer upper surface coats one layer
Base paint special, the base paint special top showering have one layer of ultraviolet light cured paint.
3. a kind of polymer nano-floor as described in claim 1, it is characterised in that: in the high molecule nano material layer
It is even equipped with the nano material particle that wavelength is 8-15 microns of far infrareds and with antibacterial, antibacterial functions inorganic nano materials
Particle.
4. a kind of polymer nano-floor as described in claim 1, it is characterised in that: the upper surface on the floor is equipped with
Concave-convex non-slip texture.
5. a kind of polymer nano-floor as described in claim 1, it is characterised in that: the link block or the link slot
Outer surface on be covered with one layer of sealed elastic layer.
6. a kind of production method of polymer nano-floor as described in claim 1, it is characterised in that: the high molecular nanometer
The production method of material layer, the specific steps are as follows:
S1: material mixture ratio, the component including following parts by weight are made, 70-80 parts of Corvics, 30-40 parts of acetic acid second
Olefine resin, 10-15 parts of epoxy resin, 20-30 parts of acrylic resins, 15-20 parts of phenolic resin, the 30-60 parts of fine carbonic acid of activity
Calcium, 5-10 parts of fire retardants, 0.5-1 parts of paraffin, 4-6 parts of nano-titanium dioxides, 4-6 parts of nano zine oxides, 2-4 parts of nanometer titanium dioxides
Silicon, 2-4 parts of nano phase ag_2 os, 1-3 parts of processing aids, 1-3 parts of plasticized modifiers, 1-2 parts of stabilizers, 0.5-1 parts of lubricants；
S2: by nano-titanium dioxide, nano zine oxide is ground into 60-80nm after nano silica and nano phase ag_2 o mixing
Powder it is spare；
S3: gained powder in S2 being put into after irradiating 25-30min under the conditions of the far infrared of wavelength 8-15um and taken out, then by its
It is placed in methyl methacrylate solution and impregnates 20-30min, drying for standby after filtering；
S4: powder obtained in proportioned material and S3 is mixed to be added in high temperature pot and be stirred by mixing material, and high temperature pot exists
Material is stirred in unit time, the temperature in high temperature pot is maintained at 150 DEG C or more by whipping process, right after the completion of stirring
Material is cooled down rapidly, then material is being carried out storage placement, until its temperature reaches room temperature；
S5: squeezing out substrate, puts the material that mixing is completed into extruder and handles, and is simultaneously squeezed material using molding die
High molecule nano material layer is obtained out.
7. a kind of production method of polymer nano-floor as claimed in claim 6, it is characterised in that: the high molecular nanometer
Material layer with a thickness of 2 ~ 8mm.
8. a kind of production method of polymer nano-floor as described in claim 1, it is characterised in that: the stabilizer is gold
Belong at least one of soaps, phosphorous acid lipid, rare-earth stabilizer.
9. a kind of production method of polymer nano-floor as described in claim 1, it is characterised in that: right in the step S4
Material after stirring carries out temperature cooling rapidly and is no more than 45 DEG C, carries out placement after cooling rapidly to the material after stirring
Time is 15- 20h.
10. a kind of production method of polymer nano-floor as described in claim 1, it is characterised in that: in the step S5
Extruder extruding zone temperature between 150-200 DEG C, the temperature of molding die is between 180-220 DEG C.
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| CN201811253609.4A CN109372217A (en) | 2018-10-25 | 2018-10-25 | A kind of polymer nano-floor and its production method |
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| CN201811253609.4A CN109372217A (en) | 2018-10-25 | 2018-10-25 | A kind of polymer nano-floor and its production method |
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| CN109372217A true CN109372217A (en) | 2019-02-22 |
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| CN110982431A (en) * | 2019-12-18 | 2020-04-10 | 广东鸿业家具制造有限公司 | Preparation method of odorless environment-friendly paint |
| CN112024335A (en) * | 2020-09-09 | 2020-12-04 | 浙江品阁木业有限公司 | Production process of wood floor film |
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Application publication date: 20190222 |